US3413243A - Orthopedic exercising device and composition and process for making the same - Google Patents
Orthopedic exercising device and composition and process for making the same Download PDFInfo
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- US3413243A US3413243A US399958A US39995864A US3413243A US 3413243 A US3413243 A US 3413243A US 399958 A US399958 A US 399958A US 39995864 A US39995864 A US 39995864A US 3413243 A US3413243 A US 3413243A
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- exercising device
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- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B21/00—Exercising apparatus for developing or strengthening the muscles or joints of the body by working against a counterforce, with or without measuring devices
- A63B21/02—Exercising apparatus for developing or strengthening the muscles or joints of the body by working against a counterforce, with or without measuring devices using resilient force-resisters
- A63B21/028—Exercising apparatus for developing or strengthening the muscles or joints of the body by working against a counterforce, with or without measuring devices using resilient force-resisters made of material having high internal friction, e.g. rubber, steel wool, intended to be compressed
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B23/00—Exercising apparatus specially adapted for particular parts of the body
- A63B23/035—Exercising apparatus specially adapted for particular parts of the body for limbs, i.e. upper or lower limbs, e.g. simultaneously
- A63B23/12—Exercising apparatus specially adapted for particular parts of the body for limbs, i.e. upper or lower limbs, e.g. simultaneously for upper limbs or related muscles, e.g. chest, upper back or shoulder muscles
- A63B23/16—Exercising apparatus specially adapted for particular parts of the body for limbs, i.e. upper or lower limbs, e.g. simultaneously for upper limbs or related muscles, e.g. chest, upper back or shoulder muscles for hands or fingers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S261/00—Gas and liquid contact apparatus
- Y10S261/72—Packing elements
Definitions
- Orthopedic exercising device in the form of a ball formed of a mass of interconnected air cells defined by resilient wall membranes formed of an expanded blend of sheet natural rubber, styrene-butadiene rubber and ground cured rubber sponge scrap.
- the mass has a density of approximately 0.012 to 0.020 pound per cubic inch and requires an application of approximately 0.57 pound per square inch pressure for a percent deflection.
- the cells at the periphery of the ball are normally maintained substantially closed to preclude passage of air from within the mass, and are opened for expelling and absorbing of air on compression of, and relaxation of pressure on, the mass.
- This invention relates to the production of an orthopedic exercising device and relates more particularly to an orthopedic exercising ball, its composition and process of manufacture.
- a further object of the instant invention is the provision of an exercising ball formed of a unique composition and in a novel manner whereby it has resultant physical 3,413,243 Patented Nov. 26, 1968 properties rendering it particularly useful in strengthening the muscles of the hand, wrist and arm.
- Another object resides in the provision of a device of the type described which may be utilized for its therapeutic value in exercising various muscular tissue weakened or damaged as the result of certain illnesses.
- a still further object of the instant invention is to provide an exerciser for building up various hand, wrist and arm muscles frequently utilized in certain sports, such as improving the grip or power in bowling, baseball, tennis, golf, and the like.
- Yet another object is the provision of a composition for making exercising devices in accordance with the instant inventive concept comprised essentially of an eX- panded or foamed blend of certain rubber materials resulting in an article which is uniquely resilient, returning to its original dimensions and configuration even after extended use, while being relatively soft and flexible whereby the user will not be discouraged from long periods of exercise because of undue tiring of his hand.
- a further object of the instant invention is to provide a process for manufacturing such an article which is particularly eflicient and reliable for producing exercisers of consistent physical properties and high quality in a most expeditious manner.
- Still another object is the provision of an orthopedic exercising device which is sturdy and durable in construction, highly efi'icient in use and relatively inexpensive to manufacture.
- FIGURE 1 is a plan view of an exercising device in accordance with the instant inventive concept
- FIGURE 2 shows the same being compressed in use
- FIGURE 3 is an enlarged fragmentary cross-sectional view of the uncompressed form of the device.
- FIGURE 4 is a view similar to FIGURE 3 showing a cross-section of the device after it has been compressed.
