US12241135B2 - High-strength hot-rolled steel sheet having excellent blanking properties and uniformity, and manufacturing method thereof - Google Patents
High-strength hot-rolled steel sheet having excellent blanking properties and uniformity, and manufacturing method thereof Download PDFInfo
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- US12241135B2 US12241135B2 US17/429,855 US201917429855A US12241135B2 US 12241135 B2 US12241135 B2 US 12241135B2 US 201917429855 A US201917429855 A US 201917429855A US 12241135 B2 US12241135 B2 US 12241135B2
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 146
- 239000010959 steel Substances 0.000 title claims abstract description 146
- 238000004519 manufacturing process Methods 0.000 title claims description 22
- 229910000734 martensite Inorganic materials 0.000 claims abstract description 63
- 229910001563 bainite Inorganic materials 0.000 claims abstract description 32
- 229910000859 α-Fe Inorganic materials 0.000 claims abstract description 19
- 239000012535 impurity Substances 0.000 claims abstract description 11
- 238000005336 cracking Methods 0.000 claims abstract description 9
- 229910052742 iron Inorganic materials 0.000 claims abstract description 7
- 238000001816 cooling Methods 0.000 claims description 60
- 239000002344 surface layer Substances 0.000 claims description 36
- 238000005096 rolling process Methods 0.000 claims description 25
- 238000005275 alloying Methods 0.000 claims description 18
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 13
- 238000005098 hot rolling Methods 0.000 claims description 13
- 229910052804 chromium Inorganic materials 0.000 claims description 9
- 229910052748 manganese Inorganic materials 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 238000005259 measurement Methods 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 229910052758 niobium Inorganic materials 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 229910052698 phosphorus Inorganic materials 0.000 claims description 6
- 238000003303 reheating Methods 0.000 claims description 6
- 229910045601 alloy Inorganic materials 0.000 abstract description 10
- 239000000956 alloy Substances 0.000 abstract description 10
- 230000000052 comparative effect Effects 0.000 description 44
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- 230000015572 biosynthetic process Effects 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000006104 solid solution Substances 0.000 description 6
- 230000007423 decrease Effects 0.000 description 5
- 239000002244 precipitate Substances 0.000 description 5
- 238000009749 continuous casting Methods 0.000 description 4
- 238000004080 punching Methods 0.000 description 4
- 238000001887 electron backscatter diffraction Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229910001339 C alloy Inorganic materials 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229910000677 High-carbon steel Inorganic materials 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
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- 230000002542 deteriorative effect Effects 0.000 description 2
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- 238000000465 moulding Methods 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000009628 steelmaking Methods 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 241000219307 Atriplex rosea Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000599 Cr alloy Inorganic materials 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 1
- 229910000914 Mn alloy Inorganic materials 0.000 description 1
- 229910001182 Mo alloy Inorganic materials 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 229910001294 Reinforcing steel Inorganic materials 0.000 description 1
- 229910000676 Si alloy Inorganic materials 0.000 description 1
- 229910000756 V alloy Inorganic materials 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229910001566 austenite Inorganic materials 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
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- 230000003111 delayed effect Effects 0.000 description 1
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Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B3/00—Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
- B21B3/02—Rolling special iron alloys, e.g. stainless steel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B37/00—Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
- B21B37/74—Temperature control, e.g. by cooling or heating the rolls or the product
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D11/00—Process control or regulation for heat treatments
- C21D11/005—Process control or regulation for heat treatments for cooling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/32—Ferrous alloys, e.g. steel alloys containing chromium with boron
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/002—Bainite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/005—Ferrite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
Definitions
- CR is a cooling rate (° C./s) in a cooling zone
- LCR is a minimum critical cooling rate (° C./s)
- a minimum value thereof is 5 and a maximum value thereof is 45
- HCR is a maximum critical cooling rate (° C./s)
- a minimum value thereof is 50 and a maximum value thereof is 200
- [C], [Si], [Mn], [Cr], [Mo] and [B] are weight % of a corresponding alloying element.
- FIG. 1 is an EBSD image illustrating a microstructure of a surface layer part and a central part of Inventive Steel 3.
- each alloy element is weight %.
- C is the most economical and effective element for reinforcing steel, and as the amount added increases, the fraction of ferrite phase decreases, and bainite and martensite phases with high hardness may be obtained due to the solid solution strengthening effect.
- the content thereof is less than 0.10%, it may be difficult to obtain a sufficient reinforcing effect, and if the content exceeds 0.30%, the martensite phase having an excessively hard and low brittleness characteristic is formed, and there is a problem in that the blanking properties is lowered.
- the C content may be 0.10 to 0.30%.
- the upper limit of C may preferably be 0.25%, more preferably 0.23%.
- the lower limit of C may preferably be 0.15%, more preferably 0.17%.
- Si deoxidizes molten steel and has a solid solution strengthening effect, and may be advantageous in improving blanking properties by delaying the formation of coarse carbides.
