US2501138A - Globular inclusion control for steel making - Google Patents
Globular inclusion control for steel making Download PDFInfo
- Publication number
- US2501138A US2501138A US60619A US6061948A US2501138A US 2501138 A US2501138 A US 2501138A US 60619 A US60619 A US 60619A US 6061948 A US6061948 A US 6061948A US 2501138 A US2501138 A US 2501138A
- Authority
- US
- United States
- Prior art keywords
- manganese
- sulphur
- steel
- melt
- sulfide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000009628 steelmaking Methods 0.000 title description 3
- 229910000831 Steel Inorganic materials 0.000 claims description 23
- 239000010959 steel Substances 0.000 claims description 23
- CADICXFYUNYKGD-UHFFFAOYSA-N sulfanylidenemanganese Chemical compound [Mn]=S CADICXFYUNYKGD-UHFFFAOYSA-N 0.000 claims description 20
- 239000000155 melt Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 6
- 229910045601 alloy Inorganic materials 0.000 claims description 5
- 239000000956 alloy Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 3
- 238000010899 nucleation Methods 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 24
- 239000005864 Sulphur Substances 0.000 description 24
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 12
- 229910052748 manganese Inorganic materials 0.000 description 12
- 239000011572 manganese Substances 0.000 description 12
- 238000007792 addition Methods 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000010622 cold drawing Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000005098 hot rolling Methods 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910000915 Free machining steel Inorganic materials 0.000 description 1
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 1
- 241000270295 Serpentes Species 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000000161 steel melt Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
Definitions
- This. invention relates to the control, of manganese sulphide inclusions in the production of steel.
- Such steels may be produced generally in accordance with the teachings of U. S. Letters Patent No. 2,157,673 and No. 2,157,674. This invention also applies to alloy steels. Such steels, however, have had variable" microstructures including elongated stringy inclusions.
- The-object of the invention is to stabilize said properties with the result that the longitudinal and transversemicrostructures have greater uniformity and are of a type conducive to better machinability and reduction in rejects.
- the feature of the invention resides in the attainment of said objectives by controlling the manganese sulphide inclusions through the method of introducing manganese and sulphur in the heat, and the form of such additive material.
- this invention relates to the method of manganese sulfide inclusion control.
- Steel of this character will be more uniform as to m'icrostructure, type and distribution of nonmetallic inclusions resulting in better machinability, hardening ability, surface condition, ductility, transverse properties, elongation, reduction of area, rolling conditions in the hot mill, and easier workin conditions at the hot mill, especially at the open hearth floor.
- Such steel will enable the hot mill to obtain a better yield. Also, the cold drawing mill may thereby produce a better yield; i. e. less rejections from each heat.
- the present invention contemplates the addi-- tion of manganese and sulphur in such form and at such a time that there results a lesser degree of iron sulfide in the (MnFe) S solid solution with the result that the inclusions are of the high temperature type and are of small globular form. Also the fuming is reduced.
- the control additive may be a manganese sulfide alloy, such as sold' by Metal'loy Corporation, and which has a melting point of about 2880-2900' F.
- Such manganese sulphide has a nominal content of manganese 56.7 sulphur 36.0%, iron 7.0% and silicon 0.3% This material is preferably introduced in lump form and of a size about an inch or more in lump form and of a size about an inch or more in diameter.
- the sulphur introduction at this time results in the manganese of the melt uniting with the sulphur to produce manganese sulfide nuclei that starts grain growth points in the ingot upon subsequent cooling and, being a high temperature manganese sulfide, tends to assume a globular form.
- the manganese and sulphur of the high temperature type serve as seeds or nuclei to form the high temperature inclusions.
- the manganese having under these conditions a greater affinity for sulphur than the iron, forms manganese sulfide in preference to the formation of iron sulfide, to the end that the formation of the iron sulfide is reduced to a minimum. The loss of sulphur incident to excess inclusion in the slag or vaporization of the sulphur is thereby reduced.
- the resultant metal product (the melt) is a sulphurized alloy steel wherein additional amounts of sulphur may be added in the ladle, if desired for resulphurization. Subsequent addition, upon the melt being substantially complete, of high temperature manganese sulfide or manganese and/or sulphur results in the continued formation of globular inclusions because of the high temperature manganese sulfide nuclei in the melt. Thus low temperature (stringlike) manganese sulfide inclusions do not develop in the steel.
- the particular material mentioned is used in an amount to meet the sulphur chemical requirements of the steel, any aluminum present being infinitesimal.
- Themanganesesulfide so used is in preponderance in this addition material, but of such low order, relative to the total metal mass, that the steel has the desired percentage of sulphur therein necessary to attain the properties desired in the steel.
- phosphorus and silicon is intentionally kept very low, that is in the order of .02%.
- the manganese sulfide seeding and growth has a very beneficial effect on the machinability of the steel as a lubricant due to the inclusion of the sulphur.
