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TWI590941B - Light guide plate manufacturing method - Google Patents

Light guide plate manufacturing method Download PDF

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Publication number
TWI590941B
TWI590941B TW102139685A TW102139685A TWI590941B TW I590941 B TWI590941 B TW I590941B TW 102139685 A TW102139685 A TW 102139685A TW 102139685 A TW102139685 A TW 102139685A TW I590941 B TWI590941 B TW I590941B
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TW
Taiwan
Prior art keywords
lens
layer
sheet
thermoplastic resin
extrusion
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Application number
TW102139685A
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Chinese (zh)
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TW201422407A (en
Inventor
Kazuo Funazaki
Tatsuya Ueda
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Kuraray Co
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Publication of TWI590941B publication Critical patent/TWI590941B/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C59/00Surface shaping of articles, e.g. embossing; Apparatus therefor
    • B29C59/02Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
    • B29C59/04Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing using rollers or endless belts
    • B29C59/046Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing using rollers or endless belts for layered or coated substantially flat surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • B29C48/08Flat, e.g. panels flexible, e.g. films
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/16Articles comprising two or more components, e.g. co-extruded layers
    • B29C48/18Articles comprising two or more components, e.g. co-extruded layers the components being layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/88Thermal treatment of the stream of extruded material, e.g. cooling
    • B29C48/911Cooling
    • B29C48/9135Cooling of flat articles, e.g. using specially adapted supporting means
    • B29C48/914Cooling drums
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/88Thermal treatment of the stream of extruded material, e.g. cooling
    • B29C48/918Thermal treatment of the stream of extruded material, e.g. cooling characterized by differential heating or cooling
    • B29C48/9185Thermal treatment of the stream of extruded material, e.g. cooling characterized by differential heating or cooling in the direction of the stream of the material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C59/00Surface shaping of articles, e.g. embossing; Apparatus therefor
    • B29C59/02Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
    • B29C59/04Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing using rollers or endless belts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Description

導光板的製造方法 Light guide plate manufacturing method

本發明係關於一種在樹脂薄片的表面具備平行排列的複數個脊狀透鏡之透鏡薄片的製造方法,詳細而言,本發明特別是關於一種可適合製造樹脂薄片的厚度厚且脊狀透鏡的高寬比高之透鏡薄片的方法。 The present invention relates to a method of manufacturing a lens sheet having a plurality of ridge lenses arranged in parallel on a surface of a resin sheet. In particular, the present invention relates in particular to a thickness which is suitable for manufacturing a resin sheet and has a high thickness of a ridge lens. A method of wide-ranging lens sheets.

已知在樹脂薄片的表面具備平行排列的複數個脊狀透鏡之透鏡薄片。就此種脊狀透鏡的形狀而言,可舉例如半圓錐體形狀的透鏡、或頂角90度的三角稜柱狀的稜鏡透鏡(參照專利文獻1~4)。在此種透鏡薄片方面,通常要求提高脊狀透鏡的高寬比(即(脊狀透鏡的高度)/(脊狀透鏡的間距))。 It is known that a lens sheet of a plurality of ridge lenses arranged in parallel is provided on the surface of the resin sheet. The shape of the ridge lens is, for example, a lens having a semi-conical shape or a triangular prism-shaped 稜鏡 lens having a vertex angle of 90 degrees (see Patent Documents 1 to 4). In the case of such a lens sheet, it is generally required to increase the aspect ratio of the ridge lens (i.e. (height of the ridge lens) / (the pitch of the ridge lens)).

就上述透鏡薄片的製造方法而言,可舉將熱塑性樹脂擠出成形或射出成形的方法、將紫外線硬化樹脂光硬化成形的方法。其中尤以將熱塑性樹脂擠出成形的方法在連續生產性的觀點上較佳。 The method for producing the lens sheet described above may be a method of extrusion molding or injection molding of a thermoplastic resin, or a method of photocuring an ultraviolet curable resin. Among them, a method of extrusion molding a thermoplastic resin is preferred from the viewpoint of continuous productivity.

作為利用熱塑性樹脂的擠出成形製造在兩面具有脊狀透鏡之透鏡薄片的方法,已知配置成以黏度低的熱塑性樹脂夾住黏度高的熱塑性樹脂而進行多層擠出成形的方法。以此種方法製造透鏡薄片,被認為可抑制製造具有高寬比高的脊狀透鏡之透鏡薄片時的熔融薄片的樹脂垂落,生產穩定性提高(參照專利文獻5)。 As a method of producing a lens sheet having a ridge lens on both sides by extrusion molding using a thermoplastic resin, a method of performing multilayer extrusion molding by sandwiching a thermoplastic resin having a high viscosity with a thermoplastic resin having a low viscosity is known. When the lens sheet is produced by such a method, it is considered that the resin dripping of the molten sheet when the lens sheet having the lenticular lens having a high aspect ratio is produced can be suppressed, and the production stability is improved (see Patent Document 5).

此外,已知使用在芯體與圖案構件之間配置熱緩衝構件的圖案輥作為賦形金屬模,將圖案構件的形狀轉印於擠出成形的熔融狀態的薄片上的方法,揭示將高寬比0.5的稜鏡透鏡排列於厚度1mm的樹脂薄片上的透鏡薄片之製造例(參照專利文獻6)。 Further, it is known to use a pattern roll in which a thermal buffer member is disposed between a core body and a pattern member as a shaping metal mold, and to transfer a shape of the pattern member onto an extruded sheet in a molten state, revealing a high width A manufacturing example of a lens sheet in which a 稜鏡 lens of 0.5 is arranged on a resin sheet having a thickness of 1 mm (see Patent Document 6).

上述透鏡薄片的其中一個用途為使用於液 晶顯示裝置等的導光板。在此種用途方面,近幾年裝置的大型化進展,伴隨此進展,為確保導光板的強度而要求加厚樹脂薄片。 One of the above-mentioned lens sheets is used for liquid A light guide plate of a crystal display device or the like. In recent years, in recent years, the development of large-scale devices has progressed, and in order to ensure the strength of the light guide plate, a resin sheet is required to be thickened.

依據本發明者等的研討,在專利文獻5所 記載的方法方面,加厚樹脂薄片時,有賦形率(即透鏡薄片之脊狀透鏡的高度/賦形金屬模之槽的深度)降低、脊狀透鏡的高寬比降低的傾向,發現有改善的餘地。 According to the study of the inventors, etc., in Patent Document 5 In the method described, when the resin sheet is thickened, the shaping rate (that is, the height of the lenticular lens of the lens sheet/the depth of the groove of the shaping metal mold) is lowered, and the aspect ratio of the ridge lens is lowered, and it is found that There is room for improvement.

此外,在專利文獻6所記載的方法方面,由於熱因為熱緩衝構件而有效地傳到樹脂薄片,所以樹脂薄片的厚度厚時,所形成的凹凸圖案的冷卻、硬化不迅速進展,從圖案輥剝下後,脊狀透鏡有變形的傾向,成為問題。 Further, in the method described in Patent Document 6, since heat is efficiently transmitted to the resin sheet by the heat buffer member, when the thickness of the resin sheet is thick, cooling and hardening of the formed uneven pattern are not progressed rapidly, from the pattern roll. After peeling off, the lenticular lens tends to be deformed, which becomes a problem.

先前技術文獻 Prior technical literature 專利文獻 Patent literature

專利文獻1 特開平2-190835號公報 Patent Document 1 Japanese Patent Publication No. 2-190835

專利文獻2 特開2009-37803號公報 Patent Document 2, JP-A-2009-37803

專利文獻3 特開2009-265380號公報 Patent Document 3, JP-A-2009-265380

專利文獻4 特開2009-283383號公報 Patent Document 4, JP-A-2009-283383

專利文獻5 特開平4-299329號公報 Patent Document 5 Japanese Patent Publication No. 4-299329

專利文獻6 特開2003-53834號公報 Patent Document 6 JP-A-2003-53834

本發明之目的係在使用熱塑性樹脂利用擠出成形製造透鏡薄片的方法方面,提供一種可在工業上容易製造適合大型導光板等、樹脂薄片的厚度厚、脊狀透鏡的高寬比高且在擠出寬度方向均勻之透鏡薄片的方法。 The object of the present invention is to provide a method for producing a lens sheet by extrusion molding using a thermoplastic resin, and to provide a resin sheet which is easy to manufacture and suitable for a large light guide plate and the like, and has a thick thickness and a high aspect ratio of the ridge lens. A method of extruding a lens sheet having a uniform width direction.

