US3434541A - In situ combustion process - Google Patents
In situ combustion process Download PDFInfo
- Publication number
- US3434541A US3434541A US674630A US3434541DA US3434541A US 3434541 A US3434541 A US 3434541A US 674630 A US674630 A US 674630A US 3434541D A US3434541D A US 3434541DA US 3434541 A US3434541 A US 3434541A
- Authority
- US
- United States
- Prior art keywords
- well
- production
- oil
- reservoir
- combustion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000002485 combustion reaction Methods 0.000 title description 45
- 238000011065 in-situ storage Methods 0.000 title description 13
- 238000004519 manufacturing process Methods 0.000 description 131
- 239000003921 oil Substances 0.000 description 66
- 238000000034 method Methods 0.000 description 34
- 238000002347 injection Methods 0.000 description 33
- 239000007924 injection Substances 0.000 description 33
- 239000007789 gas Substances 0.000 description 30
- 238000011084 recovery Methods 0.000 description 23
- 239000012530 fluid Substances 0.000 description 21
- 229930195733 hydrocarbon Natural products 0.000 description 17
- 150000002430 hydrocarbons Chemical class 0.000 description 17
- 239000004215 Carbon black (E152) Substances 0.000 description 15
- 230000015572 biosynthetic process Effects 0.000 description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 13
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 12
- 230000007423 decrease Effects 0.000 description 10
- 230000035699 permeability Effects 0.000 description 10
- 230000000694 effects Effects 0.000 description 7
- 239000001569 carbon dioxide Substances 0.000 description 6
- 229910002092 carbon dioxide Inorganic materials 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 230000006911 nucleation Effects 0.000 description 6
- 238000010899 nucleation Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000007791 liquid phase Substances 0.000 description 5
- 239000003208 petroleum Substances 0.000 description 5
- 238000005336 cracking Methods 0.000 description 4
- 239000010779 crude oil Substances 0.000 description 4
- 238000004821 distillation Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000011435 rock Substances 0.000 description 2
- 230000000153 supplemental effect Effects 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 101000635799 Homo sapiens Run domain Beclin-1-interacting and cysteine-rich domain-containing protein Proteins 0.000 description 1
- 241000184339 Nemophila maculata Species 0.000 description 1
- 102100030852 Run domain Beclin-1-interacting and cysteine-rich domain-containing protein Human genes 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000012056 semi-solid material Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- 239000011275 tar sand Substances 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/24—Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
- E21B43/243—Combustion in situ
Definitions
- This invention relates to the recovery of oil from subterranean reservoirs, and more particularly to a new and improved in-situ combustion process.
- combustion front is advanced through the reservoir in the direction of one or more production wells by the injection of a combustion-supporting gas through one or more injection wells.
- the combustion front is preceded by a high temperature zone, commonly called a retort zone, within which the reservoir oil is heated to effect a viscosity reduction and is subjected to distillation and cracking.
- Hydrocarbon fluids including the 3,434,541 Patented Mar.
- a new and improved concurrent in situ combustion process for the recovery of hydrocarbon fluids from a subterranean oil reservoir such as a tar sand or a more conventional petroleum crude oil formation.
- a combustion front is established in the reservoir and advanced through the reservoir in the direction of a production well by introducing a combustion-supporting gas through an injection Well.
- Hydrocarbon fluids are recovered from the reservoir through the production well by any suitable technique.
- the production well is choked until the bottomhole pressure thereof is increased by at least 10 atmospheres over the bottomhole pressure existing at the time the well was first subjected to choking.
- the production well then is opened in order to allow the bottomhole pressure thereof to decline and hydrocarbon fluids are withdrawn therefrom.
- the amount of oil recovered from the reservoir may be increased over that recovered by a conventional in situ combustion process.
- the production well is choked, as described above, after gas permeability is established between the injection well and the produc tion Well.
- the steps of opening and choking the well are repeated during the in-situ combustion drive.
- the present invention is carried out utilizing one or more injection Wells and one or more production wells extending from the surface of the earth into the subterranean reservoir.
- the injection and production wells may be located and spaced from one another in any desired pattern.
- the line drive pattern may be utilized in which a plurality of injection wells and a plurality of production wells are arranged in rows which are spaced from one another.
- Exemplary of other patterns which may be used are the so-called circular drive patterns in which a plurality of production wells are spaced about a central injection well.
- Typical circular drive patterns are the inverted five-spot, seven-spot, and nine-spot patterns.
- a concurrent in situ combustion drive is instituted within the reservoir by any suitable technique.
- Combustion may be initiated adjacent the injection well by locating an electrical or gas-fired heater within the Well and introducing a suitable combustion-supporting gas such as air through the well.
- a suitable combustion-supporting gas such as air
- the combustion front may be established by auto-oxidation.
- air which may be enriched with oxygen, may be injected through the injection well in order to slowly bring the reservoir oil up to the combustion temperature without the use of extraneous heating means.
- combustion will be initiated immediately adjacent the air injection well.
- air may be injected through an offset injection well in order to establish an adequate combustion front and the combustion front moved through the formation by the continued injection of air through this offset well.
- gaseous combustion products including carbon monoxide, carbon dioxide, nitrogen (where air is used as the combustion-supporting medium), and water are driven through the reservoir ahead of the combustion front and the retort zone.
- combustion products act as a displacing and heating medium with respect to the reservoir oil.
- the reservoir oil is contacted by the combustion products, it is heated, thus effecting a viscosity reduction, and driven through the reservoir in the direction of the production well.
- the reservoir oil undergoes distillation and/or cracking in the vicinity of the retort zone and the distillation and cracking products are driven ahead of the combustion zone, also functioning as heating and displacing fluids.
- the production well is operated in a conventional manner to recover hydrocarbon fluids from the reservoir.
- the production well is choked sutiiciently to effect an increase of atmospheres or more in the pressure within the interval of the well at the depth of the reservoir.
- the pressure within this interval commonly is termed the bottomhole pressure of the well and will be so designated in this description and in the appended claims.
- the production well may be throttled sufiiciently to completely shut it in such that no production is obtained during the time that the bottomhole pressure is being increased.
- the production well may be operated during this step at a reduced production rate so long as it is choked sufficiently to effect at least the specified bottomhole pressure increase.
- the production well After the production well has remained choked for the desired period of time, it is opened, with the attendant result that the bottomhole pressure of the well decreases.
- the decrease in bottomhole pressure is accompanied by a similar pressure decrease within the reservoir adjacent the production well.
- the gas in liquid phase solution will tend to come out of solution and expand.
- a portion of the dissolved gas will undergo bubble nucleation and expansion within the liquid phase.
- a portion of the gas is surrounded by the liquid phase.
- the bubbles will tend to expand, while still remaining enclosed by the liquid phase, such that the oil or water within which such gas bubbles are contained increases in volume.
- the tendency of the gas dissolved in the liquid phase to undergo bubble nucleation and expansion varies with the rate of pressure decrease.
- the effect of bubble nucleation and expansion is enhanced by effecting a rapid pressure reduction. It is therefore preferred in carrying out the present invention to effect a rapid drawdown of the production well as it is opened to production.
- the choking step should be carried out so as to effect an increase in bottomhole pressure of at least 10 atmospheres.
- the rate at which the pressure will increase during the choking step will vary widely, depending upon the particular reservoir involved. In some cases the bottomhole pressure will be increased by 10 atmospheres, or considerably more than 10 atmospheres, within a period of several hours, particularly where the production well is completely shut in during the choking step.
- While the manipulation of the production well in accordance with the steps of the present invention may be undertaken at any time during the combustion process it is particularly beneficial after gas permeability has been established between the injection well and the production well.
- the gas-saturated zones will provide effective recovery avenues leading to the production well through which oil released by bubble nucleation and expansion may flow.
- the combustion products present adjacent the production well when such gas permeability has been established are particularly effective in the bubble nucleation and expansion process.
- the combustion products typically will include about 12% carbon dioxide, with a large portion of the remainder being nitrogen which was present in the originally injected air.
- the carbon dioxide component will be readily dissolved in the reservoir oil whereas the nitrogen component will tend to proceed through the reservoir under the influence of the existing pressure gradient, it being noted in this regard that the nitrogen component will be much less soluble in the reservoir oil than the carbon dioxide.
- the dissolved carbon dioxide produces expansion of the oil whereas the nitrogen will tend to act as a driving fluid, thus displacing the reservoir oil toward the production well.
- the nitrogen will function in this manner, both during the period in which the well is choked and also during the subsequent pressure drawdown step.
- the stage of the combustion drive at which gas permeability between the injection and production wells is established can be ascertained by techniques well known to those skilled in the art.
- the production well efiiuent may be monitored with regard to the pres ence of combustion products such as nitrogen and carbon dioxide and upon the detection of such products in measureable amounts it may be assumed that gas permeability between the injection and production wells has been established.
- combustion-supporting gas into the reservoir via the injection well should be continued during manipulation of the production well in accordance with the present invention. This will aid in the maintenance of a significant pressure gradient extending through the reservoir from the injection well to the production well with the attendant beneficial results noted hereinbefore.
- a typical history of a production well operated in accordance with the present invention is as follows.
- the production rate will decrease immediately and, of course, will fall to zero if the well is shut-in.
- the bottomhole pressure of the well will increase as described before.
- the pro duction rate will increase to a value greater than the rate existing immediately prior to the choking step.
- the production rate will reach a maximum, at which point it will then decrease with time.
- the choking and opening steps may be repeated and this normally will be preferred in carrying out the present invention.
- the optimum repetition frequency of these steps will vary from reservoir to reservoir and from well to well, depending upon local conditions. It normally will be desirable to repeat the choking of the well only after the oil production rate during the opening step has declined from the maximum oil production rate by a value equivalent to at least 10% of the differential between the oil production rate observed immediately before choking of the well and the maximum oil production rate after opening of the well.
- the choking step should not thereafter be repeated until the production rate has declined by at least four barrels per day, i.e., to a level of forty-six barrels per day. While longer intervals between the repetitive steps of the invention may beand usually will beobserved, it is desirable to repeat the choking step before the production rate has declined by more than of the aforementioned production rate differential. Thus, in the example given above, the choking step should be repeated before the production rate has declined below fourteen barrels of oil per day.
