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TWI849347B - Manufacturing method of chemically plated nickel bump structure of wafer pad - Google Patents

Manufacturing method of chemically plated nickel bump structure of wafer pad Download PDF

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TWI849347B
TWI849347B TW110138181A TW110138181A TWI849347B TW I849347 B TWI849347 B TW I849347B TW 110138181 A TW110138181 A TW 110138181A TW 110138181 A TW110138181 A TW 110138181A TW I849347 B TWI849347 B TW I849347B
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electroless nickel
wafer
nickel
bumps
layer
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TW110138181A
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TW202316605A (en
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林功藝
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万閎企業有限公司
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Abstract

一種晶圓銲墊之化鍍鎳凸塊結構之製造方法,其中該化鍍鎳凸塊結構包含多個晶種層(seed layer),各該晶種層係利用無電解鎳(electroless nickle)方式在一晶圓上的多個光阻層之多個盲孔內對應形成多個以無電解鎳(化鍍鎳)構成之化鍍鎳凸塊,有效地解決現有利用無電解鎳(electroless nickel)之無電解金屬方式所產生的凸塊會有凸塊之大小、厚度或形狀不均勻或不如預期的情況的問題,有利於提升產品的良率。 A method for manufacturing a chemically plated nickel bump structure of a wafer pad, wherein the chemically plated nickel bump structure includes a plurality of seed layers, each of which is formed by using an electroless nickel method in a plurality of blind holes of a plurality of photoresist layers on a wafer to form a plurality of chemically plated nickel bumps made of electroless nickel (chemically plated nickel), which effectively solves the problem that the bumps produced by the existing electroless metal method using electroless nickel (electroless nickel) have uneven size, thickness or shape or are not as expected, and is conducive to improving the yield of products.

Description

晶圓銲墊之化鍍鎳凸塊結構之製造方法 Manufacturing method of electroless nickel bump structure for wafer pad

本發明係一種化鍍鎳凸塊結構之製造方法,尤指一種晶圓銲墊之化鍍鎳凸塊結構之製造方法。 The present invention is a method for manufacturing a chemically plated nickel bump structure, and in particular, a method for manufacturing a chemically plated nickel bump structure for a wafer pad.

在有關半導體晶片或晶圓之連結(如銲墊凸塊)、封裝(package)或其相關製程之技術領域中,目前已存在多種先前技術,如:中華民國發明專利I306638、I320588、I255538、I459362、I253733、I273651、I288447、I295498、I241658、I259572、I472371、I242866、I269461、I329917、I282132、I328266、及I284949;以及美國發明專利US8,030,767、US7,981,725、US7,969,003、US7,960,214、US7,847,414、US7,749,806、US7,651,886、US7,538,020、US7,750,467、US7,364,944、US7,019,406、US6,507,120、US7,999,387、US7,993,967、US7,868,470、US7,868,449、US7,972,902、US7,960,825、US7,952,187、US7,944,043、US7,934,313、及US7,906,855等。上述先前技術幾乎都屬於在其技術領域中之微小的改進。由此可見,在有關半導體晶片或晶圓之連結、封裝或其相關製程之技術領域中,其技術發展之空間已相當有限,因此在此技術發展空間有限之領域中(in the field of the crowded art),如能在技術上有微小之改進,亦得視為具有進步性。 In the field of semiconductor chip or wafer connection (such as solder bump), packaging or related processes, there are many prior arts, such as: Republic of China invention patents I306638, I320588, I255538, I459362, I253733, I273651, I288447, I295498, I241658, I259572, I472371, I242866, I269461, I329917, I282132, I328266, and I284949; and U.S. invention patents US8,030,767, US7,981,725, US 7,969,003, US7,960,214, US7,847,414, US7,749,806, US7,651,886, US7,538,020, US7,750,467, US7,364,944, US7,019,406, US6,507,120, US7,999,387, US7,993,967, US7,868,470, US7,868,449, US7,972,902, US7,960,825, US7,952,187, US7,944,043, US7,934,313, and US7,906,855, etc. The above-mentioned prior arts are almost all minor improvements in their technical fields. It can be seen that in the field of semiconductor chip or wafer connection, packaging or related processes, the space for technological development is already quite limited. Therefore, in this field of limited technological development space (in the field of the crowded art), if there can be a slight improvement in technology, it can also be regarded as progressive.

先前技術之凸塊結構及其製程難以符合實際使用時之需求,因此在晶圓銲墊之凸塊結構及其製法之技術領域中,發展並設計一種製程簡化、製作成本降低、凸塊之表面硬度符合後製程之接著程式要求、且設具側壁外護層 之凸塊結構,如中華民國專利I466255所揭示。然而,專利I466255中的凸塊結構係利用無電解鎳(electroless nickel)之無電解金屬方式,並配合有光阻方式,以在銲墊表面之觸媒層之表面各形成一具適當高度且以無電解鎳構成之凸塊(bump),在此亦稱為化鍍鎳(electroless nickel)凸塊,利用無電解鎳(electroless nickel)之無電解金屬方式所產生的凸塊會有凸塊之大小、厚度或形狀不均勻或不如預期的情況出現,導致產品的良率受到了影響。 The bump structure and its manufacturing process of the prior art are difficult to meet the requirements of actual use. Therefore, in the technical field of the bump structure and its manufacturing method of the wafer pad, a bump structure with simplified manufacturing process, reduced manufacturing cost, bump surface hardness meeting the requirements of the subsequent process, and provided with a side wall outer protection layer is developed and designed, as disclosed in the Republic of China Patent I466255. However, the bump structure in patent I466255 uses an electroless nickel electroless metal method and a photoresist method to form a bump of appropriate height and made of electroless nickel on the surface of the catalyst layer on the surface of the pad, which is also called electroless nickel bump. The bump produced by the electroless nickel electroless metal method may have uneven size, thickness or shape or be not as expected, which affects the yield of the product.

由上述可知,一種凸塊(亦稱為化鍍鎳凸塊)之大小、厚度或形狀均勻或符合預期的晶圓銲墊之化鍍鎳凸塊結構,為目前相關產業之迫切期待者。 From the above, it can be seen that a bump (also called electroless nickel bump) with uniform size, thickness or shape or an electroless nickel bump structure that meets the expected wafer pad is currently eagerly awaited by the relevant industry.

本發明之主要目的在於提供一種晶圓銲墊之化鍍鎳凸塊結構之製造方法,其中該化鍍鎳凸塊結構包含多個晶種層(seed layer),各該晶種層係利用無電解鎳(electroless nickle)方式在一晶圓上的多個光阻層之多個盲孔內對應形成多個以無電解鎳(化鍍鎳)構成之化鍍鎳凸塊,有效地解決現有利用無電解鎳(electroless nickel)之無電解金屬方式所產生的凸塊會有凸塊之大小、厚度或形狀不均勻或不如預期的情況的問題,有利於提升產品的良率。 The main purpose of the present invention is to provide a method for manufacturing a chemically plated nickel bump structure of a wafer pad, wherein the chemically plated nickel bump structure includes a plurality of seed layers, each of which is formed by using an electroless nickel method in a plurality of blind holes of a plurality of photoresist layers on a wafer to form a plurality of chemically plated nickel bumps made of electroless nickel (chemically plated nickel), which effectively solves the problem that the bumps produced by the existing electroless metal method using electroless nickel (electroless nickel) have uneven size, thickness or shape or are not as expected, which is beneficial to improving the yield of products.

為達成上述目的,本發明提供一種晶圓銲墊之化鍍鎳凸塊結構,該化鍍鎳凸塊結構包含一晶圓、多個晶種層(seed layer)及多個化鍍鎳凸塊;其中該晶圓具有一表面,該表面上設有多個銲墊;其中各該晶種層係覆蓋地設在該晶圓之該表面上並涵蓋於各該銲墊;其中各該晶種層係與該晶圓之各該銲墊電性連結;其中各該化鍍鎳凸塊係利用無電解鎳(electroless nickel,化學電鍍鎳)方式,以在各該晶種層之表面對應形成至少一具有適當高度及所欲形狀之該化 鍍鎳凸塊,其中各該化鍍鎳凸塊係與各該晶種層電性連結;其中各該化鍍鎳凸塊的位置及形狀係對應且涵蓋於該晶圓之各該銲墊,以使各該化鍍鎳凸塊能藉由各該晶種層與各該銲墊電性連結;其中該化鍍鎳凸塊結構更係由一化鍍鎳凸塊結構製造方法所製成,該化鍍鎳凸塊結構製造方法包含下列步驟:步驟S1:提供一晶圓,該晶圓具有一表面,該表面上設有多個銲墊;步驟S2:在該晶圓之該表面上設多個晶種層(seed layer),並使各該晶種層覆蓋地設在該晶圓之該表面上並涵蓋於各該銲墊;其中各該晶種層係與該晶圓之各該銲墊電性連結;步驟S3:在各該晶種層之表面上覆設一第一光阻層;步驟S4:在該第一光阻層上鑽孔成型至少一第一盲孔,各該第一盲孔係連通至各該晶種層;步驟S5:在各該晶種層利用無電解鎳(electroless nickle)方式在該第一光阻層的各該第一盲孔內對應形成多個以無電解鎳(化鍍鎳)構成之化鍍鎳凸塊;其中各該化鍍鎳凸塊係與各該晶種層電性連結;其中各該化鍍鎳凸塊的位置及形狀係對應且涵蓋於該晶圓之各該銲墊,以使各該化鍍鎳凸塊能藉由各該晶種層與各該銲墊電性連結;步驟S6:將該第一光阻層自各該晶種層之表面上移除,以凸露出各該化鍍鎳凸塊;及步驟S7:將該晶圓上未被各該化鍍鎳凸塊覆蓋的部份各該晶種層移除,有利於提升產品的良率。 To achieve the above-mentioned purpose, the present invention provides a nickel-plated bump structure for wafer pads, the nickel-plated bump structure comprising a wafer, a plurality of seed layers and a plurality of nickel-plated bumps; wherein the wafer has a surface, and a plurality of pads are disposed on the surface; wherein each of the seed layers is disposed on the surface of the wafer in a covering manner and covers each of the pads; wherein each of the seed layers is electrically connected to each of the pads of the wafer; wherein each of the nickel-plated bumps is formed by using electroless nickel. At least one electroplated nickel bump with a suitable height and a desired shape is formed on the surface of each seed layer, wherein each electroplated nickel bump is electrically connected to each seed layer; wherein the position and shape of each electroplated nickel bump corresponds to and covers each solder pad of the wafer, so that each electroplated nickel bump can be connected to each seed layer by each The seed layer is electrically connected to each of the pads; wherein the electroless nickel bump structure is further manufactured by a method for manufacturing an electroless nickel bump structure, and the method for manufacturing an electroless nickel bump structure comprises the following steps: step S1: providing a wafer, the wafer having a surface, and a plurality of pads are disposed on the surface; step S2: disposing a plurality of seed layers (seed layers) on the surface of the wafer step S3: covering the surface of each seed layer with a first photoresist layer; step S4: drilling at least one first blind hole in the first photoresist layer, each of which is connected to each seed layer; step S5: drilling a hole in each seed layer using electroless nickel; A plurality of electroless nickel (electrolytic nickel) plated nickel bumps are formed in the first blind holes of the first photoresist layer by a nickel-nickel method; wherein each of the electrolytic nickel bumps is electrically connected to each of the seed layers; wherein the position and shape of each of the electrolytic nickel bumps correspond to and cover each of the pads of the wafer, so that each of the The electroless nickel bumps can be electrically connected to the pads through the seed layers; step S6: removing the first photoresist layer from the surface of the seed layers to expose the electroless nickel bumps; and step S7: removing the portions of the seed layers on the wafer that are not covered by the electroless nickel bumps, which is beneficial to improving the yield of the product.

