US20040173621A1 - Self-sealing container for pressurized electro-conducting media - Google Patents
Self-sealing container for pressurized electro-conducting media Download PDFInfo
- Publication number
- US20040173621A1 US20040173621A1 US10/378,169 US37816903A US2004173621A1 US 20040173621 A1 US20040173621 A1 US 20040173621A1 US 37816903 A US37816903 A US 37816903A US 2004173621 A1 US2004173621 A1 US 2004173621A1
- Authority
- US
- United States
- Prior art keywords
- sealing
- self
- container
- shells
- ball
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000007789 sealing Methods 0.000 title claims abstract description 22
- 239000007787 solid Substances 0.000 claims abstract description 13
- 238000003487 electrochemical reaction Methods 0.000 claims abstract description 7
- 239000004033 plastic Substances 0.000 claims abstract description 6
- 239000002985 plastic film Substances 0.000 claims abstract 2
- 229920006255 plastic film Polymers 0.000 claims abstract 2
- 239000010409 thin film Substances 0.000 claims abstract 2
- 239000000463 material Substances 0.000 abstract description 6
- 239000004809 Teflon Substances 0.000 abstract 1
- 229920006362 Teflon® Polymers 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 230000004075 alteration Effects 0.000 description 1
- 238000003491 array Methods 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
- H01M8/247—Arrangements for tightening a stack, for accommodation of a stack in a tank or for assembling different tanks
- H01M8/2475—Enclosures, casings or containers of fuel cell stacks
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/70—Assemblies comprising two or more cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Definitions
- the present invention relates generally to high pressure storage, in particular to a self-sealing container for pressurized electro-conducting media adaptable for fuel cell and electorlyser applications.
- Flexible metal hose is commonly used for conveying gases and simultaneously accommodates vibrations.
- the internal pressure tends to increase the sealing effect by pushing the sealing elements against other band elements.
- the present invention uses internal pressure from an electrochemical reaction to seal each electrochemical cell. Internal pressure helps seal the cells unlike traditional system, the coating of low friction plastic serves two functions: sealing and electro isolating.
- the self-sealing container could be assembled at any length from identical elements.
- the value of internal pressure is determined by strength of materials of the toroidal solid thin shells and shapes of thin shells.
- the principal object and advantage of the present invention is to provide a self-sealing container of any length assembled from identical elements; providing element shape reduces wall thickness required to contain pressure due to flexible shape; providing a self-sealing container in which each elements are electrically isolated but mechanically connected; providing such self-sealing container which is leak resistance; providing self-sealing container which can be manufactured by standard stamping equipment or more economical way by bellow type forming machine; providing self-sealing container which is efficient in operation, capable of high number of pressurized/depressurized cycles and which is particularly very adapted for the purposes and application thereof.
- FIG. 1 is across-sectional view of a prior self-sealing flexible metal hose.
- FIG. 2 is perspective exploded view of a two cell single stack elctrolyser with flat gasket sealing internal volume between two electrodes.
- FIG. 3 is a view of multiple thin shell stacks with applied axial primal squeezing force and internal pressure build by electrochemical reaction.
- FIG. 4 is a view of one contact element with thin layer of coated plastic
- FIG. 5 is view of the stress distribution in body of toroidal solid thin shells initiated by internal pressure
- the present invention is related to the design of arrays of electrochemical cells (cell stacks) to keep internal pressure 1 (FIG. 3), initiated by electrochemical reaction.
- the value of the internal pressure 1 is a function of the shape and material properties of the toroidal solid thin shells.
- the preliminary loading by external force 3 provides the initial seal and allows the electrochemical reaction to start to increase pressure.
- the film of low friction plastic 4 (FIG. 4) on contact lip elements 5 and spherical ball type shape 6 not only provides sealing effect but simultaneously supports the electro isolation of electrochemical cells from each other.
- spherical shape 7 of the toroidal solid thin shells 2 provides a pattern for spreading stress into body of toroidal solid thin shells 2 initiated by internal pressure 1 which changes the shape 8 of thin shells 2 to the shape 9 close to spherical surface.
- the stress generated in the material of thin shells 2 converts from lateral type to longitudinal type.
- the stress limit will be very close to the yield limit of defined material.
- spherical shape 7 of the toroidal solid thin shells 2 are holds larger internal pressure in comparison to the traditional non spherical shape.
