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TWI598215B - Producing method of integrated multi-curved surface structure - Google Patents

Producing method of integrated multi-curved surface structure Download PDF

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TWI598215B
TWI598215B TW105116778A TW105116778A TWI598215B TW I598215 B TWI598215 B TW I598215B TW 105116778 A TW105116778 A TW 105116778A TW 105116778 A TW105116778 A TW 105116778A TW I598215 B TWI598215 B TW I598215B
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base material
curved structure
fiber
manufacturing
core
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TW105116778A
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TW201741121A (en
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劉文傑
許嘉仁
鄭惟升
劉宏力
王獻緯
郭紓錚
莊佳姍
蔡福財
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財團法人塑膠工業技術發展中心
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  • Moulding By Coating Moulds (AREA)

Description

一體成型多曲面結構的製造方法Method for manufacturing integrally formed multi-curved structure

一種製造方法,特別是一種以芯鞘型纖維形成的一體成型多曲面結構的製造方法。A manufacturing method, in particular, a method of manufacturing an integrally formed multi-curved structure formed of a core-sheath type fiber.

既有複合纖維材料,如預浸布的成型方法相當多種,例如手積層法(手糊成型法)、纏繞成型法、模壓成型或真空成型法。There are quite a variety of molding methods for composite fiber materials such as prepreg, such as hand lamination (hand lay-up), wrap molding, compression molding or vacuum molding.

手積層法是利用樹脂塗佈在模型表面後,於樹脂層上舖設纖維布,再塗佈樹脂層,以樹脂層、纖維層、樹脂層的形式反覆疊層達到預設的厚度後,固化樹脂成型。手積層法的缺點是纖維布需要人工一片一片貼合,手法費時,且每片纖維布間的編織花紋不連續,外觀較不美觀,而樹脂塗佈後需要馬上成型固化,否則樹脂會氧化反應,影響產品性質。The hand lamination method is to apply a resin to the surface of the model, lay a fiber cloth on the resin layer, and then apply a resin layer, and laminate the resin layer, the fiber layer, and the resin layer to a predetermined thickness, and then cure the resin. forming. The disadvantage of the hand lamination method is that the fiber cloth needs to be manually pieced together, the method is time-consuming, and the weaving pattern between each piece of fiber cloth is discontinuous, the appearance is less beautiful, and the resin needs to be formed and solidified immediately after coating, otherwise the resin will oxidize. , affecting the nature of the product.

纏繞成型法是以特定的纏繞張力將纖維紗束纏繞於旋轉的芯模上成型,其缺點是無法製作彎折角度過大或是具有多個彎折曲面的物體,且製造過程中需要可耐纏繞張力的高品質芯模,製造成本較高。The winding forming method is formed by winding a bundle of fiber yarns on a rotating mandrel with a specific winding tension. The disadvantage is that an object having a too large bending angle or having a plurality of curved curved surfaces cannot be produced, and the manufacturing process needs to be resistant to winding. The high quality mandrel of tension has a high manufacturing cost.

而模壓或真空成型則是將平面的纖維布或纖維板直接以模具熱壓、真空成型為預設形狀,其缺點是在成型彎曲角度較大的結構或具有多種曲面的物體時,纖維布因為大角度的形變或過度的彎折,造成纖維布的編織紋路移位、變形、壁厚變薄等走紗現象,甚至容易在彎曲處破裂而產生瑕疵。Molding or vacuum forming is to directly press a flat fiber cloth or fiberboard into a preset shape by hot pressing and vacuum forming, and the disadvantage is that the fiber cloth is large when forming a structure with a large bending angle or an object having a plurality of curved surfaces. The deformation of the angle or the excessive bending causes the yarn woven pattern to be displaced, deformed, and the wall thickness is thinned, and the yarn is even broken at the bend to cause flaws.

