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US3177053A - Differentially coated galvanized strip - Google Patents

Differentially coated galvanized strip Download PDF

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Publication number
US3177053A
US3177053A US256530A US25653063A US3177053A US 3177053 A US3177053 A US 3177053A US 256530 A US256530 A US 256530A US 25653063 A US25653063 A US 25653063A US 3177053 A US3177053 A US 3177053A
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United States
Prior art keywords
strip
coating
zinc
galvanized
product
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Expired - Lifetime
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US256530A
Inventor
Lusa George
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Armco Inc
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Armco Inc
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Filing date
Publication date
Priority claimed from US862082A external-priority patent/US3112213A/en
Application filed by Armco Inc filed Critical Armco Inc
Priority to US256530A priority Critical patent/US3177053A/en
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Publication of US3177053A publication Critical patent/US3177053A/en
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Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/006—Pattern or selective deposits
    • C23C2/0062—Pattern or selective deposits without pre-treatment of the material to be coated, e.g. using masking elements such as casings, shields, fixtures or blocking elements
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/922—Static electricity metal bleed-off metallic stock
    • Y10S428/9335—Product by special process
    • Y10S428/939—Molten or fused coating
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/922—Static electricity metal bleed-off metallic stock
    • Y10S428/9335—Product by special process
    • Y10S428/941—Solid state alloying, e.g. diffusion, to disappearance of an original layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771—Transition metal-base component
    • Y10T428/12785—Group IIB metal-base component
    • Y10T428/12792—Zn-base component
    • Y10T428/12799—Next to Fe-base component [e.g., galvanized]

Definitions

  • the invention relates to galvanized, i.e., zinc coated, ferrous strip or sheet materials bearing on one side a standard or heavy-weight zinc coating, and on the other side a coating which, While derived from zinc, is very much thinner.
  • a wiper blade on one side of the strip above a standard exit roll will serve to wipe off almost all of the coating resident on that side of the strip.
  • the blade may be made of metal or any other substance of sufficient strength and capable of withstanding the heat involved.
  • one side of the galvanized product may be given an organic coating of paint, enamel or other material, while it is desirable to have the other side carry a standard or heavy galvanized coating.
  • organic coating can be made to adhere to a very thin zinc layer upon the one side of the product, it will obviously not be necessary for both sides of the product to carry heavy or standard zinc coatings.
  • sheet metal parts of an automobile body such as the so-called rocker panels, where the outer surface will be covered and protected with the ordinary automobile finish, but where the inner surface is exposed to air, moisture, and other corrosive influences but cannot readily be painted or otherwise protected.
  • the sheet metal of this invention is useful for such parts.
  • the external finish of the body will adhere very well to the thinly coated side of the product of the invention, which is located outwardly, while a full single coating on the inner side will protect that side from corrosive influences.
  • the galvanized sheets are preferably formed from strip stock which has been galvanized in accordance with the teachings of the Sendzimir US. Patent No. 2,197,622.
  • cold rolled strip is first passed through an oxidizing furnace in which oils, greases, carbonaceous smudges, and other non-reducible materials are removed from their surfaces, and a thin, controlled coating of oxide is formed thereon.
  • the strip is next led into a reducing furnace wherein the thin coating of oxide is completely reduced.
