TWI811111B - Method of battery cell voltage dynamic regulation - Google Patents
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- 238000000034 method Methods 0.000 title claims abstract description 28
- 230000008961 swelling Effects 0.000 claims abstract description 109
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- 238000012360 testing method Methods 0.000 claims description 16
- 238000004519 manufacturing process Methods 0.000 claims description 14
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- 206010000060 Abdominal distension Diseases 0.000 description 4
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- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
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- 229910020599 Co 3 O 4 Inorganic materials 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02E60/10—Energy storage using batteries
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Abstract
Description
本發明係有關一種電池電壓動態調降方法,尤指一種電子裝置的電池電壓動態調降方法。 The invention relates to a method for dynamically lowering the battery voltage, in particular to a method for dynamically lowering the battery voltage of an electronic device.
現今電子裝置之應用越來越普遍,尤其是內含電池的電子裝置更是廣泛應用。其原因在於,這類電子裝置通常具有輕巧、攜帶方便,且具有長時間續航的特性。然而,這類電子裝置所搭配的電池通常為鋰電池,其缺點在於長時間的使用後,容易會發生電池鼓脹的狀況。尤其在使用者行為較為極端之情況下,鼓脹發生的時間將會大幅度的縮短。以圖1為例為使用者行為示意圖,當使用者正常狀況的使用時,電池通常可以在保固期內仍然低於預設的鼓脹率上限。然而,當使用者行為較為極端之情況下(例如但不限於邊充電邊使用高耗能操作),則極有可能使得電池無法於保固期內仍然低於預設的鼓脹率上限。 Nowadays, the application of electronic devices is becoming more and more common, especially the electronic devices with built-in batteries are widely used. The reason is that such electronic devices are usually lightweight, portable, and have the characteristics of long battery life. However, the batteries used in such electronic devices are usually lithium batteries. The disadvantage is that the battery is prone to bulge after a long period of use. Especially in the case of extreme user behavior, the time for swelling will be greatly shortened. Taking FIG. 1 as an example for a user behavior diagram, when the user uses it under normal conditions, the battery can usually still be lower than the preset upper limit of swelling rate within the warranty period. However, when the user's behavior is relatively extreme (such as but not limited to using high energy consumption while charging), it is very likely that the battery will not be able to remain below the preset upper limit of swelling rate during the warranty period.
其中,目前既有的電池鼓脹偵測方法,不外乎使用額外的壓力、位移量及/或鼓脹力感測器。這種偵測方式必須要額外的增加元件成本以及元件電力消耗,無法降低電子裝置的製造成本。此外,習知的技術通常會使用電池 降壓的機制,來延後電池鼓脹率到達預設的鼓脹率上限。然而,目前既有的降壓機制,於特定條件下固定時間內進行降壓,藉此保護電芯,避免鼓脹發生。但是固定的降壓模式,無法有效防止鼓脹發生,尤其是當使用者行為較為極端之情況。 Among them, the current existing battery swelling detection method is nothing more than using additional pressure, displacement and/or swelling force sensors. This detection method must increase the component cost and component power consumption, and cannot reduce the manufacturing cost of the electronic device. Additionally, known technologies typically use batteries The mechanism of voltage reduction is used to delay the battery swelling rate from reaching the preset upper limit of swelling rate. However, the existing depressurization mechanism currently depresses the voltage for a fixed period of time under specific conditions, thereby protecting the battery cells and avoiding swelling. However, the fixed depressurization mode cannot effectively prevent the occurrence of bloating, especially when the user's behavior is relatively extreme.
所以,如何設計出一種電子裝置的電池電壓動態調降方法,以免除額外的增加元件成本以及元件電力消耗,且避免使用者行為較為極端之情況而無法有效防止鼓脹發生,乃為本案創作人所欲行研究的一大課題。 Therefore, how to design a method for dynamically lowering the battery voltage of an electronic device, so as to avoid additional component cost and component power consumption, and to avoid the situation where the user's behavior is more extreme and cannot effectively prevent the occurrence of swelling, is the creator of this case. A great topic for research.
為了解決上述問題,本發明係提供一種電池電壓動態調降方法,以克服習知技術的問題。因此,本發明電池電壓動態調降方法係用以設定電子裝置的電池的充電門檻電壓,且電池電壓動態調降方法包括下列步驟:(a)設定特定鼓脹率,且通過鼓脹速率演算式取得電池的鼓脹率到達特定鼓脹率的特定鼓脹速率演算式。(b)基於鼓脹率演算式取得電壓變數影響指數曲線與溫度變數影響指數曲線。(c)設定基礎工作電壓及基礎工作溫度,且取得於基礎工作電壓及基礎工作溫度條件下,鼓脹率到達特定鼓脹率的達標時間。(d)通過電壓感測器與溫度感測器分別偵測電池的實際工作電壓與實際工作溫度,且計數電池於不同的實際工作電壓及實際工作溫度下的複數個累計時間。(e)通過電壓變數影響指數曲線分別換算該些實際工作電壓與基礎工作電壓的複數個電壓倍率值,且通過溫度變數影響指數曲線分別換算該些實際工作溫度與基礎工作溫度的複數個溫度倍率值。(f)通過該些電壓倍率值、該些溫度倍率值及該些累計時間計算複數個等效時間,且加總該些等效時間為總等效時間。(g)通過總等效時間與 達標時間取得電池當前的鼓脹指數。(h)通過鼓脹指數判斷是否調降充電門檻電壓。 In order to solve the above problems, the present invention provides a method for dynamically lowering the battery voltage to overcome the problems of the prior art. Therefore, the battery voltage dynamic lowering method of the present invention is used to set the charging threshold voltage of the battery of the electronic device, and the battery voltage dynamic lowering method includes the following steps: (a) setting a specific swelling rate, and obtaining the battery through the swelling rate calculation formula The specific inflation rate calculation formula for the inflation rate to reach the specific inflation rate. (b) The voltage variable influence index curve and the temperature variable influence index curve are obtained based on the swelling rate calculation formula. (c) Set the basic working voltage and the basic working temperature, and obtain the attainment time for the swelling rate to reach the specified swelling rate under the conditions of the basic working voltage and the basic working temperature. (d) Detecting the actual operating voltage and actual operating temperature of the battery through the voltage sensor and the temperature sensor respectively, and counting a plurality of accumulative times of the battery under different actual operating voltages and actual operating temperatures. (e) Convert the complex voltage multiplication values of the actual working voltage and the basic working voltage through the voltage variable influence index curve, and respectively convert the complex number of temperature multipliers of the actual working temperature and the basic working temperature through the temperature variable influence exponential curve value. (f) Calculating a plurality of equivalent times through the voltage multiplier values, the temperature multiplier values and the accumulated times, and summing up the equivalent times to form the total equivalent time. (g) by total equivalent time and Get the current inflation index of the battery at the standard time. (h) Judging whether to lower the charging threshold voltage according to the swelling index.
