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US1182947A - Boiler-cleaning composition. - Google Patents

Boiler-cleaning composition. Download PDF

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Publication number
US1182947A
US1182947A US4065015A US4065015A US1182947A US 1182947 A US1182947 A US 1182947A US 4065015 A US4065015 A US 4065015A US 4065015 A US4065015 A US 4065015A US 1182947 A US1182947 A US 1182947A
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US
United States
Prior art keywords
boiler
scale
composition
naphthalene
cleaning composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US4065015A
Inventor
George W Wallace
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HALENE PRODUCTS CO
Original Assignee
HALENE PRODUCTS CO
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HALENE PRODUCTS CO filed Critical HALENE PRODUCTS CO
Priority to US4065015A priority Critical patent/US1182947A/en
Application granted granted Critical
Publication of US1182947A publication Critical patent/US1182947A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • C02F5/10Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
    • C02F5/12Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/33Amino carboxylic acids

Definitions

  • This invention relates to substances that are used for removing scale from boilers
  • the boiler compounds or compositions that are now used for removing scale from boilers contemplate the removal of the scale by decomposing the insoluble scale-forming salts into soluble compounds.
  • Such compositions are composed principally of strong solvents, and while they succeed in removing the scale, they usually injure and frequently ruin the boiler in which they are used, by reason of the solvents attacking the iron from which the boiler is formed.
  • My improved composition difiers from the compositions that have heretofore been used for cleaning boilers in that it contains a substance that will disintegrate the scale without having any injurious effect on the iron of the boiler. It is also distinguished from prior boiler-cleaning compounds because it destroys the adhesive properties in the scale-forming salts in the water in the boiler and prevents said salts from combining or forming a scale when they are precipitated.
  • my improved boilercleaning composition consists of a saturated solution of naphthalene in hydrocarbon oil.
  • Any suitable hydrocarbon oil may be used, but I prefer to use an oil of low specific gravity.
  • Gasolene or naphtha may be used successfully, but I have obtained the best results from hydrocarbon oil of the benzin series, namely, toluene or Xylene, In pro- Specification of Letters Patent.
  • composition I simply dissolve naphthalene in hydrocarbon oil so as to form a saturated solution, and in using the composition I simply introduce it into the boiler with the feed water that is supplied to the boiler. If the inside of the boiler is dirty or coated with scale, the composition attacks the scale and disintegrates it or breaks it up into line particles by the chemical reaction of the naphthalene on the substances in the scale, which cause the particles of the scale to adhere to each other and to the iron of the boiler, the hydrocarbon oil on account of its capillary affinity penetrating into the interstices of the scale, and thus causing the naphthalene to be thoroughly distributed through the scale.
  • the composition breaks up the scale by destroying the adhesion between the particles of scale-forming salts and between saidparticles and the surface of the boiler on which they'are deposited.
  • my improved composition causes the scale-forming salts in the water in the boiler to become so thoroughly saturated or coated with the naphthalene that the salts will not combine and form a scale when they are precipitated.
  • a boiler-cleaning composition of the character above described has no injurious effect whatever on the boiler in which it is used, owing to the fact that it does not contain a strong solvent or ingredient that is injurious to iron. It merely consists of naphthalene and another ingredient that acts as a vehicle to carry the naphthalene into the pores of the scale and also to disseminate, or thoroughly distribute, the naphthalene through the feed water that carries the composition into the boiler.
  • a boiler-cleaning composition composed of naphthalene and a substance of great capillary affinity.
  • a boiler-cleaning composition consisting of a saturated solution of naphthalene in hydrocarbon oil.
  • a boiler-cleaning composition consistsignature in the presence of two witnesseses, ing of naphthalene and hydrocarbon oil of this sixteenth day of July, 1915. low specific gravity.
  • a boiler-cleaning composition consistc GEORGE WALLACE 5 ing of naphthalene and a hydrocarbon oil VVi'tnesses:

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Detergent Compositions (AREA)