在本發明另一較佳實施例中,各該化鍍鎳凸塊之厚度約為2-14微米(μm)。 In another preferred embodiment of the present invention, the thickness of each electroless nickel plated bump is approximately 2-14 microns (μm).

本發明再一目的在於提供一種晶圓銲墊之化鍍鎳凸塊結構,該化鍍鎳凸塊結構包含一晶圓、多個晶種層(seed layer)、多個化鍍鎳凸塊及多個頂面外護層;其中該晶圓具有一表面,該表面上設有多個銲墊;其中各該晶種層係覆蓋地設在該晶圓之該表面上並涵蓋於各該銲墊;其中各該晶種層係與該晶 圓之各該銲墊電性連結;其中各該化鍍鎳凸塊係利用無電解鎳(electroless nickel,化學電鍍鎳)方式,以在各該晶種層之表面對應形成至少一具有適當高度及所欲形狀之該化鍍鎳凸塊,其中各該化鍍鎳凸塊係與各該晶種層電性連結,其中各該化鍍鎳凸塊的位置及形狀係對應且涵蓋於該晶圓之各該銲墊,以使各該化鍍鎳凸塊能藉由各該晶種層與各該銲墊電性連結;其中各該頂面外護層係分別對應設在各該化鍍鎳凸塊之頂面上並與各該化鍍鎳凸塊電性連結,以使各該頂面外護層能藉由各該化鍍鎳凸塊與該晶圓之各該銲墊電性連結,且各該頂面外護層的位置及形狀係對應且涵蓋於該晶圓之各該銲墊,其中各該頂面外護層係選自浸金(IG)層、或化銀(ES)層之族群中一種材料所構成,並利用選自化金製程、或化銀製程之族群中一製程以在各該化鍍鎳凸塊之頂面形成各該頂面外護層;其中該化鍍鎳凸塊結構更係由一化鍍鎳凸塊結構製造方法所製成,該化鍍鎳凸塊結構製造方法包含下列步驟:步驟S1:提供一晶圓,該晶圓具有一表面,該表面上設有多個銲墊;步驟S2:在該晶圓之該表面上設多個晶種層(seed layer),並使各該晶種層覆蓋地設在該晶圓之該表面上並涵蓋於各該銲墊;其中各該晶種層係與該晶圓之各該銲墊電性連結;步驟S3:在各該晶種層之表面上覆設一第一光阻層;步驟S4:在該第一光阻層上鑽孔成型至少一第一盲孔,各該第一盲孔係連通至各該晶種層;步驟S5:在各該晶種層利用無電解鎳(electroless nickle)方式在該第一光阻層的各該第一盲孔內對應形成多個以無電解鎳(化鍍鎳)構成之化鍍鎳凸塊;其中各該化鍍鎳凸塊係與各該晶種層電性連結;其中各該化鍍鎳凸塊的位置及形狀係對應且涵蓋於該晶圓之各該銲墊,以使各該化鍍鎳凸塊能藉由各該晶種層與各該銲墊電性連結;步驟S6:利用選自化金製程、或化銀製程之族群中之一製程,以在各該化鍍鎳凸塊之頂 面上分別形成多個頂面外護層與各該化鍍鎳凸塊對應,各該頂面外護層與各該化鍍鎳凸塊電性連結,以使各該頂面外護層能藉由各該化鍍鎳凸塊與該晶圓之各該銲墊電性連結,且各該頂面外護層的位置及形狀係對應且涵蓋於該晶圓之各該銲墊;其中各該頂面外護層係選自浸金層、或化銀層之族群中之一種材料所構成;步驟S7:將該第一光阻層自各該晶種層之表面上移除,以凸露出各該化鍍鎳凸塊及各該頂面外護層;及步驟S8:將該晶圓上未被各該化鍍鎳凸塊覆蓋的部份各該晶種層移除,有利於提升產品的良率。 Another object of the present invention is to provide a nickel-plated bump structure for wafer pads, the nickel-plated bump structure comprising a wafer, a plurality of seed layers, a plurality of nickel-plated bumps and a plurality of top surface outer protection layers; wherein the wafer has a surface, and a plurality of pads are arranged on the surface; wherein each of the seed layers is arranged on the surface of the wafer in a covering manner and covers each of the pads; wherein each of the seed layers is electrically connected to each of the pads of the wafer; wherein each of the nickel-plated bumps is formed by using electroless nickel. At least one electroplated nickel bump with a suitable height and a desired shape is formed on the surface of each seed layer by electroplating nickel (electrochemical nickel), wherein each electroplated nickel bump is electrically connected to each seed layer, wherein the position and shape of each electroplated nickel bump corresponds to and covers each pad of the wafer, so as to Each of the electroless nickel bumps can be electrically connected to each of the pads through each of the seed layers; wherein each of the top surface outer protective layers is respectively disposed on the top surface of each of the electroless nickel bumps and electrically connected to each of the electroless nickel bumps, so that each of the top surface outer protective layers can be electrically connected to each of the pads of the wafer through each of the electroless nickel bumps, and each of the top surface outer protective layers The position and shape of the protective layer correspond to and cover each of the pads of the wafer, wherein each of the top surface outer protective layers is composed of a material selected from the group of immersion gold (IG) layer or silver (ES) layer, and is formed on the top surface of each of the electroless nickel bumps using a process selected from the group of electroless gold process or electroless silver process. wherein the electroless nickel plated bump structure is further manufactured by a method for manufacturing an electroless nickel plated bump structure, the method for manufacturing an electroless nickel plated bump structure comprising the following steps: step S1: providing a wafer, the wafer having a surface, and a plurality of pads being disposed on the surface; step S2: disposing a plurality of seed layers (seed step S3: covering the surface of each seed layer with a first photoresist layer; step S4: drilling at least one first blind hole in the first photoresist layer, each of which is connected to each seed layer; step S5: drilling a hole in each seed layer using electroless nickel; A plurality of electroless nickel (electroless nickel) electroless nickel bumps are formed in the first blind holes of the first photoresist layer by a nickel-nickel method; wherein each of the electroless nickel bumps is electrically connected to each of the seed layers; wherein the position and shape of each of the electroless nickel bumps correspond to and cover each of the solder joints of the wafer. pads, so that each of the electroless nickel-plated bumps can be electrically connected to each of the solder pads through each of the seed layers; step S6: using a process selected from the group of gold-plated processes or silver-plated processes to form a plurality of top surface outer protective layers on the top surface of each of the electroless nickel-plated bumps and corresponding to each of the electroless nickel-plated bumps, each of the top surface outer protective layers The top surface outer protective layer is electrically connected to each of the electroless nickel bumps, so that each of the top surface outer protective layers can be electrically connected to each of the pads of the wafer through each of the electroless nickel bumps, and the position and shape of each of the top surface outer protective layers correspond to and cover each of the pads of the wafer; wherein each of the top surface outer protective layers is selected from the group of immersion gold layer or silver layer Step S7: removing the first photoresist layer from the surface of each seed layer to expose each nickel plated bump and each top surface outer protective layer; and Step S8: removing the portion of each seed layer on the wafer not covered by each nickel plated bump, which is beneficial to improving the yield of the product.

在本發明另一較佳實施例中,各該化鍍鎳凸塊之厚度約為2-14微米(μm),該浸金(IG)層之厚度約為0.01-0.05微米(μm),該厚金(EG)層之厚度約為0.5-2.0微米(μm),該化銀(ES)層之厚度約為0.5-2.0微米(μm)。 In another preferred embodiment of the present invention, the thickness of each electroless nickel bump is about 2-14 micrometers (μm), the thickness of the immersion gold (IG) layer is about 0.01-0.05 micrometers (μm), the thickness of the thick gold (EG) layer is about 0.5-2.0 micrometers (μm), and the thickness of the electroless silver (ES) layer is about 0.5-2.0 micrometers (μm).

