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TWM466783U - Temperable mono-silver low emissivity coated glass - Google Patents

Temperable mono-silver low emissivity coated glass Download PDF

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Publication number
TWM466783U
TWM466783U TW102214898U TW102214898U TWM466783U TW M466783 U TWM466783 U TW M466783U TW 102214898 U TW102214898 U TW 102214898U TW 102214898 U TW102214898 U TW 102214898U TW M466783 U TWM466783 U TW M466783U
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Taiwan
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layer
silver
glass
barrier layer
functional
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TW102214898U
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Chinese (zh)
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Jia-Hong Lin
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Taiwan Glass Industry Corp
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Priority to TW102214898U priority Critical patent/TWM466783U/en
Publication of TWM466783U publication Critical patent/TWM466783U/en

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Description

可鋼單銀低輻射鍍膜玻璃Steel single silver low-emission coated glass

本創作涉及玻璃深加工領域,具體涉及一種可鋼單銀低輻射鍍膜玻璃。The present invention relates to the field of glass deep processing, and specifically relates to a steel single silver low-emission coated glass.

隨著現代建築對裝飾材料要求的提高,人們對作為建築材料之一的玻璃的要求也越來越高。玻璃是建築物和汽車不可缺少的組成部分,承擔著許多重要的功能,包括美化建築物和汽車的外觀、採光及給室內帶來開闊的視野。但是普通玻璃陽光透過率很高、紅外反射率很低,大部分太陽光透過玻璃進入室內,而導致室內溫度上昇;反之,當戶外溫度較低時,室內的能量又會以輻射形式通過玻璃散失。據統計,建築物中通過門窗散失的熱量約占整個建築採暖或製冷能耗的50%,而通過玻璃流失的熱量就占整個窗戶的80%左右。With the increasing demand for decorative materials in modern buildings, the demand for glass as one of the building materials is increasing. Glass is an integral part of buildings and cars, and it carries many important functions, including beautifying the appearance of buildings and cars, lighting, and giving the interior an open view. However, ordinary glass has a high transmittance of sunlight and a low infrared reflectivity. Most of the sunlight enters the room through the glass, which causes the room temperature to rise. Conversely, when the outdoor temperature is low, the energy in the room is dissipated through the glass in the form of radiation. . According to statistics, the heat lost through doors and windows in buildings accounts for about 50% of the heating or cooling energy consumption of the entire building, while the heat lost through the glass accounts for about 80% of the entire window.

目前市場上出現了鍍上低輻射膜的玻璃,其隔熱性大大改善,尤其是目前市場上普遍採用的單銀低輻射玻璃,是將太陽光中的紅外線排除在外同時將物體二次輻射熱反射回去的特種玻璃,越來越受到人們的歡迎。但現有單銀低輻射玻璃在使用過程中,由於單銀低輻射玻璃中內層的含銀功能層容易被氧化,而其氧化會使該膜系喪失低輻射功能,使其與普通玻璃一樣不具備隔熱性能;而且該玻璃上單銀低輻射膜系其粘附力低,在高溫情況下,容易造成脫膜的現象,因而,現有單銀低輻射玻璃有 待進一步的改進。At present, there is a glass coated with a low-emission film on the market, and its heat insulation is greatly improved. Especially, the single-silver low-radiation glass currently used in the market is to exclude the infrared rays in the sunlight and to reflect the secondary radiant heat of the object. The special glass that went back is getting more and more popular. However, in the existing single silver low-emissivity glass, the silver-containing functional layer in the inner layer of the single-silver low-emissivity glass is easily oxidized, and its oxidation causes the film system to lose the low-radiation function, so that it is not like ordinary glass. It has thermal insulation performance; and the single-silver low-emission film on the glass has low adhesion, and it is easy to cause film release under high temperature conditions. Therefore, the existing single-silver low-emission glass has To be further improved.

由以上說明可知,習知單銀低輻射鍍膜玻璃具有容易造成脫 膜之問題,故,如何提供一種抗氧化、高粘附力以及可鋼化的可鋼單銀低輻射鍍膜玻璃,以加強機械性能保護,提高耐加工性能,避免了膜層的脫落,即成為本創作所欲解決之一重要課題。It can be seen from the above description that the conventional single silver low-emission coated glass has a tendency to cause off The problem of the film, therefore, how to provide an anti-oxidation, high adhesion and temperable steel single-silver low-emission coated glass to enhance the mechanical properties protection, improve the processing resistance, avoid the falling off of the film, that is, become This creative work is to solve one of the important issues.

針對習知技術存在的前述問題,創作人憑藉從事此行業多年 的經驗,積極研究改良,終於開發設計出本創作之可鋼單銀低輻射鍍膜玻璃。For the aforementioned problems in the prior art, the creators have been engaged in this industry for many years. The experience, active research and improvement, finally developed and designed the steel single silver low-emission coated glass.