本發明之主要目的及功效在於,通過控制器利用電池的電壓及溫度來估測電池的鼓脹指數,且基電池的鼓脹指數來動態的調降電池的電壓,達到降低鼓脹發生的狀況,並提供使用者較佳之用戶體驗及用戶安全。 The main purpose and function of the present invention is to use the voltage and temperature of the battery to estimate the swelling index of the battery through the controller, and dynamically lower the voltage of the battery based on the swelling index of the battery to reduce the occurrence of swelling and provide Better user experience and user security for users.
為了能更進一步瞭解本發明為達成預定目的所採取之技術、手段及功效,請參閱以下有關本發明之詳細說明與附圖,相信本發明之目的、特徵與特點,當可由此得一深入且具體之瞭解,然而所附圖式僅提供參考與說明用,並非用來對本發明加以限制者。 In order to further understand the technology, means and effects that the present invention adopts to achieve the predetermined purpose, please refer to the following detailed description and accompanying drawings of the present invention. It is believed that the purpose, characteristics and characteristics of the present invention can be obtained from this in depth and For specific understanding, however, the accompanying drawings are provided for reference and illustration only, and are not intended to limit the present invention.
100:電子裝置 100: Electronic device
1:電池 1: battery
2:控制器 2: Controller
22:記憶體 22: Memory
24:計數器 24: Counter
3:電壓感測器 3: Voltage sensor
4:溫度感測器 4: Temperature sensor
200:充電器 200: charger
Sv:電壓訊號 Sv: voltage signal
St:溫度訊號 St: temperature signal
Scom:通訊訊號 Scom: communication signal
Vb:電壓 Vb: Voltage
(S100)~(S260):步驟 (S100)~(S260): Steps
圖1為使用者行為示意圖;圖2為本發明具有電池電壓動態調降功能之電子裝置搭配充電器的電路方塊圖;圖3A為本發明降低電芯鼓脹發生的方法流程圖;圖3B為本發明在測試溫度為35℃下不同充電狀態的電芯鼓脹實驗曲線圖;圖3C為本發明在測試溫度為40℃下不同充電狀態的電芯鼓脹實驗曲線圖;圖3D為本發明在測試溫度為45℃下不同充電狀態的電芯鼓脹實驗曲線圖;圖4為本發明動態降壓方法的方法流程圖; 圖5A為本發明電壓變數影響指數曲線圖;及圖5B為本發明溫度變數影響指數曲線圖。 Fig. 1 is a schematic diagram of user behavior; Fig. 2 is a circuit block diagram of an electronic device with a battery voltage dynamic lowering function of the present invention and a charger; Fig. 3A is a flow chart of the method for reducing battery swelling in the present invention; Fig. 3B is this The experimental curves of cell swelling in different charging states at the test temperature of 35°C; Figure 3C is the experimental curves of cell swelling in different charging states at the test temperature of 40°C; Figure 3D is the test temperature of the present invention It is a curve diagram of cell swelling experiments in different charging states at 45°C; Fig. 4 is a method flow chart of the dynamic step-down method of the present invention; FIG. 5A is a graph showing the influence index of voltage variable in the present invention; and FIG. 5B is a graph showing the influence index of temperature variable in the present invention.
茲有關本發明之技術內容及詳細說明,配合圖式說明如下:請參閱圖2為本發明具有電池電壓動態調降功能之電子裝置搭配充電器的電路方塊圖,復配合參閱圖1。電子裝置100包括電池1與控制器2,且控制器2係電性連接電池1。充電器200係電性連接電池1與控制器2,且用以對電池1充電。電池1用以供應電子裝置100運作所需的電力,且控制器2用以對電池1進行充電控制,以基於電池1的使用狀況來告知充電器200調整對電池1充電的電壓大小。具體的,電子裝置100可包括複數個感測器(或檢測電路),且至少可包括電壓感測器3與溫度感測器4。電壓感測器3電性連接電池1與控制器2,且用以偵測電池1的工作電壓而提供電壓訊號Sv至控制器2。溫度感測器4設置於電池1的電芯,且電性連接控制器2,以偵測電池1的工作溫度而提供溫度訊號St至控制器2。控制器2通常可以為電池管理晶片,用以至少接收電池1電壓訊號Sv與溫度訊號St來得知電池1的狀態,以基於電池1的狀態來管理對電池1充電的充電模式。在充電器200電性連接電池1後,控制器2通過通訊訊號Scom與充電器200相互通訊,且習知的充電器200通常會將電池1的電壓Vb充電至滿充電壓來盡可能的維持電子裝置100的續航能力。 Hereby, the technical content and detailed description of the present invention are explained as follows in conjunction with the drawings: Please refer to FIG. 2 for a circuit block diagram of an electronic device with a battery voltage dynamic lowering function of the present invention and a charger, and refer to FIG. 1 for complex cooperation. The electronic device 100 includes a battery 1 and a controller 2 , and the controller 2 is electrically connected to the battery 1 . The charger 200 is electrically connected to the battery 1 and the controller 2 and used for charging the battery 1 . The battery 1 is used to supply the electric power required for the operation of the electronic device 100 , and the controller 2 is used to control the charging of the battery 1 , so as to inform the charger 200 to adjust the charging voltage of the battery 1 based on the usage status of the battery 1 . Specifically, the electronic device 100 may include a plurality of sensors (or detection circuits), and at least include a voltage sensor 3 and a temperature sensor 4 . The voltage sensor 3 is electrically connected to the battery 1 and the controller 2 , and is used to detect the working voltage of the battery 1 and provide a voltage signal Sv to the controller 2 . The temperature sensor 4 is disposed on the cell of the battery 1 and is electrically connected to the controller 2 to detect the working temperature of the battery 1 and provide a temperature signal St to the controller 2 . The controller 2 can usually be a battery management chip for at least receiving the voltage signal Sv and the temperature signal St of the battery 1 to know the state of the battery 1 and to manage the charging mode for the battery 1 based on the state of the battery 1 . After the charger 200 is electrically connected to the battery 1, the controller 2 communicates with the charger 200 through the communication signal Scom, and the conventional charger 200 usually charges the voltage Vb of the battery 1 to the full charge voltage to maintain as much as possible The battery life of the electronic device 100 .
