TWI863594B - Cement mortar composition and use thereof - Google Patents
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- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
Description
本發明係關於一種水泥砂漿組合物,特別是一種可做為隔音材料之砂漿組成物。The present invention relates to a cement mortar composition, in particular to a mortar composition which can be used as a sound insulation material.
目前都市地區因人口密集及土地資源日愈短缺,住宅大都採用高樓層及密集之方式為主,然而,在高樓層及密集式建築方式下,各樓層樓板間常有碰撞、摩擦所產生之噪音。為了提高居住品質,建築物隔音性能之需求與日俱增,甚至對於衝擊音降噪性能規定亦明確納入建築法令規章中,因此,集合住宅分戶樓板之隔音問題一直是業界努力改良的課題。At present, due to the dense population and increasing shortage of land resources in urban areas, most of the residential buildings are high-rise and densely packed. However, in high-rise and densely packed buildings, there is often noise generated by collision and friction between the floors. In order to improve the quality of living, the demand for building sound insulation performance is increasing day by day, and even the regulations on impact sound reduction performance are clearly included in the building laws and regulations. Therefore, the sound insulation problem of the individual floors of collective housing has always been a topic that the industry has been working hard to improve.
目前習知增強建築隔音的作法是於分戶樓板配置一橡膠材質的隔音層(或稱隔音墊),該隔音層係藉由黏著劑層設置於鋼筋混凝土構造(RC樓板)之水泥層上,再於該隔音層上依序鋪設一防水隔離層以及一層水泥砂漿層(約5公分之水泥壓層),之後再於最上一層黏貼例如磁磚之表面飾材,藉此種多層結構以達樓板的隔音效果。The current common practice of enhancing building sound insulation is to configure a rubber sound insulation layer (or sound insulation pad) on the sub-floor. The sound insulation layer is set on the cement layer of the reinforced concrete structure (RC floor) through an adhesive layer, and then a waterproof isolation layer and a cement mortar layer (about 5 cm cement pressure layer) are laid on the sound insulation layer in sequence. Then, surface decoration materials such as tiles are glued on the top layer. This multi-layer structure is used to achieve the sound insulation effect of the floor.
然而,通過此種習知施作方式工序繁雜,其至少涉及四道施工程序(即分別施加黏著劑、橡膠層、隔離層及水泥壓層等),且通常需要兩週以上之工程天數,費工費時,導致成本高昂。另外,橡膠隔音墊與其上層之水泥砂漿層之間亦有牢固度不佳之嫌,造成表面飾材有破裂、突起、空心或下塌之風險。However, this conventional method is complicated and involves at least four construction procedures (i.e., applying adhesive, rubber layer, isolation layer and cement pressure layer, etc.), and usually takes more than two weeks of construction time, which is labor-intensive and time-consuming, resulting in high costs. In addition, the strength between the rubber sound insulation pad and the cement mortar layer above it is also suspected to be poor, resulting in the risk of cracking, protrusions, hollowness or collapse of the surface decoration material.
因此,業界仍需要一種建築隔音材料,除了具有良好隔音效果外,其施工操作容易,可降低複雜的工序步驟,縮短工程時間,達成省時省力、節省成本之效果。另外,業界亦希望發展出一種隔音材料,其設置在RC樓板及表面飾材之間可提供良好的牢固度與接著性。Therefore, the industry still needs a building sound insulation material that, in addition to having good sound insulation effects, is easy to construct and operate, can reduce complex process steps, shorten construction time, and achieve the effect of saving time, labor, and cost. In addition, the industry also hopes to develop a sound insulation material that can provide good firmness and adhesion when placed between RC floor slabs and surface decorative materials.
有鑑於此,本申請即是針對前述多種技術問題所為之研發成果。In view of this, this application is the research and development result for the aforementioned various technical problems.
在一個方面中,本發明提供一種水泥砂漿組合物,其包含:(a)第一橡膠粒子,其具有在0.01 mm至小於1.2 mm範圍內之粒徑;(b)第二橡膠粒子,其具有在1.2 mm至 6mm範圍內之粒徑;(c)水性空心樹脂;(d)水泥;及(e)砂。In one aspect, the present invention provides a cement mortar composition comprising: (a) first rubber particles having a particle size in the range of 0.01 mm to less than 1.2 mm; (b) second rubber particles having a particle size in the range of 1.2 mm to 6 mm; (c) water-based hollow resin; (d) cement; and (e) sand.
在另一方面中,本發明提供一種上述水泥砂漿組合物之用途,其用於形成建築物之隔音結構。In another aspect, the present invention provides a use of the cement mortar composition for forming a sound insulation structure of a building.