- an article having the exemplary features set forth above can be produced by blending a sheet natural rubber with a Styrenebutadiene rubber and ground cured rubber sponge scrap along with selected blowing agents, processing aids, peptizing agents, antioxidants, vulcanizers and other conventional rubber making materials, followed by various procedural steps in treatment of the blend to expand the same within a closed mold into a ball 10 or the like of substantially open-cellular construction having the desired characteristics.
- the cells of the completed product are defined by resilient wall membranes 12 which include openings or pores 14 interconnecting the interstices for passage of air during compression or squeezing of the exerciser.
- these pores act as minute valve members normally precluding passage of air from within the mass.
- the pores are opened to expel air in order that the mass may be compressed, the pores remaining open on relaxation of the pressure until the article has returned to its original dimensions and shape.
- the opened relationship of the pores will be seen in FIGURE 4.
- the particular ratio of the three base rubber materials for manufacture of an optimum product is approximately 110 parts by weight of the sheet natural rubber to each parts by weight of the styrene-butadiene rubber and 10 parts by weight of the ground cured rubber sponge scrap. While the above ratio has been found to be best suited to the desired physical properties in the resultant article, it is to be understood that satisfactory properties can be obtained with from 80 to 110 parts by weight sheet natural rubber, to each 10 to 40 parts by weight styrene-butadiene rubber and 5 to 20 parts by weight ground cured rubber sponge scrap.
- a blend of this material is made with conventional process aids, peptizing agents, extenders and white cotton flock. The blend is premasticated a plurality of times and intermixed with other ingredients such as blowing agents, antioxidants, accelerators, vulcanizers and other well known rubber making materials.
- the resultant intermixture is extruded and cut into slugs to form a charge of desired size, depending upon the size of the mold to be utilized.
- the weight of the slugs are predetermined to provide a completed product of a density between 0.012 and 0.020 pound per cubic inch. This weight is readily determined by multiplying the desired density of the finished article by the volume of the mold which in the case of a spherical mold would be according to the following formula:
- the slug or charge of intermixture is then introduced into the mold, which is preferably spherical in form for uniformity of product and simplicity of process and use of the product, and the mold is then closed and heated to expand the charge into contact with the interior mold walls.
- the resultant intermixture was cooled and aged for 24 hours following which it was warmed and extruded in conventional extrusion machinery.
- the extruded intermixture was cut into slugs which were introduced into a 2.5 inch diameter split spherical mold having an upper platen receiving pounds per square inch steam pressure and a lower platen receiving 50 pounds per square inch steam pressure.
- EXAMPLE IA A 45 gram slug of the intermixture is heated for ap proximately 60 minutes at which time the expanded product is removed and cooled. The density of the finished product is measured as 0.0124 pound per cubic inch and a standard compression-deflection apparatus gives a reading of 0.56 at 10 percent deflection on a cylindrical sample having a diameter of 2 inches and a height of 1 inch.
- EXAMPLE IB A 70 gram slug is similarly treated for approximately minutes, removed and cooled. The density is calculated at 0.0193 and the 10 percent deflection reading is 0.58.
- each of the above samples and other samples having a density of from about 0.012 to 0.020 pound per cubic inch are found to be relatively soft, allowing extended manipulation of the finished product by hand squeezing without undesirable weariness of the user.
- the article offers suflicient resistance to be of great value in strengtheinng of the hand, wrist and arm muscles. Extensive compression and relaxation of the exerciser is not found to affect its ability to return to its original dimensions and shape.
- a decrease of the density below about 0.012 pound per cubic inch produces an article which fails to provide suflicient resistance for proper muscle building and which has a tendency to be weak in construction and an increase of the density above about 0.020 pound per cubic inch results in a product causing undue weariness after extended use.
- Example I The procedure of Example I is repeated replacing the sodium bicarbonate with approximately equal quantities of ammonium bicarbonate or sodium carbonate and replacing the N,N-dinitrosopentamethylenetetramine with approximately equal quantities of azodicarbonamide or 70% N,N' dimethyin N,N' dinitroso terephthalamide. Samples of the resultant product having a density of from about 0.012 to 0.020 pound per cubic inch were found to be equally satisfactory.