Description

UNITED strArEs PA rEN'r OFFICE- GEORGE W.
WALLACE, OF EAST ST. LOUIS, ILLINOIS, ASSIGNOR TO HALENE PRODUCTS (30., OF ST. LOUIS, MISSOURI, A CORPORATION OF DELAWARE.
BOILER-OLEANING COMPOSITION.
No Drawing.
T 0 all whom it may concern Be it known that I, Gnoncn WV. WALLACE, a citizen of the United States, residing at East St. Louis, Illinois, have invented a certain new and useful Improvement in Boiler-Cleaning Compositions, of which the following is a full, clear, and exact description, such as will enable others skilled in the art to which it appertains, to make and use the same.
This invention relates to substances that are used for removing scale from boilers,
and has for its main object to provide a' new composition of matter that will effectively remove boiler scale and also prevent scale from forming in the boiler without danger of injuring the boiler.
The boiler compounds or compositions that are now used for removing scale from boilers contemplate the removal of the scale by decomposing the insoluble scale-forming salts into soluble compounds. Such compositions are composed principally of strong solvents, and while they succeed in removing the scale, they usually injure and frequently ruin the boiler in which they are used, by reason of the solvents attacking the iron from which the boiler is formed.
My improved composition difiers from the compositions that have heretofore been used for cleaning boilers in that it contains a substance that will disintegrate the scale without having any injurious effect on the iron of the boiler. It is also distinguished from prior boiler-cleaning compounds because it destroys the adhesive properties in the scale-forming salts in the water in the boiler and prevents said salts from combining or forming a scale when they are precipitated.
Briefly described, my improved boilercleaning composition consists of a saturated solution of naphthalene in hydrocarbon oil. Any suitable hydrocarbon oil may be used, but I prefer to use an oil of low specific gravity. Gasolene or naphtha may be used successfully, but I have obtained the best results from hydrocarbon oil of the benzin series, namely, toluene or Xylene, In pro- Specification of Letters Patent.
Application filed July 19, 1915.
Patented May 16, 1916.
Serial No. 40,650.
ducing the composition I simply dissolve naphthalene in hydrocarbon oil so as to form a saturated solution, and in using the composition I simply introduce it into the boiler with the feed water that is supplied to the boiler. If the inside of the boiler is dirty or coated with scale, the composition attacks the scale and disintegrates it or breaks it up into line particles by the chemical reaction of the naphthalene on the substances in the scale, which cause the particles of the scale to adhere to each other and to the iron of the boiler, the hydrocarbon oil on account of its capillary affinity penetrating into the interstices of the scale, and thus causing the naphthalene to be thoroughly distributed through the scale. In other words, the composition breaks up the scale by destroying the adhesion between the particles of scale-forming salts and between saidparticles and the surface of the boiler on which they'are deposited. In addition to breaking up the scale, my improved composition causes the scale-forming salts in the water in the boiler to become so thoroughly saturated or coated with the naphthalene that the salts will not combine and form a scale when they are precipitated.
A boiler-cleaning composition of the character above described has no injurious effect whatever on the boiler in which it is used, owing to the fact that it does not contain a strong solvent or ingredient that is injurious to iron. It merely consists of naphthalene and another ingredient that acts as a vehicle to carry the naphthalene into the pores of the scale and also to disseminate, or thoroughly distribute, the naphthalene through the feed water that carries the composition into the boiler.
Having thus described my invention, what I claim, and desire to secure by Letters Patent, is:
1. A boiler-cleaning composition composed of naphthalene and a substance of great capillary affinity.
2. A boiler-cleaning composition consisting of a saturated solution of naphthalene in hydrocarbon oil.
8. A boiler-cleaning composition consistsignature in the presence of two Witnesses, ing of naphthalene and hydrocarbon oil of this sixteenth day of July, 1915. low specific gravity.
4. A boiler-cleaning composition consistc GEORGE WALLACE 5 ing of naphthalene and a hydrocarbon oil VVi'tnesses:
of the benzin series. WELLS L. CHURCH, In testimony whereof I hereunto afiix my GEORGE BAKEWELL.
Copies of 1:111: patent my be obtained for five cents. each; by witnessing the Connisdoner of Patents, Washington, D. 0.
US4065015A 1915-07-19 1915-07-19 Boiler-cleaning composition. Expired - Lifetime US1182947A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US4065015A US1182947A (en) 1915-07-19 1915-07-19 Boiler-cleaning composition.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US4065015A US1182947A (en) 1915-07-19 1915-07-19 Boiler-cleaning composition.

Publications (1)

Publication Number Publication Date
US1182947A true US1182947A (en) 1916-05-16

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Family Applications (1)

Application Number Title Priority Date Filing Date
US4065015A Expired - Lifetime US1182947A (en) 1915-07-19 1915-07-19 Boiler-cleaning composition.

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Country Link
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