在另一方面中,本發明提供一種隔音結構,其包含使用本發明提供之水泥砂漿組合物所製備。In another aspect, the present invention provides a sound insulation structure, which is prepared using the cement mortar composition provided by the present invention.
在另一方面,本發明提供一種水泥砂漿添加劑組合物,In another aspect, the present invention provides a cement mortar additive composition,
本文所揭示之本發明之每個態樣或每個實施例意欲與所有其他所揭示之本發明態樣或實施例個別地組合或一同組合成其所有可能的組合。Each aspect or embodiment of the invention disclosed herein is intended to be combined with all other disclosed aspects or embodiments of the invention, individually or together in all possible combinations thereof.
在本說明書及申請專利範圍中,除非上下文另外明確規定,否則單數形式「一」及「該」包括複數。除非另外主張,否則使用本文所提供之任何及所有實例或例示性語言(例如「諸如」)僅欲更好地說明本發明,而不對本發明之範疇形成限制。本說明書中之語言不應解釋為指示任何未主張之要素為實施本發明所必需。In this specification and the scope of the patent application, unless the context clearly requires otherwise, the singular forms "a", "an" and "the" include plural forms. Unless otherwise claimed, the use of any and all examples or exemplary language (such as "such as") provided herein is only intended to better illustrate the present invention and does not limit the scope of the present invention. The language in this specification should not be interpreted as indicating that any non-claimed element is essential to the implementation of the present invention.
除非在下文中另有定義,本文中所用的所有技術術語和科學術語的含義意圖與本領域技術人員通常所理解的相同。提及本文中使用的技術意圖指在本領域中通常所理解的技術,包括那些對本領域技術人員顯而易見的技術的變化或等效技術的替換。雖然相信以下術語對於本領域技術人員很好理解,但仍然闡述以下定義以更好地解釋本發明。Unless otherwise defined below, the meanings and intentions of all technical terms and scientific terms used herein are the same as those commonly understood by those skilled in the art. Reference to the technical intentions used herein refers to the technology commonly understood in the art, including those changes in technology or replacements of equivalent technology that are obvious to those skilled in the art. Although it is believed that the following terms are well understood by those skilled in the art, the following definitions are still set forth to better explain the present invention.
如本文中所使用的術語「包括」、「包含」、「具有」、「含有」或「涉及」及其在本文中的其它變體形式為包含性的(inclusive)或開放式的,且不排除其它未列舉的項目。As used herein, the terms "include", "comprising", "having", "containing" or "involving" and other variations thereof herein are inclusive or open-ended and do not exclude other unlisted items.
在本說明書及申請專利範圍中的「固形分」或「固含量」,是指材料中非揮發成分佔總量之質量百分比,亦即不揮發份之含量。在本說明書及申請專利範圍中的「固形重(量)」,是指材料中非揮發成分之重量。"Solid matter" or "solid content" in this specification and patent application refers to the mass percentage of non-volatile components in the material, that is, the content of non-volatile components. "Solid weight (amount)" in this specification and patent application refers to the weight of non-volatile components in the material.
本發明提供一種水泥砂漿組合物,其包含: (a)第一橡膠粒子,其具有在約0.01 mm至小於1.2 mm範圍內之粒徑; (b)第二橡膠粒子,其具有在1.2 mm至約6 mm範圍內之粒徑; (c)水性空心樹脂; (d)水泥;及 (e)砂。 The present invention provides a cement mortar composition comprising: (a) first rubber particles having a particle size in the range of about 0.01 mm to less than 1.2 mm; (b) second rubber particles having a particle size in the range of 1.2 mm to about 6 mm; (c) water-based hollow resin; (d) cement; and (e) sand.
橡膠粒子具有優異的阻尼性能,可以降低樓板遭受撞擊的衝擊力,降低衝擊音。本案發明人發現在本發明組合物中添加至少兩種不同粒徑範圍之橡膠粒子,可形成幾何形式之堆疊,增加許多孔隙的空間,可增加其所形成之水泥砂漿層結構的孔隙度,有效降低聲音的傳導,進一步增加隔音效果。Rubber particles have excellent damping properties, which can reduce the impact force of the floor slab and reduce the impact sound. The inventor of this case found that adding at least two rubber particles of different particle size ranges to the composition of the present invention can form a geometric stack, increase the space of many pores, and increase the porosity of the cement mortar layer structure formed by it, effectively reducing the conduction of sound and further increasing the sound insulation effect.