然而,由於電池1在使用者的使用過程中,電池1無可避免的會發生鼓脹的狀況。因此本發明之控制器2可提供降壓機制來保護電池1的電芯,降低鼓脹發生的狀況。具體而言,由於電池1鼓脹發生的狀況與使用者的使用 習慣息息相關,在正常使用的情況,鼓脹發生的狀況較緩慢。然而在使用者行為較為極端之情況(例如但不限於邊充電邊玩高效能遊戲等),鼓脹發生的狀況通常較為迅速。因此,本發明的主要目的及功效在於,通過控制器2包括電池電壓動態調降功能,以基於使用者行為來判斷是否告知充電器200調降滿充電壓,達到降低鼓脹發生的狀況,並提供使用者較佳之用戶體驗及用戶安全。其中,本發明主要係基於電池1的鼓脹指數來做為使用者行為的依據,使用者行為較為極端之情況,通常鼓脹指數增加的速度也越快。相對的,滿充電壓調降的頻率與相對較高,於後文將有更進一步的描述。 However, due to the battery 1 being used by the user, the battery 1 will inevitably swell. Therefore, the controller 2 of the present invention can provide a voltage reduction mechanism to protect the cells of the battery 1 and reduce the occurrence of swelling. Specifically, due to the situation that the battery 1 bulges and the user's use Habit is closely related, and under normal use, bloating occurs more slowly. However, in extreme cases of user behavior (such as but not limited to playing high-efficiency games while charging, etc.), the bloat usually occurs more quickly. Therefore, the main purpose and efficacy of the present invention is to use the controller 2 to include a battery voltage dynamic lowering function to judge whether to inform the charger 200 to lower the full charge voltage based on user behavior, so as to reduce the occurrence of bulging, and provide Better user experience and user security for users. Among them, the present invention is mainly based on the swelling index of the battery 1 as the basis for the user's behavior. The more extreme the user's behavior, the faster the swelling index usually increases. In contrast, the frequency of full-charge voltage drop is relatively high, which will be further described later.
配合參閱圖3A為本發明降低電芯鼓脹發生的方法流程圖、圖3B~3D分別為本發明在不同的條件下電芯鼓脹實驗曲線圖。在步驟(S100)中,通過電芯鼓脹實驗取得電池的電芯鼓脹實驗數據(曲線)。在圖3B~3D中,使用了特定鋰電池作為電芯鼓脹實驗,且實驗條件如下表1所示:
在圖3B中,測試溫度為35℃,且在測試電壓為4.4V的條件下,電芯鼓脹的狀況在100天之後開始顯著的提升。在測試電壓為4.35V的條件下,電芯鼓脹的狀況則延後於164天之後才開始顯著的提升。在測試電壓為4.30V的條件下,電芯鼓脹的狀況則更加的延後於293天之後才開始提升。在圖3C中, 測試溫度為40℃,且測試電壓為4.4V、4.35V及4.30V的條件下,電芯鼓脹的狀況分別發生在50、78、135天之後。同樣的在圖3D中,測試溫度為45℃,且測試電壓為4.4V、4.35V及4.30V的條件下,電芯鼓脹的狀況分別發生在35、50、90天之後。因此由圖3B~3D的曲線可以得知,在電池1的工作溫度越高的狀況下,則越快發生電芯鼓脹的狀況,且在電池1的充電閾值(即充電門檻電壓)越高的狀況下,同樣發生電芯鼓脹的狀況越快。因此可以得知,電芯鼓脹的狀況與電池1的工作溫度、電池1的充電門檻電壓息息相關。 In FIG. 3B , the test temperature is 35° C., and the test voltage is 4.4 V, the condition of cell swelling begins to increase significantly after 100 days. Under the condition of the test voltage of 4.35V, the cell bulging condition started to increase significantly after a delay of 164 days. Under the condition of the test voltage of 4.30V, the bulging condition of the battery cell started to increase after a delay of 293 days. In Figure 3C, Under the conditions of the test temperature of 40°C and the test voltage of 4.4V, 4.35V and 4.30V, the cell swelling occurred after 50, 78 and 135 days respectively. Similarly in FIG. 3D , under the conditions of the test temperature of 45° C. and the test voltage of 4.4V, 4.35V and 4.30V, the cell swelling occurred after 35, 50 and 90 days, respectively. Therefore, it can be seen from the curves in Figures 3B~3D that the higher the operating temperature of the battery 1, the faster the cell bulge will occur, and the higher the charging threshold of the battery 1 (that is, the charging threshold voltage) Under the same conditions, the faster the cell bulge also occurs. Therefore, it can be known that the condition of the cell swelling is closely related to the working temperature of the battery 1 and the charging threshold voltage of the battery 1 .
