US1667142A - Thermocouple - Google Patents
Thermocouple Download PDFInfo
- Publication number
- US1667142A US1667142A US11261A US1126125A US1667142A US 1667142 A US1667142 A US 1667142A US 11261 A US11261 A US 11261A US 1126125 A US1126125 A US 1126125A US 1667142 A US1667142 A US 1667142A
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- US
- United States
- Prior art keywords
- elements
- metal
- heat
- equipment
- metals
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052751 metal Inorganic materials 0.000 description 26
- 239000002184 metal Substances 0.000 description 26
- 150000002739 metals Chemical class 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 8
- 238000005507 spraying Methods 0.000 description 6
- 239000010425 asbestos Substances 0.000 description 5
- 229910052895 riebeckite Inorganic materials 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 239000010956 nickel silver Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- 229920001342 Bakelite® Polymers 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910000611 Zinc aluminium Inorganic materials 0.000 description 1
- HXFVOUUOTHJFPX-UHFFFAOYSA-N alumane;zinc Chemical compound [AlH3].[Zn] HXFVOUUOTHJFPX-UHFFFAOYSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- CZJCMXPZSYNVLP-UHFFFAOYSA-N antimony zinc Chemical compound [Zn].[Sb] CZJCMXPZSYNVLP-UHFFFAOYSA-N 0.000 description 1
- 239000004637 bakelite Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000009740 moulding (composite fabrication) Methods 0.000 description 1
- 229910001120 nichrome Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000000615 nonconductor Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000004826 seaming Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N10/00—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects
Definitions
- This invention relates to apparatus for producing electric currents from a source of heat which is preferably of electrical origin but not necessarily confined to this source alone.
- the object of this invention is to provide a simple, eiicient, economical equipment for producing direct currents of relatively small power, for such sources as heating the filaments of radio tubes, charging batteries, electro chemical work, ctc.
- the voltage and'current obtainable bythe device which I have invented is not limited to any particular voltage or current.
- This device may be'produced in any size, for example, which will supply 6 volts and or 3 amperes, or it may be supplled 1n slzes which will deliver volts and smaller amperages. Much larger units may be constructed if desired, but the present large commercial demand appears to be for relatively small units.
- Figure I shows a section t. en in a horizontal plane through one form of the device covered ⁇ by my in.-
- Figure II shows a vertical elevation partly in section, of my invention.
- Figure III shows in more detail one of the elements used in generating the current.
- Figure IV shows a side elevation of the details shown in Figure III.
- Figure V shows a modied form of element similar to that shown in Figure III but adapted for larger currents and lower voltages, and having a lower internal resistance.
- Figure VI shows a plan view of a spacer element used to confine the heat in my device.
- (1)' represents a frame or base, which may be made of cast iron, steel, porcelain, or other desired material.
- a housing (2) covered by cap (3) which is held in lplace by cap nut (4), threaded on rod (5), t eother extremity of which is supported in base 1).
- a spacer member (6) 1s mountedon base (1) and a corresponding co-actin' Amember (7) is mounted at the upper end o rod (5).
- Heating member (8) oi' base (il) and extends vertically between spacing member (6) and spaemg member (7) v Heating member (8) may be constructed in any desired form but I have found it very practical to construct it from an insulating tube (9), such as porcelain, upon which a lain or related material. 1s placed centrally ⁇ resistance element (10) is wound. Resistance' wire may be of nichrome and may be coiled into independent spirals prior to winding on tube (9). For convemence, in
- the elements (13) may be placed exactly radial, or in case the heating element 8) should not take the form of a cylindrical tube as shown, the elements would be placed substantially perpendicular to the surface of the heating element (8) at its nearest point.
- Electrodes 13) may conveniently be made from a sheet or card formed of asbestos, asbestos composition, millboard, transite,l bakelite sheet, or even thin strips of orce-
- the deslrable characteristics of the material from which plate (16) of element (13) is formed, are, it should be resistant to lrelatively high temperatures, it should be an electrical insulator, it should be a poor conductor of heat and should have reasonable mechanical vstrength to retain its shape and support the thermal elements.
- Binding posts are Aalso of securing excellent contact between' connected to these at desired points.
- Element (13) comprises a series of thermo couple elements (17) mounted on a plate or sheet (1G).
