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US20070006526A1 - Fuel pellet briquettes from biomass and recovered coal slurries - Google Patents

Fuel pellet briquettes from biomass and recovered coal slurries Download PDF

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Publication number
US20070006526A1
US20070006526A1 US11/176,603 US17660305A US2007006526A1 US 20070006526 A1 US20070006526 A1 US 20070006526A1 US 17660305 A US17660305 A US 17660305A US 2007006526 A1 US2007006526 A1 US 2007006526A1
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United States
Prior art keywords
biomass
burnable
briquettes
coal
waste
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US11/176,603
Inventor
Donald Cullen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
New Energy USA LLC
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New Energy USA LLC
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Filing date
Publication date
Application filed by New Energy USA LLC filed Critical New Energy USA LLC
Priority to US11/176,603 priority Critical patent/US20070006526A1/en
Assigned to NEW ENERGY USA, LLC reassignment NEW ENERGY USA, LLC ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: CULLEN, DONALD L.
Publication of US20070006526A1 publication Critical patent/US20070006526A1/en
Abandoned legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L5/00Solid fuels
    • C10L5/02Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
    • C10L5/34Other details of the shaped fuels, e.g. briquettes
    • C10L5/36Shape
    • C10L5/361Briquettes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/42Solid fuels essentially based on materials of non-mineral origin on animal substances or products obtained therefrom, e.g. manure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/46Solid fuels essentially based on materials of non-mineral origin on sewage, house, or town refuse
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/48Solid fuels essentially based on materials of non-mineral origin on industrial residues and waste materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

Definitions

  • the present invention generally relates to for formation of environmentally friendly, fuel pellet briquettes and more particularly to their formation from biomass (e.g., municipal solid waste (MSW) burnable fractions), recovered coal from coal slurry ponds, and binder.
  • biomass e.g., municipal solid waste (MSW) burnable fractions
  • MSW municipal solid waste
  • biomass sources provide an opportunity as a fuel source. Often, such biomass is a “waste” material, such as sawdust from lumber mills, waste wood pallets, construction wood waste, and the like. Additionally, cellulose and like burnable fractions from municipal solid waste (MSW) represents another potential fuel source, once it is successfully separated from the entire MSW.
  • MSW municipal solid waste
  • the invention makes burnable renewal fuel (RF) briquettes from recovered coal from coal slurry ponds, biomass, and a binder.
  • the briquettes may be augmented with one or more of recovered environmental burnable fraction from municipal solid waste (MSW), agricultural livestock waste, lumber processing residue, solid wood waste material, agricultural by-products and crops, and like burnable waste material.
  • the method for making burnable renewal fuel (RF) briquettes includes the steps of recovering coal from coal slurry ponds; recovering biomass; adding a binder to said recovered coal and said biomass; and forming solid burnable RF fuel briquettes therefrom.
  • FIG. 1 is a simplified block diagram showing the formation of the burnable renewal fuel (RF) briquettes of the present invention.
  • the inventive burnable renewal fuel (RF) briquettes are formed from three primary materials: recovered coal from coal slurry ponds; biomass; and a binder therefor.
  • coal fines are unimportant, as such fines otherwise would remain burden to the owner; rather than an opportunity to utilize the energy component of such coal fines.
  • a primary biomass source is solid waste materials of the type typified by MSW, which traditionally have presented problems of disposal. These disposal difficulties have become increasingly critical as populations have expanded and as the per capita production of solid waste has increased.
  • industrial and home refuse or MSW typically comprises several components or fractions, which are worth reclaiming.
  • glass, ferrous and non-ferrous metals, plastic, and paper components are sufficiently valuable to justify their separation from composite MSW.
  • solid waste has been disposed of by incineration and/or landfill. With the present concern over problems associated with the protection of the environment and because of scarcity of landfill space and governmental regulations, both of these traditional techniques of disposal have become undesirable.
  • separation systems to remain efficient, must be capable of having a reasonably high throughput rate for the material processed and since MSW varies from one area to the next, and between collections, the separation system also must be capable of handling materials, which vary widely in nature and composition.
  • throughput rates of conventional systems have not been adequately high enough to derive efficiencies permitting the use of equipment in municipalities of small or medium size.
  • some technique must be found to effectively increase such output rates.
  • MSW separation system is represented in U.S. Pat. Nos. 4,844,351, 4,540,495, and 4,342,830, this disclosures of which are expressly incorporated herein by reference.
  • Additional biomass includes, for example, agricultural animal waste (e.g., manure); agricultural livestock waste nutrients such as, for example, litter, wood shavings, rice hulls, straw, and like animal bedding; forest related waste, such as, for example, mill and timber harvesting residue, pre-commercial thinning lumber, slash, and brush; sold wood waster, such as, for example, waste wooden pallets, crates, dunnage, manufacturing and construction wood wastes (other than pressure-treated, chemically treated, or painted wood waste), landscape or right-of-way tree trimmings, and the like; agricultural sources including, for example, bagasse, orchard tree crops, vineyard, grain, legumes, sugar, and like crop by-products and residues; and the like and mixtures thereof.
  • agricultural animal waste e.g., manure
  • agricultural livestock waste nutrients such as, for example, litter, wood shavings, rice hulls, straw, and like animal bedding
  • forest related waste such as, for example, mill and timber harvesting residue, pre-commercial thinning lumber, s
  • biomass is suitable for inclusion in the inventive fuel pellets or briquettes.
  • Individual biomass components often have a size of around 0.25 inches or smaller, which is suitable for use in the present invention.
  • a wide variety of materials are suitable for use as a binder in making the inventive fuel briquettes.
  • the binder similarly can be a waste product and/or it can be a new binder material.
  • molten hydrocarbons e.g., asphalt
  • Additional binders include, for example, wood tar, starch (e.g., corn starch), and the like. Burnable binders enhance the process and the value of the inventive fuel briquettes. Just enough binder is used in order to produce fuel briquettes that have sufficient mechanical strength to be handled from production to burning.
  • Briquetters of choice often influence the choice and amount of binder.
  • Representative briquetters include the Model DH briquetters (K.R. Komarek, Inc., Elk Grove, Ill. 60007). Heat and pressure typically is used by commercial briquetting equipment and can be used for making the inventive fuel briquettes.
  • coal fines are recovered in step 10 of the process.
  • Biomass is recovered and processed in step 12 of the process.
  • the suitable binder is provided in step 14 of the process.
  • Each of these products is sent to briquetting step 16 of the process. Withdrawn from briquetting step 16 are the desired fuel briquettes, 18 .
  • the ratio of coal fines:biomass:binder particle size thereof more often is determined by availability of each component, requirements of the briquette equipment, intended use for the fuel briquettes, and like factors known to those skilled in the art.
  • a ratio of about 5% to about 25% biomass with the balance being coal plus binder is acceptable for briquetting.
  • Final briquette sizes often are about 0.5 by about 2 inches in size.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