為了解決上述複合纖維材料成型方法種種限制,本發明提供一種一體成型多曲面結構的製造方法,其包含:織造預成型步驟:將一芯鞘型纖維以編織方式形成一體成型的一預成型結構,該預成型結構的輪廓、大小對應該一體成型多曲面結構的輪廓、大小,該芯鞘型纖維包含一基體材料及一增強材料,該基體材料包覆該增強材料形成該芯鞘型纖維,該增強材料的熔點高於該基體材料;及固化成型步驟:利用一模穴輪廓、大小對應該多曲面結構的模具將該預成型結構固化成型,過程中該基體材料在高溫下會融熔黏合後固化成型為該一體成型多曲面結構。In order to solve the above various limitations of the composite fiber material molding method, the present invention provides a method for manufacturing an integrally formed multi-curved structure, comprising: a weaving preforming step: forming a core-sheath fiber into a preformed preformed structure in a braided manner, The contour and the size of the preformed structure correspond to the contour and size of the multi-curved structure. The core-sheath type fiber comprises a base material and a reinforcing material, and the base material covers the reinforcing material to form the core-sheath type fiber. The melting point of the reinforcing material is higher than the base material; and the curing forming step: curing the preformed structure by using a mold having a contour and a size corresponding to the multi-curved structure, and the base material is melted and bonded at a high temperature in the process. Curing is formed into the integrally formed multi-curved structure.

其中,該織造預成型步驟及該固化成型步驟之間,進一步施予一預定型步驟,使該預成型結構之局部或部分的該基體材料熔融結合。Wherein, between the weaving preforming step and the curing forming step, a predetermined step is further applied to melt or bond a part or a portion of the matrix material of the preformed structure.

其中,該預定型步驟是以紅外線加熱方式將預成型結構之局部或部分的該基體材料熔融結合。Wherein, the predetermined step is to melt-bond the part or part of the base material of the preform structure by infrared heating.

其中,該基體材料是熱塑性樹脂,包含聚乙烯、聚丙烯、多胺、聚醯胺、熱塑性聚胺基甲酸酯、聚甲基丙烯酸,進一步地包含低分子量聚乙烯、低密度聚乙烯、共聚型聚丙烯、非晶型共聚酯、低結晶型聚對苯二甲酸乙二酯、右旋聚乳酸或低熔點聚酰胺66。Wherein, the base material is a thermoplastic resin comprising polyethylene, polypropylene, polyamine, polyamine, thermoplastic polyurethane, polymethacrylic acid, further comprising low molecular weight polyethylene, low density polyethylene, copolymerization Polypropylene, amorphous copolyester, low crystalline polyethylene terephthalate, dextran polylactic acid or low melting polyamide 66.

其中,該增強材料包含超高分子量聚乙烯、均聚聚丙烯、聚對苯二甲酸乙二酯、左旋聚乳酸、高熔點聚酰胺66、碳纖維或玻璃纖維。Wherein, the reinforcing material comprises ultra high molecular weight polyethylene, homopolypropylene, polyethylene terephthalate, L-polylactic acid, high melting polyamide 66, carbon fiber or glass fiber.

其中,該固化成型步驟是使用熱壓固化或真空成型。Wherein, the curing molding step is using hot press curing or vacuum forming.

藉由上述說明可知,本發明具有以下之優點:As can be seen from the above description, the present invention has the following advantages:

1.相較於既有的手積層法需要耗費人工一片一片以樹脂黏貼纖維布,且成品的編織花紋不連續的缺點,本發明的芯鞘型纖維可以使用機械編織的方法成為一體成型的預成型結構,不僅不需額外塗佈樹脂黏著,更可節省人工,成品具有連續的編織花紋,較為美觀。1. The core-sheath fiber of the present invention can be integrally formed by mechanical weaving as compared with the existing hand lamination method, which requires labor-intensive one-piece resin-bonded fiber cloth and discontinuous weaving pattern of the finished product. The molding structure not only does not require additional coating resin adhesion, but also saves labor, and the finished product has a continuous weaving pattern and is relatively beautiful.

2.本發明編織時相較於既有纏繞成型法可不需使用芯模,可直接以芯鞘型纖維編織成型,或是以機械編織成型,減少芯模設備的成本;而相對於既有手積層法需要人工黏貼之繁瑣加工製程,本發明除了可降低、減少人力、人工成本,甚至可使用自動化加工製程取代人力加工。2. Compared with the existing winding forming method, the knitting method of the present invention can be directly formed by core-sheath type fiber braiding, or mechanically braided to reduce the cost of the core mold equipment; The lamination method requires a cumbersome processing process of manual bonding. In addition to reducing and reducing labor and labor costs, the present invention can even replace manual processing with an automated processing process.