然後,在步驟(S120)中,利用電芯鼓脹實驗數據建立電芯鼓脹預測模型。本發明主要係利用電芯鼓脹實驗數據,搭配預設定的特定鼓脹率(例如但不限於,鼓脹率預設為10%)來建立電芯鼓脹預測模型,以據以預測電芯的鼓脹率何時(例如但不限於,天為單位)會到達特定鼓脹率(即10%)。然後,在步驟(S140)中,將電芯鼓脹預測模型寫入控制器2。在取得電芯鼓脹預測模型後,可通過燒入/資料傳輸等方式,將電芯鼓脹預測模型寫入並儲存於控制器2,或提供控制器2存取的記憶體22,以使控制器2可通過電芯鼓脹預測模型對充電門檻電壓進行調控而有效防止鼓脹發生,尤其是當使用者行為較為極端之情況。值得一提,在步驟(S140)中,除了將電芯鼓脹預測模型寫入並儲存於控制器2外,還可以寫入其他的參數設定/操作方式等資料,並不以此為限。此外,記憶體22可包含/或不包含在控制器2之中,以供控制器2進行存取。其中,鼓脹率預設為10%僅為示意,可依照使用者的需求而調整為任意百分比值。 Then, in step ( S120 ), a cell swelling prediction model is established by using the cell swelling experiment data. The present invention mainly utilizes the experimental data of cell swelling, and cooperates with a preset specific swelling rate (for example, but not limited to, the swelling rate is preset as 10%) to establish a cell swelling prediction model, so as to predict when the cell swelling rate will be (eg, but not limited to, days) will reach a certain inflation rate (ie, 10%). Then, in step ( S140 ), the cell swelling prediction model is written into the controller 2 . After the cell bulge prediction model is obtained, the cell bulge prediction model can be written and stored in the controller 2 by means of burning/data transmission, or the memory 22 accessed by the controller 2 can be provided to make the controller 2. The charging threshold voltage can be regulated by the cell swelling prediction model to effectively prevent swelling, especially when the user's behavior is relatively extreme. It is worth mentioning that in step ( S140 ), in addition to writing and storing the cell swelling prediction model in the controller 2 , other data such as parameter setting/operation mode can also be written, and the present invention is not limited thereto. In addition, the memory 22 may/or may not be included in the controller 2 for access by the controller 2 . Wherein, the swelling rate is preset as 10% for illustration only, and can be adjusted to any percentage value according to the needs of users.
具體的,在步驟(S160)中,控制器係通過使用者行為預測鼓脹情形。由於在電芯鼓脹實驗數據中得知,電芯鼓脹的狀況與電池1的工作溫度、電池1的充電門檻電壓息息相關,因此本發明主要特色在於,控制器2僅需要通 過使用感測器3、4(或檢測電路)等,偵測電池1電芯的工作溫度以及電池1的工作電壓,即可預測電芯鼓脹率到達10%的時間(即電池1的鼓脹率到達特定鼓脹率的時間)。 Specifically, in step (S160), the controller predicts the bloating situation through the user's behavior. Since it is known from the cell swelling experiment data that the cell swelling condition is closely related to the operating temperature of the battery 1 and the charging threshold voltage of the battery 1, the main feature of the present invention is that the controller 2 only needs to pass By using the sensors 3, 4 (or detection circuit), etc., to detect the operating temperature of the cell of the battery 1 and the operating voltage of the battery 1, it is possible to predict the time when the swelling rate of the battery cell reaches 10% (that is, the swelling rate of the battery 1 time to reach a specific inflation rate).
最後,在步驟(S180)中,控制器依據預測電芯鼓脹情形,適時的調整降壓機制。由於本發明的控制器2可預測電芯鼓脹率到達特定鼓脹率(即10%)的時間,因此可以依據使用者行為準確評估電芯鼓脹狀態,且通過預測電芯鼓脹情形,適時且動態的調降充電門檻電壓,以延後電芯鼓脹率到達特定鼓脹率的時間。由於本發明可以通過適時且動態的調降充電門檻電壓來延後電芯鼓脹率到達10%的時間,因此可降低電芯鼓脹退貨授權(Return Material Authorization;RMA,即顧客在產品保修期內退貨以獲得退款或更換以及維修產品)的發生。 Finally, in step ( S180 ), the controller adjusts the depressurization mechanism in a timely manner according to the predicted swelling of the battery cell. Since the controller 2 of the present invention can predict the time when the cell inflation rate reaches a specific inflation rate (i.e. 10%), it can accurately evaluate the cell inflation state according to user behavior, and by predicting the cell inflation situation, timely and dynamic Lower the charging threshold voltage to delay the time when the cell expansion rate reaches a specific expansion rate. Since the present invention can delay the time when the cell swelling rate reaches 10% by timely and dynamically reducing the charging threshold voltage, it can reduce the cell swelling Return Material Authorization (RMA, that is, the customer returns the product within the product warranty period. to obtain a refund or replacement and to repair the product) occurs.
請參閱圖4為本發明動態降壓方法的方法流程圖,復配合參閱圖2~3D。其中,圖4的流程主要係描述圖3A的步驟(S160)至(S180)的細部操作。步驟(S200)等同於步驟(S160),控制器係通過使用者行為預測鼓脹情形。其中,電池1在出廠時的規格通常具有初始滿充電壓(例如但不限於4.4V~4.5V),且控制器2可將充電門檻電壓的起始設定值設定為為初始滿充電壓,以由初始滿充電壓開始往下降壓。然後,判斷鼓脹狀態是否達預定值(S220)。當控制器2判斷鼓脹狀態達預定值時,則調降充電門檻電壓(S240),且返回步驟(S200)。反之,則維持原本的充電門檻電壓(S260),且返回步驟(S200)。藉此,可以通過適時且動態的調降充電門檻電壓,以延後電芯鼓脹率到達特定鼓脹率的時間。 Please refer to FIG. 4 which is a flow chart of the method for the dynamic pressure reduction method of the present invention, and refer to FIGS. 2-3D for complex cooperation. Wherein, the flowchart in FIG. 4 mainly describes the detailed operations of steps ( S160 ) to ( S180 ) in FIG. 3A . Step ( S200 ) is equivalent to step ( S160 ), the controller predicts the bloating situation through user behavior. Wherein, the battery 1 usually has an initial full-charge voltage (for example, but not limited to 4.4V~4.5V) when it leaves the factory, and the controller 2 can set the initial setting value of the charging threshold voltage as the initial full-charge voltage, so as to Start from the initial full charge voltage to step down. Then, it is judged whether the swelling state reaches a predetermined value (S220). When the controller 2 judges that the inflation state has reached the predetermined value, the charging threshold voltage is lowered ( S240 ), and the process returns to step ( S200 ). Otherwise, maintain the original charging threshold voltage (S260), and return to step (S200). In this way, the charging threshold voltage can be lowered in a timely and dynamic manner to delay the time when the cell inflation rate reaches a specific inflation rate.
