US1605988A - Process of removing hair from hides or skins - Google Patents
Process of removing hair from hides or skins Download PDFInfo
- Publication number
- US1605988A US1605988A US74978124A US1605988A US 1605988 A US1605988 A US 1605988A US 74978124 A US74978124 A US 74978124A US 1605988 A US1605988 A US 1605988A
- Authority
- US
- United States
- Prior art keywords
- skins
- hides
- removing hair
- water
- liquor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 210000004209 hair Anatomy 0.000 title description 12
- 238000000034 method Methods 0.000 title description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 18
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 10
- 239000005864 Sulphur Substances 0.000 description 9
- 229910021529 ammonia Inorganic materials 0.000 description 9
- 239000000292 calcium oxide Substances 0.000 description 7
- 235000012255 calcium oxide Nutrition 0.000 description 7
- 238000009835 boiling Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 4
- 108090000190 Thrombin Proteins 0.000 description 3
- 239000004572 hydraulic lime Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 210000002268 wool Anatomy 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 241001494479 Pecora Species 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241001072332 Monia Species 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- JGIATAMCQXIDNZ-UHFFFAOYSA-N calcium sulfide Chemical compound [Ca]=S JGIATAMCQXIDNZ-UHFFFAOYSA-N 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 210000000050 mohair Anatomy 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C1/00—Chemical treatment prior to tanning
- C14C1/06—Facilitating unhairing, e.g. by painting, by liming
Definitions
- Our present invention consists in following or carrying out such a process as will enable us to make use of substances in such, a form as will not damage either the hair or the hides or skins, thus said hair when removed will retain its natural properties so that its future or subsequent treatmentis not in anyway interfered with and this we have found to be of great importance and value with respect to wool removed from the skins of sheep as well as with mohair and the like.
- the hides or skins are placed directly into the unhairing pit prior or subsequent to the placing therein of the liquor for treating same.
- Each hide or skin when placed in the pit ought to be suspended therein, by any well known means, so that the liquor in the pit may have access to all the outer surface thereof.
- the quantity of ammonia used depends on the temperature at which the unhairing is carried out and this temperature may range from about 45 degrees Centigrade down to about 10 degrees according to the result required, the higher the temperature the quicker is the result attained. As the ammonia plays no part in the actual unhairing, but preserves the hides from the actions of the putrefactive bacteria, it is obvious that the amount of said ammonia depends on the temperature of the compounded liquor, the higher the temperature the more will be the added ammonia.
- the skins may be subjected to the above treatment until they are in the desired condition for pulling or unhairing which may be from about six hours to two or three days depending on the amount of thrombase in the skin.
- a bath for removing hair from hides and skins consisting of a liquor derived from powdered sulphur, boiling water, and quieklime, boiled and diluted With Water.
- a bath for removing hair from and treating hides and skins consisting of a liquor derived from powdered sulphur, boiling water, and quicklime, boiled and admixed with water and ammonia.
- a bath for removing hair from and treating hides and skins consisting of powdered sulphur, water, quicklime, and am monia.
- a bath for removing hair from hides and skins consisting of the following ingredients in substantially the proportions named; 15 pounds of powdered sulphur, gallons of boiling water, and pounds of quicklime, the resultant liquor being added to Water in the proportion of from 1 to 10 gallons to 1000 gallons.
- a bath for removing hair from and treating hides and skins consisting of the following ingredients in substantially the proportions named; 15 pounds of powdered sulphur, 10 gallons of boiling water, and 15 pounds of quicklime, the resultant liquor being added to water in the proportion of from 1 to 10 gallons to 1000 gallons, and from 5 to 15 gallons of ammonia being added to the whole.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Description
Patented Nov. 9, 1926.
UNITED STATES PATENT OFFICE.
HUGH CAMPBELL BOSS, 015 LIVERPOOL, AND I-IUBERT GLTFTON MARRIS, OF BOLTON, ENGLAND, ASSIGNOBS'TO WILLIAM WALKER AND SONS LIMITED, 0F ROSE HILL TANNERY, BOLTON, IN THE COUNTY OF LANCASTER, ENGLAND.
PROCESS OF REMOVING HAIR FROM HIDES 0B SKINS.
No Drawing.
In unhairing hides or skins the process usually followed entails the use of lime or other substances in such form as tohave the effect either of partly destroying or of. so damaging the hair which is removed, that its value is diminished.
Our present invention consists in following or carrying out such a process as will enable us to make use of substances in such, a form as will not damage either the hair or the hides or skins, thus said hair when removed will retain its natural properties so that its future or subsequent treatmentis not in anyway interfered with and this we have found to be of great importance and value with respect to wool removed from the skins of sheep as well as with mohair and the like.
In carrying out our process we make use of the known active rinciples of a substance called thrombase l which is normally present in or within all dead skins or hides) in conjunction with means for controlling the actions of putrefactive bacteria which are normally present on the outside of said hides or skins.
We employ any of the well known kind of unhairing pits or tanks with steam pipe or other suitable apparatus for heating the contents of same and maintaining said contents at the desired temperature hereinafter given.
It is desirable that the, pits or tanks should be provided with removable covers although the use of same is not absolutely essential.
