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US3196046A - Process for cleaning ovens - Google Patents

Process for cleaning ovens Download PDF

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Publication number
US3196046A
US3196046A US211356A US21135662A US3196046A US 3196046 A US3196046 A US 3196046A US 211356 A US211356 A US 211356A US 21135662 A US21135662 A US 21135662A US 3196046 A US3196046 A US 3196046A
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container
oven
mixture
article
calcium oxide
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US211356A
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Alan D Brite
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24CDOMESTIC STOVES OR RANGES ; DETAILS OF DOMESTIC STOVES OR RANGES, OF GENERAL APPLICATION
    • F24C14/00Stoves or ranges having self-cleaning provisions, e.g. continuous catalytic cleaning or electrostatic cleaning
    • F24C14/005Stoves or ranges having self-cleaning provisions, e.g. continuous catalytic cleaning or electrostatic cleaning using a cleaning liquid

Definitions

  • This invention relates to the art of cleaning and has particular reference to a process and article for cleaning grease and food stained surfaces such as those found in household cooking ovens.
  • a primary object of the present invention is to provide a novel process and article for cleaning the interior surfaces of ovens or the like, which are not subject to the above and other disadvantages of the methods and materials heretofore proposed.
  • Another object of the present invention is to provide a novel article for cleaning ovens and the like, which is non-corrosive, non-toxic, and non-inflammable, yet which is highly effective in use.
  • FIGURE 1 is a perspective view of a preferred form of the article of the present invention.
  • FIGURE 2 is a perspective view illustrating the article in place in an oven and ready for use.
  • FIGURE 3 is a vertical sectional view of the article.
  • FIGURE 3a is a sectional view taken substantially on the line 3a3a of FIGURE 3.
  • FIGURE 4 is a top plan view of a modified form of the invention.
  • FIGURE 5 is a bottom plan view thereof.
  • FIGURE 6 is a vertical sectional view illustrating the manner of use of the article of FIGURES 4 and 5.
  • a preferred form of the article of the present invention is generally indicated 10, including a generally cylindrical container 11 which may be of metal or formed of resin-impregnated cardboard having a metal bottom 12 and top 13, the top being provided with a central opening and a closure 14. Positioned within the container is a cone-shaped cup member 15 formed of resin-impregnated paper or other material suitably treated to render it resistant to cold water.
  • the cup member 15 is open at the top and is provided with a pair of relatively small openings adjacent the bottom or apex thereof, the openings being covered with a plug or layer of a low-melting material such as paraifin wax or the like.
  • the top of the cup member extends just short of the underside of the container top 13 and the apex of the cup member is positioned on the container bottom 12.
  • Stiffeners or ribs 27 of cardboard or the like are positioned inside the cup member, the top edges 28 thereof extending just short of the upper edge of the cup member and the lower edges 29 of the ribs terminating above the openings 20.
  • a chemical mixture 30 is contained in the volume of the container between the outer surface of the cup mem- 3,l%,046 Patented July 20, 1965 her and the inner surfaces of the container side wall and bottom.
  • the mixture 30 comprises calcium oxide in lump form and an ammonium salt such as the chloride, sulfate, nitrate, carbonate, etc., in granular or powder form.
  • the mixture 341 comprises about 400 grams of calcium oxide and 100 grams of ammonium chloride.
  • the relatively fine ammonium chloride settles to the lower portion of the container, leaving the relatively coarse particles of calcium oxide in the upper portion thereof.
  • the closure 14 is removed and hot water poured into the cup member 15 to the approximate level indicated in FIGURE 3.
  • the container is then immediately placed in the oven 50 as indicated in FIGURE 2.
  • the oven should be cold and therefore if of the type having a pilot light, the oven door should be left open for almost an hour prior to use of the article of this invention.
  • the oven door is closed.