- An orthopedic ball comprising a mass of interconnected air cells defined by resilient wall membranes formed of an expanded blend of sheet natural rubber, styrene-butadiene rubber and ground cured rubber sponge scrap, said expanded blend including from approximately 80 to 110 parts by weight sheet natural rubber to each 10 to 40 parts by weight styrene-butadiene rubber and 5 to 20 parts by weight ground cured rubber sponge scrap,
- said mass having a density of approximately 0.012 to 0.020 pound per cubic inch.
- portions of said wall membrane defining each cell include openings whereby each cell is in communication with at least some of the surrounding cells, the periphery of said mass being defined by said wall membrane of an outer layer of said cells, a major number of said openings in said wall membrane defining said periphery being normally maintained substantially closed to preclude passage of air from within said mass, and being opened for expelling and absorbing of air on compression of, and relaxation of pressure on, said mass.
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biophysics (AREA)
- Orthopedic Medicine & Surgery (AREA)
- General Health & Medical Sciences (AREA)
- Physical Education & Sports Medicine (AREA)
- Orthopedics, Nursing, And Contraception (AREA)
Description
Nov. 26, 1968 D. H. GRIFFIN ORTHOPEDIC EXERCISING DEVICE AND COMPOSITION AND PROCESS FOR MAKING THE SAME Filed Sept 10 1964 FIG 4 FIG 3 IN VEN T OR. Donald H. Griffin B Y X ATTORNEYS United States Patent 3,413,243 ORTHOPEDIC EXERCISING DEVICE AND COM- POSITION AND PROCESS FOR MAKING THE SAME Donald H. Grifiin, Jamestown, N.C., assignor to The Fli- Back Company, Inc., High Point, N.C., a corporation of North Carolina Filed Sept. 10, 1964, Ser. No. 399,958 3 Claims. (Cl. 260--2.5)
ABSTRACT OF THE DISCLOSURE Orthopedic exercising device in the form of a ball formed of a mass of interconnected air cells defined by resilient wall membranes formed of an expanded blend of sheet natural rubber, styrene-butadiene rubber and ground cured rubber sponge scrap. The mass has a density of approximately 0.012 to 0.020 pound per cubic inch and requires an application of approximately 0.57 pound per square inch pressure for a percent deflection. The cells at the periphery of the ball are normally maintained substantially closed to preclude passage of air from within the mass, and are opened for expelling and absorbing of air on compression of, and relaxation of pressure on, the mass.
This invention relates to the production of an orthopedic exercising device and relates more particularly to an orthopedic exercising ball, its composition and process of manufacture.
As conducive to a better understanding of the instant inventive concept, it should be recognized that various attempts have been made heretofore to produce exercising devices for strengthening the hand, wrist and arm muscles. Each of the prior art efforts have been unsatisfactory for one or more reasons. For example, certain devices currently on the market comprise angularly spaced grips interconnected at their vertex by a relatively heavy coil spring, or the like. These exercisers are not only expensive to manufacture and cumbersome to utilize and store, but they frequently discourage the user because of the excessive pressure normally required to operate them and the relatively quick muscular weariness which their use develops. Other developments have produced devices incorporating a resilient material such as conventional foam rubber or plastic as a portion or the entirety of the same. Frequently, such devices have been provided with a configuration conforming at least in part to the hand structure which results in increasing the costs to fabricate the article and decreasing the flexibility of its use since it must be positioned in a particular manner before manual pressure for exercising can be begun. Also, the particular materials used heretofore have generally been difiicult to compress and have suffered from the disadvantage that, particularly after extended use, they have failed to return to their original dimensions and shape on release of compression.
Thus, it will be seen that there is a need for a more commercially attractive exercising device.
It is, therefore, a primary object of this invention to provide an exercising device free from the foregoing and other disadvantages.
A further object of the instant invention is the provision of an exercising ball formed of a unique composition and in a novel manner whereby it has resultant physical 3,413,243 Patented Nov. 26, 1968 properties rendering it particularly useful in strengthening the muscles of the hand, wrist and arm.
