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TWI555890B - Yarns having infrared absorbing ability and textiles containing the yarns - Google Patents

Yarns having infrared absorbing ability and textiles containing the yarns Download PDF

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TWI555890B
TWI555890B TW102146830A TW102146830A TWI555890B TW I555890 B TWI555890 B TW I555890B TW 102146830 A TW102146830 A TW 102146830A TW 102146830 A TW102146830 A TW 102146830A TW I555890 B TWI555890 B TW I555890B
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fiber
fibers
yarn
infrared absorbing
powder
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TW102146830A
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TW201525212A (en
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黃泳彬
葉佩宜
張峻綺
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財團法人工業技術研究院
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Priority to CN201410455063.6A priority patent/CN104762711A/en
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Description

具有吸收紅外線功能的紗線及其紡織品 Yarn with infrared absorbing function and its textiles

本發明係有關於紗線的材料,特別有關於具有吸收紅外線功能的紗線及其製成的紡織品。 The present invention relates to materials for yarns, and more particularly to yarns having infrared absorbing functions and textiles made therefrom.

一般的紡織品要達到較佳的保暖效果,通常需藉由提高經緯密度或增加紡織品的厚度達成,但是這些方式會使得紡織品的透氣性變差且重量增加。 In order to achieve a better warming effect of a general textile, it is usually achieved by increasing the warp and weft density or increasing the thickness of the textile, but these methods may deteriorate the breathability of the textile and increase the weight.

另外,還可以使用動物羽絨作為充填物,或使用人造中空或多孔性纖維來製成紡織品,以達到保暖且輕量化的效果。然而,其製成的衣物具有高蓬鬆性,造成使用者活動不便。 In addition, it is also possible to use animal down as a filling or use artificial hollow or porous fibers to make a textile to achieve a warm and lightweight effect. However, the clothes made thereof are highly bulky, causing inconvenience to the user.

目前已發展出在紡織品內添加碳化鋯粉體來達到保暖效果,但是碳化鋯的添加會使得紡織品成為深黑色且價格昂貴,無法符合成本低且適用於淺色系的保暖紡織品之需求。 It has been developed to add zirconia powder to textiles to achieve warmth, but the addition of zirconium carbide makes textiles dark black and expensive, and cannot meet the needs of low cost and warm textiles suitable for light colors.

本揭示提供一種紗線的材料,其可以使得紗線具有吸收紅外線的功能,利用此紗線製成的紡織品具有保暖性,且適用於淺色系紡織品,同時還可以達到輕量化及避免紡織品過度蓬鬆,克服了習知技術的上述問題。 The present disclosure provides a material of a yarn which can make the yarn have a function of absorbing infrared rays, and the textile made of the yarn is warm-proof and suitable for light-colored textiles, and can also achieve weight reduction and avoid excessive textiles. Fluffy, overcoming the above problems of the prior art.

在本揭示之實施例中提供具有吸收紅外線功能的紗線,包括:組成紗線的纖維,其材質包含亞克力纖維、纖維素纖維或前述之組合;以及吸收紅外線粉體添加分散於此纖維內,吸收紅外線粉體的材質包括摻雜鎵的氧化鋅、摻雜鋁的氧化鋅、摻雜鎵和鋁的氧化鋅或前述之組合。 In the embodiment of the present disclosure, a yarn having an infrared absorbing function is provided, comprising: a fiber constituting a yarn, the material of which comprises an acrylic fiber, a cellulose fiber or a combination thereof; and an infrared absorbing powder is added and dispersed in the fiber, Materials for absorbing infrared powder include gallium-doped zinc oxide, aluminum-doped zinc oxide, gallium-doped and aluminum-doped zinc oxide, or a combination thereof.

此外,本揭示之實施例還提供一種具有吸收紅外線功能的紡織品,其包括複數條如上所述之具有吸收紅外線功能的紗線所製成。 Further, the embodiment of the present disclosure further provides a textile having an infrared absorbing function, which comprises a plurality of yarns having an infrared absorbing function as described above.

本揭示之具有吸收紅外線功能的紗線所製成的紡織品與未添加任何粉體的紡織品在平均可見光反射率的差異只有2%左右,這表示本揭示之具有吸收紅外線功能的紗線對紡織品的顏色改變很少,可適用於淺色系紡織品。 The difference between the average visible light reflectance of the textile made of the yarn having the function of absorbing infrared rays and the textile without adding any powder is only about 2%, which means that the yarn with infrared absorbing function disclosed in the present disclosure is for textiles. There are few color changes and it can be applied to light-colored textiles.

本揭示將吸收紅外線的粉體添加分散於製成紗線的纖維內,使得紗線具有吸收紅外線的功能,並使得由此紗線所製成的紡織品也具有吸收紅外線的功能,藉此讓紡織品可吸收紅外線而達到保暖效果,並且讓紡織品具有輕量化的優點及避免紡織品過度蓬鬆。 The disclosure discloses that the infrared absorbing powder is added and dispersed in the fiber of the yarn, so that the yarn has the function of absorbing infrared rays, and the textile made of the yarn also has the function of absorbing infrared rays, thereby allowing the textile to It absorbs infrared light to achieve warmth and gives textiles the advantage of being lightweight and avoids excessive fluffiness of textiles.

氧化鋅是一種半導體材料,為了提升其電氣或光學性質,通常摻雜第IIIA至VA族的元素,氧化鋅或摻雜第IIIA至VA族元素的氧化鋅通常應用在與半導體產業相關的產業 上,例如導電材料、壓電材料、氣體探測器或太陽能電池等。 Zinc oxide is a kind of semiconductor material. In order to improve its electrical or optical properties, it is usually doped with elements of Groups IIIA to VA. Zinc oxide or zinc oxide doped with Group IIIA to VA elements is usually used in industries related to the semiconductor industry. Upper, for example, a conductive material, a piezoelectric material, a gas detector, or a solar cell.

在本揭示之實施例中所使用的吸收紅外線粉體可以是摻雜鎵(Ga)、摻雜鋁(Al)、摻雜鎵(Ga)和鋁(Al)的氧化鋅(ZnO)粉體,或者是前述之組合,上述這些具有摻雜元素的氧化鋅粉體可吸收波長約在780nm以上的紅外線。 The absorbing infrared powder used in the embodiments of the present disclosure may be a gallium (Ga)-doped (Al)-doped aluminum (Al), gallium-doped (Ga)-doped (Al)-doped zinc oxide (ZnO) powder, Alternatively, in combination of the foregoing, the zinc oxide powder having the doping element may absorb infrared rays having a wavelength of about 780 nm or more.

