US1575442A - Method and means for using low-compression fuels - Google Patents
Method and means for using low-compression fuels Download PDFInfo
- Publication number
- US1575442A US1575442A US663500A US66350023A US1575442A US 1575442 A US1575442 A US 1575442A US 663500 A US663500 A US 663500A US 66350023 A US66350023 A US 66350023A US 1575442 A US1575442 A US 1575442A
- Authority
- US
- United States
- Prior art keywords
- fuel
- compression
- low
- fuels
- pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000446 fuel Substances 0.000 title description 19
- 238000007906 compression Methods 0.000 title description 17
- 238000000034 method Methods 0.000 title description 5
- 230000006835 compression Effects 0.000 description 14
- 150000001622 bismuth compounds Chemical class 0.000 description 7
- 239000000203 mixture Substances 0.000 description 4
- ZHXAZZQXWJJBHA-UHFFFAOYSA-N triphenylbismuthane Chemical compound C1=CC=CC=C1[Bi](C=1C=CC=CC=1)C1=CC=CC=C1 ZHXAZZQXWJJBHA-UHFFFAOYSA-N 0.000 description 3
- 239000003350 kerosene Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- FPYOWXFLVWSKPS-UHFFFAOYSA-N triethylbismuthane Chemical compound CC[Bi](CC)CC FPYOWXFLVWSKPS-UHFFFAOYSA-N 0.000 description 1
- AYDYYQHYLJDCDQ-UHFFFAOYSA-N trimethylbismuthane Chemical compound C[Bi](C)C AYDYYQHYLJDCDQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/30—Organic compounds compounds not mentioned before (complexes)
- C10L1/301—Organic compounds compounds not mentioned before (complexes) derived from metals
Definitions
- This invention relatesto the art of suppressing a fuel knock when a combustible gaseous mixture containing a low.compression fuel such, forexample, as kerosene and gasoline is burned under a-relat1vely h1gh pressure.
- a low.compression fuel such as kerosene and gasoline is burned under a-relat1vely h1gh pressure.
- the principal objects of this 1nvention are to employ bismuth compounds to suppress the fuel knock.
- Kerosene has a critical compression, pressure of about 55 pounds.
- the critical com- 29 pression pressure of gasoline varies from about 75 poundsfor the commoner forms now marketed to about 125 pounds for aviation gasoline employed in airplane engines. These fuels are termed low compression fuels. When the vapors of any one of them is mixed with air, compressed to a compression pressure in excess of the normal critical compression pressure of the fuel, and burned, as in an internal combus- 30 tion engine, a 'fuel knock is produced.
- This solution or high compression fuel is fed through a carburetor into the cylinder of an internal combustion engine havingv a compression pressure of about 100 pounds, the solution being vaporized and mixed with air as is common practice in engine operation.
- the gaseous high compression fuel is ignited and the engine operated without a fuel knock.
- the gasoline forms the fuel base and the bismuth compound increases the critical compression pressure of this base.
- This process may be varied by changing the proportions according to the increase in critical compression pressure desired and by using other bismuth compounds in place of the triphenyl bismuthine.
- bismuth compounds which may be employed are alkyl compounds such as triethyl bismuthine and tri-methyl bismuthine.
- Blending agents may be employed if the bismuth compound does not dissolve readily in the fuel.
- the compound may .be added to the fuel-air mixture just before the latter is burned.
- a composition of matter comprising a low compression fuel; and a volatile bismuth compound incorporated therein and adapted to increase the critical compression pressure of the fuel.
- a composition of matter comprising gasoline; and triphenyl bismuthine.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Patented Mar. 2, 1926.
UNITED STATES PATENT OFFICE.
'rnomas MIDGLEY, 1a., or DAYTON, 01110, ASSIGNOR. BY MESNE ASSIGNMENTS, TO GE ERAL morons, CORPORATION, or DETROIT, MICHIGAN, A CORPORATION E DELAWARE.
METHOD AND MEANS FOR USING LOW-COMPRESSION EUELs.
No Drawing.
To all whom z't may concern:-
Be it known that ,I, THOMAS MmeLEY, Ir.,
a citizen of the United States of America,
residing, at Dayton, county of Montgomery, 5 and State of Ohio, have invented certain new and useful Improvements in Methods and Means for Using Low-Compression Fuels, of which the following is a full, clear, and exact description.
This invention relatesto the art of suppressing a fuel knock when a combustible gaseous mixture containing a low.compression fuel such, forexample, as kerosene and gasoline is burned under a-relat1vely h1gh pressure. The principal objects of this 1nvention are to employ bismuth compounds to suppress the fuel knock. I I
Kerosene has a critical compression, pressure of about 55 pounds. The critical com- 29 pression pressure of gasoline varies from about 75 poundsfor the commoner forms now marketed to about 125 pounds for aviation gasoline employed in airplane engines. These fuels are termed low compression fuels. When the vapors of any one of them is mixed with air, compressed to a compression pressure in excess of the normal critical compression pressure of the fuel, and burned, as in an internal combus- 30 tion engine, a 'fuel knock is produced.