- Steel produced in accordance with this invention facilitates the hot rolling thereofby reason of the hot shortness being cut down resulting in the reduction of snakes, slivers and scams. Hence a higher and more profitable yield is obtainable from a given heat.
- such steel being homogeneous in character, permits more uniform production by having less seams and cold shuts, and having an improved surface condition which results in less rejections from the cold drawing mill and consequently a higher yield.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Treatment Of Steel In Its Molten State (AREA)
Description
Patented Mar. 21, 1950 GLOBULAR INCLUSION CONTROL FOR STEEL MAKING James T. Parker, Indianapolis, Ind., assignor to W. J. Holliday' 80 Company, Inc., Indianapolis,
Ind., a corporation No Drawing. Application November 17, 1948, Serial No. 60,619
, 2 Claims.
This. invention relates to the control, of manganese sulphide inclusions in the production of steel.
In the making of low carbon steel, it is known that free machining steels capable of case hardening and having high ductility and tensile strength can be produced'by suitable additions as by increasing the sulphur and manganese content, .High carbon steels are suitable for heat treatment;
Such steels may be produced generally in accordance with the teachings of U. S. Letters Patent No. 2,157,673 and No. 2,157,674. This invention also applies to alloy steels. Such steels, however, have had variable" microstructures including elongated stringy inclusions.
The-object of the invention is to stabilize said properties with the result that the longitudinal and transversemicrostructures have greater uniformity and are of a type conducive to better machinability and reduction in rejects.
The feature of the invention resides in the attainment of said objectives by controlling the manganese sulphide inclusions through the method of introducing manganese and sulphur in the heat, and the form of such additive material. In other words, this invention relates to the method of manganese sulfide inclusion control.
Steel of this character will be more uniform as to m'icrostructure, type and distribution of nonmetallic inclusions resulting in better machinability, hardening ability, surface condition, ductility, transverse properties, elongation, reduction of area, rolling conditions in the hot mill, and easier workin conditions at the hot mill, especially at the open hearth floor.
Such steel will enable the hot mill to obtain a better yield. Also, the cold drawing mill may thereby produce a better yield; i. e. less rejections from each heat.
Since the steel is sounder, when magnafiuxed the number of rejects will be greatly reduced, if not eliminated. It also has better machinability because of such control and again there are less rejects.
Heretofore in steel making to resulphurize steel, it is the practice to add sulphur to the bottom of the ladle preferably before tapping the furnace, or adding the calculated sulphur to the ladle before it is one third full, and then filling with steel. In either practice there is violent toxic fuming. Sulphur added in either manner reacts with the iron to form predominantly iron sulfide, other sulfides and low temperature manganese sulphide to a limited degree. Such low temperature manganese sulfide appears in the stringy or elongated inclusion form after hot working.
The present invention contemplates the addi-- tion of manganese and sulphur in such form and at such a time that there results a lesser degree of iron sulfide in the (MnFe) S solid solution with the result that the inclusions are of the high temperature type and are of small globular form. Also the fuming is reduced.
Such addition is made immediately after the open hearth or electric furnace has made a melt of steel in which there has been added the necessary alloying material. Thereafter the sulphur or sulphur in combined form may be added'as desired or required. The control additive may be a manganese sulfide alloy, such as sold' by Metal'loy Corporation, and which has a melting point of about 2880-2900' F. Such manganese sulphide has a nominal content of manganese 56.7 sulphur 36.0%, iron 7.0% and silicon 0.3% This material is preferably introduced in lump form and of a size about an inch or more in lump form and of a size about an inch or more in diameter.
The sulphur introduction at this time (after melting is effected) results in the manganese of the melt uniting with the sulphur to produce manganese sulfide nuclei that starts grain growth points in the ingot upon subsequent cooling and, being a high temperature manganese sulfide, tends to assume a globular form.
The result is a subsequent low production of low temperature manganese sulfide and but little production of the iron sulfide comparatively speaking. Thus in the subsequent hot rolling of the steel there does not result the usual objectionable elongated and long, stringy inclusions.
It is to be noted that sufficient manganese is supplied to the melt in the manganese and the sulphur addition to provide the required amount of manganese and sulphur which is readily determinable by analysis of samples. The manganese and the sulphur thus supplied is normally in excess of that used in the conventional steel melt practice, such excess being incorporated in the slag.
It has been determined that furnac heating after such initial addition has been made, may be continued ten to twenty minutes longer. The manganese and sulphur of the high temperature type serve as seeds or nuclei to form the high temperature inclusions. The manganese, having under these conditions a greater affinity for sulphur than the iron, forms manganese sulfide in preference to the formation of iron sulfide, to the end that the formation of the iron sulfide is reduced to a minimum. The loss of sulphur incident to excess inclusion in the slag or vaporization of the sulphur is thereby reduced.
The resultant metal product (the melt) is a sulphurized alloy steel wherein additional amounts of sulphur may be added in the ladle, if desired for resulphurization. Subsequent addition, upon the melt being substantially complete, of high temperature manganese sulfide or manganese and/or sulphur results in the continued formation of globular inclusions because of the high temperature manganese sulfide nuclei in the melt. Thus low temperature (stringlike) manganese sulfide inclusions do not develop in the steel.
The particular material mentioned is used in an amount to meet the sulphur chemical requirements of the steel, any aluminum present being infinitesimal. Themanganesesulfide so used is in preponderance in this addition material, but of such low order, relative to the total metal mass, that the steel has the desired percentage of sulphur therein necessary to attain the properties desired in the steel.
The usual care and control of oxygen, chromium, titanium, aluminum, phosphorus, silicon, carbon and the like is exercised in the present process to produce the desired type of steel with or without such last mentioned materials or combinations thereof as well understood in the steel producing art. Preferably phosphorus and silicon is intentionally kept very low, that is in the order of .02%.
Steel having this low phosphorus and silicon content is more susceptible to the inclusion of manganese and sulphur in solid solubility form.
4 The manganese sulfide seeding and growth has a very beneficial effect on the machinability of the steel as a lubricant due to the inclusion of the sulphur.
Steel produced in accordance with this invention facilitates the hot rolling thereofby reason of the hot shortness being cut down resulting in the reduction of snakes, slivers and scams. Hence a higher and more profitable yield is obtainable from a given heat.
Furthermore, such steel being homogeneous in character, permits more uniform production by having less seams and cold shuts, and having an improved surface condition which results in less rejections from the cold drawing mill and consequently a higher yield.
The invention claimed is:
l. The process of making sulphurized and resulphurized steels of the character described comprising making the melt, pouring into a ladle, and teeming, characterized by the addition to the melt, prior to pouring into the ladle, of a high temperature manganese sulfide alloy composition in lump form for high temperature manganese sulfide globular inclusion seeding purposes.
2. The process of claim 1 characterized by the manganese sulfide alloy composition having a melting point in excess of 2700 F.
JAMES T. PARKER.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Number Name Date 2,120,894 Haag June 14, 1938 2,225,511 Soler Dec. 17, 1940
Claims (1)
1. THE PROCESS OF MAKING SULPHURIZED AND RESULPHURIZED STEELS OF THE CHARACTER DESCRIBED COMPRISING MAKING THE MELT, POURING INTO A LADLE, AND TEEMING, CHARACTERIZED BY THE ADDITION TO THE MELT, PRIOR TO POURING INTO THE LADLE, OF A HIGH TEMPERATURE MANGANESE SULFIDE ALLOY COMPOSITION IN LUMP FORM FOR HIGH TEMPERATURE MANGANESE SULFIDE GLOBULAR INCLUSION SEEDING PURPOSES.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US60619A US2501138A (en) | 1948-11-17 | 1948-11-17 | Globular inclusion control for steel making |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US60619A US2501138A (en) | 1948-11-17 | 1948-11-17 | Globular inclusion control for steel making |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2501138A true US2501138A (en) | 1950-03-21 |
Family
ID=22030666
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US60619A Expired - Lifetime US2501138A (en) | 1948-11-17 | 1948-11-17 | Globular inclusion control for steel making |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2501138A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3259488A (en) * | 1960-03-31 | 1966-07-05 | Ishikawajima Harima Heavy Ind | Nitride-bearing low carbon ductile steels |
| US5885326A (en) * | 1997-06-27 | 1999-03-23 | The United States Of America As Represented By The United States Department Of Energy | Process for removing technetium from iron and other metals |
| US6733565B1 (en) * | 2002-04-24 | 2004-05-11 | Rodney L. Naro | Additive for production of irons and steels |
| US7618473B1 (en) | 2003-10-27 | 2009-11-17 | Rodney L. Naro | Method for improving operational efficiency in clogged induction melting and pouring furnaces |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2120894A (en) * | 1935-06-24 | 1938-06-14 | Haag Johannes | Method of producing free cutting steel |
| US2225511A (en) * | 1939-09-23 | 1940-12-17 | Timken Roller Bearing Co | Free machining steel |
-
1948
- 1948-11-17 US US60619A patent/US2501138A/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2120894A (en) * | 1935-06-24 | 1938-06-14 | Haag Johannes | Method of producing free cutting steel |
| US2225511A (en) * | 1939-09-23 | 1940-12-17 | Timken Roller Bearing Co | Free machining steel |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3259488A (en) * | 1960-03-31 | 1966-07-05 | Ishikawajima Harima Heavy Ind | Nitride-bearing low carbon ductile steels |
| US5885326A (en) * | 1997-06-27 | 1999-03-23 | The United States Of America As Represented By The United States Department Of Energy | Process for removing technetium from iron and other metals |
| US6733565B1 (en) * | 2002-04-24 | 2004-05-11 | Rodney L. Naro | Additive for production of irons and steels |
| US7618473B1 (en) | 2003-10-27 | 2009-11-17 | Rodney L. Naro | Method for improving operational efficiency in clogged induction melting and pouring furnaces |
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