本發明再一目的在於提供一種晶圓銲墊之化鍍鎳凸塊結構,該化鍍鎳凸塊結構包含一晶圓、多個晶種層(seed layer)、多個化鍍鎳凸塊及多個頂面外護層;其中該晶圓具有一表面,該表面上設有多個銲墊;其中各該晶種層係覆蓋地設在該晶圓之該表面上並涵蓋於各該銲墊,其中各該晶種層係與該晶圓之各該銲墊電性連結;其中各該化鍍鎳凸塊係利用無電解鎳(electroless nickel,化學電鍍鎳)方式,以在各該晶種層之表面對應形成至少一具有適當高度及所欲形狀之該化鍍鎳凸塊;其中各該化鍍鎳凸塊係與各該晶種層電性連結,其中各該化鍍鎳凸塊的位置及形狀係對應且涵蓋於該晶圓之各該銲墊,以使各該化鍍鎳凸塊能藉由各該晶種層與各該銲墊電性連結;其中各該頂面外護層係分別對應設在各該化鍍鎳凸塊之頂面上並與各該化鍍鎳凸塊電性連結,以使各該頂面外護層能藉由各該化鍍鎳凸塊與該晶圓之各該銲墊電性連結,且各該頂面外護層的位置及形狀係對應且涵蓋於該晶圓之各該銲墊,其中各該頂面 外護層係選自浸金(IG)層、或化銀(ES)層之族群中一種材料所構成,並利用選自化金製程、或化銀製程之族群中一製程以在各該化鍍鎳凸塊之頂面形成各該頂面外護層;其中各該側壁外護層係分別設在各該化鍍鎳凸塊之環側面上並與各該化鍍鎳凸塊電性連結,以使各該側壁外護層能藉由各該化鍍鎳凸塊與該晶圓之各該銲墊電性連結,其中各該側壁外護層係包含至少一選自浸金(IG)層、或化銀(ES)層之族群中一種材料所構成之保護層,並利用選自化金製程、或化銀製程之族群中一製程以在各該化鍍鎳凸塊之環側面上分別形成各該側壁外護層;其中各該化鍍鎳凸塊在其頂面上所形成之各該頂面外護層與在其環側面上所形成之各該側壁外護層係完全密合地包覆在各該化鍍鎳凸塊之外表面,以形成一完整的外護層;其中該化鍍鎳凸塊結構更係由一化鍍鎳凸塊結構製造方法所製成,該化鍍鎳凸塊結構製造方法包含下列步驟:步驟S1:提供一晶圓,該晶圓具有一表面,該表面上設有多個銲墊;步驟S2:在該晶圓之該表面上設多個晶種層(seed layer),並使各該晶種層覆蓋地設在該晶圓之該表面上並涵蓋於各該銲墊;其中各該晶種層係與該晶圓之各該銲墊電性連結;步驟S3:在各該晶種層之表面上覆設一第一光阻層;步驟S4:在該第一光阻層上鑽孔成型至少一第一盲孔,各該第一盲孔係連通至各該晶種層;步驟S5:在各該晶種層利用無電解鎳(electroless nickle)方式在該第一光阻層的各該第一盲孔內對應形成多個以無電解鎳(化鍍鎳)構成之化鍍鎳凸塊;其中各該化鍍鎳凸塊係與各該晶種層電性連結;其中各該化鍍鎳凸塊的位置及形狀係對應且涵蓋於該晶圓之各該銲墊,以使各該化鍍鎳凸塊能藉由各該晶種層與各該銲墊電性連結;步驟S6:利用選自化金製程、或化銀製程之族群中之一製程,以在各該化鍍鎳凸塊之頂面上分別形成多個頂面外護層與各該化鍍鎳凸塊對應,各該頂面外護層與 各該化鍍鎳凸塊電性連結,以使各該頂面外護層能藉由各該化鍍鎳凸塊與該晶圓之各該銲墊電性連結,且各該頂面外護層的位置及形狀係對應且涵蓋於該晶圓之各該銲墊;其中各該頂面外護層係選自浸金層、或化銀層之族群中之一種材料所構成;步驟S7:將該第一光阻層自各該晶種層之表面上移除,以凸露出各該化鍍鎳凸塊及各該頂面外護層;步驟S8:將該晶圓上未被各該化鍍鎳凸塊覆蓋的部份各該晶種層移除;步驟S9:在該晶圓之該表面上覆設一第二光阻層;步驟S10:在該第二光阻層上貫穿地鑽孔成型至少一第一盲孔及至少一第二盲孔,各該第一盲孔及各該第二盲孔係連通至該晶圓;步驟S11:在該晶圓利用無電解鎳方式在該第二光阻層的各該第一盲孔及各該第二盲孔內利用選自化金製程、或化銀製程之族群中之一製程,以在各該化鍍鎳凸塊之環側面上分別形成多個側壁外護層,各該側壁外護層與各該化鍍鎳凸塊電性連結,以使各該側壁外護層能藉由各該化鍍鎳凸塊與該晶圓之各該銲墊電性連結;其中各該側壁外護層包含至少一保護層其係選自浸金層、或化銀層之族群中之一種材料所構成;及步驟S12:將該第二光阻層自該晶圓之該表面上移除,有利於提升產品的良率。 Another object of the present invention is to provide a nickel-plated bump structure for wafer pads, the nickel-plated bump structure comprising a wafer, a plurality of seed layers, a plurality of nickel-plated bumps and a plurality of top surface outer protection layers; wherein the wafer has a surface, and a plurality of pads are disposed on the surface; wherein each of the seed layers is disposed on the surface of the wafer in a covering manner and covers each of the pads, wherein each of the seed layers is electrically connected to each of the pads of the wafer; wherein each of the nickel-plated bumps is formed by using electroless nickel. At least one electroplated nickel bump with a suitable height and a desired shape is formed on the surface of each seed layer in a manner corresponding to nickel, wherein each electroplated nickel bump is electrically connected to each seed layer, wherein the position and shape of each electroplated nickel bump corresponds to and covers each solder pad of the wafer, so that each electroplated nickel bump can be electrically connected to each solder pad through each seed layer; wherein each top surface outer protective layer is respectively disposed on the top surface of each electroplated nickel bump and is electrically connected to each electroplated nickel bump. The top surface outer protective layer is electrically connected to each of the pads of the wafer through each of the electroless nickel bumps, and the position and shape of each of the top surface outer protective layers correspond to and cover each of the pads of the wafer, wherein each of the top surface outer protective layers is composed of a material selected from the group of immersion gold (IG) layers or electroless silver (ES) layers, and is formed on the top surface of each of the electroless nickel bumps by a process selected from the group of electroless gold processes or electroless silver processes; wherein each of the side wall outer protective layers is respectively arranged at The sidewall outer protective layer is formed on the annular side surface of each of the electroplated nickel bumps and is electrically connected to each of the electroplated nickel bumps, so that each of the sidewall outer protective layers can be electrically connected to each of the solder pads of the wafer through each of the electroplated nickel bumps, wherein each of the sidewall outer protective layers comprises at least one protective layer composed of a material selected from the group of immersion gold (IG) layers or electroplated silver (ES) layers, and a process selected from the group of electroplated gold processes or electroplated silver processes is used to form each of the sidewall outer protective layers on the annular side surface of each of the electroplated nickel bumps; wherein each of the electroplated nickel bumps is electrically connected to each of the solder pads of the wafer through each of the electroplated nickel bumps. The top surface outer protective layer formed on the top surface and the side wall outer protective layer formed on the side surface thereof are completely and tightly covered on the outer surface of each electroless nickel bump to form a complete outer protective layer; wherein the electroless nickel bump structure is further manufactured by a method for manufacturing an electroless nickel bump structure, and the method for manufacturing an electroless nickel bump structure comprises the following steps: step S1: providing a wafer, the wafer having a surface, and a plurality of pads are disposed on the surface; step S2: disposing a plurality of seed layers (seed step S3: covering the surface of each seed layer with a first photoresist layer; step S4: drilling at least one first blind hole in the first photoresist layer, each of which is connected to each seed layer; step S5: drilling a hole in each seed layer using electroless nickel; A plurality of electroless nickel (electroless nickel) electroless nickel bumps are formed in the first blind holes of the first photoresist layer by a nickel process; wherein each of the electroless nickel bumps is electrically connected to each of the seed layers; wherein the position and shape of each of the electroless nickel bumps correspond to and cover each of the solder pads of the wafer, so that each of the electroless nickel bumps can be electrically connected to each of the solder pads through each of the seed layers; step S6: using a process selected from the group of gold electroless processes or silver electroless processes to form a plurality of electroless nickel bumps on the top surfaces of each of the electroless nickel bumps; A plurality of top surface outer protective layers are formed corresponding to each of the electroless nickel bumps, each of the top surface outer protective layers is electrically connected to each of the electroless nickel bumps, so that each of the top surface outer protective layers can be electrically connected to each of the solder pads of the wafer through each of the electroless nickel bumps, and the position and shape of each of the top surface outer protective layers correspond to and cover each of the solder pads of the wafer; wherein each of the top surface outer protective layers is composed of a material selected from the group of immersion gold layer or silver layer; step S7: removing the first photoresist layer from the surface of each of the seed layers to expose each of the electroless nickel bumps and each top outer protective layer; step S8: removing each of the seed layers on the wafer that are not covered by each of the electroless nickel-plated nickel bumps; step S9: covering the surface of the wafer with a second photoresist layer; step S10: drilling holes through the second photoresist layer to form at least one first blind hole and at least one second blind hole, each of the first blind hole and each of the second blind holes being connected to the wafer; step S11: drilling holes in each of the first blind holes and each of the second blind holes of the second photoresist layer on the wafer using an electroless nickel method using a process selected from a gold process, or a process selected from a gold process, or a process selected from a gold process, A process in the group of silver deposition processes, to form a plurality of side wall outer protective layers on the annular side surface of each of the nickel deposition bumps, each of the side wall outer protective layers is electrically connected to each of the nickel deposition bumps, so that each of the side wall outer protective layers can be electrically connected to each of the pads of the wafer through each of the nickel deposition bumps; wherein each of the side wall outer protective layers includes at least one protective layer which is selected from a material in the group of immersion gold layer or silver deposition layer; and step S12: removing the second photoresist layer from the surface of the wafer, which is beneficial to improving the yield of the product.

在本發明另一較佳實施例中,各該化鍍鎳凸塊之厚度約為2-14微米(μm),該浸金(IG)層之厚度約為0.01-0.05微米(μm),該厚金(EG)層之厚度約為0.5-2.0微米(μm),該化銀(ES)層之厚度約為0.5-2.0微米(μm)。 In another preferred embodiment of the present invention, the thickness of each electroless nickel bump is about 2-14 micrometers (μm), the thickness of the immersion gold (IG) layer is about 0.01-0.05 micrometers (μm), the thickness of the thick gold (EG) layer is about 0.5-2.0 micrometers (μm), and the thickness of the electroless silver (ES) layer is about 0.5-2.0 micrometers (μm).

本發明再一目的在於提供一種晶圓銲墊之化鍍鎳凸塊結構之製造方法,該化鍍鎳凸塊結構製造方法包含下列步驟:步驟S1:提供一晶圓,該晶圓具有一表面,該表面上設有多個銲墊;步驟S2:在該晶圓之該表面上設多個晶種層(seed layer),並使各該晶種層覆蓋地設在該晶圓之該表面上並涵蓋於 各該銲墊;其中各該晶種層係與該晶圓之各該銲墊電性連結;步驟S3:在各該晶種層之表面上覆設一第一光阻層;步驟S4:在該第一光阻層上鑽孔成型至少一盲孔,各該盲孔係連通至各該晶種層;步驟S5:在各該晶種層利用無電解鎳(electroless nickle)方式在該第一光阻層的各該盲孔內對應形成多個以無電解鎳(化鍍鎳)構成之厚度約為2-14微米(μm)的化鍍鎳凸塊;其中各該化鍍鎳凸塊係與各該晶種層電性連結;其中各該化鍍鎳凸塊的位置及形狀係對應且涵蓋於該晶圓之各該銲墊,以使各該化鍍鎳凸塊能藉由各該晶種層與各該銲墊電性連結;步驟S6:在該第一光阻層上貫穿地形成至少一第一溝槽及至少一第二溝槽,且各該第一溝槽及各該第二溝槽更係貫穿各該晶種層而連通至該晶圓;步驟S7:利用選自化金製程、或化銀製程之族群中之一製程,以在各該化鍍鎳凸塊之頂面及環側面上分別形成至少一頂面外護層及多個側壁外護層,其中各該頂面外護層及各該側壁外護層包含至少一保護層其係選自浸金層、或化銀層之族群中之一種材料所構成,使各該頂面外護層與在其環側面上所形成之各該側壁外護層係完全密合地包覆在各該化鍍鎳凸塊之外表面,以形成一完整的外護層;其中各該頂面外護層及各該側壁外護層與各該化鍍鎳凸塊電性連結,以使各該頂面外護層及各該側壁外護層能藉由各該化鍍鎳凸塊與該晶圓之各該銲墊電性連結;步驟S8:將該第一光阻層自各該晶種層之表面上移除;及步驟S9:將該晶圓上未被各該化鍍鎳凸塊覆蓋的部份各該晶種層移除,有利於提升產品的良率。 Another object of the present invention is to provide a method for manufacturing a nickel-plated bump structure of a wafer pad, the method comprising the following steps: step S1: providing a wafer, the wafer having a surface, the surface being provided with a plurality of pads; step S2: providing a plurality of seed layers on the surface of the wafer layer), and each of the seed layers is covered on the surface of the wafer and covers each of the pads; wherein each of the seed layers is electrically connected to each of the pads of the wafer; step S3: a first photoresist layer is covered on the surface of each of the seed layers; step S4: at least one blind hole is drilled on the first photoresist layer, and each of the blind holes is connected to each of the seed layers; step S5: electroless nickel is used to form a hole in each of the seed layers. A plurality of electroless nickel (electroless nickel) electroless nickel bumps with a thickness of about 2-14 micrometers (μm) are formed in the blind holes of the first photoresist layer by a nickel-nickel method; wherein each of the electroless nickel bumps is electrically connected to each of the seed layers; wherein the position and shape of each of the electroless nickel bumps correspond to and cover each of the pads of the wafer, so that each of the electroless nickel bumps can be electrically connected to each of the seed layers by the seed layers. The first photoresist layer is electrically connected to each of the pads; step S6: at least one first trench and at least one second trench are formed through the first photoresist layer, and each of the first trench and each of the second trenches penetrates each of the seed layers and is connected to the wafer; step S7: using a process selected from the group of gold deposition process or silver deposition process to form at least one top surface and a peripheral side surface of each of the nickel deposition bumps. The outer protective layer and the side wall outer protective layers, wherein each of the top surface outer protective layer and each of the side wall outer protective layers comprises at least one protective layer which is made of a material selected from the group of immersion gold layer or silver layer, so that each of the top surface outer protective layer and each of the side wall outer protective layers formed on the surrounding side surface are completely and tightly coated on the outer surface of each of the chemically plated nickel bumps to form a complete outer protective layer; wherein each of the top surface outer protective layer and Each of the side wall outer protective layers is electrically connected to each of the electroless nickel bumps, so that each of the top surface outer protective layers and each of the side wall outer protective layers can be electrically connected to each of the pads of the wafer through each of the electroless nickel bumps; step S8: removing the first photoresist layer from the surface of each of the seed layers; and step S9: removing the portion of each of the seed layers on the wafer that is not covered by each of the electroless nickel bumps, which is beneficial to improving the yield of the product.