藉由本發明,上述目的可為包含以下形態的發明所解決: With the present invention, the above object can be solved by an invention comprising the following forms:

〔1〕一種透鏡薄片的擠出製造方法,其包含第一步驟,係將熱塑性樹脂(A)與MFR(依據ISO1133,以230℃、負荷37.3N的條件測定之值)小於前述熱塑性樹脂(A)的熱塑性樹脂(B)擠出成形,利用多歧管模具得到熔融狀態的多層薄片,該熔融狀態的多層薄片係鄰接具備:第1層,其係由熱塑性樹脂(A)構成,每單位長度的體積為y(y為正數),並且為表層;及第2層,其係由熱塑性樹脂(B)構成;以及第二步驟,係使具有複數個每單位長度的容積x(x為正數)滿足下式(1)的槽之賦形金屬模與由以第一步驟得到的熔融狀態的多層薄片之第1層構成的表面密合,形成n個(n為自然數)脊狀透鏡。 [1] A method for producing an extrusion of a lens sheet, comprising a first step of lowering a thermoplastic resin (A) and an MFR (a value measured according to ISO 1133 at 230 ° C under a load of 37.3 N) to be less than the thermoplastic resin (A) The thermoplastic resin (B) is extrusion-molded, and a multilayer sheet in a molten state is obtained by a multi-manifold mold, and the molten multi-layer sheet is provided adjacent to the first layer, which is composed of a thermoplastic resin (A) per unit length. The volume is y (y is a positive number) and is a surface layer; and the second layer is composed of a thermoplastic resin (B); and the second step is to have a plurality of volumes x per unit length (x is a positive number) The shaping die of the groove satisfying the following formula (1) is adhered to the surface composed of the first layer of the multilayer sheet in the molten state obtained in the first step to form n (n is a natural number) ridge lens.

0.7≦y/nx≦2.0 (1) 0.7≦y/nx≦2.0 (1)

〔2〕如〔1〕所記載之透鏡薄片的擠出製造方法,其特徵在於:前述y、n、x滿足下式(2):1.05≦y/nx≦1.4 (2) [2] The method for producing a lens sheet according to [1], wherein the y, n, and x satisfy the following formula (2): 1.05 ≦ y / n x ≦ 1.4 (2)

藉由本發明,可在工業上容易製造適合大型導光板等的樹脂薄片的厚度厚、脊狀透鏡的高寬比高的透鏡薄片,例如樹脂薄片的厚度為2.5~15mm、脊狀透鏡的高寬比為0.3~1.0的透鏡薄片。 According to the present invention, it is industrially easy to manufacture a lens sheet having a thick thickness of a resin sheet suitable for a large light guide plate or the like and a high aspect ratio of the ridge lens. For example, the thickness of the resin sheet is 2.5 to 15 mm, and the width and width of the ridge lens are high. A lens sheet with a ratio of 0.3 to 1.0.

1‧‧‧擠出成形機 1‧‧‧Extrusion molding machine

2‧‧‧多層擠出T型模具 2‧‧‧Multilayer extrusion T-die

31‧‧‧推壓金屬模滾筒 31‧‧‧Pushing the metal mold roller

32‧‧‧賦形金屬模滾筒 32‧‧‧Shaping metal mold roller

33、34‧‧‧冷卻滾筒 33, 34‧‧‧ Cooling roller

4‧‧‧透鏡薄片 4‧‧‧Lens Sheet

第1圖為顯示實施例1~5及比較例3、4的脊狀透鏡中央部的賦形率與y/nx之關係的圖。 Fig. 1 is a graph showing the relationship between the forming ratio of the central portion of the ridge lens of Examples 1 to 5 and Comparative Examples 3 and 4 and y/nx.

第2圖為製造實施例及比較例的透鏡薄片之擠出成形機的概略圖。 Fig. 2 is a schematic view showing an extrusion molding machine for manufacturing lens sheets of the examples and the comparative examples.

〔熱塑性樹脂〕 [thermoplastic resin]

在本發明的製造方法中使用的熱塑性樹脂(B)之MFR小於熱塑性樹脂(A)之MFR。即,以熱塑性樹脂(A)之MFR為MFR(A)、以熱塑性樹脂(B)之MFR為MFR(B)時,MFR(A)/MFR(B)之值超過1。MFR(A)/MFR(B)之值較好為1.5~40的範圍,更好為2~30的範圍,最好為3~20的範圍。MFR(A)/MFR(B)之值超過1可提高脊狀透鏡的高寬比。從提高所得到的透鏡薄片厚度的均勻性之觀點,MFR(A)/MFR(B)之值為40以下較好。再者,在本說明書中,所謂MFR,係依據ISO1133,以230℃、負荷37.3N的條件測定之值。 The MFR of the thermoplastic resin (B) used in the production method of the present invention is smaller than the MFR of the thermoplastic resin (A). That is, when the MFR of the thermoplastic resin (A) is MFR (A) and the MFR of the thermoplastic resin (B) is MFR (B), the value of MFR (A) / MFR (B) exceeds 1. The value of MFR(A)/MFR(B) is preferably in the range of 1.5 to 40, more preferably in the range of 2 to 30, and most preferably in the range of 3 to 20. A value of MFR(A)/MFR(B) of more than 1 can increase the aspect ratio of the lenticular lens. From the viewpoint of improving the uniformity of the thickness of the obtained lens sheet, the value of MFR (A) / MFR (B) is preferably 40 or less. In the present specification, the MFR is a value measured under conditions of 230 ° C and a load of 37.3 N in accordance with ISO 1133.

MFR(A)從將熱塑性樹脂(A)盡可能無間隙地填充於賦形金屬模之槽內的觀點,高於在以往的擠出 成形中所用之熱塑性樹脂的範圍較好。例如,7~50g/10分的範圍較好,7~30g/10分的範圍更好,10~25g/10分的範圍再更好,10~20g/10分的範圍特別好。若MFR(A)小於7g/10分,則有時所得到的透鏡薄片的賦形率會降低,若大於50g/10分,則有時擠出成形時的熱塑性樹脂(A)的擠出量會不穩定。 MFR (A) is superior to the conventional extrusion from the viewpoint that the thermoplastic resin (A) is filled in the groove of the shaping metal mold as much as possible without gaps. The range of the thermoplastic resin used in the forming is good. For example, the range of 7 to 50 g/10 minutes is better, the range of 7 to 30 g/10 minutes is better, the range of 10 to 25 g/10 minutes is even better, and the range of 10 to 20 g/10 minutes is particularly good. When the MFR (A) is less than 7 g/10 minutes, the forming ratio of the obtained lens sheet may be lowered, and if it is more than 50 g/10 minutes, the amount of extrusion of the thermoplastic resin (A) during extrusion molding may be obtained. It will be unstable.

再者,在本說明書中,以「~」連接兩個數值的記載方式意味著該兩個數值及其間的範圍。 In addition, in this specification, the description of the two numerical values connected by "~" means the two numerical values and the range between them.

MFR(B)從擠出成形的操作穩定性之觀點, 0.2~5g/10分的範圍較好,0.4~4g/10分的範圍更好,0.5~3g/10分的範圍再更好。若MFR(B)小於0.2g/10分,則擠出成形機內的熔融樹脂的壓力變得過高,擠出成形機有時會破損,若大於5g/10分,則有時所得到的透鏡薄片的厚度不均勻會增大。 MFR (B) from the viewpoint of operational stability of extrusion molding, The range of 0.2~5g/10 points is better, the range of 0.4~4g/10 points is better, and the range of 0.5~3g/10 points is better. When the MFR (B) is less than 0.2 g/10 minutes, the pressure of the molten resin in the extrusion molding machine becomes too high, and the extrusion molding machine may be broken. When it is more than 5 g/10 minutes, the obtained may be obtained. The uneven thickness of the lens sheet increases.