- a reaction force 10 at the point of contact 11 between lip elements 5 and spherical ball type shape 6 (FIG. 4) is sum of force generate by internal pressure 1 and force initiated by changing shape of the toroidal solid thin shells 2 .
- FIG. 5 shows more detailed picture of equivalent stress (Von Mises) generated by internal pressure 1 and alteration of the shape toroidal solid thin shells 2 .
- the darkest area represents more local stress.
- An additional cathode shoulder 12 and membrane-anode shoulder 13 is destined for holding additional elements of electrolyser apparatus.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Secondary Cells (AREA)
Abstract
A self-sealing container for pressurized electro-conducting media including toroidal solid thin shells with flexible lip elements covered by a thin film of low friction plastic with electrical isolating and sealing features (for example Teflon type material). Each toroidal solid thin shell contacts with another shell by ball-socket type shape. Initial axial squeezing force during assembly creates the primary seal. Internal pressure from outside source or internal electrochemical reaction forces flexible lip elements against each other and creates contact force between each pair of ball-socket type shapes. The contact force is applied to the plastic film to seal internal volume of container.
Description
- I. Field of the Invention
- The present invention relates generally to high pressure storage, in particular to a self-sealing container for pressurized electro-conducting media adaptable for fuel cell and electorlyser applications.
- II. Description of the Prior Art
- Flexible metal hose is commonly used for conveying gases and simultaneously accommodates vibrations. In particular, the internal pressure tends to increase the sealing effect by pushing the sealing elements against other band elements.
- Maximum internal pressure is determined only by friction force between two contacting bend elements. Additionally, absence of electrical isolator between contact elements makes it impossible to use flexible metal hose as container for pressurized electro-conducting media. (U.S. Pat. No. 6,378,561 B1)
- Other applications related to electrochemical cell and electrochemical systems use one piece of unitary electrode. An insulating wall separates compartments of adjacent electrode pair assemblies which are connected by the double electrode plate in the single stack electrolyser. Each cell element contacts the next through an electrically isolating flat plastic gasket. The sealing effect is only achieved by preliminary squeezing load. The internal pressure initiated by electrochemical reaction expands the electrode-gasket sandwich and decreases pressure containing ability. Maximum internal pressure is determinate by preliminary squeezing loading and friction between electrode and gaskets. (U.S. Pat. No. 6,395,154 B1)
- The present invention uses internal pressure from an electrochemical reaction to seal each electrochemical cell. Internal pressure helps seal the cells unlike traditional system, the coating of low friction plastic serves two functions: sealing and electro isolating.
- The self-sealing container could be assembled at any length from identical elements. The value of internal pressure is determined by strength of materials of the toroidal solid thin shells and shapes of thin shells.
- It is an object of the present invention to provide an electrochemical system which has self-sealing and electrical isolating feature between cells; the maximum internal pressure is determined by strength of material of the toroidal solid thin shells and shapes of thin shells.
- The principal object and advantage of the present invention is to provide a self-sealing container of any length assembled from identical elements; providing element shape reduces wall thickness required to contain pressure due to flexible shape; providing a self-sealing container in which each elements are electrically isolated but mechanically connected; providing such self-sealing container which is leak resistance; providing self-sealing container which can be manufactured by standard stamping equipment or more economical way by bellow type forming machine; providing self-sealing container which is efficient in operation, capable of high number of pressurized/depressurized cycles and which is particularly very adapted for the purposes and application thereof.
- FIG. 1 is across-sectional view of a prior self-sealing flexible metal hose.
- FIG. 2 is perspective exploded view of a two cell single stack elctrolyser with flat gasket sealing internal volume between two electrodes.
- FIG. 3 is a view of multiple thin shell stacks with applied axial primal squeezing force and internal pressure build by electrochemical reaction.