- the content is less than 0.001%, it may be difficult to obtain the above effect, and if the content thereof exceeds 1.0%, red scale is formed on the surface of the steel sheet during hot rolling, resulting in significantly poor quality of the steel sheet surface and lowering the surface hardness. Therefore, it may be preferable to limit the content thereof to 1.0% or less. Accordingly, the Si content may be 0.001 to 1.0%.
- the upper limit of Si may preferably be 0.7%, more preferably 0.5%.
- the lower limit of Si may preferably be 0.003%, more preferably 0.005%.
- Mn is an effective element for solid-solution strengthening of steel, and increases the hardenability of the steel and suppresses the formation of ferrite upon cooling, thereby increasing the strength and hardness of the steel.
- the content thereof is less than 0.5%, the above effect due to the addition thereof may not be obtained, and if the content exceeds 2.5%, the segregation part is greatly developed at the thickness center during a continuous casting process of the slab, and when cooling after hot rolling, the microstructure in the thickness direction is formed non-uniformly, resulting in inferior blanking properties.
- the Mn content may be 0.5 to 2.5%.
- the upper limit of Mn may preferably be 2.2%, more preferably 2.0%.
- the lower limit of Mn may preferably be 0.8%, more preferably 1.0%.
- Cr is an element for solid-solution strengthening of steel and increases hardenability of steel to suppress ferrite formation, thereby increasing the strength and hardness of steel.
- the Cr content may be 0.001 to 1.5%.
- the upper limit of Cr may preferably be 1.2%, more preferably 1.0%.
- the lower limit of Cr may preferably be 0.003%, more preferably 0.005%.
- Mo serves to improve blanking properties by strengthening the grain boundary and to increase the strength of steel by improving the hardenability of the steel.
- the Mo content may be 0.001 to 0.5%.
- the upper limit of Mo may preferably be 0.45%, more preferably 0.4%.
- the lower limit of Mo may preferably be 0.003%, more preferably 0.005%.
- Al is a component added for deoxidation, and if the content thereof in the dissolved state is less than 0.001%, the deoxidation effect is not sufficient. If the content thereof exceeds 0.5%, defects are likely to occur due to the formation of inclusions, and there is a problem causing nozzle clogging during continuous casting. Accordingly, the Al content may be 0.001 to 0.5%.
- the upper limit of Al may preferably be 0.45%, more preferably 0.4%.
- the lower limit of Al may preferably be 0.003%, more preferably 0.005%.
- P is an impurity unavoidably contained in steel, and it may be advantageous to control the content thereof as low as possible. However, in order to enable the P content to be less than 0.001%, a lot of manufacturing cost is required, and thus, it may be economically disadvantageous. If the content exceeds 0.01%, brittleness occurs due to grain boundary segregation, thereby deteriorating blanking properties of the steel. Therefore, the P content may be 0.001 to 0.01%.
- the upper limit of P may preferably be 0.008%, more preferably 0.007%.
- the lower limit of P may preferably be 0.002%, more preferably 0.003%.
- S is an impurity present in steel, and if the content thereof exceeds 0.01%, S is combined with Mn or the like and thus, it may be easy to form non-metallic inclusions, which causes a decrease in blanking properties of the steel.
- the S content may be 0.001 to 0.01%.
- the upper limit of S may preferably be 0.008%, more preferably 0.007%.
- the lower limit of S may preferably be 0.002%, more preferably 0.003%.
- N is a solid solution strengthening element.
- the N content may be 0.001 to 0.01%.
- the upper limit of N may preferably be 0.008%, more preferably 0.007%.
- the lower limit of N may preferably be 0.002%, more preferably 0.003%.
- B is an element increasing the hardenability of steel to facilitate securing of martensite and bainite phases, and the effect thereof is known to be excellent compared to other elements.
- the content may be less than 0.0001%, it may be difficult to obtain a sufficient hardenability synergistic effect, and if the content thereof exceeds 0.004%, the hardenability synergistic effect is saturated, and thus, it may be difficult to expect an increase in hardenability by additional addition.
- the B content may be 0.0001 to 0.004%.
- the upper limit of B may preferably be 0.0035%, more preferably 0.003%.
- the lower limit of B may preferably be 0.0003%, more preferably 0.0005%.
- Ti has a precipitation strengthening effect through the generation of TiC, and has a strong affinity with N to form coarse TiN in steel, and has the effect of improving the hardenability of steel by suppressing the formation of BN.
- the Ti content may be 0.001 to 0.1%.
- the upper limit of Ti may preferably be 0.08%, more preferably 0.07%.
- the lower limit of Ti may preferably be 0.003%, more preferably 0.005%.
- Nb is a representative precipitation strengthening element, and precipitates during hot rolling to contribute to the improvement of strength, hardness and blanking properties of steel due to the effect of grain refinement due to delayed recrystallization.
- the Nb content may be 0.001 to 0.1%.
- the upper limit of Nb may preferably be 0.08%, more preferably 0.07%.
- the lower limit of Nb may preferably be 0.003%, more preferably 0.005%.
- the remainder is iron (Fe).
