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US2038723A - Treatment and manufacture of textile materials - Google Patents

Treatment and manufacture of textile materials Download PDF

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Publication number
US2038723A
US2038723A US585381A US58538132A US2038723A US 2038723 A US2038723 A US 2038723A US 585381 A US585381 A US 585381A US 58538132 A US58538132 A US 58538132A US 2038723 A US2038723 A US 2038723A
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fibres
materials
substances
treatment
manufacture
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US585381A
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Dreyfus Henry
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Henry Dreyfuss Associates LLC
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Henry Dreyfuss Associates LLC
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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
    • D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
    • D06M11/71—Salts of phosphoric acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D06M11/57—Sulfates or thiosulfates of elements of Groups 3 or 13 of the Periodic Table, e.g. alums
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/64—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
    • D06M11/65—Salts of oxyacids of nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/80—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides
    • D06M11/82—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides with boron oxides; with boric, meta- or perboric acids or their salts, e.g. with borax
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/10—Processes in which the treating agent is dissolved or dispersed in organic solvents; Processes for the recovery of organic solvents thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2904—Staple length fiber
    • Y10T428/2907—Staple length fiber with coating or impregnation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2964—Artificial fiber or filament
    • Y10T428/2965—Cellulosic

Definitions

  • roughness is imparted to the staple fibres by means of substances deposited onto the surface of the fibresor of the materials from which they'are produced, such substances being capable of ready removal without modification of. the material of the fibres.
  • the substances which are with advantage of a crystalline nature, adhere with suflicient tenacity and are applied in sufiicient quantity to increase to 25 aconsiderable degree the coefficient of friction of the materials, or, at any rate, the adhesion between the treated fibres during the spinning operation. After this operation, the substances can be removed to leave the fibres unaffected.
  • the substances may be applied in various ways. For example, a solution of the substance in a solvent inert to the textile material under treatment is applied and crystals or particles are deposited onto the materials either by evaporation or by precipitation. A further method consists in forming the substance itself upon the materials by chemical reaction to leave the substance precipitated on the surface of the material. Yet a Great Britain February 10, I
  • the formation of the rough deposit on the 5 fibres may be carried out either on the filaments from which the fibres are produced, or on the fibres, or on both.
  • filaments as untwisted or twisted threads may be run over a wick, roller, or other device adapted to apply the 10 desired amount of the liquid containing the substance, or placed as hanks or other packages in the liquid, and more or less completely dried before being cut into fibre.
  • the cut fibres may be placed, loose or in bags, perforated boxes, or other containers, into a bath of the liquid in batches or as a continuous process and afterwards more or less completely dried before spinning.
  • the liquid treatment may be carried out in one or more stages.
  • the removal of the substances may be carried out either after the fibres have been spun, or after the spun yarns have been woven, knitted, or otherwise formed into fabrics or articles, and may not necessarily involve a special treatment, but may be carried out in any washing or like treatment to which the materials are ordinarily subjected, for example, the scouring carried out in the finishing of fabrics.
  • the substance applied should be capable of removal by a solvent inert to the fibres to avoid any detrimental 40 action on the fibres. It will beunderstoodftherefore, that while solvents such as water or alcohol which are of the requisite harmless nature can in general be used, it is possible to use on some materials solvents'which would be harmful to others, by reason of either physical or chemical action. When there is this possibility, care must be exercised in choosing the solvent to be used.
  • the substances themselves shouldnot be capable of exerting any detrimental action on the materials.
  • a desirable property in the materials is that they should be non-hygroscopic, particularly in cases where the filaments or fibres are required to be stored before use.
  • the coating it is preferred to use substances which are highly soluble in the solvent employed in applying the coating, so that a more or less highly concentrated solution may be employed in quantities sumcient to give the right amount of coating, and leaving 'compara 'vely little of the solvent to be dried of! the materials. Similar considerations will also apply when the substances are actually formed on the materials by that comparatively little liquor remains to be dried off.
  • the applying treatment may be carried out with heated solutions, which are particularly advantageous where the substances are more soluble at high temperatures than at low, so that cooling can be resorted to to accelerate thedeposition of the substances.
  • the amount of roughening' substance required to be deposited is comparatively small (say 2% or thereabouts of the weight of the fibres) and should in any case be kept down to suchamount that there is little danger of excessive quantities being rubbed off during handling of the filaments or fibres.
  • ammonium, potassium, sodium, aluminium,barium, bismuth, iron, magnesium, lithium, and zinc may be employed.
  • ammonium phosphate ammonium borate
  • ammonium borate ammonium borate
  • the alums for example potash alum, and boric acid'may be emplo Organic bodies may be used..
  • an aqueous solution for example an aqueous solution.
  • lead chloride which may be formed by first treating the materials with a solution of lead acetate, for example, and afterwards with a solution of a chloride.
  • Lead chloride though practically insoluble in cold water, is readily removed by means of hot water, and so, caneasily be secured off the materials.
  • Such substances can be deposited by passing filaments in turn over applying means supplied with the necessary reagents, before cutting, or by treating filaments with one reagent andv the fibres with the other, or by treating the fibres solely after cutting.
  • the removal of the same solvent may be used as that from which it was deposited, or other solvents may be used if desired or necessary.
  • the substances may, of course, be recovered after removal, either by crystallization or drying in readiness for the preparation of a further solution, or by concentration or the wash liquor up to the requisite strength for re-use.
  • Patent is:-