本創作之一目的,係提供一種可鋼單銀低輻射鍍膜玻璃,該 可鋼單銀低輻射鍍膜玻璃包括一玻璃基底及沉積在該玻璃基底上之一功能膜系,該功能膜系包括縱向迭置在該玻璃基底上之一第一阻擋層、一第一電介質層、一第二阻擋層、一功能銀層、一第三阻擋層及一第二電介質層。 此外,可選地,該第一阻擋層、第二阻擋層及第三阻擋層均為鎳鉻(NiCr)薄膜;可選地,該功能銀層為摻雜銀層或銀單質;可選地,所述摻雜銀層為摻鎳的銀層;可選地,該第一電介質層和及第二電介質層均採用的是氮化矽(Si3 N4 )。如此,本創作藉由設置該第一阻擋層,有效地避免了玻璃中的鈉離子(Na+ )擴散,減小了其對膜系的影響;此外,藉由在該功能膜系中設置該第二阻擋層及第三阻擋層,有效地改善了該功能膜系的抗氧化性能和耐加工性能,並藉由設置該第一電介質層及第二電介質層,加強了該功能膜系的機械性能保護,進而使該可鋼單銀低輻射鍍膜玻璃具有低輻射、可鋼化的優點,值得推廣使用。One object of the present invention is to provide a steel single silver low-emission coated glass comprising a glass substrate and a functional film system deposited on the glass substrate, the functional film system comprising a longitudinal direction A first barrier layer, a first dielectric layer, a second barrier layer, a functional silver layer, a third barrier layer and a second dielectric layer are stacked on the glass substrate. In addition, optionally, the first barrier layer, the second barrier layer and the third barrier layer are all nickel-chromium (NiCr) films; optionally, the functional silver layer is doped silver layer or silver element; The doped silver layer is a nickel-doped silver layer; optionally, both the first dielectric layer and the second dielectric layer are tantalum nitride (Si 3 N 4 ). Thus, by providing the first barrier layer, the present invention effectively avoids diffusion of sodium ions (Na + ) in the glass and reduces its influence on the film system; further, by providing the functional film system The second barrier layer and the third barrier layer effectively improve the oxidation resistance and the process resistance of the functional film system, and the mechanical mechanism of the functional film system is strengthened by providing the first dielectric layer and the second dielectric layer The performance protection, in turn, makes the steel single silver low-emission coated glass have the advantages of low radiation and temperability, and is worthy of popularization.

為便 貴審查委員能對本創作目的、技術特徵及其功效,做更進一步之認識與瞭解,茲舉實施例配合圖式,詳細說明如下:For the sake of your review, you can make a further understanding and understanding of the purpose, technical features and efficacy of this creation. The examples are shown in the following diagram:

〔本創作〕[this creation]

1‧‧‧玻璃基底1‧‧‧glass substrate

2‧‧‧功能膜系2‧‧‧Functional membrane system

21‧‧‧第一阻擋層21‧‧‧First barrier

22‧‧‧第一電介質層22‧‧‧First dielectric layer

23‧‧‧第二阻擋層23‧‧‧ second barrier

24‧‧‧功能銀層24‧‧‧ functional silver layer

25‧‧‧第三阻擋層25‧‧‧ third barrier

26‧‧‧第二電介質層26‧‧‧Second dielectric layer

第1圖所示為本創作之可鋼單銀低輻射鍍膜玻璃結構示意圖。Figure 1 shows the schematic diagram of the structure of the single-silver low-emission coated glass of the steel.

為了闡明本創作的技術方案及技術目的,以下結合附圖及具體實施方式對本創作做進一步的介紹。In order to clarify the technical solutions and technical purposes of the present creation, the present invention will be further described below in conjunction with the drawings and specific embodiments.

請參閱第1圖所示,係本創作之可鋼單銀低輻射鍍膜玻璃的結構示意圖。該可鋼單銀低輻射鍍膜玻璃,包括玻璃基底1和沉積在該玻璃基底1上之一功能膜系2。該功能膜系2進一步包括縱向迭置在該玻璃基底1上之一第一阻擋層21、一第一電介質層22、一第二阻擋層23、一功能銀層24、一第三阻擋層25及一第二電介質層26。Please refer to the first figure, which is a schematic diagram of the structure of the steel single-silver low-emission coated glass. The steel single silver low-emission coated glass comprises a glass substrate 1 and a functional film system 2 deposited on the glass substrate 1. The functional film system 2 further includes a first barrier layer 21, a first dielectric layer 22, a second barrier layer 23, a functional silver layer 24, and a third barrier layer 25 stacked longitudinally on the glass substrate 1. And a second dielectric layer 26.

