US2591481A - Spongious cleaning device - Google Patents
Spongious cleaning device Download PDFInfo
- Publication number
- US2591481A US2591481A US2591481DA US2591481A US 2591481 A US2591481 A US 2591481A US 2591481D A US2591481D A US 2591481DA US 2591481 A US2591481 A US 2591481A
- Authority
- US
- United States
- Prior art keywords
- cleaning device
- spongious
- detergent
- water
- sponge
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004140 cleaning Methods 0.000 title claims description 18
- 239000003599 detergent Substances 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000007787 solid Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 4
- 239000000271 synthetic detergent Substances 0.000 description 4
- 239000004753 textile Substances 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 239000004141 Sodium laurylsulphate Substances 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 239000004627 regenerated cellulose Substances 0.000 description 2
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- -1 Sodium alkyl benzene Chemical class 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000005108 dry cleaning Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 150000002888 oleic acid derivatives Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000019983 sodium metaphosphate Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- GGHPAKFFUZUEKL-UHFFFAOYSA-M sodium;hexadecyl sulfate Chemical compound [Na+].CCCCCCCCCCCCCCCCOS([O-])(=O)=O GGHPAKFFUZUEKL-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/049—Cleaning or scouring pads; Wipes
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
- A47K7/00—Body washing or cleaning implements
- A47K7/02—Bathing sponges, brushes, gloves, or similar cleaning or rubbing implements
- A47K7/03—Bathing sponges, brushes, gloves, or similar cleaning or rubbing implements containing soap or other cleaning ingredients, e.g. impregnated
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0208—Tissues; Wipes; Patches
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/06—Inorganic compounds
- C11D9/08—Water-soluble compounds
- C11D9/10—Salts
- C11D9/14—Phosphates; Polyphosphates
Definitions
- the present invention relates to a cleaning device particularly adapted for the removal of spots and stains from articles of clothing.
- One object of my invention is to provide a cleaning device which has a self-contained supply of a suitable detergent.
- a second object of the invention is the provision of a cleaning device which is made ready for use simply by moistening with water.
- my invention contemplates the impregnation of a spongious body with a substantially anhydrous synthetic detergent, which, upon the addition of water, will be activated to provide a highly efficient cleansing medium.
- the spongious body can be either a portion of a natural sponge or a section of a regenerated cellulose or cellulated rubber sponge.
- the synthetic sponge material for the communicating cell structure thereof is more uniform than can ever be found in a nat- 4 ural sponge and in addition the synthetic material lends itself more favorably to the formation of small, regular sections most suitable for packaging and handling.
- the detergent employed in the cleaning device be selected from those which when contacted with water and aerated develop a heavy froth of bubbles or suds.
- One group of synthetic detergents possessing this property is that consisting of sodium lauryl sulphate and its higher homologues including sodium cetyl sulphate together with the oleic and stearic acid esters. Similarly, a mixture of the esters formed from the higher acids produced by the oxidation of petroleum fractions can be included within this group.
- Sodium alkyl benzene sulfonate and other analogous organic sulfonates are further examples of desirable detergents. This class of detergents is also marked by its freedom from curd-forming characteristics.
- the spongious body of any desired size and shape is impregnated with the synthetic detergent by immersion in a, water solution thereof, accompanied by repeated compression of the spongious medium, and is thereafter dried.
- the amount of detergent remaining within the cellulated structure will, of course, depend upon the concentration of the detergent solution used for impregnation. For most purposes a solu tion containing from 2-12% of detergent will permit the absorption of sufiicient liquid to leave from 55-10% by weight of solids within the spongious body. However, as little as 1% by weight of solids or as much as 15% by weight of solids will yield serviceable cleaners. Considerations of weight and cost are really the only limiting factors in determining the amount of detergent to be added to the spongious body.
- a detergent aid or water softener for example, a sodium phosphate such as sodium metaphosphate or tetra sodium pyrophosphate, will assist in the cleaning action. A large amount of the phosphate additive is not necessary. I have found that from A; to 3% of the phosphate is sufficient for most purposes.
- the treated sponge In service the treated sponge is moistened with water and flexed several times to develop a dense froth or foam of small bubbles upon its surface. The bubbles are applied to the soiled area of the textile and brushed thereover until they disappear. The bubbles liftthe dirt from the textile and transfer it to the cleaner.
- the damp sponge may be allowed to dry and in any case is immediately ready for the next cleaning task. Where it is intended to be carried in a pocket or purse, a waterproof envelope may be provided into which container the damp sponge may be placed immediately after use.
- a cleaning device as contemplated by this invention can be used repeatedly before the detergent supply is exhausted.