Another object resides in the provision of a device of the type described which may be utilized for its therapeutic value in exercising various muscular tissue weakened or damaged as the result of certain illnesses.
A still further object of the instant invention is to provide an exerciser for building up various hand, wrist and arm muscles frequently utilized in certain sports, such as improving the grip or power in bowling, baseball, tennis, golf, and the like.
Yet another object is the provision of a composition for making exercising devices in accordance with the instant inventive concept comprised essentially of an eX- panded or foamed blend of certain rubber materials resulting in an article which is uniquely resilient, returning to its original dimensions and configuration even after extended use, while being relatively soft and flexible whereby the user will not be discouraged from long periods of exercise because of undue tiring of his hand.
A further object of the instant invention is to provide a process for manufacturing such an article which is particularly eflicient and reliable for producing exercisers of consistent physical properties and high quality in a most expeditious manner.
Still another object is the provision of an orthopedic exercising device which is sturdy and durable in construction, highly efi'icient in use and relatively inexpensive to manufacture.
Other and further objects reside in the combination of materials, steps of procedure and characteristics of the article to be fully described in detail hereinafter and as shown on the accompanying drawing wherein:
FIGURE 1 is a plan view of an exercising device in accordance with the instant inventive concept;
FIGURE 2 shows the same being compressed in use;
FIGURE 3 is an enlarged fragmentary cross-sectional view of the uncompressed form of the device; and
FIGURE 4 is a view similar to FIGURE 3 showing a cross-section of the device after it has been compressed.
Like reference characters refer to like parts throughout the several views of the drawings.
Referring now to the drawing, it has been found that an article having the exemplary features set forth above can be produced by blending a sheet natural rubber with a Styrenebutadiene rubber and ground cured rubber sponge scrap along with selected blowing agents, processing aids, peptizing agents, antioxidants, vulcanizers and other conventional rubber making materials, followed by various procedural steps in treatment of the blend to expand the same within a closed mold into a ball 10 or the like of substantially open-cellular construction having the desired characteristics. By maintaining the weight of material deposited within the mold in a certain relationship to the volume of the mold, an article having a density of from 0.012 to 0.020 pound per cubic inch can be produced which has been found to provide the best muscle strengthening and building function without unduly tiring the hand during use. The cells of the completed product are defined by resilient wall membranes 12 which include openings or pores 14 interconnecting the interstices for passage of air during compression or squeezing of the exerciser. By expanding the blended material within a closed mold, the periphery or skin 1 6 of the finished article is found to have the majority of its pores normally closed due to the inherent resiliency of the membranes and the deformation of the outer layer by contact with the mold wall, Note, particularly FIGURE 3. In effect, these pores act as minute valve members normally precluding passage of air from within the mass. On the application of pressure by squeezing the article in use as shown in FIGURE 2, the pores are opened to expel air in order that the mass may be compressed, the pores remaining open on relaxation of the pressure until the article has returned to its original dimensions and shape. The opened relationship of the pores will be seen in FIGURE 4.
The particular ratio of the three base rubber materials for manufacture of an optimum product is approximately 110 parts by weight of the sheet natural rubber to each parts by weight of the styrene-butadiene rubber and 10 parts by weight of the ground cured rubber sponge scrap. While the above ratio has been found to be best suited to the desired physical properties in the resultant article, it is to be understood that satisfactory properties can be obtained with from 80 to 110 parts by weight sheet natural rubber, to each 10 to 40 parts by weight styrene-butadiene rubber and 5 to 20 parts by weight ground cured rubber sponge scrap. A blend of this material is made with conventional process aids, peptizing agents, extenders and white cotton flock. The blend is premasticated a plurality of times and intermixed with other ingredients such as blowing agents, antioxidants, accelerators, vulcanizers and other well known rubber making materials.