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Description

Patented Apr. 28, 193 6 UNITED STATES TREATMENT AND PATENT OFFICE some F 'No. 585,381. In
2 Claims.
This invention relates to the treatment and manufacture of textile materials. and in particular to the manufacture of staple fibre and spun yarns, being concerned with a method of roughening staple fibre. As is-well' known, filaments of artificial material such as organic derivatives of cellulose and cellulosic artificial silks, and to a less degree, natural silk, are of a smooth nature, and thus have a very low coemcient of friction. This renders staple fibres of such materials extremely liable to slip and thus more dinicult to spin into spun yarns than the relatively rough natural fibres, such as cotton and wool. The object of the present invention is to over- 15 come this tendency in a simple manner.
According to'the invention, roughness is imparted to the staple fibres by means of substances deposited onto the surface of the fibresor of the materials from which they'are produced, such substances being capable of ready removal without modification of. the material of the fibres. The substances, which are with advantage of a crystalline nature, adhere with suflicient tenacity and are applied in sufiicient quantity to increase to 25 aconsiderable degree the coefficient of friction of the materials, or, at any rate, the adhesion between the treated fibres during the spinning operation. After this operation, the substances can be removed to leave the fibres unaffected. 30 By regulation of the precise quantity of solution applied to the fibres, and/or its concentration, the amount of substance deposited on the fibres may easily be regulated to give the rough effect desired.
The invention contemplates in particular the application of substances readily removable by solution in solvents which are in no way detrimental to the materials of the fibres, The invention therefore includes within its scope not only the fibres which have been treated in the manner above indicated, and yarns or threads containing such fibres, and fabrics or articles made therefrom, but also methods of treating or preparing such fibres, both before and after spinning.
The substances may be applied in various ways. For example, a solution of the substance in a solvent inert to the textile material under treatment is applied and crystals or particles are deposited onto the materials either by evaporation or by precipitation. A further method consists in forming the substance itself upon the materials by chemical reaction to leave the substance precipitated on the surface of the material. Yet a Great Britain February 10, I
further method consists in subliming the substance and depositing it on the materials by having the materials in an atmosphere containing the vapours of the substance. a 4
The formation of the rough deposit on the 5 fibres may be carried out either on the filaments from which the fibres are produced, or on the fibres, or on both. For example, filaments as untwisted or twisted threads may be run over a wick, roller, or other device adapted to apply the 10 desired amount of the liquid containing the substance, or placed as hanks or other packages in the liquid, and more or less completely dried before being cut into fibre. Similarly, the cut fibres may be placed, loose or in bags, perforated boxes, or other containers, into a bath of the liquid in batches or as a continuous process and afterwards more or less completely dried before spinning. The liquid treatment may be carried out in one or more stages.
The removal of the substances may be carried out either after the fibres have been spun, or after the spun yarns have been woven, knitted, or otherwise formed into fabrics or articles, and may not necessarily involve a special treatment, but may be carried out in any washing or like treatment to which the materials are ordinarily subjected, for example, the scouring carried out in the finishing of fabrics.
The invention is applicable to all kinds of smooth materials, e. g., filaments or fibres of cellulose acetate or other organic derivative of-cellulose, e. g. cellulose formate, propionate, and butyrate, and ethyl, methyl and benzyl cellulose,
or of 'cellulosic materials such as viscose, nitrocellulose and cuprammonium artificial silk, and natural silk.
It has already been mentioned-that the substance applied should be capable of removal by a solvent inert to the fibres to avoid any detrimental 40 action on the fibres. It will beunderstoodftherefore, that while solvents such as water or alcohol which are of the requisite harmless nature can in general be used, it is possible to use on some materials solvents'which would be harmful to others, by reason of either physical or chemical action. When there is this possibility, care must be exercised in choosing the solvent to be used.
Similarly, the substances themselves shouldnot be capable of exerting any detrimental action on the materials. A desirable property in the materials is that they should be non-hygroscopic, particularly in cases where the filaments or fibres are required to be stored before use.
-' material results are quite suitable for the purpose of chemical action, so
7 if imparting the desired It is to be understood that the applied substances need not raise the actual coefiicient of friction of the fibres, since substances which themselves have a lower coefficient of friction than the fibres but provide sufficient projections the invention.
In order to facilitate the application of the coating, it is preferred to use substances which are highly soluble in the solvent employed in applying the coating, so that a more or less highly concentrated solution may be employed in quantities sumcient to give the right amount of coating, and leaving 'compara 'vely little of the solvent to be dried of! the materials. Similar considerations will also apply when the substances are actually formed on the materials by that comparatively little liquor remains to be dried off. In certain cases the applying treatment may be carried out with heated solutions, which are particularly advantageous where the substances are more soluble at high temperatures than at low, so that cooling can be resorted to to accelerate thedeposition of the substances.
It will be understood that the amount of roughening' substance required to be deposited is comparatively small (say 2% or thereabouts of the weight of the fibres) and should in any case be kept down to suchamount that there is little danger of excessive quantities being rubbed off during handling of the filaments or fibres.
It is immaterial whether colouration of the from the treatment, provided that any undesired staining which occurs can readily be removed.
Bearing in mind the above-mentioned considerations as to suitability of the substances which may be applied to different kinds of filaments or fibres, there is a wide range of bodies capable roughness. For-example manyiinorganic salts, such as chlorides, ni-
- hydrous zinc sulphate;
and sodium and trates, sulphates, carbonates and bicarbonates, phosphates, and borates, of ammonium, potassium, sodium, aluminium,barium, bismuth, iron, magnesium, lithium, and zinc may be employed. Examples of theseare ammonium, barium, or lead chloride; barium, potassium, or sodium nitrate; amminium, ammonium, iron, potassium, or sodium sulphate; hydrated or anv carbonates and bicarbonates of ammonium and the alkali metals; ammonium or sodium phosphate;
ammonium phosphate; ammonium borate. Likewise, the alums, for example potash alum, and boric acid'may be emplo Organic bodies may be used.. For example an aqueous solution.
acetates, oxalates, tartrates, and many of the sodium salts of organic acids. Examples of these calcium, and lead acetate; potassium, sodium, and magnesium oxalate; potassium hydrogen oxalate, ammonium oxalate; potassium o nium tartrate; Rochelle salt and tartaremetic; naphthalene; benzoic, and tartaric acids.
Most of the above alate; ammobodies may be applied as Boric acid and benzoic acid, however, require to be applied from a solution in an organic solvent, such as alcohol.
As an example of a substance which may be formed on the materials by chemical reaction and magnesium citric, phthalic, salicylic,
may be mentioned lead chloride, which may be formed by first treating the materials with a solution of lead acetate, for example, and afterwards with a solution of a chloride. Lead chloride, though practically insoluble in cold water, is readily removed by means of hot water, and so, caneasily be secured off the materials. Such substances can be deposited by passing filaments in turn over applying means supplied with the necessary reagents, before cutting, or by treating filaments with one reagent andv the fibres with the other, or by treating the fibres solely after cutting.
Qn the removal of the same solvent may be used as that from which it was deposited, or other solvents may be used if desired or necessary. The substances may, of course, be recovered after removal, either by crystallization or drying in readiness for the preparation of a further solution, or by concentration or the wash liquor up to the requisite strength for re-use.
applied substances, the
Patent is:-
1. In a process for the manufacture of staple fibre, the step of temporarily roughening the material of. the fibre so as to facilitate spinning by applying to the material of the fibre a concentrated alcoholic solution of a weak acid se-. lected from the group consisting of benzoic acid and boric acid, and depositing said acid from said solution in crystalline form on the surface of said material.
2. In a. process for the manufacture of staple fibre comprising cellulose acetate, the step of temporarily toughening the material of the fibre so as to facilitate spinning by applying to the material'of the fibre a concentrated alcoholic solution of a weak acid selected from the group consisting of benzoic acid and boric acid, and .depositing said aci from said solution in crystalline form on the surface of said material.
' HENRY DREYFUS.
US585381A 1931-02-10 1932-01-07 Treatment and manufacture of textile materials Expired - Lifetime US2038723A (en)