本創作藉由在該玻璃基底1上設置該第一阻擋層21,可有效地避免該玻璃基底1中的鈉離子擴散,減小了其對該功能膜系2的影響。此外,本創作藉由在該功能銀層24的上、下表面各沉積形成緻密之該第二阻擋層23及第三阻擋層25,避免了該功能銀層24的氧化,使其在加工預處理或高溫處理(如:鋼化、熱彎)時,其性能均不會受到影響,進而能避免了膜層的脫落,以令耐磨、抗氧化更好,且能夠可長期儲存。By providing the first barrier layer 21 on the glass substrate 1, the present invention can effectively prevent sodium ion diffusion in the glass substrate 1 and reduce its influence on the functional film system 2. In addition, the present invention avoids the oxidation of the functional silver layer 24 by forming a dense second barrier layer 23 and a third barrier layer 25 on each of the upper and lower surfaces of the functional silver layer 24. When treated or treated with high temperature (such as tempering or hot bending), its performance will not be affected, which can avoid the falling off of the film layer, so that the wear resistance and oxidation resistance are better, and it can be stored for a long time.

作為具體的實施方式,在本創作中,該第一阻擋層21、第二阻擋層23及第三阻擋層25均為鎳鉻薄膜。藉由將該鎳鉻薄膜分別設置在該功能銀層24之上下層,能有效的對該功能銀層24起到保護作用,避 免了該功能銀層24的氧化,延長存儲時間。本實施例通過該功能銀層24有效阻絕了紅外線,實現了該功能膜系2的低輻射率性能,並提高了隔熱和保溫的效果。As a specific embodiment, in the present creation, the first barrier layer 21, the second barrier layer 23, and the third barrier layer 25 are all nickel-chromium thin films. By disposing the nickel-chromium thin film on the lower layer of the functional silver layer 24, the functional silver layer 24 can be effectively protected from This function eliminates the oxidation of the silver layer 24 and prolongs the storage time. In this embodiment, the infrared layer 24 is effectively blocked by the function silver layer 24, the low emissivity performance of the functional film system 2 is achieved, and the effects of heat insulation and heat preservation are improved.

非限制性的列舉,本實用新型中,該功能銀層24為摻雜銀 層或銀單質作為優先方案,本實施例的摻雜銀層為摻鎳的銀層,其中,通過鎳的摻入可提高膜層粘附力,使其在具備低輻射、隔熱、保溫性能特徵的同時,抗氧化性更強。In a non-limiting list, in the present invention, the functional silver layer 24 is doped with silver. As a preferred solution, the silver-doped layer of the present embodiment is a nickel-doped silver layer, wherein the adhesion of the film can be improved by the incorporation of nickel, so that it has low radiation, heat insulation and thermal insulation properties. At the same time, the oxidation resistance is stronger.

此外,本實施例中,該第一電介質層22和第二電介質層26 均為氮化矽薄膜,利於提高該功能膜系2的機械性能,並通過該第一阻擋層21、第二阻擋層23及第三阻擋層25有效改善了該功能膜系2的抗氧化以及耐加工性能。該第二電介質層26位於該功能膜系2的頂層,使其在加工預處理或高溫處理(如:鋼化、熱彎)時,其性能均不會受到影響,進而能避免了膜層的脫落,並具有低輻射、可鋼化的優點,採用高溫鋼化不會對該功能膜系2造成影響。In addition, in this embodiment, the first dielectric layer 22 and the second dielectric layer 26 All of the tantalum nitride films are beneficial to improve the mechanical properties of the functional film system 2, and the oxidation resistance of the functional film system 2 is effectively improved by the first barrier layer 21, the second barrier layer 23 and the third barrier layer 25. Resistance to processing. The second dielectric layer 26 is located on the top layer of the functional film system 2, so that its performance is not affected during processing pretreatment or high temperature treatment (such as tempering, hot bending), thereby avoiding the film layer. It has the advantages of low radiation and tempering, and high temperature tempering does not affect the functional film system 2.

本實施例在生產時所採用的工藝為真空磁控濺射鍍膜,該可鋼單銀低輻射鍍膜玻璃的製造方法,包括:執行步驟S1:提供該玻璃基底1,並清洗、乾燥;該玻璃基底1包括但不限於單片浮法玻璃;及執行步驟S2:通過磁控濺射方法,在該玻璃基底1上依次沉積形成該第一阻擋層21、第一電介質層22、第二阻擋層23、功能銀層24、第三阻擋層25及第二電介質層26。The process used in the production of the present invention is a vacuum magnetron sputtering coating method, and the method for manufacturing the steel single-silver low-emission coated glass comprises: performing step S1: providing the glass substrate 1 and washing and drying; the glass The substrate 1 includes, but is not limited to, a single piece of float glass; and step S2 is performed: the first barrier layer 21, the first dielectric layer 22, and the second barrier layer are sequentially deposited on the glass substrate 1 by a magnetron sputtering method. 23. Functional silver layer 24, third barrier layer 25 and second dielectric layer 26.