After aging, the resultant intermixture is extruded and cut into slugs to form a charge of desired size, depending upon the size of the mold to be utilized. As mentioned hereinabove, the weight of the slugs are predetermined to provide a completed product of a density between 0.012 and 0.020 pound per cubic inch. This weight is readily determined by multiplying the desired density of the finished article by the volume of the mold which in the case of a spherical mold would be according to the following formula:
where D: diameter of the mold.
The slug or charge of intermixture is then introduced into the mold, which is preferably spherical in form for uniformity of product and simplicity of process and use of the product, and the mold is then closed and heated to expand the charge into contact with the interior mold walls.
Although the time and temperature of the expanding and curing procedure can vary, it has been found that, with a steam pressure of approximately 80 pounds per square inch on the upper platen of the mold and approximately 50 pounds per square inch on the lower platen of the mold, a time in minutes of approximately the weight of the slug in grams plus fifteen is optimum.
The following specific examples, in which parts are by weight unless otherwise stated, present data which illustrate and clarify the invention, but should not be so interpreted as to restrict or limit the scope of the same.
EXAMPLE I A blend of the following ingredients designated as #1 Breakdown was premasticated three times in conventional machinery:
An intermixture was then formed of the #1 Breakdown with various other processing ingredients as follows:
#1 Breakdown 122.75
The resultant intermixture was cooled and aged for 24 hours following which it was warmed and extruded in conventional extrusion machinery. The extruded intermixture was cut into slugs which were introduced into a 2.5 inch diameter split spherical mold having an upper platen receiving pounds per square inch steam pressure and a lower platen receiving 50 pounds per square inch steam pressure.
Those skilled in this art will recognize that many of the above ingredients may be readily replaced with their functional equivalents, the only critical constituents being the three basic rubber materials which have been found to be indispensible to satisfactory results. For example, other well-known chemical peptizers, retarders, accelerators, extruders, antioxidants, process aids, blowing agents, and the like, may be substituted for the specific constituents referred to above.
EXAMPLE IA A 45 gram slug of the intermixture is heated for ap proximately 60 minutes at which time the expanded product is removed and cooled. The density of the finished product is measured as 0.0124 pound per cubic inch and a standard compression-deflection apparatus gives a reading of 0.56 at 10 percent deflection on a cylindrical sample having a diameter of 2 inches and a height of 1 inch.
EXAMPLE IB A 70 gram slug is similarly treated for approximately minutes, removed and cooled. The density is calculated at 0.0193 and the 10 percent deflection reading is 0.58.
Each of the above samples and other samples having a density of from about 0.012 to 0.020 pound per cubic inch are found to be relatively soft, allowing extended manipulation of the finished product by hand squeezing without undesirable weariness of the user. However, the article offers suflicient resistance to be of great value in strengtheinng of the hand, wrist and arm muscles. Extensive compression and relaxation of the exerciser is not found to affect its ability to return to its original dimensions and shape.
A decrease of the density below about 0.012 pound per cubic inch produces an article which fails to provide suflicient resistance for proper muscle building and which has a tendency to be weak in construction and an increase of the density above about 0.020 pound per cubic inch results in a product causing undue weariness after extended use.
EXAMPLE [I The procedure of Example I is repeated replacing the sodium bicarbonate with approximately equal quantities of ammonium bicarbonate or sodium carbonate and replacing the N,N-dinitrosopentamethylenetetramine with approximately equal quantities of azodicarbonamide or 70% N,N' dimethyin N,N' dinitroso terephthalamide. Samples of the resultant product having a density of from about 0.012 to 0.020 pound per cubic inch were found to be equally satisfactory.
Thus, it will be seen that there is herein provided an orthopedic exercising device and a composition and process for producing the same which satisfies all of the objects of the instant invention, and others, including many advantages of great practical utility and commercial importance.
Since many embodiments may be made of the instant inventive concept, and since many modifications may be made of the embodiments hereinbetore described, it is to be understood that all matter herein is to be interpreted merely as illustrative and not in a limiting sense.