  • the temperature in the reducing furnace may, if desired, be sufiicient to anneal the stock.
  • the strip From the reducing furnace, the strip passes through a cooling hood in which it is still protected by reducing gases, and thence is carried beneath the surface of a pot of molten galvanizing metal the entrance end of which is flux-free.
  • the strip has a very short path of travel through the galvanizing pot.
  • Zinc metal in the pot contains a small proportion of aluminum. All of these conditions combine to produce a galvanized product in which the interface alloy is extremely thin. It is believed to be due largely to this factor that the galvanized product is characterized by extraordinary ductility and adherence of the coating, so that the coating can withstand substantially any bending, forming, drawing, or other working operations which can be performed on the base stock.
  • a 1621i treatment which would result in an increase in the thickness of the interface alloy would, to a considerable extent, impair the ductility and adherence to the galvanized coating.
  • the new product therefore, is a sheet or strip which has a standard or heavy zinc coating upon one side, the characteristics of which have not been affected, and upon the other side a very thin layer of Zinc alloyed with the ferrous base metal. Such a product has never before been produced.
  • the pretreatment of the strip and the coating are carried on as is usual in the practice of the Sendzimir patent to which reference has been made.
  • the exit rolls may be grooved in such a way as to apply coatings of diiferent thicknesses to opposite sides of the strip, or an air blast may be used on the meniscus on one side, as mentioned above.
  • These expedients are not necessary.
  • the use of a scraper blade is the preferred procedure, the blade being so located as to deflect the strip and insure contact all across its width. A blade properly used will be effective in removing the major portion of the zinc galvanizing metal on the side of the strip contacted by it.
  • the zinc coating on the opposite side of the strip does not constitute a limitation on the invention.
  • the heavy coating can be as heavy as that normally produced commercially, which could be as much as one ounce or heavier, per square foot.
  • the other, or light side, of the strip can have coatings as light as .1 ounce, or less, er square foot.
  • the heat applied to the wiped side of the strip is conveniently produced by one or more gas ribbon burners or some other suitable heat source, such as an electrical heating means. Assuming that the strip leaves the coating pot in a vertical direction, the burners will be placed in a horizontal position extending across the strip. The exact position of the burners with respect to the exit rolls is not critical; and it has been found that the burners may vary from about one foot to ten feet from the exit rolls. The burners will be located at such a distance from the surface of the strip as to produce the proper heat at that surface. In general, the burners will lie from 2 inches to 8 inches away from the strip. The heat may vary from 500 F. to about 1400 F. at the surface of the strip.
  • the heating should be done in such a way that, While the adjacent and thinly coated surface of the strip is heated to the desired temperature, the rate of heat dissipation from the strip as it cools in air will prevent the transmission of any great degree of heat to the opposite side of the strip.
  • the temperature may be varied in accordance with the thickness of the zinc coating remaining on the wiped side of the strip, and the amount of heat required to cause it to alloy with the base metal.
  • the pot temperature may be raised as high as about 870 F. without essentially affecting the characteristics of the standard or heavy zinc coating upon the one side of the sheet.
  • a galvanized sheet material bearing upon one of its sides a layer of coating metal consisting principally of zinc, and characterized by a thin interface alloy layer lying between the zinc and the ferrous base, and characterized on the other side by a thin layer of zinc substantially Wholly alloyed with the ferrous base.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Coating With Molten Metal (AREA)