在本發明另一較佳實施例中,各該化鍍鎳凸塊之厚度約為2-14微米(μm),該浸金(IG)層之厚度約為0.01-0.05微米(μm),該厚金(EG)層之厚度約為0.5-2.0微米(μm),該化銀(ES)層之厚度約為0.5-2.0微米(μm) In another preferred embodiment of the present invention, the thickness of each electroless nickel bump is about 2-14 micrometers (μm), the thickness of the immersion gold (IG) layer is about 0.01-0.05 micrometers (μm), the thickness of the thick gold (EG) layer is about 0.5-2.0 micrometers (μm), and the thickness of the electroless silver (ES) layer is about 0.5-2.0 micrometers (μm)

1:化鍍鎳凸塊結構 1: Chemically plated nickel bump structure

1a:化鍍鎳凸塊結構 1a: Electroless nickel plated bump structure

1b:化鍍鎳凸塊結構 1b: Electroless nickel plated bump structure

1c:化鍍鎳凸塊結構 1c: Electroless nickel plated bump structure

10:晶圓 10: Wafer

11:表面 11: Surface

12:銲墊 12: Welding pad

20:晶種層 20: Seed layer

30:化鍍鎳凸塊 30: Electroless nickel plated bumps

31:頂面 31: Top

40:頂面外護層 40: Top outer protective layer

50:側壁外護層 50: Side wall outer protective layer

60:第一光阻層 60: First photoresist layer

61:盲孔 61: Blind hole

62:第一溝槽 62: First groove

63:第二溝槽 63: Second groove

70:第二光阻層 70: Second photoresist layer

71:第一盲孔 71: First blind hole

72:第二盲孔 72: Second blind hole

圖1為本發明之晶圓銲墊之化鍍鎳凸塊結構之第一實施例之截面示意圖。 FIG1 is a cross-sectional schematic diagram of the first embodiment of the electroless nickel plated bump structure of the wafer pad of the present invention.

圖2為本發明之晶圓之截面示意圖。 Figure 2 is a schematic cross-sectional view of the wafer of the present invention.

圖3為本發明之晶種層覆蓋地設在晶圓之表面上之截面示意圖。 FIG3 is a cross-sectional schematic diagram of the seed layer of the present invention being arranged coveringly on the surface of the wafer.

圖4為本發明之第一光阻層覆蓋地設在晶種層之表面上之截面示意圖。 FIG4 is a cross-sectional schematic diagram of the first photoresist layer of the present invention being disposed coveringly on the surface of the seed layer.

圖5為利用無電解鎳方式在第一光阻層的盲孔內對應形成化鍍鎳凸塊之截面示意圖。 Figure 5 is a schematic cross-sectional view of forming a nickel-plated bump in a blind hole of the first photoresist layer using an electroless nickel method.

圖6為將第一光阻層自晶種層之表面上移除之截面示意圖。 FIG6 is a cross-sectional schematic diagram of removing the first photoresist layer from the surface of the seed layer.

圖7為本發明之晶圓銲墊之化鍍鎳凸塊結構之第二實施例之截面示意圖。 FIG7 is a cross-sectional schematic diagram of the second embodiment of the electroless nickel-plated bump structure of the wafer pad of the present invention.

圖8為利用無電解鎳方式在第一光阻層的盲孔內對應形成化鍍鎳凸塊且在化鍍鎳凸塊上形成頂面外護層之截面示意圖。 Figure 8 is a cross-sectional schematic diagram of forming a nickel-plated bump in a blind hole of a first photoresist layer using an electroless nickel method and forming a top surface outer protective layer on the nickel-plated bump.

圖9為將圖8中第一光阻層移除之截面示意圖。 FIG9 is a cross-sectional schematic diagram showing the removal of the first photoresist layer in FIG8 .

圖10為本發明之晶圓銲墊之化鍍鎳凸塊結構之第三實施例之截面示意圖。 FIG10 is a schematic cross-sectional view of the third embodiment of the electroless nickel plated bump structure of the wafer pad of the present invention.

圖11為在圖8中之第二光阻層上貫穿地鑽孔成型第一盲孔及第二盲孔之截面示意圖。 FIG11 is a schematic cross-sectional view of the first blind hole and the second blind hole formed by drilling through the second photoresist layer in FIG8 .

圖12為在圖11中第二光阻層的第一盲孔及第二盲孔內利用選自化金製程、或化銀製程之族群中之一製程在化鍍鎳凸塊之環側面上分別形成側壁外護層之截面示意圖。 FIG. 12 is a cross-sectional schematic diagram of forming a sidewall outer protective layer on the annular side surface of the electroless nickel plated bump in the first blind hole and the second blind hole of the second photoresist layer in FIG. 11 using a process selected from the group of electroless gold process or electroless silver process.

圖13為在圖8中之第一光阻層上貫穿地鑽孔成型盲孔、第一溝槽及第二溝槽之截面示意圖。 FIG13 is a schematic cross-sectional view of the blind hole, the first trench and the second trench formed by drilling through the first photoresist layer in FIG8.

圖14為在圖13中之第一光阻層的盲孔、第一溝槽及第二溝槽內分別成型頂面外護層及側壁外護層之截面示意圖。 FIG14 is a cross-sectional schematic diagram of the top surface outer protective layer and the side wall outer protective layer formed in the blind hole, the first groove and the second groove of the first photoresist layer in FIG13 respectively.

圖15為將圖14中之第二光阻層移除之截面示意圖。 FIG15 is a cross-sectional schematic diagram showing the removal of the second photoresist layer in FIG14 .

圖16為之晶圓銲墊之化鍍鎳凸塊結構之第四實施例之截面示意圖。 FIG16 is a schematic cross-sectional view of the fourth embodiment of the electroless nickel-plated bump structure of the wafer pad.

圖17為本發明之第一實施例之兩個以上化鍍鎳凸塊結構之截面示意圖。 FIG17 is a schematic cross-sectional view of a structure of two or more electroless nickel-plated bumps of the first embodiment of the present invention.

圖18為本發明之第二實施例之兩個以上化鍍鎳凸塊結構之截面示意圖。 FIG18 is a cross-sectional schematic diagram of a structure of two or more electroless nickel-plated bumps of the second embodiment of the present invention.

圖19為本發明之第三實施例之兩個以上化鍍鎳凸塊結構之截面示意圖。 FIG19 is a schematic cross-sectional view of a structure of two or more electroless nickel-plated bumps of the third embodiment of the present invention.

配合圖示,將本發明的結構及其技術特徵詳述如後,其中各圖示只用以說明本發明的結構關係及相關功能,因此各圖示中各元件的尺寸並非依實際比例畫製且非用以限制本發明。 The structure and technical features of the present invention are described in detail below with the help of diagrams. Each diagram is only used to illustrate the structural relationship and related functions of the present invention. Therefore, the size of each component in each diagram is not drawn according to the actual scale and is not used to limit the present invention.

參考圖1、7、10及16,本發明提供一種晶圓銲墊之化鍍鎳凸塊結構1、1a、1b及1c,該化鍍鎳凸塊結構1、1a、1b及1c能解決現有利用無電解鎳(electroless nickel)之無電解金屬方式所產生的凸塊會有凸塊之大小、厚度或形狀不均勻或不如預期的情況的問題,然而,本發明之該化鍍鎳凸塊結構1、1a、1b及1c可透過不同的製造方法來成型,有利於提升產品的良率。根據該化鍍鎳凸塊結構1、1a、1b及1c彼此之間不同的製造方法可將該化鍍鎳凸塊結構1、1a、1b及1c分類為第一實施例、第二實施例、第三實施例及第四實施例,以下針對各實施例並配合圖式進行說明: 在圖1至5、8至12及17中所示的施實例為本發明之第一實施例,在第一實施例中的該化鍍鎳凸塊結構1包含一晶圓10、多個晶種層(seed layer)20、多個化鍍鎳凸塊30、多個頂面外護層40及多個側壁外護層50。 Referring to FIGS. 1, 7, 10 and 16, the present invention provides a chemically plated nickel bump structure 1, 1a, 1b and 1c for a wafer pad. The chemically plated nickel bump structure 1, 1a, 1b and 1c can solve the problem that the bumps produced by the existing electroless metal method using electroless nickel have uneven size, thickness or shape or are not as expected. However, the chemically plated nickel bump structure 1, 1a, 1b and 1c of the present invention can be formed by different manufacturing methods, which is beneficial to improving the yield of the product. According to the different manufacturing methods of the electroless nickel bump structures 1, 1a, 1b and 1c, the electroless nickel bump structures 1, 1a, 1b and 1c can be classified into a first embodiment, a second embodiment, a third embodiment and a fourth embodiment. The following describes each embodiment with the help of drawings: The embodiment shown in Figures 1 to 5, 8 to 12 and 17 is the first embodiment of the present invention. In the first embodiment, the electroless nickel bump structure 1 includes a wafer 10, a plurality of seed layers 20, a plurality of electroless nickel bumps 30, a plurality of top surface outer protective layers 40 and a plurality of side wall outer protective layers 50.

該晶圓10具有一表面11如圖1所示,該表面11上設有多個銲墊12。 The wafer 10 has a surface 11 as shown in FIG. 1 , and a plurality of pads 12 are disposed on the surface 11 .

各該晶種層20係覆蓋地設在該晶圓10之該表面11上並涵蓋於各該銲墊12如圖1所示;其中各該晶種層20係與該晶圓10之各該銲墊12電性連結。 Each of the seed layers 20 is disposed on the surface 11 of the wafer 10 in a covering manner and covers each of the pads 12 as shown in FIG. 1 ; wherein each of the seed layers 20 is electrically connected to each of the pads 12 of the wafer 10 .

各該化鍍鎳凸塊30係利用無電解鎳(electroless nickel,化學電鍍鎳)方式,以在各該晶種層20之表面對應形成至少一具有適當高度及所欲形狀之該化鍍鎳凸塊30如圖1所示;其中各該化鍍鎳凸塊30係與各該晶種層20電性連結;其中各該化鍍鎳凸塊30的位置及形狀係對應且涵蓋於該晶圓10之各該銲墊12,以使各該化鍍鎳凸塊30能藉由各該晶種層20與各該銲墊12電性連結。 Each of the electroless nickel bumps 30 is formed by electroless nickel (electroless nickel, chemical nickel plating) on the surface of each of the seed layers 20 to form at least one electroless nickel bump 30 with a suitable height and a desired shape as shown in FIG1 ; wherein each of the electroless nickel bumps 30 is electrically connected to each of the seed layers 20 ; wherein the position and shape of each of the electroless nickel bumps 30 correspond to and cover each of the pads 12 of the wafer 10 , so that each of the electroless nickel bumps 30 can be electrically connected to each of the pads 12 through each of the seed layers 20 .