- FIG. 4 is a view of one contact element with thin layer of coated plastic
- FIG. 5 is view of the stress distribution in body of toroidal solid thin shells initiated by internal pressure
- The present invention is related to the design of arrays of electrochemical cells (cell stacks) to keep internal pressure1 (FIG. 3), initiated by electrochemical reaction. The value of the
internal pressure 1 is a function of the shape and material properties of the toroidal solid thin shells. The preliminary loading byexternal force 3 provides the initial seal and allows the electrochemical reaction to start to increase pressure. The film of low friction plastic 4 (FIG. 4) oncontact lip elements 5 and sphericalball type shape 6 not only provides sealing effect but simultaneously supports the electro isolation of electrochemical cells from each other. - Referring to the drawings in more detail FIG. 3,
spherical shape 7 of the toroidal solidthin shells 2 provides a pattern for spreading stress into body of toroidal solidthin shells 2 initiated byinternal pressure 1 which changes theshape 8 ofthin shells 2 to theshape 9 close to spherical surface. In this case, the stress generated in the material ofthin shells 2 converts from lateral type to longitudinal type. The stress limit will be very close to the yield limit of defined material. - Moreover, the change in
shape 8 ofthin shells 2 from conical types to more spherical types brings down equivalent stress. - Hence
spherical shape 7 of the toroidal solidthin shells 2 are holds larger internal pressure in comparison to the traditional non spherical shape. - A
reaction force 10 at the point ofcontact 11 betweenlip elements 5 and spherical ball type shape 6 (FIG. 4) is sum of force generate byinternal pressure 1 and force initiated by changing shape of the toroidal solidthin shells 2. - FIG. 5 shows more detailed picture of equivalent stress (Von Mises) generated by
internal pressure 1 and alteration of the shape toroidal solidthin shells 2. The darkest area represents more local stress. - An
additional cathode shoulder 12 and membrane-anode shoulder 13 is destined for holding additional elements of electrolyser apparatus.
Claims (1)
1) a self-sealing container for pressurized electro-conducting media, which includes toroidal solid thin shells
2) said a flexible lips element belongs to thin shells
3) said thin film of low friction plastic that covered lips elements serves two functions: electro isolating and sealing
4) said toroidal solid thin shells contact with other shells by ball-socket type shape
5) said initial axial squeezing force created primal sealing
6) said internal pressure from outside source or internal electrochemical reaction bend flexible lips element against each other and creates contact force between each pair of spherical ball-socket shape.
7) said a contact force is applied to plastic film to seal internal volume of container
8) said a self-sealing container at any length can be assembled from identical elements.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/378,169 US20040173621A1 (en) | 2003-03-03 | 2003-03-03 | Self-sealing container for pressurized electro-conducting media |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/378,169 US20040173621A1 (en) | 2003-03-03 | 2003-03-03 | Self-sealing container for pressurized electro-conducting media |
Publications (1)
Publication Number | Publication Date |
---|---|
US20040173621A1 true US20040173621A1 (en) | 2004-09-09 |
Family
ID=32926420
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/378,169 Abandoned US20040173621A1 (en) | 2003-03-03 | 2003-03-03 | Self-sealing container for pressurized electro-conducting media |
Country Status (1)
Country | Link |
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US (1) | US20040173621A1 (en) |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2787397A (en) * | 1953-07-16 | 1957-04-02 | Walter A Radford | Self-sealing pressurized reinforced plastics container |
US3255780A (en) * | 1962-02-15 | 1966-06-14 | Plastiflex Co | Flexible hose of interlocking helical convolutions |
US3442297A (en) * | 1967-04-21 | 1969-05-06 | George Wesesku | Flexible tubing |
US4814071A (en) * | 1987-03-23 | 1989-03-21 | Rotex, Inc. | Flexible connector for screening machine |
US4865362A (en) * | 1988-07-29 | 1989-09-12 | Dayco Products, Inc. | Connectible flexible convoluted tubing |
US4906027A (en) * | 1988-02-12 | 1990-03-06 | Angli Holding B.V. | Insulating joint for metal pipelines |
-
2003
- 2003-03-03 US US10/378,169 patent/US20040173621A1/en not_active Abandoned
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2787397A (en) * | 1953-07-16 | 1957-04-02 | Walter A Radford | Self-sealing pressurized reinforced plastics container |
US3255780A (en) * | 1962-02-15 | 1966-06-14 | Plastiflex Co | Flexible hose of interlocking helical convolutions |
US3442297A (en) * | 1967-04-21 | 1969-05-06 | George Wesesku | Flexible tubing |
US4814071A (en) * | 1987-03-23 | 1989-03-21 | Rotex, Inc. | Flexible connector for screening machine |
US4906027A (en) * | 1988-02-12 | 1990-03-06 | Angli Holding B.V. | Insulating joint for metal pipelines |
US4865362A (en) * | 1988-07-29 | 1989-09-12 | Dayco Products, Inc. | Connectible flexible convoluted tubing |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |