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US2776255A - Method of making formed, plated articles - Google Patents

Method of making formed, plated articles Download PDF

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Publication number
US2776255A
US2776255A US520617A US52061755A US2776255A US 2776255 A US2776255 A US 2776255A US 520617 A US520617 A US 520617A US 52061755 A US52061755 A US 52061755A US 2776255 A US2776255 A US 2776255A
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Prior art keywords
coating
nickel
zinc
bumper
strip
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US520617A
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Milton B Hammond
Glade B Bowman
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Rockwell Spring and Axle Co
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Rockwell Spring and Axle Co
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/34—Pretreatment of metallic surfaces to be electroplated
    • C25D5/36—Pretreatment of metallic surfaces to be electroplated of iron or steel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S205/00—Electrolysis: processes, compositions used therein, and methods of preparing the compositions
    • Y10S205/917—Treatment of workpiece between coating steps

Definitions

  • This invention relates to a method of making formed, plated articles.
  • a flat steel strip is formed in dies into the shape desired for the bumper. This leaves die marks on the steel bumper. The die marks are removed by polishing and then the bumper is nickel-plated. If the die marks were not removed, the nickel-plating would not be satisfactorily smooth. Instead of simply nickel-plating the formed bumper from which the die marks have been removed by polishing, one may first plate it with copper before plating it with nickel.
  • a flat steel strip is plated with zinc, the zinc' coated strip is then formed into a bumper, the die marks formed in the Zinc coating in forming the bumper are then removed by dipping the zinc coated formed bumper in acid to strip ofi the Zinc coating and the formed steel bumper is then plated with nickel.
  • a flat steel strip is plated with nickel or copper or witha layer of nickel and then with a layer of copper, the coated strip is then plated with zinc, the Zinc coated strip is thereafter formed into a bumper, the Zinc coating is stripped from the formed bumper and the formed bumper is plated. with nickel.
  • the die marks made in forming the bumper are formed in the zinc coating which is thereafter dissolved oil. of the bumper toremove the die marks, thereby eliminating the necessity of polishing steel to remove die marks.
  • the following examples illustrate various ways in which our process can be carried out.
  • the bath preferably is maintained at a temperature of about 190 F. and an anode current density of about 45 to 75 amperes per square foot is employed.
  • the strip is then rinsed in water, dipped for about 10 to seconds in an acid solution containing 15% by volume of hydrochloric or sulphuric acid and then water rinsed.
  • the strip is then coated electrolytically with a zinc plate having a thickness of about 0.0001"-0.0006".
  • an aqueous solution of the following composition may be employed:
  • the zinc plated strip is then given a phosphate coating by dipping or spraying.
  • a bath of the following com-' position may be employed:
  • the formed bumper is then subjected to an anodic alkaline cleaning to remove the phosphate coating and drawing compound.
  • the alkaline cleaning solution may be the same as that given in Step 2 of this example except that the N213PO4 is omitted.
  • the anodic current density and the temperature of the bath may be as given in the above step.
  • the formed bumper is then dipped in acid to remove the Zinc coating which carries the die marks.
  • a suitable solution is either hydrochloric acid or sulphuric acid of 15 to 20% strength.
  • the immersion time for removing the zinc coating of the thickness above given is approximately /2 minute. This acid treatment leaves a black residue of zinc oxide on the steel bumper.
  • the formed steel bumper is then anodicallyelectropolished to remove the residue by passing an electric current from the strip through an aqueous solution containing phosphoric acid and sulphuric acid.
  • a suitable bath for use in this electropolishing step is:
  • the solution may be used under widely varying conditions, the anode current density being as low as 25 or as high as 2,000 amperes per square foot and the temperature can be any temperature up to about 250 F. In the preferred method, an anode current density of about 285 amperes per square foot is employed and the bath temperature is about 100 F.
  • the time for polishing the steel will vary depending upon the polish required, from about 1 to 20 minutes, the usual period being about 5 minutes.
  • the formed and polished steel bumper is then given an anodic alkaline cleaning employing the same bath and other conditions as given in step 7 of this example.
  • the bumper is then water rinsed, acid clipped and water rinsed in the same manner as given in step 2 of this example.
  • a suitable aqueous bath may contain:
  • a cathode current density of about 50 amperes per square foot is employed, the bath is maintained at a temperature of 130 to 135 F. and 'a nickel anode is used.
  • Example 11 l A fiat steel strip is polished with abrasive and grease as instep 1 of Example I.
  • The-strip is subjected to an anodic alkaline cleaning operation as in step 2 of Example I and is then water rinsed.
  • the electropolished steel strip is then subjected to an anodic alkaline cleaning operation, a water rinse, an acid dip and a water rinse as in step 2 of Example I.
  • the strip is then electroplated with nickel as in step ll'of Example I to provide a nickel coating having a thickness of 0.0002"0.0006 and the strip is rinsed in water.