- Fe iron
- the remainder is iron (Fe).
- unintended impurities from raw materials or the surrounding environment may inevitably be mixed, and thus, it cannot be excluded. Since these impurities are known to those skilled in the art, all details thereof are not described in detail.
- the high-strength hot-rolled steel sheet according to an exemplary embodiment of the present disclosure satisfies the above-described alloy composition, and also satisfies the following Relation Expression (1) to secure blanking properties.
- CL ⁇ 1, CL ⁇ 0.692 ⁇ 0.158 ⁇ [Mn]+0.121 ⁇ [Mn] 2 +0.061 ⁇ [Cr] 2 ⁇ 0.319 ⁇ [Mo]+0.035 ⁇ [Hardness_HRC], [Relationship Expression (1)]
- the effective cracking index (CL) is an index indicating the blanking characteristics of steel. When this value is 1 or more, it may be determined that a crack of an effective size that leads to a fatal defect occurs in the punched surface of the steel.
- the blanking properties of steel are affected by segregation according to the content of alloying elements, and the contents of Mn and Cr, which are mainly included in large amounts in the steel and are known to cause segregation in the continuous casting process, are major indicators related thereto. As the content of Mn and Cr increases, blanking properties is deteriorated due to segregation by exceeding linear tendency.
- the main phase consists of a martensite phase and a bainite phase
- the fraction of the martensite phase is 50% or more and less than 90%
- the fraction of the bainite phase is 5% or more and 50% or less.
- the sum of the fractions of the martensite phase and the bainite phase may be 90% or more, and the balance may consist of a ferrite phase.
- the average packet size of the martensite phase is 1 to 7 ⁇ m in a circle-equivalent diameter
- the aspect ratio of the packet structure of the martensite phase may be 1 to 5 in a central part (t/4 to t/2) in the thickness direction, and may be 1.1 to 6 in the surface layer part (surface layer to t/8) in the thickness direction, and the value obtained by dividing the aspect ratio of a surface layer part by the aspect ratio of the central part may be 0.9-2.
- the main phase consists of a martensite phase and a bainite phase, and in this case, the fraction of the martensite phase may be 50% or more and less than 90%. If the fraction of the martensite phase is less than 50%, the fraction of the ferrite/bainite phase having a relatively low hardness increases, and thus the target hardness may not be secured. On the other hand, if the fraction of the martensite phase is 90% or more, the toughness of the steel is significantly insufficient, and it may be difficult to secure target blanking characteristics. Therefore, it may be preferable to limit the fraction of the martensite phase to 50% or more and less than 90%.
- the fraction of the bainite phase may be 5% or more and 50% or less.
- the bainite phase has a slightly lower hardness than that of the martensite phase, but has a similar level thereto, and the degree of contribution of the bainite phase to blanking properties during production is superior to that of the martensite phase, and thus, it is necessary to include at least 5% or more of bainite phase to maintain the balance of hardness and blanking properties.
- the fraction thereof exceeds 50%, it may be difficult to satisfy the target hardness, and thus, a maximum value thereof is limited to 50% or less. Therefore, it may be preferable to limit the fraction of the bainite phase to 5% or more and 50% or less.
- the sum of the fractions of the martensite phase and the bainite phase may be 90% or more, and the remainder may consist of a ferrite phase. If the fraction of the ferrite phase, which is the remainder except for the martensite phase and the bainite phase, is 10% or more, the blanking property is reduced due to the difference in hardness between the phases at the ferrite-martensite interface, and thus, the fraction of the ferrite phase may be preferably limited to less than 10%.
- the martensite phase is the main phase among the martensite phase and the bainite phase, and the fraction thereof is 75% or more.
- the microstructure of the hot-rolled steel sheet according to an exemplary embodiment of the present disclosure may consist of only a martensite phase and a bainite phase without a ferrite phase.
- the average packet size of the martensite phase may be 1 to 7 ⁇ m in a circle-equivalent diameter.
- the packet of the martensite phase indicates adjacent structures having the same azimuthal texture in martensite, and the average size thereof may be defined by obtaining the circle-equivalent diameter of microstructures showing the same direction through SEM measurement to obtain the average value, or by specifying the size of microstructures having the same azimuth relationship through EBSD measurement or the like.
- the average packet size is preferably measured at the central portion of the steel sheet, and may also be measured by other well-known methods well known in the related art.
- the blanking properties of the steel may be increased through grain refinement. If the average packet size thereof is less than 1 ⁇ m, an excessive rolling load occurs in the hot rolling process for grain refinement, whereas if the average packet size thereof exceeds 7 ⁇ m, it may be difficult to expect an effect of increasing hardness through grain refinement. Therefore, it may be preferable that the average packet size of the martensite phase is 1 to 7 ⁇ m in a circle-equivalent diameter.
- the aspect ratio of the packet structure of the martensite phase may be 1 to 5 in the central part (t/4 to t/2) in the thickness direction, and may be 1.1-6 in the surface layer part (surface layer to t/8) in the thickness direction, and the value obtained by dividing the aspect ratio of the surface layer part by the aspect ratio of the central part may be 0.9-2.