I have found that vapors of bismuth compounds added to the. fuel-air mixture sup-- press this fuel knock and permit an increase in the engine compression pressure with a normal burning characteristic ofthe) fuel.
By way of anexample of one method of carrying out my invention, I dissolve 40 grams of triphenyl bismuthine B. (C H in 1 gallon of gasoline having a normal Application filed September 18, 1923. Serial No. 663,500.
critical compression pressure of about 7 5 4 pounds. This solution or high compression fuel is fed through a carburetor into the cylinder of an internal combustion engine havingv a compression pressure of about 100 pounds, the solution being vaporized and mixed with air as is common practice in engine operation. The gaseous high compression fuel is ignited and the engine operated without a fuel knock. The gasoline forms the fuel base and the bismuth compound increases the critical compression pressure of this base.
This process may be varied by changing the proportions according to the increase in critical compression pressure desired and by using other bismuth compounds in place of the triphenyl bismuthine. Among the com pounds of bismuth which may be employed are alkyl compounds such as triethyl bismuthine and tri-methyl bismuthine.
I prefer to employ the bismuth compounds which are soluble in the fuel to promote the mixing of the two. Blending agents may be employed if the bismuth compound does not dissolve readily in the fuel. The compound may .be added to the fuel-air mixture just before the latter is burned. v
1. A composition of matter comprising a low compression fuel; and a volatile bismuth compound incorporated therein and adapted to increase the critical compression pressure of the fuel.
2. A composition of matter comprising gasoline; and triphenyl bismuthine.
In testimony whereof I hereto affix my signature.
THOMAS MIDGLEY JR.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US663500A US1575442A (en) | 1923-09-18 | 1923-09-18 | Method and means for using low-compression fuels |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US663500A US1575442A (en) | 1923-09-18 | 1923-09-18 | Method and means for using low-compression fuels |
Publications (1)
Publication Number | Publication Date |
---|---|
US1575442A true US1575442A (en) | 1926-03-02 |
Family
ID=24662070
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US663500A Expired - Lifetime US1575442A (en) | 1923-09-18 | 1923-09-18 | Method and means for using low-compression fuels |
Country Status (1)
Country | Link |
---|---|
US (1) | US1575442A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2806348A (en) * | 1953-12-21 | 1957-09-17 | Gulf Research Development Co | Bismuth triphenyl jet fuel compositions and process of using same |
WO2016191409A1 (en) * | 2015-05-28 | 2016-12-01 | Exxonmobil Research And Engineering Company | Composition and method for preventing or reducing engine knock and pre-ignition in high compression spark ignition engines |
-
1923
- 1923-09-18 US US663500A patent/US1575442A/en not_active Expired - Lifetime
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2806348A (en) * | 1953-12-21 | 1957-09-17 | Gulf Research Development Co | Bismuth triphenyl jet fuel compositions and process of using same |
WO2016191409A1 (en) * | 2015-05-28 | 2016-12-01 | Exxonmobil Research And Engineering Company | Composition and method for preventing or reducing engine knock and pre-ignition in high compression spark ignition engines |
US10119093B2 (en) | 2015-05-28 | 2018-11-06 | Exxonmobil Research And Engineering Company | Composition and method for preventing or reducing engine knock and pre-ignition in high compression spark ignition engines |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2405560A (en) | Fuel | |
US2427173A (en) | Fuel | |
US3341311A (en) | Liquid hydrocarbon fuels | |
US2785662A (en) | Compositions and methods for removing deposits | |
US3697240A (en) | Aerosol bomb filled with starting agent for diesel engine | |
US2093008A (en) | Fuel for internal combustion engines | |
US1713589A (en) | Low-compression fuel | |
US1606431A (en) | Motor fuel | |
US1575442A (en) | Method and means for using low-compression fuels | |
US1575436A (en) | Method and means for using low-compression fuels | |
US1575440A (en) | Method and means for using low-compression fuels | |
US1575444A (en) | Method and means for using low-compression fuels | |
US1635216A (en) | Method and means for using low-compression fuels | |
US1757837A (en) | Motor fuel | |
US1575438A (en) | Method and means for using low-compression fuels | |
US1592955A (en) | Motor fuel | |
US1575443A (en) | Method and means for using low-compression fuels | |
US1605663A (en) | Motor fuel | |
US1504837A (en) | Fuel for use in internal-combustion engines | |
US1575441A (en) | Method and means for using low-compression fuels | |
US1575437A (en) | Method and means for using low-compression fuels | |
US1980097A (en) | Motor fuel lubricating and antiknock materials | |
US1575439A (en) | Method and means for using low-compression fuels | |
US2985522A (en) | Unleaded motor fuel | |
US1757838A (en) | Liquid fuel |