可選地,該可鋼單銀低輻射鍍膜玻璃進一步包括: 執行步驟S3:在該功能膜系2上沉積形成類金剛石保護薄膜,或者採用噴粉處理並用PE布密封包裝保護。Optionally, the slab single silver low-emission coated glass further comprises: Step S3 is performed: depositing a diamond-like protective film on the functional film system 2, or using a dusting treatment and sealing with a PE cloth.

基於上述,本創作藉由設置該第一阻擋層21,避免該玻璃 基底1中的鈉離子擴散;藉由在該功能銀層24的上下表面分別形成緻密之該第二阻擋層23及第三阻擋層25,避免該功能銀層24的氧化,使其在加工預處理或高溫處理(如:鋼化、熱彎)時,其性能均不會受到影響,進而能避免了膜層的脫落,耐磨、抗氧化更好,可長期儲存。該膜系具有機械加工性能好、可鋼化、抗氧化性能好、高粘附力、低輻射率的優點,值得推廣使用。Based on the above, the present invention avoids the glass by providing the first barrier layer 21 The sodium ions in the substrate 1 are diffused; by forming the dense second barrier layer 23 and the third barrier layer 25 on the upper and lower surfaces of the functional silver layer 24, the oxidation of the functional silver layer 24 is prevented from being processed. When treated or high temperature treatment (such as tempering and hot bending), its performance will not be affected, thereby avoiding the falling off of the film layer, better wear resistance and oxidation resistance, and long-term storage. The film system has the advantages of good mechanical processing property, temperability, good oxidation resistance, high adhesion, and low emissivity, and is worthy of popularization.

按,以上所述,僅係本創作之若干較佳實施例,惟,本創作 所主張之權利範圍,並不侷限於此,按凡熟悉該項技藝之人士,依據本創作所揭露之技術內容,可輕易思及之等效變化,均應屬不脫離本創作之保護範疇。According to the above, it is only a few preferred embodiments of the present creation, but this creation The scope of the claimed rights is not limited to this. Anyone who is familiar with the art, based on the technical content disclosed in this creation, can easily think of the equivalent changes, and should not fall within the protection scope of this creation.

1‧‧‧玻璃基底1‧‧‧glass substrate

2‧‧‧功能膜系2‧‧‧Functional membrane system

21‧‧‧第一阻擋層21‧‧‧First barrier

22‧‧‧第一電介質層22‧‧‧First dielectric layer

23‧‧‧第二阻擋層23‧‧‧ second barrier

24‧‧‧功能銀層24‧‧‧ functional silver layer

25‧‧‧第三阻擋層25‧‧‧ third barrier

26‧‧‧第二電介質層26‧‧‧Second dielectric layer

Claims (5)

一種可鋼單銀低輻射鍍膜玻璃,包括:一玻璃基底;及一功能膜系,係沉積在該玻璃基底上,該功能膜系包括縱向迭置沉積在該玻璃基底上之一第一阻擋層、一第一電介質層、一第二阻擋層、一功能銀層、一第三阻擋層及一第二電介質層。A steel single silver low-emission coated glass comprising: a glass substrate; and a functional film system deposited on the glass substrate, the functional film comprising a first barrier layer deposited longitudinally on the glass substrate a first dielectric layer, a second barrier layer, a functional silver layer, a third barrier layer, and a second dielectric layer. 如請求項1所述的鍍膜玻璃,其中該第一阻擋層、第二阻擋層、第三阻擋層均係鎳鉻薄膜。The coated glass of claim 1, wherein the first barrier layer, the second barrier layer, and the third barrier layer are each a nickel chromium film. 如請求項1所述的鍍膜玻璃,其中該功能銀層係摻雜銀層或銀單質。The coated glass of claim 1, wherein the functional silver layer is doped with a silver layer or a silver element. 如請求項3所述的鍍膜玻璃,其中所述摻雜銀層係摻鎳的銀層。The coated glass of claim 3, wherein the doped silver layer is a silver-doped silver layer. 如請求項1所述的鍍膜玻璃,其中該第一電介質層及第二電介質層均係採用氮化矽。The coated glass of claim 1, wherein the first dielectric layer and the second dielectric layer are both tantalum nitride.
TW102214898U 2013-08-08 2013-08-08 Temperable mono-silver low emissivity coated glass TWM466783U (en)

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