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US2596377A - Surface covering materials - Google Patents

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US2596377A
US2596377A US13485A US1348548A US2596377A US 2596377 A US2596377 A US 2596377A US 13485 A US13485 A US 13485A US 1348548 A US1348548 A US 1348548A US 2596377 A US2596377 A US 2596377A
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sheet
areas
embossed
sizing
adhesive
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US13485A
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Derman Harry
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/21Paper; Textile fabrics
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00Presence of inorganic and organic materials
    • C09J2400/20Presence of organic materials
    • C09J2400/26Presence of textile or fabric
    • C09J2400/263Presence of textile or fabric in the substrate
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/907Resistant against plant or animal attack
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24628Nonplanar uniform thickness material
    • Y10T428/24669Aligned or parallel nonplanarities
    • Y10T428/24678Waffle-form

Definitions

  • This invention relates to surface covering materials used in covering walls, ceilings and other surfaces. More particularly, the invention deals with materials of this type and kind which are embossed so as to present, on the rear surface of the sheet material, high-spots characterized by the border of the embossing. Still more particularly, the invention deals With sheet material of the character described employing a suitable adhesive or other sizing on the high-spots only of the lower or back surface of the sheet and, wherein, the upper or front surface of the sheet is coated with a plastic protective filmto render the same water repellent.
  • Fig. l is a diagrammatic view of the upper or front surface of the sheet indicating part of the embossing thereon and showing one corner of the sheet turned to render part of the back surface visible.
  • Fig. 2 is an enlarged section taken through the sheet on the line 2--2 of Fig. 1 and omitting all background illustrations;
  • Fig. 3 is a view similar to Fig. 2 with the section taken on the line 33 of Fig. l.
  • the distinctive feature of my invention resides in applying to the back surface of the sheet an adhesive or sizing covering only part of the area of the sheet, so as to minimize contact engagement of the sheet with the supporting surface and, particularly, in attaching what is known as embossed sheets to a surface, in which event, the adhesive or sizing is applied to the raised areas which are disposed on the rear or back surface of the sheet.
  • a thin film-like coating 14 is.de.- posited on the upper or front surface of the sheet ID, in other words, the surface to which the decorative printing or coating is applied.
  • This film-like deposit is sprayed upon the surface of the sheet by any number of spraying operations, depending upon the degree of deposit to be formed and the protective film I4 is preferably of a plastic-type including, for example, ethyl cellulose; toluol; aryle sulfonamide formaldehyde; nomilamine resin; dibutyl phathalate; and ethyl alcohol in suitab'le proportions to provide a spraying solution.
  • the embossed square sections ll form, where they join the rounded knob members l3, raised'portions H) on the back surface of the sheet IOand, in like manner, where the embossed portions H join the bars or ribs I2, similar raised portions 16' are formed.
  • These raised portions l5 and 16 are coatedwith a suitable adhesive or sizing, as seen at H. Thesizing is. applied to the raised portions by passing the sheetover an applicator cylinder, or. the like, so asto be assured that substantially the high-spots only of the sheet are coated.
  • This type of covering will produce on walls or ceilings an insulation as against transmission of sound or sound vibrations, in other words, it will be suitable in control and regulation of acoustics.
  • the spasmodic or wide spreading deposit of the adhesive on the back of the sheet is employed by passing the sheet over a drum or the like having a pattern surface characterizing the deposit of the adhesive or sizing on the sheet; in other words, somewhat in the form of a printing cylinder.
  • the adhesion of the sheet to the surface will be localized thus leaving unadhered areas on the sheet, which, in drying, will produce slightly extended sections or areas which would be somewhat equivalent to the embossing heretofore referred to.
  • the fiat surface sheet there will be some degree of spreading of the adhesive in application of moisture to the back surface of the sheet.
  • the greater amount of adhesive or sizing will be localized on the sheet to establish greater adhesions of these particularareas orsections of the sheet.
  • the sheet may be used as a wall, ceiling or other surface covering and, in some of such instances, the application of the waterproof film coating need not always be employed. However, it is desirable to use this coating, particularly where washing and the cleaning of the walls is desirable. I have always found 'my improved sheet material practical for use in lining closets, particularly closets used for preparation comprising three parts of tapioca dextrin, one part natural gum and one part of water produces very desirable results. However, the type and kind of adhesive sizing may be varied to suit different conditions or uses.