3.本發明利用織造預成型的前處理步驟,對製造具有多曲面結構的物體,相較於既有以平面纖維布直接模壓或真空成型之方法,可減少纖維布在模壓或真空成型時的形變量,纖維布較不易產生破裂瑕疵,更可強化高曲率轉折處的結構強度。3. The invention utilizes the pre-processing step of the woven preform to reduce the fabric of the object having a multi-curved structure, compared with the method of directly molding or vacuum forming the flat fiber cloth, thereby reducing the fiber cloth during molding or vacuum forming. The shape variable, the fiber cloth is less prone to cracking, and the structural strength of the high curvature turning point can be strengthened.

請參考圖1~圖2,本發明第一較佳實施例是一體成型多曲面安全帽10的製造方法,其步驟包含:Referring to FIG. 1 to FIG. 2, a first preferred embodiment of the present invention is a method for manufacturing an integrally formed multi-curved helmet 10, the steps of which include:

步驟1 織造預成型:將一芯鞘型纖維11以機械或人工編織方式形成一體成型的一安全帽預成型結構10A,該安全帽預成型結構10A的輪廓、大小對應該安全帽10。前述所謂的輪廓或大小對應指得是該安全帽預成型結構10A與該安全帽10的輪廓、大小相近、近似或相同。Step 1 Weaving Preform: A core-sheath fiber 11 is integrally or mechanically knitted to form an integrally formed helmet pre-form 10A having a contour and size corresponding to the helmet 10. The aforementioned so-called contour or size correspondence means that the helmet preform structure 10A is similar to, similar to, or identical in contour and size to the helmet 10.

請參考圖2,本實施例所描述的該芯鞘型纖維11是以一基體材料111包覆一增強材料112所形成,該增強材料112之融熔溫度高於該基體材料111之融熔溫度,使該增強材料112與該基體材料111之融熔溫度形成一工作區間,該工作區間用於加熱固化成型時,足以融熔該基體材料111而均勻包覆該增強材料112但使該增強材料112仍維持纖維狀態。該基體材料111不限定,較佳是熱塑性樹脂,例如聚乙烯(PE)、聚丙烯(PP)、多胺(PA)、聚醯胺(Nylon)、熱塑性聚胺基甲酸酯(TPU)、聚甲基丙烯酸(PMMA)等,進一步地,如低分子量聚乙烯(LMWPE)、低密度聚乙烯(LDPE)、共聚型聚丙烯(CORA-PP)、非晶型共聚酯(PETG)、低結晶型聚對苯二甲酸乙二酯(PET)、右旋聚乳酸(PLA)或低熔點聚酰胺66(Nylon66);而該增強材料112則較佳是超高分子量聚乙烯(UHMWPE)、均聚聚丙烯(PP)、聚對苯二甲酸乙二酯(PET)、左旋聚乳酸(PLA)、高熔點聚酰胺66(Nylon66)、碳纖維(Carbon fiber)或玻璃纖維(Glass fiber)。Referring to FIG. 2, the core-sheath type fiber 11 described in this embodiment is formed by coating a reinforcing material 112 with a base material 111. The melting temperature of the reinforcing material 112 is higher than the melting temperature of the base material 111. The melting temperature of the reinforcing material 112 and the base material 111 forms a working interval for heating and solidifying molding, sufficient to melt the base material 111 to uniformly coat the reinforcing material 112 but make the reinforcing material 112 still maintains the fiber state. The base material 111 is not limited, and is preferably a thermoplastic resin such as polyethylene (PE), polypropylene (PP), polyamine (PA), polyamine (Nylon), thermoplastic polyurethane (TPU), Polymethacrylic acid (PMMA), etc., further, such as low molecular weight polyethylene (LMWPE), low density polyethylene (LDPE), copolymerized polypropylene (CORA-PP), amorphous copolyester (PETG), low Crystalline polyethylene terephthalate (PET), dextran polylactic acid (PLA) or low melting polyamide 66 (Nylon 66); and the reinforcing material 112 is preferably ultra high molecular weight polyethylene (UHMWPE), both Polypropylene (PP), polyethylene terephthalate (PET), L-polylactic acid (PLA), high melting polyamide 66 (Nylon 66), carbon fiber or Glass fiber.