- the foregoing criteria is to be applied with regard to the production rate differential existing before the well is first choked in and the maximum production rate obtained after opening of the well on each cycle of operation.
- the first opening step should be instituted when the oil production rate has declined to a value within the range of forty barrels per day (25 of the production rate differential of forty barrels per day) and twenty barrels per day (75% of the production rate differential).
- the subsequent choking step should be instituted when the oil production rate has declined to a rate within the range of thirty-seven barrels per day (25% of the production rate differential of thirty-six barrels per day) and nineteen barrels per day (75% of the production rate differential).
- step (c) The method of claim 1, wherein said production well is choked in step (c) for a period of no more than thirty (30) days.
- step (c) is initiated after gas permeability is established between said injection well and said production well.
- step (d) 7. The method of claim 1, wherein hydrocarbon fluids are recovered in accordance wth step (d) until the oil production rate has declined from the maximum oil production rate obtained after opening the production well in step (d) by an amount equivalent to at least 10% of the production rate differential between the oil production rate existing before choking the production well in step (c) and said maximum oil production rate in step (d), and thereafter repeating steps (c) and (d).
- steps (c) and (d) are repeated before the oil production rate has declined from said maximum oil production rate in step (d) by more than 90% of said production rate differential.
- step (d) hydrocarbon fluids are recovered in accordance with step (d) until the oil production rate has declined from the maximum oil production rate obtained after opening the production well in step (d) by an amount within the range of 25% to 75% of the production rate differential between the oil production rate existing before choking the production well in step (c) and said maximum oil production rate in step (d), and thereafter repeating steps (c) and (d).
- step (d) The method of claim 10, wherein hydrocarbon fluids are recovered in accordance with step (d) until the oil production rate has declined from the maximum oil production rate obtained after opening the production well in step (d) by an amount within the range of 25 to 75% of the production rate differential between the oil production rate existing before choking the production Well in step (c) and said maximum oil production rate in step (d), and thereafter repeating steps (c) and (d).
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Geology (AREA)
- Mining & Mineral Resources (AREA)
- Physics & Mathematics (AREA)
- Environmental & Geological Engineering (AREA)
- Fluid Mechanics (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Feeding And Controlling Fuel (AREA)
Description
US. Cl. 166-256 11 Claims ABSTRACT OF THE DISCLOSURE This specification discloses an in situ combustion process in which the production Well or wells are alternately choked and opened to eflect an increase in oil recovery. The production well is choked, preferably to the extent of shutting it in, until an increase in bottomhole pressure of at least atmospheres is obtained. Thereafter, the production well is opened and hydrocarbon fluids are recovered therefrom as the bottomhole pressure declines. Preferably, the choking step is instituted after gas permeability is established between the injection and production wells. Also, the choking and opening steps may be repeated at appropriate intervals during the process.
BACKGROUND OF THE INVENTION Field of the invention This invention relates to the recovery of oil from subterranean reservoirs, and more particularly to a new and improved in-situ combustion process.
DESCRIPTION OF THE PRIOR ART In the recovery of petroleum crude oils from subterranean reservoirs it usually is possible to recover only a minor portion of the oil originally in place in a reservoir by the so-called primary recovery methods, i.e., those methods which utilize only the natural forces present in the reservoir. Thus, a variety of supplemental recovery techniques have been employed in order to increase the recovery of oil from subterranean reservoirs. In these supplemental techniques which are commonly referred to as secondary recovery operations, although they may be primary or tertiary in sequence of employment, energy is supplied to the reservoir as a means of moving the oil in the reservoir to suitable production wells through which it may be withdrawn to the surface of the earth. Perhaps the most common secondary recovery processes are those in which displacing fluids such as Water or gas are injected into an oil-bearing reservoir in order to displace the oil therein to suitable production wells. Other widely known secondary recovery processes are the so-called huff and puff gas injection techniques such as the procedure disclosed by US. Patent No. 3,123,134 to I. R. Kyte et al. In this procedure the reservoir typically is closed off to production and a suitable gas, such as air, natural gas, combustion products, etc., is injected into the reservoir. Thereafter, gas injection is terminated and the reservoir is placed on production through the wells used for gas injection and/ or additional production wells.
Another secondary recovery process which is showing increasing promise is the concurrent or forward burn insitu combustion technique. In this procedure a portion of the reservoir oil is burned or oxidized in-situ to create a combustion front. This combustion front is advanced through the reservoir in the direction of one or more production wells by the injection of a combustion-supporting gas through one or more injection wells. The combustion front is preceded by a high temperature zone, commonly called a retort zone, within which the reservoir oil is heated to effect a viscosity reduction and is subjected to distillation and cracking. Hydrocarbon fluids including the 3,434,541 Patented Mar. 25, 1969 heated, relatively low viscosity oil and the distillation and cracking products of the oil then are displaced to production wells where they are withdrawn to the surface of the earth. The in situ combustion procedure is particularly useful in the recovery of thick, heavy oils such as viscous petroleum crude oils and the heavy, tar-like hydrocarbons present in tar sands. While these tar-like hydrocarbons may exist as solid or semi-solid materials in their native state, they undergo a sharp viscosity reduction upon heating and in an in situ combustion process behave like the more conventional petroleum crude oils.
In in situ combustion oil recovery procedures various techniques have been proposed which involve the manipulation of one or more production wells in the recovery pattern. These techniques typically are for the purpose of controlling the movement of the combustion front or the flow of fluids wtihin the formation, particularly those fluids in the vicinity of the retort Zone and combustion zone. Thus, in US. Patent No. 2,390,770 to Barton et al. there is disclosed a procedure for controlling the movement of the combustion front by such procedures as throttling, to the extent if necessary of closing, a production well toward which the combustion front is preferentially moving and/ or injecting various fluids such as drilling mud or water into such a well. Also, in U.S. Patent No. 2,862,557 to van Utenhove et al. there is disclosed an in situ combustion process in which gas is injected through a production well in order to bring about a pressure gradient reversal within the formation so as to force condensed products away from the production well into a heated portion of the formation.
SUMMARY OF THE INVENTION In accordance With the present invention, there is provided a new and improved concurrent in situ combustion process for the recovery of hydrocarbon fluids from a subterranean oil reservoir such as a tar sand or a more conventional petroleum crude oil formation. In carrying out the invention, a combustion front is established in the reservoir and advanced through the reservoir in the direction of a production well by introducing a combustion-supporting gas through an injection Well. Hydrocarbon fluids are recovered from the reservoir through the production well by any suitable technique. Thereafter, the production well is choked until the bottomhole pressure thereof is increased by at least 10 atmospheres over the bottomhole pressure existing at the time the well was first subjected to choking. The production well then is opened in order to allow the bottomhole pressure thereof to decline and hydrocarbon fluids are withdrawn therefrom. By this procedure the amount of oil recovered from the reservoir may be increased over that recovered by a conventional in situ combustion process.
In one embodiment of the invention the production well is choked, as described above, after gas permeability is established between the injection well and the produc tion Well. In a further embodiment of the invention the steps of opening and choking the well are repeated during the in-situ combustion drive.
DESCRIPTION OF SPECIFIC EMBODIMENTS The present invention is carried out utilizing one or more injection Wells and one or more production wells extending from the surface of the earth into the subterranean reservoir. The injection and production wells may be located and spaced from one another in any desired pattern. For example, the line drive pattern may be utilized in which a plurality of injection wells and a plurality of production wells are arranged in rows which are spaced from one another. Exemplary of other patterns which may be used are the so-called circular drive patterns in which a plurality of production wells are spaced about a central injection well. Typical circular drive patterns are the inverted five-spot, seven-spot, and nine-spot patterns. The above and other patterns for effecting secondary recovery operations are well known to those skilled in the art. For a more detailed description of such patterns, reference is made to Uren, L. C., Petroleum Production Engineering-Oil Field Exploitation, 3d ed, McGraw- Hill Book Company, New York, Toronto, London, 1953, and more particularly to the section entitled Arrangement of Injection and Production Wells in Waterfiooding, appearing at pages 528-532. While the well patterns described in Uren are with reference to waterflooding operations, it will be recognized that such patterns are also applicable to in situ combustion procedures.
For the purpose of simplicity in describing the invention, reference sometimes will be made herein to only one injection Well and one production well in a recovery pattern. However, it will be recognized that in practical applications of the invention a plurality of such wells, particularly the production wells, may be and in most cases will be utilized.
In practicing the invention, a concurrent in situ combustion drive is instituted within the reservoir by any suitable technique. Combustion may be initiated adjacent the injection well by locating an electrical or gas-fired heater within the Well and introducing a suitable combustion-supporting gas such as air through the well. Also, in some reservoirs the combustion front may be established by auto-oxidation. Thus, air, which may be enriched with oxygen, may be injected through the injection well in order to slowly bring the reservoir oil up to the combustion temperature without the use of extraneous heating means.
Normally, combustion will be initiated immediately adjacent the air injection well. However, in some instances it may be desirable to use separate wells for ignition and air injection. For example, it sometimes happens that the well utilized for ignition becomes damaged because of the extremely high temperatures developed. In this case, air may be injected through an offset injection well in order to establish an adequate combustion front and the combustion front moved through the formation by the continued injection of air through this offset well.
As the combustion front advances through the reservoir in the direction of the production well, gaseous combustion products including carbon monoxide, carbon dioxide, nitrogen (where air is used as the combustion-supporting medium), and water are driven through the reservoir ahead of the combustion front and the retort zone. These combustion products act as a displacing and heating medium with respect to the reservoir oil. As the reservoir oil is contacted by the combustion products, it is heated, thus effecting a viscosity reduction, and driven through the reservoir in the direction of the production well. In addition, the reservoir oil undergoes distillation and/or cracking in the vicinity of the retort zone and the distillation and cracking products are driven ahead of the combustion zone, also functioning as heating and displacing fluids.
During the initial phase of the combustion drive the production well is operated in a conventional manner to recover hydrocarbon fluids from the reservoir. At a suitable stage of the process, preferably after gas permeability between the injection and the production well has been established as described hereinafter, the production well is choked sutiiciently to effect an increase of atmospheres or more in the pressure within the interval of the well at the depth of the reservoir. The pressure within this interval commonly is termed the bottomhole pressure of the well and will be so designated in this description and in the appended claims. The production well may be throttled sufiiciently to completely shut it in such that no production is obtained during the time that the bottomhole pressure is being increased. Alternatively, the production well may be operated during this step at a reduced production rate so long as it is choked sufficiently to effect at least the specified bottomhole pressure increase.
