US2184672A - Manufacture of plastic sheets - Google Patents

Description

Dec. 26, 1939. F. w. JACKMAN 2,184,672

MANUFACTURE OF PLASTIC SHEETS Original Filed June 17, 1935 A TTORNEY Patented Dec. 26, 1939 I UNITED STATES PATENT OFFICE 7 Fred W. Jackman, Beverly Hills. Calif., assignor to Warner Bros. Pictures, Inc., New York, N. Y.,

a corporation of Delaware Application June 17,

1935. Serial No. 27,018

Renewed August 12, 1939 10Clalm8.

This invention relates to a method of making a plastic sheet, and more particularly a translucent motion picture screen of cellulose ester material, such as cellulose acetate or cellulose nitrate.

'5 Heretofore, cellulose acetate, and the nitrate as well, have been offered for sale in sheet form. In the form in which it is available on the market. it has not been satisfactory as a translucent screen because in the first place the sheets are 10 not translucent, and in the second place the ticularly for a screen which is translucent and.

' of any desired size, small or large, and in par- 25 ticular, much larger than the sheets of transparent cellulose acetate heretofore available.

According to the invention, the sheet is made of any desired size; large or small, by dissolving in a solvent either the transparent cellulose ace- 3o tate in sheet form referred to above, or acetated ily be made of any desired size, large or small,

a sheet of cellulose ester material of any desired size can be produced. I consider this process of making a sheet of cellulose ester material to be 49 an important part of my invention. However, according to another feature of the invention I treat this sheet so that it will be suitable as a translucent screen for motion picture projection.

In other words, I render thesheet translucent.

45 This may be accomplished in the'course .of manufacturing the sheet by providing a matrix having an array of minute irregular projections on one surface thereof such as produced by sand blasting, etching or other methods known in the 50 art. The solution, as above described, is then sprayed onto the figured surface of the matrix.- After the sheet, thus formed, is dried and stripped from the matrix, it will be translucent by reason (I the fact that it carries on one surface thereof I Q an one of minute irregular light refracting surfaces which are faithful copies of the minute projections on the matrix.

In the course of manufacturing this screen as above described, the acetate solution is trans parent, special precautions hereafter described ,5 being taken to keep it transparent during the spraying and solidifying processes so that the body of the screen is transparent. In making the screen translucent, however, the outer surface of this transparent body of cellulose material is 10 treated to render it translucent.

A further object of the invention is to prevent the production of air bubbles or opacity in the sheet or screen. The prevention of air bubbles is accomplished by spraying the solution in a thin l5 'layer on the matrix, instead of flowing it on, and also by supplying the cellulose acetate solution tothe spray gun under hydrostatic pressure of the solution free from air pressure. Opacity is prevented by recognizing that the presence of 20 moisture will convert the transparent solution to the opaque or cotton form of cellulose ester, i. e. moisture will regenerate acetated cotton from its solution. In fact, water is one of the hardening agents which has been used heretofore in manufacturing lace or other cotton goods from cellulose solution. In the first place," I prevent moisture from rendering the screen opaque by performing the spraying operation in dry conconditioned air. The use of no air pressure for. the spray nozzle also contributes to this, the solution being atomized by hydrostatic pressure thereof. Furthermore, due to the fact that rapid evaporation of the solvent from a coat which is drying would cause the moisture in the air (even from dry conditioned air) to condense and form upon the surface of the celluiosesheet, I preferably add a retarding agent to the solution. For. example, I may add a liquid known in the trade as Methyl Cellosolve which is ethylene glycol 40 terial used in making the screen. Preferably, this is accomplished by placing a border on the matrix, before or after some of the coats have been sprayed thereon, the remaining coats being sprayed to cover this border whereby it is integrally united with the screen.

The present application is a continuation in part of my application Serial No. 631,964, filed September 7, 1932, for Translucent picture projection screen, now Patent No. 2,071,344. The present application claims the process of making the screen, and the screen itself is covered in my co-pending application Serial No. 27,017, filed June 17, 1935, for Translucent projection screen, now Patent No. 2,071,342.

For further details of this invention reference may be made to the drawing, wherein:

Fig. 1 is a fragmentary side elevation of a screen mounted in a supporting frame.

Fig. 2 is a side elevation partly in cross section of a preferred arrangementyof parts, used to prepare a screen according to this invention.

Fig. 3 is an enlarged fragmentary section of the base and resulting screen.

Fig. 4 is an enlarged fragmentary section of the screen showing an eyelet attached to the border thereof for suspending the screen within a suitable frame.

Fig. 5 is an enlarged fragmentary section of a modified arrangement for reinforcing the border of the screen.

The solution for making the sheet or screen comprises acetated cotton or cellulose acetate which I dissolve in C. P. acetone, plus such additives as are necessary to produce a flexible, transparent and tough film. A preferred mixture comprises the following:

10# acetated cotton 25 gal. chemically pure acetone 4 gal. ethylene glycol mono methyl ether 1 gal. ethylene glycol mono ethyl ether monoacetate 1# di-ethyl phthalate The Methyl Cellosolve and "Cellosolve Acetate which is ethylene glycol mono ethyl ether monoacetate are added to retard evaporation of the acetone and prevent the solution from evaporating so rapidly that it would cool the dry air to the dew point whereby moisture from the dry air is prevented from condensing on the sprayed surface. Also, by retarding the evaporation of the solvent, the Methyl Cellosolve" and Cellosolve Acetate retain the sprayed material in a fiuid condition for a longer time than would otherwise be the case, whereby the sprayed material more readily flows into the crevices of the surface 25 and also this results in forming a substantially smooth outer surface 23 which has an unobjectionable small amount of orange-peel texture. The di-ethyl-phthalate serves as a plasticizer and any other suitable plasticizer may be used instead. An alternative cellulose mixture may include: 7

4.2 grams of cellulose acetate sheets cut up into small sheets or powdered 100 c. c. chemically pure acetone 20 c. c. of 80 to 90% glacial acetic acid The above ingredients are encased in a drum which is rotated for the length of time necessary to insure a complete solution of the cellulose acetate. The drum I (Fig. 2) containing the transparent cellulose acetate solution is then hoisted to a height where its hydrostatic pressure is approximately 15 lbs. per square inch at ground level. Drum i is supported by any suitable means, such as a beam 2. A tube 3 which is preferably of pure gum rubber, in order that the cellulose acetate solution will not chemically react with it during its passage therethrough, is

attached to the drum I. The tube 3 passes through a wall 4 in a room, the floor of which is covered by a suitable frame 5 encasing a desired stationary base or matrix 6 which may be glass or preferably of metal such as aluminum having its upper surface sandblasted with a medium fine grain sand as shown at 25. When large sheets of cellulose material are to be made, the base 6 may be comprised of sections as at l8, l9 and 20 of metal welded together and finished to provide a large unbroken surface. An inlet 9 serves to supply especially dry conditioned air to the chamber and an outlet i exhausts the air and insures a continuous flow of dry conditioned air across the surface of the base 6.

In the operation of this device, a nozzle or spray gun H at the end of the tube 3 is opened and a thin coating of cellulose acetate solution (1. e. cellulose ester) is. sprayed onto the base 6, the solution being atomized by hydrostatic pressure of the solution, free from air pressure ordinarily used in painting. This avoids the'necessity for chemicals to prevent blush or opacity. This coating is allowed to dry thoroughly for example, 30 to 40 minutes, in the conditioned air which fiows through the chamber. When this is accomplished, a second coating is applied and the same procedure followed, After about half of the desired coatings are applied, border strips as at I are secured upon the. surface of the last coating. These strips 1 are preferably of fabric which is impregnated with a cellulose acetate solution and applied to the sheet is while the cellulose material is still tacky. The additional coatings are then sprayed on over both the former coatings and the border strips to provide a secure bond therebetween as shown in Fig. 3. Twenty to thirty coats of the solution are applied, each being allowed to dry separately until a desired thickness is obtained. The sheet of cellulose acetate is-bodily stripped off the base 6 and comprises a sheet shown in Figs. 1, 3 and 4 and at H5 in Fig. 5. This sheet i6 is flexlble and light in weight and has a body portion which is substantially transparent with one surface 24 having a' copy of the minute irregular light refracting projectionson the surface 25 of the matrix 5. The sheet i8 is translucent due to the refraction or dispersion of light by the surface 24. Eyelets I? are then secured within the border 8 of the sheet i8 (Fig. 4) whereby the sheet may be mounted within a suitable frame l2 (Fig. 1). These sheets or screens may be of considerable size, such as from ten to twenty feet along each edge.

Fig. 5 shows a modified arrangement for applying a reinforcing border upon the edge of the sheet l6. In this case, a border strip if is first laid around the edges of the base 5 and the cellulose solution is sprayed on so as to cover and provide a bond between itself and the border strip 2|. A second border strip '22 may then be secured to the opposite face of the resulting sheet l6. Eyelets l5 are then passed through the assembly and then secured thereto. The border 8 may also be made up by combining the forms shown in Figs. 4 and 5.

The frame I2 is supported for mobility by means of any suitable rollers l3. A series of pins H are then placed along the edges of the frame [2 and are resiliently connected by means of springs or rubber bands H to a series of eyelets 15 in the border 8 along the edges of the screen l6. By using this form of mounting the screen will always remain taut without any wrinkles therein. This form of mounting is disclosed and claimed in my United States Patent No. 1,960,632, patented May 29, 1934.

Thus it will be seen that a screen is provided which is flexible, light in weight, inexpensive to make and readily rolled into a compact form for storage or transportation. A further advantage of this type of translucent screen is that, due to the thinness of the cellulose sheet (i. e., .020" to .030") very little light is lost in transmission, whereas in a glass screen the thickness must necessarily be large, usually on the order of A" to to prevent breakage. It has been found by photometer readings that, other factors being equal, the intensity of illumination of a screen made by this process, and on which a mo- ,tion picture is projected from behind the screen,

{is approximately 100% greater than the illumination of a treated glass screen. Therefore, a

projector lamp of less intensity may be used thereby greatly reducing the amount of heat that is emitted from the projector onto the film or slide to be projected. Due to its acetate base, a screen of cellulose material formed by this process is practically non-inflammable and the risk of fire is reduced to a minimum.

In setting the translucent screen l6 between the projector and the camera or audience the smooth surface 23 is placed so that it faces the projector thus preventing any stray light which might fall upon the screen from being reflected into the camera or audience.

Various modifications may be made within the scope of the following claims. For example, the hydraulic pressure of the solution may be hydrodynamic instead of hydrostatic.

Having thus described the invention, what is claimed as new and desired to secure by Letters Patent, is:

l. The method of making a translucent picture projection screen which comprises spraying on a matrix under hydraulic pressure free from air pressure, a plurality of coats of a transparent solution of cellulose acetate, allowing each coat to dry before applying the next coat. performing said spraying and drying operations in dry air, stripping the sheet thus produced from said matrix, and forming an array of light refracting surfaces on one side of said sheet.

2. The method according to claim 1 which comprises retarding the evaporation of the solvent from said coats.

3. In translucent screen manufacture. the

method of making a reinforced edge which comprises placing a body strip of fabric adjacent a sheet of cellulose ester on a surface, and spraying a plurality of coats of a solution of cellulose material on said sheet and on said strip to integrally unite the same, and stripping the said sheet from said surface.

4. The method of making a translucent projection screen which comprises spraying on a matrix a plurality of initial coats of cellulose ester material to form a part of the body portion of said screen, allowing each of said coats to dry, applying a border strip of fabric on said partial body portion at the edge thereof, spraying a second plurality of coats of said cellulose material over said partial body portion and over said border strip to build up said screen to the desired thickness and to integrally unite said strip with the body of said screen, allowing each of said last mentioned coats to dry, and stripping said sheet from said matrix.

5. The method in accordance with claim 4 which comprises making said screen translucent by providing an array of light refracting surfaces on one side of said screen.

6. The process of integrally uniting a light refracting surface and a homogeneous multi-layer transparent screen body portion of cellulose material which comprises spraying a solution of cellulose ester (11) to form said refracting surface and (b) to form said body portion, and integrally uniting said refracting surface and said body portion by spraying one on the other while retarding evaporation of the solvent in said solution.

7. The process of making a homogeneous multi-layer body portion of cellulose ester which comprises spraying on a matrix multiple coats of a transparent solution of cellulose ester containing an evaporation retarding agent to reduce condensation of moisture from the air on the sprayed surface, allowing each coat to dry before spraying the succeeding coat, and stripping the sheet thus produced from said matrix.

8. The process of integrally uniting a light refracting surface and a homogeneous multi-layer transparent screen body portion of screen material to form a translucent picture, projection screen which comprises spraying asubstantially transparent solution of screen material (a) to form said refracting surface and b) to form said body portion, and integrally uniting said refracting surface and said body portion by spraying one on the other.

9. The process according to claim 8, wherein said solution of screen material comprises a volatile solvent with plastic forming material dissolved therein, said plastic forming material being capable of setting to form a plastic on evaporation of said solvent.

10. The process according to claim 8 wherein said body portion is formed on, and later stripped from, a matrix.

FRED W. JACKMAN.

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