- the aspect ratio of the packet structure of the martensite phase may be defined as a value obtained by dividing a long axis of an oval by a short axis thereof by simplifying adjacent microstructures having the same azimuthal texture in the form of the oval in martensite.
- the aspect ratio of the packet structure of the martensite phase is less than 1 in the central part (t/4 to t/2) in the thickness direction, the crystal grain refinement effect due to the recrystallization delay is insufficient to increase the hardness, whereas if the aspect ratio exceeds 5, partial recrystallization occurs up to the central part of the steel and blanking properties are deteriorated due to material deviation of the steel in the thickness direction.
- the aspect ratio is less than 1.1 in the surface layer part (surface layer to t/8) in the thickness direction, the recrystallization delay phenomenon by rolling hardly occurs even in the surface layer, and thus, the surface hardening effect to obtain the target hardness is insufficient.
- the value exceeds 6 excessive partial recrystallization occurs in the surface layer, causing deterioration of blanking properties due to material deviation in the thickness direction.
- the value obtained by dividing the aspect ratio of the surface layer part by the aspect ratio of the central part is less than 0.9, the hardening effect of the surface layer due to recrystallization delay is insufficient, and if the value exceeds 2, the blanking characteristics are deteriorated due to material deviation in the thickness direction.
- the aspect ratio of the packet structure of the martensite phase is 1 to 5 in the central part (t/4 to t/2) in the thickness direction and is 1.1 to 6 in the surface layer part (surface layer to t/8) in the thickness direction, and the value obtained by dividing the aspect ratio of the surface layer part by the aspect ratio of the central part is 0.9 to 2.
- the high-strength hot-rolled steel sheet has a tensile strength of 1100 MPa or more and a surface hardness of 35 HRC or more.
- the difference between a maximum value and a minimum value of each measurement result is within 140 MPa of tensile strength and within 4 HRC of surface hardness.
- the 9 sites of the total width indicates selecting 9 portions of the coiled hot-rolled steel sheet
- the 3 sites of the total length indicates selecting 3 portions of the coiled hot-rolled steel sheet in the longitudinal direction.
- a method of manufacturing a high-strength hot-rolled steel sheet includes reheating a steel slab satisfying the following Relationship Expression (1) to 1180-1350° C., the steel slab comprising, by weight %, C: 0.10 to 0.30%, Si: 0.001 to 1.0%, Mn: 0.5 to 2.5%, Cr: 0.001 to 1.5%, Mo: 0.001 to 0.5%, Al: 0.001 to 0.5%, P: 0.001 to 0.01%, S: 0.001 to 0.01%, N: 0.001 to 0.01%, B: 0.0001 to 0.004%, Ti: 0.001 to 0.1%, Nb: 0.001 to 0.1%, and balances of iron and unavoidable impurities; hot rolling the reheated steel slab to satisfy the following Relationship Expression (2); cooling a hot-rolled steel sheet to a temperature in a range of 0 to 400° C.
- Tn is a critical rolling temperature (° C.)
- FDT is a rolling finishing temperature (° C.)
- [C], [Si], [Mn], [Cr], [Mo], [B], [Nb] and [Ti] are weight % of a corresponding alloying element.
- CR is a cooling rate (° C./s) in a cooling zone
- LCR is a minimum critical cooling rate (° C./s)
- a minimum value thereof is 5 and a maximum value thereof is 45
- HCR is a maximum critical cooling rate (° C./s)
- a minimum value thereof is 50 and a maximum value thereof is 200
- [C], [Si], [Mn], [Cr], [Mo] and [B] are weight % of a corresponding alloying element.
- a steel slab having the above-described alloy composition and satisfying the above relationship expression (1) is reheated at a temperature of 1180 to 1350° C.
- the reheating temperature is less than 1180° C.
- the precipitates are not sufficiently re-dissolved, and thus, the formation of precipitates in the process after hot rolling is reduced, coarse TiN remains, and it may be difficult to solve the segregation generated during continuous casting by diffusion.
- the reheating temperature may preferably be limited to 1180 to 1350° C.
- the reheated slab is hot-rolled at a temperature in the range of 750 to 1000° C. If hot rolling is started at a high temperature exceeding 1000° C., the temperature of the hot-rolled steel sheet increases, resulting in coarse grain size and insufficient descaling, and thereby, resulting in poor surface quality of the hot-rolled steel sheet. In addition, if the rolling is finished at a temperature of less than 750° C., the recrystallization behavior of the steel is different for respective locations, the material is not uniform, and the blanking properties are deteriorated.
- the hot rolling is performed to satisfy the following Relationship Expression (2) for the rolling finishing temperature (FDT).
- Tn ⁇ 70 ⁇ FDT ⁇ Tn Tn 967 ⁇ 280 ⁇ [C]+35.7 ⁇ [Si] ⁇ 28.1 ⁇ [Mn] ⁇ 11.4 ⁇ [Cr]+11.4 ⁇ [Mo] ⁇ 62 ⁇ [Ti]+46.2 ⁇ [Nb], [Relationship Expression (2)]
- Tn is the critical rolling temperature (° C.)
