US2950409A - Storage tube - Google Patents
Storage tube Download PDFInfo
- Publication number
- US2950409A US2950409A US723873A US72387358A US2950409A US 2950409 A US2950409 A US 2950409A US 723873 A US723873 A US 723873A US 72387358 A US72387358 A US 72387358A US 2950409 A US2950409 A US 2950409A
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- Prior art keywords
- screen
- storage tube
- image
- energy
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000126 substance Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 239000010445 mica Substances 0.000 description 7
- 229910052618 mica group Inorganic materials 0.000 description 7
- 238000010894 electron beam technology Methods 0.000 description 6
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 229910052709 silver Inorganic materials 0.000 description 4
- 239000004332 silver Substances 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 229910052770 Uranium Inorganic materials 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 3
- 229910052716 thallium Inorganic materials 0.000 description 3
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 235000011164 potassium chloride Nutrition 0.000 description 2
- 239000001103 potassium chloride Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 229910001887 tin oxide Inorganic materials 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000004300 dark adaptation Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000010849 ion bombardment Methods 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J29/00—Details of cathode-ray tubes or of electron-beam tubes of the types covered by group H01J31/00
- H01J29/02—Electrodes; Screens; Mounting, supporting, spacing or insulating thereof
- H01J29/10—Screens on or from which an image or pattern is formed, picked up, converted or stored
- H01J29/18—Luminescent screens
- H01J29/182—Luminescent screens acting upon the lighting-up of the luminescent material other than by the composition of the luminescent material, e.g. by infra red or UV radiation, heating or electric fields
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J29/00—Details of cathode-ray tubes or of electron-beam tubes of the types covered by group H01J31/00
- H01J29/02—Electrodes; Screens; Mounting, supporting, spacing or insulating thereof
- H01J29/10—Screens on or from which an image or pattern is formed, picked up, converted or stored
- H01J29/14—Screens on or from which an image or pattern is formed, picked up, converted or stored acting by discoloration, e.g. halide screen
Definitions
- Image screens consisting of phosphorescent luminous substances and in which the portions that are hit by an electron beam have an afterglow effect which last for some time after the excitation.
- the reason for this resides in the fact that crystal electrons, which are excited by the electron beam, are lifted into impurities of the crystal, where they remain until being accidentally released from the impurity by an energy quantum of the heat radiation and, under the emission of light, are forced to return to the original energy level.
- image screens substantially consisting of an alkali-halide which, upon being bombarded by an electron beam, produces a tenebrescence phenomena, in the the portions hit by the electron beam change their colour towards dark. Accordingly, in this case the image will only become visible when the screen is being illuminated from the outside.
- the time of storage of these types of image screens is longer than with the phosphorescent types of image screens.
- a storage tube with a screen image which is visible in the light as well as in the dark.
- screen properties are very useful e.g. for wide-range displays in the directionndingand radar-technique.
- an observer only uses the radar equipment as an auxiliary means, and when the direct viewing or inspection of the surroundings during night-time requires a permanent or continuous dark-adaptation of the human eye, then every kind of illumination of the tube will act disturbingly.
- a bright image screen is by all means desirable.
- a tube combining both of these possibilities would render a re-adaptation of the eye, which takes several minutes, or a superfluous timewasting and circumstantial exchange of the tube.
- the present invention provides a storage tube featuring both of these advantageous properties.
- the storage tube according to the invention is provided with a screen on which the image recorded by an electron beam contrasts with the screen within a bright surrounding bybeing amplied on a bright background, while appearing in the dark as a phosphorescent image. Accordingly, the storage screen is not only featured by a tenebrescence phenomena, but also, by phosphorescent phenomena.
- This possibility results from the discovery that an alkali-halide activated with particular metals exhibit uorescents when heated.
- suitable alkali-halides such as potassium chloride, which may be activated by traces of foreign substances, such as thallium, titanium, manganese, copper, uranium, lead or silver.
- a double-layer screen which is composed of corresponding substances.
- one of these layers displays tenebrescence, and the other one phosphorescence.
- a controlling of the desired screen property may be accomplished by a corresponding arrangement of the screens and by varying the accelerating voltage.
- the storage tube is shown in a sectional representation.
- the envelope is denoted by 1, and the gun system (or beam generating system) is-denoted by 2.
- Reference numeral 3 designates a mica disk carrying the screen substance 4.
- a transparent resistive layer or coating e.g. of S1102, and which, through the contacts 6 and 7, is connected with a source of voltage 8 controlled by switch 9, thus effecting a heating of the mica disk by a passage of current.
- a transparent resistive layer or coating e.g. of S1102
- the screen Upon being hit by the electron beam, the screen, within a bright surrounding, will display a change in colour toward bluish-violet. If the screen is not illuminated from the outside then, upon heating of the mica disk, there will appear the same image as a luminous phosphorescent picture.