  • the hot water in the cup member melts the wax plug 25, permitting the water to slowly seep into contact with the ammonium chloride and calcium oxide mixture. Since the bulk of the ammonium chloride is positioned in the lower portion of the container it is first contacted by the water, causing it to dissolve readily. The water progressively moves upwardly through the mixture, contacting the calcium oxide with the usual exothermic reaction, forming steam. Simultaneously, ammonia gas is liberated from the ammonium chloride. The steam tends to soften the upper portion of the cup member and cause it to collapse inwardly as indicated by the phanton lines of FIGURE 3.
  • the mixture of ammonia gas and steam thus formed rises out of the container opening into the oven and contacts the cold walls thereof, condensing the steam and depositing the ammonia thereon in the form of ammonium hydroxide which exerts its cleaning and dissolving action on the grease and other foreign matter on the oven walls.
  • the reaction is completed in 10-15 minutes and after this period of time the oven door may be opened and the container removed. The oven wall surfaces are then easily wiped clean with a wet cloth or sponge.
  • FIG- URES 4, 5 and 6 A modified form of the invention is illustrated in FIG- URES 4, 5 and 6.
  • the modified article comprises a container 61, preferably of metal, having a cylindrical side Wall 62, a bottom wall 63 and a top closure 64.
  • the top closure is provided with a plurality of small openings 65 covered by a removable cover 66 of pressure-sensitive adhesive tape or the like.
  • the bottom wall 63 is provided with a single central aperture 68, and a similar cover 63a.
  • An indicator mark 69 is provided on the outer surface of the side wall 62.
  • the bottom wall 63 Resting on the upper surface of the bottom wall 63 is a square sheet '70 of paper or like material, the diagonal dimension thereof being approximately equal to the inside diameter of the cylindrical wall 62. Overlying the sheet 70 and bottom wall 63 is a layer 72 of pa-raflin wax or other low melting material.
  • the chemical mixture 30a of the same composition as the mixture 30 described above, fills substantially all of the container above the paraffin layer 72.
  • the article of FIGURES 4-6 In use of the article of FIGURES 4-6, it is placed in a pan or other suitable container and the pan filled with cold water to the indicator mark 69. The article is then removed from the pan and the water heated to a boil. The pan and its contained hot water is then placed in the cold oven, the covers 66 and 68a are removed from the container top and bottom walls and the article is placed in the pan of hot water. The hot water raises the temperature of the container 61 suificiently to melt the wax, permitting the water to seep into the container through the aperture 68, under the sheet 70 and thence into contact with the mixture 30a with the resultant formation of ammonia gas and steam in the same manner and with the same results as described above. It will be seen that the sheet 76 functions as a valve to permit only a relatively slow inflow of water, the outflow of steam and ammonia gas being controlled by the size and number of openings 65.
  • a method for cleaning ovens and the like comprising the steps of placing a container of a mixture of calcium oxide and an ammonium salt in an enclosed oven, adding water to said mixture to form steam and ammonia gas, condensing said steam and gas on the inner surfaces of said oven, and removing said condensate from said surfaces.
  • a method for cleaning ovens and the like comprising- 4 ing the steps or" placing a container of a mixture of calcium oxide and ammonium chloride in an enclosed oven, adding water to said mixture to form steam and ammonia gas, condensing said steam and gas on the inner surfaces of said oven, and removing said condensate from said surfaces.
  • a method for cleaning ovens and the like comprising the steps of adding water to a container of a mixture of calcium oxide and an ammonium salt, immediately placing said container in an enclosed oven whereby steam and ammonia gas from the container is condensed on the inner surfaces of the oven, and removing the condensate thus formed from said surfaces.
  • a method for cleaning ovens and the like comprising the steps of adding water to a container of a mixture of calcium oxide and ammonium chloride, immediately placing said container in an enclosed oven whereby steam and ammonia gas from the container is condensed on the inner surfaces of the oven, and removing the condensate thus formed from said surfaces.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Detergent Compositions (AREA)