復參閱圖3A,在步驟(S120)中,建立電芯鼓脹預測模型主要係通過鼓脹速率演算法取得電池1的鼓脹率到達特定鼓脹率的鼓脹速率演算式。具 體而言,電芯鼓脹預測模型主要係通過膨脹模擬方程、阿瑞尼斯方程式及電池產氣反應式來建立。膨脹模擬方程與阿瑞尼斯方程式分別如下式1~2所示:初始鼓脹值+A×e(R 0×t)...(1) Referring again to FIG. 3A , in step ( S120 ), the establishment of the cell swelling prediction model is mainly to obtain the swelling rate calculation formula that the swelling rate of the battery 1 reaches a specific swelling rate through the swelling rate calculation algorithm. Specifically, the cell inflation prediction model is mainly established through the expansion simulation equation, the Arenis equation, and the battery gas production reaction equation. The expansion simulation equation and the Arenis equation are respectively shown in the following formulas 1~2: initial inflation value + A × e ( R 0 × t )...(1)
k=A 0×e(-Ea/RT)...(2) k = A 0 × e (- Ea/RT )...(2)
由於造成電池1鼓脹之氣體主要為CO2,故以正極的化學反應考慮為主電池產氣反應式如下3~5所示:Li i-x CoO 2→(1-x)Li ++(1-x)e -+CoO 2...(3) Since the gas that causes battery 1 to bulge is mainly CO 2 , the chemical reaction of the positive electrode is considered to produce gas in the main battery. The reaction formula is as follows: Li ix CoO 2 →(1- x ) Li + +(1- x ) e − + CoO 2 ...(3)
3CoO 2→Co 3 O 4+O 2...(4) 3 CoO 2 → Co 3 O 4 + O 2 ... (4)
電解質溶劑(EC/DMC)+O 2→H 2 O+CO 2...(5) Electrolyte solvent ( EC/DMC ) + O 2 → H 2 O + CO 2 ...(5)
其中,上述式3的x可代表為電池1的充電狀態(State of Charge;SOC)。在電池1的充電門檻電壓為4.4V時,x為0.6、充電門檻電壓為4.35V時,x為0.575,且充電門檻電壓為4.3V時,x為0.55。由於實驗條件為固定電壓下浮充,因此式3應可視為反應平衡。在式5中,由經驗來說當電解液接觸O2時,電解液很快就被氧化產生CO2,因此推論式4應為反應速率決定步驟。因此,反應平衡與反應速率可以整理為下式6~7所示:Keq=[Li](1-x)×[CoO 2]/[Li 1-x CoO 2]→[CoO 2]=Keq×[Li 1-x CoO 2]/[Li](1-x)...(6,反應平衡式) Wherein, x in the above formula 3 may represent the state of charge (State of Charge; SOC) of the battery 1 . When the charging threshold voltage of the battery 1 is 4.4V, x is 0.6, when the charging threshold voltage is 4.35V, x is 0.575, and when the charging threshold voltage is 4.3V, x is 0.55. Since the experimental condition is floating charge at a fixed voltage, Equation 3 should be regarded as a reaction balance. In Equation 5, it is empirically said that when the electrolyte contacts O 2 , the electrolyte is quickly oxidized to produce CO 2 , so it is deduced that Equation 4 should be the reaction rate-determining step. Therefore, the reaction equilibrium and reaction rate can be organized as the following formulas 6~7: Keq =[ Li ] (1- x ) ×[ CoO 2 ]/[ Li 1- x CoO 2 ]→[ CoO 2 ]= Keq × [ Li 1- x CoO 2 ]/[ Li ] (1- x ) ... (6, reaction equilibrium formula)
反應速率=k×[CoO 2] n ...(7) Reaction rate = k × [ CoO 2 ] n ... (7)
其中式7的k為反應速率常數,且n為反應級數(Reaction order),其可以為1~3。所以,綜上所述,電池1的產氣速率由下式8所示:產氣速率=k×(Keq×[Li 1-x CoO 2]/[Li](1-x)) n ...(8) Wherein k in formula 7 is a reaction rate constant, and n is a reaction order (Reaction order), which can be 1-3. Therefore, in summary, the gas production rate of battery 1 is expressed by the following formula 8: gas production rate = k × ( Keq × [ Li 1- x CoO 2 ]/[ Li ] (1- x ) ) n .. .(8)
在帶入反應速率的常數k可以獲改寫產氣速率如下式8所示: 產氣速率=A 0×e(-Ea/RT)×(Keq×[Li 1-x CoO 2]/[Li](1-x)) n ...(9) The constant k brought into the reaction rate can be rewritten as the gas production rate as shown in Equation 8: Gas production rate = A 0 × e (- Ea/RT ) × ( Keq ×[ Li 1- x CoO 2 ]/[ Li ] (1- x ) ) n ... (9)
由於電池1的鼓脹速率正比於電池1的產氣速率,且較理想而言鼓脹速率等於產氣速率,因此式1的膨脹模擬方程即改寫為式9,且式9即為鼓脹速率演算式。其中,n以經驗來說應為1級反應,所以n可設定為1。由於電池1鼓脹之氣體主要為CO2而以正極的化學反應考慮為主,因此鼓脹速率演算式係以電池1的正極的化學反應為基礎。由於本發明的電芯鼓脹預測模型係以電芯鼓脹率到達特定鼓脹率(例如但不限於10%)來建立,因此可進一步推得鼓脹速率到達特定鼓脹率(即10%)所需之時間等於電池1的產氣速率如下式(10)所示:ln(鼓脹速率到達特定鼓脹率的時間)=ln(A 0×Keq×[Li 1-x CoO 2])-Ea/RT+(x-1)×ln([Li])...(10) Since the swelling rate of battery 1 is directly proportional to the gas production rate of battery 1, and ideally the swelling rate is equal to the gas production rate, the expansion simulation equation of Equation 1 is rewritten as Equation 9, and Equation 9 is the inflation rate calculation formula. Among them, n should be a first-order reaction based on experience, so n can be set to 1. Since the bulging gas of the battery 1 is mainly CO 2 and the chemical reaction of the positive electrode is considered as the main consideration, the swelling rate calculation formula is based on the chemical reaction of the positive electrode of the battery 1 . Since the cell inflation prediction model of the present invention is established based on the cell inflation rate reaching a specific inflation rate (such as but not limited to 10%), the time required for the inflation rate to reach a specific inflation rate (i.e. 10%) can be further deduced It is equal to the gas production rate of battery 1 as shown in the following formula (10): ln (the time for the swelling rate to reach a specific swelling rate)=ln( A 0 × Keq ×[ Li 1- x CoO 2 ])- Ea/RT +( x -1)×ln([ Li ])...(10)