Description

United States Patent 0 gen 3,177,953 DIFFERENTIALLY COATED GALVANIZED STRIP George Lusa, Dayton, Ohio, assignor to Armco Steei Corporation, Middic-towu, (iizio, a corporation of Ghio No Drawing. Griginal application Dec. 23, 1959, Ser. No. 862,082, now Patent No. 3,112,213, dated Nov. 26, 1963. Divided and this application Feb. 6, 1963, Ser. No. 256,530
2 Claims. (Cl. 29196.5)
This is a division of the copending application in the name of the same inventor, Serial No. 862,082, filed December 28, 1959, and entitled Differentially Coated Galvanized Strip, now Patent No. 3,112,213, issued November 26, 1963.
The invention relates to galvanized, i.e., zinc coated, ferrous strip or sheet materials bearing on one side a standard or heavy-weight zinc coating, and on the other side a coating which, While derived from zinc, is very much thinner.
It has hitherto been realized that there are various uses for a galvanized product having a heavy or standard coating upon one side and a lighter coating upon the other. For example, when galvanized sheets are used for roofing or siding on buildings, theheavy weights of coating are needed on the exterior to secure a long life and resist corrosion when exposed to the weather; but the inside surface of such sheets, not being exposed to the elements, do notrequire 'such' a heavy weight of coating.
Various -suggestions 'have been made in the past looking toward the provision of differentially coated galvan ized sheets or strip. In thecoating operation, the ferrous material is passed through a' bath of molten zinc and emerges; therefrom between exit rolls which are grooved to control the extent and uniformity as -well as the thickness of the coating. It has been found that the exit roll on one side of the strip may begrooved in such a way as to leave a lesser weight of coating on the strip surface at that side. Again, it has been disclosed in the copending application of Whitley, Kemplin and Jones, Serial No. 733,708, filed May 7, 1958, and entitled Exit Machine for Coating Apparatus and Method of Controlling Coating Thickness, now Patent No. 2,992,941, issued July 18, 1961, that the use of an air blast on the meniscus at the exit rolls can decrease the amount of coating metal which is applied or left on the surface of the strip. The meniscus, of course, refers to that quantity of zinc which collects above an exit roll and between it and the surface of the strip as it is leaving the exit roll.
It has also been found that the use of a wiper blade on one side of the strip above a standard exit roll will serve to wipe off almost all of the coating resident on that side of the strip. The blade may be made of metal or any other substance of sufficient strength and capable of withstanding the heat involved.
One dimculty with the formation of differentially coated galvanized strip lies in the fact that the wiped or otherwise more thinly coated side of the material is likely to have a streakedand unsightly appearance. While this may make no difierence in certain uses, where the thinly coated side of the product is exposed to view, it will usually be desired to have it covered with paint or enamel. Zinc coatings as usually produced are not very receptive to coatings of paint and enamel unless they are given pretreatments. These pretreatments are generally expensive and involve the installation of fairly bulky apparatus.
In still other uses, one side of the galvanized product may be given an organic coating of paint, enamel or other material, while it is desirable to have the other side carry a standard or heavy galvanized coating. If the Patented Apr. 6, 1965 organic coating can be made to adhere to a very thin zinc layer upon the one side of the product, it will obviously not be necessary for both sides of the product to carry heavy or standard zinc coatings. As an example of one such use, there are certain sheet metal parts of an automobile body, such as the so-called rocker panels, where the outer surface will be covered and protected with the ordinary automobile finish, but where the inner surface is exposed to air, moisture, and other corrosive influences but cannot readily be painted or otherwise protected. The sheet metal of this invention is useful for such parts. The external finish of the body will adhere very well to the thinly coated side of the product of the invention, which is located outwardly, while a full single coating on the inner side will protect that side from corrosive influences.
Another problem is involved in the use of galvanized sheets on the under sides of automobiles. It is usual to spot Weld adjacent panels together; but the standard zinc coatings cause a considerable amount of build-up on the copper welding electrode tips. This impedes the welding operation and makes for a frequent cessation of the work so thatthe electrode tips may be cleaned. l The principal object of the invention is the provision of new galvanized product and a method of making it, which avoids all of the difiiculties mentioned above. This object, and others which will be set forth hereinafter or will be apparent to one skilled in the art upon reading these specifications, are accomplished by that procedure and in that product of which certain exem plary embodiments will now be described.
The copending application of Schnedler, Serial No. 735,015, filed August 4, 1958, now Patent No. 2,986,808, issued June 6, 1961, and entitled Steel Body Having Alloyed Zinc Coating and Method of Producing Such Coating, teaches that a zinc coated sheet, which has been subjected to aheat treatment so as to cause an increase in the thickness of the interface alloy, will be usefully increased as to its acceptance of paints and enamels while still having a surprising amount of corrosion resistance. However, it is not generally advantageous to increase the extent of the interface alloy on both sides of the sheet for reasons which will now be set forth.