〔第一步驟〕 [first step]

在第一步驟中,將熱塑性樹脂(A)與熱塑性 樹脂(B)擠出成形,得到熔融狀態的多層薄片,該熔融狀態的多層薄片係鄰接具備:第1層,其係由熱塑性樹脂(A)構成,為表層;及第2層,其係由熱塑性樹脂(B)構成。 In the first step, the thermoplastic resin (A) and thermoplastic The resin (B) is extrusion-molded to obtain a multilayer sheet in a molten state, and the multilayer sheet in a molten state is provided with a first layer which is composed of a thermoplastic resin (A) and is a surface layer, and a second layer which is composed of The thermoplastic resin (B) is composed.

關於熱塑性樹脂(A)與熱塑性樹脂(B)的擠出成形的條件,無特別限制。通常,將熱塑性樹脂(A)及熱塑性樹脂(B)分別在擠出成形機的筒體中熔融,在擠出模具內層積後,擠出成形,得到熔融狀態的多層薄片。擠出模具從使各層的厚度均勻之觀點,使用在內部具有複數個歧管的多歧管模具。 The conditions for extrusion molding of the thermoplastic resin (A) and the thermoplastic resin (B) are not particularly limited. Usually, the thermoplastic resin (A) and the thermoplastic resin (B) are each melted in a cylinder of an extrusion molding machine, laminated in an extrusion die, and then extrusion-molded to obtain a multilayer sheet in a molten state. The extrusion die uses a multi-manifold mold having a plurality of manifolds inside from the viewpoint of making the thickness of each layer uniform.

以在本申請案中使用的多歧管模具製造多層薄片時,構成各層的熱塑性樹脂被供應給模具內部的各別的流路,構成各層的樹脂被分別向板的寬度方向展開之後,在模具的吐出口附近被匯合而擠出。因此,利用多歧管模具,即使樹脂的流動性不同,也可以使各層的厚度在板的寬度方向均勻。 When the multilayer sheet is produced by the multi-manifold mold used in the present application, the thermoplastic resin constituting each layer is supplied to the respective flow paths inside the mold, and the resins constituting the respective layers are respectively spread in the width direction of the sheet, and then in the mold. The spit exit is merged and squeezed out. Therefore, with the multi-manifold mold, even if the fluidity of the resin is different, the thickness of each layer can be made uniform in the width direction of the sheet.

在擠出成形方面,使熱塑性樹脂(A)及熱塑 性樹脂(B)熔融的溫度(成形溫度)最好例如比熱塑性樹脂(A)及熱塑性樹脂(B)的負荷撓曲溫度通常分別提高130~180℃。熱塑性樹脂(A)與熱塑性樹脂(B)的成形溫度也可以不同。在第二步驟的脊狀透鏡的形成方面,從提高熱塑性樹脂(A)的流動性來提高賦形率之觀點,最好使高熱塑性樹脂(A)的成形溫度比熱塑性樹脂(B)的成形溫度還高。 In terms of extrusion molding, thermoplastic resin (A) and thermoplastic The temperature at which the resin (B) is melted (forming temperature) is preferably, for example, higher than the load deflection temperature of the thermoplastic resin (A) and the thermoplastic resin (B) by 130 to 180 ° C, respectively. The molding temperature of the thermoplastic resin (A) and the thermoplastic resin (B) may also be different. In the formation of the ridge lens of the second step, from the viewpoint of improving the fluidity of the thermoplastic resin (A) to improve the forming ratio, it is preferable to form the high thermoplastic resin (A) at a molding temperature higher than that of the thermoplastic resin (B). The temperature is still high.

多歧管模具通常具有用於加熱各熱塑性樹 脂的加熱器。多歧管模具具有的加熱器也可以各熱塑性樹脂不同,此情況,可分別變更各熱塑性樹脂的加熱器的溫度(成形溫度)。成為第1層的熱塑性樹脂(A)接觸的加熱器的溫度比多歧管模具具有的熱塑性樹脂(B)接觸的加熱器的溫度,通常以5~40℃的溫度差提高較好,以10~35℃的溫度差提高更好,以15~30℃的溫度差提高再更好。將此種溫度差設定為40℃以下,所得到的透鏡薄片不易產生翹曲。 Multi-manifold molds are typically used to heat individual thermoplastic trees Fat heater. The heater of the multi-manifold mold may be different from each thermoplastic resin. In this case, the temperature (forming temperature) of the heater of each thermoplastic resin can be changed. The temperature of the heater in contact with the thermoplastic resin (A) of the first layer is higher than the temperature of the heater in contact with the thermoplastic resin (B) of the multi-manifold mold, and is usually preferably increased by a temperature difference of 5 to 40 ° C to 10 The temperature difference of ~35 °C is better, and the temperature difference of 15~30 °C is better. When such a temperature difference is set to 40 ° C or less, the obtained lens sheet is less likely to cause warpage.

對熱塑性樹脂(A)的擠出量無特別限制,但可設定為例如5~100kg/小時等。 The amount of extrusion of the thermoplastic resin (A) is not particularly limited, but may be, for example, 5 to 100 kg/hr.

對熱塑性樹脂(B)的擠出量無特別限制,但可設定為例如50~400kg/小時等。 The amount of extrusion of the thermoplastic resin (B) is not particularly limited, but may be, for example, 50 to 400 kg/hr.

熱塑性樹脂(A)與熱塑性樹脂(B)的擠出量之比可設定為例如1:2~1:50等。 The ratio of the extrusion amount of the thermoplastic resin (A) to the thermoplastic resin (B) can be set to, for example, 1:2 to 1:50.

對熔融狀態的多層薄片的擠出速度無特別限制,但可設定為例如0.1~10m/分等。 The extrusion speed of the multilayer sheet in a molten state is not particularly limited, but may be, for example, 0.1 to 10 m/min.

可依據按照使用的各熱塑性樹脂的擠出量及多歧管模具吐出口的寬度等所調整的熔融狀態的多層薄片之厚度,調整第1層的每單位長度的體積y。 The volume y per unit length of the first layer can be adjusted in accordance with the thickness of the multilayer sheet in a molten state adjusted according to the amount of extrusion of each thermoplastic resin used and the width of the manifold mold discharge port.

在擠出成形方面,也可以按照需要,在上述熱塑性樹脂(A)及熱塑性樹脂(B)的一方或兩方添加抗氧化劑、抗熱劣化劑、紫外線吸收劑、光穩定化劑、潤滑劑、脫模劑、防靜電劑、高分子加工輔助劑、阻燃劑、染料顏料、光擴散劑、耐衝擊性改性劑、螢光體等。 In the extrusion molding, an antioxidant, a heat-resistant deterioration agent, an ultraviolet absorber, a photostabilizer, a lubricant, or the like may be added to one or both of the thermoplastic resin (A) and the thermoplastic resin (B) as needed. A release agent, an antistatic agent, a polymer processing aid, a flame retardant, a dye pigment, a light diffusing agent, an impact modifier, a phosphor, and the like.

在本步驟得到的熔融狀態的多層薄片之厚度,通常2~20mm的範圍較好,2.5~10mm的範圍更好。厚度若比2mm薄,則有時樹脂薄片的強度會不足,若比20mm厚,則形成的凹凸圖案的冷卻、硬化不迅速進展,從賦形金屬模剝下後,脊狀透鏡有變形的傾向。 The thickness of the multilayer sheet in a molten state obtained in this step is usually in the range of 2 to 20 mm, and more preferably in the range of 2.5 to 10 mm. When the thickness is thinner than 2 mm, the strength of the resin sheet may be insufficient. If it is thicker than 20 mm, the cooling and hardening of the formed uneven pattern may not progress rapidly, and the ridge lens may be deformed after being peeled off from the shaping die. .

在本步驟中所得到的熔融狀態的多層薄片之第1層與第2層的厚度之比可設定為例如1:2~1:50等。 The ratio of the thickness of the first layer to the second layer of the multilayer sheet in a molten state obtained in this step can be set to, for example, 1:2 to 1:50.

在本說明書中,將第1層的每單位長度的體積定義為y。此外,第1層為熔融狀態的多層薄片之表層,在第二步驟中與賦形金屬模密合。此結果,第1 層成為在第二步驟中所形成的n個脊狀透鏡的至少一部分。 In the present specification, the volume per unit length of the first layer is defined as y. Further, the first layer is a surface layer of a multilayer sheet in a molten state, and is adhered to the shaping metal mold in the second step. This result, the first The layer becomes at least a portion of the n ridge lenses formed in the second step.