上述的式10即為特定鼓脹速率演算式,且ln(A 0×Keq×[Li 1-x CoO 2])為常數項,Ea/RT為溫度變量,(x-1)×ln([Li])為電壓變量。由於電池1鼓脹發生的狀況與使用者的使用習慣息息相關,且電池1鼓脹發生的狀況係明顯與電池1的電壓、溫度相關,因此需取得溫度變量與電壓變量來預測預測電芯的鼓脹速率。由於在圖3B~3C中,取得了電芯鼓脹實驗數據(簡易列表如下表2所示),因此可通過電芯鼓脹實驗數據搭配特定鼓脹速率演算式進行模擬而分別取得圖5A的電壓變數影響指數曲線圖與圖5B的溫度變數影響指數曲線圖。藉此,即可完成步驟(S120)的電芯鼓脹預測模型之建立,且通過步驟(S140)將其寫入控制器2之中。值得一提,於本發明之一實施例中,電芯鼓脹預測模型並非僅能通過膨脹模擬方程、阿瑞尼斯方程式及電池產氣反應式來建立。具 體的,預測模型的建立主要係基於電池的產氣速率相關,因此只要是利用電池產氣速率的構想來建立預測模型的實施方式,皆應包含在本發明之範疇當中。 The above formula 10 is the specific inflation rate calculation formula, and ln( A 0 × Keq ×[ Li 1- x CoO 2 ]) is a constant term, Ea/RT is a temperature variable, ( x -1)×ln([ Li ]) is the voltage variable. Since the swelling of the battery 1 is closely related to the usage habits of the user, and the swelling of the battery 1 is obviously related to the voltage and temperature of the battery 1, it is necessary to obtain temperature variables and voltage variables to predict the swelling rate of the battery cell. Since in Figures 3B~3C, the experimental data of cell swelling is obtained (a simple list is shown in Table 2 below), so the influence of voltage variables in Figure 5A can be obtained by simulating the experimental data of cell swelling with a specific swelling rate calculation formula The exponential graph and the temperature variable influence exponential graph of FIG. 5B. In this way, the establishment of the cell swelling prediction model in step ( S120 ) can be completed, and it can be written into the controller 2 through step ( S140 ). It is worth mentioning that, in one embodiment of the present invention, the cell swelling prediction model can not only be established by the expansion simulation equation, the Arenis equation and the battery gas production reaction equation. Specifically, the establishment of the prediction model is mainly based on the gas production rate of the battery. Therefore, as long as the implementation of the prediction model is established using the concept of the gas production rate of the battery, it should be included in the scope of the present invention.
然後,控制器2設定基礎工作電壓及基礎工作溫度,且取得於基礎工作電壓及基礎工作溫度條件下,鼓脹率到達特定鼓脹率的達標時間。具體的,控制器2係通過電芯鼓脹實驗取得電芯的電芯鼓脹實驗數據曲線(即圖3B~3D),且基於電芯鼓脹實驗數據曲線取得基礎工作電壓及基礎工作溫度條件下的達標時間(如表2所示)。以表2為範例,本發明例如但不限於將4.3V設定基礎工作電壓,且將35℃設定基礎工作溫度,以取得鼓脹率到達特定鼓脹率(10%)的達標時間為342天。但上述範例僅為示意,其可以將任意的電壓與溫度設定為基礎工作電壓及基礎工作溫度,此設定也可以通過步驟(S140)的方式寫入控制器2之中。 Then, the controller 2 sets the basic working voltage and the basic working temperature, and obtains the attainment time for the swelling rate to reach a specific swelling rate under the conditions of the basic working voltage and the basic working temperature. Specifically, the controller 2 obtains the data curve of the cell swelling experiment of the battery cell through the cell swelling experiment (ie, Fig. 3B~3D), and obtains the basic working voltage and the standard working temperature under the condition of the basic working voltage and the basic working temperature based on the battery swelling experimental data curve. time (as shown in Table 2). Taking Table 2 as an example, in the present invention, for example but not limited to, the basic operating voltage is set at 4.3V, and the basic operating temperature is set at 35°C, so that the time required for the swelling rate to reach a specific swelling rate (10%) is 342 days. However, the above example is only for illustration, and any voltage and temperature can be set as the basic working voltage and basic working temperature, and this setting can also be written into the controller 2 through step ( S140 ).