  • the nickel-plated strip is then electroplated with zinc to provide a coating having a thickness between 0.0001" and 0.0006 as in step 3 of Example I.
  • the strip having an undercoat of nickel and an overcoat of zinc is then given a phosphate coating, a drawing compound is applied, the strip is formed into a bumper, the bumper is subjected to an anodic alkaline cleaning operation and the zinc coating is removed by an acid treatment, all in accordance with steps 48 of Example I.
  • the bumper is given an anodic electropolish in a phosphoric acid and sulphuric acid bath as in step 9 of Example I to remove the black zinc oxide residue.
  • the nickel coated bumper is subjected to a cathodic alkaline cleaning operation to activate the nickel.
  • this cathodic alkaline cleaning step the same bath is used as in step 10 of Example I.
  • the bumper is then water rinsed, acid dipped and water rinsed as instep 2 of Example I.
  • the nickel-plated bumper is then given an additional electroplate of nickel using the bath and other conditions described in step 5 of this example.
  • Example II-differs from Example I in the following respects.
  • step 3 the steel strip is given an anodic electropolish in addition to the polish with abrasive and grease accomplished in step 1.
  • the steel strip is coated with nickel before he zinc coating is applied.
  • the nickel coated bumper is subjected to a' cathodic alkaline cleaning step'toactivate the nickel coating sol'th'at it is better adapted to receive and bond with the nickel-plate applied in step 14.
  • Example III The steps of this example'are the same 'asin Example II except that an electroplate of copper, preferably 0.001" thick, is applied to the nickel-plated strip prior to coating the strip with zinc. Accordingly, when -thezinc c'oating is dissolved off of the formed bumper, the'burnpenhas an outer coat of-copperand an undercoat of nickel. Nickel is then electroplated on the copper so that the bumper comprises'a steel base, a coating of nickel,'a coating of copper and a coatingof nickel.
  • a suitable aqueous copper plating bath may contain:
  • a cathode current density of 40 to 50 amperes per square foot is employed and the bath preferably is maintained at a temperature of about F.
  • Example IV This example is the same asExample III except that nickel is electroplated on the copper coating before the strip is plated with zinc. Accordingly, after the bumper has been formed from the flat strip and the zinc coating has been removed, the bumper comprises a steel base, a coating of nickel, a coating of copper and a coating of nickel so that, if desired, no further nickel-plate need be applied after the zinc coating has been removed.
  • the steps corresponding to steps 4 and 5 of Example I can be omitted, although it is preferred to employ these steps.
  • the bumper In the known method of making bumpers in which a bumper is formed from a flat steel strip and the nickelplated is applied after the bumper has been formed, the bumper, due to its shape, contains pockets or cavities which are difiicult to reach in the electrodeposition of the nickel. These difficulties are overcome or minimized in accordance with Examples II-IV of the present invention wherein the nickel-plate is applied to the fiat steel strip prior to forming the strip into a bumper.
  • the method of making formed, plated articles which comprises electroplating a coating of nickel on a polished flat steel strip, electroplating a coating of zinc on the nickel coating, forming the coated strip into an article, dissolving off in an acid solution from the formed article the zinc coating containing imperfections resulting from the forming operation, subjecting the nickel coated formed article to a cathodic alkaline cleaning operation to activate the nickel, contacting the formed article with an acid, and electroplating a nickel coating on the formed article.
  • the method of making formed, plated articles which comprises electroplating a coating of nickel on a polished flat steel strip, electroplating a coating of zinc on the nickel coating, forming the coated strip into an article, dissolving off in an acid solution from the formed article the zinc coating containing imperfections resulting from the forming operation, subjecting the nickel coated formed article to an anodic electropolishing operation in an acid aqueous bath containing phosphoric acid to remove residue resulting from dissolving off the zinc coating, subjecting the nickel coated formed article to a cathodic alkaline cleaning operation to activate the nickel, contacting the formed article with an acid, and electroplating a nickel coating on the formed article.
  • the abrasive and grease subjecting the steel strip to an 0 anodic electropolishing operation in an acid aqueous bath containing phosphoric acid, anodically cleaning the strip in an aqueous alkaline bath, contacting the strip with an acid, electroplating a coating of nickel on the flat polished strip, electroplating a coating of zinc on the nickel coating, applying a phosphate coating and a drawing compound to the zinc coating, forming the coated strip into an article, subjecting the formed article to an anodic alkaline cleaning operation to remove the phosphate coating and drawing compound, dissolving oil?
  • the zinc coating containing imperfections resulting from the forming operation, subjecting the nickel coated formed article to an anodic electropolishing operation in an acid aqueous bath containing phosphoric acid to remove residue resulting from dissolving off the zinc coating, subjecting the nickel coated formed article to a cathodic alkaline cleaning operation to activate the nickel, contacting the formed article with an acid, and electroplating a nickel coating on the formed article.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electroplating Methods And Accessories (AREA)

