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US3138480A - Insulating wall board sizing - Google Patents

Insulating wall board sizing Download PDF

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Publication number
US3138480A
US3138480A US141016A US14101661A US3138480A US 3138480 A US3138480 A US 3138480A US 141016 A US141016 A US 141016A US 14101661 A US14101661 A US 14101661A US 3138480 A US3138480 A US 3138480A
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US
United States
Prior art keywords
board
water
gallons
polyvinyl acetate
solids
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US141016A
Inventor
Christian F Girard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
International Paper Canada Inc
Original Assignee
International Paper Canada Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by International Paper Canada Inc filed Critical International Paper Canada Inc
Priority to US141016A priority Critical patent/US3138480A/en
Application granted granted Critical
Publication of US3138480A publication Critical patent/US3138480A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21JFIBREBOARD; MANUFACTURE OF ARTICLES FROM CELLULOSIC FIBROUS SUSPENSIONS OR FROM PAPIER-MACHE
    • D21J1/00Fibreboard
    • D21J1/16Special fibreboard
    • D21J1/20Insulating board
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/21Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24Polysaccharides
    • D21H17/25Cellulose
    • D21H17/26Ethers thereof
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/34Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/36Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/67Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/68Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/27Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
    • Y10T428/273Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.] of coating
    • Y10T428/277Cellulosic substrate
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31855Of addition polymer from unsaturated monomers
    • Y10T428/3188Next to cellulosic
    • Y10T428/31895Paper or wood
    • Y10T428/31906Ester, halide or nitrile of addition polymer

Definitions

  • This invention relates to fiber board, More particularly, it relates to improving the surfaces of insulating wall board made from Wood fibers.
  • One manner of forming the fiber board involves the use of an Oliver filter-type forming machine, though a Fourdrinier machine can also be used.
  • the pulp is reduced to about 1% consistency and is flowed through a head box and into the Oliver vat, where the sheet is formed on the filter to the required thickness.
  • This wet mat at about 80% moisture content, is then transferred to a series of suction rolls whereby the moisture content is progressively reduced to about 60%.
  • the mat then goes into steam-heated driers wherein it becomes fiber board having a moisture content of about 2 to 4%, Gas-heated kilns could, of course, be used in place of the steam-heated driers.
  • the board is then cut up into the required dimensions for processing into tiles, e.g., about 52 by 52".
  • the surfaces of the fiber board thus produced are fairly smooth, it has been found that they can be made smoother for purposes of painting, gluing, etc., by sanding or the use of a hot-rolling preceded by a waterspraying of the board surfaces. Both methods are used to achieve an evening out of the small hills and valleys, e.g., wire markings, caused by stock formation during the manufacturing process.
  • sanding becomes quite costly and does not produce results sufficiently satisfactory in terms of smoothness.
  • spraying the surface fibers with water prior to hot-rolling is not altogether suitable, since it fails to achieve adequate binding of the surface fibers or sealing of the surfaces.
  • fiber board 3,138,480 Patented June 23, 1964 is treated on its surfaces with a size, for example, on a reverse coater after it is cut into tiles and before it is hotrolled.
  • the product of this process has substantially unscorched, non-tacky, and unblistered surfaces which are semi-glazed, colorless, and well-sealed for purposes of painting, gluing, etc.
  • the usual water-base coatings can be applied economically to produce attractive wall board products in the form of panels, planks, and decorative tiles.
  • Such coatings can include water-based paints of the polyvinyl acetate emulsion or latex type applied with a flow coater or other conventional means, as well as waterbased paints of butadiene styrene, acrylic, polyvinylidene chloride latex types, alkyd emulsions, and protein paints of the casein and soya types.
  • water-based paints of the polyvinyl acetate emulsion or latex type applied with a flow coater or other conventional means as well as waterbased paints of butadiene styrene, acrylic, polyvinylidene chloride latex types, alkyd emulsions, and protein paints of the casein and soya types.
  • oil-based flat colored paints, as well as waterbased paints can be employed on the fiber board of the present invention, without resort to sealers, by use of brushes, roller coaters, or spray guns and there result improved hold-out, hiding, flow, and, levelling of the pigmented
  • a size developed in accordance with the present invention is, for example, one in which water, carboxymethylcellulose, colloidal silica, and polyvinyl acetate are mixed and applied at from about 8 to 10 grams per square foot of fiber board per side or surface prior to a hot-rolling thereof at about 700 F.
  • 60.24 U.S. gallons of hot water, 5 lbs. of medium viscosity sodium carboxymethylcellulose, 50 lbs, of Nalcoag 1050 (a commercially available product containing 50% colloidal silica solids), and 12.04 U.S. gallons of Latex D-Sl (a commercially available 55% polyvinyl acetate emulsion) are employed.
  • a sizing composition for insulating board consisting essentially of water, carboxymethylcellulose, colloidal silica, and polyvinyl acetate in proportions of about 60.24 U.S. gallons of Water, about 5 pounds of medium v iscgsity carboxymethylcellulose, about 50 pounds of coll dal silica containing about 50% solids, and about 12.04 U.S. gallons of polyvinyl acetate emulsion containing about 55 solids.
  • Insulating board having disposed on at least one of its surfaces a dried sizing composition consisting essentially of water, carboxymethylcellulose, colloidal silica, and polyvinylacetate in proportions of about 60.24 U.S. gallons of water, about 5 pounds of medium viscosity carboxymethylcellulose, about 50 pounds of colloidal silica containing about 50% solids, and about 12.04 U.S. gallons of polyvinyl acetate emulsion containing about 55% solids.
  • Insulating board having disposed on at least one of its surfaces a hot-rolled sizing composition consisting essentially of water, carboxymethylcellulose, colloidal silica, and polyvinyl acetate in proportions of about 60.24 US. gallons of Water, about 5 pounds of medium viscosity carboxymethylcellulose, about 50 pounds of colloidal silica containing about 50% solids, and about 12.04 US. gallons of polyvinyl acetate emulsion containing about 55% solids.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Description

