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US1575442A - Method and means for using low-compression fuels - Google Patents

Method and means for using low-compression fuels Download PDF

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Publication number
US1575442A
US1575442A US663500A US66350023A US1575442A US 1575442 A US1575442 A US 1575442A US 663500 A US663500 A US 663500A US 66350023 A US66350023 A US 66350023A US 1575442 A US1575442 A US 1575442A
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US
United States
Prior art keywords
fuel
compression
low
fuels
pressure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US663500A
Inventor
Jr Thomas Midgley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Motors Liquidation Co
Original Assignee
General Motors Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Motors Corp filed Critical General Motors Corp
Priority to US663500A priority Critical patent/US1575442A/en
Application granted granted Critical
Publication of US1575442A publication Critical patent/US1575442A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/30Organic compounds compounds not mentioned before (complexes)
    • C10L1/301Organic compounds compounds not mentioned before (complexes) derived from metals

Definitions

  • This invention relatesto the art of suppressing a fuel knock when a combustible gaseous mixture containing a low.compression fuel such, forexample, as kerosene and gasoline is burned under a-relat1vely h1gh pressure.
  • a low.compression fuel such as kerosene and gasoline is burned under a-relat1vely h1gh pressure.
  • the principal objects of this 1nvention are to employ bismuth compounds to suppress the fuel knock.
  • Kerosene has a critical compression, pressure of about 55 pounds.
  • the critical com- 29 pression pressure of gasoline varies from about 75 poundsfor the commoner forms now marketed to about 125 pounds for aviation gasoline employed in airplane engines. These fuels are termed low compression fuels. When the vapors of any one of them is mixed with air, compressed to a compression pressure in excess of the normal critical compression pressure of the fuel, and burned, as in an internal combus- 30 tion engine, a 'fuel knock is produced.
  • This solution or high compression fuel is fed through a carburetor into the cylinder of an internal combustion engine havingv a compression pressure of about 100 pounds, the solution being vaporized and mixed with air as is common practice in engine operation.
  • the gaseous high compression fuel is ignited and the engine operated without a fuel knock.
  • the gasoline forms the fuel base and the bismuth compound increases the critical compression pressure of this base.
  • This process may be varied by changing the proportions according to the increase in critical compression pressure desired and by using other bismuth compounds in place of the triphenyl bismuthine.
  • bismuth compounds which may be employed are alkyl compounds such as triethyl bismuthine and tri-methyl bismuthine.
  • Blending agents may be employed if the bismuth compound does not dissolve readily in the fuel.
  • the compound may .be added to the fuel-air mixture just before the latter is burned.
  • a composition of matter comprising a low compression fuel; and a volatile bismuth compound incorporated therein and adapted to increase the critical compression pressure of the fuel.
  • a composition of matter comprising gasoline; and triphenyl bismuthine.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

Patented Mar. 2, 1926.
UNITED STATES PATENT OFFICE.
'rnomas MIDGLEY, 1a., or DAYTON, 01110, ASSIGNOR. BY MESNE ASSIGNMENTS, TO GE ERAL morons, CORPORATION, or DETROIT, MICHIGAN, A CORPORATION E DELAWARE.
METHOD AND MEANS FOR USING LOW-COMPRESSION EUELs.
No Drawing.
To all whom z't may concern:-
Be it known that ,I, THOMAS MmeLEY, Ir.,
a citizen of the United States of America,
residing, at Dayton, county of Montgomery, 5 and State of Ohio, have invented certain new and useful Improvements in Methods and Means for Using Low-Compression Fuels, of which the following is a full, clear, and exact description.
This invention relatesto the art of suppressing a fuel knock when a combustible gaseous mixture containing a low.compression fuel such, forexample, as kerosene and gasoline is burned under a-relat1vely h1gh pressure. The principal objects of this 1nvention are to employ bismuth compounds to suppress the fuel knock. I I
Kerosene has a critical compression, pressure of about 55 pounds. The critical com- 29 pression pressure of gasoline varies from about 75 poundsfor the commoner forms now marketed to about 125 pounds for aviation gasoline employed in airplane engines. These fuels are termed low compression fuels. When the vapors of any one of them is mixed with air, compressed to a compression pressure in excess of the normal critical compression pressure of the fuel, and burned, as in an internal combus- 30 tion engine, a 'fuel knock is produced.
I have found that vapors of bismuth compounds added to the. fuel-air mixture sup-- press this fuel knock and permit an increase in the engine compression pressure with a normal burning characteristic ofthe) fuel.
By way of anexample of one method of carrying out my invention, I dissolve 40 grams of triphenyl bismuthine B. (C H in 1 gallon of gasoline having a normal Application filed September 18, 1923. Serial No. 663,500.
critical compression pressure of about 7 5 4 pounds. This solution or high compression fuel is fed through a carburetor into the cylinder of an internal combustion engine havingv a compression pressure of about 100 pounds, the solution being vaporized and mixed with air as is common practice in engine operation. The gaseous high compression fuel is ignited and the engine operated without a fuel knock. The gasoline forms the fuel base and the bismuth compound increases the critical compression pressure of this base.
This process may be varied by changing the proportions according to the increase in critical compression pressure desired and by using other bismuth compounds in place of the triphenyl bismuthine. Among the com pounds of bismuth which may be employed are alkyl compounds such as triethyl bismuthine and tri-methyl bismuthine.
I prefer to employ the bismuth compounds which are soluble in the fuel to promote the mixing of the two. Blending agents may be employed if the bismuth compound does not dissolve readily in the fuel. The compound may .be added to the fuel-air mixture just before the latter is burned. v
1. A composition of matter comprising a low compression fuel; and a volatile bismuth compound incorporated therein and adapted to increase the critical compression pressure of the fuel.
2. A composition of matter comprising gasoline; and triphenyl bismuthine.
In testimony whereof I hereto affix my signature.
THOMAS MIDGLEY JR.
US663500A 1923-09-18 1923-09-18 Method and means for using low-compression fuels Expired - Lifetime US1575442A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US663500A US1575442A (en) 1923-09-18 1923-09-18 Method and means for using low-compression fuels

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US663500A US1575442A (en) 1923-09-18 1923-09-18 Method and means for using low-compression fuels

Publications (1)

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US1575442A true US1575442A (en) 1926-03-02

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US663500A Expired - Lifetime US1575442A (en) 1923-09-18 1923-09-18 Method and means for using low-compression fuels

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2806348A (en) * 1953-12-21 1957-09-17 Gulf Research Development Co Bismuth triphenyl jet fuel compositions and process of using same
WO2016191409A1 (en) * 2015-05-28 2016-12-01 Exxonmobil Research And Engineering Company Composition and method for preventing or reducing engine knock and pre-ignition in high compression spark ignition engines

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2806348A (en) * 1953-12-21 1957-09-17 Gulf Research Development Co Bismuth triphenyl jet fuel compositions and process of using same
WO2016191409A1 (en) * 2015-05-28 2016-12-01 Exxonmobil Research And Engineering Company Composition and method for preventing or reducing engine knock and pre-ignition in high compression spark ignition engines
US10119093B2 (en) 2015-05-28 2018-11-06 Exxonmobil Research And Engineering Company Composition and method for preventing or reducing engine knock and pre-ignition in high compression spark ignition engines

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