第2層可以是熔融狀態的多層薄片之表 層,也可以為其他層所覆蓋。即,熔融狀態的多層薄片也可以含有第1層、第2層以外的其他層。此種其他層可以由熱塑性樹脂(A)或熱塑性樹脂(B)構成,也可以由其他熱塑性樹脂構成。從抑制所得到的的透鏡薄片翹曲之觀點,最好使用由熱塑性樹脂(A)構成的第3層作為別的層,形成為按第1層/第2層/第3層之順序配置的三層多層薄片。製造此種三層多層薄片時,此時,第3層的擠出量設定為第1層的擠出量的0.9~1.1倍的範圍較好,和第1層的擠出量相等更好。 The second layer may be a sheet of a multilayer sheet in a molten state Layers can also be covered by other layers. In other words, the multilayer sheet in a molten state may contain other layers than the first layer and the second layer. Such other layer may be composed of a thermoplastic resin (A) or a thermoplastic resin (B), or may be composed of another thermoplastic resin. From the viewpoint of suppressing warpage of the obtained lens sheet, it is preferable to use a third layer made of a thermoplastic resin (A) as another layer, and to form the first layer/second layer/third layer in the order of the first layer/second layer/third layer. Three layers of multilayer sheets. In the case of producing such a three-layer multilayer sheet, in this case, the extrusion amount of the third layer is preferably in the range of 0.9 to 1.1 times the extrusion amount of the first layer, and is preferably equal to the extrusion amount of the first layer.

〔第二步驟〕 [Second step]

在第二步驟中,使具有複數個槽之賦形金 屬模與由以第一步驟得到的熔融狀態的多層薄片之第1層構成的表面密合,形成n個脊狀透鏡,上述槽的每單位長度的容積x係滿足式(1)。此時,最好使推壓金屬模與熔融狀態的多層薄片之其他表面密合。 In the second step, the shaping gold having a plurality of grooves is made The mold is adhered to the surface of the first layer of the multilayer sheet in the molten state obtained in the first step to form n ridge lenses, and the volume x per unit length of the groove satisfies the formula (1). At this time, it is preferable that the pressing metal mold is adhered to the other surface of the multilayer sheet in a molten state.

賦形金屬模及推壓金屬模的形狀可舉例如帶狀、滾筒狀等。 The shape of the shaping die and the pressing die can be, for example, a belt shape, a drum shape or the like.

形成n個脊狀透鏡之際所需的賦形金屬模之槽的每單位長度的容積的合計為nx。式(1)的y/nx之值從實現高的賦形率之觀點,為0.7~2.0的範圍,1.05~1.4的範圍較好,1.2~1.3的範圍更好。 The total volume per unit length of the grooves of the forming metal mold required to form the n ridge lenses is nx. The value of y/nx of the formula (1) is in the range of 0.7 to 2.0 from the viewpoint of achieving a high shaping rate, a range of 1.05 to 1.4 is preferable, and a range of 1.2 to 1.3 is more preferable.

本發明的透鏡薄片之脊狀透鏡的個數n係 以(製造的透鏡薄片之寬度)/(脊狀透鏡之間距)而定。可依據此種脊狀透鏡的個數n、在前述第一步驟中所決定的熔融狀態的多層薄片之第1層的每單位長度的體積y、及賦形金屬模之槽的每單位長度的容積x,將y/nx之值調整在希望的範圍內。具體而言,於在前述第一步驟中製造熔融狀態的多層薄片之際,若以使用的全部熱塑性樹脂的每單位時間的擠出量的合計為r、以熱塑性樹脂(A)的每單位時間的擠出量為r1,則藉由調整比率r1/r,可調整y/nx之值,y/nx隨著增大r1/r而變大。 The number n of ridge lenses of the lens sheet of the present invention is determined by (the width of the manufactured lens sheet) / (the distance between the lenticular lenses). Depending on the number n of such ridge lenses, the volume y per unit length of the first layer of the multilayer sheet in the molten state determined in the first step, and the per unit length of the groove of the shaping die The volume x adjusts the value of y/nx to the desired range. Specifically, when the multilayer sheet in a molten state is produced in the first step, the total amount of extrusion per unit time of all the thermoplastic resins used is r, and the unit time of the thermoplastic resin (A) The amount of extrusion is r 1 , and by adjusting the ratio r 1 /r, the value of y/nx can be adjusted, and y/nx becomes larger as the r 1 /r is increased.

依據y/nx之值而決定第1層在賦形金屬模 之槽內的容積之中滿足到哪種程度。即,y/nx之值超過1時,僅熱塑性樹脂(A)填滿該槽內,所得到的透鏡薄片之第1層可形成脊狀透鏡及樹脂薄片的一部分,第2層可形成樹脂薄片。另一方面,若y/nx之值小於1,則槽內係熱塑性樹脂(A)的全部量及熱塑性樹脂(B)的一部分填滿,所得到的透鏡薄片之第1層可形成脊狀透鏡的一部分,第2層可形成脊狀透鏡的一部分及樹脂薄片。若y/nx之值為1,則僅熱塑性樹脂(A)填滿該槽內,所得到的透鏡薄片之第1層僅可形成脊狀透鏡,第2層僅可形成樹脂薄片。如以上所說明,本發明的製造方法係藉由調整第1層之中形成脊狀透鏡的比例、及脊狀透鏡之中以第1層形成的比例來達成目的。 Determine the first layer in the shaping metal mold according to the value of y/nx Which of the volumes in the tank is satisfied. That is, when the value of y/nx exceeds 1, only the thermoplastic resin (A) fills the groove, and the first layer of the obtained lens sheet can form a part of the ridge lens and the resin sheet, and the second layer can form a resin sheet. . On the other hand, when the value of y/nx is less than 1, the entire amount of the thermoplastic resin (A) in the groove and a part of the thermoplastic resin (B) are filled, and the first layer of the obtained lens sheet can form a ridge lens. As part of the second layer, a part of the ridge lens and the resin sheet can be formed. When the value of y/nx is 1, only the thermoplastic resin (A) is filled in the groove, and the first layer of the obtained lens sheet can only form a ridge lens, and the second layer can only form a resin sheet. As described above, the manufacturing method of the present invention achieves the object by adjusting the ratio of the lenticular lens formed in the first layer and the ratio of the first layer formed in the lenticular lens.

賦形金屬模的溫度從將熱塑性樹脂(A)盡可 能無間隙地填充於賦形金屬模內之觀點,在熱塑性樹脂 (A)的負荷撓曲溫度±10℃的範圍較好。賦形金屬模的溫度比熱塑性樹脂(A)的負荷撓曲溫度低超過10℃,則樹脂無法充分填充於賦形金屬模內,而高超過10℃,則樹脂從賦形金屬模的脫模會無法順利地進行,產生樹脂薄片捲在滾筒上的事故、或產生被稱為脫模痕跡的表面缺陷。 The temperature of the forming metal mold is from the thermoplastic resin (A) Can be filled in a shaped metal mold without gaps, in thermoplastic resin The range of the load deflection temperature of (A) is preferably ±10 °C. When the temperature of the shaping metal mold is lower than the load deflection temperature of the thermoplastic resin (A) by more than 10 ° C, the resin cannot be sufficiently filled in the shaping metal mold, and when the height exceeds 10 ° C, the resin is released from the shaping metal mold. This may not proceed smoothly, resulting in an accident in which the resin sheet is wound on the drum or a surface defect called a mold release mark.

推壓金屬模的溫度從充分冷卻熱塑性樹脂(B)之觀點,在(熱塑性樹脂(B)的負荷撓曲溫度-20℃)~(熱塑性樹脂(B)的負荷撓曲溫度)的範圍較好。 The temperature at which the metal mold is pushed is preferably in the range of (the deflection temperature of the thermoplastic resin (B) is -20 ° C) to (the deflection temperature of the thermoplastic resin (B)) from the viewpoint of sufficiently cooling the thermoplastic resin (B). .

再者,熱塑性樹脂(A)及熱塑性樹脂(B)的負荷撓曲溫度係依據ISO75-2而測定。 Further, the load deflection temperature of the thermoplastic resin (A) and the thermoplastic resin (B) was measured in accordance with ISO 75-2.