在步驟(S160)中,控制器2係通過使用者行為預測鼓脹情形,主要是通過電壓感測器3與溫度感測器4分別偵測電池1的實際工作電壓與實際工作溫度,且計數電池1於不同的實際工作電壓及實際工作溫度下的複數個累計時間。其中,計數的工作可以通過例如但不限於計數器24來實施,且計數器24可包含/或不包含在控制器2之中。由於使用者的使用習慣(玩遊戲、上網、通聯 等),會造成電量的損耗而使得電池1的電壓Vb逐漸下降,且再經由充電器200進行充電而使得電壓Vb反覆的上升/下降。因此每個實際工作電壓下,電芯的實際工作溫度有可能會不同,甚至有可能發生當下的實際工作電壓有不同的實際工作溫度的狀況。因此,控制器2對每個不同的實際工作電壓,以及不同的實際工作電壓下的實際工作溫度進行計數/累加,以取得不同的實際工作電壓及實際工作溫度下的複數個累計時間。其中,上述計數/累加的結果可記錄於例如但不限於,記憶體22之中。 In step (S160), the controller 2 predicts the swelling situation through the user's behavior, mainly through the voltage sensor 3 and the temperature sensor 4 respectively detecting the actual operating voltage and the actual operating temperature of the battery 1, and counting the battery 1 Multiple cumulative times under different actual operating voltages and actual operating temperatures. Wherein, the counting work may be implemented by, for example but not limited to, the counter 24 , and the counter 24 may/or may not be included in the controller 2 . Due to the user's usage habits (playing games, surfing the Internet, communicating etc.), will cause power loss and cause the voltage Vb of the battery 1 to drop gradually, and then charge through the charger 200 to make the voltage Vb rise/fall repeatedly. Therefore, under each actual working voltage, the actual working temperature of the cell may be different, and it may even happen that the current actual working voltage has a different actual working temperature. Therefore, the controller 2 counts/accumulates each different actual operating voltage and the actual operating temperature under different actual operating voltages to obtain a plurality of accumulated times under different actual operating voltages and actual operating temperatures. Wherein, the above counting/accumulating results can be recorded in, for example but not limited to, the memory 22 .
由於控制器2於先前步驟已設定基礎工作電壓、基礎工作溫度及達標時間,且於步驟(S160)中取得了不同的實際工作電壓及實際工作溫度下的複數個累計時間,因此可以通過圖5A與圖5B的曲線,將實際工作電壓、實際工作溫度及累計時間等比例的換算。具體的,通過圖5A的電壓變數影響指數曲線圖,可取出實際工作電壓與基礎工作電壓之間的電壓倍率值,且通過圖5B的溫度變數影響指數曲線圖,可取出實際工作溫度與基礎工作溫度之間的溫度倍率值。因此,可以換算複數個實際工作電壓與複數個實際工作溫度為複數個電壓倍率值與溫度倍率值。之後,再通過電壓倍率值及其所對應的溫度倍率值、累計時間來計算複數個等效時間。 Since the controller 2 has set the basic operating voltage, basic operating temperature and standard time in the previous step, and obtained a plurality of cumulative times under different actual operating voltages and actual operating temperatures in step (S160), it can be obtained through FIG. 5A Compared with the curve in FIG. 5B , the actual operating voltage, actual operating temperature, and accumulated time are converted in equal proportions. Specifically, the voltage multiplier value between the actual operating voltage and the basic operating voltage can be obtained through the graph of the influence index of the voltage variable in Figure 5A, and the value of the voltage multiplier between the actual operating voltage and the basic operating voltage can be obtained, and through the graph of the influence index of the temperature variable in Figure 5B, the relationship between the actual operating temperature and the basic operating voltage can be obtained. Temperature multiplier value between temperatures. Therefore, the plurality of actual operating voltages and the plurality of actual operating temperatures can be converted into a plurality of voltage multiplier values and temperature multiplier values. Afterwards, multiple equivalent times are calculated through the voltage multiplier value, the corresponding temperature multiplier value, and the accumulated time.
這些等效時間為實際工作電壓與基礎工作電壓換算為基礎工作電壓及基礎工作溫度下的等效時間,且每個等效時間的計算方式主要係分別通過相應的電壓倍率值、溫度倍率值及累計時間之乘積來取得,但不排除可以通過其他的方式來取得(例如但不限於分別計算電壓倍率值、溫度倍率值與累計時間之乘積等方式)。最後,控制器2再加總這些等效時間為總等效時間,總等效時間相應於電池1於基礎工作電壓及基礎工作溫度下的工作時間。 These equivalent times are the equivalent time converted from the actual working voltage and the basic working voltage to the basic working voltage and basic working temperature, and the calculation method of each equivalent time is mainly through the corresponding voltage multiplier value, temperature multiplier value and It can be obtained by multiplying the cumulative time, but it can be obtained in other ways (for example, but not limited to calculating the product of the voltage multiplier value, temperature multiplier value and the cumulative time, etc.). Finally, the controller 2 sums up these equivalent times to form a total equivalent time, and the total equivalent time corresponds to the working time of the battery 1 at the basic working voltage and the basic working temperature.
由於控制器2已設定電池1於基礎工作電壓及基礎工作溫度下,鼓脹率到達特定鼓脹率的達標時間(其可以通過圖3B~3D得出),且也獲得了總等效時間。因此,控制器2可以通過總等效時間與達標時間取得電池1當前的鼓脹指數,且通過鼓脹指數判斷是否調降充電門檻電壓。當鼓脹指數低於預設的閾值,控制器2可通過調降充電門檻電壓來延後電池1的鼓脹率達到特定鼓脹率(10%)的時間。其中,鼓脹指數可以是總等效時間與達標時間的比值,可以通過總等效時間與達標時間之商而獲得,然而鼓脹指數也並不排除可以通過其他的方式來取得(例如但不限於計算總等效時間與達標時間差距時間(天數)之比值等方式)。 Since the controller 2 has set the battery 1 under the basic operating voltage and basic operating temperature, the time for the swelling rate to reach a specific swelling rate (which can be obtained from FIGS. 3B-3D ), and the total equivalent time is also obtained. Therefore, the controller 2 can obtain the current swelling index of the battery 1 through the total equivalent time and the standard reaching time, and judge whether to lower the charging threshold voltage according to the swelling index. When the swelling index is lower than the preset threshold, the controller 2 can delay the time when the swelling ratio of the battery 1 reaches a specific swelling ratio (10%) by lowering the charging threshold voltage. Among them, the inflation index can be the ratio of the total equivalent time to the time to reach the standard, and can be obtained through the quotient of the total equivalent time and the time to reach the standard. However, the inflation index does not exclude that it can be obtained by other methods (such as but not limited to calculating The ratio of the total equivalent time to the standard time gap time (days) etc.).
