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US3377162A - Stainless steel - Google Patents

Stainless steel Download PDF

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Publication number
US3377162A
US3377162A US483826A US48382665A US3377162A US 3377162 A US3377162 A US 3377162A US 483826 A US483826 A US 483826A US 48382665 A US48382665 A US 48382665A US 3377162 A US3377162 A US 3377162A
Authority
US
United States
Prior art keywords
stainless steel
copper
vanadium
steel
iron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US483826A
Other languages
English (en)
Inventor
Bleloch William
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rand Mines Ltd
Original Assignee
Rand Mines Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rand Mines Ltd filed Critical Rand Mines Ltd
Application granted granted Critical
Publication of US3377162A publication Critical patent/US3377162A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/20Ferrous alloys, e.g. steel alloys containing chromium with copper

Definitions

  • This invention relates to a stainless steel and more particularly to a stainless steel having good rust resistant a properties but which does not require a large proportion of expensive alloying elements such as molybdenum.
  • Stainless steel has become generally recognized as a steel which includes more than of chromium but the term is used in this specification to include steels which have any effective amount of chromium in their composition and it is to be understood that an effective amount of chromium as far as rust resistance is concerned is 1% or more. Where percentages of constituents are referred to hereinafter it will be appreciated that these are given as percentages by weight.
  • a stainless steel having a constituent composition of at least iron, an effective quantity of chromium, a minimum vanadium content of 0.3% and a carbon content which is below a maximum 0.03%.
  • iron-copper phase diagram indicates that up to 8% of copper is soluble in austenite, and therefore under equilibrium conditions iron-copper alloys up to this composition and of low carbon content should be forgeable in the normal industrial range of 1l001200 C. Alloys containing larger amounts of copper have a duplex structure; the copper rich phase is molten above 1094 C. and incipient melting of the alloys takes place if they are exposed to temperatures above this. In practice, iron-copper alloys containing very considerably less than 8% of copper are subject to incipient melting when exposed to temperatures above 1094 C. and even in some cases below this temperature.
  • the copper-rich phase is very difficult to remove because the rate of diffusion of copper in iron is low below 1100 C. Hot-working helps, but if the amount of copper-rich phase is large the metal disintegrates, so that the alternatives are either to prevent the formation of the low melting point phase by adjusment of composition or hot-work only below its melting point.
  • the stainless steel of the type specified includes copper as an alloying element in a quantity in excess of 2.5 and for the percentage of vanadium in the steel to increase with increased copper content.
  • the invention also provides for the vanadium to be obtained and introduced directly into the steel from an ore containing vanadium such as a Transvaal type titaniferous magnetite.
  • a still further feature of this invention provides for the steel to be made by the process set forth in our patent application Ser. No. 355,895.
  • this invention provides a stainless steel which includes appreciable quantities of vanadium and also the very low carbon content which features enable a product to be obtained which has desirable rust resistant properties and at a highly competitive price when made in accordance with the process of our previous patent application Ser. No. 355,895. It will also be clear to those skilled in the art that for certain purposes, the advantageous properties obtainable through the inclusion in very low carbon content stainless steel of vanadium in the range 0.3% to 2.0% and copper in the tectural cladding purposes the steel will have a composition consisting essentially of:
  • the balance being iron and the carbon content being below 0.03%.
  • a stainless steel consisting essentially of 1% to 30% chromium; 0.3% to 2.0% vanadium; 2.5% to 4% copper; up to 0.03% carbon, the balance being iron, all percentages being by weight of the composition.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)
  • Treatment Of Steel In Its Molten State (AREA)
US483826A 1964-09-10 1965-08-30 Stainless steel Expired - Lifetime US3377162A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ZA644319 1964-09-10

Publications (1)

Publication Number Publication Date
US3377162A true US3377162A (en) 1968-04-09

Family

ID=25560848

Family Applications (1)

Application Number Title Priority Date Filing Date
US483826A Expired - Lifetime US3377162A (en) 1964-09-10 1965-08-30 Stainless steel

Country Status (6)

Country Link
US (1) US3377162A (xx)
AT (1) AT271534B (xx)
BE (1) BE669439A (xx)
ES (1) ES317217A1 (xx)
GB (1) GB1084877A (xx)
NL (1) NL6511773A (xx)

Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1803467A (en) * 1930-07-03 1931-05-05 Gilby Wire Company Electrical-resistance alloy
US2120554A (en) * 1935-06-08 1938-06-14 Union Carbide & Carbon Corp Chromium steel
US2187525A (en) * 1929-09-19 1940-01-16 Krupp Nirosta Company Inc Article of welded construction
US2193222A (en) * 1930-01-02 1940-03-12 Allegheny Steel Co Vanadium steel alloy
US2315156A (en) * 1941-10-10 1943-03-30 Clifford P Larrsbee Low-alloy corrosion-resistant steel
US2797992A (en) * 1954-07-30 1957-07-02 Babcock & Wilcox Co Forgeable high strength austenitic alloy with copper and columbiumtantalum additions
US2845345A (en) * 1958-07-29 Process for purifying mercury
US2848323A (en) * 1955-02-28 1958-08-19 Birmingham Small Arms Co Ltd Ferritic steel for high temperature use
US2850380A (en) * 1957-03-04 1958-09-02 Armco Steel Corp Stainless steel
US2854330A (en) * 1957-03-04 1958-09-30 Armco Steel Corp Stainless steel and method
US2865741A (en) * 1957-11-06 1958-12-23 United States Steel Corp Acid resistant austenitic stainless steel
US2894867A (en) * 1957-07-11 1959-07-14 United States Steel Corp Method of producing transformation hardenable stainless steel and articles produced therefrom
US2968549A (en) * 1959-06-10 1961-01-17 United States Steel Corp High strength alloy for use at elevated temperatures

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2845345A (en) * 1958-07-29 Process for purifying mercury
US2187525A (en) * 1929-09-19 1940-01-16 Krupp Nirosta Company Inc Article of welded construction
US2193222A (en) * 1930-01-02 1940-03-12 Allegheny Steel Co Vanadium steel alloy
US1803467A (en) * 1930-07-03 1931-05-05 Gilby Wire Company Electrical-resistance alloy
US2120554A (en) * 1935-06-08 1938-06-14 Union Carbide & Carbon Corp Chromium steel
US2315156A (en) * 1941-10-10 1943-03-30 Clifford P Larrsbee Low-alloy corrosion-resistant steel
US2797992A (en) * 1954-07-30 1957-07-02 Babcock & Wilcox Co Forgeable high strength austenitic alloy with copper and columbiumtantalum additions
US2848323A (en) * 1955-02-28 1958-08-19 Birmingham Small Arms Co Ltd Ferritic steel for high temperature use
US2850380A (en) * 1957-03-04 1958-09-02 Armco Steel Corp Stainless steel
US2854330A (en) * 1957-03-04 1958-09-30 Armco Steel Corp Stainless steel and method
US2894867A (en) * 1957-07-11 1959-07-14 United States Steel Corp Method of producing transformation hardenable stainless steel and articles produced therefrom
US2865741A (en) * 1957-11-06 1958-12-23 United States Steel Corp Acid resistant austenitic stainless steel
US2968549A (en) * 1959-06-10 1961-01-17 United States Steel Corp High strength alloy for use at elevated temperatures

Also Published As

Publication number Publication date
BE669439A (xx) 1965-12-31
AT271534B (de) 1969-06-10
ES317217A1 (es) 1966-03-16
NL6511773A (xx) 1966-03-11
GB1084877A (en) 1967-09-27

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