從提高所得到的透鏡薄片之脊狀透鏡的高寬比之觀點,使用的賦形金屬模的間距通常0.05~1.0mm的範圍較好,0.1~0.8mm的範圍更好。 From the viewpoint of increasing the aspect ratio of the ridge lens of the obtained lens sheet, the pitch of the forming metal mold to be used is usually preferably in the range of 0.05 to 1.0 mm, and more preferably in the range of 0.1 to 0.8 mm.

在本發明中,係在與通常擠出方向垂直的方向切斷在第二步驟之後所得到的薄片成形品,調整長度而形成透鏡薄片。此外,也可以適當切斷與擠出方向平行的擠出寬度方向的兩端,調整寬度。 In the present invention, the sheet molded article obtained after the second step is cut in a direction perpendicular to the normal extrusion direction, and the length is adjusted to form a lens sheet. Further, both ends in the extrusion width direction parallel to the extrusion direction may be appropriately cut and the width may be adjusted.

[實施例] [Examples]

以下顯示實施例及比較例來詳細說明本發明,但本發明並不受此等例子限定。 The present invention will be described in detail below by way of examples and comparative examples, but the invention is not limited thereto.

使用的賦形金屬模如下:使用兩液硬化型矽樹脂轉印賦形金屬模的表面形狀,用顯微鏡觀察其剖面形狀,測定槽之間距與深度。此結果,賦形金屬模滾筒之槽的剖面形狀,係間距為0.4mm、深度為0.231mm的半橢圓形。 The shaping metal mold used was as follows: the surface shape of the shaping metal mold was transferred using a two-liquid hardening type resin, and the cross-sectional shape thereof was observed with a microscope to measure the distance and depth between the grooves. As a result, the cross-sectional shape of the groove of the shaping metal mold cylinder was a semi-elliptical shape having a pitch of 0.4 mm and a depth of 0.231 mm.

此外,從所得到的槽之間距與深度算出半橢圓形狀之槽的面積,並且算出每單位長度的容積x(m3/m)。此結果,x為0.14×10-6m3Further, the area of the groove of the semi-elliptical shape was calculated from the obtained groove pitch and depth, and the volume x (m 3 /m) per unit length was calculated. As a result, x is 0.14 × 10 -6 m 3 .

所得到的透鏡薄片用以下方法進行評估: The resulting lens sheet was evaluated by the following method:

(1)脊狀透鏡的高度 (1) height of the lenticular lens

用顯微鏡觀察與透鏡薄片的擠出方向垂直的剖面,測定與從脊狀透鏡的頂部到谷部的厚度方向平行的距離。以在擠出寬度方向的中央部測定到的值為中央部的脊狀透鏡的高度,以在從擠出寬度方向的中央部往一方的擠出寬度方向的端部離開600mm處測定到的值為端部的脊狀透鏡的高度。 The cross section perpendicular to the extrusion direction of the lens sheet was observed with a microscope, and the distance parallel to the thickness direction from the top of the ridge lens to the valley portion was measured. The value measured in the central portion of the extrusion width direction is the value measured at a distance of 600 mm from the central portion in the extrusion width direction to the end portion in the extrusion width direction at a height of the ridge lens at the center portion. The height of the lenticular lens at the end.

(2)樹脂薄片的厚度 (2) Thickness of resin sheet

用顯微鏡觀察與透鏡薄片的擠出方向垂直的剖面,測定從脊狀透鏡的谷部到第3層表面的距離。 The cross section perpendicular to the extrusion direction of the lens sheet was observed with a microscope, and the distance from the valley portion of the ridge lens to the surface of the third layer was measured.

(3)算出y/nx (3) Calculate y/nx

從熱塑性樹脂(A)的擠出量Q(kg/小時)、透鏡薄片的擠出速度v(m/分)、熱塑性樹脂(A)的比重ρ(g/cm3),依據下式算出第1層的每單位長度的體積y(m3/m):y=Q/(60000×ρ×v)(m3/m) The extrusion amount Q (kg/hour) of the thermoplastic resin (A), the extrusion speed v (m/min) of the lens sheet, and the specific gravity ρ (g/cm 3 ) of the thermoplastic resin (A) were calculated according to the following formula. Volume y (m 3 /m) per unit length of 1 layer: y = Q / (60000 × ρ × v) (m 3 / m)

從算出的y與形成的脊狀透鏡數量n及前述算出的x(m3/m)算出y/nx。 From the calculated y and the number of ridge lenses n formed and the above calculated x (m 3 /m), y/nx was calculated.

(4)脊狀透鏡的間距 (4) The spacing of the lenticular lenses

用顯微鏡觀察與透鏡薄片的擠出方向垂直的剖面,測定從脊狀透鏡的頂部到相鄰的脊狀透鏡的頂部的距離。 The cross section perpendicular to the extrusion direction of the lens sheet was observed with a microscope, and the distance from the top of the ridge lens to the top of the adjacent ridge lens was measured.

(5)脊狀透鏡的高寬比 (5) The aspect ratio of the lenticular lens

在前述(1)測定到的中央部之脊狀透鏡的高度除以在前述(4)測定到的脊狀透鏡的間距,作為高寬比。 The height of the ridge lens at the center portion measured in the above (1) is divided by the pitch of the ridge lens measured in the above (4) as the aspect ratio.

(6)賦形率(%) (6) Forming rate (%)

求出在前述(1)測定到的中央部及端部之脊狀透鏡的高度對於賦形金屬模之槽的深度的百分率,作為中央部及端部的賦形率(%)。 The percentage of the height of the ridge lens at the center portion and the end portion measured in the above (1) to the depth of the groove of the shaping die was determined as the shaping rate (%) of the center portion and the end portion.

(7)第3層的厚度 (7) Thickness of the third layer

用顯微鏡觀察並測定與薄片的擠出方向垂直的剖面。以在擠出寬度方向的中央部測定到的值為中央部的第3層的厚度,以在從擠出寬度方向的中央部往一方的擠出寬度方向的端部離開600mm處測定到的值為端部的第3層的厚度。 The cross section perpendicular to the extrusion direction of the sheet was observed with a microscope. The value measured in the central portion in the extrusion width direction is the thickness of the third layer in the center portion, and is measured at a distance of 600 mm from the center portion in the extrusion width direction to the end portion in the extrusion width direction. The thickness of the third layer of the end.

第2圖為在實施例及比較例中使用之擠出 成形機1的概略圖。擠出成形機1係由未圖示的擠出螺旋部、多層擠出T型多歧管模具2、推壓金屬模滾筒31、賦形金屬模滾筒32、冷卻滾筒33、34所構成。在賦形金屬模滾筒32的表面設有3250條沿著滾筒外周延伸的槽。 Figure 2 is an extrusion used in the examples and comparative examples. A schematic view of the molding machine 1. The extrusion molding machine 1 is composed of an extrusion spiral portion (not shown), a multilayer extrusion T-type manifold mold 2, a pressing die cylinder 31, a shaping die cylinder 32, and cooling drums 33 and 34. On the surface of the shaping die drum 32, 3250 grooves extending along the outer circumference of the drum are provided.

推壓金屬模滾筒31、冷卻滾筒33、34的表面為平滑。從多層擠出T型多歧管模具2之熔融樹脂吐出部向下方吐出熔融的帶狀樹脂。推壓金屬模滾筒31與賦形金屬模滾筒32係以夾住熔融樹脂的方式對向且互相平行、水平地配置。冷卻滾筒33、34係與推壓金屬模滾筒31及賦形金屬模滾筒32平行地配置成各自的旋轉軸位於同一平面。 The surfaces of the pressing die 31 and the cooling rollers 33, 34 are smoothed. The molten strip-shaped resin is discharged downward from the molten resin discharge portion of the multilayer extruded T-type manifold mold 2. The pressing die roll 31 and the shaping die roll 32 are opposed to each other so as to sandwich the molten resin, and are arranged parallel to each other and horizontally. The cooling drums 33 and 34 are arranged in parallel with the pressing die drum 31 and the shaping die drum 32 so that the respective rotation axes are located on the same plane.