- FDT is the rolling finishing temperature (° C.)
- [C], [Si], [Mn], [Cr], [Mo], [B], [Nb] and [Ti] are the weight % of the corresponding alloying element.
- the above Relationship Expression (2) is an expression which shows the relationship between the rolling finishing temperature and a component of the steel.
- the rolling finishing temperature (FDT) of the steel is controlled to be the critical rolling temperature (Tn) or lower, the average packet size of the martensite phase in the microstructures of the manufactured steel is 1 to 7 ⁇ m in a circle-equivalent diameter to increase the punchability of the steel through grain refinement.
- the rolling finishing temperature (FDT) of the steel to be Tn ⁇ 70 or higher, controlling the aspect ratio of the packet structure of the martensite phase to be 1 to 5 in the central part (t/4 to t/2) in the thickness direction and 1.1 to 6 in the surface layer part (surface layer to t/8) in the thickness direction, and controlling the value obtained by dividing the aspect ratio of the surface layer part by the aspect ratio of the central part to be 0.9 to 2, the blanking properties and uniformity of steel may be improved.
- the rolled steel sheet is cooled to a temperature in the range of 0 to 400° C. at an average cooling rate of 5 to 200° C./sec, and is coiled at a temperature in the range of 0 to 400° C., and the cooling rate of the steel sheet at this time is set to satisfy the following Relationship Expression (3) according to the component of steel grade.
- CR is the cooling rate (° C./s) in the cooling zone
- LCR is a minimum critical cooling rate (° C./s)
- a minimum value thereof is 5 and a maximum value thereof is 45
- HCR is a maximum critical cooling rate (° C./s)
- a minimum value thereof is 50 and a maximum value thereof is 200
- [C], [Si], [Mn], [Cr], [Mo] and [B] are the weight % of the corresponding alloying element.
- the above Relationship Expression (3) is an expression for the cooling conditions of the steel.
- the cooling conditions in the cooling zone determine the microstructure of the steel and have a dominant influence on strength and hardness.
- the cooling condition of the steel should consider the change in hardenability according to the amount of alloying element added. Therefore, it is essential to apply an optimum cooling rate according to the alloying elements contained in the steel.
- the maximum critical cooling rate (HCR) and the minimum critical cooling rate (LCR) are respectively obtained by the addition amount of the alloying element, and the cooling rate (CR) in the cooling zone is provided to satisfy between the maximum critical cooling rate (HCR) and the minimum critical cooling rate (LCR). If the steel is cooled at a faster rate than the maximum critical cooling rate (HCR), the martensitic structure having a hard but poor brittleness characteristic is created, which reduces blanking properties, deteriorates the shape of the steel, and lowers uniformity due to a non-uniform amount of pouring water in all sections by excessive rapid cooling in the cooling zone.
- the packet structure of the martensite phase was observed in the central part in the thickness direction and the surface layer part in the thickness direction, and each packet was simplified in the form of an ellipse.
- the aspect ratio obtained by dividing a length of a long axis of the ellipse by a length of a short axis thereof was measured and the measurement results are illustrated in Table 3 below.
- the tensile strength in Table 4 below is the total average of values obtained by measuring the tensile strength or Rockwell hardness at uniform intervals in 9 sites of the total width and 3 sites in the total length of the coil-shaped hot-rolled steel sheet after coiling. The tensile strength was measured once for each location, and the hardness was measured 10 times for each location. The deviation of tensile strength indicates the difference between maximum and minimum values among the measured values.
- CL represents the effective cracking index, and when cracks of an effective size occur when punching steel, it is indicated by ‘’ for satisfaction of blanking properties, and indicated by ‘X’ if not.
- Inventive Steels 1 to 8 satisfy the alloy composition presented in the present disclosure, and thus all have a tensile strength of 1100 MPa or more and a surface hardness of 35 HRC or more.
- Comparative Steel 1 had a carbon concentration of 0.08%, which fell short of the component range, and thus, the solid solution strengthening effect by C was insufficient, and thus the hardness and strength compared to the target were insufficient.
- the component range of each alloy component of Comparative Steel 2 satisfies the conditions of the present disclosure, but the Tn value is lower than usual, and thus the FDT is higher than Tn, such that the Relationship Expression (2) is not satisfied. Due to this high rolling finishing temperature, the martensitic structure of the surface layer and the deep layer was coarse, resulting in lowering of the blanking properties. In addition, in the case of Comparative Steel 3, the FDT temperature was lower than Tn ⁇ 70 because the rolling was finished at an excessively low temperature, such that the Relationship Expression (2) was not satisfied. As a result, an excessively deformed microstructure was formed in the surface layer, and the blanking properties were reduced due to the microstructure deviation between the surface layer part and the central part, and the uniformity was reduced.