本揭示之吸收紅外線粉體的製造方法可為:(1)將鋅的硝酸鹽或者硫酸鹽與摻雜元素(包括鎵、鋁)的氯化物或硫酸鹽配製成混合溶液,濃度為0.5ml/L~5.0ml/L,摻雜元素的添加量為鋅和摻雜元素總重量的0.1%~10.0%;(2)將步驟(1)中所配置的混合鹽溶液和碳酸氫銨溶液一起滴加到水中,過程中保持在40℃、pH值控制在7.0-7.5,同時強烈攪拌,即獲得均勻摻雜的白色鹼式碳酸鋅沉澱物生成;(3)將上述沉澱物經過洗滌分離後烘乾,所得的粉末在氫氣和氬氣的混合下燒結,燒結溫度400℃-700℃,時間30分鐘-60分鐘,燒結後即得到最終的摻雜鎵、摻雜鋁、摻雜鎵和鋁的氧化鋅粉體。 The method for producing the infrared absorbing powder disclosed in the present disclosure may be: (1) preparing a mixed solution of a nitrate or a sulfate of zinc with a chloride or a sulfate of a doping element (including gallium or aluminum) at a concentration of 0.5 ml. /L~5.0ml/L, the doping element is added in an amount of 0.1% to 10.0% of the total weight of the zinc and the doping element; (2) the mixed salt solution and the ammonium hydrogencarbonate solution disposed in the step (1) are together Dropping into water, maintaining the temperature at 40 ° C, the pH is controlled at 7.0-7.5, while stirring vigorously, that is, the uniformly doped white basic zinc carbonate precipitate is obtained; (3) after the above precipitate is washed and separated Drying, the obtained powder is sintered under the mixture of hydrogen and argon, sintering temperature 400 ° C -700 ° C, time 30 minutes -60 minutes, after sintering, the final doped gallium, doped aluminum, doped gallium and aluminum Zinc oxide powder.

在一些實施例中,於摻雜元素的氧化鋅粉體中,元素的摻雜比例為鋅和摻雜元素總重的約0.1至20重量百分比(wt%)。 In some embodiments, in the zinc oxide powder of the doping element, the doping ratio of the element is about 0.1 to 20 weight percent (wt%) of the total weight of the zinc and the doping element.

依據本揭示之實施例,可將上述吸收紅外線粉體均勻分散在亞克力纖維或纖維素纖維的材質中,形成複合材料,也可將粉體均勻分散在亞克力纖維或纖維素纖維的溶液中,形成分散液,然後將此複合材料或是分散液進行紡絲並形成具有吸收紅外線功能的紗線。 According to the embodiment of the present disclosure, the infrared absorbing powder can be uniformly dispersed in the material of the acrylic fiber or the cellulose fiber to form a composite material, or the powder can be uniformly dispersed in a solution of the acrylic fiber or the cellulose fiber to form a composite material. The dispersion is then spun and the dispersion is formed into a yarn having an infrared absorbing function.

由於亞克力纖維具有碳氮參鍵(C≡N)官能基,此 官能基的有助於提升分散在纖維內的吸收紅外線粉體的導電性以及提高亞克力纖維及其紗線之吸收紅外線的能力。 Since the acrylic fiber has a carbon-nitrogen bond (C≡N) functional group, this The functional group contributes to the improvement of the conductivity of the infrared absorbing powder dispersed in the fiber and the ability of the acrylic fiber and its yarn to absorb infrared rays.

此外,由於纖維素纖維具有大約10重量百分比(wt%)的含水量,此高含水量有助於提升分散在纖維內的吸收紅外線粉體的導電性以及提高纖維素纖維及其紗線之吸收紅外線的能力。 In addition, since the cellulose fibers have a water content of about 10% by weight (wt%), the high water content contributes to the improvement of the conductivity of the infrared absorbing powder dispersed in the fibers and the absorption of the cellulose fibers and their yarns. The ability of infrared.

在本揭示之實施例中,吸收紅外線粉體約佔纖維和吸收紅外線粉體總重的0.1至20重量百分比(wt%)。 In the embodiment of the present disclosure, the infrared absorbing powder accounts for about 0.1 to 20% by weight (wt%) based on the total weight of the fibers and the infrared absorbing powder.

在一些實施例中,可採用濕式紡絲工程製成具有吸收紅外線功能的纖維,其材質可以是聚丙烯腈(polyacrylonitrile;PAN)。首先將上述吸收紅外線粉體分散在溶劑中形成分散液,例如溶劑是二甲基乙醯胺(dimethyl acetamid;DMAc)。另外將聚丙烯腈溶解在相同的溶劑中形成溶液,接著將粉體分散液與聚丙烯腈溶液混合,形成紡絲溶液,或者可直接將吸收紅外線粉體分散在聚丙烯腈的溶液中,例如聚丙烯腈的DMAc溶液,以形成紡絲溶液。然後,以濕式紡絲工程,經過浸凝固液、延伸、乾燥及切斷等步驟,將紡絲溶液製成含有吸收紅外線粉體的亞克力纖維。 In some embodiments, a fiber having an infrared absorbing function may be formed by wet spinning, and the material may be polyacrylonitrile (PAN). First, the above-mentioned infrared absorbing powder is dispersed in a solvent to form a dispersion. For example, the solvent is dimethyl acetamid (DMAc). Further, the polyacrylonitrile is dissolved in the same solvent to form a solution, and then the powder dispersion is mixed with the polyacrylonitrile solution to form a spinning solution, or the infrared absorbing powder can be directly dispersed in a solution of polyacrylonitrile, for example, A DMAc solution of polyacrylonitrile to form a spinning solution. Then, the spinning solution is made into an acrylic fiber containing infrared absorbing powder by a wet spinning process through a step of immersion coagulating, stretching, drying, and cutting.

在一些實施例中,可採用濕式紡絲工程製成具有吸收紅外線功能的纖維,其材質可以是再生纖維素(regenerated cellulose)。從含有96%以上α纖維素之紙漿中可純化及磺化並製得磺酸鈉纖維素鹼黏液,首先將上述吸收紅外線粉體分散在溶劑中形成分散液,溶劑例如是NaOH水溶液,另外將磺酸鈉纖維素鹼黏液與粉體分散液混合,形成再生纖 維素紡絲黏液,或者可直接將吸收紅外線粉體分散在磺酸鈉纖維素鹼黏液中,使用的溶劑例如NaOH水溶液,以形成再生纖維素紡絲黏液。然後,將再生纖維素紡絲黏液輸送至紡絲機,再分配至各紡位之計量幫浦擠壓出,由白金製之紡絲嘴擠出於紡絲浴中。黏液離開紡絲嘴,隨即與紡絲浴內的凝固液進行凝固再生作用,在紡絲速度300~800m/min下,同時也接受延伸作用,使再生纖維素的分子獲得順向排列和應力引誘結晶作用,而具備纖維物性,絲束經倒出捲取成絲餅,再經除酸、脫硫、除鹼、水洗、脫水、上油、烘乾、回潮等,即可繞成筒裝嫘縈纖維或絞裝嫘縈纖維,完成嫘縈纖維製造。 In some embodiments, fibers having an infrared absorbing function may be formed by wet spinning, and the material may be regenerated cellulose. Purifying and sulfonating from a pulp containing more than 96% of α cellulose and preparing a sodium sulfonate alkali mucilage, first dispersing the above-mentioned infrared absorbing powder in a solvent to form a dispersion, the solvent is, for example, an aqueous NaOH solution, and the sulfonate is additionally Sodium cellulose alkali mucus mixed with powder dispersion to form recycled fiber Weaving the mucus, or directly dispersing the infrared absorbing powder in the sodium sulfonate alkali mucilage, using a solvent such as aqueous NaOH to form a regenerated cellulose spinning mucilage. Then, the regenerated cellulose spinning mucilage is conveyed to a spinning machine, and then distributed to a metering pump of each spinning position, and extruded from a spinning nozzle made of platinum to the spinning bath. The mucus leaves the spinning nozzle and then coagulates with the coagulating liquid in the spinning bath. At the spinning speed of 300~800m/min, it also accepts the extension, so that the regenerated cellulose molecules can be aligned and stressed. Crystallization, and fiber properties, the tow is taken up into a cake, and then de-acidified, desulfurized, de-alkali, washed, dehydrated, oiled, dried, regained, etc. The fiber is twisted or twisted to complete the fiber production.

