US3339638A - Corrosion arrestor for fire extinguisher - Google Patents
Corrosion arrestor for fire extinguisher Download PDFInfo
- Publication number
- US3339638A US3339638A US462505A US46250565A US3339638A US 3339638 A US3339638 A US 3339638A US 462505 A US462505 A US 462505A US 46250565 A US46250565 A US 46250565A US 3339638 A US3339638 A US 3339638A
- Authority
- US
- United States
- Prior art keywords
- corrosion
- arrestor
- fire extinguisher
- extinguisher
- tank
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000007797 corrosion Effects 0.000 title description 39
- 238000005260 corrosion Methods 0.000 title description 39
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 9
- 229910001220 stainless steel Inorganic materials 0.000 description 9
- 239000010935 stainless steel Substances 0.000 description 9
- 229910052725 zinc Inorganic materials 0.000 description 9
- 239000011701 zinc Substances 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62C—FIRE-FIGHTING
- A62C13/00—Portable extinguishers which are permanently pressurised or pressurised immediately before use
- A62C13/76—Details or accessories
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F13/00—Inhibiting corrosion of metals by anodic or cathodic protection
- C23F13/02—Inhibiting corrosion of metals by anodic or cathodic protection cathodic; Selection of conditions, parameters or procedures for cathodic protection, e.g. of electrical conditions
- C23F13/06—Constructional parts, or assemblies of cathodic-protection apparatus
- C23F13/08—Electrodes specially adapted for inhibiting corrosion by cathodic protection; Manufacture thereof; Conducting electric current thereto
- C23F13/18—Means for supporting electrodes
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F2213/00—Aspects of inhibiting corrosion of metals by anodic or cathodic protection
- C23F2213/30—Anodic or cathodic protection specially adapted for a specific object
Definitions
- the invention was partially concerned with the prevention of corrosion to certain internal parts, such as metal siphon tubes, valve housings, and the like, forming a part of the interior construction of the extinguisher.
- the present invention is directed for the most part towards preventing corrosion on the inner surface of stainless steel fire extinguisher tanks, as such.
- Corrosion of stainless steel tanks of fire extinguishers is most often prevalent under conditions in which water is used as an extinguishing agent, and wherein sodium chloride or salt is contained in the water which reacts to form a solution with other than neutral pH readings.
- the present invention is directed, for the most part, to water type extinguishers in which the water with the presence of sodium chloride or other impurities may give rise to acidic or alkaline conditions such that an electrolyte is formed which in turn effects corrosion of the interior of the stainless steel fire extinguishers shell or tank.
- magnesium was used as the corrosion arrestor element because of its point in the electromotive series or electro-chemical scale.
- magnesium since magnesium is at the higher end of the electrochemical scale, it would tend to become a sacrificial anode; further than this, magnesium combines with the water and/or acid to form magnesium hydroxide which also has a neutralizing effect with respect to certain acids that might otherwise corrode the internal components within the fire extinguisher tank or shell.
- the corrosion arrestor of the present invention is preferably formed of zinc in view of the lesser expense involved, although it is, of course, possible to use any element higher in the electro-chemical scale.
- one of the objects of the present invention is to provide an improved corrosion arrestor which may be inexpensively formed and securely mounted within the fire extinguisher tank.
- Another object of the present invention is to provide an improved corrosion arrestor structure which is so constructed that it will not readilly deteriorate into small pieces or result in any loose particles which could interrupt the discharge of the extinguisher.
- a still further object of the present invention is to provide a very simple structure for a corrosion arrestor and for the manufacture of same with the end in view of mass production of the corrosion arrestor as well as avoiding any maintenance therefor.
- Still a further object of the present invention is to provide an improved corrosion arrest-or which embodies a sacrificial anode which may be replaced after it has been used up or substantially used up in an electrolytic solution.