- Comparative Steel 8 contains a large amount of component systems such as C that hardens the steel, and thus has a component system with a significantly high hardness value.
- Relationship Expression (1) was not satisfied due to an excessive increase in hardness, and a number of effective cracks that had a fatal impact on product quality occurred during punching.
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Abstract
CL<1, [Relationship Expression (1)]
CL=−0.692−0.158×[Mn]+0.121×[Mn]2+0.061×[Cr]2−0.319×[Mo]+0.035×[Hardness_HRC] (where CL is an effective cracking index, [Mn], [Cr] and [Mo] are the percentages by weight of respective corresponding alloy elements, and [Hardness_HRC] is a Rockwell hardness (HRC).)
Description
- (Patent Document 1) European Patent Application Publication No. 1375694
- (Patent Document 2) Japanese Patent Laid-Open Publication No. 1999-302781
CL<1,
CL=−0.692−0.158×[Mn]+0.121×[Mn]2+0.061×[Cr]2−0.319×[Mo]+0.035×[Hardness_HRC], [Relationship Expression (1)]
Tn−70≤FDT≤Tn,
Tn=967−280×[C]+35.7×[Si]−28.1×[Mn]−11.4×[Cr]+11.4×[Mo]−62×[Ti]+46.2×[Nb], [Relationship Expression (2)]
LCR≤CR≤HCR,
LCR=2000/(−1076+2751×[C]+17×[Si]+301×[Mn]+330×[Cr]+355×[Mo]+42939×[B])
HCR=2500/(−70.3+198×[C]+32.0×[Si]+16.7×[Mn]+18.4×[Cr]+42.1×[Mo]+5918×[B]), [Relationship Expression (3)]
CL<1,
CL=−0.692−0.158×[Mn]+0.121×[Mn]2+0.061×[Cr]2−0.319×[Mo]+0.035×[Hardness_HRC], [Relationship Expression (1)]
CL<1,
CL=−0.692−0.158×[Mn]+0.121×[Mn]2+0.061×[Cr]2−0.319×[Mo]+0.035×[Hardness_HRC], [Relationship Expression (1)]
CL<1,
CL=−0.692−0.158×[Mn]+0.121×[Mn]2+0.061×[Cr]2−0.319×[Mo]+0.035×[Hardness_HRC] [Relationship Expression (1)]
Tn−70≤FDT≤Tn
Tn=967−280×[C]+35.7×[Si]−28.1×[Mn]−11.4×[Cr]+11.4×[Mo]−62×[Ti]+46.2×[Nb], [Relationship Expression (2)]
LCR≤CR≤HCR
LCR=2000/(−1076+2751×[C]+17×[Si]+301×[Mn]+330×[Cr]+355×[Mo]+42939×[B])
HCR=2500/(−70.3+198×[C]+32.0×[Si]+16.7×[Mn]+18.4×[Cr]+42.1×[Mo]+5918×[B]), [Relationship Expression (3)]
Tn−70≤FDT≤Tn
Tn=967−280×[C]+35.7×[Si]−28.1×[Mn]−11.4×[Cr]+11.4×[Mo]−62×[Ti]+46.2×[Nb], [Relationship Expression (2)]
LCR≤CR≤HCR,
LCR=2000/(−1076+2751×[C]+17×[Si]+301×[Mn]+330×[Cr]+355×[Mo]+42939×[B])
HCR=2500/(−70.3+198×[C]+32.0×[Si]+16.7×[Mn]+18.4×[Cr]+42.1×[Mo]+5918×[B]), [Relationship Expression (3)]
-
- FDT: Rolling finishing temperature (° C.)
- Tn: Critical rolling temperature (° C.)