各該頂面外護層40係分別對應設在各該化鍍鎳凸塊30之頂面31上並與各該化鍍鎳凸塊30電性連結如圖1所示,以使各該頂面外護層40能藉由各該化鍍鎳凸塊30與該晶圓10之各該銲墊12電性連結,且各該頂面外護層40的位置及形狀係對應且涵蓋於該晶圓10之各該銲墊12;其中各該頂面外護層40係選自浸金(IG)層、或化銀(ES)層之族群中一種材料所構成,並利用選自化金製程、或化銀製程之族群中一製程以在各該化鍍鎳凸塊30之頂面31形成各該頂面外護層40。 Each of the top surface outer protective layers 40 is disposed on the top surface 31 of each of the electroless nickel plated bumps 30 and is electrically connected to each of the electroless nickel plated bumps 30 as shown in FIG. 1 , so that each of the top surface outer protective layers 40 can be electrically connected to each of the pads 12 of the wafer 10 through each of the electroless nickel plated bumps 30, and the position and shape of each of the top surface outer protective layers 40 are corresponding to the top surface 31 of each of the electroless nickel plated bumps 30. It should also cover each of the pads 12 of the wafer 10; wherein each of the top surface outer protective layers 40 is composed of a material selected from the group of immersion gold (IG) layers or silver (ES) layers, and a process selected from the group of gold or silver processes is used to form each of the top surface outer protective layers 40 on the top surface 31 of each of the nickel plated bumps 30.

各該側壁外護層50係分別設在各該化鍍鎳凸塊30之環側面32上並與各該化鍍鎳凸塊30電性連結如圖1所示,以使各該側壁外護層50能藉由各該化鍍鎳凸塊30與該晶圓10之各該銲墊12電性連結;其中各該側壁外護層50係包含至少一選自浸金(IG)層、或化銀(ES)層之族群中一種材料所構成之保護層,並利用選自化金製程、或化銀製程之族群中一製程以在各該化鍍鎳凸塊30之環側面32上分別形成各該側壁外護層50。 Each of the side wall outer protective layers 50 is disposed on the circumferential side surface 32 of each of the electroless nickel plated bumps 30 and is electrically connected to each of the electroless nickel plated bumps 30 as shown in FIG. 1 , so that each of the side wall outer protective layers 50 can be electrically connected to each of the pads 12 of the wafer 10 through each of the electroless nickel plated bumps 30; wherein each of the side wall outer protective layers 50 is electrically connected to each of the pads 12 of the wafer 10 through each of the electroless nickel plated bumps 30. The protective layer 50 includes at least one protective layer made of a material selected from the group of immersion gold (IG) layers or ES layers, and uses a process selected from the group of ES processes to form each of the sidewall outer protective layers 50 on the annular side surface 32 of each ES nickel plated bump 30.

其中,各該化鍍鎳凸塊30在其頂面31上所形成之各該頂面外護層40與在其環側面32上所形成之各該側壁外護層50係完全密合地包覆在各該化鍍鎳凸塊30之外表面,以形成一完整的外護層如圖1所示。 Among them, each of the top surface outer protective layers 40 formed on the top surface 31 of each of the electroless nickel plated bumps 30 and each of the side wall outer protective layers 50 formed on the surrounding side surface 32 are completely and tightly covered on the outer surface of each of the electroless nickel plated bumps 30 to form a complete outer protective layer as shown in FIG1 .

此外,該化鍍鎳凸塊結構1更係由一化鍍鎳凸塊結構製造方法所製成,該化鍍鎳凸塊結構1製造方法包含下列步驟: In addition, the electroless nickel plated bump structure 1 is manufactured by a method for manufacturing an electroless nickel plated bump structure, and the method for manufacturing an electroless nickel plated bump structure 1 includes the following steps:

步驟S1:提供一晶圓10如圖2所示,該晶圓10具有一表面11,該表面11上設有多個銲墊12。 Step S1: Provide a wafer 10 as shown in FIG2 . The wafer 10 has a surface 11 , and a plurality of pads 12 are disposed on the surface 11 .

步驟S2:在該晶圓10之該表面11上設多個晶種層(seed layer)20如圖3所示,並使各該晶種層20覆蓋地設在該晶圓10之該表面11上並涵蓋於各該銲墊12;其中各該晶種層20係與該晶圓10之各該銲墊12電性連結。 Step S2: multiple seed layers 20 are provided on the surface 11 of the wafer 10 as shown in FIG3, and each seed layer 20 is provided on the surface 11 of the wafer 10 in a covering manner and covers each solder pad 12; wherein each seed layer 20 is electrically connected to each solder pad 12 of the wafer 10.

步驟S3:在各該晶種層20之表面上覆設一第一光阻層60如圖4所示。 Step S3: A first photoresist layer 60 is formed on the surface of each seed layer 20 as shown in FIG4 .

步驟S4:在該第一光阻層60上鑽孔成型至少一盲孔61如圖4所示,各該盲孔61係連通至各該晶種層20。 Step S4: Drill at least one blind hole 61 on the first photoresist layer 60 as shown in FIG. 4 , and each blind hole 61 is connected to each seed layer 20 .

步驟S5:在各該晶種層20利用無電解鎳(electroless nickle)方式在各該盲孔61內對應形成多個以無電解鎳(化鍍鎳)構成之化鍍鎳凸塊30如圖5所示;其中各該化鍍鎳凸塊30係與各該晶種層20電性連結;其中各該化鍍鎳凸塊30的位置及形狀係對應且涵蓋於該晶圓10之各該銲墊12,以使各該化鍍鎳凸塊30能藉由各該晶種層20與各該銲墊12電性連結。 Step S5: A plurality of electroless nickel bumps 30 made of electroless nickel (electroless nickel) are formed in each blind hole 61 in each seed layer 20 by an electroless nickel method as shown in FIG. 5 ; wherein each electroless nickel bump 30 is electrically connected to each seed layer 20 ; wherein the position and shape of each electroless nickel bump 30 correspond to and cover each solder pad 12 of the wafer 10 , so that each electroless nickel bump 30 can be electrically connected to each solder pad 12 through each seed layer 20 .

步驟S6:利用選自化金製程、或化銀製程之族群中之一製程,以在各該化鍍鎳凸塊30之頂面上分別形成多個頂面外護層40與各該化鍍鎳凸塊30對應如圖8所示,各該頂面外護層40與各該化鍍鎳凸塊30電性連結,以使各該頂面外護層40能藉由各該化鍍鎳凸塊30與該晶圓10之各該銲墊12電性連結,且各該頂面外護層40的位置及形狀係對應且涵蓋於該晶圓10之各該銲墊12;其中各該頂面外護層40係選自浸金層、或化銀層之族群中之一種材料所構成。 Step S6: Using a process selected from the group of gold deposition process or silver deposition process, a plurality of top surface outer protection layers 40 are formed on the top surface of each of the nickel deposition bumps 30, and each of the nickel deposition bumps 30 corresponds to the top surface of each of the nickel deposition bumps 30, as shown in FIG. 8. Each of the top surface outer protection layers 40 is electrically connected to each of the nickel deposition bumps 30, so that each of the top surface outer protection layers 40 is electrically connected to each of the nickel deposition bumps 30. The protective layer 40 can be electrically connected to each of the pads 12 of the wafer 10 through each of the electroless nickel-plated bumps 30, and the position and shape of each of the top surface outer protective layers 40 correspond to and cover each of the pads 12 of the wafer 10; wherein each of the top surface outer protective layers 40 is composed of a material selected from the group of immersion gold layer or electroless silver layer.

步驟S7:將該第一光阻層60自各該晶種層20之表面上移除如圖9所示,以凸露出各該化鍍鎳凸塊30及各該頂面外護層40。 Step S7: Remove the first photoresist layer 60 from the surface of each seed layer 20 as shown in FIG9 to expose each nickel-plated bump 30 and each top surface outer protective layer 40.

步驟S8:將該晶圓10上未被各該化鍍鎳凸塊30覆蓋的部份各該晶種層20移除如圖10所示。 Step S8: Remove the portions of the seed layer 20 on the wafer 10 that are not covered by the nickel-plated bumps 30 as shown in FIG. 10 .

步驟S9:在該晶圓10之該表面11上覆設一第二光阻層70如圖11所示。 Step S9: A second photoresist layer 70 is formed on the surface 11 of the wafer 10 as shown in FIG. 11 .

步驟S10:在該第二光阻層70上貫穿地鑽孔成型至少一第一盲孔71及至少一第二盲孔72如圖11所示,各該第一盲孔71及各該第二盲孔72係連通至該晶圓10。 Step S10: Drill through the second photoresist layer 70 to form at least one first blind hole 71 and at least one second blind hole 72 as shown in FIG. 11 . Each of the first blind holes 71 and each of the second blind holes 72 are connected to the wafer 10 .

步驟S11:在該晶圓10利用無電解鎳方式在各該第一盲孔71及各該第二盲孔72內利用選自化金製程、或化銀製程之族群中之一製程,以在各該化鍍鎳凸塊30之環側面32上分別形成多個側壁外護層50如圖12所示,各該側壁外護層50與各該化鍍鎳凸塊30電性連結,以使各該側壁外護層50能藉由各該化鍍鎳凸塊30與該晶圓10之各該銲墊12電性連結;其中各該側壁外護層50包含至少一保護層其係選自浸金層、或化銀層之族群中之一種材料所構成。 Step S11: Using electroless nickel in the wafer 10, a process selected from the group of gold plating process or silver plating process is used in each of the first blind holes 71 and the second blind holes 72 to form a plurality of side wall outer protection layers 50 on the annular side surface 32 of each nickel plating bump 30 as shown in FIG. 12. The protective layer 50 is electrically connected to each of the electroless nickel plated bumps 30, so that each of the side wall outer protective layers 50 can be electrically connected to each of the pads 12 of the wafer 10 through each of the electroless nickel plated bumps 30; wherein each of the side wall outer protective layers 50 includes at least one protective layer which is composed of a material selected from the group of immersion gold layer or silver layer.

步驟S12:將該第二光阻層70自該晶圓10之該表面11上移除如圖1所示。 Step S12: Remove the second photoresist layer 70 from the surface 11 of the wafer 10 as shown in FIG1 .

其中,各該化鍍鎳凸塊30之厚度約為2-14微米(μm)但不限制,該浸金(IG)層之厚度約為0.01-0.05微米(μm)但不限制,該厚金(EG)層之厚度約為0.5-2.0微米(μm)但不限制,該化銀(ES)層之厚度約為0.5-2.0微米(μm)但不限制。 Among them, the thickness of each electroless nickel plated bump 30 is about 2-14 micrometers (μm) but not limited, the thickness of the immersion gold (IG) layer is about 0.01-0.05 micrometers (μm) but not limited, the thickness of the thick gold (EG) layer is about 0.5-2.0 micrometers (μm) but not limited, and the thickness of the electroless silver (ES) layer is about 0.5-2.0 micrometers (μm) but not limited.

此外,該化鍍鎳凸塊結構1更是以多個數量進行大量製造後才逐各分切成一個體但不限制如圖17所示。 In addition, the electroless nickel plated bump structure 1 is manufactured in large quantities and then cut into a body one by one, but not limited to that shown in FIG. 17 .

在圖2至7及18中所示的施實例為本發明之第二實施例,在第二實施例中的該化鍍鎳凸塊結構1a包含一晶圓10、多個晶種層(seed layer)20及多個化鍍鎳凸塊30。 The embodiment shown in FIGS. 2 to 7 and 18 is the second embodiment of the present invention. The electroless nickel plated bump structure 1a in the second embodiment includes a wafer 10, a plurality of seed layers 20 and a plurality of electroless nickel plated bumps 30.

該晶圓10其具有一表面11如圖7所示,該表面11上設有多個銲墊12。 The wafer 10 has a surface 11 as shown in FIG. 7 , and a plurality of pads 12 are disposed on the surface 11 .