所述第一橡膠粒子較佳具有約0.03 mm至約1.0 mm範圍內之粒徑,更佳具有約0.05 mm至約0.8 mm範圍內之粒徑。The first rubber particles preferably have a particle size in the range of about 0.03 mm to about 1.0 mm, and more preferably have a particle size in the range of about 0.05 mm to about 0.8 mm.
在一些實施例中,所述第一橡膠粒子之材料包含苯乙烯丁二烯橡膠、丁基橡膠、丁晴橡膠、丙烯酸酯橡膠、丁二炔橡膠、氯丁二烯橡膠、氟橡膠、天然橡膠、聚氨酯橡膠、矽氧橡膠或上述之組合。在較佳實施例中,所述第一橡膠粒子之材料包含苯乙烯丁二烯橡膠。In some embodiments, the material of the first rubber particles includes styrene butadiene rubber, butyl rubber, nitrile rubber, acrylic rubber, diacetylene rubber, chloroprene rubber, fluororubber, natural rubber, polyurethane rubber, silicone rubber or a combination thereof. In a preferred embodiment, the material of the first rubber particles includes styrene butadiene rubber.
所述第二橡膠粒子較佳具有1.5 mm至5 mm範圍內之粒徑,更佳具有1.8 mm至4 mm範圍內之粒徑。The second rubber particles preferably have a particle size in the range of 1.5 mm to 5 mm, and more preferably have a particle size in the range of 1.8 mm to 4 mm.
在一些實施例中,所述第二橡膠粒子之材料包含苯乙烯丁二烯橡膠、丁基橡膠、丁晴橡膠、丙烯酸酯橡膠、丁二炔橡膠、氯丁二烯橡膠、氟橡膠、天然橡膠、聚氨酯橡膠、矽氧橡膠或上述之組合。在較佳實施例中,所述第二橡膠粒子之材料包含苯乙烯丁二烯橡膠。In some embodiments, the material of the second rubber particles includes styrene butadiene rubber, butyl rubber, nitrile rubber, acrylic rubber, diacetylene rubber, chloroprene rubber, fluororubber, natural rubber, polyurethane rubber, silicone rubber or a combination thereof. In a preferred embodiment, the material of the second rubber particles includes styrene butadiene rubber.
在一些實施例中,所述第一橡膠粒子及/或所述第二橡膠粒子可由輪胎回收所得之橡膠所製備,藉此可進一步增進環境保護、達成節能減碳之效果。In some embodiments, the first rubber particles and/or the second rubber particles can be prepared from rubber recycled from tires, thereby further improving environmental protection and achieving the effect of energy saving and carbon reduction.
在一些實施例中,以本發明組合物之總固形重量計,該等第一橡膠粒子之含量為1至30重量%,較佳為5至25重量%,更佳為12至20重量%。在一些實施例中,以本發明組合物之總固形重量計,該等第二橡膠粒子之含量為1至20重量%,較佳為3至15重量%,更佳為5至12重量%。In some embodiments, the content of the first rubber particles is 1 to 30% by weight, preferably 5 to 25% by weight, and more preferably 12 to 20% by weight, based on the total solid weight of the composition of the present invention. In some embodiments, the content of the second rubber particles is 1 to 20% by weight, preferably 3 to 15% by weight, and more preferably 5 to 12% by weight, based on the total solid weight of the composition of the present invention.
根據本發明之一些實施例,所述第一橡膠粒子與所述第二橡膠粒子的重量比為10:1~1:10,較佳為6:1~1:2,更佳為3:1~1:1。若第一橡膠粒子與第二橡膠粒子的重量比過低,所形成的水泥砂漿層結構強度會較低,若第一橡膠粒子與第二橡膠粒子的重量比過高,則會降低水泥砂漿層的隔音效果。According to some embodiments of the present invention, the weight ratio of the first rubber particles to the second rubber particles is 10:1 to 1:10, preferably 6:1 to 1:2, and more preferably 3:1 to 1:1. If the weight ratio of the first rubber particles to the second rubber particles is too low, the structural strength of the cement mortar layer formed will be low, and if the weight ratio of the first rubber particles to the second rubber particles is too high, the sound insulation effect of the cement mortar layer will be reduced.