The hides or skins are placed directly into the unhairing pit prior or subsequent to the placing therein of the liquor for treating same. Each hide or skin when placed in the pit ought to be suspended therein, by any well known means, so that the liquor in the pit may have access to all the outer surface thereof.
To prepare the liquor we add to each fifteen pounds of flowers of sulphur (or other form of sulphur in fine powder) ten gallons of boiling water and to this mixture we add fifteen pounds of quicklime (or its equivalent in slaked lime) and boil the whole for one hour. We allow the heavier matter to settle and then we run off the clear liquor which is of a deep orange colour and Application filed November 13, 1924. Serial No 749,781.
characteristics or condition of the skins,
hides or tails to be treated as the thrombase varies in amount as will befound in practice. To this mixture we add from five to fifteengallons of ordinary commercial liquor ammonia of a specific'gravityof about .9 accordingto the conditionsof putrefactive infection and temperature.
The quantity of ammonia used depends on the temperature at which the unhairing is carried out and this temperature may range from about 45 degrees Centigrade down to about 10 degrees according to the result required, the higher the temperature the quicker is the result attained. As the ammonia plays no part in the actual unhairing, but preserves the hides from the actions of the putrefactive bacteria, it is obvious that the amount of said ammonia depends on the temperature of the compounded liquor, the higher the temperature the more will be the added ammonia.
l/Ve are aware that it is possible to produce in other ways a compound or mixture of sulphur calcium and ammonium but we prefer the method stated. The skins may be subjected to the above treatment until they are in the desired condition for pulling or unhairing which may be from about six hours to two or three days depending on the amount of thrombase in the skin.
The substances used and compounded as hereinbefore described have given desirable results at the approximate temperatures and within the time or duration of treatment stated, but we are aware that the said proportions and the period of treatment may be considerably varied without departing from the nature of our invention.
By following our process in the treatment of sheep skins we have found the Wool to be removable without damage to the grain and without that deterioration of the wool which takes place in the ordinary process of fellmongering with powerful caustics. 1
Such being the nature and object of our said invention what we claim is l. The process of removing hair from hides or skins consisting in subjecting same to the actions of a liquor consisting of water, sulphur, lime and ammonia, substantially as described.
2. The process of removing hair from hides or skins, consisting in immersing the same in a liquid bath consisting of a water dilution of a boiled solution of powdered sulphur, water, and quicklime, and maintaining the bath at a predetermined temperature.
3. The process of removing hair from and treating hides or skins, consisting in immersing the same in .a liquid bath consisting of a boiled solution of powdered sulphur, water, and quicklime, to which water and ammonia have been added, and maintaining the bath at a predetermined teinperature.
at. A bath for removing hair from hides and skins, consisting of a liquor derived from powdered sulphur, boiling water, and quieklime, boiled and diluted With Water.
5. A bath for removing hair from and treating hides and skins, consisting of a liquor derived from powdered sulphur, boiling water, and quicklime, boiled and admixed with water and ammonia.
6. A bath for removing hair from and treating hides and skins, consisting of powdered sulphur, water, quicklime, and am monia.
7. A bath for removing hair from hides and skins, consisting of the following ingredients in substantially the proportions named; 15 pounds of powdered sulphur, gallons of boiling water, and pounds of quicklime, the resultant liquor being added to Water in the proportion of from 1 to 10 gallons to 1000 gallons.
8. A bath for removing hair from and treating hides and skins, consisting of the following ingredients in substantially the proportions named; 15 pounds of powdered sulphur, 10 gallons of boiling water, and 15 pounds of quicklime, the resultant liquor being added to water in the proportion of from 1 to 10 gallons to 1000 gallons, and from 5 to 15 gallons of ammonia being added to the whole.
H. C. ROSS. H. C. MARRIS,
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB20556/24A GB241666A (en) | 1924-09-01 | 1924-09-01 | Improvements in the process of removing hair from hides or skins |
US74978124 US1605988A (en) | 1924-09-01 | 1924-11-13 | Process of removing hair from hides or skins |
FR603228D FR603228A (en) | 1924-09-01 | 1925-09-18 | Improvements to the seaming of leathers and skins |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB20556/24A GB241666A (en) | 1924-09-01 | 1924-09-01 | Improvements in the process of removing hair from hides or skins |
US74978124 US1605988A (en) | 1924-09-01 | 1924-11-13 | Process of removing hair from hides or skins |
FR603228T | 1925-09-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
US1605988A true US1605988A (en) | 1926-11-09 |
Family
ID=89574628
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US74978124 Expired - Lifetime US1605988A (en) | 1924-09-01 | 1924-11-13 | Process of removing hair from hides or skins |
Country Status (3)
Country | Link |
---|---|
US (1) | US1605988A (en) |
FR (1) | FR603228A (en) |
GB (1) | GB241666A (en) |
-
1924
- 1924-09-01 GB GB20556/24A patent/GB241666A/en not_active Expired
- 1924-11-13 US US74978124 patent/US1605988A/en not_active Expired - Lifetime
-
1925
- 1925-09-18 FR FR603228D patent/FR603228A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
FR603228A (en) | 1926-04-12 |
GB241666A (en) | 1925-10-29 |
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