Description

METHOD OF MAKING FORMED, PLATED ARTICLES Milton B. Hammond and Glade B. Bowman, Edgeworth, Pa., assignors to Rockwell Spring and Axle Company, Coraopolis, Pin, a corporation of Pennsylvania No Drawing. Application July 7, 1955, Serial No. 520,617
4 Claims. (Cl. 204-23) This invention relates to a method of making formed, plated articles.
In a known method of making a formed, plated article such, for example, as an automobile bumper, a flat steel strip is formed in dies into the shape desired for the bumper. This leaves die marks on the steel bumper. The die marks are removed by polishing and then the bumper is nickel-plated. If the die marks were not removed, the nickel-plating would not be satisfactorily smooth. Instead of simply nickel-plating the formed bumper from which the die marks have been removed by polishing, one may first plate it with copper before plating it with nickel.
In accordance with the present invention, a flat steel strip is plated with zinc, the zinc' coated strip is then formed into a bumper, the die marks formed in the Zinc coating in forming the bumper are then removed by dipping the zinc coated formed bumper in acid to strip ofi the Zinc coating and the formed steel bumper is then plated with nickel. In a preferred embodiment of the invention, a flat steel strip is plated with nickel or copper or witha layer of nickel and then with a layer of copper, the coated strip is then plated with zinc, the Zinc coated strip is thereafter formed into a bumper, the Zinc coating is stripped from the formed bumper and the formed bumper is plated. with nickel. V
In our process, the die marks made in forming the bumper are formed in the zinc coating which is thereafter dissolved oil. of the bumper toremove the die marks, thereby eliminating the necessity of polishing steel to remove die marks. The following examples illustrate various ways in which our process can be carried out.
Example I Ounces/ gal. NaOl-I 4 Nazcoa 6 NaaPO4 1.5
The bath preferably is maintained at a temperature of about 190 F. and an anode current density of about 45 to 75 amperes per square foot is employed. The strip is then rinsed in water, dipped for about 10 to seconds in an acid solution containing 15% by volume of hydrochloric or sulphuric acid and then water rinsed.
3. The strip is then coated electrolytically with a zinc plate having a thickness of about 0.0001"-0.0006". In
Patented Jan. 1, 1957 forming the zinc coating, an aqueous solution of the following composition may be employed:
Ounces/ gal. ZnSO4.7H2O 40 ZnClz 2 ZI1(C2H302) 2 2 The bath is maintained at a pH of about 3.5 to 5, a zinc anode is employed, the temperature of the bath is maintained at about F. and the cathode current density is about 20 to 60 amperes per square foot.
4. The zinc plated strip is then given a phosphate coating by dipping or spraying. A bath of the following com-' position may be employed:
Grams per liter Zinc 11.0 P205 9 to 9.5 N03 18 NazO 1.5 Ni 0.1 Cu 0.03 NaNOz 1 to 1.5
'7. The formed bumper is then subjected to an anodic alkaline cleaning to remove the phosphate coating and drawing compound. The alkaline cleaning solution may be the same as that given in Step 2 of this example except that the N213PO4 is omitted. The anodic current density and the temperature of the bath may be as given in the above step.
8. The formed bumper is then dipped in acid to remove the Zinc coating which carries the die marks. A suitable solution is either hydrochloric acid or sulphuric acid of 15 to 20% strength. The immersion time for removing the zinc coating of the thickness above given is approximately /2 minute. This acid treatment leaves a black residue of zinc oxide on the steel bumper.
9. The formed steel bumper is then anodicallyelectropolished to remove the residue by passing an electric current from the strip through an aqueous solution containing phosphoric acid and sulphuric acid. A suitable bath for use in this electropolishing step is:
The solution may be used under widely varying conditions, the anode current density being as low as 25 or as high as 2,000 amperes per square foot and the temperature can be any temperature up to about 250 F. In the preferred method, an anode current density of about 285 amperes per square foot is employed and the bath temperature is about 100 F. The time for polishing the steel will vary depending upon the polish required, from about 1 to 20 minutes, the usual period being about 5 minutes.
