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US3007781A - Chemical cleaning of oil heating systems - Google Patents

Chemical cleaning of oil heating systems Download PDF

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Publication number
US3007781A
US3007781A US19512A US1951260A US3007781A US 3007781 A US3007781 A US 3007781A US 19512 A US19512 A US 19512A US 1951260 A US1951260 A US 1951260A US 3007781 A US3007781 A US 3007781A
Authority
US
United States
Prior art keywords
volume
cleaning
oil
butyl alcohol
furnaces
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US19512A
Other languages
English (en)
Inventor
Robert A Billmeier
John F Mchale
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Socony Mobil Oil Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE609353D priority Critical patent/BE609353A/xx
Application filed by Socony Mobil Oil Co Inc filed Critical Socony Mobil Oil Co Inc
Priority to US19512A priority patent/US3007781A/en
Priority to FR876258A priority patent/FR1303921A/fr
Application granted granted Critical
Publication of US3007781A publication Critical patent/US3007781A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/32Organic compounds containing nitrogen
    • C11D7/3281Heterocyclic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/24Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/188Carboxylic acids; metal salts thereof
    • C10L1/1886Carboxylic acids; metal salts thereof naphthenic acid
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/232Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring

Definitions

  • furnaces which operate automatically on distillate petroleum oil to maintain a pre-set room temperature and/or supply domestic hot water.
  • the furnaces and burning equipment become coated with soot and carbonaceous deposits of various kinds during operation which results in the impairment of the heating efficiency.
  • the deposits may even build up to such a level, if not attended to, so as to cause a breakdown of the equipment and hence a periodic cleaning of the burner and various related parts of the furnace is recommended.
  • the customary procedure followed involves the disassembly of the burner mechanism and furnace or boiler parts to expose the carboned and sooted parts to mechanical cleaning.
  • the deposits are scraped, rubbed and abraded from the surfaces and the furnace and burner parts are reassembled.
  • home burners generally this is done annually and this single cleaning is intended to last for the entire heating season.
  • Service calls have been too frequent and hence an improved cleaning technique has been sought.
  • the object of this invention is to provide a method and product for cleaning oil heating furnaces which overcomes the objections of prior cleaning techniques.
  • a further object of this invention is to provide a method and product for cleaning oil burning furnaces that is faster, more economical and more efficient than prior cleaning procedures.
  • a further object of this invention is to provide a chemical cleaning composition for oil heating furnaces that permits cleaning of burner parts and furnace parts without disassembly.
  • a further object of this invention is to provide a cleaning solution that will dissolve deposits from burner parts and remove soot from furnace surfaces in oil heating furnaces during short cleaning periods without requiring disassembly of the burner or furnace.
  • the first ingredient of our formulation comprises a highly aromatic distillate oil containing about 75100% aromatics and boiling within the range of 300700 F.
  • aromatic oil of this invention such as fractions from recycle bottoms from catalytic cracking, bottoms from catalytic reforming, aromatic-rich bottoms from the production of ethylene and propylene at high temperature, Edeleanu extracts, aromatic coal tar fractions, aromatic fractions from the hydrogenation of coal or the hydrogenation of coker gas oil.
  • the second compound of our formulation is also critical, being the lactate salt of 2 heptadecyl imidazoline.
  • This salt appears to provide unusual cleaning ability in this environment.
  • the salt appears to combine with the highly aromatic oil, butyl alcohol and metal naphthenate to provide unusual and rapid removal of carbonaceous burner deposits, soot and other furnace deposits. Without the butyl alcohol and metal naphthenate or without the specified oil the cleaning results, if any, are far less spectacular. There appears to be a synergistic action of these compounds whereby the cleaning of the furnace parts is effected to a high degree both of deposits of a firm nature as well as soot and other clinging deposits.
  • the imidazoline salt structure is as follows:
  • butyl alcohol a small portion of a butyl alcohol must be mixed in this formulation and that other alcohols will not operate satisfactorily. Any butyl alcohol functions satisfactorily, normal, iso, secondary or tertiary butyl alcohols being equally effective. Broadly the alcohol should be about 520% by volume of the formulation, the preferred range being about -15 by volume.
  • the final material in this formulation is either a lead, manganese or copper naphthenate. These compounds work effectively with the other ingredients in the removal of carbonaceous deposits and the removal of soot from the furnace surfaces, particularly the heat exchanger surfaces.
  • the liquid formulation is compounded from the ingredients disclosed above in the prescribed proportions.
  • a measured quantity of the cleaning composition is fed into the burner in place of the fuel oil.
  • from one to two pints of the composition can be introduced from a suitable canister directly to the suction side of the fuel pump or, if the system is equipped with a filter, directly into the filter housing.
  • the formulation is passed through the burner and burns in the furnace without difficulty.
  • About l-2 pints of the composition is generally adequate to clean the burner and remove the soot and deposits from the average home heating system.
  • a somewhat larger charge may be used in the larger heating systems used in factories and large buildings.
  • Boiler fluessoot almost completely removedth is was also indicated by a decrease in flue gas temperature from 720 F. to 600 F.
  • a liquid composition for use in removing deposits from oil burning furnaces and the burners of said furnaces comprising:
  • a liquid composition for use in removing deposits from oil burning furnaces and the burners of said furnaces comprising:
  • a liquid composition for use in removing deposits from oil burning furnaces and the burners of said furnaces comprising:
  • a liquid composition for use in removing deposits from oil burning furnaces and the burners of said furnaces comprising:
  • a liquid composition for use in removing deposits from oil burning furnaces and the burners of said furnaces comprising:

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
US19512A 1960-04-04 1960-04-04 Chemical cleaning of oil heating systems Expired - Lifetime US3007781A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
BE609353D BE609353A (zh) 1960-04-04
US19512A US3007781A (en) 1960-04-04 1960-04-04 Chemical cleaning of oil heating systems
FR876258A FR1303921A (fr) 1960-04-04 1961-10-18 Procédé de nettoyage chimique des systèmes de chauffage à l'huile combustible

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US19512A US3007781A (en) 1960-04-04 1960-04-04 Chemical cleaning of oil heating systems

Publications (1)

Publication Number Publication Date
US3007781A true US3007781A (en) 1961-11-07

Family

ID=21793604

Family Applications (1)

Application Number Title Priority Date Filing Date
US19512A Expired - Lifetime US3007781A (en) 1960-04-04 1960-04-04 Chemical cleaning of oil heating systems

Country Status (3)

Country Link
US (1) US3007781A (zh)
BE (1) BE609353A (zh)
FR (1) FR1303921A (zh)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4505718A (en) * 1981-01-22 1985-03-19 The Lubrizol Corporation Organo transition metal salt/ashless detergent-dispersant combinations
US4621593A (en) * 1984-12-24 1986-11-11 Ford Motor Company Automotive dispensing apparatus for fuel additive
US5551957A (en) * 1992-05-06 1996-09-03 Ethyl Corporation Compostions for control of induction system deposits
US20090071068A1 (en) * 2007-09-14 2009-03-19 John Cook Method for reducing flammable creosote and other organic deposits in fireboxes
EP2197992A1 (en) * 2007-09-13 2010-06-23 Timburn, Inc. Method for reducing flammable creosote and other organic deposits in fireboxes

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2141848A (en) * 1938-12-27 Soot remover
US2230642A (en) * 1938-08-13 1941-02-04 Standard Oil Dev Co Fuel oil
US2509197A (en) * 1948-01-16 1950-05-30 Shell Dev Carbon remover and metal surface cleaning composition
US2566298A (en) * 1951-09-04 Cleaning composition
US2622671A (en) * 1949-07-07 1952-12-23 Nat Aluminate Corp Soot remover
US2669546A (en) * 1949-12-23 1954-02-16 Alrose Chemical Company Detergents containing imidazoline lactates
US2904458A (en) * 1954-09-02 1959-09-15 Ethyl Corp Removing combustion chamber deposits from internal combustion engines and compositions

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2141848A (en) * 1938-12-27 Soot remover
US2566298A (en) * 1951-09-04 Cleaning composition
US2230642A (en) * 1938-08-13 1941-02-04 Standard Oil Dev Co Fuel oil
US2509197A (en) * 1948-01-16 1950-05-30 Shell Dev Carbon remover and metal surface cleaning composition
US2622671A (en) * 1949-07-07 1952-12-23 Nat Aluminate Corp Soot remover
US2669546A (en) * 1949-12-23 1954-02-16 Alrose Chemical Company Detergents containing imidazoline lactates
US2904458A (en) * 1954-09-02 1959-09-15 Ethyl Corp Removing combustion chamber deposits from internal combustion engines and compositions

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4505718A (en) * 1981-01-22 1985-03-19 The Lubrizol Corporation Organo transition metal salt/ashless detergent-dispersant combinations
US4621593A (en) * 1984-12-24 1986-11-11 Ford Motor Company Automotive dispensing apparatus for fuel additive
US5551957A (en) * 1992-05-06 1996-09-03 Ethyl Corporation Compostions for control of induction system deposits
EP2197992A1 (en) * 2007-09-13 2010-06-23 Timburn, Inc. Method for reducing flammable creosote and other organic deposits in fireboxes
EP2197992A4 (en) * 2007-09-13 2011-12-14 Timburn Inc METHOD FOR REDUCING FLAMMABLE CREOSOT AND OTHER ORGANIC DEPOSITS IN COMBUSTION CHAMBERS
US20090071068A1 (en) * 2007-09-14 2009-03-19 John Cook Method for reducing flammable creosote and other organic deposits in fireboxes

Also Published As

Publication number Publication date
BE609353A (zh)
FR1303921A (fr) 1962-09-14

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