在本揭示的一些實施例中,為避免造成纖維物性的大幅降低,上述吸收紅外線粉體的粒徑大都選擇低於800nm的尺寸,其中採用濕式紡絲工程製成纖維的實施例可使用粒徑較大的粉體,其吸收紅外線粉體的粒徑大都低於2,000nm的尺寸。 In some embodiments of the present disclosure, in order to avoid causing a large decrease in fiber physical properties, the particle size of the above-mentioned infrared absorbing powder is selected to be less than 800 nm, and examples in which the fiber is formed by wet spinning may be used. The powder having a large diameter, the particle size of the infrared absorbing powder is mostly less than 2,000 nm.

在一些實施例中,可將含有吸收紅外線粉體的亞克力纖維材質紡絲溶液或嫘縈纖維材質的紡絲黏液,以紡絲工程製成具有吸收紅外線功能的紗線。在一些實施例中,也可將含有吸收紅外線粉體的亞克力纖維或嫘縈纖維或前述之組合與其他的纖維進行混紡,製成具有吸收紅外線功能的混紡紗線。在一些實施例中,可將含有吸收紅外線粉體的紗線與其他的紗線進行合撚,製成具有吸收紅外線功能的合股紗線。 In some embodiments, a spinning dope containing an acrylic fiber material or a spinning dope of a rayon fiber material may be used to spin-process a yarn having an infrared absorbing function. In some embodiments, acrylic fibers or rayon fibers containing infrared absorbing powder or a combination thereof may be blended with other fibers to form a blended yarn having an infrared absorbing function. In some embodiments, the yarn containing the infrared absorbing powder may be combined with other yarns to form a plied yarn having an infrared absorbing function.

在一些實施例中,其他的纖維或其他的紗線可選 自於由聚乙烯纖維、聚丙烯纖維、聚醯胺纖維、聚酯纖維、亞克力纖維、聚丙烯酸酯纖維、聚氨基甲酸酯纖維、纖維素纖維、纖維素醋酸酯纖維、動物纖維(包括繭纖維、羊毛纖維及毛髮纖維等)及前述纖維之改質纖維等多種纖維所隨意組合的群組。上述纖維之改質纖維可藉由添加劑的混練或聚合的使用或是異形斷面或中空或其他方式而具有其他功能,例如抗紫外線、抗菌、抗靜電、陽離子可染、高氨價低溫可染、吸濕排汗及保暖等功能。 In some embodiments, other fibers or other yarns are optional From polyethylene fiber, polypropylene fiber, polyamide fiber, polyester fiber, acrylic fiber, polyacrylate fiber, polyurethane fiber, cellulose fiber, cellulose acetate fiber, animal fiber (including 茧A group in which a plurality of fibers such as fibers, wool fibers, and hair fibers, and modified fibers of the fibers are randomly combined. The modified fiber of the above fiber may have other functions by kneading or polymerizing the additive or by a profiled section or hollow or other means, such as anti-ultraviolet, antibacterial, antistatic, cationic dyeable, high ammonia low temperature dyeable. , moisture wicking and warmth and other functions.

在本揭示的一些實施例中,可單獨使用上述具有吸收紅外線功能的紗線製成紡織品,也可以使用上述具有吸收紅外線功能的紗線與其他的紗線製成紡織品,這些紡織品因為含有具吸收紅外線功能的紗線,因此有保暖的功效。 In some embodiments of the present disclosure, the above-mentioned yarn having an infrared absorbing function may be used alone to make a textile, and the above-mentioned yarn having an infrared absorbing function and other yarns may be used to make a textile, and these textiles have absorption due to absorption. The infrared function of the yarn, therefore, has the effect of keeping warm.

在一些實施例中,其他的紗線可選自於由聚乙烯纖維、聚丙烯纖維、聚醯胺纖維、聚酯纖維、亞克力纖維、聚丙烯酸酯纖維、聚氨基甲酸酯纖維、纖維素纖維、纖維素醋酸酯纖維、動物纖維(包括繭纖維、羊毛纖維及毛髮纖維等)及前述纖維之改質纖維等多種纖維所隨意組合的群組。 In some embodiments, the other yarns may be selected from the group consisting of polyethylene fibers, polypropylene fibers, polyamide fibers, polyester fibers, acrylic fibers, polyacrylate fibers, polyurethane fibers, cellulose fibers. A group in which a plurality of fibers such as cellulose acetate fibers, animal fibers (including rayon fibers, wool fibers, and hair fibers) and modified fibers of the fibers are randomly combined.

以下列舉各實施例說明本揭示之具有吸收紅外線功能的紗線及紡織品的製造方法與特性,並且與比較例之紗線及紡織品比較: The following describes the production methods and characteristics of the yarns and textiles having the infrared absorbing function of the present disclosure, and compares them with the yarns and textiles of the comparative examples:

實施例1-含摻雜鋁的氧化鋅粉體之亞克力纖維 Example 1 - Acrylic Fiber Containing Aluminum-Doped Zinc Oxide Powder

將摻雜鋁的氧化鋅粉體(鋁的摻雜量為鋅和鋁總重的1.2wt%)分散於聚丙烯腈的二甲基乙醯胺(DMAc)溶液中,其中以聚丙烯腈和摻雜鋁的氧化鋅粉體的總重為基準,粉體添加量為 0.8wt%,DMAc的使用量為85wt%。以紡絲工程製成2.0d及51mm的亞克力纖維,再與尼龍6/嫘縈/羊毛混紡,製成亞克力/尼龍6/嫘縈/羊毛(重量比為61/18/15/6)的2/48s紗線,最後製成12針的織片。對實施例1的織物進行近紅外線的照光溫升試驗,測得溫度為44.3℃;對實施例1的織物進行近紅外線吸收率試驗(波長範圍為1,000-2,500nm),測得平均近紅外線吸收率為50%。 Dispersing an aluminum-doped zinc oxide powder (a doping amount of aluminum of 1.2 wt% of the total weight of zinc and aluminum) in a solution of polyacrylonitrile in dimethylacetamide (DMAc), wherein polyacrylonitrile and The total weight of the aluminum-doped zinc oxide powder is based on the reference, and the amount of powder added is 0.8 wt%, the amount of DMAc used was 85 wt%. Made of 2.0d and 51mm acrylic fiber by spinning, and blended with nylon 6/嫘萦/wool to make acrylic/nylon 6/嫘萦/wool (weight ratio 61/18/15/6) 2 /48s yarn, and finally made a 12-pin woven piece. The fabric of Example 1 was subjected to a near-infrared illuminating temperature rise test, and the temperature was measured to be 44.3 ° C; the fabric of Example 1 was subjected to a near-infrared absorption test (wavelength range of 1,000 to 2,500 nm), and the average near-infrared absorption was measured. The rate is 50%.