所述水性空心樹脂係指具有空心結構之樹脂材料,較佳為具有球形的結構,該樹脂材料可分散於水中。在一些實施例中,該水性空心樹脂之粒徑為約300至600 nm,較佳為400至500 nm。所述水性空心樹脂本身之固形分為約20%至約40%。所述水性空心樹脂之空心度為約30至約50%(空心度係指空心區域體積佔整個粒子體積之百分比)。The water-based hollow resin refers to a resin material with a hollow structure, preferably a spherical structure, and the resin material can be dispersed in water. In some embodiments, the particle size of the water-based hollow resin is about 300 to 600 nm, preferably 400 to 500 nm. The solid content of the water-based hollow resin itself is about 20% to about 40%. The hollowness of the water-based hollow resin is about 30 to about 50% (hollowness refers to the percentage of the volume of the hollow area to the total volume of the particle).
在一些實施例中,該水性空心樹脂可為水性空心丙烯酸樹脂、水性空心苯乙烯樹脂、水性空心聚氨酯樹脂、水性空心環氧樹脂、水性空心聚脂樹脂或上述之組合。在本發明一些實施例中,所述水性空心樹脂包含水性空心丙烯酸樹脂。In some embodiments, the water-based hollow resin can be a water-based hollow acrylic resin, a water-based hollow styrene resin, a water-based hollow polyurethane resin, a water-based hollow epoxy resin, a water-based hollow polyester resin or a combination thereof. In some embodiments of the present invention, the water-based hollow resin comprises a water-based hollow acrylic resin.
所述水性空心樹脂可以進一步提供更多的孔隙度,降低聲音的傳導,且水性空心樹脂球形的結構可以改變聲音的傳導方向,將音波散射,降低音量達到隔音效果。在一些實施例中,以本發明組合物之總固形重量計,該水性空心樹脂之固含量為0.1至5重量%,較佳為1至3重量%。The water-based hollow resin can further provide more porosity, reduce the conduction of sound, and the spherical structure of the water-based hollow resin can change the conduction direction of sound, scatter sound waves, reduce the volume and achieve a sound insulation effect. In some embodiments, the solid content of the water-based hollow resin is 0.1 to 5% by weight, preferably 1 to 3% by weight, based on the total solid weight of the composition of the present invention.
本發明組合物所使用之水泥和砂並無特殊限制,習知一般建築材料所採用之水泥及砂即可做為本發明組合物之成分。There is no particular limitation on the cement and sand used in the composition of the present invention. Cement and sand commonly used in building materials can be used as components of the composition of the present invention.
在一些實施例中,以本發明組合物之總固形重量計,所述水泥之固含量為約10至約30重量%,較佳為約15至20重量%。In some embodiments, the solid content of the cement is about 10 to about 30 wt %, preferably about 15 to 20 wt %, based on the total solid weight of the composition of the present invention.
在一些實施例中,以本發明組合物之總固形重量計,所述砂之固含量為約30至約70重量%,較佳為約40至50重量%。為使組合物具有更佳的混合均勻性及接著性,在本發明之一些實施態樣,本發明之水泥砂漿組合物可進一步包含(f)水性丙烯酸樹脂。所述水性丙烯酸樹脂含水份但並不具有空心結構。在一些實施例中,該水性丙烯酸樹脂具有小於0°C的玻璃轉換溫度(Tg)。In some embodiments, the solid content of the sand is about 30 to about 70% by weight, preferably about 40 to 50% by weight, based on the total solid weight of the composition of the present invention. In order to make the composition have better mixing uniformity and adhesion, in some embodiments of the present invention, the cement mortar composition of the present invention may further include (f) a water-based acrylic resin. The water-based acrylic resin contains water but does not have a hollow structure. In some embodiments, the water-based acrylic resin has a glass transition temperature (Tg) of less than 0°C.
在一些實施例中,以本發明組合物之總固形重量計,該水性丙烯酸樹脂之固含量為0.1至15重量%,較佳為1至10重量%。在一些實施例中,該水性丙烯酸樹脂本身之固形分為約40%至約60%。In some embodiments, the solid content of the waterborne acrylic resin is 0.1 to 15% by weight, preferably 1 to 10% by weight, based on the total solid weight of the composition of the present invention. In some embodiments, the solid content of the waterborne acrylic resin itself is about 40% to about 60%.
在一些實施例中,所述水性丙烯酸樹脂之樹脂可衍生自甲基丙烯酸甲酯、丙烯酸甲酯、丙烯酸丁酯、丙烯酸2-乙基己酯、丙烯酸、甲基丙烯酸、苯乙烯之聚合物或兩者以上組合之共聚物。In some embodiments, the resin of the waterborne acrylic resin may be derived from a polymer of methyl methacrylate, methyl acrylate, butyl acrylate, 2-ethylhexyl acrylate, acrylic acid, methacrylic acid, styrene, or a copolymer of a combination of two or more thereof.
