US2079108A - Textile process and product - Google Patents
Textile process and product Download PDFInfo
- Publication number
- US2079108A US2079108A US445202A US44520230A US2079108A US 2079108 A US2079108 A US 2079108A US 445202 A US445202 A US 445202A US 44520230 A US44520230 A US 44520230A US 2079108 A US2079108 A US 2079108A
- Authority
- US
- United States
- Prior art keywords
- cellulose
- fatty acid
- higher fatty
- partial
- cellulose acetate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004753 textile Substances 0.000 title description 23
- 238000000034 method Methods 0.000 title description 14
- 235000014113 dietary fatty acids Nutrition 0.000 description 23
- 239000000194 fatty acid Substances 0.000 description 23
- 229930195729 fatty acid Natural products 0.000 description 23
- 239000000463 material Substances 0.000 description 23
- 230000036961 partial effect Effects 0.000 description 22
- 229920002678 cellulose Polymers 0.000 description 21
- 150000005846 sugar alcohols Polymers 0.000 description 21
- 239000001913 cellulose Substances 0.000 description 20
- 229920002301 cellulose acetate Polymers 0.000 description 19
- -1 fatty acid ester Chemical class 0.000 description 16
- 239000012237 artificial material Substances 0.000 description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 150000002148 esters Chemical class 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 239000004744 fabric Substances 0.000 description 6
- 150000004665 fatty acids Chemical class 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Natural products CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- UPWGQKDVAURUGE-UHFFFAOYSA-N glycerine monooleate Natural products CCCCCCCCC=CCCCCCCCC(=O)OC(CO)CO UPWGQKDVAURUGE-UHFFFAOYSA-N 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 229940049964 oleate Drugs 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000010902 straw Substances 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- KFUSEUYYWQURPO-UHFFFAOYSA-N 1,2-dichloroethene Chemical group ClC=CCl KFUSEUYYWQURPO-UHFFFAOYSA-N 0.000 description 1
- PHDVPEOLXYBNJY-KTKRTIGZSA-N 2-(2-hydroxyethoxy)ethyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCOCCO PHDVPEOLXYBNJY-KTKRTIGZSA-N 0.000 description 1
- MUHFRORXWCGZGE-KTKRTIGZSA-N 2-hydroxyethyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCO MUHFRORXWCGZGE-KTKRTIGZSA-N 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
- 101100005001 Caenorhabditis elegans cah-5 gene Proteins 0.000 description 1
- 229920013683 Celanese Polymers 0.000 description 1
- DQEFEBPAPFSJLV-UHFFFAOYSA-N Cellulose propionate Chemical compound CCC(=O)OCC1OC(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C1OC1C(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C(COC(=O)CC)O1 DQEFEBPAPFSJLV-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 229920006218 cellulose propionate Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- JFVXEJADITYJHK-UHFFFAOYSA-L disodium 2-(3-hydroxy-5-sulfonato-1H-indol-2-yl)-3-oxoindole-5-sulfonate Chemical class [Na+].[Na+].Oc1c([nH]c2ccc(cc12)S([O-])(=O)=O)C1=Nc2ccc(cc2C1=O)S([O-])(=O)=O JFVXEJADITYJHK-UHFFFAOYSA-L 0.000 description 1
- 238000000578 dry spinning Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000010944 ethyl methyl cellulose Nutrition 0.000 description 1
- 239000001761 ethyl methyl cellulose Substances 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000002895 organic esters Chemical class 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C10M2207/289—Partial esters containing free hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/10—Phosphatides, e.g. lecithin, cephalin
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/46—Textile oils
Definitions
- finishes which soften and lubricate the yarns.
- such finishes should preferably .be hydroscopic in order to soften such yarns and should also be-oleaginous in order to lubricate the same.
- the partial higher fatty'acid esters of "polyhydric alcohols that is compounds wherein not all of the hydroxyl groups of the polyhydric alcohols are substituted by the fatty acid radical, produce excellent results, when employed infinishes for such yarns, or are incorporated in the spinning solution from which they are formed. Because of the presence of the unsubstituted hydroxyl group, such compounds are hydroscopic and act. as softening agents for the textile material, and because they are esters of fatty acids, they have lubricating properties.
- polyhydriqalcoh'ols is intended to include such compounds wherein at least one of the hydi'oxyl groups-of the polyhydric alcohols is unsubstituted.