10. The formed and polished steel bumper is then given an anodic alkaline cleaning employing the same bath and other conditions as given in step 7 of this example. The bumper is then water rinsed, acid clipped and water rinsed in the same manner as given in step 2 of this example.
11. The formed bumper is then nickel-plated. A suitable aqueous bath may contain:
Ounces/ gal. NiSO4 45-50 NiClv -6 Boric acid 5-5.5 Coumarin 0.025 Lauryl sulphate .05
A cathode current density of about 50 amperes per square foot is employed, the bath is maintained at a temperature of 130 to 135 F. and 'a nickel anode is used.
Example 11 l. A fiat steel strip is polished with abrasive and grease as instep 1 of Example I.
2. The-strip is subjected to an anodic alkaline cleaning operation as in step 2 of Example I and is then water rinsed.
3. The steel .strip is then .anodically electropolished as in step 9 of Example .I and is then rinsed in water.
4. The electropolished steel strip is then subjected to an anodic alkaline cleaning operation, a water rinse, an acid dip and a water rinse as in step 2 of Example I.
5. The strip is then electroplated with nickel as in step ll'of Example I to provide a nickel coating having a thickness of 0.0002"0.0006 and the strip is rinsed in water.
6. The nickel-plated strip is then electroplated with zinc to provide a coating having a thickness between 0.0001" and 0.0006 as in step 3 of Example I.
7-11. The strip having an undercoat of nickel and an overcoat of zinc is then given a phosphate coating, a drawing compound is applied, the strip is formed into a bumper, the bumper is subjected to an anodic alkaline cleaning operation and the zinc coating is removed by an acid treatment, all in accordance with steps 48 of Example I.
12. The bumper is given an anodic electropolish in a phosphoric acid and sulphuric acid bath as in step 9 of Example I to remove the black zinc oxide residue.
13. The nickel coated bumper is subjected to a cathodic alkaline cleaning operation to activate the nickel. In this cathodic alkaline cleaning step, the same bath is used as in step 10 of Example I. The bumper is then water rinsed, acid dipped and water rinsed as instep 2 of Example I.
14. The nickel-plated bumper is then given an additional electroplate of nickel using the bath and other conditions described in step 5 of this example.
. Comparing Examples I and II, it will be seen that Example II-differs from Example I in the following respects. In step 3, the steel strip is given an anodic electropolish in addition to the polish with abrasive and grease accomplished in step 1. The steel strip is coated with nickel before he zinc coating is applied. After the zinc plate lias'been removed from the formed bumper and the bumper has been given an anodic electropolish, "the nickel coated bumper is subjected to a' cathodic alkaline cleaning step'toactivate the nickel coating sol'th'at it is better adapted to receive and bond with the nickel-plate applied in step 14.
. Example III The steps of this example'are the same 'asin Example II except that an electroplate of copper, preferably 0.001" thick, is applied to the nickel-plated strip prior to coating the strip with zinc. Accordingly, when -thezinc c'oating is dissolved off of the formed bumper, the'burnpenhas an outer coat of-copperand an undercoat of nickel. Nickel is then electroplated on the copper so that the bumper comprises'a steel base, a coating of nickel,'a coating of copper and a coatingof nickel.
A suitable aqueous copper plating bath may contain:
A cathode current density of 40 to 50 amperes per square foot is employed and the bath preferably is maintained at a temperature of about F.
Example IV This example is the same asExample III except that nickel is electroplated on the copper coating before the strip is plated with zinc. Accordingly, after the bumper has been formed from the flat strip and the zinc coating has been removed, the bumper comprises a steel base, a coating of nickel, a coating of copper and a coating of nickel so that, if desired, no further nickel-plate need be applied after the zinc coating has been removed.
In all of the examples, the steps corresponding to steps 4 and 5 of Example I can be omitted, although it is preferred to employ these steps. In other words, it is not essential that the zinc plated strip be provided with a phosphate coating or that a drawing compound be employed in forming the strip into a bumper but these steps are desirable.
