[go: up one dir, main page]

US2773024A - Method for electrolytically pointing wire - Google Patents

Method for electrolytically pointing wire Download PDF

Info

Publication number
US2773024A
US2773024A US421859A US42185954A US2773024A US 2773024 A US2773024 A US 2773024A US 421859 A US421859 A US 421859A US 42185954 A US42185954 A US 42185954A US 2773024 A US2773024 A US 2773024A
Authority
US
United States
Prior art keywords
wire
tube
electrolyte
housing
end portion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US421859A
Inventor
Robert W Gurry
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
United States Steel Corp
Original Assignee
United States Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by United States Steel Corp filed Critical United States Steel Corp
Priority to US421859A priority Critical patent/US2773024A/en
Application granted granted Critical
Publication of US2773024A publication Critical patent/US2773024A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25FPROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
    • C25F3/00Electrolytic etching or polishing
    • C25F3/02Etching

Definitions

  • An object of the invention is to provide an improved apparatus and method which are capable of forming a smooth sharp point by electrolytic means.
  • a further object is to provide an improved apparatus and method for pointing wires in which the taper of the point can be controlled accurately by regulating the current distribution along the length of the 'pointed portion.
  • a more specific object is to provide an improved electrolytic wire pointing apparatus which includes an impervious tube preferably of J-shape for housing the end of a wire within an electrolyte, said tube acting to diminish progressively the current reaching the wire away from its tip. 7
  • Figure 1 is a top plan view of a wire pointing apparatus constructed in accordance with my invention
  • Figure 2 is a vertical section on line IIII of Figure 1;
  • Figure 3 is a fragmentary vertical section on a larger scale of one of the J-shaped tubes.
  • Figure 4 is a view similar to Figure 3, but showing a modification.
  • My apparatus comprises a vessel which contains an electrolyte and a cathode 12.
  • Suitable electrolytes for the purpose are well known; consequently it is believed unnecessary to explain in detail those which can be used.
  • One example of a suitable electrolyte consists of the following:
  • the cathode is a strip of copper gauze which forms a closed loop within the vessel.
  • one or more J-shaped tubes 13 are supported in the vessel 10. These tubes are of a rigid impervious material which is inert to the electrolyte, for example glass. Both ends of the tubes are open. They are supported with their two arms vertical and with their longer arms extending above the electrolyte and their shorter arms fully immersed therein all at the same level.
  • the support means illustrated includes a pair of clamping bars 14, which rest on the upper edges of the vessel walls, and thumb screws 15, which hold the bars together with the tubes between them.
  • successive tubes 13 extend in opposite directions from the bars 14.
  • Wires W for example of hard drawn high carbon steel or stainless steel, can be inserted in the tubes 13, a different wire in each tube.
  • the wires are pushed through the tubes from above and a suflicient length is left pro- "ice truding above the longer arms to enable an electrical connection to be made thereon.
  • the other ends of the wires terminate approximately even with the tops of the shorter arms of the tubes.
  • the straight por tions of these shorter arms contain means for centering a wire therein. This centering means can be either an integral constriction 16 within the tube bore ( Figure 3), or else a separate insert 17 of material inert to the electrolyte ( Figure 4).
  • the cathode 12 is connected to the negative terminal and the wires W to the positive terminal of a suitable source of direct current, for example a six volt storage battery.
  • a suitable source of direct current for example a six volt storage battery.
  • the current density does not appear critical.
  • the configuration of the point can be controlled by selection of a tube having the proper bore diameter, and by adjusting the temperature of the electrolyte. The larger the diameter of the tube bore, the more gradual the taper of the point. For a wire diameter of 0.01 inch, a bore diameter of a little more than a millimeter is satisfactory to produce a smooth gradual taper.
  • the electrolyte temperature be Within the range of to C. At these temperatures a sharp strong point is obtained regardless of the length of time the current is applied. Higher temperatures tend to produce a dull point, and lower temperatures an undesirable fine filament.
  • the J-shaped tubes have the advantage that a thin protective layer of spent electrolyte adjacent the Wires, being more dense than the remainder of the electrolyte, flows down over the Wire away from the tip and protects the wire from electrolytic attack. This spent electrolyte acts in conjunction with the tube to diminish progressively the current which reaches the wire away from the tip. 7
  • a method of forming a point on the end portion of a wire comprising housing the wire within an impervious open-ended tube which is inert to electrolytic action, immersing the tube and wire including the end of the latter in an electrolyte with the end portion of the wire and tube extending vertically upward and the tube housing the entire immersed portion of the wire allowing the electrolyte access to the wire only through the open end, and applying electric current to the wire as an anode and to a cathode surrounding the wire and tube.
  • a method of forming a point on the end portion of a wire comprising housing the wire in a J-shaped impervious open-ended tube which is inert to electrolytic action, the tip of the wire terminating approximately even with the shorter arm of the tube, immersing the tube and wire in an electrolyte with the shorter arm of the tube and the end portion of the wire extending vertically upward and the tube housing the entire immersed portion of the wire allowing the electrolyte access to the Wire only through the open end, and applying electric current to the wire as an anode and to a cathode surrounding the wire and tube.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)