- CR: Cooling rate in the cooling zone (° C./s)
- LCR: Minimum critical cooling rate (° C./s)
- HCR: Maximum critical cooling rate (° C./s)
TABLE 1 | ||||||||||||
Specimen | C | Si | Mn | Cr | Mo | Al | P | S | N | B | Ti | Nb |
Comparative steel1 | 0.080 | 0.100 | 1.400 | 0.400 | 0.002 | 0.002 | 0.003 | 0.003 | 0.002 | 0.002 | 0.015 | 0.001 |
Comparative steel2 | 0.295 | 0.050 | 1.200 | 0.300 | 0.100 | 0.002 | 0.003 | 0.003 | 0.003 | 0.002 | 0.015 | 0.001 |
Comparative steel3 | 0.160 | 0.040 | 1.800 | 0.200 | 0.200 | 0.200 | 0.002 | 0.002 | 0.002 | 0.001 | 0.002 | 0.001 |
Comparative steel4 | 0.180 | 0.500 | 1.350 | 0.060 | 0.200 | 0.010 | 0.002 | 0.004 | 0.003 | 0.001 | 0.010 | 0.050 |
Comparative steel5 | 0.195 | 0.150 | 1.500 | 0.100 | 0.100 | 0.010 | 0.003 | 0.003 | 0.003 | 0.001 | 0.020 | 0.010 |
Comparative steel6 | 0.170 | 0.300 | 2.200 | 0.100 | 0.050 | 0.002 | 0.003 | 0.002 | 0.004 | 0.001 | 0.015 | 0.015 |
Comparative steel7 | 0.190 | 0.300 | 1.500 | 1.480 | 0.010 | 0.002 | 0.003 | 0.002 | 0.002 | 0.001 | 0.015 | 0.015 |
Comparative steel8 | 0.270 | 0.100 | 1.600 | 0.700 | 0.010 | 0.002 | 0.003 | 0.002 | 0.002 | 0.002 | 0.015 | 0.020 |
Inventive steel1 | 0.210 | 0.002 | 1.400 | 0.002 | 0.200 | 0.002 | 0.003 | 0.002 | 0.002 | 0.0015 | 0.025 | 0.002 |
Inventive steel2 | 0.210 | 0.002 | 1.800 | 0.002 | 0.002 | 0.003 | 0.002 | 0.003 | 0.003 | 0.0015 | 0.025 | 0.002 |
Inventive steel3 | 0.195 | 0.100 | 1.250 | 0.600 | 0.200 | 0.002 | 0.003 | 0.003 | 0.002 | 0.0015 | 0.015 | 0.020 |
Inventive steel4 | 0.195 | 0.100 | 1.100 | 0.800 | 0.200 | 0.003 | 0.003 | 0.004 | 0.002 | 0.0015 | 0.015 | 0.020 |
Inventive steel5 | 0.210 | 0.003 | 1.250 | 0.800 | 0.200 | 0.003 | 0.004 | 0.002 | 0.003 | 0.0015 | 0.015 | 0.020 |
Inventive steel6 | 0.210 | 0.002 | 1.400 | 0.400 | 0.200 | 0.004 | 0.002 | 0.002 | 0.003 | 0.0015 | 0.015 | 0.020 |
Inventive steel7 | 0.210 | 0.003 | 1.400 | 0.800 | 0.200 | 0.002 | 0.002 | 0.001 | 0.002 | 0.0015 | 0.015 | 0.002 |
Inventive steel8 | 0.230 | 0.100 | 1.400 | 0.800 | 0.200 | 0.002 | 0.001 | 0.003 | 0.002 | 0.0015 | 0.015 | 0.020 |
TABLE 2 | ||||
Rolling conditions | Cooling conditions | Microstructure Fraction |
(Relationship Expression 2) | (Relationship Expression 3) | Satisfied or |
Specimen | Tn-70 | FDT | Tn | LCR | CR | HCR | Fer | Bai | Mar | Not Satisfied |
Comparative steel1 | 833 | 880 | 903 | 5 | 45 | 50 | 0.05 | 0.08 | 0.87 | ◯ |
Comparative steel2 | 779 | 860 | 849 | 5 | 65 | 80 | 0.08 | 0.12 | 0.80 | ◯ |
Comparative steel3 | 803 | 790 | 873 | 23 | 145 | 200 | 0.02 | 0.10 | 0.88 | ◯ |
Comparative steel4 | 830 | 850 | 900 | 5 | 140 | 129 | 0.00 | 0.02 | 0.98 | X |
Comparative steel5 | 805 | 840 | 875 | 45 | 40 | 200 | 0.15 | 0.25 | 0.60 | X |
Comparative steel6 | 797 | 830 | 867 | 13 | 100 | 128 | 0.00 | 0.11 | 0.89 | ◯ |
Comparative steel7 | 795 | 840 | 865 | 5 | 65 | 70 | 0.01 | 0.14 | 0.85 | ◯ |
Comparative steel8 | 772 | 830 | 842 | 5 | 60 | 65 | 0.01 | 0.09 | 0.89 | ◯ |
Inventive steel1 | 800 | 850 | 870 | 34 | 80 | 200 | 0.01 | 0.10 | 0.89 | ◯ |
Inventive steel2 | 786 | 850 | 856 | 18 | 120 | 200 | 0.02 | 0.15 | 0.83 | ◯ |
Inventive steel3 | 806 | 870 | 876 | 12 | 110 | 121 | 0.01 | 0.11 | 0.88 | ◯ |
Inventive steel4 | 808 | 870 | 878 | 10 | 80 | 114 | 0.01 | 0.20 | 0.79 | ◯ |
Inventive steel5 | 796 | 800 | 866 | 7 | 95 | 103 | 0.00 | 0.12 | 0.88 | ◯ |
Inventive steel6 | 797 | 800 | 867 | 10 | 100 | 129 | 0.00 | 0.13 | 0.87 | ◯ |