比較例1-不含粉體的亞克力纖維 Comparative Example 1 - Acrylic fiber without powder

將2.0d及51mm之亞克力纖維與尼龍6/嫘縈/羊毛混紡成亞克力/尼龍6/嫘縈/羊毛(重量比為61/18/15/6)的2/48s紗線,再製成12針的織片。對比較例1的織片進行近紅外線的照光溫升試驗,測得溫度為42.0℃;對比較例1的織片進行近紅外線吸收率試驗(波長範圍為1,000-2,500nm),測得平均近紅外線吸收率為38%。 Blend 2.0d and 51mm acrylic fibers with nylon 6/嫘萦/wool into 2/48s yarn of acrylic/nylon 6/嫘萦/wool (weight ratio 61/18/15/6), then make 12 The woven piece of the needle. The woven sheet of Comparative Example 1 was subjected to a near-infrared illuminating temperature rise test, and the temperature was measured to be 42.0 ° C; the woven sheet of Comparative Example 1 was subjected to a near-infrared absorption rate test (wavelength range of 1,000 to 2,500 nm), and the average was measured. The infrared absorption rate was 38%.

實施例2-含摻雜鋁的氧化鋅粉體之嫘縈纖維 Example 2 - Tantalum fiber containing aluminum-doped zinc oxide powder

將摻雜鋁的氧化鋅粉體(鋁的摻雜量為鋅和鋁總重的1.2wt%)分散於磺酸鈉纖維素鹼黏液中,其中以摻雜鋁的氧化鋅粉體和再生纖維素的總重為基準,粉體添加量為0.8wt%。以紡絲工程製成1.2d及38mm的嫘縈纖維,再與棉花纖維混紡,製成嫘縈/棉(重量比為60/40)的30s/l紗線,最後製成布重200g/m2的圓編機針織布。對實施例2的圓編機針織布進行近紅外線的照光溫升試驗,測得溫度為44.4℃;對實施例2的圓編機針織布進行近紅外線吸收率試驗(波長範圍為1,000-2,500nm),測得平均近紅外線吸收率為53%。 The aluminum-doped zinc oxide powder (the doping amount of aluminum is 1.2 wt% of the total weight of zinc and aluminum) is dispersed in the sodium sulfonate alkali alkali mucilage, wherein the aluminum-doped zinc oxide powder and the recycled fiber are used. The total weight of the element was based on the basis, and the amount of powder added was 0.8% by weight. The 1.2d and 38mm rayon fibers were made by spinning, and then blended with cotton fiber to make 嫘萦/cotton (60/40 by weight) 30s/l yarn. The final fabric weight was 200g/m. 2 circular knitting machine knitted fabric. The circular knitting machine knitted fabric of Example 2 was subjected to a near-infrared illuminating temperature rise test, and the measured temperature was 44.4 ° C; the near-infrared absorption rate test was performed on the circular knitting machine knitted fabric of Example 2 (wavelength range was 1,000-2,500 nm). ), the average near-infrared absorption rate was measured to be 53%.

比較例2-不含粉體的嫘縈纖維 Comparative Example 2 - Non-powdered rayon fiber

將1.2d及38mm之嫘縈纖棉與棉花纖維混紡製成嫘縈/棉(重量比為60/40)的30s/l紗線,再製成布重200g/m2的圓編機針織布。對比較例2的圓編機針織布進行近紅外線的照光溫升試驗,測得溫度為42.5℃;對比較例2的圓編機針織布進行近紅外線吸收率試驗(波長範圍為1,000-2,500nm),測得平均近紅外線吸收率為40%。 The 1.2d and 38mm twisted cotton and cotton fiber were blended into a 30s/l yarn of 嫘萦/cotton (60/40 weight ratio), and then made into a circular knitting machine with a cloth weight of 200g/m 2 . . The circular knitting machine knitted fabric of Comparative Example 2 was subjected to a near-infrared illuminating temperature rise test, and the measured temperature was 42.5 ° C; the near-infrared absorption rate test was performed on the circular knitting machine knitted fabric of Comparative Example 2 (wavelength range was 1,000-2,500 nm). ), the average near-infrared absorption rate was measured to be 40%.

實施例3-含摻雜鋁的氧化鋅粉體之亞克力纖維 Example 3 - Acrylic Fiber Containing Aluminum-Doped Zinc Oxide Powder

實施例3與實施例1的差別在於摻雜鋁的氧化鋅粉體,其鋁的摻雜量為鋅和鋁總重的5.0wt%。以紡絲工程製成2.0d及51mm的亞克力纖維,再與尼龍6/嫘縈/羊毛混紡,製成亞克力/尼龍6/嫘縈/羊毛(重量比為61/18/15/6)的2/48s紗線,最後製成12針的織片。對實施例3的織片進行近紅外線的照光溫升試驗,測得溫度為48.0℃;對實施例3的織片進行近紅外線吸收率試驗(波長範圍為1,000-2,500nm),測得平均近紅外線吸收率為63%。 The difference between Example 3 and Example 1 is that the aluminum-doped zinc oxide powder has a doping amount of aluminum of 5.0% by weight based on the total weight of zinc and aluminum. Made of 2.0d and 51mm acrylic fiber by spinning, and blended with nylon 6/嫘萦/wool to make acrylic/nylon 6/嫘萦/wool (weight ratio 61/18/15/6) 2 /48s yarn, and finally made a 12-pin woven piece. The woven sheet of Example 3 was subjected to a near-infrared illuminating temperature rise test, and the temperature was measured to be 48.0 ° C; the woven sheet of Example 3 was subjected to a near-infrared absorption rate test (wavelength range of 1,000 to 2,500 nm), and the average was measured. The infrared absorption rate was 63%.