In the known method of making bumpers in which a bumper is formed from a flat steel strip and the nickelplated is applied after the bumper has been formed, the bumper, due to its shape, contains pockets or cavities which are difiicult to reach in the electrodeposition of the nickel. These difficulties are overcome or minimized in accordance with Examples II-IV of the present invention wherein the nickel-plate is applied to the fiat steel strip prior to forming the strip into a bumper.
We have referred to the formation of an automobile bumper but, of course, it will be understood that the invention may be applied to producing various other kinds of formed and plated articles.
The invention is not limited to the preferred embodiments but may be otherwise embodied or practiced within the scope of the following claims.
We claim:
1. The method of making formed, plated articles, which comprises electroplating a coating of nickel on a polished flat steel strip, electroplating a coating of zinc on the nickel coating, forming the coated strip into an article, dissolving off in an acid solution from the formed article the zinc coating containing imperfections resulting from the forming operation, subjecting the nickel coated formed article to a cathodic alkaline cleaning operation to activate the nickel, contacting the formed article with an acid, and electroplating a nickel coating on the formed article.
2. The method of making formed, plated articles which comprises electroplating a coating of nickel on a polished flat steel strip, electroplating a coating of zinc on the nickel coating, forming the coated strip into an article, dissolving off in an acid solution from the formed article the zinc coating containing imperfections resulting from the forming operation, subjecting the nickel coated formed article to an anodic electropolishing operation in an acid aqueous bath containing phosphoric acid to remove residue resulting from dissolving off the zinc coating, subjecting the nickel coated formed article to a cathodic alkaline cleaning operation to activate the nickel, contacting the formed article with an acid, and electroplating a nickel coating on the formed article.
3. The method of making formed, plated articles, which compriseselectroplating 'a coating -of nickel on a polished flat steel strip, electroplating"a coating of zinc on the nickel coating, applying a phosphate'coating "and a drawing compound to the zinc coating, forming the coated strip 'into'an'article, subjecting the formed article to an anodic alkaline cleaning operation to remove .the phosphate coating and drawing compound, dissolving off in an acid solution from the formed article the zinc coating containing imperfections resulting from the forming operation, subjectingthe nickel coated formed article' tolan anodicelectropolishing operation in an acid 15 aqueous bath containing phosphoric acid to remove residue resulting from dissolving oil? the zinc coating, sub
the abrasive and grease, subjecting the steel strip to an 0 anodic electropolishing operation in an acid aqueous bath containing phosphoric acid, anodically cleaning the strip in an aqueous alkaline bath, contacting the strip with an acid, electroplating a coating of nickel on the flat polished strip, electroplating a coating of zinc on the nickel coating, applying a phosphate coating and a drawing compound to the zinc coating, forming the coated strip into an article, subjecting the formed article to an anodic alkaline cleaning operation to remove the phosphate coating and drawing compound, dissolving oil? in an acid solution from the formed article the zinc coating containing imperfections resulting from the forming operation, subjecting the nickel coated formed article to an anodic electropolishing operation in an acid aqueous bath containing phosphoric acid to remove residue resulting from dissolving off the zinc coating, subjecting the nickel coated formed article to a cathodic alkaline cleaning operation to activate the nickel, contacting the formed article with an acid, and electroplating a nickel coating on the formed article.
References Cited in the file of this patent UNITED STATES PATENTS 316,600 Brown Apr. 28, 1885 1,273,506 Lederer July 23, 1918 1,597,189 Gero Aug. 24, 1926 2,206,662 Conradi et a1 July 2, 1940 2,293,810 Domm Aug. 25, 1942 2,315,740 Schoomnaker et a1. Apr. 6, 1943 2,323,890 Adler July 13, 1943 2,613,626 Whitney Oct. 14, 1952 2,726,201 Prine Dec. 6, 1955