Inventive steel7 | 791 | 830 | 861 | 6 | 80 | 93 | 0.01 | 0.11 | 0.89 | ◯ |
Inventive steel8 | 790 | 820 | 860 | 5 | 70 | 74 | 0.01 | 0.16 | 0.84 | ◯ |
TABLE 3 | |||
Aspect ratio of packet structure of martensite phase |
Average | Central part | Surface layer part | Aspect ratio of | ||
packet size | in thickness | in thickness | surface layer part/ | Satisfied | |
of martensite | direction | direction (Surface | aspect ratio of | or Not | |
Specimen | phase (μm) | (t/4~t/2) | layer~t/2) | central part | Satisfied |
Comparative steel1 | 3.14 | 3.71 | 4.00 | 1.07 | ◯ |
Comparative steel2 | 7.08 | 2.89 | 3.21 | 1.10 | X |
Comparative steel3 | 2.37 | 3.14 | 8.44 | 2.68 | X |
Comparative steel4 | 4.47 | 3.88 | 4.28 | 1.10 | ◯ |
Comparative steel5 | 3.74 | 4.54 | 4.81 | 1.06 | ◯ |
Comparative steel6 | 4.88 | 4.98 | 5.14 | 1.0 | ◯ |
Comparative steel7 | 6.14 | 3.04 | 5.12 | 1.68 | ◯ |
Comparative steel8 | 5.77 | 4.87 | 5.87 | 1.20 | ◯ |
Inventive steel1 | 4.15 | 3.81 | 4.11 | 1.08 | ◯ |
Inventive steel2 | 5.12 | 4.11 | 4.51 | 1.09 | ◯ |
Inventive steel3 | 4.36 | 4.12 | 4.71 | 1.14 | ◯ |
Inventive steel4 | 4.87 | 3.71 | 4.72 | 1.27 | ◯ |
Inventive steel5 | 3.54 | 4.12 | 5.11 | 1.24 | ◯ |
Inventive steel6 | 3.81 | 4.47 | 5.64 | 1.26 | ◯ |
Inventive steel7 | 4.12 | 3.81 | 5.07 | 1.33 | ◯ |
Inventive steel8 | 3.94 | 4.24 | 4.41 | 1.04 | ◯ |
TABLE 4 | ||||||
Tensile | Tensile strength | Surface | Hardness | CL | Blanking property | |
strength | deviation | hardness | deviation | (Relationship | satisfied or | |
Specimen | (MPa) | (Δ MPa) | (HRC) | (Δ HRC) | Expression 1) | not satisfied |
Comparative steel1 | 984 | 51 | 35.1 | 1.8 | 0.56 | ◯ |
Comparative steel2 | 1901 | 121 | 52.9 | 5.1 | 1.12 | X |
Comparative steel3 | 1336 | 131 | 42.0 | 7.2 | 0.82 | ◯ |
Comparative steel4 | 1345 | 98 | 42.1 | 5.2 | 0.73 | ◯ |
Comparative steel5 | 1085 | 54 | 37.1 | 2.1 | 0.81 | ◯ |
Comparative steel6 | 1436 | 66 | 43.9 | 2.3 | 1.07 | X |
Comparative steel7 | 1476 | 72 | 44.7 | 2.2 | 1.04 | X |
Comparative steel8 | 1776 | 124 | 50.5 | 6.7 | 1.16 | X |
Inventive steel1 | 1443 | 62 | 44.0 | 1.8 | 0.80 | ◯ |
Inventive steel2 | 1459 | 55 | 44.3 | 1.9 | 0.97 | ◯ |
Inventive steel3 | 1406 | 68 | 43.3 | 2.2 | 0.77 | ◯ |
Inventive steel4 | 1389 | 41 | 43.0 | 1.4 | 0.76 | ◯ |
Inventive steel5 | 1488 | 66 | 44.9 | 2.4 | 0.85 | ◯ |
Inventive steel6 | 1485 | 31 | 44.8 | 1.5 | 0.84 | ◯ |
Inventive steel7 | 1527 | 52 | 45.7 | 1.9 | 0.90 | ◯ |
Inventive steel8 | 1631 | 67 | 47.7 | 2.1 | 0.97 | ◯ |
Claims (6)
CL<1,
CL=−0.692−0.158×[Mn]+0.121×[Mn]2+0.061×[Cr]2−0.319×[Mo]+0.035×[Hardness_HRC], Relationship Expression (1):
Tn−70≤FDT≤Tn,
Tn=967−280×[C]+35.7×[Si]−28.1×[Mn]−11.4×[Cr]+11.4×[Mo]−62×[Ti]+46.2×[Nb], Relationship Expression (2):
LCR≤CR≤HCR,
LCR=2000/(−1076+2751×[C]+17×[Si]+301×[Mn]+330×[Cr]+355×[Mo]+42939×[B])
HCR=2500/(−70.3+198×[C]+32.0×[Si]+16.7×[Mn]+18.4×[Cr]+42.1×[Mo]+5918×[B]) Relationship Expression (3):
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Also Published As
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US20220106656A1 (en) | 2022-04-07 |
CN113574199A (en) | 2021-10-29 |
WO2021125386A1 (en) | 2021-06-24 |
EP4079911A4 (en) | 2022-12-28 |
EP4079911A1 (en) | 2022-10-26 |
CN113574199B (en) | 2022-11-29 |
JP2022520835A (en) | 2022-04-01 |
JP7373576B2 (en) | 2023-11-02 |
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