實施例4-含摻雜鋁的氧化鋅粉體之嫘縈纖維 Example 4 - Tantalum fiber containing aluminum-doped zinc oxide powder

實施例4與實施例2的差別在於摻雜鋁的氧化鋅粉體,其鋁的摻雜量為鋅和鋁總重的5.0wt%,並且以再生纖維素和摻雜鋁的氧化鋅粉體的總重為基準,粉體添加量為6.0wt%。以紡絲工程製成1.2d及38mm的嫘縈纖維,再與棉花纖維混紡製成嫘縈/棉(重量比為60/40)的30s/l紗線,最後製成布重200g/m2的圓編機針織布。對實施例4的圓編機針織布進行近紅外線的照光溫升試驗,測得溫度為49.8℃;對實施例4圓編機針織物 進行近紅外線吸收率試驗(波長範圍為1,000-2,500nm),測得平均近紅外線吸收率為69%。 The difference between Example 4 and Example 2 is that the aluminum-doped zinc oxide powder has a doping amount of aluminum of 5.0 wt% of the total weight of zinc and aluminum, and is a regenerated cellulose and an aluminum-doped zinc oxide powder. The total weight was based on the basis, and the amount of powder added was 6.0 wt%. The 1.2d and 38mm rayon fibers were made by spinning, and then blended with cotton fiber to make 嫘萦/cotton (weight ratio 60/40) 30s/l yarn, and finally made into cloth weight 200g/m 2 Circular knitting machine for knitting. The circular knitting machine knitted fabric of Example 4 was subjected to a near-infrared illuminating temperature rise test, and the measured temperature was 49.8 ° C; the near-infrared absorption rate test (wavelength range of 1,000-2,500 nm) was carried out on the knitted fabric of the circular knitting machine of Example 4. The average near-infrared absorption rate was measured to be 69%.

實施例5-含摻雜鋁的氧化鋅粉體之亞克力纖維 Example 5 - Acrylic fiber containing aluminum-doped zinc oxide powder

實施例5與實施例1的差別在於摻雜鋁的氧化鋅粉體,其鋁的摻雜量為鋅和鋁總重的10.0wt%。以紡絲工程製成2.0d及51mm的亞克力纖維,再與尼龍6/嫘縈/羊毛混紡,製成亞克力/尼龍6/嫘縈/羊毛(重量比為61/18/15/6)的2/48s紗線,最後製成12針的織片。對實施例5的織片進行近紅外線的照光溫升試驗,測得溫度為49.0℃;對實施例5的織片進行近紅外線吸收率試驗(波長範圍為1,000-2,500nm),測得平均近紅外線吸收率為65%。 The difference between Example 5 and Example 1 is that the aluminum-doped zinc oxide powder has a doping amount of aluminum of 10.0% by weight based on the total weight of zinc and aluminum. Made of 2.0d and 51mm acrylic fiber by spinning, and blended with nylon 6/嫘萦/wool to make acrylic/nylon 6/嫘萦/wool (weight ratio 61/18/15/6) 2 /48s yarn, and finally made a 12-pin woven piece. The woven sheet of Example 5 was subjected to a near-infrared illuminating temperature rise test, and the temperature was measured to be 49.0 ° C; the woven sheet of Example 5 was subjected to a near-infrared absorption rate test (wavelength range of 1,000 to 2,500 nm), and the average was measured. The infrared absorption rate is 65%.

實施例6-含摻雜鎵的氧化鋅粉體之亞克力纖維 Example 6 - Acrylic fiber containing gallium-doped zinc oxide powder

實施例6與實施例1的差別在於使用摻雜鎵的氧化鋅粉體,其鎵的摻雜量為鋅和鎵總重的2.2wt%,並且以亞克力纖維和摻雜鎵的氧化鋅粉體的總重為基準,粉體添加量為0.2wt%。以紡絲工程製成2.0d及51mm的亞克力纖維,再與尼龍6/嫘縈/羊毛混紡,製成亞克力/尼龍6/嫘縈/羊毛(重量比為61/18/15/6)的2/48s紗線,最後製成12針的織片。對實施例6的織片進行近紅外線的照光溫升試驗,測得溫度為44.5℃;對實施例6的織片進行近紅外線吸收率試驗(波長範圍為1,000-2,500nm),測得平均近紅外線吸收率為52%。 The difference between Example 6 and Example 1 is that the gallium-doped zinc oxide powder is used, the doping amount of gallium is 2.2 wt% of the total weight of zinc and gallium, and the acrylic fiber and the gallium-doped zinc oxide powder are used. The total weight was based on the basis, and the powder addition amount was 0.2% by weight. Made of 2.0d and 51mm acrylic fiber by spinning, and blended with nylon 6/嫘萦/wool to make acrylic/nylon 6/嫘萦/wool (weight ratio 61/18/15/6) 2 /48s yarn, and finally made a 12-pin woven piece. The woven sheet of Example 6 was subjected to a near-infrared illuminating temperature rise test, and the temperature was measured to be 44.5 ° C; the woven sheet of Example 6 was subjected to a near-infrared absorption rate test (wavelength range of 1,000 to 2,500 nm), and the average was measured. The infrared absorption rate was 52%.

實施例7-含摻雜鎵的氧化鋅粉體之亞克力纖維 Example 7 - Acrylic fiber containing gallium-doped zinc oxide powder

實施例7與實施例6的差別在於摻雜鎵的氧化鋅粉體,其鎵的摻雜量為鋅和鎵總重的5.0wt%,並且以亞克力纖維和摻雜鎵 的氧化鋅粉體的總重為基準,粉體添加量為5.0wt%。以紡絲工程製成2.0d及51mm的亞克力纖維,再與尼龍6/嫘縈/羊毛混紡,製成亞克力/尼龍6/嫘縈/羊毛(重量比為61/18/15/6)的2/48s紗線,最後製成12針的織片。對實施例7的織片進行近紅外線的照光溫升試驗,測得溫度為55℃;對實施例7的織片進行近紅外線吸收率試驗(波長範圍為1,000-2,500nm),測得平均近紅外線吸收率為93%。 The difference between Example 7 and Example 6 is that the gallium-doped zinc oxide powder has a gallium doping amount of 5.0 wt% of the total weight of zinc and gallium, and is made of acrylic fiber and doped gallium. The total weight of the zinc oxide powder was based on the basis, and the powder addition amount was 5.0% by weight. Made of 2.0d and 51mm acrylic fiber by spinning, and blended with nylon 6/嫘萦/wool to make acrylic/nylon 6/嫘萦/wool (weight ratio 61/18/15/6) 2 /48s yarn, and finally made a 12-pin woven piece. The woven sheet of Example 7 was subjected to a near-infrared illuminating temperature rise test, and the temperature was measured to be 55 ° C; the woven sheet of Example 7 was subjected to a near-infrared absorption rate test (wavelength range of 1,000 to 2,500 nm), and the average was measured. The infrared absorption rate was 93%.

實施例8-含摻雜鎵的氧化鋅粉體之亞克力纖維 Example 8 - Acrylic fiber containing gallium-doped zinc oxide powder

實施例8與實施例6的差別在於摻雜鎵的氧化鋅粉體,其鎵的摻雜量為鋅和鎵總重的10.0wt%,並且以亞克力和摻雜鎵的氧化鋅粉體的總重為基準,粉體添加量為0.5wt%。以紡絲工程製成2.0d及51mm的亞克力纖維,再與尼龍6/嫘縈/羊毛混紡,製成亞克力/尼龍6/嫘縈/羊毛(重量比為61/18/15/6)的2/48s紗線,最後製成12針的織片。對實施例8的織片進行近紅外線的照光溫升試驗,測得溫度為51℃;對實施例8的織片進行近紅外線吸收率試驗(波長範圍為1,000-2,500nm),測得平均近紅外線吸收率為81%。 The difference between Example 8 and Example 6 is that the gallium-doped zinc oxide powder has a gallium doping amount of 10.0% by weight of the total weight of zinc and gallium, and a total of acrylic and gallium-doped zinc oxide powder. Based on the weight, the powder was added in an amount of 0.5% by weight. Made of 2.0d and 51mm acrylic fiber by spinning, and blended with nylon 6/嫘萦/wool to make acrylic/nylon 6/嫘萦/wool (weight ratio 61/18/15/6) 2 /48s yarn, and finally made a 12-pin woven piece. The woven sheet of Example 8 was subjected to a near-infrared illuminating temperature rise test, and the temperature was measured to be 51 ° C; the woven sheet of Example 8 was subjected to a near-infrared absorption rate test (wavelength range of 1,000 to 2,500 nm), and the average was measured. The infrared absorption rate was 81%.

實施例9-含摻雜鎵的氧化鋅粉體之嫘縈纖維 Example 9 - Tantalum fiber containing gallium-doped zinc oxide powder

實施例9與實施例2的差別在於摻雜鎵的氧化鋅粉體,其鎵的摻雜量為鋅和鎵總重的2.2wt%,並且以再生纖維素和摻雜鎵的氧化鋅粉體的總重為基準,粉體添加量為0.2wt%。以紡絲工程製成1.2d及38mm的嫘縈纖維,再與棉花纖維混紡製成嫘縈/棉(重量比為60/40)的30s/l紗線,最後製成布重200g/m2的圓編機針織布。對實施例9的圓編機針織布進行近紅外線的 照光溫升試驗,測得溫度為44.7℃;對實施例9的圓編機針織布進行近紅外線吸收率試驗(波長範圍為1,000-2,500nm),測得平均近紅外線吸收率為55%。 The difference between Example 9 and Example 2 is that the gallium-doped zinc oxide powder has a gallium doping amount of 2.2 wt% of the total weight of zinc and gallium, and is a regenerated cellulose and a gallium-doped zinc oxide powder. The total weight was based on the basis, and the powder addition amount was 0.2% by weight. The 1.2d and 38mm rayon fibers were made by spinning, and then blended with cotton fiber to make 嫘萦/cotton (weight ratio 60/40) 30s/l yarn, and finally made into cloth weight 200g/m 2 Circular knitting machine for knitting. The circular knitting machine knitted fabric of Example 9 was subjected to a near-infrared illuminating temperature rise test, and the measured temperature was 44.7 ° C; the near-infrared absorption rate test was performed on the circular knitting machine knitted fabric of Example 9 (wavelength range was 1,000-2,500 nm). ), the average near-infrared absorption rate was measured to be 55%.

實施例10-含摻雜鎵的氧化鋅粉體之嫘縈纖維 Example 10 - Tantalum fiber containing gallium-doped zinc oxide powder

實施例10與實施例9的差別在於摻雜鎵的氧化鋅粉體,其鎵的摻雜量為鋅和鎵總重的5.0wt%,並且以再生纖維素和摻雜鎵的氧化鋅粉體的總重為基準,粉體添加量為5.0wt%。以紡絲工程製成1.2d及38mm的嫘縈纖維,再與棉花纖維混紡製成嫘縈/棉(重量比為60/40)的30s/l紗線,最後製成布重200g/m2的圓編機針織布。對實施例10的圓編機針織布進行近紅外線的照光溫升試驗,測得溫度為56.0℃;對實施例10的圓編機針織布進行近紅外線吸收率試驗(波長範圍為1,000-2,500nm),測得平均近紅外線吸收率為93%。 The difference between Example 10 and Example 9 is that the gallium-doped zinc oxide powder has a gallium doping amount of 5.0 wt% of the total weight of zinc and gallium, and is a regenerated cellulose and a gallium-doped zinc oxide powder. The total weight was based on the basis, and the powder addition amount was 5.0% by weight. The 1.2d and 38mm rayon fibers were made by spinning, and then blended with cotton fiber to make 嫘萦/cotton (weight ratio 60/40) 30s/l yarn, and finally made into cloth weight 200g/m 2 Circular knitting machine for knitting. The circular knitting machine knitted fabric of Example 10 was subjected to a near-infrared illuminating temperature rise test, and the measured temperature was 56.0 ° C; the near-infrared absorption rate test was performed on the circular knitting machine knitted fabric of Example 10 (wavelength range was 1,000-2,500 nm). ), the average near-infrared absorption rate was measured to be 93%.

比較例3-含摻雜鋁的氧化鋅粉體之聚酯纖維 Comparative Example 3 - Polyester fiber containing aluminum-doped zinc oxide powder

比較例3使用摻雜鋁的氧化鋅粉體添加分散於聚酯纖維內,其中鋁的摻雜量為鋅和鋁總重的5.0wt%,並且以聚丙烯和摻雜鋁的氧化鋅粉體的總重為基準,粉體添加量為6.0wt%。以紡絲工程製成2.0d及51mm的聚酯纖維,再與尼龍6/嫘縈/羊毛混紡,製成聚酯/尼龍6/嫘縈/羊毛(重量比為61/18/15/6)的2/48s紗線,最後製成12針的織片。對比較例3的織物進行近紅外線吸收率試驗(波長範圍為1,000-2,500nm),測得平均近紅外線吸收率為60%。 Comparative Example 3 was dispersed and dispersed in a polyester fiber using an aluminum-doped zinc oxide powder in which the doping amount of aluminum was 5.0 wt% of the total weight of zinc and aluminum, and the polypropylene and the aluminum-doped zinc oxide powder were used. The total weight was based on the basis, and the amount of powder added was 6.0 wt%. Made of 2.0d and 51mm polyester fiber by spinning, and blended with nylon 6/嫘萦/wool to make polyester/nylon 6/嫘萦/wool (weight ratio 61/18/15/6) The 2/48s yarn is finally made into a 12-needle woven piece. The fabric of Comparative Example 3 was subjected to a near-infrared absorption rate test (wavelength range of 1,000 to 2,500 nm), and the average near-infrared absorption rate was measured to be 60%.