- an improved corrosion arrestor including a U-shaped bracket designed for attachment to the tank sidewall, .a flat member of zinc material functioning as the sacrificial anode metal, and a means of coupling the flat material to the U-shaped bracket.
- FIGURE 1 is a view of a permanent type corrosion arrestor structure, according to the present invention.
- FIGURE 2 is .a view taken in the direction of the arrows 22 of FIGURE 1 illustrating the zinc strip forming the sacrificial material of the corrosion arrestor of FIGURE 1;
- FIGURE 3 is a view of a corrosion arrestor structure in which a replaceable anode disc is embodied.
- FIGURE 4 is a view of a modified form of the corrosion arrestor structure of FIGURE 3 showing a somewhat different mounting bracket and position of same with respect to the fire extinguisher tank.
- FIG- URES l and 2 there is shown in FIG- URES l and 2, a corrosion arrestor 10 mounted on the bottom portion 11 of an extinguisher tank 12.
- the bottom portion 11 is usually formed separately, at which time the corrosion arrestor 10 is mounted therein; thereafter, the bottom portion 11 is welded to the sidewalls 12 of the tank.
- the corrosion arrestor 10 embodies an elongated strip 13 which is bent at its ends to form legs 14, the latter being in turn bent to form feet 15 for spot welding to the tank bottom 11.
- the actual sacrificial metal or anode is formed by a zinc strip 16 which is secured to the elongated member 13 of the bracket 10 by rivets 17.
- a permanent type corrosion arrestor is formed with the strip 16 forming the sacrificial metal preventing corrosion of the interior of the sidewalls of the tank 12, the latter being formed of stainless steel.
- the corrosion arrestor will be employed in tanks including plastic siphon tubes not shown in the attached drawing.
- the structure for a corrison arrestor illustrated in FIGURE 1 may not be quite so advantageous.
- the corrosion arrestor is of a permanent type, there also exists a possibility that the zinc strip may be eaten away intermediate of the ends such that portions of the stri may become free within the fire extinguisher tank with the resultant possibility of interference with the discharge of the extinguisher.
- FIGURE 3 discloses a replaceable corrosion arrestor unit also located in the bottom portion of the extinguisher.
- the corrosion arrestor 18 includes a U-shaped bracket 19 having feet 20 welded to the bottom 11 of the fire extinguisher tank.
- the U-shaped bracket 19 further embodies an upper base portion 21 preferably having welded to the bottom thereof a nut 22 designed to receive a screw 23.
- a circular disc 24 of Zinc material Positioned above the base portion 21 of the bracket 18 is a circular disc 24 of Zinc material functioning as the sacrificial anode in this case.
- FIGURE 4 An alternate construction is shown in FIGURE 4.
- FIGURE 4 in which the same numerals indicate the same parts, there is shown a bracket 25 also U-shaped, including a foot 26 welded to the extinguishers sidewalls 12 and another foot 27 designed to have welded thereto a nut 28 for receiving a screw 29.
- the foot 27 has coupled thereto a disc of sacrificial zinc material 30 in the same manner as the construction of FIGURE 3.
- a corrosion arrestor designed for mounting in said shell, said corrosion arrestor comprising: a bracket having one portion securely connected to the interior sidewall of said stainless steel shell proximate said upper opening so that access may be had through said opening, another portion of said bracket being designed to receive a screw; a substantially flat member made of metal higher in the electrochemical scale than stainless steel connected'at a central portion to said another portion of said bracket by said screw and in contact therewith such that said flat member is in metal to metal contact with said bracket whereby said flat member acts as a sacrificial anode relative to said stainless steel shell so that the flat member is eaten away generally in a direction from its periphery towards its central portion receiving said screw as a result of any electrolytical action from said liquid rather than the stainless steel shell and whereby said fiat member may be replaced by removing said screw when eaten away as a sacrificial anode.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Prevention Of Electric Corrosion (AREA)
Description
p 5 1967' c. K. HUTHSING, JR 3,339,638
CORROSION ARRESTOR FOR FIRE EXTINGUISHER Filed June 9, 1965 INVENTOR. CHARLES K. H(/7f/J//V6, c/E.