  • the entire inner or back surface of the sheet I0 may be covered with water in the preparation of the sheet for attachment to a wall. This would eliminate the care of applying moisture only to the adhered or sized areas and any spreading of the adhesive or sizing on an embossed paper would not be detrimental to maintaining the otherwise effective embossed characteristics thereof. I have found, in practice, that pressure can be applied to the surface of the paper to insure complete contact of all of the sized or gummed areas with the supporting surface and without injury to or destruction to the embossed characteristics of the sheet.
  • the front or characterized surface of the sheet may be of a plain color throughout the entire area thereof or the colored sheet may also include patterns or designs of any type or kind. However, in the accompanying drawing, a plain sheet is shown and no attempt is made to illustrate in Figs. 2 and 3 the print or coloring of the surface.
  • the sheet After the sheet has been prepared, the same is embossed and, after embossing the sheet, it is then sprayed for the protective coating on the front, printed or characterized surface thereof, after which the adhesive or sizing is applied to sectional areas of the back of the sheet in the manner stated above. After this, the sheet may be rolled up and packaged in suitable lengths for shipment and sale.
  • the square embossings be arranged diagthe storageof clothing.
  • my improved surface covering material comprises a new method which consists in adhering the back surface of the material to the supporting surface at pre-controlled sections or areas which are materially less than the total area of the sheet and, more particularly, in arranging the adhesion areas to form a multiplicity of completely surrounded unadhered sections, thus forming, on the resulting surface, a multiplicity of air pockets. This may be further described, particularly with respect to flat, unembossed sheet as areas or sections capable of free expansion and contraction.
  • my improved method comprises th use of a plastic film coating on the front surface of the sheet rendering the same moistureproof and, further, insulating the surface from a standpoint of exposure to damp atmospheric conditions. It will be understood that, by applying the sizing to limited areas only of the back surface of the sheet, a material saving is effected in the production of pre-sized sheets of the kind under consideration.
  • the sizing being deposited on the back surface of the sheet in intersecting sections, said sections intermediate pairs of aligned intersections being widely spaced one with respect to the other to form on the back of the sheet relatively large unsized areas throughout the width and length of the sheet, the deposit of the sizing on said sheet being such as to completely envelope substantially all of the unsized areas of the sheet, and the unsized areas of the sheet being embossed.
  • the sizing being deposited on the back surface of the sheet in intersecting sections, said sections intermediate pairs of aligned inter sections being widely spaced one with respect to the other to form on the back of the sheet relatively large unsized areas throughout the width and length of the sheet, the deposit of the sizing on said sheet being such as to completely envelope substantially all of the unsized areas of the sheet, the unsized areas of the sheet being embossed, and other smaller areas of the sheet, between portions of said first named areas, bein embossed. and unsized.
  • the sizing being deposited on the back surface of the sheet in intersecting sections, said sections intermediate pairs of aligned intersections being widely spaced one with respect to the other to form on the back of the sheet relatively large unsized areas throughout the width and length of the sheet, the deposit of the sizing on said sheet being such as to completely envelope substantially all of the unsized areas of the sheet, the unsized areas of the sheet being embossed, other smaller areas of the sheet, between portions of said first named areas, being embossed and unsized, and other areas of the sheet having, in alinement with the sizing thereon, other embossed and sized areas.
  • a surface covering paper sheet of the class described comprising embossings extending over the entire areas of th sheet and forming, on the back surface of the sheet, raised intersecting surfaces intermediate embossings on the sheet, an adhesive coating applied and secured to all of the raised areas on the back of the sheet, leaving the major portion of the embossed areas free of said adhesive coating.
  • a surface covering paper sheet of the class described comprising embossings extending over the entire areas of th sheet and forming, on the back surface of the sheet, raised intersecting surfaces intermediate embossings on the sheet, an adhesive coating applied and secured to all of the raised areas on the back of the sheet, leaving the major portion of the embossed areas free of said adhesive coating, and the front and characterized surface of the sheet having a plastic film coating thereon.
  • a surface covering paper sheet of the class described comprising embossings extending over the entire areas of the sheet and forming, on the back surface of the sheet, raised intersecting surfaces intermediate embossings on the sheet, an adhesive coating applied and secured to all of the raised areas on the back of the sheet, leaving the major portion of th embossed areas free of said adhesive coating, the front and characterized surface of the sheet having a plastic film coating thereon, said coating including an insecticide.
  • a surface covering paper sheet of the class described comprising embossings extending over the entire areas of the sheet and forming, on the back surface of the sheet, raised intersecting surfaces intermediate embossings on the sheet, an adhesive coating applied and secured to all of the raised areas on the back of the sheet, leaving the major portion of the embossed areas free of said adhesive coating, the front and characterized surface of the sheet having a plastic film. coating thereon, said coating including an insecticide, such for example as dichlor diphenyl trichlorethane.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Paper (AREA)

Description

y 1952 H. DERMAN 2,596,377
SURFACE COVERING MATERIALS Filed March 6, 1948 INVENTOR HARFJY DERMAN ATTORNE Patented May 13, 1952 UNITED STATES PATENT OFFICE SURFACE COVERING MATERIALS Harry Derman, Great Neck, Y. Application March 6, 1948, Serial No. 13,485
' 7 (llaiins. (o1. iii-1i) This invention relates to surface covering materials used in covering walls, ceilings and other surfaces. More particularly, the invention deals with materials of this type and kind which are embossed so as to present, on the rear surface of the sheet material, high-spots characterized by the border of the embossing. Still more particularly, the invention deals With sheet material of the character described employing a suitable adhesive or other sizing on the high-spots only of the lower or back surface of the sheet and, wherein, the upper or front surface of the sheet is coated with a plastic protective filmto render the same water repellent.
The novel features of the invention will be best understood from the following description, when taken together with the accompanying drawing, in which certain embodiments of the invention are disclosed and, in which, the separate parts are designated by suitable reference characters in each of the views and, in which:
Fig. l is a diagrammatic view of the upper or front surface of the sheet indicating part of the embossing thereon and showing one corner of the sheet turned to render part of the back surface visible.
Fig. 2 is an enlarged section taken through the sheet on the line 2--2 of Fig. 1 and omitting all background illustrations; and
Fig. 3 is a view similar to Fig. 2 with the section taken on the line 33 of Fig. l.
In surface covering materials of the type and kind under consideration, it is known to provide, on the rear or back surface of the sheet, a coating covering the entire surface to form an adhesive or sizing for adhering the sheet to a support. Further, it has been known to provide, on the front or printed surface of the sheet, a protective coating such, for example, as varnish.
The distinctive feature of my invention resides in applying to the back surface of the sheet an adhesive or sizing covering only part of the area of the sheet, so as to minimize contact engagement of the sheet with the supporting surface and, particularly, in attaching what is known as embossed sheets to a surface, in which event, the adhesive or sizing is applied to the raised areas which are disposed on the rear or back surface of the sheet.
In illustrating one adaptation and use of my invention, I have shown, in the accompanying drawing, a sheet of paper or other suitable material embossed to form a series of square raised or embossed portions ll, bordered by slightly raised bar portions II, which intersect in raised, rounded or knob-like members l3 dis-. posed at cornerportions of the squares! l. The squares ll have a greater embossing. depth. than the rounded members or knobs [3, as will clearly appear from a consideration of Fig. 2 or the drawing; whereas, the ribs or bars l2 have a still lesser degreeof embossing than the members l3, as will appear from a consideration of Fig. 3. of the drawing. As clearly seen in Figs. 2.. and 3 of the drawing, a thin film-like coating 14 is.de.- posited on the upper or front surface of the sheet ID, in other words, the surface to which the decorative printing or coating is applied. This film-like deposit is sprayed upon the surface of the sheet by any number of spraying operations, depending upon the degree of deposit to be formed and the protective film I4 is preferably of a plastic-type including, for example, ethyl cellulose; toluol; aryle sulfonamide formaldehyde; nomilamine resin; dibutyl phathalate; and ethyl alcohol in suitab'le proportions to provide a spraying solution. In usual practice, I find that one or two spraying applications is ample for average surface covering materials but,-in other instances, additional coatings canbe provided. These coating materials maintain the soft and pliable char acteristics to the material while, at the same time, render the surface water repellent;thus, the front surface of the paper can be washed for cleaning purposes.
Considering Fig. 2 of the drawing, it will appear that the embossed square sections ll form, where they join the rounded knob members l3, raised'portions H) on the back surface of the sheet IOand, in like manner, where the embossed portions H join the bars or ribs I2, similar raised portions 16' are formed. These raised portions l5 and 16 are coatedwith a suitable adhesive or sizing, as seen at H. Thesizing is. applied to the raised portions by passing the sheetover an applicator cylinder, or. the like, so asto be assured that substantially the high-spots only of the sheet are coated. However, in the process of drying, a slight amountof the adhesive or sizing will extend onto parts of the raised or embossed portions, as is indicated, for example, at IT inFig. 2 and atil in Fig. 3. The spreading of the adhesive or sizing I! will be sufficient to cover the surface of theshallow eimbossings 12, but not sufficient to cover the raised members I3, thus. leaving the center portion of the members l3 uncovered, as is seen at [8 in Fig.2 of the drawing and also noted on the upturned corner of the sheet, as seen in Fig. 1.
From the foregoing, it will be apparent that a 3 surface covering sheet of the pre-glued or presized type is employed and the same will be distributed and sold on this basis, so that the consumer or ultimate user of the sheet will only have to apply moisture to the high-spots or areas [5, I6 coated with the glue or sizing IT. This may be done by a moist brush, cloth, sponge or the like. If, in this operation, some of the glue spreads to the other areas of the sheet, this is not objectionable as adhesion to the surface would be primarily established at the high points or sections of the embossed sheet. It will thus be apparent that, after the sheet has been secured to the wall and the adhesive or sizing dryed, the embossed portions will stand out from the surface producing a very attractive appearance and, at the same time, a more or less cushioned wall covering material will be provided, in that air will be pocketed or housed within the embossed sections or areas of the sheet, particularly the sections or areas H and l3. 7
This type of covering will produce on walls or ceilings an insulation as against transmission of sound or sound vibrations, in other words, it will be suitable in control and regulation of acoustics.
In other uses of my invention and. where the question of' pie-embossing of the sheet is not desirable, the spasmodic or wide spreading deposit of the adhesive on the back of the sheet is employed by passing the sheet over a drum or the like having a pattern surface characterizing the deposit of the adhesive or sizing on the sheet; in other words, somewhat in the form of a printing cylinder. In such instances, the adhesion of the sheet to the surface will be localized thus leaving unadhered areas on the sheet, which, in drying, will produce slightly extended sections or areas which would be somewhat equivalent to the embossing heretofore referred to. However, in the fiat surface sheet, there will be some degree of spreading of the adhesive in application of moisture to the back surface of the sheet. However, in all instances, the greater amount of adhesive or sizing will be localized on the sheet to establish greater adhesions of these particularareas orsections of the sheet.
- Aside from uses of the sheet material as hereinbefore mentioned, the sheet may be used as a wall, ceiling or other surface covering and, in some of such instances, the application of the waterproof film coating need not always be employed. However, it is desirable to use this coating, particularly where washing and the cleaning of the walls is desirable. I have always found 'my improved sheet material practical for use in lining closets, particularly closets used for preparation comprising three parts of tapioca dextrin, one part natural gum and one part of water produces very desirable results. However, the type and kind of adhesive sizing may be varied to suit different conditions or uses.
As indicated above, it will be understood that the entire inner or back surface of the sheet I0 may be covered with water in the preparation of the sheet for attachment to a wall. This would eliminate the care of applying moisture only to the adhered or sized areas and any spreading of the adhesive or sizing on an embossed paper would not be detrimental to maintaining the otherwise effective embossed characteristics thereof. I have found, in practice, that pressure can be applied to the surface of the paper to insure complete contact of all of the sized or gummed areas with the supporting surface and without injury to or destruction to the embossed characteristics of the sheet.