As the bottomhole pressure of the production well increases, a corresponding pressure increase takes place within the reservoir adjacent to the production well. In response to this pressure increase, gas in the formation is forced into solution with the reservoir oil and, similarly, into solution with water which may be present in the reservoir. This dissolved gas has the effect of reducing the oil viscosity, swelling the oil, and also reducing the interfacial tension between the oil and water which may be present. During the time that the production well is choked, the pressure gradient in the reservoir from the injection well in the direction of the production well may be reduced. However, some pressure gradient will still exist so that there is some movement of the reservoir oil through the formation in the direction of the production oil.
After the production well has remained choked for the desired period of time, it is opened, with the attendant result that the bottomhole pressure of the well decreases. The decrease in bottomhole pressure is accompanied by a similar pressure decrease within the reservoir adjacent the production well. As this takes place the gas in liquid phase solution will tend to come out of solution and expand. Depending upon the rate of pressure decline, as described hereinafter, a portion of the dissolved gas will undergo bubble nucleation and expansion within the liquid phase. In this regard, a portion of the gas is surrounded by the liquid phase. As the pressure within the formation further decreases, the bubbles will tend to expand, while still remaining enclosed by the liquid phase, such that the oil or water within which such gas bubbles are contained increases in volume. As an exemplary illustration, consider a globule of oil containing dissolved gas and residing in an individual pore within the reservoir rock. As the pressure decreases, the globule of oil containing an expanding gas bubble is displaced out of the pore space. Thus, the oil may be displaced through the reservoir rock in the direction of the production well and the overall oil recovery is enhanced.
As noted previously, the tendency of the gas dissolved in the liquid phase to undergo bubble nucleation and expansion varies with the rate of pressure decrease. In this regard, the effect of bubble nucleation and expansion is enhanced by effecting a rapid pressure reduction. It is therefore preferred in carrying out the present invention to effect a rapid drawdown of the production well as it is opened to production.
An increase of 10 atmospheres during the choking step normally will be necessary in order to provide for a significant increase in oil recovery by the bubble nucleation and expansion mechanism described above. Thus, at a minimum, the choking step should be carried out so as to effect an increase in bottomhole pressure of at least 10 atmospheres. The rate at which the pressure will increase during the choking step will vary widely, depending upon the particular reservoir involved. In some cases the bottomhole pressure will be increased by 10 atmospheres, or considerably more than 10 atmospheres, within a period of several hours, particularly where the production well is completely shut in during the choking step. Even where a rapid pressure build-up is obtained it is preferred to continue the choking step for a period of at least one-quarter of a day in order to obtain an increase in pressure within the formation a significant distance from the production well. Even in reservoirs of relatively low permeability no advantage will be obtained by continuing the choking step for a period of more than thirty days. Thus, it will be preferred in carrying out the invention to choke the production well for a time period of at least one-quarter day but no longer than thirty days.
While the manipulation of the production well in accordance with the steps of the present invention may be undertaken at any time during the combustion process it is particularly beneficial after gas permeability has been established between the injection well and the production well. The gas-saturated zones will provide effective recovery avenues leading to the production well through which oil released by bubble nucleation and expansion may flow. Also, the combustion products present adjacent the production well when such gas permeability has been established are particularly effective in the bubble nucleation and expansion process. In this regard, the combustion products typically will include about 12% carbon dioxide, with a large portion of the remainder being nitrogen which was present in the originally injected air. The carbon dioxide component will be readily dissolved in the reservoir oil whereas the nitrogen component will tend to proceed through the reservoir under the influence of the existing pressure gradient, it being noted in this regard that the nitrogen component will be much less soluble in the reservoir oil than the carbon dioxide. The dissolved carbon dioxide produces expansion of the oil whereas the nitrogen will tend to act as a driving fluid, thus displacing the reservoir oil toward the production well. The nitrogen will function in this manner, both during the period in which the well is choked and also during the subsequent pressure drawdown step.
The stage of the combustion drive at which gas permeability between the injection and production wells is established can be ascertained by techniques well known to those skilled in the art. For example, the production well efiiuent may be monitored with regard to the pres ence of combustion products such as nitrogen and carbon dioxide and upon the detection of such products in measureable amounts it may be assumed that gas permeability between the injection and production wells has been established.
The introduction of combustion-supporting gas into the reservoir via the injection well should be continued during manipulation of the production well in accordance with the present invention. This will aid in the maintenance of a significant pressure gradient extending through the reservoir from the injection well to the production well with the attendant beneficial results noted hereinbefore.
The steps of choking the well and thereafter opening it to production may be repeated at appropriate intervals during the combustion drive until oil recovery becomes uneconomical. A typical history of a production well operated in accordance with the present invention is as follows. When the well is choked, the production rate will decrease immediately and, of course, will fall to zero if the well is shut-in. During this time the bottomhole pressure of the well will increase as described before. When the well is thereafter opened, after a bottomhole pressure increase of atmospheres or more, the pro duction rate will increase to a value greater than the rate existing immediately prior to the choking step. The production rate will reach a maximum, at which point it will then decrease with time.
As noted previously, the choking and opening steps may be repeated and this normally will be preferred in carrying out the present invention. The optimum repetition frequency of these steps will vary from reservoir to reservoir and from well to well, depending upon local conditions. It normally will be desirable to repeat the choking of the well only after the oil production rate during the opening step has declined from the maximum oil production rate by a value equivalent to at least 10% of the differential between the oil production rate observed immediately before choking of the well and the maximum oil production rate after opening of the well. Thus, for a well in which the production rate immediately before choking was ten barrels of oil per day and for which a maximum production rate of fifty barrels of oil per day was obtained upon opening of the well, the choking step should not thereafter be repeated until the production rate has declined by at least four barrels per day, i.e., to a level of forty-six barrels per day. While longer intervals between the repetitive steps of the invention may beand usually will beobserved, it is desirable to repeat the choking step before the production rate has declined by more than of the aforementioned production rate differential. Thus, in the example given above, the choking step should be repeated before the production rate has declined below fourteen barrels of oil per day.
It is preferred in carrying out the invention to repeat the choking step after the production rate has declined by a value within the range of 25% to 75% of the production rate differential between the oil production rate existing immediately before choking the well and the maximum oil production rate obtained after opening of the well. For most reservoir and well systems, operating within this range will result in the most economical rate of oil recovery with consideration given to production which is lost during the choking steps.
It is to be recognized that the foregoing criteria is to be applied with regard to the production rate differential existing before the well is first choked in and the maximum production rate obtained after opening of the well on each cycle of operation. Thus, when operating within the preferred range of 25% to 75% of the production rate differential in the example given above, the first opening step should be instituted when the oil production rate has declined to a value within the range of forty barrels per day (25 of the production rate differential of forty barrels per day) and twenty barrels per day (75% of the production rate differential). If upon the next subsequent opening step the oil production rate rises to a maximum of forty-six barrels per day, the subsequent choking step should be instituted when the oil production rate has declined to a rate within the range of thirty-seven barrels per day (25% of the production rate differential of thirty-six barrels per day) and nineteen barrels per day (75% of the production rate differential).
Having described specific embodiments of the instant invention it will be understood that further modifications thereof may be suggested to those skilled in the art, and it is intended to cover all such modifications as fall within the scope of the appended claims.
What is claimed is:
1. In the recovery of hydrocarbon fluids from a subterranean oil reservoir penetrated by an injection well and a production well, the method comprising:
(a) establishing a combustion front in said formation and advancing said combustion front through said formation in the direction of said production well by introducing a combustion-supporting gas through said injection well;
(b) recovering hydrocarbon fluids from said formation through said production well;
(0) choking said production well until the bottomhole pressure of said production well is increased by at least 10 atmospheres; and
(d) opening said production well and recovering hydrocarbon fluids therefrom as the bottomhole pressure of said well declines.
2. The method of claim 1, wherein said well is shut-in during step (c).
3. The method of claim 1, wherein said production well is choked in step (c) for a period of no more than thirty (30) days.
4. The method of claim 3, wherein said production well is choked in step (c) for a period of at least onequarter A) day.
5. The method of claim 1, wherein step (c) is initiated after gas permeability is established between said injection well and said production well.
6. The method of claim 1, further comprising repeating steps (c) and (d).
7. The method of claim 1, wherein hydrocarbon fluids are recovered in accordance wth step (d) until the oil production rate has declined from the maximum oil production rate obtained after opening the production well in step (d) by an amount equivalent to at least 10% of the production rate differential between the oil production rate existing before choking the production well in step (c) and said maximum oil production rate in step (d), and thereafter repeating steps (c) and (d).
8. The method of claim 7, wherein steps (c) and (d) are repeated before the oil production rate has declined from said maximum oil production rate in step (d) by more than 90% of said production rate differential.
9. The method of claim 1, wherein hydrocarbon fluids are recovered in accordance with step (d) until the oil production rate has declined from the maximum oil production rate obtained after opening the production well in step (d) by an amount within the range of 25% to 75% of the production rate differential between the oil production rate existing before choking the production well in step (c) and said maximum oil production rate in step (d), and thereafter repeating steps (c) and (d).
10. In the recovery of hydrocarbon fluids from a subterranean oil reservoir penetrated by an injection well and a production well, the method comprising:
(a) establishing a combustion front in said formation and advancing said combustion front through said formation in the direction of said production well by introducing a combustion-supporting gas through said injection well;
(b) recovering hydrocarbon fluids from said formation through said production well;
(0) after gas permeability is established between said injection well and said production well, choking said production well for a period within the range of one- 8 quarter A4) day to thirty (30) days and effecting an increase in the bottomhole pressure of said production well of at least 10 atmospheres; and
((1) opening said production Well and recovering hydrocarbon fluids therefrom as the bottomhole pressure of said well declines.
11. The method of claim 10, wherein hydrocarbon fluids are recovered in accordance with step (d) until the oil production rate has declined from the maximum oil production rate obtained after opening the production well in step (d) by an amount within the range of 25 to 75% of the production rate differential between the oil production rate existing before choking the production Well in step (c) and said maximum oil production rate in step (d), and thereafter repeating steps (c) and (d).
