US1550064A - Explosive - Google Patents
Explosive Download PDFInfo
- Publication number
- US1550064A US1550064A US28242A US2824225A US1550064A US 1550064 A US1550064 A US 1550064A US 28242 A US28242 A US 28242A US 2824225 A US2824225 A US 2824225A US 1550064 A US1550064 A US 1550064A
- Authority
- US
- United States
- Prior art keywords
- explosive
- sulpho
- amino
- salt
- explosives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002360 explosive Substances 0.000 title description 27
- 150000003839 salts Chemical class 0.000 description 15
- 239000002253 acid Substances 0.000 description 14
- -1 amino sulpho acids Chemical class 0.000 description 13
- 239000000126 substance Substances 0.000 description 5
- 239000007800 oxidant agent Substances 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical class 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- HVBSAKJJOYLTQU-UHFFFAOYSA-N 4-aminobenzenesulfonic acid Chemical compound NC1=CC=C(S(O)(=O)=O)C=C1 HVBSAKJJOYLTQU-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical class O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 1
- 229940081735 acetylcellulose Drugs 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000010685 fatty oil Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical class OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000002828 nitro derivatives Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- 229950000244 sulfanilic acid Drugs 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B43/00—Compositions characterised by explosive or thermic constituents not provided for in groups C06B25/00 - C06B41/00
Definitions
- Patented Auig 18, 1925 Patented Auig 18, 1925.
- JAeoE EHRLICIH or BELLEVILLE
- nEw JERSEY ASSIGNOIR.
- r vEnoNA CHEMICAL (10., or NORTH NEWARK, NEW JERSEY, A conronarrou or NEW. JERSEY.
- My invention relates to explosives and refers particularly to explosives containing salts of organic amino sulphonie acids.
- Explosives of increased efliciency maybe produced by intermixing solutions of the ingredients and bringing to dryness, because of the more complete and uniform composition of theproducts thus produced.
- the explosive force and effect is due largely'to the rapidity of oxidation of the oxidizable ingredient and the ability of the oxidizing ingredients to furnish the required oxygen with sufficient rapidity'and in suflicient quantities to satisfy 3 the explosive reaction.
- the explosives of my invention possess all of the above mentioned, and other, valuable properties and are materials of this character of the highest value and efliciency.
- organic amino sulpho acids I mean the sulpho acids of amino compounds of produced.
- the salts of the organic amino sulpho acids may replace wholly, or in part, other oxldizable substances such as aliphatic and aromatic hydrocarbons, wood meal or other forms of cellulose, coal, charcoal or other forms of carbon, sulphides, sulphur, carbohydrates, acetyl cellulose, salts of aliphatic or aromatic sulphonic acids, resins, fatty oils, glue, metallic magnesium, zinc, al-umi- -num, lI'On complex cyamdes, alcohols, glycerines, aromatic bases, ureas, tars, turpentines, camphor, soap, etc. Inert materials such as.
- kiesel'guhr, mica, etc. may be usedto reduce the explosive power.
- I can use 20 parts by weight of theanhydrous sodium salt of sulphanilic acid and 43 parts by weight of potassium nitrate. These salts may be employed b intermixing their aqueous solutions and drying, or by intermixing the finely ground dr ed powders,
- An explosive containinga water-soluble salt of an organic amino sulpho acid 3.
- An explosive containing a water-soluble oxidizing of an organlc amino sulpho acid 4.
- An explosive comprlsmg an OXIdIZIIIg substance and a salt of an organic amino sulpho acid.
- An explosive comprising an oxidizing substance and a salt of an aromatic amino sulpho acid.
- An explosive comprising an oxidizing substance and a water soluble salt of an organic amino sulpho acid.
- An explosive comprising an' oxidizing substance and a water-soluble salt of an aromatic amino sulpho 9.
- An explosive comprising a Water soluble substance and a Water-soluble salt 10.
- An explosive comprising a Watersoluble oxidizing substance and a water solible salt of an aromatic amino sulpho ac1 Signed at Belleville in the county of Essex and State of New Jersey this 29th day of April, 1925.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Patented Auig 18, 1925.
UNITED STATES Ivar-sar 1,550,064 F'FICE.
JAeoE EHRLICIH, or BELLEVILLE, nEw JERSEY, ASSIGNOIR. r vEnoNA CHEMICAL (10., or NORTH NEWARK, NEW JERSEY, A conronarrou or NEW. JERSEY.
No Drawin To all whom it may concern: Be it known that I, JACOB EHRLICH, a citizen of the United States, residing at Belle- I 'ville, in the county of Essex and State of New Jersey, have invented new and useful Improvements in Explosives, of which the following is a full, clear, and exact specifica tion. I I
My invention relates to explosives and refers particularly to explosives containing salts of organic amino sulphonie acids.
Explosives of increased efliciency maybe produced by intermixing solutions of the ingredients and bringing to dryness, because of the more complete and uniform composition of theproducts thus produced. In order that. explosives of this character shall possess the ,highest' efiiciency, it is essential that the oxidizing =and oxidizable in gredients be soluble, inert with respect to each other during their soluble condition and during their production into dry form, stable under ordinary atmospheric and temperature conditions, and that they be capable of explosion with a maximum of effect under explosive means.
It is further evident, that the explosive force and effect is due largely'to the rapidity of oxidation of the oxidizable ingredient and the ability of the oxidizing ingredients to furnish the required oxygen with sufficient rapidity'and in suflicient quantities to satisfy 3 the explosive reaction.
