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US2531091A - N-acetonyl-pyridinium chloride as an azo coupling component in diazotypes - Google Patents

N-acetonyl-pyridinium chloride as an azo coupling component in diazotypes Download PDF

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Publication number
US2531091A
US2531091A US686951A US68695146A US2531091A US 2531091 A US2531091 A US 2531091A US 686951 A US686951 A US 686951A US 68695146 A US68695146 A US 68695146A US 2531091 A US2531091 A US 2531091A
Authority
US
United States
Prior art keywords
diazotypes
acetonyl
pyridinium chloride
coupling component
azo coupling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US686951A
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English (en)
Inventor
Andre E Van Dormael
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gevaert Photo Producten NV
Original Assignee
Gevaert Photo Producten NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gevaert Photo Producten NV filed Critical Gevaert Photo Producten NV
Application granted granted Critical
Publication of US2531091A publication Critical patent/US2531091A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/52Compositions containing diazo compounds as photosensitive substances
    • G03C1/58Coupling substances therefor

Definitions

  • This invention relates to a process for preparing diazotypes.
  • the primary object of this invention is to provide a color coupler to be used in the preparation of diazotypes which is of great effectiveness.
  • R represents aryl, alkyl or aralkyl
  • X represents H, aryl, alkyl, aralkyl, acyl or a hydroaromatic residue
  • Y represents H, aryl, alkyl, aralkyl, acyl or a hydroaromatic residue.
  • I employ N- acetonyl-pyridinium chloride as a coupler.
  • my new coupling component is its great solubility and its quality of rapidly coupling and giving very intense dyestuffs with the usual diazo compounds.
  • the coupling element of my invention may be used singly or in any combination. Whenused in mixtures, diazotypes of very intense neutral color are obtained whereas, for instance, the use of phloroglucinol alone produces only a brown violet color.
  • EwampZe.-To a suitable paper is applied a solution of 1.5 g. of diazonium compound from p-diethylamino aniline, 1 g. of tartaric acid, 0.8 g. of aluminum sulphate, 0.15 g. of phloroglucinol and 0.08 g. of N-acetonylpyridinium chloride in cm. of water.
  • the paper is exposed through a diapositive and developed in an ammoniacal atmosphere.
  • the paper is exposed through a diapositive and developed in an ammoniacal atmosphere. A dark magenta print is obtained.
  • My new coupling component may be added either to the developer when the half-wet process is used, or to a solution which contains one or more diazo compounds and which is applied as light-sensitive layer to an adapted paper.
  • the method which comprises selectively exposing a lightsensitive material containing a light-sensitive diazo compound, and coupling the diazo compound retained in the unexposed areas with N- acetonyl-pyridinium chloride.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
US686951A 1945-08-03 1946-07-29 N-acetonyl-pyridinium chloride as an azo coupling component in diazotypes Expired - Lifetime US2531091A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BE266905X 1945-08-03

Publications (1)

Publication Number Publication Date
US2531091A true US2531091A (en) 1950-11-21

Family

ID=3866827

Family Applications (1)

Application Number Title Priority Date Filing Date
US686951A Expired - Lifetime US2531091A (en) 1945-08-03 1946-07-29 N-acetonyl-pyridinium chloride as an azo coupling component in diazotypes

Country Status (7)

Country Link
US (1) US2531091A (fr)
BE (1) BE459543A (fr)
CH (1) CH266905A (fr)
ES (1) ES176413A1 (fr)
FR (1) FR931187A (fr)
GB (1) GB617115A (fr)
NL (1) NL62542C (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3307952A (en) * 1963-11-20 1967-03-07 Ibm Formation of diazo couplers in situ
US4130426A (en) * 1974-04-22 1978-12-19 Fuji Photo Film Co., Ltd. Heat developable light-sensitive diazotype materials and process of use

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE489248A (fr) * 1948-11-05
DE966201C (de) * 1953-08-14 1957-07-18 Bayer Ag Verfahren zur Herstellung von Cyclohexanonoxim durch katalytische Hydrierung von Nitrocyclohexansalzen

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1822065A (en) * 1928-10-19 1931-09-08 Kalle & Co Ag Azo dyestuff components and process of preparing them
US2027229A (en) * 1931-07-08 1936-01-07 Frederick Post Company Accelerated diazo printing and materials therefor
US2154918A (en) * 1937-07-30 1939-04-18 Agfa Ansco Corp Coupling compounds for color forming development
US2217189A (en) * 1938-12-05 1940-10-08 Kalle & Co Ag Process of preparing photographic prints
US2331326A (en) * 1939-07-22 1943-10-12 Ilford Ltd Production of colored photographic images
US2405523A (en) * 1944-08-09 1946-08-06 Du Pont Light-sensitive photographic compositions and elements

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1822065A (en) * 1928-10-19 1931-09-08 Kalle & Co Ag Azo dyestuff components and process of preparing them
US2027229A (en) * 1931-07-08 1936-01-07 Frederick Post Company Accelerated diazo printing and materials therefor
US2154918A (en) * 1937-07-30 1939-04-18 Agfa Ansco Corp Coupling compounds for color forming development
US2217189A (en) * 1938-12-05 1940-10-08 Kalle & Co Ag Process of preparing photographic prints
US2331326A (en) * 1939-07-22 1943-10-12 Ilford Ltd Production of colored photographic images
US2405523A (en) * 1944-08-09 1946-08-06 Du Pont Light-sensitive photographic compositions and elements

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3307952A (en) * 1963-11-20 1967-03-07 Ibm Formation of diazo couplers in situ
US4130426A (en) * 1974-04-22 1978-12-19 Fuji Photo Film Co., Ltd. Heat developable light-sensitive diazotype materials and process of use

Also Published As

Publication number Publication date
ES176413A1 (es) 1948-07-01
BE459543A (fr) 1900-01-01
NL62542C (fr)
GB617115A (en) 1949-02-01
CH266905A (fr) 1950-02-28
FR931187A (fr) 1948-02-16

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