- the thermo couple elements may be made of any desired composition but for practical purposes I prefer a combination of German silver for one element and antiinony for the other element. On the drawing it may be assumed that element (18) represents the German silver, and the black element (20) represents the antiinoiiy.
- element (18) represents the German silver
- the black element (20) represents the antiinoiiy.
- antimony I may use zinc antimony, Zinc aluminum, and similar elements.
- the metal is conveyed into a .so-called sprayer in the form of wire, where it is melted by an oxyhydrogen flame so arranged that the velocity of the gases from the tiame are sufficient to forcibly blow the melted metal against the surface to be coated.
- the means of supplying the metals in the manner described permits of a permanent, substantial support, free from the diliculties due to welded or soldered joints.
- the metal applied in this manner also appears to be in a peculiarly favorablel condition for the production of electrical curi'ents, due presumably to the intimate contact obtained, and possibly to the structure.
- the moving stream of air which passes in the manner described above serves to keep the outer edge of the elements cool, thus giving the maximum available temperature difference, which of course increases the'output of the equipment.
- Equipment of the class described may be used to operate the well known tubes of radio sets, either for heating the filament or supplying the plate potential, depending on the design of the equipment.
- the equipment may also be used for any other purpose where the source of a direct current is required, and the e uipment it will be noted serves as a means o .converting a direct current of one potential to a direct current ofy another potential by, means of a conversion to heat.
- the provision for circulating a cooling medium around the outside of the elements is an important feature, as the heat must be removed from the elements as rapidly as it is supplied, in order to maintain the desired potential difference on the couple.
- the means of spraying the metal which produces a rough matte surface is very advantageously used and increases the eiiiciency of the device.
- one of the dissimilar metals which make up the couple may be of sheet or wire, applied to the supporting plate in any desired manner, in which case the other metal of the, couple may be sprayed in place in contact with the other member of the couple.
- an element consisting of a metal layer of granularform.
- a thermo electric couple consisting of two dissimilar metals in contact, one of said elements consistin of particlesof granular form onto an insu ating support.
Landscapes
- Resistance Heating (AREA)
Description
April 24, 192s. Y W. A. DARRAH THERMOC QUPLE Filed Feb. 24. '1925 /C/'GUREI Patented Apr. 24, 1928.
' WILLIAM: A. DARRAH, OF CHICAGO, ILLINOIS.
THERMOCOUPLE.
Application led February 24, 1925. Serial No. 11,261.
This invention relates to apparatus for producing electric currents from a source of heat which is preferably of electrical origin but not necessarily confined to this source alone.
The object of this invention is to provide a simple, eiicient, economical equipment for producing direct currents of relatively small power, for such sources as heating the filaments of radio tubes, charging batteries, electro chemical work, ctc.
The voltage and'current obtainable bythe device which I have invented is not limited to any particular voltage or current. This device may be'produced in any size, for example, which will supply 6 volts and or 3 amperes, or it may be supplled 1n slzes which will deliver volts and smaller amperages. Much larger units may be constructed if desired, but the present large commercial demand appears to be for relatively small units.
Referrinfr to the drawing, Figure I shows a section t. en in a horizontal plane through one form of the device covered `by my in.-
Vvention. Figure II shows a vertical elevation partly in section, of my invention. Figure III shows in more detail one of the elements used in generating the current. Figure IV shows a side elevation of the details shown in Figure III. Figure V shows a modied form of element similar to that shown in Figure III but adapted for larger currents and lower voltages, and having a lower internal resistance. Figure VI shows a plan view of a spacer element used to confine the heat in my device.
Referring to the drawing, (1)' represents a frame or base, which may be made of cast iron, steel, porcelain, or other desired material. On said frame (1) is a housing (2) covered by cap (3) which is held in lplace by cap nut (4), threaded on rod (5), t eother extremity of which is supported in base 1). A spacer member (6) 1s mountedon base (1) and a corresponding co-actin' Amember (7) is mounted at the upper end o rod (5). A heating-member (8) oi' base (il) and extends vertically between spacing member (6) and spaemg member (7) v Heating member (8) may be constructed in any desired form but I have found it very practical to construct it from an insulating tube (9), such as porcelain, upon which a lain or related material. 1s placed centrally` resistance element (10) is wound. Resistance' wire may be of nichrome and may be coiled into independent spirals prior to winding on tube (9). For convemence, in
Vthe form of invention which I have shown the upper end of spiral- (10) to flexible lead (11).