The front or characterized surface of the sheet may be of a plain color throughout the entire area thereof or the colored sheet may also include patterns or designs of any type or kind. However, in the accompanying drawing, a plain sheet is shown and no attempt is made to illustrate in Figs. 2 and 3 the print or coloring of the surface. After the sheet has been prepared, the same is embossed and, after embossing the sheet, it is then sprayed for the protective coating on the front, printed or characterized surface thereof, after which the adhesive or sizing is applied to sectional areas of the back of the sheet in the manner stated above. After this, the sheet may be rolled up and packaged in suitable lengths for shipment and sale.
In the present construction, it is preferred that the square embossings be arranged diagthe storageof clothing. In such instances, I
combined with the plastic spray used on the front or printed surface of the sheet suitable proportions of dichlor diphenyl trichlorethane, commonly referred to as D. D. T., which are placed in the spraying solution and sprayed in the application of the waterproof coating. This will afford added utility to the sheet material, particularly in rendering the walls of a closet protective against moths and other insects, thereby adding protection to the garments arranged in the closet. With the plastic ingredient, heretofore mentioned, in the following proportions; i. e., ethyl cellulose 58 lbs.; toluol 18 gallons; aryle sulfonamide formaldehylde 7 lbs.; nomilamine resin 9 lbs.; dibutyl phthalate 19 lbs.; ethyl alcohol 72 gallons, I add substantially 26 lbs. of dichlor diphenyl trichlorethane.
For the adhesive or sizing, I have found that a onally on the sheet; that is to say, in diamond formation with the embossed bars or ribs extending at to each other and 45 to the edges of the sheet. However, any type or kind of embossings can be employed.
It will be apparent that the use of my improved surface covering material comprises a new method which consists in adhering the back surface of the material to the supporting surface at pre-controlled sections or areas which are materially less than the total area of the sheet and, more particularly, in arranging the adhesion areas to form a multiplicity of completely surrounded unadhered sections, thus forming, on the resulting surface, a multiplicity of air pockets. This may be further described, particularly with respect to flat, unembossed sheet as areas or sections capable of free expansion and contraction.
Still further, my improved method comprises th use of a plastic film coating on the front surface of the sheet rendering the same moistureproof and, further, insulating the surface from a standpoint of exposure to damp atmospheric conditions. It will be understood that, by applying the sizing to limited areas only of the back surface of the sheet, a material saving is effected in the production of pre-sized sheets of the kind under consideration.
Having fully described my invention, what I claim as new and desire to secure by Letters Patent is:
1. In surface covering paper materials having pre-sized back surfaces for attachment to a supporting surface, the sizing being deposited on the back surface of the sheet in intersecting sections, said sections intermediate pairs of aligned intersections being widely spaced one with respect to the other to form on the back of the sheet relatively large unsized areas throughout the width and length of the sheet, the deposit of the sizing on said sheet being such as to completely envelope substantially all of the unsized areas of the sheet, and the unsized areas of the sheet being embossed.
2. In surface covering paper materials having pre-sized back surfaces for attachment to a supporting surface, the sizing being deposited on the back surface of the sheet in intersecting sections, said sections intermediate pairs of aligned inter sections being widely spaced one with respect to the other to form on the back of the sheet relatively large unsized areas throughout the width and length of the sheet, the deposit of the sizing on said sheet being such as to completely envelope substantially all of the unsized areas of the sheet, the unsized areas of the sheet being embossed, and other smaller areas of the sheet, between portions of said first named areas, bein embossed. and unsized.
3. In surface covering paper materials having pre-sized back surfaces for attachment to a supporting surface, the sizing being deposited on the back surface of the sheet in intersecting sections, said sections intermediate pairs of aligned intersections being widely spaced one with respect to the other to form on the back of the sheet relatively large unsized areas throughout the width and length of the sheet, the deposit of the sizing on said sheet being such as to completely envelope substantially all of the unsized areas of the sheet, the unsized areas of the sheet being embossed, other smaller areas of the sheet, between portions of said first named areas, being embossed and unsized, and other areas of the sheet having, in alinement with the sizing thereon, other embossed and sized areas.
4. A surface covering paper sheet of the class described comprising embossings extending over the entire areas of th sheet and forming, on the back surface of the sheet, raised intersecting surfaces intermediate embossings on the sheet, an adhesive coating applied and secured to all of the raised areas on the back of the sheet, leaving the major portion of the embossed areas free of said adhesive coating.