Description

Dec. 4, 1956 R. w. GURRY METHOD FOR ELECTROLYTICALLY POINTING mm Filed April 8, 1954 F IE- Imam.- 05527 if. 61/59): 7
United States Patent Robert W. Gurry, Westfield, N. J., assignor to United States Steel Corporation, a corporation of New Jersey Application April 8, 1954, Serial No. 421,859
2 Claims. (Cl. 204-142) This invention relates to apparatus and methods for forming points on the ends of wires.
An object of the invention is to provide an improved apparatus and method which are capable of forming a smooth sharp point by electrolytic means.
A further object is to provide an improved apparatus and method for pointing wires in which the taper of the point can be controlled accurately by regulating the current distribution along the length of the 'pointed portion.
A more specific object is to provide an improved electrolytic wire pointing apparatus which includes an impervious tube preferably of J-shape for housing the end of a wire within an electrolyte, said tube acting to diminish progressively the current reaching the wire away from its tip. 7
In accomplishing these and other objects of the invention, I have provided improved details of structure, preferred forms of which are shown in the accompanying drawing, in which:
Figure 1 is a top plan view of a wire pointing apparatus constructed in accordance with my invention;
Figure 2 is a vertical section on line IIII of Figure 1;
Figure 3 is a fragmentary vertical section on a larger scale of one of the J-shaped tubes; and
Figure 4 is a view similar to Figure 3, but showing a modification.
My apparatus comprises a vessel which contains an electrolyte and a cathode 12. Suitable electrolytes for the purpose are well known; consequently it is believed unnecessary to explain in detail those which can be used. One example of a suitable electrolyte consists of the following:
Parts by volume Sulfuric acid (sp. gr. 1.84) 34 Orthophosphoric acid (sp. gr. 1.69) 42 Water 24 Nevertheless those familiar with the electroplating art will recognize that many equivalents are possible. Preferably the cathode is a strip of copper gauze which forms a closed loop within the vessel.
In accordance with my invention, one or more J-shaped tubes 13 are supported in the vessel 10. These tubes are of a rigid impervious material which is inert to the electrolyte, for example glass. Both ends of the tubes are open. They are supported with their two arms vertical and with their longer arms extending above the electrolyte and their shorter arms fully immersed therein all at the same level. The support means illustrated includes a pair of clamping bars 14, which rest on the upper edges of the vessel walls, and thumb screws 15, which hold the bars together with the tubes between them. Preferably successive tubes 13 extend in opposite directions from the bars 14.
Wires W, for example of hard drawn high carbon steel or stainless steel, can be inserted in the tubes 13, a different wire in each tube. The wires are pushed through the tubes from above and a suflicient length is left pro- "ice truding above the longer arms to enable an electrical connection to be made thereon. The other ends of the wires terminate approximately even with the tops of the shorter arms of the tubes. Preferably the straight por tions of these shorter arms contain means for centering a wire therein. This centering means can be either an integral constriction 16 within the tube bore (Figure 3), or else a separate insert 17 of material inert to the electrolyte (Figure 4).
The cathode 12 is connected to the negative terminal and the wires W to the positive terminal of a suitable source of direct current, for example a six volt storage battery. The current density does not appear critical. The configuration of the point can be controlled by selection of a tube having the proper bore diameter, and by adjusting the temperature of the electrolyte. The larger the diameter of the tube bore, the more gradual the taper of the point. For a wire diameter of 0.01 inch, a bore diameter of a little more than a millimeter is satisfactory to produce a smooth gradual taper. I prefer that the electrolyte temperature be Within the range of to C. At these temperatures a sharp strong point is obtained regardless of the length of time the current is applied. Higher temperatures tend to produce a dull point, and lower temperatures an undesirable fine filament. The J-shaped tubes have the advantage that a thin protective layer of spent electrolyte adjacent the Wires, being more dense than the remainder of the electrolyte, flows down over the Wire away from the tip and protects the wire from electrolytic attack. This spent electrolyte acts in conjunction with the tube to diminish progressively the current which reaches the wire away from the tip. 7
While I have shown and described certain preferred embodiments of the invention, it is apparent that other modifications may arise. Therefore, I do not Wish to be limited to the disclosure set forth but only by the scope of the appended claims.
I claim:
1. A method of forming a point on the end portion of a wire comprising housing the wire within an impervious open-ended tube which is inert to electrolytic action, immersing the tube and wire including the end of the latter in an electrolyte with the end portion of the wire and tube extending vertically upward and the tube housing the entire immersed portion of the wire allowing the electrolyte access to the wire only through the open end, and applying electric current to the wire as an anode and to a cathode surrounding the wire and tube.
2. A method of forming a point on the end portion of a wire comprising housing the wire in a J-shaped impervious open-ended tube which is inert to electrolytic action, the tip of the wire terminating approximately even with the shorter arm of the tube, immersing the tube and wire in an electrolyte with the shorter arm of the tube and the end portion of the wire extending vertically upward and the tube housing the entire immersed portion of the wire allowing the electrolyte access to the Wire only through the open end, and applying electric current to the wire as an anode and to a cathode surrounding the wire and tube.
References Cited in the file of this patent UNITED STATES PATENTS 711,565 Harris Oct. 21, 1902 1,861,446 Maag June 7, 1932 1,992,310 Hultman Feb. 26, 1935 2,721,838 Visser Oct. 25, 1955 FOREIGN PATENTS 763,863 France Feb. 19, 1934