United States Patent 3,138,480 INSULATING WALL BOARD SIZING Christian F. Girard, Ottawa, Ontario, Canada, assignor to Canadian International Paper Company, Montreal, Quebec, Canada, a corporation of Canada No Drawing. Filed Sept. 27, 1961, Ser. No. 141,016 9 Claims. (Cl. 117-65.2)
This invention relates to fiber board, More particularly, it relates to improving the surfaces of insulating wall board made from Wood fibers.
It is well known to make wall board from wood fibers ranging in density from as low at 12 lbs. per cubic foot to as high as 24 lbs. per cubic foot. In some instances, most of the wood used consists of poplar, some of which is converted to the fibrous form by grinding on conventional stones and some of which is converted by chipping and steaming, followed by disc refining. Some slush pulp in the form of rejects from newsprint mills can be mixed in with the virgin furnish, as can some of the dust which is returned from the board finishing operation. These various pulps are then mixed in the ratio required for the type of board being produced, are screened, and have a wax emulsion and alum added thereto for water resistance. When needed, a cooked flour to increase the fiexural strength can also be added as described in co-pending application Serial No. 41,249, filed July 7, 1960, now abandoned.
One manner of forming the fiber board involves the use of an Oliver filter-type forming machine, though a Fourdrinier machine can also be used. The pulp is reduced to about 1% consistency and is flowed through a head box and into the Oliver vat, where the sheet is formed on the filter to the required thickness. This wet mat, at about 80% moisture content, is then transferred to a series of suction rolls whereby the moisture content is progressively reduced to about 60%. The mat then goes into steam-heated driers wherein it becomes fiber board having a moisture content of about 2 to 4%, Gas-heated kilns could, of course, be used in place of the steam-heated driers. The board is then cut up into the required dimensions for processing into tiles, e.g., about 52 by 52".
Although the surfaces of the fiber board thus produced are fairly smooth, it has been found that they can be made smoother for purposes of painting, gluing, etc., by sanding or the use of a hot-rolling preceded by a waterspraying of the board surfaces. Both methods are used to achieve an evening out of the small hills and valleys, e.g., wire markings, caused by stock formation during the manufacturing process. However, it has been found that sanding becomes quite costly and does not produce results sufficiently satisfactory in terms of smoothness. It has also been found that spraying the surface fibers with water prior to hot-rolling is not altogether suitable, since it fails to achieve adequate binding of the surface fibers or sealing of the surfaces.
It is an object of the present invention, therefore, to achieve a smooth finish on the surface of fiber board useful for insulating wall boards or the like, so as to improve its appearance, to prepare more perfectly its front surface for painting, to prepare more perfectly its back surface for gluing, and, more generally, to give the entire board heightened dust-free properties.
It is a further object of the present invention so to treat the front and back surfaces of fiber board as to achieve the desired results without appreciable scorching of the surfaces when they are subjected to hot roll temperatures of up to about 750 F., without sticking of the surfaces to the heated rolls at operational speeds of about 100 feet per minute or to each other when the fiber board is cut into tiles and stacked.
In accordance with the present invention, fiber board 3,138,480 Patented June 23, 1964 is treated on its surfaces with a size, for example, on a reverse coater after it is cut into tiles and before it is hotrolled. The product of this process has substantially unscorched, non-tacky, and unblistered surfaces which are semi-glazed, colorless, and well-sealed for purposes of painting, gluing, etc. The usual water-base coatings can be applied economically to produce attractive wall board products in the form of panels, planks, and decorative tiles. Such coatings can include water-based paints of the polyvinyl acetate emulsion or latex type applied with a flow coater or other conventional means, as well as waterbased paints of butadiene styrene, acrylic, polyvinylidene chloride latex types, alkyd emulsions, and protein paints of the casein and soya types. In addition, commercially available oil-based flat colored paints, as well as waterbased paints, can be employed on the fiber board of the present invention, without resort to sealers, by use of brushes, roller coaters, or spray guns and there result improved hold-out, hiding, flow, and, levelling of the pigmented paints.
A size developed in accordance with the present invention is, for example, one in which water, carboxymethylcellulose, colloidal silica, and polyvinyl acetate are mixed and applied at from about 8 to 10 grams per square foot of fiber board per side or surface prior to a hot-rolling thereof at about 700 F. In a preferred formula, 60.24 U.S. gallons of hot water, 5 lbs. of medium viscosity sodium carboxymethylcellulose, 50 lbs, of Nalcoag 1050 (a commercially available product containing 50% colloidal silica solids), and 12.04 U.S. gallons of Latex D-Sl (a commercially available 55% polyvinyl acetate emulsion) are employed.
What is claimed is:
1. In the process of manufacturing insulating board, a first step of sizing the surfaces of the fiber board with a composition consisting essentially of water, carboxymethylcellulose, colloidal silica, and polyvinyl acetate and a second step of hot-rolling the surfaces in which the composition is proportioned to about 60.24 U.S. gallons of water, about 5 pounds of medium viscosity carboxymethylcellulose, about 50 pounds of colloidal silica containing about 50% solids, and about 12.04 U.S. gallons of polyvinyl acetate emulsion containing about 55% solids.
2. The process of claim 1 in which the hot-rolling step is conducted at a temperature of up to about 750 F.
3. The process of claim 1 in which the hot-rolling step is conducted at a speed of up to feet of board per minute.
4. The process of claim 1 in which the composition is applied at a rate of about 8 to 10 grams per square foot of the insulating board.
5. A sizing composition for insulating board, the composition consisting essentially of water, carboxymethylcellulose, colloidal silica, and polyvinyl acetate in proportions of about 60.24 U.S. gallons of Water, about 5 pounds of medium v iscgsity carboxymethylcellulose, about 50 pounds of coll dal silica containing about 50% solids, and about 12.04 U.S. gallons of polyvinyl acetate emulsion containing about 55 solids.
6. Insulating board having disposed on at least one of its surfaces a dried sizing composition consisting essentially of water, carboxymethylcellulose, colloidal silica, and polyvinylacetate in proportions of about 60.24 U.S. gallons of water, about 5 pounds of medium viscosity carboxymethylcellulose, about 50 pounds of colloidal silica containing about 50% solids, and about 12.04 U.S. gallons of polyvinyl acetate emulsion containing about 55% solids.
7. The product of claim 6 in which the composition is disposed in a sizing of about 8 to 10 grams per square foot of the product.
8. Insulating board having disposed on at least one of its surfaces a hot-rolled sizing composition consisting essentially of water, carboxymethylcellulose, colloidal silica, and polyvinyl acetate in proportions of about 60.24 US. gallons of Water, about 5 pounds of medium viscosity carboxymethylcellulose, about 50 pounds of colloidal silica containing about 50% solids, and about 12.04 US. gallons of polyvinyl acetate emulsion containing about 55% solids.
9. The product of claim 8 in which the composition is disposed in a sizing of about 8 to 10 grams per square foot of the product.
References Cited in the file of this patent UNITED STATES PATENTS Deney Sept. 26, 1950 Cowgill May 29, 1951 Iler May 6, 1958 Emblem et al Aug. 28, 1962