- a cathode ray tube comprising a screen and a source of energy, a layer of energy responsive material mounted on said screen which exhibits the properties of phosphorescence in a first state and tenebrescence in a second state, and means for heating said layer to selectively change the state of said material to respond to said source of energy whereby said screen will either phosphoresce or tenebresce.
- said layer consists of a mixture of fan alkali halide and a material from a group consisting of thallium, titanium, manganese, copper, uranium, lead or silver.
- a cathode ray tube comprising a screen, a source of energy, ⁇ a layer of energy responsive material which exhibits the properties of phosphorescence in a rst state and tenebrescence in a second state applied to one surface of said screen, a resistive layer applied to the other surface of said screen, means for applying ⁇ a source of voltage to said resistive layer so as to cause said energy responsive material to change from said second state to said rst state.
- a cathode ray tube comprising a mica disc, a
- a layer of energy responsive material said tin oxide so as to cause said energy responsive macomprising a mixture ofalkali halide and-a ⁇ material vfromV terial to change from said second state to said first-state a group consisting of thallium, titanium, manganese, d he e of JLht t copper, uranium, lead or silver, which exhibits the proper- References Cite m t 1 1S pa en tiesy of phosphoresceueein Ia rst statev andl tenebrescenceV UNITED STATES PATENTS ina-secondrstate applied to one smfaceofsaid mica disc,
Landscapes
- Cathode-Ray Tubes And Fluorescent Screens For Display (AREA)
Description
w. SER1-HOLD ETAL 2,950,4G9
STORAGE TUBE Aug. 23, 1960 Filed March 25. 1958 ATTORNEY United States Patent O STORAGE TUBE Wolfgang Berthold, Belmar, NJ., and Jrgen Rottgardt,
Numberg, and Gerhard Heller, Ludwigsburg, Germany, assiguors to International Standard Electric Corporation, New York, N.Y., a corporation of Delaware Filed Mar. 25, 1958, Ser. No. 723,873 Claims priority, application Germany Mar. 27, 1957 4 Claims. (Cl. 313-92) For the purpose of storing electric signals there are used cathode ray tubes which, depending on their respective iield of application, are equipped with different kinds of fluorescent screens.
Image screens are known, consisting of phosphorescent luminous substances and in which the portions that are hit by an electron beam have an afterglow effect which last for some time after the excitation. The reason for this resides in the fact that crystal electrons, which are excited by the electron beam, are lifted into impurities of the crystal, where they remain until being accidentally released from the impurity by an energy quantum of the heat radiation and, under the emission of light, are forced to return to the original energy level.
The viewing of a phosphorescent image is only possible in the dark, because its light intensity is Very small.
Furthermore there are known image screens, substantially consisting of an alkali-halide which, upon being bombarded by an electron beam, produces a tenebrescence phenomena, in the the portions hit by the electron beam change their colour towards dark. Accordingly, in this case the image will only become visible when the screen is being illuminated from the outside. The time of storage of these types of image screens is longer than with the phosphorescent types of image screens. By means of a new energy supply, e.g. by radiation with a visible light, or by heating the crystalline layer, the change in colour may be eliminated again.
The article appearing in the Zeitschrift fr Naturforschung, 1955, pages 620-630 by P. Dobrinski and H. Hinrichs describes the luminescence of potassium chloride activated with silver. It is discussed that NaCl-Ag crystals radiated by X-rays display the phenomenon of phosphorescence.
For many applications it is advantageous to provide a storage tube, with a screen image which is visible in the light as well as in the dark. Such screen properties are very useful e.g. for wide-range displays in the directionndingand radar-technique. For example, when an observer only uses the radar equipment as an auxiliary means, and when the direct viewing or inspection of the surroundings during night-time requires a permanent or continuous dark-adaptation of the human eye, then every kind of illumination of the tube will act disturbingly. On the other hand, during the day-time a bright image screen is by all means desirable. A tube combining both of these possibilities would render a re-adaptation of the eye, which takes several minutes, or a superfluous timewasting and circumstantial exchange of the tube.
The present invention provides a storage tube featuring both of these advantageous properties. The storage tube according to the invention is provided with a screen on which the image recorded by an electron beam contrasts with the screen within a bright surrounding bybeing amplied on a bright background, while appearing in the dark as a phosphorescent image. Accordingly, the storage screen is not only featured by a tenebrescence phenomena, but also, by phosphorescent phenomena. This possibility results from the discovery that an alkali-halide activated with particular metals exhibit uorescents when heated. As a luminous substance there are suitable alkali-halides, such as potassium chloride, which may be activated by traces of foreign substances, such as thallium, titanium, manganese, copper, uranium, lead or silver. Further it has proved to be very advantageous, to articially increase the number of lattice defects, serving as the traps for the secondary electrons. This may be accomplished e.g. by an evaporation of the luminous layer in a micro-crystalline form, or else by way of ion bombardment.