The invention makes burnable renewal fuel (RF) briquettes from recovered coal from coal slurry ponds, biomass, and a binder. The briquettes may be augmented with one or more of recovered environmental burnable fraction from municipal solid waste (MSW), agricultural livestock waste, lumber processing residue, solid wood waste material, agricultural by-products and crops, and like burnable waste material. Accordingly, the method for making burnable renewal fuel (RF) briquettes includes the steps of recovering coal from coal slurry ponds; recovering biomass; adding a binder to said recovered coal and said biomass; and forming solid burnable RF fuel briquettes therefrom.

Description

    CROSS-REFERENCE TO RELATED APPLICATIONS
  • None.
  • STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH
  • Not applicable.
  • BACKGROUND OF THE INVENTION
  • The present invention generally relates to for formation of environmentally friendly, fuel pellet briquettes and more particularly to their formation from biomass (e.g., municipal solid waste (MSW) burnable fractions), recovered coal from coal slurry ponds, and binder.
  • A variety of biomass sources provide an opportunity as a fuel source. Often, such biomass is a “waste” material, such as sawdust from lumber mills, waste wood pallets, construction wood waste, and the like. Additionally, cellulose and like burnable fractions from municipal solid waste (MSW) represents another potential fuel source, once it is successfully separated from the entire MSW.
  • In an environmentally related area, abandoned coal fines represent a continuing and unnecessary liability to the mine owner. In the United States alone, there are an estimated one billion tons of economically recoverable coal fines. This is the energy equivalent of approximately 10 years of electricity needs for the United States.
  • Uniting these two fuel sources would represent an opportunity to reuse and recycle materials that otherwise represent a disposal burden. It is to such an opportunity that the present invention is addressed.
  • BRIEF SUMMARY OF THE INVENTION
  • The invention makes burnable renewal fuel (RF) briquettes from recovered coal from coal slurry ponds, biomass, and a binder. The briquettes may be augmented with one or more of recovered environmental burnable fraction from municipal solid waste (MSW), agricultural livestock waste, lumber processing residue, solid wood waste material, agricultural by-products and crops, and like burnable waste material.
  • Accordingly, the method for making burnable renewal fuel (RF) briquettes includes the steps of recovering coal from coal slurry ponds; recovering biomass; adding a binder to said recovered coal and said biomass; and forming solid burnable RF fuel briquettes therefrom.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • For a fuller understanding of the nature and advantages of the present invention, reference should be had to the following detailed description taken in connection with the accompanying drawings, in which:
  • FIG. 1 is a simplified block diagram showing the formation of the burnable renewal fuel (RF) briquettes of the present invention.
  • It will be described in further detail below.
  • DETAILED DESCRIPTION OF THE INVENTION
  • The inventive burnable renewal fuel (RF) briquettes are formed from three primary materials: recovered coal from coal slurry ponds; biomass; and a binder therefor.
  • Coal Slurry Fines Component
  • One coal slurry recovery system is represented in U.S. Pat. No. 6,544,425 (the '425 patent), the disclosure of which is expressly incorporated herein by reference. The '425 patent employs a tank that dewaters coal slurry ponds for recovering coal fines from their admixture with water and contaminants, that forms the coal slurry pond. Other separation techniques and equipment could be used also, provided that the recovered coal fines were not overly contaminated with heavy metals, chlorine sources, and like materials whose presence is no desired when combustion of the coal fines is implemented. Purity of the coal fines is more important than the recovery rate of the process to be employed. That is, the final fuel briquette must comply with current laws regarding combustion by-products and like environmental laws and regulations.
  • The particular type or grade of coal fines is unimportant, as such fines otherwise would remain burden to the owner; rather than an opportunity to utilize the energy component of such coal fines.
  • Biomass Component
  • A primary biomass source is solid waste materials of the type typified by MSW, which traditionally have presented problems of disposal. These disposal difficulties have become increasingly critical as populations have expanded and as the per capita production of solid waste has increased. In addition to using waste as a source of fuel or compost, industrial and home refuse or MSW typically comprises several components or fractions, which are worth reclaiming. In particular, glass, ferrous and non-ferrous metals, plastic, and paper components are sufficiently valuable to justify their separation from composite MSW. Conventionally, such solid waste has been disposed of by incineration and/or landfill. With the present concern over problems associated with the protection of the environment and because of scarcity of landfill space and governmental regulations, both of these traditional techniques of disposal have become undesirable. Further, separation systems, to remain efficient, must be capable of having a reasonably high throughput rate for the material processed and since MSW varies from one area to the next, and between collections, the separation system also must be capable of handling materials, which vary widely in nature and composition. To the present, the throughput rates of conventional systems have not been adequately high enough to derive efficiencies permitting the use of equipment in municipalities of small or medium size. However, because of the ever-increasing rigid requirements for carrying out waste treatment and because of the increasing scarcity of landfill space, some technique must be found to effectively increase such output rates.