References Cited UNITED STATES PATENTS 2,390,770 11/1945 Barton et a1. 166-11 2,862,557 12/ 1958 Baron van Utenhove et al.
166-11 3,115,928 12/1963 Campion et al. 166-11 3,155,160 11/1964 Craig et al. 166-40 3,174,544 3/1965 Campion et al. 166-11 3,182,721 5/1965 Hardy 166-11 3,232,345 2/1966 Trantham et al. 166-11 X 3,280,910 10/1966 Crider 166-11 3,332,482 7/ 1967 Trantham 166-2 STEPHEN J. NOVOSAD, Primary Examiner.
US. Cl. X.R. 166-263, 272
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US67463067A | 1967-10-11 | 1967-10-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3434541A true US3434541A (en) | 1969-03-25 |
Family
ID=24707346
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US674630A Expired - Lifetime US3434541A (en) | 1967-10-11 | 1967-10-11 | In situ combustion process |
Country Status (1)
Country | Link |
---|---|
US (1) | US3434541A (en) |
Cited By (43)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3771598A (en) * | 1972-05-19 | 1973-11-13 | Tennco Oil Co | Method of secondary recovery of hydrocarbons |
US3999606A (en) * | 1975-10-06 | 1976-12-28 | Cities Service Company | Oil recovery rate by throttling production wells during combustion drive |
US4062404A (en) * | 1976-09-30 | 1977-12-13 | The United States Of America As Represented By The United States Energy Research And Development Administration | Method for in situ combustion |
US4127172A (en) * | 1977-09-28 | 1978-11-28 | Texaco Exploration Canada Ltd. | Viscous oil recovery method |
US4127170A (en) * | 1977-09-28 | 1978-11-28 | Texaco Exploration Canada Ltd. | Viscous oil recovery method |
US4359091A (en) * | 1981-08-24 | 1982-11-16 | Fisher Charles B | Recovery of underground hydrocarbons |
US4362212A (en) * | 1979-07-19 | 1982-12-07 | Helmut Schulz | Method for enhanced petroleum oil recovery |
US4465137A (en) * | 1982-06-25 | 1984-08-14 | Texaco Inc. | Varying temperature oil recovery method |
US4641709A (en) * | 1985-05-17 | 1987-02-10 | Conoco Inc. | Controlling steam distribution |
US4687057A (en) * | 1985-08-14 | 1987-08-18 | Conoco, Inc. | Determining steam distribution |
US4718489A (en) * | 1986-09-17 | 1988-01-12 | Alberta Oil Sands Technology And Research Authority | Pressure-up/blowdown combustion - a channelled reservoir recovery process |
US20020027001A1 (en) * | 2000-04-24 | 2002-03-07 | Wellington Scott L. | In situ thermal processing of a coal formation to produce a selected gas mixture |
US20020029885A1 (en) * | 2000-04-24 | 2002-03-14 | De Rouffignac Eric Pierre | In situ thermal processing of a coal formation using a movable heating element |
US20030100451A1 (en) * | 2001-04-24 | 2003-05-29 | Messier Margaret Ann | In situ thermal recovery from a relatively permeable formation with backproduction through a heater wellbore |
US20030111223A1 (en) * | 2001-04-24 | 2003-06-19 | Rouffignac Eric Pierre De | In situ thermal processing of an oil shale formation using horizontal heat sources |
US20050051327A1 (en) * | 2003-04-24 | 2005-03-10 | Vinegar Harold J. | Thermal processes for subsurface formations |
US6932155B2 (en) | 2001-10-24 | 2005-08-23 | Shell Oil Company | In situ thermal processing of a hydrocarbon containing formation via backproducing through a heater well |
US7011154B2 (en) | 2000-04-24 | 2006-03-14 | Shell Oil Company | In situ recovery from a kerogen and liquid hydrocarbon containing formation |
US7040400B2 (en) | 2001-04-24 | 2006-05-09 | Shell Oil Company | In situ thermal processing of a relatively impermeable formation using an open wellbore |
US7066254B2 (en) | 2001-04-24 | 2006-06-27 | Shell Oil Company | In situ thermal processing of a tar sands formation |
US7073578B2 (en) | 2002-10-24 | 2006-07-11 | Shell Oil Company | Staged and/or patterned heating during in situ thermal processing of a hydrocarbon containing formation |
US7077199B2 (en) | 2001-10-24 | 2006-07-18 | Shell Oil Company | In situ thermal processing of an oil reservoir formation |
US7090013B2 (en) | 2001-10-24 | 2006-08-15 | Shell Oil Company | In situ thermal processing of a hydrocarbon containing formation to produce heated fluids |
US7104319B2 (en) | 2001-10-24 | 2006-09-12 | Shell Oil Company | In situ thermal processing of a heavy oil diatomite formation |
US7165615B2 (en) | 2001-10-24 | 2007-01-23 | Shell Oil Company | In situ recovery from a hydrocarbon containing formation using conductor-in-conduit heat sources with an electrically conductive material in the overburden |
US20070137857A1 (en) * | 2005-04-22 | 2007-06-21 | Vinegar Harold J | Low temperature monitoring system for subsurface barriers |
US20070289733A1 (en) * | 2006-04-21 | 2007-12-20 | Hinson Richard A | Wellhead with non-ferromagnetic materials |
US7320364B2 (en) | 2004-04-23 | 2008-01-22 | Shell Oil Company | Inhibiting reflux in a heated well of an in situ conversion system |
US20080017370A1 (en) * | 2005-10-24 | 2008-01-24 | Vinegar Harold J | Temperature limited heater with a conduit substantially electrically isolated from the formation |
US20080093071A1 (en) * | 2005-01-13 | 2008-04-24 | Larry Weiers | In Situ Combustion in Gas Over Bitumen Formations |
US7540324B2 (en) | 2006-10-20 | 2009-06-02 | Shell Oil Company | Heating hydrocarbon containing formations in a checkerboard pattern staged process |
US20090321071A1 (en) * | 2007-04-20 | 2009-12-31 | Etuan Zhang | Controlling and assessing pressure conditions during treatment of tar sands formations |
US20100155070A1 (en) * | 2008-10-13 | 2010-06-24 | Augustinus Wilhelmus Maria Roes | Organonitrogen compounds used in treating hydrocarbon containing formations |
US7866386B2 (en) | 2007-10-19 | 2011-01-11 | Shell Oil Company | In situ oxidation of subsurface formations |
US8151907B2 (en) | 2008-04-18 | 2012-04-10 | Shell Oil Company | Dual motor systems and non-rotating sensors for use in developing wellbores in subsurface formations |
US8327932B2 (en) | 2009-04-10 | 2012-12-11 | Shell Oil Company | Recovering energy from a subsurface formation |
US8631866B2 (en) | 2010-04-09 | 2014-01-21 | Shell Oil Company | Leak detection in circulated fluid systems for heating subsurface formations |
US8701768B2 (en) | 2010-04-09 | 2014-04-22 | Shell Oil Company | Methods for treating hydrocarbon formations |
US8820406B2 (en) | 2010-04-09 | 2014-09-02 | Shell Oil Company | Electrodes for electrical current flow heating of subsurface formations with conductive material in wellbore |
US9016370B2 (en) | 2011-04-08 | 2015-04-28 | Shell Oil Company | Partial solution mining of hydrocarbon containing layers prior to in situ heat treatment |
US9033042B2 (en) | 2010-04-09 | 2015-05-19 | Shell Oil Company | Forming bitumen barriers in subsurface hydrocarbon formations |
US9309755B2 (en) | 2011-10-07 | 2016-04-12 | Shell Oil Company | Thermal expansion accommodation for circulated fluid systems used to heat subsurface formations |
US10047594B2 (en) | 2012-01-23 | 2018-08-14 | Genie Ip B.V. | Heater pattern for in situ thermal processing of a subsurface hydrocarbon containing formation |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2390770A (en) * | 1942-10-10 | 1945-12-11 | Sun Oil Co | Method of producing petroleum |
US2862557A (en) * | 1954-09-17 | 1958-12-02 | Shell Dev | Petroleum production by underground combustion |
US3115928A (en) * | 1959-08-14 | 1963-12-31 | Pan American Petroleum Corp | Heavy oil recovery |
US3155160A (en) * | 1959-11-27 | 1964-11-03 | Pan American Petroleum Corp | Recovery of heavy oils by steam extraction |
US3174544A (en) * | 1964-05-15 | 1965-03-23 | Pan American Petroleum Corp | Recovery of petroleum by combination reverse-direct in situ combustion |
US3182721A (en) * | 1962-11-02 | 1965-05-11 | Sun Oil Co | Method of petroleum production by forward in situ combustion |
US3232345A (en) * | 1964-07-17 | 1966-02-01 | Phillips Petroleum Co | Thermal recovery of heavy crude oil |
US3280910A (en) * | 1964-03-20 | 1966-10-25 | Mobil Oil Corp | Heating of a subterranean formation |
US3332482A (en) * | 1964-11-02 | 1967-07-25 | Phillips Petroleum Co | Huff and puff fire flood process |
-
1967
- 1967-10-11 US US674630A patent/US3434541A/en not_active Expired - Lifetime
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2390770A (en) * | 1942-10-10 | 1945-12-11 | Sun Oil Co | Method of producing petroleum |
US2862557A (en) * | 1954-09-17 | 1958-12-02 | Shell Dev | Petroleum production by underground combustion |
US3115928A (en) * | 1959-08-14 | 1963-12-31 | Pan American Petroleum Corp | Heavy oil recovery |
US3155160A (en) * | 1959-11-27 | 1964-11-03 | Pan American Petroleum Corp | Recovery of heavy oils by steam extraction |
US3182721A (en) * | 1962-11-02 | 1965-05-11 | Sun Oil Co | Method of petroleum production by forward in situ combustion |
US3280910A (en) * | 1964-03-20 | 1966-10-25 | Mobil Oil Corp | Heating of a subterranean formation |
US3174544A (en) * | 1964-05-15 | 1965-03-23 | Pan American Petroleum Corp | Recovery of petroleum by combination reverse-direct in situ combustion |
US3232345A (en) * | 1964-07-17 | 1966-02-01 | Phillips Petroleum Co | Thermal recovery of heavy crude oil |
US3332482A (en) * | 1964-11-02 | 1967-07-25 | Phillips Petroleum Co | Huff and puff fire flood process |
Cited By (252)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3771598A (en) * | 1972-05-19 | 1973-11-13 | Tennco Oil Co | Method of secondary recovery of hydrocarbons |