比較例4-含摻雜鎵的氧化鋅粉體之尼龍6纖維 Comparative Example 4 - Nylon 6 fiber containing gallium-doped zinc oxide powder

比較例4使用摻雜鎵的氧化鋅粉體添加分散於尼龍6纖維內, 其中鎵的摻雜量為鋅和鎵總重的5.0wt%,並且以尼龍6和摻雜鎵的氧化鋅粉體的總重為基準,粉體添加量為5.0wt%。以紡絲工程製成2.0d及51mm的尼龍6保暖纖維,再與尼龍6/嫘縈/羊毛混紡,製成尼龍6(保暖)/尼龍6/嫘縈/羊毛(重量比為61/18/15/6)的2/48s紗線,最後製成12針的織片。對比較例4的針織布進行近紅外線吸收率試驗(波長範圍為1,000-2,500nm),測得平均近紅外線吸收率為87%。 Comparative Example 4 was added to the nylon 6 fiber by using a gallium-doped zinc oxide powder. The doping amount of gallium is 5.0 wt% of the total weight of zinc and gallium, and the powder is added in an amount of 5.0 wt% based on the total weight of the nylon 6 and the gallium-doped zinc oxide powder. Made of 2.0d and 51mm nylon 6 warm fiber by spinning, and blended with nylon 6/嫘萦/wool to make nylon 6 (warm)/nylon 6/嫘萦/wool (weight ratio 61/18/ 15/6) 2/48s yarn, and finally made 12-pin woven. The knitted fabric of Comparative Example 4 was subjected to a near-infrared absorption rate test (wavelength range of 1,000 to 2,500 nm), and the average near-infrared absorption rate was measured to be 87%.

比較上述使用摻雜鋁的氧化鋅粉體之各實施例與各比較例的織物之成分與特性,如表1所列。 The composition and characteristics of the fabrics of the respective examples using the aluminum-doped zinc oxide powder and the comparative examples described above were compared as listed in Table 1.

由表1可得知,使用摻雜鋁的氧化鋅粉體添加分散於亞克力纖維或嫘縈纖維內,其製成的織物相較於未添加粉體的織物具有較高的平均近紅外線吸收率和照光溫升試驗溫度,表示本揭示實施例之織物可達到較佳的保暖效果。 It can be seen from Table 1 that the aluminum-doped zinc oxide powder is dispersed and dispersed in the acrylic fiber or the rayon fiber, and the woven fabric has a higher average near-infrared absorbing rate than the woven fabric without the powder. And the illumination temperature rise test temperature, indicating that the fabric of the embodiment of the present disclosure can achieve a better warmth effect.

此外,使用鋁摻雜量較高的氧化鋅粉體以及/或粉 體添加量較高的粉體添加分散於纖維內,其製成的織物具有較高的平均近紅外線吸收率和照光溫升試驗溫度,表示鋁元素的摻雜量較高以及粉體添加量較高有助於達到較佳的保暖效果。 In addition, zinc oxide powder and/or powder with a high amount of aluminum doping is used. The powder with higher body addition is dispersed and dispersed in the fiber, and the fabric made thereof has a high average near-infrared absorption rate and a temperature rise test temperature, indicating that the doping amount of the aluminum element is higher and the powder addition amount is higher. High helps to achieve better warmth.

另外,以相同的鋁摻雜量和粉體添加量為基準,本揭示實施例4之嫘縈纖維所製成的織物相較於比較例3之聚酯纖維所製成的織物具有較高的平均近紅外線吸收率,表示本揭示實施例之嫘縈纖維相較於聚酯纖維可達到較佳的保暖效果。 In addition, the fabric made of the ray fiber of Example 4 of the present disclosure has a higher fabric than that of the polyester fiber of Comparative Example 3, based on the same aluminum doping amount and powder addition amount. The average near-infrared absorption rate indicates that the ruthenium fiber of the embodiment of the present disclosure can achieve a better warming effect than the polyester fiber.

比較上述使用摻雜鎵的氧化鋅粉體之各實施例與各比較例的織物之成分與特性,如表2所列。 The composition and characteristics of the fabrics of the respective examples of the use of the gallium-doped zinc oxide powder and the comparative examples are as shown in Table 2.

由表2可得知,使用雜摻鎵的氧化鋅粉體添加分散於亞克力纖維或嫘縈纖維內,其製成的織物相較於未添加粉體的織物具有較高的平均近紅外線吸收率和照光溫升試驗溫度,表示本揭示實施例之織物可達到較佳的保暖效果。 It can be seen from Table 2 that the zinc-doped zinc oxide powder is dispersed and dispersed in the acrylic fiber or the yttrium fiber, and the woven fabric has a higher average near-infrared absorbing rate than the woven fabric without the powder. And the illumination temperature rise test temperature, indicating that the fabric of the embodiment of the present disclosure can achieve a better warmth effect.

此外,使用鎵摻雜量較高的氧化鋅粉體以及/或粉體添加量較高的粉體添加分散於纖維內,其製成的織物具有較高的平均近紅外線吸收率和照光溫升試驗溫度,表示鎵元素的摻雜量較高以及粉體添加量較高有助於達到較佳的保暖效果。 In addition, a zinc oxide powder having a higher amount of gallium doping and/or a powder having a higher amount of powder added are dispersed and dispersed in the fiber, and the resulting fabric has a high average near-infrared absorption rate and an illumination temperature rise. The test temperature indicates that the doping amount of the gallium element is high and the powder addition amount is high to help achieve a better warming effect.

另外,以相同的鎵摻雜量和粉體添加量為基準,本揭示實施例7之亞克力纖維和實施例10之嫘縈纖維所製成的織物相較於比較例4之尼龍6纖維所製成的織物具有較高的平均近紅外線吸收率和照光溫升試驗溫度,表示本揭示實施例之亞克力纖維和嫘縈纖維相較於尼龍6纖維可達到較佳的保暖效果。 Further, the acryl fiber of the embossing Example 7 and the woven fiber of Example 10 were compared with the nylon 6 fiber of Comparative Example 4, based on the same amount of gallium doping and the amount of powder added. The resulting fabric has a high average near-infrared absorption rate and an illumination temperature rise test temperature, indicating that the acrylic fibers and the ray fibers of the disclosed embodiments can achieve a better warming effect than the nylon 6 fibers.

綜上所述,本揭示之實施例使用摻雜鋁、鎵的氧化鋅粉體添加分散於亞克力纖維或嫘縈纖維內,製成具有吸收紅外線功能的紗線及織物,相較於未添加粉體的織物,以及相較於添加相同粉體且添加量相同的織物,本揭示之紗線所製成的織物具有較高的平均近紅外線吸收率和照光溫升試驗溫度,這證實本揭示使用摻雜鋁以及/或鎵的氧化鋅粉體添加分散於亞克力纖維或嫘縈纖維內,其製成的紗線和紡織品可達到較佳的保暖效果。 In summary, the embodiments of the present disclosure use aluminum-doped or gallium-doped zinc oxide powder to be dispersed in acrylic fibers or ruthenium fibers to form yarns and fabrics having infrared absorbing functions, compared to un-added powder. The fabric of the body, and the fabric made of the yarn of the present disclosure have a higher average near-infrared absorption rate and an illumination temperature rise test temperature than the fabric added with the same powder, which confirms the use of the present disclosure. The zinc oxide powder doped with aluminum and/or gallium is added and dispersed in the acrylic fiber or the ytterbium fiber, and the yarn and the textile made by the yarn can achieve better warming effect.

