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US2079108A - Textile process and product - Google Patents

Textile process and product Download PDF

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Publication number
US2079108A
US2079108A US445202A US44520230A US2079108A US 2079108 A US2079108 A US 2079108A US 445202 A US445202 A US 445202A US 44520230 A US44520230 A US 44520230A US 2079108 A US2079108 A US 2079108A
Authority
US
United States
Prior art keywords
cellulose
fatty acid
higher fatty
partial
cellulose acetate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US445202A
Other languages
English (en)
Inventor
Dreyfus Camille
Whitehead William
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese Corp
Original Assignee
Celanese Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Corp filed Critical Celanese Corp
Priority to US445202A priority Critical patent/US2079108A/en
Priority to GB9570/31A priority patent/GB380042A/en
Priority to FR715183D priority patent/FR715183A/fr
Application granted granted Critical
Publication of US2079108A publication Critical patent/US2079108A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224Esters of carboxylic acids; Esters of carbonic acid
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02Water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/287Partial esters
    • C10M2207/289Partial esters containing free hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
    • C10M2207/404Fatty vegetable or animal oils obtained from genetically modified species
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/10Phosphatides, e.g. lecithin, cephalin
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/02Groups 1 or 11
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/46Textile oils

Definitions

  • finishes which soften and lubricate the yarns.
  • such finishes should preferably .be hydroscopic in order to soften such yarns and should also be-oleaginous in order to lubricate the same.
  • the partial higher fatty'acid esters of "polyhydric alcohols that is compounds wherein not all of the hydroxyl groups of the polyhydric alcohols are substituted by the fatty acid radical, produce excellent results, when employed infinishes for such yarns, or are incorporated in the spinning solution from which they are formed. Because of the presence of the unsubstituted hydroxyl group, such compounds are hydroscopic and act. as softening agents for the textile material, and because they are esters of fatty acids, they have lubricating properties.
  • polyhydriqalcoh'ols is intended to include such compounds wherein at least one of the hydi'oxyl groups-of the polyhydric alcohols is unsubstituted.
  • esters are glycerine. mono- 55 oleate, 'C:Hii(OH)2C1aH33O2; glycerine dl-oleate,
  • an appropriate amount of the fatty acid ester say, from 2 to 20% of the weight of the derivative of cellulose present, may be added, and such solution be extruded through orifices into an evaporative atmosphere as in dry spinning, or into a precipitating bath, as in wet spinning.
  • the organic derivative of cellulose employed in the textile material may be a. suitable organic ester of cellulose or a cellulose ether.
  • suitable organic ester of cellulose or a cellulose ether examples include cellulose esters cellulose acetate, cellulose formate, cellulose propionate and cellui lose butyrate, while examples of cellulose others are ethyl cellulose, methyl cellulose and benzyl cellulose. 7
  • the higher fatty acid partial esters of the polyhydric alcohols may be applied to the yarns, filaments or fabrics after their formation. They may .be applied either alone or in admixture with other materials to the textile material. As they are strong solvents for the polyhydric alcohols themselves, fatty acids and soaps, they may be used in finishes for yarns, which finishes also contain such compounds.
  • polyhydric alcohol partial fatty may be employed with advantage in the making of printing pastes for application to fabrics in place of oils.
  • Such polyhydric alcohol partial fatty may be applied to I textile materials very readily from aqueous emulsions where finishing is desired of yarns, fabrics
  • The-term partial .higher fatty acid esters of acid esters are miscible with the polyhydric a1- cohols, which are solvents for fugitive dyestufls for cellulose acetate yarns, such as the acid dyes (e. 'g. the sodium salt of sulfonated indigotine).
  • a finish may be made which contains the partial esters and the fugitive dyestufi dissolved in the polyhydric alcohol, and the same may be applied to cellulose acetate yarn for the purpose of yarn identification.
  • the partial esters of the polyhydric alcohols have sufilcient solvent power. for such fugitive dye-- stuifs so that solutions of the dyestuff in them alone may be applied to yarn both as a finish and as a fugitive tint.
  • Example I A finish is prepared as follows:
  • the above mixture is applied to an acetonesoluble cellulose acetate yarn, by causing such yarn to pass over wicks, rollers or other suitable devices for applying such mixture, in their transit to a winding machine.
  • the amount of finish applied is 10% of the weight of the yarn.
  • the yarn so treated is more pliable, knits with less distortion and irregularities, takes high twists more smoothly and generally exhibits improved properties from a textile manipulation point of view. Fabrics en greigecomprising this yarn scour oil-free very readily and also wet out rapidly.
  • glycerine mono-oleate alone is applied in amounts of about 10% of the weight of the yarn, similar benefits are obtained.
  • Example II markable ease, the finish diffusing from the yarn quite readily, even in cold water.
  • Example III The following spinning solution is prepared Parts by weight Qlycerine mono-oleate The solution is thoroughly mixed and filtered and then is forced through orifices of a spinneret into a warm evaporative atmosphere where the acetone and water are substantially evaporated oil.
  • the filaments thus formed are twisted to form yarn.
  • the yarn so formed is immediately'ready for textile operations and has the improved properties of the yarn described in the preceding examples.
  • Process of forming artificial materials comprising shaping a solution containing an organic derivative of cellulose and a partial higher fatty acid ester of a polyhydric alcohol and setting the same into solid form.
  • Process of forming artificial materials comprising shaping a solution containing cellulose 75- vated temperatures.
  • Process of forming a textile material of re- I **d lustre comprising subjecting organic cle- 10 rivative oi cellulose textile material containing a partial higher fatty acid esterof a polyhydric alcohol to the action of an aqueous fluid at ele- 14.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
US445202A 1930-04-17 1930-04-17 Textile process and product Expired - Lifetime US2079108A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US445202A US2079108A (en) 1930-04-17 1930-04-17 Textile process and product
GB9570/31A GB380042A (en) 1930-04-17 1931-03-30 Improvements relating to the preparation or treatment of textile materials
FR715183D FR715183A (fr) 1930-04-17 1931-04-13 Perfectionnements dans la préparation ou le traitement des matières textiles