A series of elements (13), similar to the detail shown in Figures III, IV and V, are
assembled in a somewhat radial manner laround heatingr element (8). The elements (13) may be placed exactly radial, or in case the heating element 8) should not take the form of a cylindrical tube as shown, the elements would be placed substantially perpendicular to the surface of the heating element (8) at its nearest point.
It is intended in the case oflarge units to have several tubes similar to the single tube (8) in this unit, placed side by side, or various other obvious configurations are possible with equally satisfactory results, the essential point being that one yedge of the sheet-like element (13) proximity to the heating element (8), and the other edge shall be as far removed from the heating element (8) as possible. The element (13) is provided with interlocking notches or grooves (14) and (15) which are made to interlock with corresponding lprojections on spacing elements (7) and (6) respectively, thus serving to Ahold the elements 13) in a denite spacial relation.
vshall be in close'A .Elements 13) may conveniently be made from a sheet or card formed of asbestos, asbestos composition, millboard, transite,l bakelite sheet, or even thin strips of orce- The deslrable characteristics of the material from which plate (16) of element (13) is formed, are, it should be resistant to lrelatively high temperatures, it should be an electrical insulator, it should be a poor conductor of heat and should have reasonable mechanical vstrength to retain its shape and support the thermal elements.
- Figures I and II. Binding posts are Aalso of securing excellent contact between' connected to these at desired points.
Element (13) comprises a series of thermo couple elements (17) mounted on a plate or sheet (1G). The thermo couple elements may be made of any desired composition but for practical purposes I prefer a combination of German silver for one element and antiinony for the other element. On the drawing it may be assumed that element (18) represents the German silver, and the black element (20) represents the antiinoiiy. In
place of German silver I may use copper,
nickel, brass, or even tinned iron, and in place of antimony I may use zinc antimony, Zinc aluminum, and similar elements.
I have found that the metals used for the couples can to excellent advantage be applied by the process of spraying. Spraying is best accomplished by heating the metal to a melting temperature and throwing it `with considerable velocity against the surface to be coated. There are many commeicial equipments for accomplishing this result and the spraying equipment itself constitutes no part of this invention.
In some well known processes which ai'c very effective for the purpose of my invention, the metal is conveyed into a .so-called sprayer in the form of wire, where it is melted by an oxyhydrogen flame so arranged that the velocity of the gases from the tiame are sufficient to forcibly blow the melted metal against the surface to be coated.
Other equipments employ electrical means for accomplishing the melting, and a stream of air for forcing the melted metal on the surface to be coated.
I have found that it is also feasible to spray the metal on the surface in the form of a lacquer, and when applied with considerable velocity the lacquer coating is conducting. I prefer, however, some of the thermal methods of the type described above.
In the spraying of the metal it is convenient to form templates or stencils which Y Cover upi'all parts of the asbestos sheet on which the metal is to be placed except those` portions to be coated with metal. The coating of the sheet with metal in this manner permits of securing very thin layers and the two metals of the couple.
As a result of this arrangement very efli-i cient couples are produced. Some of the advantages of these couples arelong life without deterioration, unusual Contact between the two metals, relatively low heat conductivity and large ratio of surface to cross section, thus making the heat transfer through the metal a minimum. By obtaining a low heat transfer through the metal, the outer or cooler end of thc` metal is naturally maintained at a much lower temperature than would otherwise be possible, thus increasing the efficiency of the device.
Itwill of course be evident that thc cost of applying metals in this manner is relatively very low, as skill is' reduced to a minimum and no special mechanical equipment is necessary for bending, seaming, forming, etc.
The excellent Contact which is made at the terminals of the couples gives a maximum potential and-a minimum electrical resistance. This permits of the use of equipment of this type as a generator of relatively large currents, which has not previously been possible.
The means of supplying the metals in the manner described permits of a permanent, substantial support, free from the diliculties due to welded or soldered joints.
The metal applied in this manner also appears to be in a peculiarly favorablel condition for the production of electrical curi'ents, due presumably to the intimate contact obtained, and possibly to the structure.
