TWI457160B - Golf ball having high initial velocity - Google Patents
Golf ball having high initial velocity Download PDFInfo
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- TWI457160B TWI457160B TW100129080A TW100129080A TWI457160B TW I457160 B TWI457160 B TW I457160B TW 100129080 A TW100129080 A TW 100129080A TW 100129080 A TW100129080 A TW 100129080A TW I457160 B TWI457160 B TW I457160B
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Classifications
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- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
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- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/02—Special cores
- A63B37/06—Elastic cores
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- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/0023—Covers
- A63B37/0029—Physical properties
- A63B37/003—Coefficient of restitution
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- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/005—Cores
- A63B37/006—Physical properties
- A63B37/0061—Coefficient of restitution
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- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/007—Characteristics of the ball as a whole
- A63B37/0077—Physical properties
- A63B37/0078—Coefficient of restitution
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- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/007—Characteristics of the ball as a whole
- A63B37/0077—Physical properties
- A63B37/0084—Initial velocity
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- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/02—Special cores
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/007—Characteristics of the ball as a whole
- A63B37/0072—Characteristics of the ball as a whole with a specified number of layers
- A63B37/0076—Multi-piece balls, i.e. having two or more intermediate layers
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- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/12—Special coverings, i.e. outer layer material
Landscapes
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Physical Education & Sports Medicine (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
- Professional, Industrial, Or Sporting Protective Garments (AREA)
Description
本申請案依據35 U.S.C.§119(e)請求名稱為“具有高初始速度之高爾夫球(Golf Ball Having High Initial Velocity)”且在2010年8月20日申請之美國暫時專利申請案第61/375,775號的優先權,該申請案在此加入作為參考。This application is based on 35 USC § 119(e), entitled "Golf Ball Having High Initial Velocity", and U.S. Provisional Patent Application No. 61/375,775, filed on Aug. 20, 2010. Priority is hereby incorporated by reference.
本發明係大致有關於一種具有多數層之高爾夫球。該等層係設計成具有恢復係數與壓縮之一特定關係以便得到一高初始速度。The present invention is generally directed to a golf ball having a plurality of layers. The layers are designed to have a specific relationship between the recovery factor and compression to achieve a high initial velocity.
製造具有多數層之高爾夫球在工業中是標準的。個人設計者在該工業中會感覺到某些特性比其他的特性更重要,且會設計一高爾夫球以使某些特性最適當化。個人設計者亦會感覺到某些特性比其他的特性更重要或更需要。Making golf balls with most layers is standard in the industry. Individual designers in the industry will feel that certain characteristics are more important than others, and a golf ball will be designed to optimize certain characteristics. Individual designers will also feel that certain characteristics are more important or needed than others.
在許多情形下,高爾夫球員希望高爾夫球提供越長越好的開球。除了高爾夫球員之控制以外,開球長度亦受到許多因素控制,例如該發球區(tee box)及該球道之相對高度,在或靠近該球道之障礙物,風速,及氣候等。開球長度亦受到該高爾夫球員之揮桿參數控制,例如他或她的球桿頭速度,他或她的健康狀態,及他或她為一特殊開球選擇使用之球桿。開球長度亦受該離開該開球木桿(driver)時 之初始速度控制。In many cases, the golfer wants the golf ball to provide the longer the better the kickoff. In addition to the golfer's control, the length of the tee shot is also controlled by a number of factors, such as the tee box and the relative height of the fairway, obstacles at or near the fairway, wind speed, and climate. The length of the tee shot is also controlled by the golfer's swing parameters, such as his or her club head speed, his or her health status, and the club he or she chooses for a particular kickoff. The length of the tee shot is also affected by the departure of the driver. The initial speed control.
在其他情形中,例如,在打短桿(short game)時,高爾夫球員需要在擊球時具有一良好傳感(feel)及良好旋轉/旋轉性之高爾夫球。一高爾夫球之傳感經常受到製成一或多數覆蓋層之材料控制。該覆蓋材料之選擇亦可依據耐用性、耐擦性、及顏色等決定。In other situations, for example, when playing a short game, the golfer needs to have a good feel and a good spin/rotation golf ball when hitting the ball. The sensing of a golf ball is often controlled by the material from which one or more cover layers are made. The choice of the covering material can also be determined based on durability, rub resistance, and color.
許多高爾夫球員需要在該球軌跡之長度與該球之傳感之間的一平衡。雖然某些高爾夫球員只想要其中一個或另一個,但是更可能的是一高爾夫球員將會想要這些特徵之一平衡。Many golfers need a balance between the length of the ball track and the sensing of the ball. While some golfers only want one or the other, it is more likely that a golfer will want to balance one of these features.
因此,需要發展包括一良好傳感及一最大初始速度之特徵之組合的一球。一高爾夫球員在擊球時通常認為這些特徵之組合是必要的。Therefore, there is a need to develop a ball that includes a combination of good sensing and a feature of a maximum initial velocity. A golfer generally considers a combination of these features necessary when hitting the ball.
在一實施例中,提供一高爾夫球。該高爾夫球可具有一球心及一包圍該球心之覆蓋物。該覆蓋物包含一高度中和化聚合物。該球心可包含一和緩化材料。該球心可具有一第一恢復係數且該球可具有一第二恢復係數。在該第一恢復係數與該第二恢復係數之間的差小於大約0.032。In an embodiment, a golf ball is provided. The golf ball can have a center of the ball and a cover that surrounds the center of the ball. The cover comprises a highly neutralized polymer. The core may comprise a mildening material. The ball core can have a first recovery factor and the ball can have a second recovery factor. The difference between the first recovery factor and the second recovery coefficient is less than about 0.032.
在另一實施例中,提供一高爾夫球。該高爾夫球可具有一球心及一包圍該球心之覆蓋物。該球心可具有一壓縮x。該球之恢復係數可用該式0.6511-0.024x2 +0.1165x表示。該球心之恢復係數可用該式0.7951-0.0121x2 +0.416x表示。依據這趨勢線製成之任何球的恢復係數可定上限以產生一合格球。使用該和緩化材料作為該覆蓋物可容許一設計者產生使用一高能球心之一合格球。In another embodiment, a golf ball is provided. The golf ball can have a center of the ball and a cover that surrounds the center of the ball. The center of the sphere can have a compression x. The recovery coefficient of the ball can be expressed by the formula 0.6511-0.024x 2 + 0.1165x. The coefficient of recovery of the center of the sphere can be expressed by the formula 0.7951-0.0121x 2 +0.416x. The recovery factor of any ball made according to this trend line can be capped to produce a qualified ball. The use of the tempered material as the cover allows a designer to produce a qualified ball that uses a high energy center.
一高爾夫球可設計成在壓縮、恢復係數、及初始速度之間有一特殊關係。該球心之材料及恢復係數可設計成產生一高於一球之預期初始速度及/或一球之旋轉性者。該球心之材料及恢復係數可設計成產生一與所預期者不同之該球整體的恢復係數。特別地,對一給定恢復係數而言,依據本發明製成之球將傾向於具有一比所預期者高之初始速度。這表示一高爾夫球員可具有足夠之初始速度以便獲得一良好開球距離同時由於在打短桿時,特別是在半挖起桿打擊時之低恢復係數而具有更大之旋轉性。A golf ball can be designed to have a special relationship between compression, recovery factor, and initial speed. The material of the core and the coefficient of restitution can be designed to produce an expected initial velocity above one ball and/or a rotation of a ball. The material of the sphere and the coefficient of restitution can be designed to produce a recovery factor that is different from the expected one of the sphere as a whole. In particular, for a given recovery factor, a ball made in accordance with the present invention will tend to have an initial velocity that is higher than expected. This means that a golfer can have sufficient initial speed to achieve a good tee shot distance while having greater rotatability due to the low recovery factor when hitting the short rod, particularly at the time of the semi-trick shot.
在該球心中包括例如高度中和化聚合物之高能材料,及在該覆蓋物中包括例如熱塑性聚胺基甲酸酯之和緩化或緩衝材料的球可得到這些好處。一具有一給定高能球心之球可給予一設計者更多覆蓋物選擇以便得到所需之球性能參數。These benefits are obtained by including, in the center of the sphere, a high energy material such as a highly neutralized polymer, and a ball comprising, for example, a thermoplastic polyurethane and a buffering or cushioning material in the cover. A ball having a given high energy center can give a designer more coverage options to achieve the desired ball performance parameters.
在檢視以下圖式及詳細說明後,所屬技術領域中具有通常知識者將或將會了解本發明之其他系統、方法、特徵及優點。企圖的是所有這些另外的系統、方法、特徵及優點應包括在這說明及這概要內,應在本發明之範疇內,且應受以下申請專利範圍保護。Other systems, methods, features, and advantages of the present invention will be or become apparent to those skilled in the <RTIgt; All such additional systems, methods, features, and advantages are intended to be included within the scope of the invention and are intended to be within the scope of the invention and
本發明可參照以下圖式及說明更佳地了解。在圖中之組件不一定依照比例,而是著重在顯示本發明之原理。此外,在圖中,類似符號在全部不同圖中表示對應部件。The invention will be better understood with reference to the following drawings and description. The components in the figures are not necessarily to scale, In addition, in the drawings, like reference characters refer to the
第1圖是依據本發明之一高爾夫球之側視圖;第2圖是依據本發明之一球之一實施例的橫截面圖;第3圖是依據本發明之一球之另一實施例的橫截面圖;第4圖是依據本發明之一球之另一實施例的橫截面圖;第5圖是比較當以一開球木桿測試時之初始速度與該球之恢復係數的圖;第6圖是比較兩球及它們之對應球心之恢復係數及壓縮的圖;及第7圖是顯示來自第5與6圖之各種球心之各種趨勢線的圖。1 is a side view of a golf ball according to the present invention; FIG. 2 is a cross-sectional view of an embodiment of a ball according to the present invention; and FIG. 3 is a view of another embodiment of the ball according to the present invention. Cross-sectional view; Figure 4 is a cross-sectional view of another embodiment of the ball in accordance with the present invention; Figure 5 is a graph comparing the initial velocity of the ball when tested with a driver of the ball and the recovery factor of the ball; Figure 6 is a graph comparing the recovery coefficients and compression of the two spheres and their corresponding spheres; and Figure 7 is a graph showing various trend lines from the various spheres of Figures 5 and 6.
本發明揭露一種多層球。雖然在此所述之實施例限定於高爾夫球,但是本發明不是要如此限定。在此所述之技術可應用於任何多層物品,特別是一拋射體、球、娛樂裝置、或其組件。The present invention discloses a multilayer ball. Although the embodiments described herein are limited to golf balls, the invention is not so limited. The techniques described herein are applicable to any multi-layer article, particularly a projectile, ball, entertainment device, or component thereof.
第1圖是一依據在此揭露之技術製造之球100的側視圖。第1圖顯示施加在球100之一外表面102上的一般凹坑圖案。雖然在球100上之凹坑圖案會影響球100之飛行路徑,但是沒有特定凹坑圖案對於使用所揭露之實施例是重要的。一設計者可由欲施加至球100上之任何適當凹坑圖案選擇。1 is a side view of a ball 100 made in accordance with the techniques disclosed herein. FIG. 1 shows a general pit pattern applied to one of the outer surfaces 102 of the ball 100. While the dimple pattern on the ball 100 affects the flight path of the ball 100, the absence of a particular dimple pattern is important to the disclosed embodiment. A designer can be selected by any suitable dimple pattern to be applied to the ball 100.
第2圖是沿第1圖之線2-2所截取之球100之一第一實施例的橫截面圖。如第2圖所示,一球200可具有兩層。球200可包括一球心204及一包圍球心204之覆蓋物206。任一在此所述之高爾夫球的實施例可依據任何習知技術製造,例如壓縮及射出模製該球心,射出模製任何外層,任選地以一黏著劑將該高爾夫球之多數層黏在一起,及例如藉噴塗、塗刷、浸漬、及移印等塗裝或塗覆該球。Figure 2 is a cross-sectional view of a first embodiment of a ball 100 taken along line 2-2 of Figure 1. As shown in Fig. 2, a ball 200 can have two layers. The ball 200 can include a ball 204 and a cover 206 that surrounds the ball 204. Any of the embodiments of the golf ball described herein can be made according to any conventional technique, such as compression and ejection molding of the core, injection molding any outer layer, optionally with an adhesive to the majority of the golf ball. Stick together and apply or coat the ball, for example by spraying, painting, dipping, and pad printing.
球心204可由一高能量效率材料製成。一高能量效率材料係會以一高彈性方式碰撞之材料。在某些實施例中,球心204可主要或完全由一高度中和化聚合物製成。在某些實施例中,該高度中和化聚合物可以是由E.I. DuPont de Nemours and Company取得之HPF 1000或HPF 2000。在某些實施例中,球心204可具有一在大約38與大約41mm之間的直徑。在某些實施例中,覆蓋物206可由一較低能量效率或和緩化材料製成。一較低能量效率材料係會以一較小彈性方式碰撞之材料。在某些實施例中,覆蓋物206可主要或完全由一熱塑性胺基甲酸酯樹脂製成。在某些實施例中,覆蓋物206可具有一至少2.1mm之厚度。The core 204 can be made of a high energy efficient material. A high energy efficiency material will hit the material in a highly elastic manner. In certain embodiments, the core 204 can be made primarily or entirely of a highly neutralized polymer. In certain embodiments, the highly neutralized polymer can be HPF 1000 or HPF 2000 available from E.I. DuPont de Nemours and Company. In certain embodiments, the core 204 can have a diameter of between about 38 and about 41 mm. In certain embodiments, the cover 206 can be made of a lower energy efficiency or mildening material. A lower energy efficient material will hit the material in a less elastic manner. In certain embodiments, the cover 206 can be made primarily or entirely of a thermoplastic urethane resin. In certain embodiments, the cover 206 can have a thickness of at least 2.1 mm.
在某些實施例中,可包括一或多個另外之外層,但是未顯示在第2圖或任一剩餘圖中。在第2圖中之覆蓋物206外可以一頂塗層。該頂塗層可以是一被塗布成改善或調整球200之外觀的塗層。例如,該頂塗層可被塗布成改變球200之顏色或改變在球200上之光澤度。在另一實施例中,一另外之塗層可採用將一標誌或其他印刷物施加在球200之外表面202上的形式。所屬技術領域中具有通常知識者應了解的是這些外部塗層可以施加至任一在此所述之實施例,且因此,這任選之塗層將不再連同以下實施例一起說明。應注意的是高爾夫球通常是經塗覆的。在這申請案中所述之所有經測試的球均具有塗層,例如塗裝及保護塗層。雖然該等塗層會對該球之恢復係數有某些影響,但是一般相信這影響對於這些實施例之考慮是可忽略的。但是,如果該等塗層被作成足夠厚或由一非常硬或非常軟之材料製成,這影響對於依據本發明之實施例之設計目的會是明顯的。In some embodiments, one or more additional outer layers may be included, but are not shown in FIG. 2 or any of the remaining figures. A top coat can be applied to the cover 206 in Figure 2. The top coat can be a coating that is coated to improve or adjust the appearance of the ball 200. For example, the top coat can be applied to change the color of the ball 200 or to change the gloss on the ball 200. In another embodiment, an additional coating may take the form of applying a logo or other print to the outer surface 202 of the ball 200. It will be appreciated by those of ordinary skill in the art that these outer coatings can be applied to any of the embodiments described herein and, therefore, such optional coatings will not be described in conjunction with the following examples. It should be noted that golf balls are typically coated. All of the tested balls described in this application have coatings, such as coatings and protective coatings. While such coatings may have some effect on the recovery factor of the sphere, it is generally believed that this effect is negligible for consideration of these embodiments. However, if the coatings are made thick enough or made of a very hard or very soft material, this effect will be apparent for design purposes in accordance with embodiments of the present invention.