雖然本發明已揭露較佳實施例如上,然其並非用以限定本發明,在此技術領域中具有通常知識者當可瞭解,在不脫離本發明之精神和範圍內,當可做些許更動與潤飾。因此,本發明之保護範圍當視後附之申請專利範圍所界定為準。 While the present invention has been described in its preferred embodiments, it is not intended to limit the invention, and it is understood by those of ordinary skill in the art that Retouching. Accordingly, the scope of the invention is defined by the scope of the appended claims.

Claims (10)

一種具有吸收紅外線功能的紗線,包括:一組成紗線的纖維,該纖維的材質包含亞克力纖維;以及一吸收紅外線粉體,添加分散於該纖維內,該吸收紅外線粉體的材質包括摻雜鎵的氧化鋅、摻雜鋁的氧化鋅、摻雜鎵和鋁的氧化鋅或前述之組合。 The invention relates to a yarn having an infrared absorbing function, comprising: a fiber constituting a yarn, the fiber material comprises acrylic fiber; and an infrared absorbing powder is added and dispersed in the fiber, and the material for absorbing the infrared powder comprises doping. Gallium zinc oxide, aluminum-doped zinc oxide, gallium-doped and aluminum-doped zinc oxide, or a combination thereof. 如申請專利範圍第1項所述之具有吸收紅外線功能的紗線,其中在該吸收紅外線粉體中,摻雜元素鎵、鋁、或鎵和鋁的摻雜量為該粉體中的鋅和該摻雜元素之總重的0.1至20重量百分比。 The yarn having an infrared absorbing function according to claim 1, wherein in the infrared absorbing powder, the doping amount of the doping element gallium, aluminum, or gallium and aluminum is zinc and The total weight of the doping element is 0.1 to 20 weight percent. 如申請專利範圍第1項所述之具有吸收紅外線功能的紗線,其中該吸收紅外線粉體重量為組成紗線的該纖維和該吸收紅外線粉體總重的0.1至20重量百分比。 The yarn having an infrared absorbing function as described in claim 1, wherein the infrared absorbing powder has a weight of 0.1 to 20% by weight based on the total weight of the fiber constituting the yarn and the infrared absorbing powder. 如申請專利範圍第1項所述之具有吸收紅外線功能的紗線,更包括一另一纖維與含有該吸收紅外線粉體的該纖維混紡形成一混紡紗線。 The yarn having the infrared absorbing function as described in claim 1 further comprises a further fiber blended with the fiber containing the infrared absorbing powder to form a blended yarn. 如申請專利範圍第4項所述之具有吸收紅外線功能的紗線,其中該另一纖維的材質係選自於由聚乙烯纖維、聚丙烯纖維、聚醯胺纖維、聚酯纖維、亞克力纖維、聚丙烯酸酯纖維、聚氨基甲酸酯纖維、纖維素纖維、纖維素醋酸酯纖維、動物纖維及前述纖維之改質纖維所組合的群組,其中該動物纖維包括繭纖維、羊毛纖維、毛髮纖維或前述之組合。 The yarn having an infrared absorbing function as described in claim 4, wherein the material of the other fiber is selected from the group consisting of polyethylene fiber, polypropylene fiber, polyamide fiber, polyester fiber, acrylic fiber, a combination of polyacrylate fibers, polyurethane fibers, cellulose fibers, cellulose acetate fibers, animal fibers, and modified fibers of the foregoing fibers, wherein the animal fibers comprise rayon fibers, wool fibers, hair fibers Or a combination of the foregoing. 如申請專利範圍第1項所述之具有吸收紅外線功能的紗線,更包括一另一紗線與含有該吸收紅外線粉體的該纖維所 組成的紗線合撚形成一合股紗線。 A yarn having an infrared absorbing function as described in claim 1 further comprising a further yarn and the fiber containing the infrared absorbing powder. The resulting yarns are combined to form a plied yarn. 如申請專利範圍第6項所述之具有吸收紅外線功能的紗線,其中該另一紗線的材質係選自於由聚乙烯纖維、聚丙烯纖維、聚醯胺纖維、聚酯纖維、亞克力纖維、聚丙烯酸酯纖維、聚氨基甲酸酯纖維、纖維素纖維、纖維素醋酸酯纖維、動物纖維及前述纖維之改質纖維所組合的群組,其中該動物纖維包括繭纖維、羊毛纖維、毛髮纖維或前述之組合。 The yarn having an infrared absorbing function according to claim 6, wherein the material of the other yarn is selected from the group consisting of polyethylene fiber, polypropylene fiber, polyamide fiber, polyester fiber, and acrylic fiber. a combination of a polyacrylate fiber, a polyurethane fiber, a cellulose fiber, a cellulose acetate fiber, an animal fiber, and a modified fiber of the foregoing fiber, wherein the animal fiber comprises rayon fiber, wool fiber, hair Fiber or a combination of the foregoing. 一種具有吸收紅外線功能的紡織品,包括:複數條如申請專利範圍第1項所述之具有吸收紅外線功能的紗線所製成。 A textile having an infrared absorbing function, comprising: a plurality of yarns made of a yarn having an infrared absorbing function as described in claim 1 of the patent application. 如申請專利範圍第8項所述之具有吸收紅外線功能的紡織品,更包括複數條另一紗線與該具有吸收紅外線功能的紗線所共同製成。 The textile having the infrared absorbing function as described in claim 8 of the patent application, further comprising a plurality of other yarns and the yarn having the function of absorbing infrared rays. 如申請專利範圍第9項所述之具有吸收紅外線功能的紡織品,其中該另一紗線的材質係選自於由聚乙烯纖維、聚丙烯纖維、聚醯胺纖維、聚酯纖維、亞克力纖維、聚丙烯酸酯纖維、聚氨基甲酸酯纖維、纖維素纖維、纖維素醋酸酯纖維、動物纖維及前述纖維之改質纖維所組合的群組,其中該動物纖維包括繭纖維、羊毛纖維、毛髮纖維或前述之組合。 The textile having the function of absorbing infrared rays according to claim 9, wherein the material of the other yarn is selected from the group consisting of polyethylene fiber, polypropylene fiber, polyamide fiber, polyester fiber, acrylic fiber, a combination of polyacrylate fibers, polyurethane fibers, cellulose fibers, cellulose acetate fibers, animal fibers, and modified fibers of the foregoing fibers, wherein the animal fibers comprise rayon fibers, wool fibers, hair fibers Or a combination of the foregoing.
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