The galvanized sheets are preferably formed from strip stock which has been galvanized in accordance with the teachings of the Sendzimir US. Patent No. 2,197,622. In' the practice taught by this patent, cold rolled strip is first passed through an oxidizing furnace in which oils, greases, carbonaceous smudges, and other non-reducible materials are removed from their surfaces, and a thin, controlled coating of oxide is formed thereon. The strip is next led into a reducing furnace wherein the thin coating of oxide is completely reduced. The temperature in the reducing furnace may, if desired, be sufiicient to anneal the stock.
From the reducing furnace, the strip passes through a cooling hood in which it is still protected by reducing gases, and thence is carried beneath the surface of a pot of molten galvanizing metal the entrance end of which is flux-free. The strip has a very short path of travel through the galvanizing pot. Zinc metal in the pot contains a small proportion of aluminum. All of these conditions combine to produce a galvanized product in which the interface alloy is extremely thin. It is believed to be due largely to this factor that the galvanized product is characterized by extraordinary ductility and adherence of the coating, so that the coating can withstand substantially any bending, forming, drawing, or other working operations which can be performed on the base stock. A 1621i treatment which would result in an increase in the thickness of the interface alloy would, to a considerable extent, impair the ductility and adherence to the galvanized coating.
It has been found, however, in HCCOILHDCC with the present invention, that if one side of the galvanized strip is wiper shortly after it emerges from the exit rolls and before the zinc coating thereon has hardened, so as to remove the greater part of the coating thereon, it then becomes possible to apply a small amount of heat to the thinly coated side of the strip so as to cause the zinc coating on that side to alloy rapidly with the base material, and that if the heat is properly controlled, the interface alloy on the opposite side of the strip will not be increased in thickness, and that the standard or heavy zinc coating thereon will not be affected as to its adherence or ductility. The new product, therefore, is a sheet or strip which has a standard or heavy zinc coating upon one side, the characteristics of which have not been affected, and upon the other side a very thin layer of Zinc alloyed with the ferrous base metal. Such a product has never before been produced.
In the practice of the invention the pretreatment of the strip and the coating are carried on as is usual in the practice of the Sendzimir patent to which reference has been made. If desired, the exit rolls may be grooved in such a way as to apply coatings of diiferent thicknesses to opposite sides of the strip, or an air blast may be used on the meniscus on one side, as mentioned above. These expedients, however, are not necessary. The use of a scraper blade is the preferred procedure, the blade being so located as to deflect the strip and insure contact all across its width. A blade properly used will be effective in removing the major portion of the zinc galvanizing metal on the side of the strip contacted by it.
The zinc coating on the opposite side of the strip does not constitute a limitation on the invention. Depending upon the usage to which the product is to be put, the heavy coating can be as heavy as that normally produced commercially, which could be as much as one ounce or heavier, per square foot. The other, or light side, of the strip can have coatings as light as .1 ounce, or less, er square foot.
The heat applied to the wiped side of the strip is conveniently produced by one or more gas ribbon burners or some other suitable heat source, such as an electrical heating means. Assuming that the strip leaves the coating pot in a vertical direction, the burners will be placed in a horizontal position extending across the strip. The exact position of the burners with respect to the exit rolls is not critical; and it has been found that the burners may vary from about one foot to ten feet from the exit rolls. The burners will be located at such a distance from the surface of the strip as to produce the proper heat at that surface. In general, the burners will lie from 2 inches to 8 inches away from the strip. The heat may vary from 500 F. to about 1400 F. at the surface of the strip. The heating should be done in such a way that, While the adjacent and thinly coated surface of the strip is heated to the desired temperature, the rate of heat dissipation from the strip as it cools in air will prevent the transmission of any great degree of heat to the opposite side of the strip. The temperature may be varied in accordance with the thickness of the zinc coating remaining on the wiped side of the strip, and the amount of heat required to cause it to alloy with the base metal.
In the practice of the invention, it may be found advisable to raise the temperature of the molten metal in the coating pot. The pot temperature may be raised as high as about 870 F. without essentially affecting the characteristics of the standard or heavy zinc coating upon the one side of the sheet.
Modifications may be made in the invention Without departing from the spirit of it. The invention having been described in certain exemplary embodiments, what is claimed as new and desired to be secured by Letters Patent is:
1. A galvanized sheet material bearing upon one of its sides a layer of coating metal consisting principally of zinc, and characterized by a thin interface alloy layer lying between the zinc and the ferrous base, and characterized on the other side by a thin layer of zinc substantially Wholly alloyed with the ferrous base.
2. The structure claimed in claim 1 wherein the zinc contains a minor amount of aluminum.
References Cited by the Examiner UNITED STATES PATENTS 2,034,348 3/36 Lytle 117461.2 2,126,244 8/38 Cook 29-196.5 2,398,034 4/46 Oganowski 117-114 2,719,820 10/55 Allen 20437 2,770,872 11/56 Kadell 29-1964 2,914,419 11/59 Oganowski 117-114 2,986,808 6/61 Schnedler 29196.5 2,994,126 8/61 Kennedy 29196.5
DAVID L. RECK, Primary Examiner.
HYLAND BIZOT, Examiner.