Description

July 20, 1965 A. D. BRITE 3,196,046
PROCESS FOR CLEANING OVENS Original Filed March 23, 1959 2 Sheets-Sheet 1 INVENTOR. flflfu D BAP/7E y 1965 A. D. BRlTE 3,196,046
PROCESS FOR CLEANING OVENS Original Filed March 23, 1959 2 Sheets-Sheet 2 IHMERSE TO INVENTOR. ALA/V .0. 5/9/72 United States Patent 3,196,046 PRUQEEBS 1 0R CLEANING GVENS Aian I). Erite, 514"! W. .ieiferson Blvd, Los Angeles, Calif.
Original appiication Mar. 23, 1959, Ser. No. 801,355, new Patent No. 3,051,559, dated Aug. 28, 1962. Divided and this application July 20, 1962, Ser. No. 211,356
6 Claims. ((31.134-22) This application is a division of my copending application Serial No. 801,355, filed March 23, 1959, now Patent No. 3,051,559, dated August 28, 1962.
This invention relates to the art of cleaning and has particular reference to a process and article for cleaning grease and food stained surfaces such as those found in household cooking ovens.
One of the most difficult and poorly performed tasks which faces the modern housewife is that of cleaning the soiled interior surfaces of the oven. Many preparations have been devised and sold specifically for this purpose, but all those that are effective to any degree in removing the food and grease stains contain caustic or other corrosive chemicals which are difiicult and even dangerous to apply. A primary object of the present invention is to provide a novel process and article for cleaning the interior surfaces of ovens or the like, which are not subject to the above and other disadvantages of the methods and materials heretofore proposed.
Another object of the present invention is to provide a novel article for cleaning ovens and the like, which is non-corrosive, non-toxic, and non-inflammable, yet which is highly effective in use.
Other objects and advantages of this invention it is believed will be readily apparent from the following detailed description of preferred embodiments thereof when read in connection with the accompanying drawings.
Referring now to the drawings:
FIGURE 1 is a perspective view of a preferred form of the article of the present invention.
FIGURE 2 is a perspective view illustrating the article in place in an oven and ready for use.
FIGURE 3 is a vertical sectional view of the article.
FIGURE 3a is a sectional view taken substantially on the line 3a3a of FIGURE 3.
FIGURE 4 is a top plan view of a modified form of the invention.
FIGURE 5 is a bottom plan view thereof.
FIGURE 6 is a vertical sectional view illustrating the manner of use of the article of FIGURES 4 and 5.
Referring now to the drawings, a preferred form of the article of the present invention is generally indicated 10, including a generally cylindrical container 11 which may be of metal or formed of resin-impregnated cardboard having a metal bottom 12 and top 13, the top being provided with a central opening and a closure 14. Positioned within the container is a cone-shaped cup member 15 formed of resin-impregnated paper or other material suitably treated to render it resistant to cold water. The cup member 15 is open at the top and is provided with a pair of relatively small openings adjacent the bottom or apex thereof, the openings being covered with a plug or layer of a low-melting material such as paraifin wax or the like. The top of the cup member extends just short of the underside of the container top 13 and the apex of the cup member is positioned on the container bottom 12. Stiffeners or ribs 27 of cardboard or the like are positioned inside the cup member, the top edges 28 thereof extending just short of the upper edge of the cup member and the lower edges 29 of the ribs terminating above the openings 20.
A chemical mixture 30 is contained in the volume of the container between the outer surface of the cup mem- 3,l%,046 Patented July 20, 1965 her and the inner surfaces of the container side wall and bottom. The mixture 30 comprises calcium oxide in lump form and an ammonium salt such as the chloride, sulfate, nitrate, carbonate, etc., in granular or powder form. Preferably the mixture 341 comprises about 400 grams of calcium oxide and 100 grams of ammonium chloride.
As shown in the drawings, the relatively fine ammonium chloride settles to the lower portion of the container, leaving the relatively coarse particles of calcium oxide in the upper portion thereof.
In use of the article, the closure 14 is removed and hot water poured into the cup member 15 to the approximate level indicated in FIGURE 3. The container is then immediately placed in the oven 50 as indicated in FIGURE 2. The oven should be cold and therefore if of the type having a pilot light, the oven door should be left open for almost an hour prior to use of the article of this invention.
After placing the article 10 in the oven, the oven door is closed. The hot water in the cup member melts the wax plug 25, permitting the water to slowly seep into contact with the ammonium chloride and calcium oxide mixture. Since the bulk of the ammonium chloride is positioned in the lower portion of the container it is first contacted by the water, causing it to dissolve readily. The water progressively moves upwardly through the mixture, contacting the calcium oxide with the usual exothermic reaction, forming steam. Simultaneously, ammonia gas is liberated from the ammonium chloride. The steam tends to soften the upper portion of the cup member and cause it to collapse inwardly as indicated by the phanton lines of FIGURE 3.