上述該芯鞘型纖維11透過該基體材料111及該增強材料112的材料選擇可形成一自增強纖維(Self-reinforced fiber),該自增強纖維是指該基體材料111與該增強材料112均為相同化學成分之高分子材料所組成,例如可將該基體材料111選擇共聚型聚丙烯,搭配該增強材料112選擇均聚聚丙烯以形成所謂之自增強纖維。The core-sheath type fiber 11 is selected from the base material 111 and the material of the reinforcing material 112 to form a self-reinforced fiber. The self-reinforced fiber means that the base material 111 and the reinforcing material 112 are both For example, a polymer material of the same chemical composition may be used. For example, the base material 111 may be selected from a copolymerized polypropylene, and the reinforcing material 112 may be used to select a homopolypropylene to form a so-called self-reinforced fiber.

步驟2 固化成型:取一安全帽模具20,該安全帽模具20的內表面具有一模穴21,該模穴21的輪廓、大小對應該安全帽10,將前述該安全帽預成型結構10A利用該安全帽模具20中之該模穴21固化成型為該安全帽10,較佳是以熱壓固化或真空成型。Step 2: Forming a hard hat mold 20, the inner surface of the helmet mold 20 has a cavity 21, the contour and size of the cavity 21 corresponding to the helmet 10, and the aforementioned safety helmet preform structure 10A is utilized. The cavity 21 in the helmet mold 20 is solidified into the helmet 10, preferably by hot press curing or vacuum forming.

本步驟固化成型之製程溫度高於該基體材料111之熔點,但低於該增強材料112之熔點,固化成型的過程中,該芯鞘型纖維11外層之該基體材料111會融熔黏合並固化成型為該安全帽10。The process temperature of the solidification molding in this step is higher than the melting point of the base material 111, but lower than the melting point of the reinforcing material 112. During the solidification molding process, the base material 111 of the outer layer of the core-sheath type fiber 11 is melted and cured. Formed as the helmet 10.

本實施例使用該芯鞘型纖維11編織安全帽預成型結構10A的目的,是因為每一根該芯鞘型纖維11的外部,都包覆有在高溫下可融熔黏合並固化成型的該基體材料111,當固化成型時,纖維與纖維之間的該基體材料111會融熔黏合,使成型的整體結構更加緊密,結構剛性更佳,不需再額外塗佈樹脂黏著層即可成型,可改善一般預浸布,固化成型時容易產生樹脂層和織布層脫層或纖維剝落的缺點。且編織後的該安全帽預成型結構10A具有連續編織花紋,外觀較美觀。The purpose of the present invention is to use the core-sheath type fiber 11 to woven the helmet preform structure 10A because the outer portion of each of the core-sheath fibers 11 is coated with a melt-adhesive and solidified molding at a high temperature. The base material 111, when solidified and formed, the base material 111 between the fiber and the fiber is melted and bonded, so that the overall structure of the molding is tighter, the structural rigidity is better, and the resin adhesive layer can be formed without additional coating. The general prepreg can be improved, and the defects of delamination of the resin layer and the woven fabric layer or the peeling of the fibers are liable to occur at the time of solidification molding. And the woven pre-formed structure 10A has a continuous weaving pattern, and the appearance is more beautiful.

本實施例於步驟1的織造預成型步驟及步驟2的固化成型步驟之間,可進一步施予一預定型的步驟,由於織造預成型步驟後的該安全帽預成型結構10A可能會因為該基體材料111尚未熔融接合固定,而整體結構呈現稍微軟塌的狀況,為了避免影響後續固化成型步驟的進行,故可利用例如紅外線等加熱方式,使該基體材料111部分或局部稍微結合,使該安全帽預成型結構10A可稍微固化、固定,維持在預設的多曲面結構狀態,以利固化成型步驟的實施。In this embodiment, between the weaving preforming step of step 1 and the curing forming step of step 2, a predetermined type of step may be further applied, because the helmet pre-formed structure 10A after the weaving preforming step may be due to the substrate. The material 111 has not been melt-bonded and fixed, and the overall structure exhibits a slight soft collapse condition. In order to avoid affecting the subsequent curing molding step, the base material 111 may be partially or partially bonded by heating means such as infrared rays to make the safety. The cap preform structure 10A can be slightly cured, fixed, and maintained in a preset multi-curved structure state to facilitate the implementation of the curing molding step.