在步驟(S180)中,本發明更提供了特定的充電門檻電壓調降方式。具體而言,如下表3所示為本發明的降壓階段表:
降壓階段表包括複數階段(以一至十階示意),且每個階段對應預設的鼓脹指數預定值及降壓幅度預定值。控制器2在判斷鼓脹指數滿足某階的鼓脹指數預定值時,相應的將充電門檻電壓依降壓幅度調降。在上述表3中可以看出,降壓幅度並非等比例調降,其原因在於電池1一旦發生鼓脹的狀況,其惡化速度過快(如圖3B~3D所示),必須要更加的降低充電門檻電壓才能有效的達到抑制鼓脹速度過快的狀況。因此在降壓階段表的設計上,由第一階至最後一階的鼓脹指數預定值的差值可以為固定值(固定差),且由第一階至最後一階的降壓幅度的差值可以為指數值(指數差),或可設計為其他非等比差。 The depressurization stage table includes a plurality of stages (shown in steps from one to ten), and each stage corresponds to a preset predetermined value of inflation index and predetermined value of depressurization range. When the controller 2 judges that the inflation index satisfies a predetermined inflation index value of a certain order, the charging threshold voltage is correspondingly lowered according to the step-down range. It can be seen from the above Table 3 that the step-down range is not reduced proportionally. The reason is that once the battery 1 bulges, its deterioration speed is too fast (as shown in Figure 3B~3D), and the charging must be further reduced. Threshold voltage can effectively achieve the situation of suppressing the swelling speed too fast. Therefore, in the design of the decompression stage table, the difference between the predetermined value of the inflation index from the first stage to the last stage can be a fixed value (fixed difference), and the difference of the step-down range from the first stage to the last stage The value can be an exponential value (exponential difference), or can be designed as another unequal difference.
以上述的實施方式舉例而言,假設電芯工作條件及等效天數如下表4所示:
假設初始滿充電壓為4.4V,且充電門檻電壓的起始設定值設定在初始滿充電壓。控制器2將基礎工作電壓設定為4.3V,基礎工作溫度設定為35℃, 通過表2可得知電芯鼓脹率到達特定鼓脹率的時間為342天。控制器2開始偵測並記錄使用者的使用狀況,得到不同的實際工作電壓及實際工作溫度下的複數個累計時間。然後通過圖5A與圖5B的曲線,將實際工作電壓及實際工作溫度轉換為電壓倍率與溫度倍率。以4.40V、42℃為例,4.4V與4.3V換算的電壓倍率為2.74,且42℃與35℃換算的溫度倍率為2.29。在將2.74乘上2.29及累計時間(3天)獲得等效時間18.8(天)。依此類推,獲得所有的等效時間,且將其加總獲得總等效時間為82.5天。然後將總等效時間(82.5天)除以電芯鼓脹率到達特定鼓脹率的時間(342天)獲得膨脹指數(0.241)。最後將膨脹指數(0.241)對比表3可得知降壓幅度落在第二階段,因此控制器將充電門檻電壓依降壓幅度調降25mV為4.375V。 Assume that the initial full-charge voltage is 4.4V, and the initial setting value of the charging threshold voltage is set at the initial full-charge voltage. The controller 2 sets the basic operating voltage to 4.3V, and the basic operating temperature to 35°C. From Table 2, it can be seen that the time for the cell swelling rate to reach a specific swelling rate is 342 days. The controller 2 starts to detect and record the usage status of the user, and obtains multiple accumulative times under different actual operating voltages and actual operating temperatures. Then, the actual operating voltage and the actual operating temperature are converted into a voltage multiplier and a temperature multiplier through the curves in FIG. 5A and FIG. 5B . Taking 4.40V and 42°C as examples, the voltage multiplier converted from 4.4V to 4.3V is 2.74, and the temperature multiplier converted from 42°C to 35°C is 2.29. After multiplying 2.74 by 2.29 and the cumulative time (3 days), the equivalent time is 18.8 (days). By analogy, all equivalent times are obtained and summed up to obtain a total equivalent time of 82.5 days. Then divide the total equivalent time (82.5 days) by the time for the cell swelling rate to reach a specific swelling rate (342 days) to obtain the expansion index (0.241). Finally, comparing the expansion index (0.241) with Table 3, it can be seen that the step-down range falls in the second stage, so the controller lowers the charging threshold voltage by 25mV to 4.375V according to the step-down range.
因此,本發明之電池1不需要額外使用任何的壓力、位移量及/或鼓脹力感測器,且也無需使用任何偵測電池1的至少一偵測點位的壓力、位移量及/或鼓脹力的步驟,而是僅偵測電池1的電壓與溫度,即可準確的預測電芯鼓脹的狀況,並基於使用者行為來判斷是否告知充電器200調降滿充電壓,達到降低鼓脹發生的狀況,並提供使用者較佳之用戶體驗及用戶安全。 Therefore, the battery 1 of the present invention does not need to use any additional pressure, displacement and/or swelling force sensors, and does not need to use any pressure, displacement and/or pressure of at least one detection point of the battery 1. The step of bulging force, but only by detecting the voltage and temperature of the battery 1, can accurately predict the bulging condition of the battery cell, and judge whether to inform the charger 200 to lower the full charge voltage based on the user's behavior, so as to reduce the occurrence of bulging situation, and provide users with better user experience and user security.
惟,以上所述,僅為本發明較佳具體實施例之詳細說明與圖式,惟本發明之特徵並不侷限於此,並非用以限制本發明,本發明之所有範圍應以下述之申請專利範圍為準,凡合於本發明申請專利範圍之精神與其類似變化之實施例,皆應包括於本發明之範疇中,任何熟悉該項技藝者在本發明之領域內,可輕易思及之變化或修飾皆可涵蓋在以下本案之專利範圍。 However, the above description is only a detailed description and drawings of preferred embodiments of the present invention, but the features of the present invention are not limited thereto, and are not intended to limit the present invention. The entire scope of the present invention should be applied for as follows The scope of the patent shall prevail, and all embodiments that conform to the spirit of the patent scope of the present invention and its similar changes shall be included in the scope of the present invention, and any person familiar with the art can easily think of it in the field of the present invention Changes or modifications can be covered by the scope of the following patents in this case.
(S200)~(S260):步驟 (S200)~(S260): Steps
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