各該晶種層20係覆蓋地設在該晶圓10之該表面11上並涵蓋於各該銲墊12如圖7所示;其中各該晶種層20係與該晶圓10之各該銲墊12電性連結。 Each of the seed layers 20 is disposed on the surface 11 of the wafer 10 in a covering manner and covers each of the pads 12 as shown in FIG. 7 ; wherein each of the seed layers 20 is electrically connected to each of the pads 12 of the wafer 10 .

各該化鍍鎳凸塊30係利用無電解鎳(electroless nickel,化學電鍍鎳)方式,以在各該晶種層20之表面對應形成至少一具有適當高度及所欲形狀之該化鍍鎳凸塊30如圖7所示;其中各該化鍍鎳凸塊30係與各該晶種層20電性連結。 Each of the electroless nickel plated bumps 30 utilizes electroless nickel (electroless nickel, chemical electroplating nickel) to form at least one electroless nickel plated bump 30 with a suitable height and desired shape on the surface of each of the seed layers 20 as shown in FIG. 7; wherein each of the electroless nickel plated bumps 30 is electrically connected to each of the seed layers 20.

其中,各該化鍍鎳凸塊30的位置及形狀係對應且涵蓋於該晶圓10之各該銲墊12如圖7所示,以使各該化鍍鎳凸塊30能藉由各該晶種層20與各該銲墊12電性連結。 The position and shape of each electroless nickel plated bump 30 correspond to and cover each solder pad 12 of the wafer 10 as shown in FIG. 7 , so that each electroless nickel plated bump 30 can be electrically connected to each solder pad 12 through each seed layer 20 .

此外,該化鍍鎳凸塊結構1a更係由一化鍍鎳凸塊結構製造方法所製成,該化鍍鎳凸塊結構1a製造方法包含下列步驟: In addition, the electroless nickel plated bump structure 1a is manufactured by a method for manufacturing an electroless nickel plated bump structure, and the method for manufacturing an electroless nickel plated bump structure 1a includes the following steps:

步驟S1:提供一晶圓10如圖2所示,該晶圓10具有一表面11,該表面11上設有多個銲墊12。 Step S1: Provide a wafer 10 as shown in FIG2 . The wafer 10 has a surface 11 , and a plurality of pads 12 are disposed on the surface 11 .

步驟S2:在該晶圓10之該表面11上設多個晶種層(seed layer)20如圖3所示,並使各該晶種層20覆蓋地設在該晶圓10之該表面11上並涵蓋於各該銲墊12;其中各該晶種層20係與該晶圓10之各該銲墊12電性連結。 Step S2: multiple seed layers 20 are provided on the surface 11 of the wafer 10 as shown in FIG3, and each seed layer 20 is provided on the surface 11 of the wafer 10 in a covering manner and covers each solder pad 12; wherein each seed layer 20 is electrically connected to each solder pad 12 of the wafer 10.

步驟S3:在各該晶種層20之表面上覆設一第一光阻層60如圖4所示。 Step S3: A first photoresist layer 60 is formed on the surface of each seed layer 20 as shown in FIG4 .

步驟S4:在該第一光阻層60上鑽孔成型至少一盲孔61如圖4所示,各該盲孔61係連通至各該晶種層20。 Step S4: Drill at least one blind hole 61 on the first photoresist layer 60 as shown in FIG. 4 , and each blind hole 61 is connected to each seed layer 20 .

步驟S5:在各該晶種層20利用無電解鎳(electroless nickle)方式在各該盲孔61內對應形成多個以無電解鎳(化鍍鎳)構成之化鍍鎳凸塊30如圖5 所示;其中各該化鍍鎳凸塊30係與各該晶種層20電性連結;其中各該化鍍鎳凸塊30的位置及形狀係對應且涵蓋於該晶圓10之各該銲墊12,以使各該化鍍鎳凸塊30能藉由各該晶種層20與各該銲墊12電性連結。 Step S5: A plurality of electroless nickel bumps 30 made of electroless nickel (electroless nickel) are formed in each blind hole 61 in each seed layer 20 by using an electroless nickel (electroless nickel) method as shown in FIG. 5 ; wherein each electroless nickel bump 30 is electrically connected to each seed layer 20 ; wherein the position and shape of each electroless nickel bump 30 correspond to and cover each solder pad 12 of the wafer 10 , so that each electroless nickel bump 30 can be electrically connected to each solder pad 12 through each seed layer 20 .

步驟S6:將該第一光阻層60自各該晶種層20之表面上移除如圖6所示,以凸露出各該化鍍鎳凸塊30。 Step S6: Remove the first photoresist layer 60 from the surface of each seed layer 20 as shown in FIG6 to expose each nickel-plated bump 30.

步驟S7:將該晶圓10上未被各該化鍍鎳凸塊30覆蓋的部份各該晶種層20移除如圖7所示。 Step S7: remove the portions of the seed layer 20 on the wafer 10 that are not covered by the nickel-plated bumps 30 as shown in FIG. 7 .

其中,各該化鍍鎳凸塊30之厚度約為2-14微米(μm)但不限制。 The thickness of each electroless nickel plated bump 30 is about 2-14 micrometers (μm) but is not limited.

此外,該化鍍鎳凸塊結構1a更是以多個數量進行大量製造後才逐各分切成一個體但不限制如圖18所示。 In addition, the electroless nickel plated bump structure 1a is manufactured in large quantities and then cut into a body one by one, but not limited to that shown in FIG. 18 .

在圖2至5、8至10及19中所示的施實例為本發明之第三實施例,在第三實施例中的該化鍍鎳凸塊結構1b包含一晶圓10、多個晶種層(seed layer)20、多個化鍍鎳凸塊30及多個頂面外護層40。 The embodiment shown in Figures 2 to 5, 8 to 10 and 19 is the third embodiment of the present invention. The electroless nickel plated bump structure 1b in the third embodiment includes a wafer 10, a plurality of seed layers 20, a plurality of electroless nickel plated bumps 30 and a plurality of top surface outer protective layers 40.

該晶圓10具有一表面11如圖10所示,該表面11上設有多個銲墊12。 The wafer 10 has a surface 11 as shown in FIG. 10 , and a plurality of pads 12 are disposed on the surface 11 .

各該晶種層20係覆蓋地設在該晶圓10之該表面11上並涵蓋於各該銲墊12如圖10所示;其中各該晶種層20係與該晶圓10之各該銲墊12電性連結。 Each of the seed layers 20 is disposed on the surface 11 of the wafer 10 in a covering manner and covers each of the pads 12 as shown in FIG. 10 ; wherein each of the seed layers 20 is electrically connected to each of the pads 12 of the wafer 10 .

各該化鍍鎳凸塊30係利用無電解鎳(electroless nickel,化學電鍍鎳)方式如圖10所示,以在各該晶種層20之表面對應形成至少一具有適當高度及所欲形狀之該化鍍鎳凸塊30;其中各該化鍍鎳凸塊30係與各該晶種層20電性連結;其中各該化鍍鎳凸塊30的位置及形狀係對應且涵蓋於該晶圓10之各該銲墊12,以使各該化鍍鎳凸塊30能藉由各該晶種層20與各該銲墊12電性連結。 Each of the electroless nickel bumps 30 is formed by electroless nickel (electroless nickel, chemical nickel plating) as shown in FIG10, so as to form at least one electroless nickel bump 30 with a suitable height and a desired shape on the surface of each of the seed layers 20; wherein each of the electroless nickel bumps 30 is electrically connected to each of the seed layers 20; wherein the position and shape of each of the electroless nickel bumps 30 correspond to and cover each of the pads 12 of the wafer 10, so that each of the electroless nickel bumps 30 can be electrically connected to each of the pads 12 through each of the seed layers 20.

各該頂面外護層40係分別對應設在各該化鍍鎳凸塊30之頂面31上並與各該化鍍鎳凸塊30電性連結如圖10所示,以使各該頂面外護層40能藉由各 該化鍍鎳凸塊30與該晶圓10之各該銲墊12電性連結,且各該頂面外護層40的位置及形狀係對應且涵蓋於該晶圓10之各該銲墊12;其中各該頂面外護層40係選自浸金(IG)層、或化銀(ES)層之族群中一種材料所構成,並利用選自化金製程、或化銀製程之族群中一製程以在各該化鍍鎳凸塊30之頂面31形成各該頂面外護層40。 Each of the top surface outer protective layers 40 is respectively disposed on the top surface 31 of each of the electroless nickel plated bumps 30 and is electrically connected to each of the electroless nickel plated bumps 30 as shown in FIG. 10 , so that each of the top surface outer protective layers 40 can be electrically connected to each of the pads 12 of the wafer 10 through each of the electroless nickel plated bumps 30, and the position and shape of each of the top surface outer protective layers 40 are Corresponding to and covering each of the pads 12 of the wafer 10; wherein each of the top surface outer protective layers 40 is composed of a material selected from the group of immersion gold (IG) layer or silver (ES) layer, and a process selected from the group of gold process or silver process is used to form each of the top surface outer protective layers 40 on the top surface 31 of each of the nickel plated bumps 30.

此外,該化鍍鎳凸塊結構1b更係由一化鍍鎳凸塊結構製造方法所製成,該化鍍鎳凸塊結構1b製造方法包含下列步驟: In addition, the electroless nickel plated bump structure 1b is manufactured by a method for manufacturing an electroless nickel plated bump structure, and the method for manufacturing an electroless nickel plated bump structure 1b includes the following steps:

步驟S1:提供一晶圓10如圖2所示,該晶圓10具有一表面11,該表面11上設有多個銲墊12。 Step S1: Provide a wafer 10 as shown in FIG2 . The wafer 10 has a surface 11 , and a plurality of pads 12 are disposed on the surface 11 .

步驟S2:在該晶圓10之該表面11上設多個晶種層(seed layer)20如圖3所示,並使各該晶種層20覆蓋地設在該晶圓10之該表面11上並涵蓋於各該銲墊12;其中各該晶種層20係與該晶圓10之各該銲墊12電性連結。 Step S2: multiple seed layers 20 are provided on the surface 11 of the wafer 10 as shown in FIG3, and each seed layer 20 is provided on the surface 11 of the wafer 10 in a covering manner and covers each solder pad 12; wherein each seed layer 20 is electrically connected to each solder pad 12 of the wafer 10.

步驟S3:在各該晶種層20之表面上覆設一第一光阻層60如圖4所示。 Step S3: A first photoresist layer 60 is formed on the surface of each seed layer 20 as shown in FIG4 .

步驟S4:在該第一光阻層60上鑽孔成型至少一盲孔61如圖4所示,各該盲孔61係連通至各該晶種層20。 Step S4: Drill at least one blind hole 61 on the first photoresist layer 60 as shown in FIG. 4 , and each blind hole 61 is connected to each seed layer 20 .

步驟S5:在各該晶種層20利用無電解鎳(electroless nickle)方式在各該盲孔61內對應形成多個以無電解鎳(化鍍鎳)構成之化鍍鎳凸塊30如圖5所示;其中各該化鍍鎳凸塊30係與各該晶種層20電性連結;其中各該化鍍鎳凸塊30的位置及形狀係對應且涵蓋於該晶圓10之各該銲墊12,以使各該化鍍鎳凸塊30能藉由各該晶種層20與各該銲墊12電性連結。 Step S5: A plurality of electroless nickel bumps 30 made of electroless nickel (electroless nickel) are formed in each blind hole 61 in each seed layer 20 by an electroless nickel method as shown in FIG. 5 ; wherein each electroless nickel bump 30 is electrically connected to each seed layer 20 ; wherein the position and shape of each electroless nickel bump 30 correspond to and cover each solder pad 12 of the wafer 10 , so that each electroless nickel bump 30 can be electrically connected to each solder pad 12 through each seed layer 20 .