Claims (1)

  1. 3. THE METHOD OF MAKING FORMED, PLATED ARTICLES, WHICH COMPRISES ELECTROPLATING A COATING OF NICKEL ON A POLISHED FLAT STEEL STRIP, ELECTROPLATING A COATING OF ZINC ON THE NICKEL COATING, APPLYING A PHOSPHATE COATING AND A DRAWING COMPOUND TO THE ZINC COATING, FORMING THE COATED STRIP INTO AN ARTICLE, SUBJECTING THE FORMED ARTICLE TO AN ANODIC ALKALINE CLEANING OPERATION TO REMOVE THE PHOSPHATE COATING AND DRAWING COMPOUND, DISSOLVING OFF IN AN ACID SOLUTION FROM THE FORMED ARTICLE THE ZINC COATING CONTAINING IMPERFECTIONS RESULTING FROM THE FORMING OPERATION, SUBJECTING THE NICKEL COATED FORMED ARTICLE TO AN ANODIC ELECTROPOLISHING OPERATION IN AN ACID AQUEOUS BATH CONTAINING PHOSPHERIC ACID TO REMOVE RESIDUE RESULTING FROM DISSOLVING OFF THE ZINC COATING, SUBJECTING THE NICKEL COATED FORMED ARTICLE TO A CATHODIC ALKALINE CLEANING OPERATION TO ACTIVATE THE NICKEL, CONTACTING THE FORMED ARTICLE WITH AN ACID, AND ELECTROPLATING A NICKEL COATING ON THE FORMED ARTICLE.
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Cited By (12)

* Cited by examiner, † Cited by third party
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US2886499A (en) * 1957-01-07 1959-05-12 Glenn R Schaer Protective metal coatings for molybdenum
US2938841A (en) * 1956-04-13 1960-05-31 Olin Mathieson Preparation of zirconium for cold working
US3183067A (en) * 1961-12-06 1965-05-11 Harshaw Chemcial Company Metal having two coats of sulfurcontaining nickel and method of making same
US3194694A (en) * 1962-06-18 1965-07-13 Satoh Shinzoh Process for surface-treating iron and steel materials to bestow high acid and wear resistivity
US3213008A (en) * 1961-06-14 1965-10-19 Ametek Inc Electrolytic polishing of stainless steel
US3271284A (en) * 1963-10-29 1966-09-06 United States Steel Corp Method of treating galvanized sheet to inhibit staining
US3668090A (en) * 1970-04-20 1972-06-06 United States Steel Corp Method for the electrolytic removal of drawing or rolling lubricants on steel strands
US3719567A (en) * 1970-12-31 1973-03-06 Nippon Telegraph & Telephone Method for producing a contact reed
US4046646A (en) * 1973-09-04 1977-09-06 Miele & Cie Method of galvanizing steel parts
US6146516A (en) * 1995-12-22 2000-11-14 Hueck Engraving Gmbh Method and device for the repair and/or touch-up of small surface flaws in a press plate or an endless band for surface-embossing of plastic-coated wooden or laminated panels
US20060005390A1 (en) * 2004-07-09 2006-01-12 Chin-Tong Wang Method of coating hub and electroplating a portion thereof
EP3162919A1 (en) * 2015-10-29 2017-05-03 GmbH Franz Method for efficient black chromium plating i