- esters are glycerine. mono- 55 oleate, 'C:Hii(OH)2C1aH33O2; glycerine dl-oleate,
- an appropriate amount of the fatty acid ester say, from 2 to 20% of the weight of the derivative of cellulose present, may be added, and such solution be extruded through orifices into an evaporative atmosphere as in dry spinning, or into a precipitating bath, as in wet spinning.
- the organic derivative of cellulose employed in the textile material may be a. suitable organic ester of cellulose or a cellulose ether.
- suitable organic ester of cellulose or a cellulose ether examples include cellulose esters cellulose acetate, cellulose formate, cellulose propionate and cellui lose butyrate, while examples of cellulose others are ethyl cellulose, methyl cellulose and benzyl cellulose. 7
- the higher fatty acid partial esters of the polyhydric alcohols may be applied to the yarns, filaments or fabrics after their formation. They may .be applied either alone or in admixture with other materials to the textile material. As they are strong solvents for the polyhydric alcohols themselves, fatty acids and soaps, they may be used in finishes for yarns, which finishes also contain such compounds.
- polyhydric alcohol partial fatty may be employed with advantage in the making of printing pastes for application to fabrics in place of oils.
- Such polyhydric alcohol partial fatty may be applied to I textile materials very readily from aqueous emulsions where finishing is desired of yarns, fabrics
- The-term partial .higher fatty acid esters of acid esters are miscible with the polyhydric a1- cohols, which are solvents for fugitive dyestufls for cellulose acetate yarns, such as the acid dyes (e. 'g. the sodium salt of sulfonated indigotine).
- a finish may be made which contains the partial esters and the fugitive dyestufi dissolved in the polyhydric alcohol, and the same may be applied to cellulose acetate yarn for the purpose of yarn identification.
- the partial esters of the polyhydric alcohols have sufilcient solvent power. for such fugitive dye-- stuifs so that solutions of the dyestuff in them alone may be applied to yarn both as a finish and as a fugitive tint.
- Example I A finish is prepared as follows:
- the above mixture is applied to an acetonesoluble cellulose acetate yarn, by causing such yarn to pass over wicks, rollers or other suitable devices for applying such mixture, in their transit to a winding machine.
- the amount of finish applied is 10% of the weight of the yarn.
- the yarn so treated is more pliable, knits with less distortion and irregularities, takes high twists more smoothly and generally exhibits improved properties from a textile manipulation point of view. Fabrics en greigecomprising this yarn scour oil-free very readily and also wet out rapidly.
- glycerine mono-oleate alone is applied in amounts of about 10% of the weight of the yarn, similar benefits are obtained.
- Example II markable ease, the finish diffusing from the yarn quite readily, even in cold water.
- Example III The following spinning solution is prepared Parts by weight Qlycerine mono-oleate The solution is thoroughly mixed and filtered and then is forced through orifices of a spinneret into a warm evaporative atmosphere where the acetone and water are substantially evaporated oil.
- the filaments thus formed are twisted to form yarn.
- the yarn so formed is immediately'ready for textile operations and has the improved properties of the yarn described in the preceding examples.
- Process of forming artificial materials comprising shaping a solution containing an organic derivative of cellulose and a partial higher fatty acid ester of a polyhydric alcohol and setting the same into solid form.
- Process of forming artificial materials comprising shaping a solution containing cellulose 75- vated temperatures.