請參考圖3,本發明第二較佳實施例則是一體成型多曲面行李箱外殼30的製造方法,例如一般市售的長方體行李箱外殼,其四個頂點皆具有高角度彎折角。本發明第二較佳實施例的步驟同本發明第一較佳實施例,是先以織造預成型之步驟將該芯鞘型纖維11編織為對應該行李箱30輪廓、大小的之行李箱預成型結構,再將該行李箱預成型結構以固化成型的步驟成型為該行李箱30。Referring to FIG. 3, a second preferred embodiment of the present invention is a method of manufacturing a one-piece multi-curved luggage case 30, such as a generally commercially available cuboid case having four corners with high angle bend angles. The step of the second preferred embodiment of the present invention is the same as the first preferred embodiment of the present invention. The core-sheath type fiber 11 is first woven into a trunk pre-corresponding to the outline and size of the trunk 30 by the step of weaving preforming. The molding structure is formed into the luggage case 30 by the step of solidifying the luggage preform structure.

本發明在固化成型前先以將芯鞘型纖維11編織為預成型結構之目的,是為了改善一般平面纖維布往往會在模塑固化的步驟中,在由平面變形成型為高曲率結構的時候,因彎曲度、形變量太大而導致纖維布破損的問題,由於本發明先將該芯鞘型纖維11編織為接近該高彎折角度的結構外型,固化成型時,纖維布的彎曲或形變量相對於直接以平面的纖維布去塑型,本發明可降低纖維布在高彎折角度區域破損缺陷的問題,使各部分補強較均勻。本發明進一步可運用編織工藝的優點,適應性的編出厚薄不一的結構,針對高曲率的區域可編得較厚,以補強結構強度。The purpose of the invention is to weave the core-sheath fiber 11 into a preformed structure before curing, in order to improve the general planar fiber cloth tends to be formed into a high-curvature structure in the step of molding and curing. The problem that the fiber cloth is damaged due to the curvature and the deformation amount is too large. Since the present invention first ties the core-sheath type fiber 11 to a structural shape close to the high bending angle, the bending of the fiber cloth during solidification molding or The shape variable is shaped relative to the fiber cloth directly in the plane, and the invention can reduce the problem of the fiber cloth being damaged in the high bending angle region, and the reinforcement of each part is more uniform. The invention can further utilize the advantages of the weaving process, adaptively formulate structures of different thicknesses, and can be thicker for regions with high curvature to reinforce structural strength.

上述者僅是本發明的實施例而已,非為限定本發明實施的範圍,舉凡依據本發明的實施步驟、專利申請範圍內容所做的簡單修飾或變化,皆仍屬於本發明所涵蓋的範圍內。The above is only the embodiment of the present invention, and is not intended to limit the scope of the present invention. Any modifications or changes made in accordance with the embodiments of the present invention and the scope of the patent application are still within the scope of the present invention. .

10‧‧‧安全帽10‧‧‧Safety helmet

10A‧‧‧安全帽預成型結構10A‧‧‧Safety cap preformed structure

11‧‧‧芯鞘型纖維11‧‧‧core sheath fiber

111‧‧‧基體材料111‧‧‧Base material

112‧‧‧增強材料112‧‧‧Enhanced materials

20‧‧‧安全帽模具20‧‧‧Safety helmet mould

21‧‧‧模穴21‧‧‧ cavity

30‧‧‧行李箱外殼30‧‧‧Luggage compartment

圖1為本發明第一較佳實施例的製造流程示意圖。 圖2為本發明之芯鞘型纖維剖面示意圖。 圖3為本發明第二較佳實施例示意圖。1 is a schematic view showing a manufacturing process of a first preferred embodiment of the present invention. 2 is a schematic cross-sectional view of a core-sheath fiber of the present invention. Figure 3 is a schematic view of a second preferred embodiment of the present invention.