為進一步增加組合物的分散效果,根據本發明之一些實施態樣,本發明之水泥砂漿組合物進一步包含(g)界面活性劑。To further enhance the dispersing effect of the composition, according to some embodiments of the present invention, the cement mortar composition of the present invention further comprises (g) a surfactant.
在一些實施例中,所述界面活性劑包含離子型界面活性劑,諸如月桂醇硫酸酯鈉(Sodium lauryl sulfate, SLS)或十二烷基苯磺酸鈉(sodium dodecyl benzene sulfonate, SDBS);或非離子型界面活性劑,例如脂肪醇聚氧乙烯醚、烯丙基封端環氧乙烷(EO)和環氧丙烷(PO)之嵌段共聚物等。在一些實施例中,所述界面活性劑包含聚氧乙烯月桂醇醚。In some embodiments, the surfactant comprises an ionic surfactant, such as sodium lauryl sulfate (SLS) or sodium dodecyl benzene sulfonate (SDBS); or a non-ionic surfactant, such as fatty alcohol polyoxyethylene ether, allyl-terminated block copolymers of ethylene oxide (EO) and propylene oxide (PO), etc. In some embodiments, the surfactant comprises polyoxyethylene lauryl alcohol ether.
在一些實施例中,以本發明組合物之總固形重量計,該界面活性劑之固含量為0.1至5重量%,較佳為0.5至3重量%。In some embodiments, the solid content of the surfactant is 0.1 to 5 wt %, preferably 0.5 to 3 wt %, based on the total solid weight of the composition of the present invention.
本發明之水泥砂漿組合物可用做為建築材料,例如做為建築物樓板結構中的塗層、牆面結構中之塗層,或用以粉刷牆壁、黏貼磁磚、磚塊或修補混凝土裂縫等。The cement mortar composition of the present invention can be used as a building material, for example, as a coating in a building floor structure, a coating in a wall structure, or for painting walls, pasting tiles, bricks, or repairing concrete cracks.
本發明之水泥砂漿組合物透過兩種不同粒徑範圍之橡膠粒以及水性空心樹脂之選用搭配,可達到良好隔音效果,例如可降低15分貝或17分貝以上之衝擊音,甚至可降低20分貝、23分貝或25分貝以上之衝擊音;另外,此一搭配組合也可維持後續施工後水泥之強度及固著性。The cement mortar composition of the present invention can achieve good sound insulation effect by selecting and matching two rubber particles with different particle size ranges and water-based hollow resin. For example, it can reduce impact sound above 15 decibels or 17 decibels, and even reduce impact sound above 20 decibels, 23 decibels or 25 decibels. In addition, this combination can also maintain the strength and fixation of cement after subsequent construction.
當使用本發明之水泥砂漿組合物做為建築物樓板結構中的水泥塗層時,由於僅需該水泥塗層即可達成良好隔音效果,因此,相較於習知使用橡膠隔音墊之工法,使用本發明之水泥砂漿組合物做為隔音層可減少多道工序步驟,縮短工程時間,達成省時省力、節省成本之效果。另外,使用本發明之水泥砂漿組合物做為建築物之水泥塗層時,亦可具有優異的抗壓強度,且可在RC樓板及表面飾材之間提供良好的牢固度,避免表面飾材破裂、突起或下塌之風險。When the cement mortar composition of the present invention is used as a cement coating in the floor structure of a building, since only the cement coating is needed to achieve a good sound insulation effect, compared with the conventional method of using a rubber sound insulation pad, the use of the cement mortar composition of the present invention as a sound insulation layer can reduce multiple process steps, shorten the construction time, and achieve the effect of saving time, labor, and cost. In addition, when the cement mortar composition of the present invention is used as a cement coating of a building, it can also have excellent compressive strength, and can provide good firmness between the RC floor and the surface decoration material, avoiding the risk of cracking, protruding or collapsing of the surface decoration material.
因此,在另一方面中,本發明提供一種上述水泥砂漿組合物之用途,其用於形成建築物之隔音裝置。該隔音裝置具有良好的隔音效果,在形成厚度2至5公分之塗層時,即可降低15分貝或17分貝以上之衝擊音,甚至可降低20分貝、23分貝或25分貝以上之衝擊音。Therefore, in another aspect, the present invention provides a use of the cement mortar composition, which is used to form a sound insulation device for a building. The sound insulation device has a good sound insulation effect, and when a coating layer with a thickness of 2 to 5 cm is formed, the impact sound of 15 decibels or more than 17 decibels can be reduced, and even the impact sound of 20 decibels, 23 decibels or more than 25 decibels can be reduced.