It will be apparent. of course. that. my device provides a source of heat in the central portion, which source of heat is thoroughly insulated except for the series of elements arranged on the asbestos or other supports, as shown in Figure III. The outer ends of these elements, however, are exposed to the rapid movement of a current of air, as shown in Figure II. In Figure II the air enters through the series of holes (20A) and passes upward through the space (21) between the outside of the system of elements andthe shell (2). The cooling air also passes between the various elements at their outer end, leaving by a series of ports or holes (22) in the top of the cap (3).
The moving stream of air which passes in the manner described above, serves to keep the outer edge of the elements cool, thus giving the maximum available temperature difference, which of course increases the'output of the equipment.
Since the only means by which heat can pass from the central coil is through the series of elements (13), and since the main body of the element (13) is composed of a material which has relatively high insulating properties (asbestos or the equivalent) as compared to the metals themselves, it isassumes of course that the insulation of the balance of the equipment is `relatively high.
Equipment of the class described may be used to operate the well known tubes of radio sets, either for heating the filament or supplying the plate potential, depending on the design of the equipment. The equipment may also be used for any other purpose where the source of a direct current is required, and the e uipment it will be noted serves as a means o .converting a direct current of one potential to a direct current ofy another potential by, means of a conversion to heat.
The provision for circulating a cooling medium around the outside of the elements is an important feature, as the heat must be removed from the elements as rapidly as it is supplied, in order to maintain the desired potential difference on the couple. In this connection again, the means of spraying the metal which produces a rough matte surface, is very advantageously used and increases the eiiiciency of the device.
It will be apparent that many modifications can be made of the equipment described herein and still keep within the spirit of this invention. This invention,
' therefore, should be limited only by the disclosures in the prior art. It will be apparent, however, that by spraying the metals 1n place many important advantages may be obtained which cannot readily be obtained in other ways. One advantage is the ability to produce a thin layer which is a poor heat conductor and exposes a large surace to radiation.
It will be apparent that if desired, one of the dissimilar metals which make up the couple may be of sheet or wire, applied to the supporting plate in any desired manner, in which case the other metal of the, couple may be sprayed in place in contact with the other member of the couple.
Having now fully described my invention, what I claim as new and wish to sesource of heat, a series of metal couples of granular' form supported by insulating sheets, insulation around said source of heat, a shell enclosing said generator, and a circulation passage for air within said shell and around the outside ed es -of said sheets.
4. In an e ectric generator an element consisting of a metal layer of granularform. 5. A thermo electric couple consisting of two dissimilar metals in contact, one of said elements consistin of particlesof granular form onto an insu ating support.
' WILLIAM A. DARRAH.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11261A US1667142A (en) | 1925-02-24 | 1925-02-24 | Thermocouple |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11261A US1667142A (en) | 1925-02-24 | 1925-02-24 | Thermocouple |
Publications (1)
Publication Number | Publication Date |
---|---|
US1667142A true US1667142A (en) | 1928-04-24 |
Family
ID=21749574
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11261A Expired - Lifetime US1667142A (en) | 1925-02-24 | 1925-02-24 | Thermocouple |
Country Status (1)
Country | Link |
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US (1) | US1667142A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2519785A (en) * | 1944-08-14 | 1950-08-22 | Okolicsanyi Ferenc | Thermopile |
US2629757A (en) * | 1943-11-08 | 1953-02-24 | Warren Dunham Foster | Method of construction of sensitive thermopiles |
US2672492A (en) * | 1950-03-09 | 1954-03-16 | Sukacev Lev | Thermopiles |
US2886475A (en) * | 1953-02-24 | 1959-05-12 | Warren D Foster | Method of producing an electrical device |
US3284245A (en) * | 1961-04-10 | 1966-11-08 | Lockheed Aircraft Corp | Thermoelectric generators |
-
1925
- 1925-02-24 US US11261A patent/US1667142A/en not_active Expired - Lifetime
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2629757A (en) * | 1943-11-08 | 1953-02-24 | Warren Dunham Foster | Method of construction of sensitive thermopiles |
US2519785A (en) * | 1944-08-14 | 1950-08-22 | Okolicsanyi Ferenc | Thermopile |
US2672492A (en) * | 1950-03-09 | 1954-03-16 | Sukacev Lev | Thermopiles |
US2886475A (en) * | 1953-02-24 | 1959-05-12 | Warren D Foster | Method of producing an electrical device |
US3284245A (en) * | 1961-04-10 | 1966-11-08 | Lockheed Aircraft Corp | Thermoelectric generators |
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