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US445202A US2079108A (en) 1930-04-17 1930-04-17 Textile process and product

Publications (1)

Publication Number Publication Date
US2079108A true US2079108A (en) 1937-05-04

Family

ID=23767973

Family Applications (1)

Application Number Title Priority Date Filing Date
US445202A Expired - Lifetime US2079108A (en) 1930-04-17 1930-04-17 Textile process and product

Country Status (3)

Country Link
US (1) US2079108A (fr)
FR (1) FR715183A (fr)
GB (1) GB380042A (fr)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2433097A (en) * 1944-02-25 1947-12-23 Monsanto Chemicals Polyvinyl acetals plasticized with partial esters of polyhydric alcohols with unsaturated aliphatic acids
US2433098A (en) * 1944-02-25 1947-12-23 Monsanto Chemicals Polyvinyl acetal resin composition
US2436979A (en) * 1944-07-26 1948-03-02 Ind Rayon Corp Tire cord and method of manufacture
US2495714A (en) * 1944-12-13 1950-01-31 Baker Caster Oil Company Cellulose derivative plasticized with an oily diester of a polyhydric alcohol
US2545125A (en) * 1947-02-05 1951-03-13 Addressograph Multigraph Image-forming composition and a process of making it
US3173427A (en) * 1962-02-05 1965-03-16 Eastman Kodak Co Tow with internally incorporated additive
US3296020A (en) * 1964-08-27 1967-01-03 Bibb Mfg Co Process for producing antistatic characteristic in nylon fibers
US3509048A (en) * 1966-10-03 1970-04-28 American Cyanamid Co Softening agent for cotton and for synthetic textile substrates
US3637408A (en) * 1969-05-26 1972-01-25 Formica Corp Decorative laminates carrying removable protective coating
US3928212A (en) * 1972-07-12 1975-12-23 Dai Ichi Kogyo Seiyaku Co Ltd Harmless softening agent for fabrics having excellent moisture absorbability
US20050262643A1 (en) * 2002-12-18 2005-12-01 Blanca Nogues Lopez Lubrication of textile fibres
CN104358117A (zh) * 2014-11-27 2015-02-18 何庆堃 一种牛奶蛋白纤维高弹丝变形油剂

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3264815A (en) * 1964-11-27 1966-08-09 Standard Chem Products Inc Process of texturizing dyed thermoplastic yarns

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2433097A (en) * 1944-02-25 1947-12-23 Monsanto Chemicals Polyvinyl acetals plasticized with partial esters of polyhydric alcohols with unsaturated aliphatic acids
US2433098A (en) * 1944-02-25 1947-12-23 Monsanto Chemicals Polyvinyl acetal resin composition
US2436979A (en) * 1944-07-26 1948-03-02 Ind Rayon Corp Tire cord and method of manufacture
US2495714A (en) * 1944-12-13 1950-01-31 Baker Caster Oil Company Cellulose derivative plasticized with an oily diester of a polyhydric alcohol
US2545125A (en) * 1947-02-05 1951-03-13 Addressograph Multigraph Image-forming composition and a process of making it
US3173427A (en) * 1962-02-05 1965-03-16 Eastman Kodak Co Tow with internally incorporated additive
US3296020A (en) * 1964-08-27 1967-01-03 Bibb Mfg Co Process for producing antistatic characteristic in nylon fibers
US3509048A (en) * 1966-10-03 1970-04-28 American Cyanamid Co Softening agent for cotton and for synthetic textile substrates
US3637408A (en) * 1969-05-26 1972-01-25 Formica Corp Decorative laminates carrying removable protective coating
US3928212A (en) * 1972-07-12 1975-12-23 Dai Ichi Kogyo Seiyaku Co Ltd Harmless softening agent for fabrics having excellent moisture absorbability
US20050262643A1 (en) * 2002-12-18 2005-12-01 Blanca Nogues Lopez Lubrication of textile fibres
CN104358117A (zh) * 2014-11-27 2015-02-18 何庆堃 一种牛奶蛋白纤维高弹丝变形油剂

Also Published As

Publication number Publication date
GB380042A (en) 1932-08-30
FR715183A (fr) 1931-11-26

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