. ATTORNEYS United States Patent 3,339,638 CORROSION ARRESTOR FOR FIRE EXTINGUISHER Charles K. Huthsing, Jr., 1685 Shermer Road, Northbrook, II]. 60062 FiledJuue 9, 1965, Ser. No. 462,505 1 Claim. (Cl. 169-30) ABSTRACT OF THE DISCLOSURE The present invention relates to improvements in corrosion ar restors for use in fire exinguishers for preventing corrosion therein. The present invention represents an improvement over applicants previously issued Patents No.
r 2,563,171, dated Aug. 7, 1951, for Apparatus for Controlling Corrosion in Fire Extinguishers, and No. 3,153,453, dated Oct. 20, 19 64, for Corrosion Arrestor for use in Fire Extinguishers.
In each of the aforementioned patents, the invention was partially concerned with the prevention of corrosion to certain internal parts, such as metal siphon tubes, valve housings, and the like, forming a part of the interior construction of the extinguisher.
The present invention is directed for the most part towards preventing corrosion on the inner surface of stainless steel fire extinguisher tanks, as such.
Corrosion of stainless steel tanks of fire extinguishers is most often prevalent under conditions in which water is used as an extinguishing agent, and wherein sodium chloride or salt is contained in the water which reacts to form a solution with other than neutral pH readings. Thus, the present invention is directed, for the most part, to water type extinguishers in which the water with the presence of sodium chloride or other impurities may give rise to acidic or alkaline conditions such that an electrolyte is formed which in turn effects corrosion of the interior of the stainless steel fire extinguishers shell or tank.
Although the invention will be described from the standpoint of pressurized water type extinguishers, it will also be appreciated that the corrosion arrestor of the present invention may also 'be used with soda-acid and foam type extinguishers.
In the aforementioned patents of applicant, magnesium was used as the corrosion arrestor element because of its point in the electromotive series or electro-chemical scale. Thus, since magnesium is at the higher end of the electrochemical scale, it would tend to become a sacrificial anode; further than this, magnesium combines with the water and/or acid to form magnesium hydroxide which also has a neutralizing effect with respect to certain acids that might otherwise corrode the internal components within the fire extinguisher tank or shell.
Since the present invention is, however, directed for the most part, to the extinguisher shell or tank, as such, and since zinc is considerably further up the elect-romotive scale than any of the metals'contained in steel, the corrosion arrestor of the present invention is preferably formed of zinc in view of the lesser expense involved, although it is, of course, possible to use any element higher in the electro-chemical scale.
With this state of the art in mind, one of the objects of the present invention is to provide an improved corrosion arrestor which may be inexpensively formed and securely mounted within the fire extinguisher tank.
Another object of the present invention is to provide an improved corrosion arrestor structure which is so constructed that it will not readilly deteriorate into small pieces or result in any loose particles which could interrupt the discharge of the extinguisher.
A still further object of the present invention is to provide a very simple structure for a corrosion arrestor and for the manufacture of same with the end in view of mass production of the corrosion arrestor as well as avoiding any maintenance therefor.
Still a further object of the present invention is to provide an improved corrosion arrest-or which embodies a sacrificial anode which may be replaced after it has been used up or substantially used up in an electrolytic solution.
These and other objects and advantages of the present invention are generally achieved by providing an improved corrosion arrestor including a U-shaped bracket designed for attachment to the tank sidewall, .a flat member of zinc material functioning as the sacrificial anode metal, and a means of coupling the flat material to the U-shaped bracket.