What is claimed is:
1. An orthopedic ball comprising a mass of interconnected air cells defined by resilient wall membranes formed of an expanded blend of sheet natural rubber, styrene-butadiene rubber and ground cured rubber sponge scrap, said expanded blend including from approximately 80 to 110 parts by weight sheet natural rubber to each 10 to 40 parts by weight styrene-butadiene rubber and 5 to 20 parts by weight ground cured rubber sponge scrap,
and said mass having a density of approximately 0.012 to 0.020 pound per cubic inch.
2. The article of claim 1 wherein said mass requires an application of approximately 0.57 pound per square inch pressure for a ten percent deflection.
3. The article of claim 1 wherein portions of said wall membrane defining each cell include openings whereby each cell is in communication with at least some of the surrounding cells, the periphery of said mass being defined by said wall membrane of an outer layer of said cells, a major number of said openings in said wall membrane defining said periphery being normally maintained substantially closed to preclude passage of air from within said mass, and being opened for expelling and absorbing of air on compression of, and relaxation of pressure on, said mass.
References Cited UNITED STATES PATENTS 2,539,931 1/1951 Rogers et al 2602.5 3,083,124 3/1963 Rahmes 2602.5 1,345,904 7/1920 Wishart 27358 2,891,016 6/1959 Kern et al. 2602.5
MURRAY TILLMAN, Primary Examiner.
W. I. BRIGGS, SR., Assistant Examiner.
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US399958A US3413243A (en) | 1964-09-10 | 1964-09-10 | Orthopedic exercising device and composition and process for making the same |
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US399958A US3413243A (en) | 1964-09-10 | 1964-09-10 | Orthopedic exercising device and composition and process for making the same |
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Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4114449A (en) * | 1976-08-18 | 1978-09-19 | Dikeman Forrest L | Squeeze type exerciser device with force measuring gauge |
US4711445A (en) * | 1981-09-03 | 1987-12-08 | Duro Med Industries, Inc. | Therapeutic hand exerciser |
US4840370A (en) * | 1980-07-29 | 1989-06-20 | Biddlecombe Thomas W | Hand and digit exerciser |
EP0320958A1 (en) * | 1987-12-18 | 1989-06-21 | Mauch, Walter, Dr. med. | Massage device |
WO1991000754A1 (en) * | 1989-07-06 | 1991-01-24 | Davis J Mark | Exercise device |
DE9002290U1 (en) * | 1990-02-27 | 1991-03-28 | Coronet - Werke Heinrich Schlerf Gmbh, 6948 Wald-Michelbach | Massager |
US5798411A (en) * | 1997-09-19 | 1998-08-25 | The Hygenic Corporation | Compressible polyurethane compositions having minimal tack and articles therefrom |
US5971890A (en) * | 1997-11-12 | 1999-10-26 | Tyne; Philip J. | Chin and neck exerciser |
US6203470B1 (en) | 1997-11-12 | 2001-03-20 | Christopher B. Lundin | Chin and neck exerciser with a vibrator |
US6210304B1 (en) | 1992-06-09 | 2001-04-03 | Mark A. Scatterday | Deformable grip |
US6454681B1 (en) | 1998-01-05 | 2002-09-24 | Thomas Brassil | Hand rehabilitation glove |
WO2002018018A3 (en) * | 2000-08-03 | 2002-10-10 | Terry Paul Zachary | Apparatus for exercising the human hand |
US20040009846A1 (en) * | 2002-07-15 | 2004-01-15 | Smith Joseph O. | Hand exerciser with enhanced strengthening ability |
US20050221909A1 (en) * | 2004-04-02 | 2005-10-06 | Sang-Ki Nam | Golf club with transparent grip |
US20070087901A1 (en) * | 1998-01-05 | 2007-04-19 | Brassil Thomas W | Therapy system |
US20160346626A1 (en) * | 2015-05-28 | 2016-12-01 | Adidas Ag | Non-inflatable sports balls |