在實施例及比較例中使用下面的丙烯酸樹脂(a)及丙烯酸樹脂(b):丙烯酸樹脂(a):Kuraray(股)製「PARAPET GH」、MFR=10(依據ISO1133,以230℃、負荷37.3N測定之目錄值)、負荷撓曲溫度=95℃(依據ISO75-2,有退火,以負荷1.82MPa測定之目錄值)、比重1.19。 In the examples and comparative examples, the following acrylic resin (a) and acrylic resin (b) were used: acrylic resin (a): "PARAPET GH" manufactured by Kuraray Co., Ltd., MFR = 10 (according to ISO 1133, at 230 ° C, load) 37.3N measurement catalog value), load deflection temperature = 95 ° C (according to ISO 75-2, annealing, catalogue value measured by load 1.82 MPa), specific gravity 1.19.

丙烯酸樹脂(b):Kuraray(股)製「PARAPET EH」、MFR=1.3g/10分(依據ISO1133,以230℃、負荷37.3N測定之目錄值)、負荷撓曲溫度=93℃(測定條件:依據ISO75-2,有退火,以負荷1.82MPa測定之目錄值)、比重1.19。 Acrylic resin (b): "PARAPET EH" manufactured by Kuraray Co., Ltd., MFR = 1.3 g/10 min (catalog value measured according to ISO 1133 at 230 ° C, load 37.3 N), load deflection temperature = 93 ° C (measurement conditions) : According to ISO75-2, there is annealing, the catalog value measured by the load of 1.82MPa), and the specific gravity is 1.19.

實施例1 Example 1

將丙烯酸樹脂(a)及丙烯酸樹脂(b)裝入擠出成形機,將丙烯酸樹脂(a)加熱到260℃,將丙烯酸樹脂(b)加熱到245℃,在吐出熔融樹脂的擠出寬度方向的長度約1500mm的多層擠出T型多歧管模具內按丙烯酸樹脂(a)、丙烯酸樹脂(b)、丙烯酸樹脂(a)的順序層積,擠出以丙烯酸樹脂(a)為第1層、以丙烯酸樹脂(b)為第2層、以丙烯酸樹脂(a)為第3層的熔融狀態的多層薄片。丙烯酸樹脂(a)(第1層及第3層)的擠出量分別為20kg/小時,丙烯酸樹脂(b)(第2層)的擠出量為200kg/小時。 The acrylic resin (a) and the acrylic resin (b) are placed in an extrusion molding machine, the acrylic resin (a) is heated to 260 ° C, and the acrylic resin (b) is heated to 245 ° C in the extrusion width direction of the discharged molten resin. The multilayer extruded T-multi-manifold mold having a length of about 1500 mm is laminated in the order of acrylic resin (a), acrylic resin (b), and acrylic resin (a), and the acrylic resin (a) is extruded as the first layer. A multilayer sheet in which the acrylic resin (b) is the second layer and the acrylic resin (a) is the third layer in a molten state. The extrusion amount of the acrylic resin (a) (the first layer and the third layer) was 20 kg/hr, and the extrusion amount of the acrylic resin (b) (the second layer) was 200 kg/hr.

其次,將此種熔融狀態的多層薄片供應給離開3mm且互相平行配置的推壓金屬模滾筒31與賦形金屬模滾筒32之間,賦予透鏡形狀,其次使其與冷卻滾筒33、34密合,得到在表面排列有複數個脊狀透鏡的薄片成形品。薄片成形品的寬度大約為1.4(m)。 Next, the multi-layered sheet in the molten state is supplied between the pressing metal mold cylinder 31 and the shaping metal mold cylinder 32 which are disposed apart from each other and disposed in parallel with each other to give a lens shape, and secondly, it is brought into close contact with the cooling drums 33, 34. A sheet molded article in which a plurality of ridge lenses are arranged on the surface is obtained. The sheet molded article has a width of about 1.4 (m).

推壓金屬模滾筒31的表面溫度為80℃,賦形金屬模滾筒32的表面溫度為100℃,冷卻滾筒33的表面溫度為100℃,冷卻滾筒34的表面溫度為70℃,透鏡薄片的擠出速度為0.8m/分。 The surface temperature of the pressing die 31 was 80 ° C, the surface temperature of the shaping die 32 was 100 ° C, the surface temperature of the cooling drum 33 was 100 ° C, and the surface temperature of the cooling drum 34 was 70 ° C. The exit speed is 0.8 m/min.

y/nx之值為0.750。 The value of y/nx is 0.750.

與擠出方向垂直地以1.3m的長度切斷所得到的薄片成形品。此外,以均等寬度分別切斷與擠出方向平行的擠出寬度方向的兩端,使寬度成為1.3m,製成透鏡薄片。 The obtained sheet molded product was cut into a length of 1.3 m perpendicular to the extrusion direction. Further, both ends of the extrusion width direction parallel to the extrusion direction were cut at equal widths to have a width of 1.3 m, and a lens sheet was produced.

如以上得到的透鏡薄片之脊狀透鏡的間距為0.4mm,樹脂薄片的厚度為2.8mm,中央部的脊狀透鏡的高度為0.16mm,端部的脊狀透鏡的高度為0.159mm,脊狀透鏡的高寬比為0.400,中央部及端部的賦形率為69%。中央部的第3層厚度為0.136mm,端部的第3層厚度為0.135mm。 The lenticular lens of the lens sheet obtained above has a pitch of 0.4 mm, the thickness of the resin sheet is 2.8 mm, the height of the ridge lens at the center portion is 0.16 mm, and the height of the ridge lens at the end portion is 0.159 mm, ridge shape. The aspect ratio of the lens was 0.400, and the shaping rate at the center portion and the end portion was 69%. The third layer of the central portion has a thickness of 0.136 mm, and the third layer of the end portion has a thickness of 0.135 mm.

實施例2 Example 2

除了以丙烯酸樹脂(a)(第1層及第3層)的擠出量分別為28.8kg/小時、丙烯酸樹脂(b)(第2層)的擠出量為182.3kg/小時之外,其餘以和實施例1同樣的方式製造了透鏡薄片。此結果,y/nx成為1.081。如以上得到的透鏡薄片之脊狀透鏡的間距為0.4mm,樹脂薄片的厚度為2.8mm,中央部的脊狀透鏡的高度為0.164mm,端部的脊狀透鏡的高度為0.162mm,脊狀透鏡的高寬比為0.410,中央部的賦形率為71%,端部的賦形率為70%。中央部的第3層厚度為0.196mm,端部的第3層厚度為0.196mm。 Except that the extrusion amount of the acrylic resin (a) (the first layer and the third layer) was 28.8 kg/hr, and the extrusion amount of the acrylic resin (b) (the second layer) was 182.3 kg/hr, the rest was A lens sheet was produced in the same manner as in Example 1. As a result, y/nx becomes 1.081. The pitch of the lenticular lens of the lens sheet obtained above was 0.4 mm, the thickness of the resin sheet was 2.8 mm, the height of the ridge lens at the center portion was 0.164 mm, and the height of the ridge lens at the end portion was 0.162 mm, ridge shape. The aspect ratio of the lens was 0.410, the shaping rate at the center portion was 71%, and the shape at the end portion was 70%. The third layer of the central portion has a thickness of 0.196 mm, and the third layer of the end portion has a thickness of 0.196 mm.

實施例3 Example 3

除了以丙烯酸樹脂(a)(第1層及第3層)的擠出量分別為32kg/小時、丙烯酸樹脂(b)(第2層)的擠出量為176kg/小時之外,其餘以和實施例1同樣的方式製造了透鏡薄片。此結果,y/nx成為1.230。如以上得到的透鏡薄片之脊狀透鏡的間距為0.4mm,樹脂薄片的厚度為2.8mm,中央部及端部的脊狀透鏡的高度為0.177mm,脊狀透鏡的高寬比為0.443,中央部及端部的賦形率為77%。中央部的第3層厚度為0.223mm,端部的第3層厚度為0.222mm。 Except that the extrusion amount of the acrylic resin (a) (the first layer and the third layer) was 32 kg/hr, and the extrusion amount of the acrylic resin (b) (the second layer) was 176 kg/hr, A lens sheet was produced in the same manner as in Example 1. As a result, y/nx becomes 1.230. The lenticular lens of the lens sheet obtained above has a pitch of 0.4 mm, the thickness of the resin sheet is 2.8 mm, the height of the ridge lens at the center portion and the end portion is 0.177 mm, and the aspect ratio of the ridge lens is 0.443, and the center The shaping rate of the part and the end is 77%. The third layer of the central portion has a thickness of 0.223 mm, and the third layer of the end portion has a thickness of 0.222 mm.