在另一方面中,本發明提供一種隔音裝置,其包含使用本發明提供之水泥砂漿組合物所製備。In another aspect, the present invention provides a sound insulation device, which is prepared using the cement mortar composition provided by the present invention.
在又一方面中,本發明亦提供一種水泥砂漿添加劑組合物,其包含(i)水性空心樹脂、(ii)水性丙烯酸樹脂及(iii)界面活性劑,其中該水性空心樹脂、該水性丙烯酸樹脂及該界面活性劑之技術特徵如同前文所描述之(c)水性空心樹脂、(f)水性丙烯酸樹脂及(g)界面活性劑。In another aspect, the present invention also provides a cement mortar additive composition, which comprises (i) a water-based hollow resin, (ii) a water-based acrylic resin and (iii) a surfactant, wherein the technical features of the water-based hollow resin, the water-based acrylic resin and the surfactant are the same as those of the (c) water-based hollow resin, (f) water-based acrylic resin and (g) surfactant described above.
本發明之添加劑組合物係做為本發明之水泥砂漿組合物之添加劑,亦即,將該水泥砂漿添加劑組合物添加至含有前述(a)第一橡膠粒子、前述(b)第二橡膠粒子、(d)水泥及(e)砂之組合物時,可製備形成本發明之水泥砂漿組合物。The additive composition of the present invention is used as an additive for the cement mortar composition of the present invention. That is, when the cement mortar additive composition is added to a composition containing the aforementioned (a) first rubber particles, the aforementioned (b) second rubber particles, (d) cement and (e) sand, the cement mortar composition of the present invention can be prepared.
以下實施例係用於對本發明作進一步說明,唯非用以限制本發明之範圍。任何熟悉此項技藝之人士可輕易達成之修飾及改變均包括於本案說明書揭示內容及所附申請專利範圍之範圍內。 實施例 The following embodiments are used to further illustrate the present invention, but are not intended to limit the scope of the present invention. Any modifications and changes that can be easily achieved by anyone familiar with this technology are included in the scope of the disclosure of the description of this case and the scope of the attached patent application.
除非另有說明,以下實施例中使用的原料和試劑均為市售商品,或者可以通過已知方法製備。Unless otherwise specified, the raw materials and reagents used in the following examples are commercially available or can be prepared by known methods.
< 製備水性空心樹脂 > :以兩階段合成水性空心樹脂。首先將30重量份丙烯酸、60重量份丙烯酸甲酯、10重量份丙烯酸丁酯、2重量份烷基硫酸鈉乳化劑以及70重量份水一同混合以形成預乳化液1。將1重量份水性過硫酸鉀起始劑溶解於20重量份水,於約80℃將預乳化液1與過硫酸鉀溶液滴入反應釜中反應,滴入反應時間約60分鐘,經60分鐘之反應後,合成為第一段聚合物。將800重量份苯乙烯單體、4重量份烷基硫酸鈉以及600重量份水混合成預乳化液2,另將4重量份水性過硫酸鉀起始劑溶解於80重量份水,於約80℃,將預乳化液2、過硫酸鉀溶液分別一起滴入第一段聚合物中,滴入反應時間為120分鐘,經120分鐘反應以成第一段聚合物的外殼,再加入氨水調製為pH>8.0,進行中和,接著於90℃高溫澎脹,最後形成具有 300~1000 nm 粒徑且帶有空心結構之水性空心樹脂(其固形分約為30%)。使用前述反應物之比例以製備所需不同重量之水性空心樹脂。 < Preparation of water-based hollow resin > : The water-based hollow resin is synthesized in two stages. First, 30 parts by weight of acrylic acid, 60 parts by weight of methyl acrylate, 10 parts by weight of butyl acrylate, 2 parts by weight of sodium alkyl sulfate emulsifier and 70 parts by weight of water are mixed together to form a pre-emulsion 1. 1 part by weight of aqueous potassium persulfate initiator is dissolved in 20 parts by weight of water, and the pre-emulsion 1 and potassium persulfate solution are dripped into a reactor at about 80°C for reaction. The dripping reaction time is about 60 minutes. After 60 minutes of reaction, the first stage polymer is synthesized. 800 parts by weight of styrene monomer, 4 parts by weight of sodium alkyl sulfate and 600 parts by weight of water are mixed to form a pre-emulsion 2, and 4 parts by weight of aqueous potassium persulfate initiator are dissolved in 80 parts by weight of water. At about 80°C, the pre-emulsion 2 and potassium persulfate solution are dripped into the first stage polymer respectively. The dripping reaction time is 120 minutes. After 120 minutes of reaction, the shell of the first stage polymer is formed. Ammonia water is then added to adjust the pH to 8.0 for neutralization, and then the mixture is expanded at a high temperature of 90°C to finally form a water-based hollow resin with a particle size of 300-1000 nm and a hollow structure (the solid content is about 30%). The ratio of the above-mentioned reactants is used to prepare the required water-based hollow resin of different weights.