  • To achieve the efficient separation of more valuable fractions of MSW and to derive environmentally safe, marketable compost or renewal fuel product, a waste treatment process should be carried out wherein raw MSW is passed through a variety of reduction, separation, and related treatment stages. These stages serve to remove inorganic components such as metals, glass, and plastics from the organic component of the MSW. The segregated or separated by-product materials, such as ferrous and non-ferrous metals, glass, and plastic, increasingly are becoming valuable resources worthy of the expenditure of capital for effective separation equipment. Of course, the quality and resultant value of the organic material also is dependent upon the corresponding quality of separation, the presence of plastics, glass, or other foreign particles being undesirable or unacceptable for most commercial applications.
  • A broad variety of separation techniques have been known to industry. Among those, both manual and automatic techniques have been used. The manual technique that generally involves human pickers usually is neither cost effective nor desirable. The automatic techniques which rely on the fraction size for sorting by a grizzly or the magnetic characteristics of the fraction or the density of the fraction for air separation have generally not been employed by industry in such a manner as to eliminate the extensive need of human pickers to further separate MSW into the various fractions where air separation techniques have been applied to municipal waste separation. Designers have found that achieving high quality separation within reasonable cost limits proves to be an elusive goal. Since municipal waste varies widely in geographical, as well as daily, make-up and consistency, a uniform product is not available for separation treatment. Therefore, any separation system involving the sorting of solid waste must be capable of handling a wide variation of waste components.
  • One acceptable such MSW separation system is represented in U.S. Pat. Nos. 4,844,351, 4,540,495, and 4,342,830, this disclosures of which are expressly incorporated herein by reference.
  • Additional biomass includes, for example, agricultural animal waste (e.g., manure); agricultural livestock waste nutrients such as, for example, litter, wood shavings, rice hulls, straw, and like animal bedding; forest related waste, such as, for example, mill and timber harvesting residue, pre-commercial thinning lumber, slash, and brush; sold wood waster, such as, for example, waste wooden pallets, crates, dunnage, manufacturing and construction wood wastes (other than pressure-treated, chemically treated, or painted wood waste), landscape or right-of-way tree trimmings, and the like; agricultural sources including, for example, bagasse, orchard tree crops, vineyard, grain, legumes, sugar, and like crop by-products and residues; and the like and mixtures thereof.
  • Thus, it will be apparent that a wide variety of biomass is suitable for inclusion in the inventive fuel pellets or briquettes. Individual biomass components often have a size of around 0.25 inches or smaller, which is suitable for use in the present invention.
  • Binder Component
  • A wide variety of materials are suitable for use as a binder in making the inventive fuel briquettes. The binder similarly can be a waste product and/or it can be a new binder material. Traditionally, molten hydrocarbons (e.g., asphalt) have been used to bind coal fines together for forming briquettes. Additional binders include, for example, wood tar, starch (e.g., corn starch), and the like. Burnable binders enhance the process and the value of the inventive fuel briquettes. Just enough binder is used in order to produce fuel briquettes that have sufficient mechanical strength to be handled from production to burning.
  • Briquetting Equipment
  • Briquetters of choice often influence the choice and amount of binder. Representative briquetters include the Model DH briquetters (K.R. Komarek, Inc., Elk Grove, Ill. 60007). Heat and pressure typically is used by commercial briquetting equipment and can be used for making the inventive fuel briquettes.
  • Briquetting Process
  • Referring to FIG. 1, coal fines are recovered in step 10 of the process. Biomass is recovered and processed in step 12 of the process. The suitable binder is provided in step 14 of the process. Each of these products is sent to briquetting step 16 of the process. Withdrawn from briquetting step 16 are the desired fuel briquettes, 18. The ratio of coal fines:biomass:binder particle size thereof more often is determined by availability of each component, requirements of the briquette equipment, intended use for the fuel briquettes, and like factors known to those skilled in the art. A ratio of about 5% to about 25% biomass with the balance being coal plus binder is acceptable for briquetting. Final briquette sizes often are about 0.5 by about 2 inches in size.
  • While the invention has been described with reference to a preferred embodiment, those skilled in the art will understand that various changes may be made and equivalents may be substituted for elements thereof without departing from the scope of the invention. In addition, many modifications may be made to adapt a particular situation or material to the teachings of the invention without departing from the essential scope thereof. Therefore, it is intended that the invention not be limited to the particular embodiment disclosed as the best mode contemplated for carrying out this invention, but that the invention will include all embodiments falling within the scope of the appended claims. In this application all units are in the metric system and all amounts and percentages are by weight, unless otherwise expressly indicated. Also, all citations referred herein are expressly incorporated herein by reference.