Claims (1)

1. A GALVANIZED SHEET MATERIAL BEARING UPON ONE OF ITS SIDES A LAYER OF COATING METAL CONSISTING PRINCIPALLY OF ZINC, AND CHARACTERIZED BY A THIN SURFACE ALLOY LAYER LYING BETWEEN THE ZINC AND THE FERROUS BASE, AND CHARACTERIZED ON THE OTHER SIDE BY A THIN LAYER OF ZINC SUBSTANTIALLY WHOLLY ALLOYED WITH THE FERROUS BASE.
US256530A 1959-12-28 1963-02-06 Differentially coated galvanized strip Expired - Lifetime US3177053A (en)

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US256530A US3177053A (en) 1959-12-28 1963-02-06 Differentially coated galvanized strip

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3383189A (en) * 1964-04-16 1968-05-14 Sendzimir Inc T Prevention of white rust on galvanized sheets
US3431091A (en) * 1965-03-18 1969-03-04 Air Liquide Wires for arc welding having a low carbon core and a zinc coating
US4120997A (en) * 1976-05-11 1978-10-17 Inland Steel Company Process for producing one-side galvanized sheet material
US4243730A (en) * 1976-05-19 1981-01-06 Nippon Steel Corporation Steel sheet having a zinc coating on one side
WO2013189601A1 (en) * 2012-06-20 2013-12-27 Tata Steel Nederland Technology B.V. Single sided coated metal strip

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2034348A (en) * 1930-09-03 1936-03-17 Lytle Clark Kenneth Nonspangled galvanized sheet
US2126244A (en) * 1935-12-13 1938-08-09 Wheeling Steel Corp Metal coated product
US2398034A (en) * 1943-05-11 1946-04-09 American Rolling Mill Co Treatment means and method for hot coated strip
US2719820A (en) * 1951-01-26 1955-10-04 United States Steel Corp Method for coating steel strip
US2770872A (en) * 1952-04-10 1956-11-20 Nat Steel Corp Marked electrolytic tinplate and method for producing same
US2914419A (en) * 1953-08-03 1959-11-24 Armco Steel Corp Method and apparatus for continuously coating a metal strand-like article with molten metal
US2986808A (en) * 1958-08-04 1961-06-06 Armco Steel Corp Steel body having alloyed zinc coating and method of producing such coating
US2994126A (en) * 1957-10-29 1961-08-01 Porter Co Inc H K Ferrous metal body with alloyed zinc coating

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2034348A (en) * 1930-09-03 1936-03-17 Lytle Clark Kenneth Nonspangled galvanized sheet
US2126244A (en) * 1935-12-13 1938-08-09 Wheeling Steel Corp Metal coated product
US2398034A (en) * 1943-05-11 1946-04-09 American Rolling Mill Co Treatment means and method for hot coated strip
US2719820A (en) * 1951-01-26 1955-10-04 United States Steel Corp Method for coating steel strip
US2770872A (en) * 1952-04-10 1956-11-20 Nat Steel Corp Marked electrolytic tinplate and method for producing same
US2914419A (en) * 1953-08-03 1959-11-24 Armco Steel Corp Method and apparatus for continuously coating a metal strand-like article with molten metal
US2994126A (en) * 1957-10-29 1961-08-01 Porter Co Inc H K Ferrous metal body with alloyed zinc coating
US2986808A (en) * 1958-08-04 1961-06-06 Armco Steel Corp Steel body having alloyed zinc coating and method of producing such coating

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3383189A (en) * 1964-04-16 1968-05-14 Sendzimir Inc T Prevention of white rust on galvanized sheets
US3431091A (en) * 1965-03-18 1969-03-04 Air Liquide Wires for arc welding having a low carbon core and a zinc coating
US4120997A (en) * 1976-05-11 1978-10-17 Inland Steel Company Process for producing one-side galvanized sheet material
US4243730A (en) * 1976-05-19 1981-01-06 Nippon Steel Corporation Steel sheet having a zinc coating on one side
WO2013189601A1 (en) * 2012-06-20 2013-12-27 Tata Steel Nederland Technology B.V. Single sided coated metal strip

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