US3999606A (en) * | 1975-10-06 | 1976-12-28 | Cities Service Company | Oil recovery rate by throttling production wells during combustion drive |
US4062404A (en) * | 1976-09-30 | 1977-12-13 | The United States Of America As Represented By The United States Energy Research And Development Administration | Method for in situ combustion |
US4127172A (en) * | 1977-09-28 | 1978-11-28 | Texaco Exploration Canada Ltd. | Viscous oil recovery method |
US4127170A (en) * | 1977-09-28 | 1978-11-28 | Texaco Exploration Canada Ltd. | Viscous oil recovery method |
US4362212A (en) * | 1979-07-19 | 1982-12-07 | Helmut Schulz | Method for enhanced petroleum oil recovery |
US4359091A (en) * | 1981-08-24 | 1982-11-16 | Fisher Charles B | Recovery of underground hydrocarbons |
US4465137A (en) * | 1982-06-25 | 1984-08-14 | Texaco Inc. | Varying temperature oil recovery method |
US4641709A (en) * | 1985-05-17 | 1987-02-10 | Conoco Inc. | Controlling steam distribution |
US4687057A (en) * | 1985-08-14 | 1987-08-18 | Conoco, Inc. | Determining steam distribution |
US4718489A (en) * | 1986-09-17 | 1988-01-12 | Alberta Oil Sands Technology And Research Authority | Pressure-up/blowdown combustion - a channelled reservoir recovery process |
US8485252B2 (en) | 2000-04-24 | 2013-07-16 | Shell Oil Company | In situ recovery from a hydrocarbon containing formation |
US6953087B2 (en) | 2000-04-24 | 2005-10-11 | Shell Oil Company | Thermal processing of a hydrocarbon containing formation to increase a permeability of the formation |
US20020038069A1 (en) * | 2000-04-24 | 2002-03-28 | Wellington Scott Lee | In situ thermal processing of a coal formation to produce a mixture of olefins, oxygenated hydrocarbons, and aromatic hydrocarbons |
US20020038711A1 (en) * | 2000-04-24 | 2002-04-04 | Rouffignac Eric Pierre De | In situ thermal processing of a hydrocarbon containing formation using heat sources positioned within open wellbores |
US20020043365A1 (en) * | 2000-04-24 | 2002-04-18 | Berchenko Ilya Emil | In situ thermal processing of a coal formation with a selected ratio of heat sources to production wells |
US20020043367A1 (en) * | 2000-04-24 | 2002-04-18 | Rouffignac Eric Pierre De | In situ thermal processing of a hydrocarbon containing formation to increase a permeability of the formation |
US20020053431A1 (en) * | 2000-04-24 | 2002-05-09 | Wellington Scott Lee | In situ thermal processing of a hydrocarbon containing formation to produce a selected ratio of components in a gas |
US20020053429A1 (en) * | 2000-04-24 | 2002-05-09 | Stegemeier George Leo | In situ thermal processing of a hydrocarbon containing formation using pressure and/or temperature control |
US20020057905A1 (en) * | 2000-04-24 | 2002-05-16 | Wellington Scott Lee | In situ thermal processing of a hydrocarbon containing formation to produce oxygen containing formation fluids |
US20020056551A1 (en) * | 2000-04-24 | 2002-05-16 | Wellington Scott Lee | In situ thermal processing of a hydrocarbon containing formation in a reducing environment |
US20020077515A1 (en) * | 2000-04-24 | 2002-06-20 | Wellington Scott Lee | In situ thermal processing of a hydrocarbon containing formation to produce hydrocarbons having a selected carbon number range |
US20020084074A1 (en) * | 2000-04-24 | 2002-07-04 | De Rouffignac Eric Pierre | In situ thermal processing of a hydrocarbon containing formation to increase a porosity of the formation |
US20020104654A1 (en) * | 2000-04-24 | 2002-08-08 | Shell Oil Company | In situ thermal processing of a coal formation to convert a selected total organic carbon content into hydrocarbon products |
US7798221B2 (en) | 2000-04-24 | 2010-09-21 | Shell Oil Company | In situ recovery from a hydrocarbon containing formation |
US7096953B2 (en) | 2000-04-24 | 2006-08-29 | Shell Oil Company | In situ thermal processing of a coal formation using a movable heating element |
US8789586B2 (en) | 2000-04-24 | 2014-07-29 | Shell Oil Company | In situ recovery from a hydrocarbon containing formation |
US7017661B2 (en) | 2000-04-24 | 2006-03-28 | Shell Oil Company | Production of synthesis gas from a coal formation |
US20030164234A1 (en) * | 2000-04-24 | 2003-09-04 | De Rouffignac Eric Pierre | In situ thermal processing of a hydrocarbon containing formation using a movable heating element |
US7011154B2 (en) | 2000-04-24 | 2006-03-14 | Shell Oil Company | In situ recovery from a kerogen and liquid hydrocarbon containing formation |
US20030213594A1 (en) * | 2000-04-24 | 2003-11-20 | Shell Oil Company | In situ thermal processing of a hydrocarbon containing formation to produce a mixture with a selected hydrogen content |
US20040108111A1 (en) * | 2000-04-24 | 2004-06-10 | Vinegar Harold J. | In situ thermal processing of a coal formation to increase a permeability/porosity of the formation |
US6997255B2 (en) | 2000-04-24 | 2006-02-14 | Shell Oil Company | In situ thermal processing of a hydrocarbon containing formation in a reducing environment |
US6994160B2 (en) | 2000-04-24 | 2006-02-07 | Shell Oil Company | In situ thermal processing of a hydrocarbon containing formation to produce hydrocarbons having a selected carbon number range |
US20020027001A1 (en) * | 2000-04-24 | 2002-03-07 | Wellington Scott L. | In situ thermal processing of a coal formation to produce a selected gas mixture |
US6973967B2 (en) | 2000-04-24 | 2005-12-13 | Shell Oil Company | Situ thermal processing of a coal formation using pressure and/or temperature control |
US6966372B2 (en) | 2000-04-24 | 2005-11-22 | Shell Oil Company | In situ thermal processing of a hydrocarbon containing formation to produce oxygen containing formation fluids |
US6923258B2 (en) | 2000-04-24 | 2005-08-02 | Shell Oil Company | In situ thermal processsing of a hydrocarbon containing formation to produce a mixture with a selected hydrogen content |
US20020029885A1 (en) * | 2000-04-24 | 2002-03-14 | De Rouffignac Eric Pierre | In situ thermal processing of a coal formation using a movable heating element |
US7086468B2 (en) | 2000-04-24 | 2006-08-08 | Shell Oil Company | In situ thermal processing of a hydrocarbon containing formation using heat sources positioned within open wellbores |
US6959761B2 (en) | 2000-04-24 | 2005-11-01 | Shell Oil Company | In situ thermal processing of a coal formation with a selected ratio of heat sources to production wells |
US6964300B2 (en) | 2001-04-24 | 2005-11-15 | Shell Oil Company | In situ thermal recovery from a relatively permeable formation with backproduction through a heater wellbore |
US20030209348A1 (en) * | 2001-04-24 | 2003-11-13 | Ward John Michael | In situ thermal processing and remediation of an oil shale formation |
US6948562B2 (en) | 2001-04-24 | 2005-09-27 | Shell Oil Company | Production of a blending agent using an in situ thermal process in a relatively permeable formation |
US6929067B2 (en) | 2001-04-24 | 2005-08-16 | Shell Oil Company | Heat sources with conductive material for in situ thermal processing of an oil shale formation |
US6966374B2 (en) | 2001-04-24 | 2005-11-22 | Shell Oil Company | In situ thermal recovery from a relatively permeable formation using gas to increase mobility |
US6923257B2 (en) | 2001-04-24 | 2005-08-02 | Shell Oil Company | In situ thermal processing of an oil shale formation to produce a condensate |
US6918443B2 (en) | 2001-04-24 | 2005-07-19 | Shell Oil Company | In situ thermal processing of an oil shale formation to produce hydrocarbons having a selected carbon number range |
US6981548B2 (en) | 2001-04-24 | 2006-01-03 | Shell Oil Company | In situ thermal recovery from a relatively permeable formation |
US6991032B2 (en) | 2001-04-24 | 2006-01-31 | Shell Oil Company | In situ thermal processing of an oil shale formation using a pattern of heat sources |
US6991036B2 (en) | 2001-04-24 | 2006-01-31 | Shell Oil Company | Thermal processing of a relatively permeable formation |
US6991033B2 (en) | 2001-04-24 | 2006-01-31 | Shell Oil Company | In situ thermal processing while controlling pressure in an oil shale formation |
US6918442B2 (en) | 2001-04-24 | 2005-07-19 | Shell Oil Company | In situ thermal processing of an oil shale formation in a reducing environment |
US6994169B2 (en) | 2001-04-24 | 2006-02-07 | Shell Oil Company | In situ thermal processing of an oil shale formation with a selected property |
US6915850B2 (en) | 2001-04-24 | 2005-07-12 | Shell Oil Company | In situ thermal processing of an oil shale formation having permeable and impermeable sections |
US7735935B2 (en) | 2001-04-24 | 2010-06-15 | Shell Oil Company | In situ thermal processing of an oil shale formation containing carbonate minerals |
US6997518B2 (en) | 2001-04-24 | 2006-02-14 | Shell Oil Company | In situ thermal processing and solution mining of an oil shale formation |
US7004251B2 (en) | 2001-04-24 | 2006-02-28 | Shell Oil Company | In situ thermal processing and remediation of an oil shale formation |
US6951247B2 (en) | 2001-04-24 | 2005-10-04 | Shell Oil Company | In situ thermal processing of an oil shale formation using horizontal heat sources |
US7013972B2 (en) | 2001-04-24 | 2006-03-21 | Shell Oil Company | In situ thermal processing of an oil shale formation using a natural distributed combustor |