Claims (10)

1. Method for making burnable renewal fuel (RF) briquettes, which comprises the steps of:
(a) recovering coal from coal slurry ponds;
(b) recovering biomass;
(c) adding a binder to said recovered coal and said biomass; and
(d) forming solid burnable RF fuel briquettes therefrom.
2. The method of claim 1, wherein said biomass is one or more of a burnable cellulose fraction of municipal solid waste (MSW), animal waste, agricultural livestock waste nutrients, wood, bagasse, or agricultural crop waste.
3. The method of claim 2, wherein said biomass is one or more of manure, litter, wood shavings, rice hulls, straw, mill and timber harvesting residue, pre-commercial thinning lumber, slash, brush, wooden pallets, crates, dunnage, manufacturing and construction wood wastes, landscape and right-of-way tree trimmings, bagasse, orchard tree crops, vineyard, grain, legumes, or sugar.
4. The method of claim 1, wherein said binder is a hydrocarbon.
5. The method of claim 4, wherein said hydrocarbon is one or more of wood tar, asphalt, or starch.
6. The briquette made according to the process of claim 1.
7. The briquette made according to the process of claim 2.
8. The briquette made according to the process of claim 3.
9. The briquette made according to the process of claim 4.
10. The briquette made according to the process of claim 5.
US11/176,603 2005-07-07 2005-07-07 Fuel pellet briquettes from biomass and recovered coal slurries Abandoned US20070006526A1 (en)

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