- Process of forming a textile material of re- I **d lustre comprising subjecting organic cle- 10 rivative oi cellulose textile material containing a partial higher fatty acid esterof a polyhydric alcohol to the action of an aqueous fluid at ele- 14.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US445202A US2079108A (en) | 1930-04-17 | 1930-04-17 | Textile process and product |
GB9570/31A GB380042A (en) | 1930-04-17 | 1931-03-30 | Improvements relating to the preparation or treatment of textile materials |
FR715183D FR715183A (fr) | 1930-04-17 | 1931-04-13 | Perfectionnements dans la préparation ou le traitement des matières textiles |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US445202A US2079108A (en) | 1930-04-17 | 1930-04-17 | Textile process and product |
Publications (1)
Publication Number | Publication Date |
---|---|
US2079108A true US2079108A (en) | 1937-05-04 |
Family
ID=23767973
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US445202A Expired - Lifetime US2079108A (en) | 1930-04-17 | 1930-04-17 | Textile process and product |
Country Status (3)
Country | Link |
---|---|
US (1) | US2079108A (fr) |
FR (1) | FR715183A (fr) |
GB (1) | GB380042A (fr) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2433097A (en) * | 1944-02-25 | 1947-12-23 | Monsanto Chemicals | Polyvinyl acetals plasticized with partial esters of polyhydric alcohols with unsaturated aliphatic acids |
US2433098A (en) * | 1944-02-25 | 1947-12-23 | Monsanto Chemicals | Polyvinyl acetal resin composition |
US2436979A (en) * | 1944-07-26 | 1948-03-02 | Ind Rayon Corp | Tire cord and method of manufacture |
US2495714A (en) * | 1944-12-13 | 1950-01-31 | Baker Caster Oil Company | Cellulose derivative plasticized with an oily diester of a polyhydric alcohol |
US2545125A (en) * | 1947-02-05 | 1951-03-13 | Addressograph Multigraph | Image-forming composition and a process of making it |
US3173427A (en) * | 1962-02-05 | 1965-03-16 | Eastman Kodak Co | Tow with internally incorporated additive |
US3296020A (en) * | 1964-08-27 | 1967-01-03 | Bibb Mfg Co | Process for producing antistatic characteristic in nylon fibers |
US3509048A (en) * | 1966-10-03 | 1970-04-28 | American Cyanamid Co | Softening agent for cotton and for synthetic textile substrates |
US3637408A (en) * | 1969-05-26 | 1972-01-25 | Formica Corp | Decorative laminates carrying removable protective coating |
US3928212A (en) * | 1972-07-12 | 1975-12-23 | Dai Ichi Kogyo Seiyaku Co Ltd | Harmless softening agent for fabrics having excellent moisture absorbability |
US20050262643A1 (en) * | 2002-12-18 | 2005-12-01 | Blanca Nogues Lopez | Lubrication of textile fibres |
CN104358117A (zh) * | 2014-11-27 | 2015-02-18 | 何庆堃 | 一种牛奶蛋白纤维高弹丝变形油剂 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3264815A (en) * | 1964-11-27 | 1966-08-09 | Standard Chem Products Inc | Process of texturizing dyed thermoplastic yarns |
-
1930
- 1930-04-17 US US445202A patent/US2079108A/en not_active Expired - Lifetime
-
1931
- 1931-03-30 GB GB9570/31A patent/GB380042A/en not_active Expired
- 1931-04-13 FR FR715183D patent/FR715183A/fr not_active Expired
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2433097A (en) * | 1944-02-25 | 1947-12-23 | Monsanto Chemicals | Polyvinyl acetals plasticized with partial esters of polyhydric alcohols with unsaturated aliphatic acids |
US2433098A (en) * | 1944-02-25 | 1947-12-23 | Monsanto Chemicals | Polyvinyl acetal resin composition |
US2436979A (en) * | 1944-07-26 | 1948-03-02 | Ind Rayon Corp | Tire cord and method of manufacture |
US2495714A (en) * | 1944-12-13 | 1950-01-31 | Baker Caster Oil Company | Cellulose derivative plasticized with an oily diester of a polyhydric alcohol |
US2545125A (en) * | 1947-02-05 | 1951-03-13 | Addressograph Multigraph | Image-forming composition and a process of making it |
US3173427A (en) * | 1962-02-05 | 1965-03-16 | Eastman Kodak Co | Tow with internally incorporated additive |
US3296020A (en) * | 1964-08-27 | 1967-01-03 | Bibb Mfg Co | Process for producing antistatic characteristic in nylon fibers |
US3509048A (en) * | 1966-10-03 | 1970-04-28 | American Cyanamid Co | Softening agent for cotton and for synthetic textile substrates |
US3637408A (en) * | 1969-05-26 | 1972-01-25 | Formica Corp | Decorative laminates carrying removable protective coating |
US3928212A (en) * | 1972-07-12 | 1975-12-23 | Dai Ichi Kogyo Seiyaku Co Ltd | Harmless softening agent for fabrics having excellent moisture absorbability |
US20050262643A1 (en) * | 2002-12-18 | 2005-12-01 | Blanca Nogues Lopez | Lubrication of textile fibres |
CN104358117A (zh) * | 2014-11-27 | 2015-02-18 | 何庆堃 | 一种牛奶蛋白纤维高弹丝变形油剂 |
Also Published As
Publication number | Publication date |
---|---|
GB380042A (en) | 1932-08-30 |
FR715183A (fr) | 1931-11-26 |
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