US20030131994A1 (en) * | 2001-04-24 | 2003-07-17 | Vinegar Harold J. | In situ thermal processing and solution mining of an oil shale formation |
US7032660B2 (en) | 2001-04-24 | 2006-04-25 | Shell Oil Company | In situ thermal processing and inhibiting migration of fluids into or out of an in situ oil shale formation |
US7040398B2 (en) | 2001-04-24 | 2006-05-09 | Shell Oil Company | In situ thermal processing of a relatively permeable formation in a reducing environment |
US7040400B2 (en) | 2001-04-24 | 2006-05-09 | Shell Oil Company | In situ thermal processing of a relatively impermeable formation using an open wellbore |
US7040397B2 (en) | 2001-04-24 | 2006-05-09 | Shell Oil Company | Thermal processing of an oil shale formation to increase permeability of the formation |
US7040399B2 (en) | 2001-04-24 | 2006-05-09 | Shell Oil Company | In situ thermal processing of an oil shale formation using a controlled heating rate |
US8608249B2 (en) | 2001-04-24 | 2013-12-17 | Shell Oil Company | In situ thermal processing of an oil shale formation |
US7051807B2 (en) | 2001-04-24 | 2006-05-30 | Shell Oil Company | In situ thermal recovery from a relatively permeable formation with quality control |
US7051811B2 (en) | 2001-04-24 | 2006-05-30 | Shell Oil Company | In situ thermal processing through an open wellbore in an oil shale formation |
US7055600B2 (en) * | 2001-04-24 | 2006-06-06 | Shell Oil Company | In situ thermal recovery from a relatively permeable formation with controlled production rate |
US20080314593A1 (en) * | 2001-04-24 | 2008-12-25 | Shell Oil Company | In situ thermal processing of an oil shale formation using a pattern of heat sources |
US20030111223A1 (en) * | 2001-04-24 | 2003-06-19 | Rouffignac Eric Pierre De | In situ thermal processing of an oil shale formation using horizontal heat sources |
US7066254B2 (en) | 2001-04-24 | 2006-06-27 | Shell Oil Company | In situ thermal processing of a tar sands formation |
US7225866B2 (en) | 2001-04-24 | 2007-06-05 | Shell Oil Company | In situ thermal processing of an oil shale formation using a pattern of heat sources |
US20030102124A1 (en) * | 2001-04-24 | 2003-06-05 | Vinegar Harold J. | In situ thermal processing of a blending agent from a relatively permeable formation |
US20030100451A1 (en) * | 2001-04-24 | 2003-05-29 | Messier Margaret Ann | In situ thermal recovery from a relatively permeable formation with backproduction through a heater wellbore |
US7096942B1 (en) | 2001-04-24 | 2006-08-29 | Shell Oil Company | In situ thermal processing of a relatively permeable formation while controlling pressure |
US7077199B2 (en) | 2001-10-24 | 2006-07-18 | Shell Oil Company | In situ thermal processing of an oil reservoir formation |
US7461691B2 (en) | 2001-10-24 | 2008-12-09 | Shell Oil Company | In situ recovery from a hydrocarbon containing formation |
US7086465B2 (en) | 2001-10-24 | 2006-08-08 | Shell Oil Company | In situ production of a blending agent from a hydrocarbon containing formation |
US7077198B2 (en) | 2001-10-24 | 2006-07-18 | Shell Oil Company | In situ recovery from a hydrocarbon containing formation using barriers |
US7100994B2 (en) | 2001-10-24 | 2006-09-05 | Shell Oil Company | Producing hydrocarbons and non-hydrocarbon containing materials when treating a hydrocarbon containing formation |
US7104319B2 (en) | 2001-10-24 | 2006-09-12 | Shell Oil Company | In situ thermal processing of a heavy oil diatomite formation |
US7114566B2 (en) | 2001-10-24 | 2006-10-03 | Shell Oil Company | In situ thermal processing of a hydrocarbon containing formation using a natural distributed combustor |
US6932155B2 (en) | 2001-10-24 | 2005-08-23 | Shell Oil Company | In situ thermal processing of a hydrocarbon containing formation via backproducing through a heater well |
US7090013B2 (en) | 2001-10-24 | 2006-08-15 | Shell Oil Company | In situ thermal processing of a hydrocarbon containing formation to produce heated fluids |
US7128153B2 (en) | 2001-10-24 | 2006-10-31 | Shell Oil Company | Treatment of a hydrocarbon containing formation after heating |
US7156176B2 (en) | 2001-10-24 | 2007-01-02 | Shell Oil Company | Installation and use of removable heaters in a hydrocarbon containing formation |
US7165615B2 (en) | 2001-10-24 | 2007-01-23 | Shell Oil Company | In situ recovery from a hydrocarbon containing formation using conductor-in-conduit heat sources with an electrically conductive material in the overburden |
US6991045B2 (en) | 2001-10-24 | 2006-01-31 | Shell Oil Company | Forming openings in a hydrocarbon containing formation using magnetic tracking |
US7051808B1 (en) | 2001-10-24 | 2006-05-30 | Shell Oil Company | Seismic monitoring of in situ conversion in a hydrocarbon containing formation |
US8627887B2 (en) | 2001-10-24 | 2014-01-14 | Shell Oil Company | In situ recovery from a hydrocarbon containing formation |
US7066257B2 (en) | 2001-10-24 | 2006-06-27 | Shell Oil Company | In situ recovery from lean and rich zones in a hydrocarbon containing formation |
US7063145B2 (en) | 2001-10-24 | 2006-06-20 | Shell Oil Company | Methods and systems for heating a hydrocarbon containing formation in situ with an opening contacting the earth's surface at two locations |
US7219734B2 (en) | 2002-10-24 | 2007-05-22 | Shell Oil Company | Inhibiting wellbore deformation during in situ thermal processing of a hydrocarbon containing formation |
US8224163B2 (en) | 2002-10-24 | 2012-07-17 | Shell Oil Company | Variable frequency temperature limited heaters |
US7073578B2 (en) | 2002-10-24 | 2006-07-11 | Shell Oil Company | Staged and/or patterned heating during in situ thermal processing of a hydrocarbon containing formation |
US8200072B2 (en) | 2002-10-24 | 2012-06-12 | Shell Oil Company | Temperature limited heaters for heating subsurface formations or wellbores |
US7121341B2 (en) | 2002-10-24 | 2006-10-17 | Shell Oil Company | Conductor-in-conduit temperature limited heaters |
US8238730B2 (en) | 2002-10-24 | 2012-08-07 | Shell Oil Company | High voltage temperature limited heaters |
US8224164B2 (en) | 2002-10-24 | 2012-07-17 | Shell Oil Company | Insulated conductor temperature limited heaters |
US7640980B2 (en) | 2003-04-24 | 2010-01-05 | Shell Oil Company | Thermal processes for subsurface formations |
US7121342B2 (en) | 2003-04-24 | 2006-10-17 | Shell Oil Company | Thermal processes for subsurface formations |
US20050051327A1 (en) * | 2003-04-24 | 2005-03-10 | Vinegar Harold J. | Thermal processes for subsurface formations |
US7942203B2 (en) | 2003-04-24 | 2011-05-17 | Shell Oil Company | Thermal processes for subsurface formations |
US7360588B2 (en) | 2003-04-24 | 2008-04-22 | Shell Oil Company | Thermal processes for subsurface formations |
US8579031B2 (en) | 2003-04-24 | 2013-11-12 | Shell Oil Company | Thermal processes for subsurface formations |
US20100181066A1 (en) * | 2003-04-24 | 2010-07-22 | Shell Oil Company | Thermal processes for subsurface formations |
US7431076B2 (en) | 2004-04-23 | 2008-10-07 | Shell Oil Company | Temperature limited heaters using modulated DC power |
US7424915B2 (en) | 2004-04-23 | 2008-09-16 | Shell Oil Company | Vacuum pumping of conductor-in-conduit heaters |
US7357180B2 (en) | 2004-04-23 | 2008-04-15 | Shell Oil Company | Inhibiting effects of sloughing in wellbores |
US7490665B2 (en) | 2004-04-23 | 2009-02-17 | Shell Oil Company | Variable frequency temperature limited heaters |
US7481274B2 (en) | 2004-04-23 | 2009-01-27 | Shell Oil Company | Temperature limited heaters with relatively constant current |
US7320364B2 (en) | 2004-04-23 | 2008-01-22 | Shell Oil Company | Inhibiting reflux in a heated well of an in situ conversion system |
US8355623B2 (en) | 2004-04-23 | 2013-01-15 | Shell Oil Company | Temperature limited heaters with high power factors |
US7370704B2 (en) | 2004-04-23 | 2008-05-13 | Shell Oil Company | Triaxial temperature limited heater |
US7383877B2 (en) | 2004-04-23 | 2008-06-10 | Shell Oil Company | Temperature limited heaters with thermally conductive fluid used to heat subsurface formations |
US7353872B2 (en) | 2004-04-23 | 2008-04-08 | Shell Oil Company | Start-up of temperature limited heaters using direct current (DC) |
US7510000B2 (en) | 2004-04-23 | 2009-03-31 | Shell Oil Company | Reducing viscosity of oil for production from a hydrocarbon containing formation |
US7900701B2 (en) * | 2005-01-13 | 2011-03-08 | Encana Corporation | In situ combustion in gas over bitumen formations |
US20120175110A1 (en) * | 2005-01-13 | 2012-07-12 | Larry Weiers | In situ combustion in gas over bitumen formations |
US8215387B1 (en) * | 2005-01-13 | 2012-07-10 | Encana Corporation | In situ combustion in gas over bitumen formations |
US20080093071A1 (en) * | 2005-01-13 | 2008-04-24 | Larry Weiers | In Situ Combustion in Gas Over Bitumen Formations |
US8167040B2 (en) | 2005-01-13 | 2012-05-01 | Encana Corporation | In situ combustion in gas over bitumen formations |
US8233782B2 (en) | 2005-04-22 | 2012-07-31 | Shell Oil Company | Grouped exposed metal heaters |
US7500528B2 (en) | 2005-04-22 | 2009-03-10 | Shell Oil Company | Low temperature barrier wellbores formed using water flushing |
US7831134B2 (en) | 2005-04-22 | 2010-11-09 | Shell Oil Company | Grouped exposed metal heaters |
US7860377B2 (en) | 2005-04-22 | 2010-12-28 | Shell Oil Company | Subsurface connection methods for subsurface heaters |