Claims (1)

1. IN THE PROCESS OF MANUFCTURING INSULATING BOARD, A FIRST STEP OF SIZING THE SURFACES OF THE FIBER BOARD WITH A COMPOSITION CONSISTING ESSENTIALLY OF WATER, CARBOXYMETHYLCELLULOSE, COLLOIDAL SILICA, AND POLYVINYL ACETATE AND A SECOND STEP OF HOT-ROLLING THE SURFACES IN WHICH THE COMPOSITION IS PROPORTIONED TO ABOUT 60.24 U.S. GALLONS OF WATER, ABOUT 5 POUNDS OF MEDIUM VISCOSITY CARBOXYMETHYLCELLULOSE, ABOUT 50 POUNDS OF COLLOIDAL SILICA CONTAINING ABOUT 50% SOLIDS, AND ABOUT 12.04 U.S. GALLONS OF POLYVINYL ACETATE EMULSION CONTAINING ABOUT 55% SOLIDS.
US141016A 1961-09-27 1961-09-27 Insulating wall board sizing Expired - Lifetime US3138480A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2524008A (en) * 1946-05-03 1950-09-26 Pierce & Stevens Inc Adhesive composition
US2554663A (en) * 1949-12-15 1951-05-29 Us Rubber Co Method of glossing paper
US2833661A (en) * 1952-11-28 1958-05-06 Du Pont Composition comprising water soluble organic polymer and colloidal silica and process of coating therewith
US3051669A (en) * 1958-11-05 1962-08-28 Rolls Royce Aqueous coating compositions for production of shell moulds and process for preparing same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2524008A (en) * 1946-05-03 1950-09-26 Pierce & Stevens Inc Adhesive composition
US2554663A (en) * 1949-12-15 1951-05-29 Us Rubber Co Method of glossing paper
US2833661A (en) * 1952-11-28 1958-05-06 Du Pont Composition comprising water soluble organic polymer and colloidal silica and process of coating therewith
US3051669A (en) * 1958-11-05 1962-08-28 Rolls Royce Aqueous coating compositions for production of shell moulds and process for preparing same

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