Several embodiments of the present invention are shown in the drawings, illustrating merely certain forms the invention might take, and in which:
FIGURE 1 is a view of a permanent type corrosion arrestor structure, according to the present invention;
FIGURE 2 is .a view taken in the direction of the arrows 22 of FIGURE 1 illustrating the zinc strip forming the sacrificial material of the corrosion arrestor of FIGURE 1;
, FIGURE 3 is a view of a corrosion arrestor structure in which a replaceable anode disc is embodied; and,
FIGURE 4 is a view of a modified form of the corrosion arrestor structure of FIGURE 3 showing a somewhat different mounting bracket and position of same with respect to the fire extinguisher tank.
Referring now to the drawings, there is shown in FIG- URES l and 2, a corrosion arrestor 10 mounted on the bottom portion 11 of an extinguisher tank 12. The bottom portion 11 is usually formed separately, at which time the corrosion arrestor 10 is mounted therein; thereafter, the bottom portion 11 is welded to the sidewalls 12 of the tank.
The corrosion arrestor 10 embodies an elongated strip 13 which is bent at its ends to form legs 14, the latter being in turn bent to form feet 15 for spot welding to the tank bottom 11.
The actual sacrificial metal or anode is formed by a zinc strip 16 which is secured to the elongated member 13 of the bracket 10 by rivets 17. Thus, a permanent type corrosion arrestor is formed with the strip 16 forming the sacrificial metal preventing corrosion of the interior of the sidewalls of the tank 12, the latter being formed of stainless steel. Usually the corrosion arrestor will be employed in tanks including plastic siphon tubes not shown in the attached drawing.
Under certain operating conditions, the structure for a corrison arrestor illustrated in FIGURE 1 may not be quite so advantageous. Other than the fact that the corrosion arrestor is of a permanent type, there also exists a possibility that the zinc strip may be eaten away intermediate of the ends such that portions of the stri may become free within the fire extinguisher tank with the resultant possibility of interference with the discharge of the extinguisher.
In order to avoid the latter possibility and at the same time provide for replacement of the sacrificial zinc maperhaps be preferable.
The embodiment of FIGURE 3 discloses a replaceable corrosion arrestor unit also located in the bottom portion of the extinguisher. Thus, looking at FIGURE 3, the same parts have been designated by the same numerals, such that the corrosion arrestor 18 is secured to the bottom 11 of the extinguisher tank 12. The corrosion arrestor 18 includes a U-shaped bracket 19 having feet 20 welded to the bottom 11 of the fire extinguisher tank. The U-shaped bracket 19 further embodies an upper base portion 21 preferably having welded to the bottom thereof a nut 22 designed to receive a screw 23.
Positioned above the base portion 21 of the bracket 18 is a circular disc 24 of Zinc material functioning as the sacrificial anode in this case.
With this type of structure, it will be appreciated that the likelihood of any portion of the circular disc 24 being eaten away so as to form free material within the extinguisher tank is extremely remote. In other words, it is much more likely with this type of structure that the entire disc will be eaten away gradually and in a radially inward direction. Also, it will be appreciated that a new disc may be used to replace the one that is disposed of by merely Undoing the screw 23, inserting a new disc, and thereafter rethreading the screw 23 in the nut 22 welded to the portion 21 of the bracket 19.
Some difliculty, however, might be encountered in obtaining access to the screw 23 through the upper opening in the extinguisher; for this reason, an alternate construction is shown in FIGURE 4.
Referring now to FIGURE 4, in which the same numerals indicate the same parts, there is shown a bracket 25 also U-shaped, including a foot 26 welded to the extinguishers sidewalls 12 and another foot 27 designed to have welded thereto a nut 28 for receiving a screw 29. The foot 27 has coupled thereto a disc of sacrificial zinc material 30 in the same manner as the construction of FIGURE 3.
In this construction, it will be appreciatedin view of the proximity of the corrosion arrestor to the top opening of the extinguisherthat access may be had thereto more conveniently for unthreading of the screw and reinsertion of a new disc 30. In this respect, it is only necessary, for proper functioning, that the corrosion arrestor be below the fill line of the extinguisher.