The explosives of my invention possess all of the above mentioned, and other, valuable properties and are materials of this character of the highest value and efliciency.
I hav found that the amino compounds of the alts of organic sul ho acids are explosive power, is not liable to explosure 4 highly oxidizable and. that t e presence of the amino group increases the explosive force of the: powder 'over those in which this chemical grou is absent- I have furt er found that my explosives possess eat stability to v the conditions under 'w ich explosives'are. made, stored, shipped and em loyed and that, therefore, they can be ro need and employed with a maximum 0 safety.
The explosives of my invention, therefore,
" contain the salt of an organic amino sulphonic acid intermixed with an ';oxidizing compound.
By organic amino sulpho acids, I mean the sulpho acids of amino compounds of produced.
Application filed May'5, 1925. Serial- No. 21:;242.
. gen, nitric acid esters, aliphatic and 'aro-' matic 'nitro compounds and their substituted products, although I do not limit myself to the specifically mentioned compounds.
The salts of the organic amino sulpho acids may replace wholly, or in part, other oxldizable substances such as aliphatic and aromatic hydrocarbons, wood meal or other forms of cellulose, coal, charcoal or other forms of carbon, sulphides, sulphur, carbohydrates, acetyl cellulose, salts of aliphatic or aromatic sulphonic acids, resins, fatty oils, glue, metallic magnesium, zinc, al-umi- -num, lI'On complex cyamdes, alcohols, glycerines, aromatic bases, ureas, tars, turpentines, camphor, soap, etc. Inert materials such as.
kiesel'guhr, mica, etc. may be usedto reduce the explosive power.
As an example of an explosive ofmy invention, I can use 20 parts by weight of theanhydrous sodium salt of sulphanilic acid and 43 parts by weight of potassium nitrate. These salts may be employed b intermixing their aqueous solutions and drying, or by intermixing the finely ground dr ed powders,
but I prefer the former method because of the greater uniformity The product thus obtained possesses high invention.
'What I claim is I I 1.-An explosive containing a salt of an organic amino sulpho acid.
of the product thus I 2. An explosive containing a salt of an" aromatic amino sulpho acid.
3. An explosive containinga water-soluble salt of an organic amino sulpho acid.
4. An explosive containing a water-soluble oxidizing of an organlc amino sulpho acid.
salt of an aromatic amino sulpho acid.
5. An explosive comprlsmg an OXIdIZIIIg substance and a salt of an organic amino sulpho acid.
6. An explosive comprising an oxidizing substance and a salt of an aromatic amino sulpho acid.
7. An explosive comprising an oxidizing substance and a water soluble salt of an organic amino sulpho acid. I
'8. An explosive comprising an' oxidizing substance and a water-soluble salt of an aromatic amino sulpho 9. An explosive comprising a Water soluble substance and a Water-soluble salt 10. An explosive comprising a Watersoluble oxidizing substance and a water solible salt of an aromatic amino sulpho ac1 Signed at Belleville in the county of Essex and State of New Jersey this 29th day of April, 1925.
A'ooB EHRLICH;
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US28242A US1550064A (en) | 1925-05-05 | 1925-05-05 | Explosive |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US28242A US1550064A (en) | 1925-05-05 | 1925-05-05 | Explosive |
Publications (1)
Publication Number | Publication Date |
---|---|
US1550064A true US1550064A (en) | 1925-08-18 |
Family
ID=21842343
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US28242A Expired - Lifetime US1550064A (en) | 1925-05-05 | 1925-05-05 | Explosive |
Country Status (1)
Country | Link |
---|---|
US (1) | US1550064A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2616788A (en) * | 1948-12-08 | 1952-11-04 | Ici Ltd | Method of lowering the tendency towards setting of ammonium sulfate and ammonium sulfate of free-flowing form with a reduced tendency to setting |
US2616787A (en) * | 1947-01-06 | 1952-11-04 | Ici Ltd | Free-flowing ammonium nitrate and method for the production of same |
US2616785A (en) * | 1948-12-29 | 1952-11-04 | Ici Ltd | Method of lowering the tendency towards setting of potassium nitrate and potassium nitrate of free-flowing form with a reduced tendency to setting |
US2680067A (en) * | 1950-08-31 | 1954-06-01 | Ici Ltd | Blasting explosive containing a water-soluble polysaccharide ether |
US2720446A (en) * | 1950-09-25 | 1955-10-11 | Ici Ltd | Free-flowing ammonium nitrate |
-
1925
- 1925-05-05 US US28242A patent/US1550064A/en not_active Expired - Lifetime
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2616787A (en) * | 1947-01-06 | 1952-11-04 | Ici Ltd | Free-flowing ammonium nitrate and method for the production of same |
US2616788A (en) * | 1948-12-08 | 1952-11-04 | Ici Ltd | Method of lowering the tendency towards setting of ammonium sulfate and ammonium sulfate of free-flowing form with a reduced tendency to setting |
US2616785A (en) * | 1948-12-29 | 1952-11-04 | Ici Ltd | Method of lowering the tendency towards setting of potassium nitrate and potassium nitrate of free-flowing form with a reduced tendency to setting |
US2680067A (en) * | 1950-08-31 | 1954-06-01 | Ici Ltd | Blasting explosive containing a water-soluble polysaccharide ether |
US2720446A (en) * | 1950-09-25 | 1955-10-11 | Ici Ltd | Free-flowing ammonium nitrate |
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