實施例4 Example 4

除了以丙烯酸樹脂(a)(第1層及第3層)的擠出量分別為36.8kg/小時、丙烯酸樹脂(b)(第2層)的擠出量為164.4kg/小時之外,其餘以和實施例1同樣的方式製造了透鏡薄片。此結果,y/nx成為1.379。如以上得到的透鏡薄片之脊狀透鏡的間距為0.4mm,樹脂薄片的厚度為2.8mm,中央部的脊狀透鏡的高度為0.164mm,端部的脊狀透鏡的高度為0.166mm,脊狀透鏡的高寬比為0.410,中央部的賦形率為71%,端部的賦形率為72%。中央部及端部的第3層厚度為0.25mm。 Except that the extrusion amount of the acrylic resin (a) (the first layer and the third layer) was 36.8 kg/hr, and the extrusion amount of the acrylic resin (b) (the second layer) was 164.4 kg/hr, the rest was A lens sheet was produced in the same manner as in Example 1. As a result, y/nx becomes 1.379. The lenticular lens of the lens sheet obtained above has a pitch of 0.4 mm, the thickness of the resin sheet is 2.8 mm, the height of the ridge lens at the center portion is 0.164 mm, and the height of the ridge lens at the end portion is 0.166 mm, ridge shape. The aspect ratio of the lens was 0.410, the shaping rate at the center portion was 71%, and the shaping rate at the end portion was 72%. The third layer of the central portion and the end portion has a thickness of 0.25 mm.

實施例5 Example 5

除了以丙烯酸樹脂(a)(第1層及第3層)的擠出量分別為51.5kg/小時、丙烯酸樹脂(b)(第2層)的擠出量為137kg/小時之外,其餘以和實施例1同樣的方式製造了透鏡薄片。此結果,y/nx成為1.930。如以上得到 的透鏡薄片之脊狀透鏡的間距為0.4mm,樹脂薄片的厚度為2.8mm,中央部的脊狀透鏡的高度為0.156mm,端部的脊狀透鏡的高度為0.157mm,脊狀透鏡的高寬比為0.390,中央部及端部的賦形率為68%。中央部的第3層厚度為0.35mm,端部的第3層厚度為0.348mm。 Except that the extrusion amount of the acrylic resin (a) (the first layer and the third layer) was 51.5 kg/hr, and the extrusion amount of the acrylic resin (b) (the second layer) was 137 kg/hr, the rest was A lens sheet was produced in the same manner as in Example 1. As a result, y/nx becomes 1.930. As above The lenticular lens has a pitch of 0.4 mm, the thickness of the resin sheet is 2.8 mm, the height of the ridge lens at the center is 0.156 mm, the height of the ridge lens at the end is 0.157 mm, and the height of the ridge lens is high. The width ratio is 0.390, and the shaping rate at the center portion and the end portion is 68%. The third layer of the central portion has a thickness of 0.35 mm, and the third layer of the end portion has a thickness of 0.348 mm.

比較例1 Comparative example 1

將丙烯酸樹脂(b)裝入擠出成形機,加熱到245℃,以擠出量240kg/小時從T型多歧管模具擠出熔融狀態的薄片。其次,將此種熔融狀態的薄片供應給離開3mm且互相平行配置的推壓金屬模滾筒31與賦形金屬模滾筒32之間,賦予透鏡形狀,其次使其與冷卻滾筒33、34密合,製造在表面排列有複數個脊狀透鏡的透鏡薄片。推壓金屬模滾筒31的表面溫度為80℃,賦形金屬模滾筒32的表面溫度為100℃,冷卻滾筒33的表面溫度為100℃,冷卻滾筒34的表面溫度為70℃,透鏡薄片的擠出速度為0.8m/分。 The acrylic resin (b) was placed in an extruder, heated to 245 ° C, and the sheet in a molten state was extruded from the T-manifold die at an extrusion amount of 240 kg / hour. Then, the sheet in the molten state is supplied between the pressing die cylinder 31 and the shaping die cylinder 32 which are disposed apart from each other and disposed in parallel with each other, and is given a lens shape, and then brought into close contact with the cooling rollers 33 and 34. A lens sheet in which a plurality of ridge lenses are arranged on the surface is produced. The surface temperature of the pressing die 31 was 80 ° C, the surface temperature of the shaping die 32 was 100 ° C, the surface temperature of the cooling drum 33 was 100 ° C, and the surface temperature of the cooling drum 34 was 70 ° C. The exit speed is 0.8 m/min.

如以上得到的透鏡薄片之脊狀透鏡的間距為0.4mm,樹脂薄片的厚度為2.9mm,中央部及端部的脊狀透鏡的高度為0.100mm,脊狀透鏡的高寬比為0.250,中央部及端部的賦形率為43%。 The lenticular lens of the lens sheet obtained above has a pitch of 0.4 mm, the thickness of the resin sheet is 2.9 mm, the height of the ridge lens at the center portion and the end portion is 0.100 mm, and the aspect ratio of the ridge lens is 0.250. The shaping rate of the part and the end was 43%.

比較例2 Comparative example 2

除了以丙烯酸樹脂(b)的擠出量為160kg/小時、將推壓金屬模滾筒31與賦形金屬模滾筒32之間離開2mm且互相平行配置之外,其餘以和比較例1同樣的方式製造了透鏡薄片4。 The same manner as in Comparative Example 1 except that the extrusion amount of the acrylic resin (b) was 160 kg/hr, and the pressing die 31 and the shaping die 32 were separated by 2 mm and arranged in parallel with each other. A lens sheet 4 is manufactured.

如以上得到的透鏡薄片之脊狀透鏡的間距為0.4mm,樹脂薄片的厚度為1.9mm,中央部及端部的脊狀透鏡的高度為0.150mm,脊狀透鏡的高寬比為0.375,中央部及端部的賦形率為65%。 The lenticular lens of the lens sheet obtained above has a pitch of 0.4 mm, the thickness of the resin sheet is 1.9 mm, the height of the ridge lens at the center portion and the end portion is 0.150 mm, and the aspect ratio of the ridge lens is 0.375. The shaping rate of the part and the end is 65%.

比較例3 Comparative example 3

除了以丙烯酸樹脂(a)(第1層及第3層)的擠出量分別為5.9kg/小時、丙烯酸樹脂(b)(第2層)的擠出量為228.2kg/小時之外,其餘以和實施例1同樣的方式製造了透鏡薄片。此結果,y/nx成為0.221。如以上得到的透鏡薄片之脊狀透鏡的間距為0.4mm,樹脂薄片的厚度為2.9mm,中央部的脊狀透鏡的高度為0.115mm,端部的脊狀透鏡的高度為0.113mm,脊狀透鏡的高寬比為0.288,中央部的賦形率為50%,端部的賦形率為49%。中央部及端部的第3層厚度為0.040mm。 Except that the extrusion amount of the acrylic resin (a) (the first layer and the third layer) was 5.9 kg/hr, and the extrusion amount of the acrylic resin (b) (the second layer) was 228.2 kg/hr, the rest was A lens sheet was produced in the same manner as in Example 1. As a result, y/nx becomes 0.221. The lenticular lens of the lens sheet obtained above has a pitch of 0.4 mm, the thickness of the resin sheet is 2.9 mm, the height of the ridge lens at the center portion is 0.115 mm, and the height of the ridge lens at the end portion is 0.113 mm, ridged. The aspect ratio of the lens was 0.288, the shaping rate at the center portion was 50%, and the shape at the end portion was 49%. The third layer of the central portion and the end portion has a thickness of 0.040 mm.

比較例4 Comparative example 4

除了以丙烯酸樹脂(a)(第1層及第3層)的擠出量分別為88.2kg/小時、丙烯酸樹脂(b)(第2層)的擠出量為63.5kg/小時之外,和實施例1同樣地製造了透鏡薄片。此結果,y/nx成為3.309。如以上得到的透鏡薄片之脊狀透鏡的間距為0.4mm,樹脂薄片的厚度為2.9mm,中央部及端部的脊狀透鏡的高度為0.112mm,脊狀透鏡的高寬比為0.280,中央部及端部的賦形率為48%。中央部的第3層厚度為0.600mm,端部的第3層厚度為0.597mm。 Except that the extrusion amount of the acrylic resin (a) (the first layer and the third layer) was 88.2 kg/hr, and the extrusion amount of the acrylic resin (b) (the second layer) was 63.5 kg/hr, and In the first embodiment, a lens sheet was produced in the same manner. As a result, y/nx becomes 3.309. The lenticular lens of the lens sheet obtained above has a pitch of 0.4 mm, the thickness of the resin sheet is 2.9 mm, the height of the ridge lens at the center portion and the end portion is 0.112 mm, and the aspect ratio of the ridge lens is 0.280, the center. The shaping rate of the part and the end is 48%. The third layer of the central portion has a thickness of 0.600 mm, and the third layer of the end portion has a thickness of 0.597 mm.