Claims (1)

  1. 2. A METHOD OF FORMING A POINT ON THE END PORTION OF A WIRE COMPRISING HOUSING THE WIRE IN A J-SHAPED IMPERVIOUS OPEN-ENDED TUBE WHICH IS INERT TO ELECTROLYTIC ACTION, THE TIP OF THE WIRE TERMINATING APPROXIMATELY EVEN WITH THE SHORTER ARM OF THE TUBE, IMMERSING THE TUBE AND WIRE IN AN ELECTROLYTE WITH THE SHORTER ARM OF THE TUBE AND THE END PORTION OF THE WIRE EXTENDING VERTICALLY UPWARD AND THE TUBE HOUSING THE ENTIRE IMMERSED PORTION OF THE WIRE ALLOWING THE ELECTROLYTE ACCESS TO THE WIRE ONLY THROUGH THE OPEN END, AND APPLYING ELECTRIC CURRENT TO THE WIRE AS AN ANODE AND TO A CATHODE SURROUNDING THE WIRE AND TUBE.
US421859A 1954-04-08 1954-04-08 Method for electrolytically pointing wire Expired - Lifetime US2773024A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US421859A US2773024A (en) 1954-04-08 1954-04-08 Method for electrolytically pointing wire

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US421859A US2773024A (en) 1954-04-08 1954-04-08 Method for electrolytically pointing wire

Publications (1)