US7575053B2 (en) | 2005-04-22 | 2009-08-18 | Shell Oil Company | Low temperature monitoring system for subsurface barriers |
US7575052B2 (en) | 2005-04-22 | 2009-08-18 | Shell Oil Company | In situ conversion process utilizing a closed loop heating system |
US20070137857A1 (en) * | 2005-04-22 | 2007-06-21 | Vinegar Harold J | Low temperature monitoring system for subsurface barriers |
US7435037B2 (en) | 2005-04-22 | 2008-10-14 | Shell Oil Company | Low temperature barriers with heat interceptor wells for in situ processes |
US8230927B2 (en) | 2005-04-22 | 2012-07-31 | Shell Oil Company | Methods and systems for producing fluid from an in situ conversion process |
US7942197B2 (en) | 2005-04-22 | 2011-05-17 | Shell Oil Company | Methods and systems for producing fluid from an in situ conversion process |
US8224165B2 (en) | 2005-04-22 | 2012-07-17 | Shell Oil Company | Temperature limited heater utilizing non-ferromagnetic conductor |
US7986869B2 (en) | 2005-04-22 | 2011-07-26 | Shell Oil Company | Varying properties along lengths of temperature limited heaters |
US8027571B2 (en) | 2005-04-22 | 2011-09-27 | Shell Oil Company | In situ conversion process systems utilizing wellbores in at least two regions of a formation |
US8070840B2 (en) | 2005-04-22 | 2011-12-06 | Shell Oil Company | Treatment of gas from an in situ conversion process |
US7527094B2 (en) | 2005-04-22 | 2009-05-05 | Shell Oil Company | Double barrier system for an in situ conversion process |
US7546873B2 (en) | 2005-04-22 | 2009-06-16 | Shell Oil Company | Low temperature barriers for use with in situ processes |
US7549470B2 (en) | 2005-10-24 | 2009-06-23 | Shell Oil Company | Solution mining and heating by oxidation for treating hydrocarbon containing formations |
US7556095B2 (en) | 2005-10-24 | 2009-07-07 | Shell Oil Company | Solution mining dawsonite from hydrocarbon containing formations with a chelating agent |
US8151880B2 (en) | 2005-10-24 | 2012-04-10 | Shell Oil Company | Methods of making transportation fuel |
US7556096B2 (en) | 2005-10-24 | 2009-07-07 | Shell Oil Company | Varying heating in dawsonite zones in hydrocarbon containing formations |
US7559368B2 (en) | 2005-10-24 | 2009-07-14 | Shell Oil Company | Solution mining systems and methods for treating hydrocarbon containing formations |
US7559367B2 (en) | 2005-10-24 | 2009-07-14 | Shell Oil Company | Temperature limited heater with a conduit substantially electrically isolated from the formation |
US7591310B2 (en) | 2005-10-24 | 2009-09-22 | Shell Oil Company | Methods of hydrotreating a liquid stream to remove clogging compounds |
US7562706B2 (en) | 2005-10-24 | 2009-07-21 | Shell Oil Company | Systems and methods for producing hydrocarbons from tar sands formations |
US7635025B2 (en) | 2005-10-24 | 2009-12-22 | Shell Oil Company | Cogeneration systems and processes for treating hydrocarbon containing formations |
US20080017370A1 (en) * | 2005-10-24 | 2008-01-24 | Vinegar Harold J | Temperature limited heater with a conduit substantially electrically isolated from the formation |
US8606091B2 (en) | 2005-10-24 | 2013-12-10 | Shell Oil Company | Subsurface heaters with low sulfidation rates |
US7581589B2 (en) | 2005-10-24 | 2009-09-01 | Shell Oil Company | Methods of producing alkylated hydrocarbons from an in situ heat treatment process liquid |
US7584789B2 (en) | 2005-10-24 | 2009-09-08 | Shell Oil Company | Methods of cracking a crude product to produce additional crude products |
US7597147B2 (en) | 2006-04-21 | 2009-10-06 | Shell Oil Company | Temperature limited heaters using phase transformation of ferromagnetic material |
US7631689B2 (en) | 2006-04-21 | 2009-12-15 | Shell Oil Company | Sulfur barrier for use with in situ processes for treating formations |
US7793722B2 (en) | 2006-04-21 | 2010-09-14 | Shell Oil Company | Non-ferromagnetic overburden casing |
US7610962B2 (en) | 2006-04-21 | 2009-11-03 | Shell Oil Company | Sour gas injection for use with in situ heat treatment |
US7604052B2 (en) | 2006-04-21 | 2009-10-20 | Shell Oil Company | Compositions produced using an in situ heat treatment process |
US7533719B2 (en) | 2006-04-21 | 2009-05-19 | Shell Oil Company | Wellhead with non-ferromagnetic materials |
US7635023B2 (en) | 2006-04-21 | 2009-12-22 | Shell Oil Company | Time sequenced heating of multiple layers in a hydrocarbon containing formation |
US7673786B2 (en) | 2006-04-21 | 2010-03-09 | Shell Oil Company | Welding shield for coupling heaters |
US8192682B2 (en) | 2006-04-21 | 2012-06-05 | Shell Oil Company | High strength alloys |
US7785427B2 (en) | 2006-04-21 | 2010-08-31 | Shell Oil Company | High strength alloys |
US7683296B2 (en) | 2006-04-21 | 2010-03-23 | Shell Oil Company | Adjusting alloy compositions for selected properties in temperature limited heaters |
US7866385B2 (en) | 2006-04-21 | 2011-01-11 | Shell Oil Company | Power systems utilizing the heat of produced formation fluid |
US20070289733A1 (en) * | 2006-04-21 | 2007-12-20 | Hinson Richard A | Wellhead with non-ferromagnetic materials |
US8857506B2 (en) | 2006-04-21 | 2014-10-14 | Shell Oil Company | Alternate energy source usage methods for in situ heat treatment processes |
US7912358B2 (en) | 2006-04-21 | 2011-03-22 | Shell Oil Company | Alternate energy source usage for in situ heat treatment processes |
US8083813B2 (en) | 2006-04-21 | 2011-12-27 | Shell Oil Company | Methods of producing transportation fuel |
US7673681B2 (en) | 2006-10-20 | 2010-03-09 | Shell Oil Company | Treating tar sands formations with karsted zones |
US7677314B2 (en) | 2006-10-20 | 2010-03-16 | Shell Oil Company | Method of condensing vaporized water in situ to treat tar sands formations |
US7540324B2 (en) | 2006-10-20 | 2009-06-02 | Shell Oil Company | Heating hydrocarbon containing formations in a checkerboard pattern staged process |
US7730945B2 (en) | 2006-10-20 | 2010-06-08 | Shell Oil Company | Using geothermal energy to heat a portion of a formation for an in situ heat treatment process |
US7635024B2 (en) | 2006-10-20 | 2009-12-22 | Shell Oil Company | Heating tar sands formations to visbreaking temperatures |
US7717171B2 (en) | 2006-10-20 | 2010-05-18 | Shell Oil Company | Moving hydrocarbons through portions of tar sands formations with a fluid |
US7644765B2 (en) | 2006-10-20 | 2010-01-12 | Shell Oil Company | Heating tar sands formations while controlling pressure |
US7703513B2 (en) | 2006-10-20 | 2010-04-27 | Shell Oil Company | Wax barrier for use with in situ processes for treating formations |
US7845411B2 (en) | 2006-10-20 | 2010-12-07 | Shell Oil Company | In situ heat treatment process utilizing a closed loop heating system |
US7841401B2 (en) | 2006-10-20 | 2010-11-30 | Shell Oil Company | Gas injection to inhibit migration during an in situ heat treatment process |
US7631690B2 (en) | 2006-10-20 | 2009-12-15 | Shell Oil Company | Heating hydrocarbon containing formations in a spiral startup staged sequence |
US7730946B2 (en) | 2006-10-20 | 2010-06-08 | Shell Oil Company | Treating tar sands formations with dolomite |
US7562707B2 (en) | 2006-10-20 | 2009-07-21 | Shell Oil Company | Heating hydrocarbon containing formations in a line drive staged process |
US7681647B2 (en) | 2006-10-20 | 2010-03-23 | Shell Oil Company | Method of producing drive fluid in situ in tar sands formations |
US7677310B2 (en) | 2006-10-20 | 2010-03-16 | Shell Oil Company | Creating and maintaining a gas cap in tar sands formations |
US8555971B2 (en) | 2006-10-20 | 2013-10-15 | Shell Oil Company | Treating tar sands formations with dolomite |
US7730947B2 (en) | 2006-10-20 | 2010-06-08 | Shell Oil Company | Creating fluid injectivity in tar sands formations |
US8191630B2 (en) | 2006-10-20 | 2012-06-05 | Shell Oil Company | Creating fluid injectivity in tar sands formations |
US8791396B2 (en) | 2007-04-20 | 2014-07-29 | Shell Oil Company | Floating insulated conductors for heating subsurface formations |
US8662175B2 (en) | 2007-04-20 | 2014-03-04 | Shell Oil Company | Varying properties of in situ heat treatment of a tar sands formation based on assessed viscosities |
US7849922B2 (en) | 2007-04-20 | 2010-12-14 | Shell Oil Company | In situ recovery from residually heated sections in a hydrocarbon containing formation |
US8327681B2 (en) | 2007-04-20 | 2012-12-11 | Shell Oil Company | Wellbore manufacturing processes for in situ heat treatment processes |
US9181780B2 (en) | 2007-04-20 | 2015-11-10 | Shell Oil Company | Controlling and assessing pressure conditions during treatment of tar sands formations |
US7832484B2 (en) | 2007-04-20 | 2010-11-16 | Shell Oil Company | Molten salt as a heat transfer fluid for heating a subsurface formation |
US7841425B2 (en) | 2007-04-20 | 2010-11-30 | Shell Oil Company | Drilling subsurface wellbores with cutting structures |
US7798220B2 (en) | 2007-04-20 | 2010-09-21 | Shell Oil Company | In situ heat treatment of a tar sands formation after drive process treatment |
US7931086B2 (en) | 2007-04-20 | 2011-04-26 | Shell Oil Company | Heating systems for heating subsurface formations |
US8042610B2 (en) | 2007-04-20 | 2011-10-25 | Shell Oil Company | Parallel heater system for subsurface formations |
US20090321071A1 (en) * | 2007-04-20 | 2009-12-31 | Etuan Zhang | Controlling and assessing pressure conditions during treatment of tar sands formations |