步驟S6:利用選自化金製程、或化銀製程之族群中之一製程,以在各該化鍍鎳凸塊30之頂面上分別形成多個頂面外護層40與各該化鍍鎳凸塊30對應如圖8所示,各該頂面外護層40與各該化鍍鎳凸塊30電性連結,以使各該頂 面外護層40能藉由各該化鍍鎳凸塊30與該晶圓10之各該銲墊12電性連結,且各該頂面外護層40的位置及形狀係對應且涵蓋於該晶圓10之各該銲墊12;其中各該頂面外護層40係選自浸金層、或化銀層之族群中之一種材料所構成。 Step S6: Using a process selected from the group of gold plating process or silver plating process, a plurality of top surface outer protective layers 40 are formed on the top surface of each of the nickel plating bumps 30, and each of the nickel plating bumps 30 corresponds to each of the nickel plating bumps 30 as shown in FIG. 8. Each of the top surface outer protective layers 40 is electrically connected to each of the nickel plating bumps 30, so that each of the top surface outer protective layers 40 is electrically connected to each of the nickel plating bumps 30. The protective layer 40 can be electrically connected to each of the pads 12 of the wafer 10 through each of the electroless nickel-plated bumps 30, and the position and shape of each of the top surface outer protective layers 40 correspond to and cover each of the pads 12 of the wafer 10; wherein each of the top surface outer protective layers 40 is composed of a material selected from the group of immersion gold layer or electroless silver layer.

步驟S7:將該第一光阻層60自各該晶種層20之表面上移除如圖9所示,以凸露出各該化鍍鎳凸塊30及各該頂面外護層40。 Step S7: Remove the first photoresist layer 60 from the surface of each seed layer 20 as shown in FIG9 to expose each nickel-plated bump 30 and each top surface outer protective layer 40.

步驟S8:將該晶圓10上未被各該化鍍鎳凸塊30覆蓋的部份各該晶種層20移除如圖10所示。 Step S8: Remove the portions of the seed layer 20 on the wafer 10 that are not covered by the nickel-plated bumps 30 as shown in FIG. 10 .

其中,各該化鍍鎳凸塊30之厚度約為2-14微米(μm)但不限制,該浸金(IG)層之厚度約為0.01-0.05微米(μm)但不限制,該厚金(EG)層之厚度約為0.5-2.0微米(μm)但不限制,該化銀(ES)層之厚度約為0.5-2.0微米(μm)但不限制。 Among them, the thickness of each electroless nickel plated bump 30 is about 2-14 micrometers (μm) but not limited, the thickness of the immersion gold (IG) layer is about 0.01-0.05 micrometers (μm) but not limited, the thickness of the thick gold (EG) layer is about 0.5-2.0 micrometers (μm) but not limited, and the thickness of the electroless silver (ES) layer is about 0.5-2.0 micrometers (μm) but not limited.

此外,該化鍍鎳凸塊結構1b更是以多個數量進行大量製造後才逐各分切成一個體但不限制如圖19所示。 In addition, the electroless nickel plated bump structure 1b is manufactured in large quantities and then cut into a body one by one, but not limited to that shown in FIG. 19 .

在圖2至5、13至16中所示的施實例為本發明之第四實施例,在第四實施例中的該化鍍鎳凸塊結構1c包含一晶圓10、多個晶種層(seed layer)20、多個化鍍鎳凸塊30、多個頂面外護層40及多個側壁外護層50。 The embodiment shown in Figures 2 to 5 and 13 to 16 is the fourth embodiment of the present invention. The electroless nickel plated bump structure 1c in the fourth embodiment includes a wafer 10, a plurality of seed layers 20, a plurality of electroless nickel plated bumps 30, a plurality of top surface outer protective layers 40 and a plurality of side wall outer protective layers 50.

該晶圓10具有一表面11如圖16所示,該表面11上設有多個銲墊12。 The wafer 10 has a surface 11 as shown in FIG16 , and a plurality of pads 12 are disposed on the surface 11 .

各該晶種層20係覆蓋地設在該晶圓10之該表面11上並涵蓋於各該銲墊12如圖16所示;其中各該晶種層20係與該晶圓10之各該銲墊12電性連結。 Each of the seed layers 20 is disposed on the surface 11 of the wafer 10 in a covering manner and covers each of the pads 12 as shown in FIG. 16 ; wherein each of the seed layers 20 is electrically connected to each of the pads 12 of the wafer 10 .

各該化鍍鎳凸塊30係利用無電解鎳(electroless nickel,化學電鍍鎳)方式,以在各該晶種層20之表面對應形成至少一具有適當高度及所欲形狀之該化鍍鎳凸塊30如圖16所示;其中各該化鍍鎳凸塊30係與各該晶種層20電性連 結;其中各該化鍍鎳凸塊30的位置及形狀係對應且涵蓋於該晶圓10之各該銲墊12,以使各該化鍍鎳凸塊30能藉由各該晶種層20與各該銲墊12電性連結。 Each of the electroless nickel bumps 30 is formed by electroless nickel (electroless nickel, chemical nickel plating) on the surface of each of the seed layers 20 to form at least one electroless nickel bump 30 with a suitable height and a desired shape as shown in FIG. 16 ; wherein each of the electroless nickel bumps 30 is electrically connected to each of the seed layers 20 ; wherein the position and shape of each of the electroless nickel bumps 30 correspond to and cover each of the pads 12 of the wafer 10 , so that each of the electroless nickel bumps 30 can be electrically connected to each of the pads 12 through each of the seed layers 20 .

各該頂面外護層40係分別對應設在各該化鍍鎳凸塊30之頂面31上並與各該化鍍鎳凸塊30電性連結如圖16所示,以使各該頂面外護層40能藉由各該化鍍鎳凸塊30與該晶圓10之各該銲墊12電性連結,且各該頂面外護層40的位置及形狀係對應且涵蓋於該晶圓10之各該銲墊12;其中各該頂面外護層40係選自浸金(IG)層、或化銀(ES)層之族群中一種材料所構成,並利用選自化金製程、或化銀製程之族群中一製程以在各該化鍍鎳凸塊30之頂面31形成各該頂面外護層40。 Each of the top surface outer protective layers 40 is disposed on the top surface 31 of each of the electroless nickel plated bumps 30 and is electrically connected to each of the electroless nickel plated bumps 30 as shown in FIG. 16 , so that each of the top surface outer protective layers 40 can be electrically connected to each of the pads 12 of the wafer 10 through each of the electroless nickel plated bumps 30, and the position and shape of each of the top surface outer protective layers 40 are Corresponding to and covering each of the pads 12 of the wafer 10; wherein each of the top surface outer protective layers 40 is composed of a material selected from the group of immersion gold (IG) layer or silver (ES) layer, and a process selected from the group of gold process or silver process is used to form each of the top surface outer protective layers 40 on the top surface 31 of each of the nickel plated bumps 30.

各該側壁外護層50係分別設在各該化鍍鎳凸塊30之環側面32上並與各該化鍍鎳凸塊30電性連結如圖16所示,以使各該側壁外護層50能藉由各該化鍍鎳凸塊30與該晶圓10之各該銲墊12電性連結;其中各該側壁外護層50係包含至少一選自浸金(IG)層、或化銀(ES)層之族群中一種材料所構成之保護層,並利用選自化金製程、或化銀製程之族群中一製程以在各該化鍍鎳凸塊30之環側面32上分別形成各該側壁外護層50。 Each of the side wall outer protective layers 50 is disposed on the annular side surface 32 of each of the electroless nickel plated bumps 30 and is electrically connected to each of the electroless nickel plated bumps 30 as shown in FIG. 16 , so that each of the side wall outer protective layers 50 can be electrically connected to each of the pads 12 of the wafer 10 through each of the electroless nickel plated bumps 30; wherein each of the side wall outer protective layers 50 is electrically connected to each of the pads 12 of the wafer 10 through each of the electroless nickel plated bumps 30. The outer protective layer 50 includes at least one protective layer made of a material selected from the group of immersion gold (IG) layers or silver electroplating (ES) layers, and uses a process selected from the group of gold electroplating processes or silver electroplating processes to form each of the sidewall outer protective layers 50 on the annular side surface 32 of each of the electroplated nickel bumps 30.

其中,各該化鍍鎳凸塊30在其頂面31上所形成之各該頂面外護層40與在其環側面32上所形成之各該側壁外護層50係完全密合地包覆在各該化鍍鎳凸塊30之外表面如圖16所示,以形成一完整的外護層。 Among them, each top surface outer protective layer 40 formed on the top surface 31 of each electroless nickel plated bump 30 and each side wall outer protective layer 50 formed on the surrounding side surface 32 are completely and tightly covered on the outer surface of each electroless nickel plated bump 30 as shown in FIG. 16 to form a complete outer protective layer.

而且,各該頂面外護層40及各該側壁外護層50更係以同一製程形成,且係利用選自化金製程、或化銀製程之族群中一製程以同時地形成在各該化鍍鎳凸塊30之頂面31及環側面32上如圖16所示。 Moreover, each of the top surface outer protective layers 40 and each of the side wall outer protective layers 50 are formed by the same process, and are formed simultaneously on the top surface 31 and the surrounding side surface 32 of each of the electroless nickel plated bumps 30 by a process selected from the group of electroless gold process or electroless silver process, as shown in FIG. 16 .

此外,該化鍍鎳凸塊結構1c更係由一化鍍鎳凸塊結構製造方法所製成,該化鍍鎳凸塊結構1c製造方法包含下列步驟: In addition, the electroless nickel plated bump structure 1c is manufactured by a method for manufacturing an electroless nickel plated bump structure, and the method for manufacturing an electroless nickel plated bump structure 1c includes the following steps:

步驟S1:提供一晶圓10如圖2所示,該晶圓10具有一表面11,該表面11上設有多個銲墊12。 Step S1: Provide a wafer 10 as shown in FIG2 . The wafer 10 has a surface 11 , and a plurality of pads 12 are disposed on the surface 11 .

步驟S2:在該晶圓10之該表面11上設多個晶種層(seed layer)20如圖3所示,並使各該晶種層20覆蓋地設在該晶圓10之該表面11上並涵蓋於各該銲墊12;其中各該晶種層20係與該晶圓10之各該銲墊12電性連結。 Step S2: multiple seed layers 20 are provided on the surface 11 of the wafer 10 as shown in FIG3, and each seed layer 20 is provided on the surface 11 of the wafer 10 in a covering manner and covers each solder pad 12; wherein each seed layer 20 is electrically connected to each solder pad 12 of the wafer 10.

步驟S3:在各該晶種層20之表面上覆設一第一光阻層60如圖4所示。 Step S3: A first photoresist layer 60 is formed on the surface of each seed layer 20 as shown in FIG4 .

步驟S4:在該第一光阻層60上鑽孔成型至少一盲孔61如圖4所示,各該盲孔61係連通至各該晶種層20。 Step S4: Drill at least one blind hole 61 on the first photoresist layer 60 as shown in FIG. 4 , and each blind hole 61 is connected to each seed layer 20 .