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US316600A (en) * 1885-04-28 William heney bbown
US1273506A (en) * 1914-05-16 1918-07-23 Westinghouse Lamp Co Process for the manufacture of wires from refractory materials.
US1597189A (en) * 1921-01-11 1926-08-24 Westinghouse Lamp Co Method of cold-drawing refractory materials
US2206662A (en) * 1938-02-01 1940-07-02 Ibm Fabricating article of beryllium copper
US2293810A (en) * 1938-06-22 1942-08-25 Nat Standard Co Electroplating stainless steel
US2315740A (en) * 1941-06-16 1943-04-06 Standard Steel Spring Co Protected metal article and process of producing the same
US2323890A (en) * 1939-03-31 1943-07-13 Nat Standard Co Coated wire
US2613626A (en) * 1948-07-21 1952-10-14 Heintz Mfg Co Method of cold drawing sheet metal
US2726201A (en) * 1950-08-02 1955-12-06 Int Nickel Co Anodic pickling and nickel plating of tank interior using single electrolyte

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US316600A (en) * 1885-04-28 William heney bbown
US1273506A (en) * 1914-05-16 1918-07-23 Westinghouse Lamp Co Process for the manufacture of wires from refractory materials.
US1597189A (en) * 1921-01-11 1926-08-24 Westinghouse Lamp Co Method of cold-drawing refractory materials
US2206662A (en) * 1938-02-01 1940-07-02 Ibm Fabricating article of beryllium copper
US2293810A (en) * 1938-06-22 1942-08-25 Nat Standard Co Electroplating stainless steel
US2323890A (en) * 1939-03-31 1943-07-13 Nat Standard Co Coated wire
US2315740A (en) * 1941-06-16 1943-04-06 Standard Steel Spring Co Protected metal article and process of producing the same
US2613626A (en) * 1948-07-21 1952-10-14 Heintz Mfg Co Method of cold drawing sheet metal
US2726201A (en) * 1950-08-02 1955-12-06 Int Nickel Co Anodic pickling and nickel plating of tank interior using single electrolyte

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2938841A (en) * 1956-04-13 1960-05-31 Olin Mathieson Preparation of zirconium for cold working
US2886499A (en) * 1957-01-07 1959-05-12 Glenn R Schaer Protective metal coatings for molybdenum
US3213008A (en) * 1961-06-14 1965-10-19 Ametek Inc Electrolytic polishing of stainless steel
US3183067A (en) * 1961-12-06 1965-05-11 Harshaw Chemcial Company Metal having two coats of sulfurcontaining nickel and method of making same
US3194694A (en) * 1962-06-18 1965-07-13 Satoh Shinzoh Process for surface-treating iron and steel materials to bestow high acid and wear resistivity
US3271284A (en) * 1963-10-29 1966-09-06 United States Steel Corp Method of treating galvanized sheet to inhibit staining
US3668090A (en) * 1970-04-20 1972-06-06 United States Steel Corp Method for the electrolytic removal of drawing or rolling lubricants on steel strands
US3719567A (en) * 1970-12-31 1973-03-06 Nippon Telegraph & Telephone Method for producing a contact reed
US4046646A (en) * 1973-09-04 1977-09-06 Miele & Cie Method of galvanizing steel parts
US6146516A (en) * 1995-12-22 2000-11-14 Hueck Engraving Gmbh Method and device for the repair and/or touch-up of small surface flaws in a press plate or an endless band for surface-embossing of plastic-coated wooden or laminated panels
US20060005390A1 (en) * 2004-07-09 2006-01-12 Chin-Tong Wang Method of coating hub and electroplating a portion thereof
EP3162919A1 (en) * 2015-10-29 2017-05-03 GmbH Franz Method for efficient black chromium plating i
WO2017071817A1 (en) * 2015-10-29 2017-05-04 Franz GmbH Method for efficient black chroming i
EP3312307A1 (en) * 2015-10-29 2018-04-25 Franz GmbH Method for efficient black chromium plating i

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