5. A surface covering paper sheet of the class described comprising embossings extending over the entire areas of th sheet and forming, on the back surface of the sheet, raised intersecting surfaces intermediate embossings on the sheet, an adhesive coating applied and secured to all of the raised areas on the back of the sheet, leaving the major portion of the embossed areas free of said adhesive coating, and the front and characterized surface of the sheet having a plastic film coating thereon.
6. A surface covering paper sheet of the class described comprising embossings extending over the entire areas of the sheet and forming, on the back surface of the sheet, raised intersecting surfaces intermediate embossings on the sheet, an adhesive coating applied and secured to all of the raised areas on the back of the sheet, leaving the major portion of th embossed areas free of said adhesive coating, the front and characterized surface of the sheet having a plastic film coating thereon, said coating including an insecticide.
'7. A surface covering paper sheet of the class described comprising embossings extending over the entire areas of the sheet and forming, on the back surface of the sheet, raised intersecting surfaces intermediate embossings on the sheet, an adhesive coating applied and secured to all of the raised areas on the back of the sheet, leaving the major portion of the embossed areas free of said adhesive coating, the front and characterized surface of the sheet having a plastic film. coating thereon, said coating including an insecticide, such for example as dichlor diphenyl trichlorethane.
HARRY DERMAN.
REFERENCES CITED The following references are of record in the file of this patent:
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2667436A (en) * 1950-09-21 1954-01-26 Carborundum Co Pressure sensitive adhesive coated sheet material
US3346411A (en) * 1964-01-22 1967-10-10 Leonard J O'dell Method of forming an artistic relief
US3399101A (en) * 1964-08-11 1968-08-27 Eugene A. Magid Valley printing effects and method of producing same
US4243703A (en) * 1976-04-01 1981-01-06 Montedison S.P.A. Pesticide-containing plastic coverings for agricultural cultivations, and process for obtaining said coverings and for protecting the cultivations from infestant pests
US20030126793A1 (en) * 1997-07-07 2003-07-10 Weder Donald E. Decorative wrapper for a floral grouping formed of a sheet of material having printed and embossed patterns thereon

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US366286A (en) * 1887-07-12 Ornamentation of sheet metal
US1002132A (en) * 1911-01-11 1911-08-29 M A Brown Paper Box Company Reticulated-sheet packing material.
US1819041A (en) * 1926-09-20 1931-08-18 Brown Co Paper towel and the like
US2122251A (en) * 1937-11-18 1938-06-28 Hartmann Inc Method of securing decorative effects on leather or similar goods
US2247252A (en) * 1937-08-11 1941-06-24 Charles S Price Manufacture of seals and the like
US2264628A (en) * 1939-08-03 1941-12-02 Poster Products Inc Advertising material
US2311589A (en) * 1941-06-26 1943-02-16 Barclay Mfg Co Inc Method of making scored wallboard

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US366286A (en) * 1887-07-12 Ornamentation of sheet metal
US1002132A (en) * 1911-01-11 1911-08-29 M A Brown Paper Box Company Reticulated-sheet packing material.
US1819041A (en) * 1926-09-20 1931-08-18 Brown Co Paper towel and the like
US2247252A (en) * 1937-08-11 1941-06-24 Charles S Price Manufacture of seals and the like
US2122251A (en) * 1937-11-18 1938-06-28 Hartmann Inc Method of securing decorative effects on leather or similar goods
US2264628A (en) * 1939-08-03 1941-12-02 Poster Products Inc Advertising material
US2311589A (en) * 1941-06-26 1943-02-16 Barclay Mfg Co Inc Method of making scored wallboard

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2667436A (en) * 1950-09-21 1954-01-26 Carborundum Co Pressure sensitive adhesive coated sheet material
US3346411A (en) * 1964-01-22 1967-10-10 Leonard J O'dell Method of forming an artistic relief
US3399101A (en) * 1964-08-11 1968-08-27 Eugene A. Magid Valley printing effects and method of producing same
US4243703A (en) * 1976-04-01 1981-01-06 Montedison S.P.A. Pesticide-containing plastic coverings for agricultural cultivations, and process for obtaining said coverings and for protecting the cultivations from infestant pests
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