US8381815B2 (en) | 2007-04-20 | 2013-02-26 | Shell Oil Company | Production from multiple zones of a tar sands formation |
US7841408B2 (en) | 2007-04-20 | 2010-11-30 | Shell Oil Company | In situ heat treatment from multiple layers of a tar sands formation |
US8459359B2 (en) | 2007-04-20 | 2013-06-11 | Shell Oil Company | Treating nahcolite containing formations and saline zones |
US7950453B2 (en) | 2007-04-20 | 2011-05-31 | Shell Oil Company | Downhole burner systems and methods for heating subsurface formations |
US8146661B2 (en) | 2007-10-19 | 2012-04-03 | Shell Oil Company | Cryogenic treatment of gas |
US8240774B2 (en) | 2007-10-19 | 2012-08-14 | Shell Oil Company | Solution mining and in situ treatment of nahcolite beds |
US8196658B2 (en) | 2007-10-19 | 2012-06-12 | Shell Oil Company | Irregular spacing of heat sources for treating hydrocarbon containing formations |
US7866386B2 (en) | 2007-10-19 | 2011-01-11 | Shell Oil Company | In situ oxidation of subsurface formations |
US8272455B2 (en) | 2007-10-19 | 2012-09-25 | Shell Oil Company | Methods for forming wellbores in heated formations |
US8276661B2 (en) | 2007-10-19 | 2012-10-02 | Shell Oil Company | Heating subsurface formations by oxidizing fuel on a fuel carrier |
US8162059B2 (en) | 2007-10-19 | 2012-04-24 | Shell Oil Company | Induction heaters used to heat subsurface formations |
US8536497B2 (en) | 2007-10-19 | 2013-09-17 | Shell Oil Company | Methods for forming long subsurface heaters |
US7866388B2 (en) | 2007-10-19 | 2011-01-11 | Shell Oil Company | High temperature methods for forming oxidizer fuel |
US8146669B2 (en) | 2007-10-19 | 2012-04-03 | Shell Oil Company | Multi-step heater deployment in a subsurface formation |
US8113272B2 (en) | 2007-10-19 | 2012-02-14 | Shell Oil Company | Three-phase heaters with common overburden sections for heating subsurface formations |
US8011451B2 (en) | 2007-10-19 | 2011-09-06 | Shell Oil Company | Ranging methods for developing wellbores in subsurface formations |
US8636323B2 (en) | 2008-04-18 | 2014-01-28 | Shell Oil Company | Mines and tunnels for use in treating subsurface hydrocarbon containing formations |
US8177305B2 (en) | 2008-04-18 | 2012-05-15 | Shell Oil Company | Heater connections in mines and tunnels for use in treating subsurface hydrocarbon containing formations |
US9528322B2 (en) | 2008-04-18 | 2016-12-27 | Shell Oil Company | Dual motor systems and non-rotating sensors for use in developing wellbores in subsurface formations |
US8151907B2 (en) | 2008-04-18 | 2012-04-10 | Shell Oil Company | Dual motor systems and non-rotating sensors for use in developing wellbores in subsurface formations |
US8162405B2 (en) | 2008-04-18 | 2012-04-24 | Shell Oil Company | Using tunnels for treating subsurface hydrocarbon containing formations |
US8172335B2 (en) | 2008-04-18 | 2012-05-08 | Shell Oil Company | Electrical current flow between tunnels for use in heating subsurface hydrocarbon containing formations |
US8562078B2 (en) | 2008-04-18 | 2013-10-22 | Shell Oil Company | Hydrocarbon production from mines and tunnels used in treating subsurface hydrocarbon containing formations |
US8752904B2 (en) | 2008-04-18 | 2014-06-17 | Shell Oil Company | Heated fluid flow in mines and tunnels used in heating subsurface hydrocarbon containing formations |
US8256512B2 (en) | 2008-10-13 | 2012-09-04 | Shell Oil Company | Movable heaters for treating subsurface hydrocarbon containing formations |
US9129728B2 (en) | 2008-10-13 | 2015-09-08 | Shell Oil Company | Systems and methods of forming subsurface wellbores |
US20100155070A1 (en) * | 2008-10-13 | 2010-06-24 | Augustinus Wilhelmus Maria Roes | Organonitrogen compounds used in treating hydrocarbon containing formations |
US8261832B2 (en) | 2008-10-13 | 2012-09-11 | Shell Oil Company | Heating subsurface formations with fluids |
US8220539B2 (en) | 2008-10-13 | 2012-07-17 | Shell Oil Company | Controlling hydrogen pressure in self-regulating nuclear reactors used to treat a subsurface formation |
US8267185B2 (en) | 2008-10-13 | 2012-09-18 | Shell Oil Company | Circulated heated transfer fluid systems used to treat a subsurface formation |
US9051829B2 (en) | 2008-10-13 | 2015-06-09 | Shell Oil Company | Perforated electrical conductors for treating subsurface formations |
US9022118B2 (en) | 2008-10-13 | 2015-05-05 | Shell Oil Company | Double insulated heaters for treating subsurface formations |
US8881806B2 (en) | 2008-10-13 | 2014-11-11 | Shell Oil Company | Systems and methods for treating a subsurface formation with electrical conductors |
US8267170B2 (en) | 2008-10-13 | 2012-09-18 | Shell Oil Company | Offset barrier wells in subsurface formations |
US8281861B2 (en) | 2008-10-13 | 2012-10-09 | Shell Oil Company | Circulated heated transfer fluid heating of subsurface hydrocarbon formations |
US8353347B2 (en) | 2008-10-13 | 2013-01-15 | Shell Oil Company | Deployment of insulated conductors for treating subsurface formations |
US8448707B2 (en) | 2009-04-10 | 2013-05-28 | Shell Oil Company | Non-conducting heater casings |
US8434555B2 (en) | 2009-04-10 | 2013-05-07 | Shell Oil Company | Irregular pattern treatment of a subsurface formation |
US8851170B2 (en) | 2009-04-10 | 2014-10-07 | Shell Oil Company | Heater assisted fluid treatment of a subsurface formation |
US8327932B2 (en) | 2009-04-10 | 2012-12-11 | Shell Oil Company | Recovering energy from a subsurface formation |
US9033042B2 (en) | 2010-04-09 | 2015-05-19 | Shell Oil Company | Forming bitumen barriers in subsurface hydrocarbon formations |
US9127523B2 (en) | 2010-04-09 | 2015-09-08 | Shell Oil Company | Barrier methods for use in subsurface hydrocarbon formations |
US9022109B2 (en) | 2010-04-09 | 2015-05-05 | Shell Oil Company | Leak detection in circulated fluid systems for heating subsurface formations |
US8701769B2 (en) | 2010-04-09 | 2014-04-22 | Shell Oil Company | Methods for treating hydrocarbon formations based on geology |
US8820406B2 (en) | 2010-04-09 | 2014-09-02 | Shell Oil Company | Electrodes for electrical current flow heating of subsurface formations with conductive material in wellbore |
US8701768B2 (en) | 2010-04-09 | 2014-04-22 | Shell Oil Company | Methods for treating hydrocarbon formations |
US8631866B2 (en) | 2010-04-09 | 2014-01-21 | Shell Oil Company | Leak detection in circulated fluid systems for heating subsurface formations |
US8833453B2 (en) | 2010-04-09 | 2014-09-16 | Shell Oil Company | Electrodes for electrical current flow heating of subsurface formations with tapered copper thickness |
US9127538B2 (en) | 2010-04-09 | 2015-09-08 | Shell Oil Company | Methodologies for treatment of hydrocarbon formations using staged pyrolyzation |
US8739874B2 (en) | 2010-04-09 | 2014-06-03 | Shell Oil Company | Methods for heating with slots in hydrocarbon formations |
US9399905B2 (en) | 2010-04-09 | 2016-07-26 | Shell Oil Company | Leak detection in circulated fluid systems for heating subsurface formations |
US9016370B2 (en) | 2011-04-08 | 2015-04-28 | Shell Oil Company | Partial solution mining of hydrocarbon containing layers prior to in situ heat treatment |
US9309755B2 (en) | 2011-10-07 | 2016-04-12 | Shell Oil Company | Thermal expansion accommodation for circulated fluid systems used to heat subsurface formations |
US10047594B2 (en) | 2012-01-23 | 2018-08-14 | Genie Ip B.V. | Heater pattern for in situ thermal processing of a subsurface hydrocarbon containing formation |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3434541A (en) | In situ combustion process | |
US4429745A (en) | Oil recovery method | |
US2813583A (en) | Process for recovery of petroleum from sands and shale | |
US4296969A (en) | Thermal recovery of viscous hydrocarbons using arrays of radially spaced horizontal wells | |
US5054551A (en) | In-situ heated annulus refining process | |
US2897894A (en) | Recovery of oil from subterranean reservoirs | |
US4682652A (en) | Producing hydrocarbons through successively perforated intervals of a horizontal well between two vertical wells | |
US3150715A (en) | Oil recovery by in situ combustion with water injection | |
US3515213A (en) | Shale oil recovery process using heated oil-miscible fluids | |
US4489783A (en) | Viscous oil recovery method | |
US4217956A (en) | Method of in-situ recovery of viscous oils or bitumen utilizing a thermal recovery fluid and carbon dioxide | |
US4127170A (en) | Viscous oil recovery method | |
US3051235A (en) | Recovery of petroleum crude oil, by in situ combustion and in situ hydrogenation | |
US3279538A (en) | Oil recovery | |
US3554285A (en) | Production and upgrading of heavy viscous oils | |
US4116275A (en) | Recovery of hydrocarbons by in situ thermal extraction | |
US4127172A (en) | Viscous oil recovery method | |
US3739852A (en) | Thermal process for recovering oil | |
US2946382A (en) | Process for recovering hydrocarbons from underground formations | |
US3822748A (en) | Petroleum recovery process | |
US4653583A (en) | Optimum production rate for horizontal wells | |
US4612989A (en) | Combined replacement drive process for oil recovery | |
US4034812A (en) | Method for recovering viscous petroleum from unconsolidated mineral formations | |
US4429744A (en) | Oil recovery method | |
US4121661A (en) | Viscous oil recovery method |