< 製備水性丙烯酸 > :利用乳液聚合法,將2重量份丙烯酸、50重量份丙烯酸甲酯、50重量份丙烯酸丁酯、60重量份水以及2重量份烷基硫酸鈉乳化劑混合攪拌,使其混合成預乳化液3。於約80℃,另將1重量份水性過硫酸鉀起始劑溶解於20重量份之80℃水,將預乳化液3、過硫酸鉀溶液於約80℃滴入反應釜中反應,滴入反應時間4小時後,反應形成水性丙烯酸樹脂,其固形分約為50%。使用前述反應物之比例以製備所需不同重量之水性丙烯酸樹脂。 < Preparation of water-based acrylic acid > : Using emulsion polymerization, 2 parts by weight of acrylic acid, 50 parts by weight of methyl acrylate, 50 parts by weight of butyl acrylate, 60 parts by weight of water and 2 parts by weight of sodium alkyl sulfate emulsifier are mixed and stirred to form a pre-emulsion 3. At about 80°C, 1 part by weight of aqueous potassium persulfate initiator is dissolved in 20 parts by weight of 80°C water, and the pre-emulsion 3 and potassium persulfate solution are dripped into a reactor at about 80°C for reaction. After the dripping reaction time is 4 hours, a water-based acrylic resin is formed by reaction, and its solid content is about 50%. The ratio of the above-mentioned reactants is used to prepare the required water-based acrylic resin of different weights.
< 水泥砂漿製備 >:將第一橡膠顆粒(0.25-0.6 mm粒徑,駿隆橡膠工業股份有限公司製)、第二橡膠顆粒(2-4 mm 粒徑,駿隆橡膠工業股份有限公司製)、砂子(乾拌水泥砂)、水泥(波特蘭水泥)及界面活性劑(聚氧乙烯月桂醇醚),依照表1-1至表1-3的用量(單位為公斤(kg))投入水泥砂漿攪拌機預混約5分鐘後,接著將水性空心樹脂、水性丙烯酸與水依照表1-1至表1-3的用量(單位為公斤(kg))加入前述之水泥砂漿攪拌機,攪拌15分鐘,得到各個實施例以及比較例之水泥砂漿組合物。 < Preparation of cement mortar > : The first rubber particles (0.25-0.6 mm particle size, manufactured by Junlong Rubber Industry Co., Ltd.), the second rubber particles (2-4 mm particle size, manufactured by Junlong Rubber Industry Co., Ltd.), sand (dry-mixed cement sand), cement (Portland cement) and surfactant (polyoxyethylene lauryl alcohol ether) were added to a cement mortar mixer according to the amounts (in kilograms (kg)) in Tables 1-1 to 1-3 and pre-mixed for about 5 minutes. Then, the water-based hollow resin, water-based acrylic acid and water were added to the aforementioned cement mortar mixer according to the amounts (in kilograms (kg)) in Tables 1-1 to 1-3 and stirred for 15 minutes to obtain the cement mortar compositions of each embodiment and comparative example.
表1-1
表1-2
表1-3
< 隔音樓板製作 > :於建築物2樓的樓層地板先組裝1.5m x 1.5m且厚度3公分的邊框模具,將實施例或比較例之水泥砂漿倒入該模具裡,漿料直接接觸該2樓樓層地板,使漿料自然乾燥硬化7天後,將模具邊框移去作為脫膜。 < Production of sound insulation floor > : A frame mold with a size of 1.5m x 1.5m and a thickness of 3cm is first assembled on the floor of the second floor of the building, and the cement mortar of the embodiment or the comparative example is poured into the mold. The mortar directly contacts the second floor floor. After the mortar is naturally dried and hardened for 7 days, the mold frame is removed for demolding.