10‧‧‧安全帽 10‧‧‧Safety helmet

10A‧‧‧安全帽預成型結構 10A‧‧‧Safety cap preformed structure

11‧‧‧芯鞘型纖維 11‧‧‧core sheath fiber

20‧‧‧安全帽模具 20‧‧‧Safety helmet mould

21‧‧‧模穴 21‧‧‧ cavity

Claims (8)

一種一體成型多曲面結構的製造方法,其步驟包含:織造預成型步驟:將一芯鞘型纖維以立體編織方式形成一體成型的一預成型結構,該預成型結構的輪廓、大小對應該一體成型多曲面結構的輪廓、大小,該預成型結構至少包含一個高曲率區域,該芯鞘型纖維包含一基體材料及一增強材料,該基體材料包覆該增強材料形成該芯鞘型纖維,該增強材料的熔點高於該基體材料;及固化成型步驟:利用一模穴輪廓、大小對應該多曲面結構的模具將該預成型結構固化成型,過程中該基體材料在高於該基體材料的熔點溫度及低於該增強材料的熔點溫度下,會融熔黏合後固化成型為該一體成型多曲面結構。 The manufacturing method of the integrally formed multi-curved structure comprises the steps of: weaving a preforming step: forming a core-sheath fiber into a preformed structure in a three-dimensional weaving manner, and the contour and size of the preformed structure are integrally formed. The contour and size of the multi-curved structure, the preformed structure comprising at least one region of high curvature, the core-sheath type fiber comprising a base material and a reinforcing material, the base material coating the reinforcing material to form the core-sheath fiber, the reinforcement The melting point of the material is higher than the base material; and the curing forming step: curing the preformed structure by using a mold having a contour and a size corresponding to the multi-curved structure, wherein the base material is higher than the melting point temperature of the base material And below the melting point temperature of the reinforcing material, it will be melt-bonded and then solidified into the integrally formed multi-curved structure. 如申請專利範圍第1項之一體成型多曲面結構的製造方法,該織造預成型步驟及該固化成型步驟之間,進一步施予一預定型步驟,使該預成型結構之局部或部分的該基體材料熔融結合。 For example, in the manufacturing method of the body-formed multi-curved structure of the first aspect of the patent application, between the weaving preforming step and the curing forming step, a predetermined step is further applied to make the substrate partially or partially of the preformed structure. The material is melt bonded. 如申請專利範圍第2項之一體成型多曲面結構的製造方法,該預定型步驟是以紅外線加熱方式將預成型結構之局部或部分的該基體材料熔融結合。 The method for manufacturing a body-formed multi-curved structure according to the second aspect of the patent application, wherein the predetermined step is to melt-bond the part or a portion of the base material of the preform structure by infrared heating. 如申請專利範圍第1或2或3項之一種一體成型多曲面結構的製造方法,該基體材料是熱塑性樹脂。 A method of producing an integrally formed multi-curved structure according to claim 1 or 2 or 3, wherein the base material is a thermoplastic resin. 如申請專利範圍第1或2或3項之一體成型多曲面結構的製造方法,該增強材料包含超高分子量聚乙烯、均聚聚丙烯、聚對苯二甲酸乙二酯、左旋聚乳酸、高熔點聚酰胺66、碳纖維或玻璃纖維。 A method for manufacturing a multi-curved structure of a body shape according to claim 1 or 2 or 3, the reinforcing material comprising ultra high molecular weight polyethylene, homopolypropylene, polyethylene terephthalate, L-polylactic acid, high Melting point polyamide 66, carbon fiber or glass fiber. 如申請專利範圍第4項之一體成型多曲面結構的製造方法,該基體材料包含聚乙烯、聚丙烯、多胺、聚醯胺、熱塑性聚胺基甲酸酯、聚甲基丙烯酸。 A method for producing a body-formed multi-curved structure according to claim 4, wherein the base material comprises polyethylene, polypropylene, polyamine, polyamine, thermoplastic polyurethane, polymethacrylic acid. 如申請專利範圍第4項之一體成型多曲面結構的製造方法,該基體材料包含低分子量聚乙烯、低密度聚乙烯、共聚型聚丙烯、非晶型共聚酯、低結晶型聚對苯二甲酸乙二酯、右旋聚乳酸或低熔點聚酰胺66。 The manufacturing method of the multi-curved structure of the body shape according to the fourth item of the patent application, the base material comprises low molecular weight polyethylene, low density polyethylene, copolymerized polypropylene, amorphous copolyester, low crystalline polyparaphenylene Ethylene formate, dextran polylactic acid or low melting polyamide 66. 如申請專利範圍第1或2或3項之一體成型多曲面結構的製造方法,該固化成型步驟是使用熱壓固化或真空成型。 The manufacturing method of the multi-curved structure of one of the first or second or third aspects of the patent application is the use of hot press curing or vacuum forming.
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