步驟S5:在各該晶種層20利用無電解鎳(electroless nickle)方式在各該盲孔61內對應形成多個以無電解鎳(化鍍鎳)構成之化鍍鎳凸塊30如圖5所示;其中各該化鍍鎳凸塊30係與各該晶種層20電性連結;其中各該化鍍鎳凸塊30的位置及形狀係對應且涵蓋於該晶圓10之各該銲墊12,以使各該化鍍鎳凸塊30能藉由各該晶種層20與各該銲墊12電性連結。 Step S5: A plurality of electroless nickel bumps 30 made of electroless nickel (electroless nickel) are formed in each blind hole 61 in each seed layer 20 by an electroless nickel method as shown in FIG. 5 ; wherein each electroless nickel bump 30 is electrically connected to each seed layer 20 ; wherein the position and shape of each electroless nickel bump 30 correspond to and cover each solder pad 12 of the wafer 10 , so that each electroless nickel bump 30 can be electrically connected to each solder pad 12 through each seed layer 20 .

步驟S6:在該第一光阻層60上貫穿地鑽孔成型至少一第一溝槽62及至少一第二溝槽63如圖13所示,且各該第一溝槽62及各該第二溝槽63更係貫穿各該晶種層20而連通至該晶圓10;其中各該第一溝槽62及各該第二溝槽63係位於各該化鍍鎳凸塊30的環側面32處;。 Step S6: drilling holes through the first photoresist layer 60 to form at least one first trench 62 and at least one second trench 63 as shown in FIG. 13, and each of the first trenches 62 and each of the second trenches 63 penetrates each of the seed layers 20 and connects to the wafer 10; wherein each of the first trenches 62 and each of the second trenches 63 is located at the circumferential side surface 32 of each of the electroless nickel-plated bumps 30;.

步驟S7:利用選自化金製程、或化銀製程之族群中之一製程,以在各該化鍍鎳凸塊30之頂面31及環側面32上分別形成至少一頂面外護層40及多個側壁外護層50如圖14所示,其中各該頂面外護層40及各該側壁外護層50包含至少一保護層其係選自浸金層、或化銀層之族群中之一種材料所構成,使各該頂面外護層40與在其環側面32上所形成之各該側壁外護層50係完全密合地包覆在各該化鍍鎳凸塊30之外表面,以形成一完整的外護層;其中各該頂面外護層40 及各該側壁外護層50與各該化鍍鎳凸塊30電性連結,以使各該頂面外護層40及各該側壁外護層50能藉由各該化鍍鎳凸塊30與該晶圓10之各該銲墊12電性連結。 Step S7: Using a process selected from the group of gold immersion processes or silver immersion processes, at least one top surface outer protective layer 40 and a plurality of side wall outer protective layers 50 are formed on the top surface 31 and the surrounding side surface 32 of each of the nickel plated bumps 30, as shown in FIG. 14, wherein each of the top surface outer protective layers 40 and each of the side wall outer protective layers 50 includes at least one protective layer which is selected from the group of gold immersion layers or silver immersion layers. 0 and each of the side wall outer protective layers 50 formed on its annular side surface 32 completely and tightly cover the outer surface of each of the electroless nickel plated bumps 30 to form a complete outer protective layer; wherein each of the top surface outer protective layers 40 and each of the side wall outer protective layers 50 are electrically connected to each of the electroless nickel plated bumps 30, so that each of the top surface outer protective layers 40 and each of the side wall outer protective layers 50 can be electrically connected to each of the pads 12 of the wafer 10 through each of the electroless nickel plated bumps 30.

步驟S8:將該第一光阻層60自各該晶種層20之表面上移除如圖15所示。 Step S8: Remove the first photoresist layer 60 from the surface of each seed layer 20 as shown in FIG. 15 .

步驟S9:將該晶圓10上未被各該化鍍鎳凸塊30覆蓋的部份各該晶種層20移除如圖16所示。 Step S9: remove the portions of the seed layer 20 on the wafer 10 that are not covered by the nickel-plated bumps 30 as shown in FIG. 16 .

其中,各該化鍍鎳凸塊30之厚度約為2-14微米(μm)但不限制,該浸金(IG)層之厚度約為0.01-0.05微米(μm)但不限制,該厚金(EG)層之厚度約為0.5-2.0微米(μm)但不限制,該化銀(ES)層之厚度約為0.5-2.0微米(μm)但不限制。 Among them, the thickness of each electroless nickel plated bump 30 is about 2-14 micrometers (μm) but not limited, the thickness of the immersion gold (IG) layer is about 0.01-0.05 micrometers (μm) but not limited, the thickness of the thick gold (EG) layer is about 0.5-2.0 micrometers (μm) but not limited, and the thickness of the electroless silver (ES) layer is about 0.5-2.0 micrometers (μm) but not limited.

此外,該化鍍鎳凸塊結構1b更是以多個數量進行大量製造後才逐各分切成一個體但不限制(圖未示)。 In addition, the electroless nickel plated bump structure 1b is mass-produced in multiple quantities before being cut into individual pieces one by one, but there is no limit (not shown).

以上該僅為本發明的優選實施例,對本發明而言僅係說明性的,而非限制性的;本領域普通技術人員理解,在本發明權利要求所限定的精神和範圍內可對其進行許多改變,修改,甚至等效變更,但都將落入本發明的保護範圍內。 The above are only preferred embodiments of the present invention, which are only illustrative and not restrictive. A person skilled in the art will understand that many changes, modifications, and even equivalent changes can be made within the spirit and scope defined by the claims of the present invention, but they will all fall within the scope of protection of the present invention.

1:化鍍鎳凸塊結構 1: Chemically plated nickel bump structure

10:晶圓 10: Wafer

11:表面 11: Surface

12:銲墊 12: Welding pad

20:晶種層 20: Seed layer

30:化鍍鎳凸塊 30: Electroless nickel plated bumps

31:頂面 31: Top

40:頂面外護層 40: Top outer protective layer

50:側壁外護層 50: Side wall outer protective layer

Claims (1)

一種晶圓銲墊之化鍍鎳凸塊結構之製造方法,其包含:步驟S1:提供一晶圓,該晶圓具有一表面,該表面上設有多個銲墊;步驟S2:在該晶圓之該表面上設多個晶種層(seed layer),並使各該晶種層覆蓋地設在該晶圓之該表面上並涵蓋於各該銲墊;其中各該晶種層係與該晶圓之各該銲墊電性連結;步驟S3:在各該晶種層之表面上覆設一第一光阻層;步驟S4:在該第一光阻層上鑽孔成型至少一盲孔,各該盲孔係連通至各該晶種層;步驟S5:在各該晶種層利用無電解鎳(electroless nickle)方式在該第一光阻層的各該盲孔內對應形成多個以無電解鎳(化鍍鎳)構成之厚度約為2-14微米(μm)的化鍍鎳凸塊;其中各該化鍍鎳凸塊係與各該晶種層電性連結;其中各該化鍍鎳凸塊的位置及形狀係對應且涵蓋於該晶圓之各該銲墊,以使各該化鍍鎳凸塊能藉由各該晶種層與各該銲墊電性連結;步驟S6:在該第一光阻層上貫穿地形成至少一第一溝槽及至少一第二溝槽,且各該第一溝槽及各該第二溝槽更係貫穿各該晶種層而連通至該晶圓;其中各該第一溝槽及各該第二溝槽係位於各該化鍍鎳凸塊的環側面處;步驟S7:利用選自化金製程、或化銀製程之族群中之一製程,以在各該化鍍鎳凸塊之頂面及環側面上分別形成至少一頂面外護層及多個側壁外護層,其中各該頂面外護層及各該側壁外護層包含至少一保護層其係選自厚度約為0.01-0.05微米(μm)的浸金層、厚度約為0.5-2.0微米(μm)的厚金層、或厚度約為0.5-2.0微米(μm)的化銀層之族群中之一種材料所構成,使各該頂面外護層與在其環側面上所形成之各該側壁外護層係完全密合地包覆在各該化鍍鎳凸塊之外表 面,以形成一完整的外護層;其中各該頂面外護層及各該側壁外護層與各該化鍍鎳凸塊電性連結,以使各該頂面外護層及各該側壁外護層能藉由各該化鍍鎳凸塊與該晶圓之各該銲墊電性連結;步驟S8:將該第一光阻層自各該晶種層之表面上移除;及步驟S9:將該晶圓上未被各該化鍍鎳凸塊覆蓋的部份各該晶種層移除。 A method for manufacturing a nickel-plated bump structure of a wafer pad comprises: step S1: providing a wafer, the wafer having a surface, and a plurality of pads are disposed on the surface; step S2: disposing a plurality of seed layers on the surface of the wafer Step S3: a first photoresist layer is formed on the surface of each of the seed layers; Step S4: at least one blind hole is formed on the first photoresist layer, and each of the blind holes is connected to each of the seed layers; Step S5: electroless nickel is used to form a hole in each of the seed layers; Step S6: a first photoresist layer is formed on the surface of each of the seed layers; Step S7: at least one blind hole is formed on the first photoresist layer; Step S8: at least one blind hole is formed on each of the seed layers; Step S9: at least one blind hole is formed on each of the seed layers; Step S10: at least one blind hole is formed on each of the seed layers; Step S11: at least one blind hole is formed on each of the seed layers; Step S12: at least one blind hole is formed on each of the seed layers; Step S13: at least one blind hole is formed on each of the seed layers; Step S14: at least one blind hole is formed on each of the seed layers; Step S15: at least one blind hole is formed on each of the seed layers; Step S16: at least one blind hole is formed on each of the seed layers; Step S17: at least one blind hole is formed on each of the seed layers; Step S18: at least one blind hole is formed on each of the seed layers; Step S19 ...2: at least one blind hole is formed on each of the seed layers; Step S13: at least one blind hole is formed on each of the seed layers; Step S14: at least one blind hole is formed on each of the seed layers; Step S15: at least one blind hole is formed on each of the seed layers; Step S16: at least one blind hole is formed on each of the A plurality of electroless nickel (electroless nickel) electroless nickel bumps having a thickness of about 2-14 micrometers (μm) are formed in the blind holes of the first photoresist layer by a nickel-nickel method; wherein each of the electroless nickel bumps is electrically connected to each of the seed layers; wherein the position and shape of each of the electroless nickel bumps correspond to and cover each of the pads of the wafer, so that each of the electroless nickel bumps can be electrically connected to each of the pads through each of the seed layers; step S6: in the first At least one first trench and at least one second trench are formed through the photoresist layer, and each of the first trench and each of the second trenches further penetrates each of the seed layers and is connected to the wafer; wherein each of the first trench and each of the second trenches is located at the peripheral side surface of each of the electroless nickel plated bumps; step S7: using a process selected from the group of electroless gold process or electroless silver process to form at least one top surface outer protective layer and a plurality of side wall outer protective layers on the top surface and the peripheral side surface of each of the electroless nickel plated bumps The top outer protective layer and the side wall outer protective layer each include at least one protective layer selected from a group consisting of an immersion gold layer with a thickness of about 0.01-0.05 micrometers (μm), a thick gold layer with a thickness of about 0.5-2.0 micrometers (μm), or a silver layer with a thickness of about 0.5-2.0 micrometers (μm), so that each top outer protective layer and each side wall outer protective layer formed on the surrounding side surface are completely and tightly coated on each silver layer. The outer surface of the nickel plated bump is plated to form a complete outer protective layer; wherein each of the top outer protective layer and each of the side wall outer protective layer is electrically connected to each of the nickel plated bumps, so that each of the top outer protective layer and each of the side wall outer protective layer can be electrically connected to each of the pads of the wafer through each of the nickel plated bumps; step S8: removing the first photoresist layer from the surface of each of the seed layers; and step S9: removing the portion of each of the seed layers on the wafer that is not covered by each of the nickel plated bumps.
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