Publication Number Publication Date
US2773024A true US2773024A (en) 1956-12-04

Family

ID=23672348

Family Applications (1)

Application Number Title Priority Date Filing Date
US421859A Expired - Lifetime US2773024A (en) 1954-04-08 1954-04-08 Method for electrolytically pointing wire

Country Status (1)

Country Link
US (1) US2773024A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3038475A (en) * 1960-06-27 1962-06-12 American Cyanamid Co Surgical needles and manufacture of same
US5145564A (en) * 1990-03-08 1992-09-08 Forschungszentrum Julich Gmbh Method of and apparatus for producing electrically-conductive probe tips
US6007694A (en) * 1998-04-07 1999-12-28 Phillips Plastics Corporation Electrochemical machining

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US711565A (en) * 1902-06-05 1902-10-21 Joseph W Harris Manufacture of ether.
US1861446A (en) * 1927-04-04 1932-06-07 Timken Roller Bearing Co Process of electroplating
FR763863A (en) * 1933-02-02 1934-05-08 Method and device for obtaining localized galvanic deposits
US1992310A (en) * 1933-05-17 1935-02-26 Hultman & Powell Corp Process for treating hydrocarbons
US2721838A (en) * 1950-10-28 1955-10-25 Hartford Nat Bank & Trust Co Method of electrolytically pointing wires

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US711565A (en) * 1902-06-05 1902-10-21 Joseph W Harris Manufacture of ether.
US1861446A (en) * 1927-04-04 1932-06-07 Timken Roller Bearing Co Process of electroplating
FR763863A (en) * 1933-02-02 1934-05-08 Method and device for obtaining localized galvanic deposits
US1992310A (en) * 1933-05-17 1935-02-26 Hultman & Powell Corp Process for treating hydrocarbons
US2721838A (en) * 1950-10-28 1955-10-25 Hartford Nat Bank & Trust Co Method of electrolytically pointing wires

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3038475A (en) * 1960-06-27 1962-06-12 American Cyanamid Co Surgical needles and manufacture of same
US5145564A (en) * 1990-03-08 1992-09-08 Forschungszentrum Julich Gmbh Method of and apparatus for producing electrically-conductive probe tips
US6007694A (en) * 1998-04-07 1999-12-28 Phillips Plastics Corporation Electrochemical machining

Similar Documents

Publication Publication Date Title
Grundfest et al. Stainless steel micro‐needle electrodes made by electrolytic pointing
US4420367A (en) Method for etching a recrystallized aluminum foil for electrolytic capacitors
JPS54138625A (en) Electrolytic treatment of the surface of carbon fibers and electrolytic cell therefor
US2773024A (en) Method for electrolytically pointing wire
GB1087256A (en) Process and apparatus for anodizing aluminium
US3203879A (en) Method for preparing positive electrodes
US2953507A (en) Method for electrolytic thickness reduction of metal wires
CN212955432U (en) Electrolytic polishing device for EBSD sample of metal material
US2492206A (en) Lead perchloric acid primary cell
US4540476A (en) Procedure for making nickel electrodes
US3376210A (en) Process and apparatus for electroplating annular bodies
Maget et al. The electrochemical reduction of oxygen on platinum electrodes partially immersed in sulfuric acid
CN206799764U (en) Rare earth molten-salt electrolysis device
SE7604728L (en) SODIUM ELECTROCHEMICAL CELL
JPS57101692A (en) Horizontal electroplating method by insoluble electrode
US2725353A (en) Electropolishing metallic articles
US3684480A (en) Nickel fibers useful for galvanic cell electrodes
JP3158684B2 (en) Copper electrorefining method
CN217973448U (en) Carbon fiber surface treatment device
US3635805A (en) Working of metal bodies
CN219731088U (en) An electroplated metal wire production device
JPS56139689A (en) Production of electrolytic copper foil
SU126270A1 (en) Electrochemical production of indium, tin, lead and indium-gallium alloy
GB1519600A (en) Electrolytic cells and electrodeposition methods
US6139711A (en) Hydrodynamically controlled hull cell and method of use