- a regenerated cellulose sponge approximately 3" x 1" x 1'" was impregnated with a solution containing four per cent by weight of technical sodium lauryl sulphate, one per cent of tetrasodium pyrophosphate and ninety-five per cent of water; The treated sponge was air dried and upon being weighed was found to have increased in weight by ten per cent. This sponge was moistened, worked to form a froth and subsequently allowed to dry 500 successive times before the detergent was exhausted.
- a cleaning device consisting of a spongious body impregnated'with a substantially anhydrous, synthetic, organic, non-saponaceous detergent.
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- Biomedical Technology (AREA)
- Birds (AREA)
- Dermatology (AREA)
- Inorganic Chemistry (AREA)
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
- Detergent Compositions (AREA)
Description
Patented Apr. 1 1952 SPONGIOUS CLEANING DEVICE Paul F. Webster, Mars, Pa., assignor, by mesne assignments, to Treesdale Laboratories and Textile Processing Company, a corporation of Pennsylvania No Drawing. Application August 29, 1946, Serial No. 693,813
2 Claims.
The present invention relates to a cleaning device particularly adapted for the removal of spots and stains from articles of clothing.
One object of my invention is to provide a cleaning device which has a self-contained supply of a suitable detergent.
A second object of the invention is the provision of a cleaning device which is made ready for use simply by moistening with water.
Other objects and advantages of this invention will be readily apparent from the following detailed description of certain preferred embodiments thereof.
Small, unsightly and very obvious spots appear frequently on clothing despite every precaution of the average orderly wearer. Generally, the spots are not of sumcient size to warrant subjecting the entire garment to dry cleaning or the spotting occurs when complete cleaning is not convenient. For example, a'coat may brush against a grimy wall or car fender. Again, in rainy weather, water spatters the hosiery of women pedestrians. Thus, a small, pocket-size spot remover is a desideratum. To be most serviceable, such a cleaning device should carry a reasonable supply of cleaning medium in a secure manner obviating risk of spillage. The cleaning device should be compact and of light weight.
Briefly stated, my invention contemplates the impregnation of a spongious body with a substantially anhydrous synthetic detergent, which, upon the addition of water, will be activated to provide a highly efficient cleansing medium.
The spongious body can be either a portion of a natural sponge or a section of a regenerated cellulose or cellulated rubber sponge. I particularly favor the synthetic sponge material, for the communicating cell structure thereof is more uniform than can ever be found in a nat- 4 ural sponge and in addition the synthetic material lends itself more favorably to the formation of small, regular sections most suitable for packaging and handling.
It is preferred that the detergent employed in the cleaning device be selected from those which when contacted with water and aerated develop a heavy froth of bubbles or suds. One group of synthetic detergents possessing this property is that consisting of sodium lauryl sulphate and its higher homologues including sodium cetyl sulphate together with the oleic and stearic acid esters. Similarly, a mixture of the esters formed from the higher acids produced by the oxidation of petroleum fractions can be included within this group. Sodium alkyl benzene sulfonate and other analogous organic sulfonates are further examples of desirable detergents. This class of detergents is also marked by its freedom from curd-forming characteristics. They do not combine with the calcium and magnesium salt content of hard water to form insoluble deposits. In addition many of these detergents are normally in solid form and are readily soluble in water. Accordingly, they will be activated by the addition of a small quantity of water and, furthermore, evaporation thereof will restore them quickly to their solid form.
The spongious body of any desired size and shape is impregnated with the synthetic detergent by immersion in a, water solution thereof, accompanied by repeated compression of the spongious medium, and is thereafter dried. The amount of detergent remaining within the cellulated structure will, of course, depend upon the concentration of the detergent solution used for impregnation. For most purposes a solu tion containing from 2-12% of detergent will permit the absorption of sufiicient liquid to leave from 55-10% by weight of solids within the spongious body. However, as little as 1% by weight of solids or as much as 15% by weight of solids will yield serviceable cleaners. Considerations of weight and cost are really the only limiting factors in determining the amount of detergent to be added to the spongious body.
In addition to the synthetic detergent employed in the cleaner, it is often beneficial to include therewith a detergent aid or water softener. For example, a sodium phosphate such as sodium metaphosphate or tetra sodium pyrophosphate, will assist in the cleaning action. A large amount of the phosphate additive is not necessary. I have found that from A; to 3% of the phosphate is sufficient for most purposes.
In service the treated sponge is moistened with water and flexed several times to develop a dense froth or foam of small bubbles upon its surface. The bubbles are applied to the soiled area of the textile and brushed thereover until they disappear. The bubbles liftthe dirt from the textile and transfer it to the cleaner. The damp sponge may be allowed to dry and in any case is immediately ready for the next cleaning task. Where it is intended to be carried in a pocket or purse, a waterproof envelope may be provided into which container the damp sponge may be placed immediately after use.