From the foregoing, it will be appreciated that certain variations and modifications may be made to the improved corrosion arrestor of the present invention Without departing from the spirit and scope of the invention as set forth in the following claim.
What is claimed is:
In a fire extinguisher designed to receive a liquid extinguisher agent and having a stainless steel shell including an upper opening, a corrosion arrestor designed for mounting in said shell, said corrosion arrestor comprising: a bracket having one portion securely connected to the interior sidewall of said stainless steel shell proximate said upper opening so that access may be had through said opening, another portion of said bracket being designed to receive a screw; a substantially flat member made of metal higher in the electrochemical scale than stainless steel connected'at a central portion to said another portion of said bracket by said screw and in contact therewith such that said flat member is in metal to metal contact with said bracket whereby said flat member acts as a sacrificial anode relative to said stainless steel shell so that the flat member is eaten away generally in a direction from its periphery towards its central portion receiving said screw as a result of any electrolytical action from said liquid rather than the stainless steel shell and whereby said fiat member may be replaced by removing said screw when eaten away as a sacrificial anode.
References Cited UNITED STATES PATENTS 8/1951 Huthsing 169-33 10/1964 Huthsing 169-30
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US462505A US3339638A (en) | 1965-06-09 | 1965-06-09 | Corrosion arrestor for fire extinguisher |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US462505A US3339638A (en) | 1965-06-09 | 1965-06-09 | Corrosion arrestor for fire extinguisher |
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US3339638A true US3339638A (en) | 1967-09-05 |
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US462505A Expired - Lifetime US3339638A (en) | 1965-06-09 | 1965-06-09 | Corrosion arrestor for fire extinguisher |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5584345A (en) * | 1991-01-07 | 1996-12-17 | Joy; Rick | Safety ring for bottom of fire extinguisher |
US20110180279A1 (en) * | 2010-01-24 | 2011-07-28 | Lehavot Fire Protection Ltd. | Device and method of protecting a fire extinguisher |
US20130140045A1 (en) * | 2011-11-18 | 2013-06-06 | Minimax Gmbh & Co. Kg | System For extinguishing or Inerting having a Synthetic Liquid extinguishing agent |
USD963827S1 (en) * | 2020-09-10 | 2022-09-13 | Puzhen Life Co., Ltd | Aroma diffuser |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2563171A (en) * | 1949-10-12 | 1951-08-07 | Jr Charles K Huthsing | Apparatus for controlling corrosion in fire extinguishers |
US3153453A (en) * | 1961-09-20 | 1964-10-20 | Jr Charles K Huthsing | Corrosion arrestor for use in fire extinguishers |
-
1965
- 1965-06-09 US US462505A patent/US3339638A/en not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2563171A (en) * | 1949-10-12 | 1951-08-07 | Jr Charles K Huthsing | Apparatus for controlling corrosion in fire extinguishers |
US3153453A (en) * | 1961-09-20 | 1964-10-20 | Jr Charles K Huthsing | Corrosion arrestor for use in fire extinguishers |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5584345A (en) * | 1991-01-07 | 1996-12-17 | Joy; Rick | Safety ring for bottom of fire extinguisher |
US20110180279A1 (en) * | 2010-01-24 | 2011-07-28 | Lehavot Fire Protection Ltd. | Device and method of protecting a fire extinguisher |
US20130140045A1 (en) * | 2011-11-18 | 2013-06-06 | Minimax Gmbh & Co. Kg | System For extinguishing or Inerting having a Synthetic Liquid extinguishing agent |
US9387352B2 (en) * | 2011-11-18 | 2016-07-12 | Minimax Gmbh & Co. Kg | System for extinguishing or inerting having a synthetic liquid extinguishing agent |
USD963827S1 (en) * | 2020-09-10 | 2022-09-13 | Puzhen Life Co., Ltd | Aroma diffuser |
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