< 音量分貝測試 > :於所述2樓樓層地板,硬化後砂漿層正上方高度1米,用一重量5公斤,體積約7 cm x 7 cm x 5 cm之鐵塊,重力自然掉落撞擊硬化的水泥砂漿層。於水泥砂漿層的正下方之1樓,擺置收音分貝計,分貝計離1樓地面高度1米,記錄2樓鐵塊撞擊砂漿層當下所產生的最大音量,共撞擊20次,音量分貝值採取這20次撞擊之平均值。建築物樓板高度約3.2米。測試結果如表2-1至表2-3所示。 < Volume decibel test > : On the second floor floor, a 5 kg iron block with a volume of about 7 cm x 7 cm x 5 cm was placed 1 meter above the hardened mortar layer. It was dropped by gravity and hit the hardened cement mortar layer. A radio decibel meter was placed on the first floor directly below the cement mortar layer. The decibel meter was 1 meter above the ground on the first floor. The maximum volume produced when the iron block on the second floor hit the mortar layer was recorded. A total of 20 hits were made, and the volume decibel value was the average of these 20 hits. The building floor height is about 3.2 meters. The test results are shown in Tables 2-1 to 2-3.
< 水泥砂漿強度 > :各個實施例及比較例所形成之水泥砂漿層個別經鐵塊撞擊20次後,觀察水泥砂漿層的外觀。若無龜裂、破裂,外觀無明顯變化定義為「無異常」。若產生細微裂痕小於2 mm,總數量小於5條,定義為「極小裂痕」。若產生裂痕大於2 mm,或數量多餘5條,定義為「明顯裂痕」。若砂漿層產生嚴重脫落分離,或明顯下凹的狀況,定義為「嚴重破碎」。測試結果如下表2-1至表2-3所示。 < Cement mortar strength > : After the cement mortar layers formed by each embodiment and comparative example were hit by iron blocks 20 times, the appearance of the cement mortar layers was observed. If there were no turtle cracks, cracks, and no obvious changes in appearance, it was defined as "no abnormality". If fine cracks less than 2 mm were generated, and the total number was less than 5, it was defined as "very small cracks". If cracks greater than 2 mm or more than 5 were generated, it was defined as "obvious cracks". If the mortar layer was severely detached and separated, or was obviously concave, it was defined as "severely broken". The test results are shown in Tables 2-1 to 2-3 below.
表2-1
表2-2
表2-3
由上表格可見,相較於一般含水泥和沙的水泥砂漿組合物(例如比較例1),本發明實施例之水泥砂漿組合物可達到良好隔音效果,再者,本發明之水泥砂漿組合物亦展現具有優異的抗壓強度,可避免產生破碎或明顯裂痕。As can be seen from the above table, compared with the general cement mortar composition containing cement and sand (such as Comparative Example 1), the cement mortar composition of the embodiment of the present invention can achieve a good sound insulation effect. Furthermore, the cement mortar composition of the present invention also exhibits excellent compressive strength and can avoid breakage or obvious cracks.
上述實施例僅為例示性說明本發明之功效,並闡述本發明之技術特徵,而非用於限制本發明之保護範疇。任何熟悉本技術者在不違背本發明之技術原理及精神下,可輕易完成之改變或安排,均屬本發明所主張之範圍。因此,本發明之權利保護範圍係如後附申請專利範圍所列。The above embodiments are only for illustrative purposes to illustrate the effects of the present invention and to explain the technical features of the present invention, and are not intended to limit the scope of protection of the present invention. Any changes or arrangements that can be easily accomplished by anyone familiar with the present technology without violating the technical principles and spirit of the present invention are within the scope of the present invention. Therefore, the scope of protection of the present invention is as listed in the attached patent application scope.
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CN104058661A (en) * | 2014-06-05 | 2014-09-24 | 山东科技大学 | Concrete hollow building block with junked tire rubber granules and preparation method thereof |
TW201908579A (en) * | 2017-07-17 | 2019-03-01 | 潤泰精密材料股份有限公司 | Energy-dissipating and sound-isolating device and manufacturing method thereof |
CN115028410A (en) * | 2022-06-12 | 2022-09-09 | 广东工业大学 | Green environment-friendly sound insulation rubber mortar and preparation method thereof |
TWM634852U (en) * | 2022-06-20 | 2022-12-01 | 李再興 | Sound insulation structure applied to floors to reduce impact noise |
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CN104058661A (en) * | 2014-06-05 | 2014-09-24 | 山东科技大学 | Concrete hollow building block with junked tire rubber granules and preparation method thereof |
TW201908579A (en) * | 2017-07-17 | 2019-03-01 | 潤泰精密材料股份有限公司 | Energy-dissipating and sound-isolating device and manufacturing method thereof |
CN115028410A (en) * | 2022-06-12 | 2022-09-09 | 广东工业大学 | Green environment-friendly sound insulation rubber mortar and preparation method thereof |
TWM634852U (en) * | 2022-06-20 | 2022-12-01 | 李再興 | Sound insulation structure applied to floors to reduce impact noise |
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