A cleaning device as contemplated by this invention can be used repeatedly before the detergent supply is exhausted. For example, a regenerated cellulose sponge approximately 3" x 1" x 1'" was impregnated with a solution containing four per cent by weight of technical sodium lauryl sulphate, one per cent of tetrasodium pyrophosphate and ninety-five per cent of water; The treated sponge was air dried and upon being weighed was found to have increased in weight by ten per cent. This sponge was moistened, worked to form a froth and subsequently allowed to dry 500 successive times before the detergent was exhausted.
Although I prefer to employ as the detergent media, compositions which dry to the solid form, thus precluding possible damage while the cleaning device is being carried, it is obvious that a normally liquid detergent can be used to impregnate the spongious body. In such case, a moisture proof envelope or container for the cleaning device is essential.
What I claim is l. A cleaning device consisting of a spongious body impregnated'with a substantially anhydrous, synthetic, organic, non-saponaceous detergent.
2. A cleaning device consisting of a spongious body having deposited upon the cell walls there= of a layer of a substantially anhydrous, synthetic, organic, non-saponaceous detergent.
PAUL F. WEBSTER.
REFERENCES CITED The following references are of record in the 'file of this patent:
UNITED STATES PATENTS Number Name Date 678,971 Nettlich July 23, 1901 1,614,019 Pratt Jan. 11, 1927 2,257,911 Kraft Oct. 7, 1941 2,382,164 MacMahon Aug. 14, 1945 2,382,165 MacMahon Aug. 14, 1945
Claims (1)
1. A CLEANING DEVICE CONSISTING OF A SPONGIOUS BODY IMPREGNATED WITH A SUSTANTIALLY ANHYDROUS, SYNTHETIC, ORGANIC, NON-SAPONACEOUS DETERGENT.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2591481A true US2591481A (en) | 1952-04-01 |
Family
ID=3438785
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US2591481D Expired - Lifetime US2591481A (en) | Spongious cleaning device |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2591481A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3081479A (en) * | 1960-05-23 | 1963-03-19 | American Cyanamid Co | Applicator |
| US3088158A (en) * | 1961-03-28 | 1963-05-07 | Union Carbide Corp | Cleaning and polishing sponge |
| US3112219A (en) * | 1961-12-11 | 1963-11-26 | Nylonge Corp | Method of producing a detergent impregnated cleaning device |
| US3138820A (en) * | 1961-10-05 | 1964-06-30 | August George Sterling | Disposable tooth cleaning and gum massage device and method for making same |
| US3488219A (en) * | 1965-01-23 | 1970-01-06 | Collo Rhelncollodium Koln Gmbh | Method and means for removal of radioactive contaminants |
| US3496589A (en) * | 1966-11-07 | 1970-02-24 | Howard Demner | Dog shampoo device |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US678971A (en) * | 1901-03-27 | 1901-07-23 | Otto Gustav Ludwig Nettlich | Shaving-brush. |
| US1614019A (en) * | 1923-10-17 | 1927-01-11 | Research Inc | Sponge-rubber product and process of making the same |
| US2257911A (en) * | 1939-01-23 | 1941-10-07 | Gen Tire & Rubber Co | Sponge and method of treating |
| US2382164A (en) * | 1945-08-14 | Detergent briquette | ||
| US2382165A (en) * | 1945-08-14 | Detergent briquette |
-
0
- US US2591481D patent/US2591481A/en not_active Expired - Lifetime
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2382164A (en) * | 1945-08-14 | Detergent briquette | ||
| US2382165A (en) * | 1945-08-14 | Detergent briquette | ||
| US678971A (en) * | 1901-03-27 | 1901-07-23 | Otto Gustav Ludwig Nettlich | Shaving-brush. |
| US1614019A (en) * | 1923-10-17 | 1927-01-11 | Research Inc | Sponge-rubber product and process of making the same |
| US2257911A (en) * | 1939-01-23 | 1941-10-07 | Gen Tire & Rubber Co | Sponge and method of treating |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3081479A (en) * | 1960-05-23 | 1963-03-19 | American Cyanamid Co | Applicator |
| US3088158A (en) * | 1961-03-28 | 1963-05-07 | Union Carbide Corp | Cleaning and polishing sponge |
| US3138820A (en) * | 1961-10-05 | 1964-06-30 | August George Sterling | Disposable tooth cleaning and gum massage device and method for making same |
| US3112219A (en) * | 1961-12-11 | 1963-11-26 | Nylonge Corp | Method of producing a detergent impregnated cleaning device |
| US3488219A (en) * | 1965-01-23 | 1970-01-06 | Collo Rhelncollodium Koln Gmbh | Method and means for removal of radioactive contaminants |
| US3496589A (en) * | 1966-11-07 | 1970-02-24 | Howard Demner | Dog shampoo device |
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