USD819147S1 (en) * | 2015-12-22 | 2018-05-29 | Ryan B. Johns | Stress reduction squeeze toy |
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US2539931A (en) * | 1948-03-26 | 1951-01-30 | Wingfoot Corp | Frothed latex sponge rubber |
US2891016A (en) * | 1955-08-26 | 1959-06-16 | Rhein Chemie Rheinau Gmbh | Process for the manufacture of finely porous butadiene-styrene copolymers |
US3083124A (en) * | 1959-03-20 | 1963-03-26 | Int Latex Corp | Cellular materials and articles and method of producing |
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1964
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Patent Citations (4)
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US1345904A (en) * | 1919-08-05 | 1920-07-06 | Wishart James Benjamin | Sponge-rubber article and method of making the same |
US2539931A (en) * | 1948-03-26 | 1951-01-30 | Wingfoot Corp | Frothed latex sponge rubber |
US2891016A (en) * | 1955-08-26 | 1959-06-16 | Rhein Chemie Rheinau Gmbh | Process for the manufacture of finely porous butadiene-styrene copolymers |
US3083124A (en) * | 1959-03-20 | 1963-03-26 | Int Latex Corp | Cellular materials and articles and method of producing |
Cited By (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4114449A (en) * | 1976-08-18 | 1978-09-19 | Dikeman Forrest L | Squeeze type exerciser device with force measuring gauge |
US4840370A (en) * | 1980-07-29 | 1989-06-20 | Biddlecombe Thomas W | Hand and digit exerciser |
US4711445A (en) * | 1981-09-03 | 1987-12-08 | Duro Med Industries, Inc. | Therapeutic hand exerciser |
EP0320958A1 (en) * | 1987-12-18 | 1989-06-21 | Mauch, Walter, Dr. med. | Massage device |
WO1989005622A1 (en) * | 1987-12-18 | 1989-06-29 | Walter Mauch | Massage device |
WO1991000754A1 (en) * | 1989-07-06 | 1991-01-24 | Davis J Mark | Exercise device |
DE9002290U1 (en) * | 1990-02-27 | 1991-03-28 | Coronet - Werke Heinrich Schlerf Gmbh, 6948 Wald-Michelbach | Massager |
US6210304B1 (en) | 1992-06-09 | 2001-04-03 | Mark A. Scatterday | Deformable grip |
US6482129B2 (en) | 1992-06-09 | 2002-11-19 | Mark A. Scatterday | Deformable grip |
US5798411A (en) * | 1997-09-19 | 1998-08-25 | The Hygenic Corporation | Compressible polyurethane compositions having minimal tack and articles therefrom |
US6084027A (en) * | 1997-09-19 | 2000-07-04 | The Hygenic Corporation | Compressible polyurethane compositions having minimal tack and articles therefrom |
US6203470B1 (en) | 1997-11-12 | 2001-03-20 | Christopher B. Lundin | Chin and neck exerciser with a vibrator |
US5971890A (en) * | 1997-11-12 | 1999-10-26 | Tyne; Philip J. | Chin and neck exerciser |
US6454681B1 (en) | 1998-01-05 | 2002-09-24 | Thomas Brassil | Hand rehabilitation glove |
US20030054923A1 (en) * | 1998-01-05 | 2003-03-20 | Thomas Brassil | Hand rehabilitation glove |
US20070087901A1 (en) * | 1998-01-05 | 2007-04-19 | Brassil Thomas W | Therapy system |
WO2002018018A3 (en) * | 2000-08-03 | 2002-10-10 | Terry Paul Zachary | Apparatus for exercising the human hand |
US20040009846A1 (en) * | 2002-07-15 | 2004-01-15 | Smith Joseph O. | Hand exerciser with enhanced strengthening ability |
US20050221909A1 (en) * | 2004-04-02 | 2005-10-06 | Sang-Ki Nam | Golf club with transparent grip |
US7025690B2 (en) * | 2004-04-02 | 2006-04-11 | Sang-Ki Nam | Golf club with transparent grip |
US20160346626A1 (en) * | 2015-05-28 | 2016-12-01 | Adidas Ag | Non-inflatable sports balls |
US10850165B2 (en) * | 2015-05-28 | 2020-12-01 | Adidas Ag | Non-inflatable sports balls |
USD819147S1 (en) * | 2015-12-22 | 2018-05-29 | Ryan B. Johns | Stress reduction squeeze toy |
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