The mixture of ammonia gas and steam thus formed rises out of the container opening into the oven and contacts the cold walls thereof, condensing the steam and depositing the ammonia thereon in the form of ammonium hydroxide which exerts its cleaning and dissolving action on the grease and other foreign matter on the oven walls. The reaction is completed in 10-15 minutes and after this period of time the oven door may be opened and the container removed. The oven wall surfaces are then easily wiped clean with a wet cloth or sponge.
A modified form of the invention is illustrated in FIG- URES 4, 5 and 6. As shown, the modified article comprises a container 61, preferably of metal, having a cylindrical side Wall 62, a bottom wall 63 and a top closure 64. The top closure is provided with a plurality of small openings 65 covered by a removable cover 66 of pressure-sensitive adhesive tape or the like. The bottom wall 63 is provided with a single central aperture 68, and a similar cover 63a. An indicator mark 69 is provided on the outer surface of the side wall 62.
Resting on the upper surface of the bottom wall 63 is a square sheet '70 of paper or like material, the diagonal dimension thereof being approximately equal to the inside diameter of the cylindrical wall 62. Overlying the sheet 70 and bottom wall 63 is a layer 72 of pa-raflin wax or other low melting material. The chemical mixture 30a, of the same composition as the mixture 30 described above, fills substantially all of the container above the paraffin layer 72.
In use of the article of FIGURES 4-6, it is placed in a pan or other suitable container and the pan filled with cold water to the indicator mark 69. The article is then removed from the pan and the water heated to a boil. The pan and its contained hot water is then placed in the cold oven, the covers 66 and 68a are removed from the container top and bottom walls and the article is placed in the pan of hot water. The hot water raises the temperature of the container 61 suificiently to melt the wax, permitting the water to seep into the container through the aperture 68, under the sheet 70 and thence into contact with the mixture 30a with the resultant formation of ammonia gas and steam in the same manner and with the same results as described above. It will be seen that the sheet 76 functions as a valve to permit only a relatively slow inflow of water, the outflow of steam and ammonia gas being controlled by the size and number of openings 65.
It is to be understood that the specific proportions of calcium oxide and ammonium salt recited above are not critical and that the proportions may be varied within rather wide limits, so long as sufiicient calcium oxide is present to react with the ammonium salt and form the ammonia and steam.
From the above description it will be understood that a novel and highly effective article and process for cleaning ovens and the like has been provided by the present invention. The article is highly elfective in use, yet eliminates the disadvantages inherent in the use of conventional cleaning compositions. It will further be understood that a subsidiary, yet important feature of the invention resides in providing the calcium oxide in lump form and the ammonium salt in finer particle size form so that the latter gravitates to the bottom of the container. This, combined with the structure whereby the water is admitted into the bottom of the container so that it first contacts the ammonium salt rather than the calcium oxide, permits most etficient dissolving of the ammonium salt and utilization of the steam produced by the slaking of the calcium oxide.
Having fully described my invention, it is to be understood that I' do not wish to be limited to the details set forth, but my invention is of the full scope of the appended claims.
I claim:
1. A method for cleaning ovens and the like comprising the steps of placing a container of a mixture of calcium oxide and an ammonium salt in an enclosed oven, adding water to said mixture to form steam and ammonia gas, condensing said steam and gas on the inner surfaces of said oven, and removing said condensate from said surfaces.
2. A method for cleaning ovens and the like compris- 4 ing the steps or" placing a container of a mixture of calcium oxide and ammonium chloride in an enclosed oven, adding water to said mixture to form steam and ammonia gas, condensing said steam and gas on the inner surfaces of said oven, and removing said condensate from said surfaces.
3. A method for cleaning ovens and the like comprising the steps of adding water to a container of a mixture of calcium oxide and an ammonium salt, immediately placing said container in an enclosed oven whereby steam and ammonia gas from the container is condensed on the inner surfaces of the oven, and removing the condensate thus formed from said surfaces.
4. A method for cleaning ovens and the like comprising the steps of adding water to a container of a mixture of calcium oxide and ammonium chloride, immediately placing said container in an enclosed oven whereby steam and ammonia gas from the container is condensed on the inner surfaces of the oven, and removing the condensate thus formed from said surfaces.
5. The method as defined in claim I, wherein said calcium oxide is in lump form and wherein said ammonium salt is of relatively fine particle size.
6. The method as defined in claim 4, wherein said calcium oxide is in lump form and said ammonium chloride is of relatively fine particle size.
References Cited by the Examiner UNITED STATES PATENTS 382,322 5/88 Parsons 252 709,846 9/02 Young 252-176 1,581,413 4/26 Yoakam '252-155 2,431,470 11/47 Fawkes 252-189 3,079,284 2/63 Boucher 134-4 OTHER REFERENCES The Family Circle, Aug. 11, 1944, vol. 25, No. 6 (section devoted to Short Cuts and Salvage; no page available).
DONALL H. SYLVESTER, Primary Examiner.
CHARLES A. WILLMUTH, MORRIS O. WOLK,
Examiners.