比較例5 Comparative Example 5

除了使用丙烯酸樹脂(a)取代丙烯酸樹脂(b)、加熱到260℃而擠出之外,其餘和和比較例1同樣的方式製造了透鏡薄片。從T型多歧管模具擠出的熔融狀態的薄片頻繁地破斷,無法進行穩定的製造。此外,所得到的透鏡薄片之脊狀透鏡的形狀不均勻,並不值得實用。 A lens sheet was produced in the same manner as in Comparative Example 1, except that the acrylic resin (a) was used instead of the acrylic resin (b) and heated to 260 ° C for extrusion. The molten sheet extruded from the T-type manifold mold is frequently broken, and stable production cannot be performed. Further, the shape of the lenticular lens of the obtained lens sheet is not uniform and is not worth practical.

比較例6 Comparative Example 6

除了將多層擠出T型多歧管模具變更為多層擠出T型進料方形模具之外,其餘以和實施例3同樣的方式製造了透鏡薄片。此結果,y/nx成為1.230。如以上得到的透鏡薄片之脊狀透鏡的間距為0.4mm,樹脂薄片的厚度為2.8mm,中央部的脊狀透鏡的高度為0.165mm,端部的脊狀透鏡的高度為0.114mm,脊狀透鏡的高寬比為0.413,中央部的賦形率為71%,端部的賦形率為49%。中央部的第3層厚度為0.230mm,端部的第3層厚度為0.088mm。 A lens sheet was produced in the same manner as in Example 3 except that the multilayer extruded T-type manifold mold was changed to a multilayer extruded T-type square mold. As a result, y/nx becomes 1.230. The lenticular lens of the lens sheet obtained above has a pitch of 0.4 mm, the thickness of the resin sheet is 2.8 mm, the height of the ridge lens at the center portion is 0.165 mm, and the height of the ridge lens at the end portion is 0.114 mm, ridge shape. The aspect ratio of the lens was 0.413, the shaping rate at the center portion was 71%, and the shape at the end portion was 49%. The third layer of the central portion has a thickness of 0.230 mm, and the third layer of the end portion has a thickness of 0.088 mm.

於表1中顯示在實施例及比較例中得到的透鏡薄片的y/nx之值及脊狀透鏡的高度、高寬比、賦形率等。 Table 1 shows the values of y/nx of the lens sheets obtained in the examples and the comparative examples, the heights of the lenticular lenses, the aspect ratio, the shaping ratio, and the like.

於第1圖中顯示在實施例1~5及比較例3、 4中得到的透鏡薄片之脊狀透鏡中央部的賦形率與y/nx之關係。 In the first embodiment, the first to fifth embodiments and the third comparative example are shown. The relationship between the shaping rate of the central portion of the lenticular lens of the lens sheet obtained in 4 and y/nx.

第1圖中的E1~E5係依序就實施例1、實施例2、實施例3、實施例4、實施例5進行顯示,C3、C4係分別就比較例3、比較例4進行顯示。 E1 to E5 in Fig. 1 are sequentially shown in the first embodiment, the second embodiment, the third embodiment, the fourth embodiment, and the fifth embodiment, and the C3 and C4 systems are respectively displayed in the comparative example 3 and the comparative example 4.

從第1圖及表1得知,在實施例1~5中得到的透鏡薄片相較於在比較例3及4中得到的透鏡薄片,賦形率及脊狀透鏡的高寬比較高。 As is apparent from Fig. 1 and Table 1, the lens sheets obtained in Examples 1 to 5 were higher in the forming ratio and the height and width of the lenticular lens than the lens sheets obtained in Comparative Examples 3 and 4.

此外,從比較例1及2得知,僅以丙烯酸樹脂(b)製作的透鏡薄片的賦形率及脊狀透鏡的高寬比較低,特別是在樹脂薄片的厚度厚的情況,其傾向大。 Further, from Comparative Examples 1 and 2, the shape ratio of the lens sheet made of the acrylic resin (b) and the height and width of the ridge lens are relatively low, and in particular, when the thickness of the resin sheet is thick, the tendency is large. .

此外,從比較例5得知,僅以丙烯酸樹脂(a)製作的透鏡薄片無法穩定地生產,透鏡的形狀也不均勻。 Further, from Comparative Example 5, it was found that the lens sheet produced only of the acrylic resin (a) could not be stably produced, and the shape of the lens was not uniform.

此外,從比較例6得知,不使用多歧管模具的透鏡薄片之由丙烯酸樹脂(a)構成之層的厚度在擠出寬度方向有差異,賦形率不均勻。 Further, as is understood from Comparative Example 6, the thickness of the layer composed of the acrylic resin (a) of the lens sheet which does not use the multi-manifold mold differs in the extrusion width direction, and the forming ratio is not uniform.

由以上的結果得知,藉由本發明之透鏡薄片的製造方法,即使樹脂薄片的厚度為3.0mm的較厚的情況,也可以實現高的賦形率,可得到脊狀透鏡的高寬比高的透鏡薄片。 From the above results, according to the method for producing a lens sheet of the present invention, even when the thickness of the resin sheet is 3.0 mm, a high forming ratio can be achieved, and an aspect ratio of the ridge lens can be obtained. Lens sheet.

Claims (2)

一種由透鏡薄片構成之導光板的擠出製造方法,其包含:第一步驟,係將熱塑性樹脂(A)與MFR(依據ISO1133,以230℃、負荷37.3N的條件測定之值)小於前述熱塑性樹脂(A)的熱塑性樹脂(B)及熱塑性樹脂(A)擠出成形,利用多歧管模具得到厚度2~20mm之熔融狀態的多層薄片,該熔融狀態的多層薄片係依序具備:第1層,其係由熱塑性樹脂(A)構成,每單位長度的體積為y(y為正數),並且為表層;第2層,其係由熱塑性樹脂(B)構成;及第3層,其係由熱塑性樹脂(A)構成;以及第二步驟,係使具有複數個該每單位長度的體積x(x為正數)滿足下式(1)且間距0.05~1.0mm的槽之賦形金屬模與由以第一步驟得到的熔融狀態的多層薄片之第1層構成的表面密合,形成n個(n為自然數)平行於擠出方向的脊狀透鏡,0.7≦y/nx≦2.0 (1)。 An extrusion manufacturing method of a light guide plate composed of a lens sheet, comprising: a first step of lowering thermoplastic resin (A) and MFR (value measured according to ISO 1133 at 230 ° C under a load of 37.3 N) The thermoplastic resin (B) and the thermoplastic resin (A) of the resin (A) are extrusion-molded, and a multilayer sheet having a thickness of 2 to 20 mm in a molten state is obtained by a multi-manifold mold, and the multilayer sheet in a molten state is sequentially provided: first a layer composed of a thermoplastic resin (A) having a volume per unit length of y (y is a positive number) and being a surface layer; a second layer comprising a thermoplastic resin (B); and a third layer And comprising a thermoplastic resin (A); and a second step of forming a shape of the groove having a volume x (x is a positive number) per unit length satisfying the following formula (1) and a pitch of 0.05 to 1.0 mm The surface composed of the first layer of the multilayer sheet in the molten state obtained in the first step is adhered to form n (n is a natural number) lenticular lens parallel to the extrusion direction, 0.7 ≦ y / n x ≦ 2.0 (1 ). 如申請專利範圍第1項之由透鏡薄片構成之導光板的擠出製造方法,其中前述y、n、x滿足下式(2):1.05≦y/nx≦1.4 (2)。 An extrusion manufacturing method of a light guide plate comprising a lens sheet according to the first aspect of the invention, wherein the y, n, and x satisfy the following formula (2): 1.05 ≦ y / n x ≦ 1.4 (2).
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