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GB4197/31A GB372797A (en) 1931-02-10 1931-02-10 Improvements in or relating to the treatment and manufacture of textile materials

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2488587A (en) * 1945-06-07 1949-11-22 Celanese Corp Process for treating organic substitution derivative of cellulose textile materials
US2864723A (en) * 1956-08-23 1958-12-16 American Cyanamid Co Acid resistant cellulosic material and process for producing same
US2966428A (en) * 1956-04-05 1960-12-27 Celanese Corp Heat stable saponified cellulose ester filamentary material and process of making
US3203821A (en) * 1961-05-25 1965-08-31 Plate Gmbh Dr Flocks for the production of velvet-like or plush-like materials and process for theproduction of such materials by electrostatic means
US3362846A (en) * 1964-04-06 1968-01-09 Dow Chemical Co Method of coating particulate material with metal carbonates

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2488587A (en) * 1945-06-07 1949-11-22 Celanese Corp Process for treating organic substitution derivative of cellulose textile materials
US2966428A (en) * 1956-04-05 1960-12-27 Celanese Corp Heat stable saponified cellulose ester filamentary material and process of making
US2864723A (en) * 1956-08-23 1958-12-16 American Cyanamid Co Acid resistant cellulosic material and process for producing same
US3203821A (en) * 1961-05-25 1965-08-31 Plate Gmbh Dr Flocks for the production of velvet-like or plush-like materials and process for theproduction of such materials by electrostatic means
US3362846A (en) * 1964-04-06 1968-01-09 Dow Chemical Co Method of coating particulate material with metal carbonates

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Publication number Publication date
FR730752A (en) 1932-08-24
GB372798A (en) 1932-05-10
GB372797A (en) 1932-05-10

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