US2816040A

US2816040A - Dental impression material

Info

Publication number: US2816040A
Application number: US396778A
Authority: US
Inventors: Rabchuk Alexander
Original assignee: Kerr Manufacturing Co
Current assignee: Kerr Corp
Priority date: 1953-12-07
Filing date: 1953-12-07
Publication date: 1957-12-10
Anticipated expiration: 1974-12-10

Description

2,816,040 JDENTAL IMPRESS'ION MATERIAL 9 Alexander :Raibchuk, .Detroit,..Mich., sassignor to ffKi-r Manufacturing Company, Detroit, Mich., a corporation of Michigan No Drawing. Application December 7, 1953, Serial No. 396,778

10 Claims. (Cl. 106-384) The invention relates to impression materials, particularly elastic dental impression materials. In the present state of the art of impression materials, compositions are known containing a gel-forming agent such as a soluble alginate together with other substances which in the presence of water will precipitate and solidify the gel to a consistency useful for dental purposes.

The present invention relates to an improved composition and is based on the discovery of a new precipitating agent, dibasic lead phosphiae, and a new association of other ingredients cooperating therewith and with the gel-forming agent to form an elastic impression material having desirable properties for dental purposes.

The dental impression composition of this invention comprises a gel-forming agent, usually a soluble alginate, and dibasic lead phosphite which functions as a setting or congelation agent. In addition to these two principal ingredients, the composition of this invention preferably includes a retarding agent which gives a predetermined control over the congelation or setting time, an inert filler and desirably also one or more other ingredients referred to as modifiers which impart desirable characteristics to the composition for its intended purpose.

The composition of this invention is useful in the making of full dentures, partial dentures, inlays, bridges and other devices for dental purposes and it provides a medium for taking impressions of the dental and oral tissues. The composition is mixed with water, at the time of use, to a thick yet semi-fluid mixture, which is placed in a suitable tray. This loaded tray is carried to the mouth and is seated upon or over the object or objects and in several minutes time solidifies to an elastic gel.

The gel is elastic so it can be pulled over teeth or hard undercut structures, as well as the softer tissues in situ, and produce a negative of the structure with complete detail. The gel is used as a mold, without the use of fixing solutions of any kind, for casting stone, investments or plasters, and upon their hardening they form a complete accurate duplication of the master medium.

The gel-forming agent used in the impression compositions of this invention is of the class which includes the water-soluble salts of alginic acid, such as the alkali metal alginates, Water-soluble pectate salts and other pectins, alkali metal carboxy methyl cellulose, and other equivalent materials.

Retarding agents used in the compositions of this invention are of the class including soluble alkali metal phosphates or silicates alone or in conjunction with such salts as alkali metal sulfates or chlorides. Suitable fillers are diatomaceous earth, silicas, resins, or other insoluble materails such as heavy metal phosphates, carbonates or silicates.

Modifiers include fluosilicates, fluozirconates and gluconates. The following are given as examples of impression materials whose compositions render them suitable as dental impression materials:

2,816,040 Patented Dec. 10, .1957

ice

Example '1 I weight in grams Sodium alginate-.. 2.0 Dibasic lead phosphite... a 'SLO Tetra sodium ,pyrophosphate n nfi; 05 Potassium silicofluo'ride 1.5 Diatomaceous earth 11.0

Example 2 Sodium alginate 2.0 Dibasic lead phosphite 5.0 Tetra sodium pyrophosphate 0.1 Glucono delta-lactnne 0.3 Diatomaceous earth 11.0

Example 3 Sodium alginate 2.0 Dibasic lead phosphite 5.0 Tetra sodium pyrophosphate 0.2 Potassium fluozircnnate 0.5 Diatomaceous earth 11.0

The compositions of the above examples can be prepared by blending the dry ingredients in a mill, and the mixture thus obtained may be packaged and stored with good shelf life over extended periods of time.

The composition of Example 1 when mixed with 60 cc. of water at 70 F. allows a working time of 1% minutes and has a setting time of 2 /2 minutes. Example 2 under the same conditions has a working time of 1% minutes and a setting time of 2 minutes.

It is to be understood that while the examples given include the best mode contemplated of carrying out the invention, the specific mixtures of ingredients in the examples can be modified in accordance with the general teachings without departing from the invention.

What I claim as my invention is:

1. A composition consisting essentially of a gel-forming agent of the class consisting of water-soluble alginates, pectates, pectins and carboxy methyl cellulose and dibasic lead phosphite.

2. A composition as defined in claim 1 containing also a retarder of the class consisting of alkali metal phosphates and silicates, a modifier of the class consisting of fluosilicates and gluconates, and a filler in amount at least about 50%.

3. A composition capable of forming with water an elastic impression material consisting essentially of a water-soluble alginate, dibasic lead phosphite, in amount greater than said alginate, and a filler in amount at least about 50%.

4. A composition capable of forming with water an elastic impression material consisting essentially of a water-soluble alginate, dibasic lead phosphite, an alkali metal phosphate, potassium silicofiuoride and diatomaceous earth.

5. A composition capable of forming with water an elastic impression material consisting essentially of a water-soluble alginate, dibasic lead phosphite, an alkali metal phosphate, a gluconate, and diatomaceous earth.

6. A composition capable of forming with water an elastic impression material consisting essentially of about 10% of a water-soluble alginate, about 25% dibasic lead phosphite, an alkali metal phosphate, potassium silicofluoride and at least about 50% diatomaceous earth.

7. A composition capable of forming with water an elastic impression material consisting essentially of about 10% of a water-soluble alginate, about 25% dibasic lead phosphite, at least about 50% filler and a fiuozirconate.

8. A mold formed of the reaction product of water with a composition consisting essentially of a water-soluble alginate, at least about 50% diatomaceous earth and about 25% dibasic lead phosphite.

9. A mold formed of the reaction product of water with a composition consisting essentially of a water-soluble alginate, at least about 50% diatomaceous earth, an alkali metal pyrophosphate, potassium silicofluoride and about 25%- dibasic lead phos'phite.

10; A 'dental impression composition consisting essentially of about 10% sodium alginate, about 25% dibasic'lead phosphite, at least about 50% filler, an alkali metal phosphate, and potassium silicofluoride.

References Cited in the file of this patent UNITED STATES PATENTS Wilson May 22, 1945 Evans et a1. July 31, 1945 Noyes July 29, 1947 Steiner May 18, 1948 Meyer Dec. 30, 1952 Noyes et a1. Feb. 10, 1953 Fink Sept. 15, 1953 Noyes et al May 11, 1954

Claims

1. A COMPOSITION CONSISTING ESSENTIALLY OF A GEL-FORMING AGENT OF THE CLASS CONSISTING OF WATER-SOLUBLE AIGINATES; PECTATES, PECTINS AND CARBOXY METHYL CELLULOSE AND DIBASIC LEAD PHOSPHITE.