Instead of activating the luminous substance there may `also be employed a double-layer screen, which is composed of corresponding substances. Thereby one of these layers displays tenebrescence, and the other one phosphorescence. A controlling of the desired screen property may be accomplished by a corresponding arrangement of the screens and by varying the accelerating voltage.
In the following the invention will be described in particular with reference to an exemplified embodiment shown in the accompanying drawing:
In this drawing the storage tube is shown in a sectional representation. The envelope is denoted by 1, and the gun system (or beam generating system) is-denoted by 2. Reference numeral 3 designates a mica disk carrying the screen substance 4. On the side of the mica disk not facing the cathode there is arranged a transparent resistive layer or coating 5, e.g. of S1102, and which, through the contacts 6 and 7, is connected with a source of voltage 8 controlled by switch 9, thus effecting a heating of the mica disk by a passage of current. On the side of the mica disk facing the cathode there is evaporated the screen substance, which is activated with a corresponding foreign substance. Upon being hit by the electron beam, the screen, within a bright surrounding, will display a change in colour toward bluish-violet. If the screen is not illuminated from the outside then, upon heating of the mica disk, there will appear the same image as a luminous phosphorescent picture.
While We have described above the principles of our invention in connection with specific apparatus, it is to be clearly understood that this description is made only by way of example and not as a limitation to the scope of our invention as set forth in the objects thereof and in the accompanying claims.
What is claimed is:
l. In a cathode ray tube comprising a screen and a source of energy, a layer of energy responsive material mounted on said screen which exhibits the properties of phosphorescence in a first state and tenebrescence in a second state, and means for heating said layer to selectively change the state of said material to respond to said source of energy whereby said screen will either phosphoresce or tenebresce.
2. In a cathode ray tube the combination as in claim 1 wherein said layer consists of a mixture of fan alkali halide and a material from a group consisting of thallium, titanium, manganese, copper, uranium, lead or silver.
3. A cathode ray tube comprising a screen, a source of energy, `a layer of energy responsive material which exhibits the properties of phosphorescence in a rst state and tenebrescence in a second state applied to one surface of said screen, a resistive layer applied to the other surface of said screen, means for applying `a source of voltage to said resistive layer so as to cause said energy responsive material to change from said second state to said rst state.
4. A cathode ray tube comprising a mica disc, a
a t Y Y l 4j y l source of energy, a layer of energy responsive material said tin oxide so as to cause said energy responsive macomprising a mixture ofalkali halide and-a` material vfromV terial to change from said second state to said first-state a group consisting of thallium, titanium, manganese, d he e of JLht t copper, uranium, lead or silver, which exhibits the proper- References Cite m t 1 1S pa en tiesy of phosphoresceueein Ia rst statev andl tenebrescenceV UNITED STATES PATENTS ina-secondrstate applied to one smfaceofsaid mica disc,
Y 2,416,574 Fonda. Feb. 25, 1947 allayepof` tin oxide applied toY the other surface 0f said 2,435,435 Fonda Feb. 3, 1948 mica-disc, and means for applying asorce of Voltage to 2,447,851 Fonda Aug. 24, 1948
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEL27238A DE1164579B (en) | 1957-03-27 | 1957-03-27 | Procedure for making records visible |
Publications (1)
Publication Number | Publication Date |
---|---|
US2950409A true US2950409A (en) | 1960-08-23 |
Family
ID=7264112
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US723873A Expired - Lifetime US2950409A (en) | 1957-03-27 | 1958-03-25 | Storage tube |
Country Status (2)
Country | Link |
---|---|
US (1) | US2950409A (en) |
DE (1) | DE1164579B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3148281A (en) * | 1961-02-28 | 1964-09-08 | Litton Prec Products Inc | Cathode ray storage tube using a dark trace layer and a phosphor layer |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2416574A (en) * | 1943-04-08 | 1947-02-25 | Gen Electric | Discriminative alkali halide screen |
US2435435A (en) * | 1943-04-06 | 1948-02-03 | Gen Electric | Cathode-ray screen |
US2447851A (en) * | 1944-07-24 | 1948-08-24 | Gen Electric | Luminescent screen indicating changes in image formation |
-
1957
- 1957-03-27 DE DEL27238A patent/DE1164579B/en active Pending
-
1958
- 1958-03-25 US US723873A patent/US2950409A/en not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2435435A (en) * | 1943-04-06 | 1948-02-03 | Gen Electric | Cathode-ray screen |
US2416574A (en) * | 1943-04-08 | 1947-02-25 | Gen Electric | Discriminative alkali halide screen |
US2447851A (en) * | 1944-07-24 | 1948-08-24 | Gen Electric | Luminescent screen indicating changes in image formation |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3148281A (en) * | 1961-02-28 | 1964-09-08 | Litton Prec Products Inc | Cathode ray storage tube using a dark trace layer and a phosphor layer |
Also Published As
Publication number | Publication date |
---|---|
DE1164579B (en) | 1964-03-05 |
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