Claims (1)

1. A METHOD FOR CLEANING OVENS AND THE LIKE COMPRISING THE STEPS OF PLACING A CONTAINER OF A MIXTURE OF CALCIUM OXIDE AND AN AMMONIUM SALT IN AN ENCLOSED OVEN, ADDING WATER TO SAID MIXTURE TO FORM STEAM AND AMMONIA GAS, CONDENSING SAID STEAM AND GAS ON THE INNER SURFACES OF SAID OVEN, AND REMOVING SAID CONDENSATE FROM SAID SURFACES.
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3331943A (en) * 1964-11-09 1967-07-18 Gen Electric Vaporizing apparatus for cleaning domestic oven
US3419428A (en) * 1964-11-09 1968-12-31 Gen Electric Method of loosening food soil from walls of domestic oven
US3540928A (en) * 1968-06-28 1970-11-17 Du Pont Removing ammonium chlorides from tml production equipment
US3937634A (en) * 1972-10-16 1976-02-10 Brite Alan D Oven cleaning process
DE2538591A1 (en) * 1975-08-29 1977-03-03 Alan D Brite Cleaning domestic ovens - by generating steam and ammonia on adding water to calcium oxide and ammonium salt mixt.
US5075982A (en) * 1990-09-25 1991-12-31 Allied-Signal Inc. Open top defluxer with improved solvent vapor recovery

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US382322A (en) * 1888-05-08 paesons
US709846A (en) * 1901-06-03 1902-09-23 Conrad Doersch Ammonia-generator.
US1581413A (en) * 1924-04-05 1926-04-20 Raymond M Yoakam Paint and varnish removing composition
US2431470A (en) * 1943-04-30 1947-11-25 Fawkes Walter Hugh Ammonia evolving composition
US3079284A (en) * 1960-11-30 1963-02-26 Rinshed Mason Company Method for cleaning surfaces

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US382322A (en) * 1888-05-08 paesons
US709846A (en) * 1901-06-03 1902-09-23 Conrad Doersch Ammonia-generator.
US1581413A (en) * 1924-04-05 1926-04-20 Raymond M Yoakam Paint and varnish removing composition
US2431470A (en) * 1943-04-30 1947-11-25 Fawkes Walter Hugh Ammonia evolving composition
US3079284A (en) * 1960-11-30 1963-02-26 Rinshed Mason Company Method for cleaning surfaces

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3331943A (en) * 1964-11-09 1967-07-18 Gen Electric Vaporizing apparatus for cleaning domestic oven
US3419428A (en) * 1964-11-09 1968-12-31 Gen Electric Method of loosening food soil from walls of domestic oven
US3540928A (en) * 1968-06-28 1970-11-17 Du Pont Removing ammonium chlorides from tml production equipment
US3937634A (en) * 1972-10-16 1976-02-10 Brite Alan D Oven cleaning process
DE2538591A1 (en) * 1975-08-29 1977-03-03 Alan D Brite Cleaning domestic ovens - by generating steam and ammonia on adding water to calcium oxide and ammonium salt mixt.
US5075982A (en) * 1990-09-25 1991-12-31 Allied-Signal Inc. Open top defluxer with improved solvent vapor recovery

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