第3圖是沿第1圖之線2-2所截取之球100之一第二實施例的橫截面圖。如第3圖所示,一球300可具有三層。球300可包括一球心304,一包圍球心304之內覆蓋層308,及一包圍內覆蓋層308之外覆蓋層310。Figure 3 is a cross-sectional view of a second embodiment of a ball 100 taken along line 2-2 of Figure 1. As shown in Fig. 3, a ball 300 can have three layers. The ball 300 can include a core 304, an inner cover 308 surrounding the core 304, and a cover 310 surrounding the inner cover 308.
球心304可由一高能量效率材料製成。一高能量效率材料係會以一高彈性方式碰撞之材料。在某些實施例中,球心304可主要或完全由一高度中和化聚合物製成。在某些實施例中,該高度中和化聚合物可以是由E.I. DuPont de Nemours and Company取得之HPF 1000或HPF 2000。在某些實施例中,球心304可具有一在大約38mm與大約41mm之間的直徑。在某些實施例中,該(等)覆蓋層以外之任何層可包括一高度中和化離子聚合物。在某些實施例中,該(等)覆蓋層以外之所有層可聚集為一在大約38mm與41mm之間的尺寸。在某些實施例中,該(等)覆蓋層以外之所有層可聚集為大約38.6mm。The core 304 can be made of a high energy efficient material. A high energy efficiency material will hit the material in a highly elastic manner. In certain embodiments, the core 304 can be made primarily or entirely of a highly neutralized polymer. In certain embodiments, the highly neutralized polymer can be HPF 1000 or HPF 2000 available from E.I. DuPont de Nemours and Company. In certain embodiments, the core 304 can have a diameter of between about 38 mm and about 41 mm. In certain embodiments, any layer other than the (equal) cover layer can comprise a highly neutralized ionic polymer. In some embodiments, all of the layers other than the (equal) cover layer can be gathered into a size between about 38 mm and 41 mm. In some embodiments, all of the layers other than the (equal) cover layer may aggregate to approximately 38.6 mm.
在某些實施例中,內覆蓋層308與外覆蓋層310可由一或多個較低能量效率或和緩化材料製成。在某些實施例中,內覆蓋層308,外覆蓋層310,或兩者可主要或完全由一熱塑性胺基甲酸酯樹脂或一熱塑性聚胺基甲酸酯樹脂製成。在其他實施例中,內覆蓋層308,外覆蓋層310,或兩者可主要或完全由一離子聚合樹脂製成。在某些實施例中,該離子聚合樹脂可以是由E.I.DuPont de Nemours and Company購得SURLYN®。在某些實施例中,內覆蓋層308與外覆蓋層310之合併厚度可以是大約2.1mm。In certain embodiments, inner cover 308 and outer cover 310 may be made of one or more lower energy efficient or milder materials. In certain embodiments, inner cover 308, outer cover 310, or both may be made primarily or entirely of a thermoplastic urethane resin or a thermoplastic polyurethane resin. In other embodiments, inner cover 308, outer cover 310, or both may be made primarily or entirely of an ionic polymeric resin. In certain embodiments, the ionic polymeric resin can be SURLYN® available from E. I. DuPont de Nemours and Company. In some embodiments, the combined thickness of inner cover layer 308 and outer cover layer 310 can be about 2.1 mm.
第4圖是沿第1圖之線2-2所截取之球100的橫截面圖。如第4圖所示,一球400可具有四層。一第一層412可以是一內球心層,一第二層414可以是一外球心層且可包圍第一層412。一第三層416可以是一內覆蓋層且可包圍第二層414。一第四層418可以是一外覆蓋層且可包圍第三層416。第一層412或內球心層及第二層414或外球心層可一起被視為且被稱為球心420。第三層416或內覆蓋層及第四層414或外覆蓋層可一起被視為且被稱為覆蓋物422。Figure 4 is a cross-sectional view of the ball 100 taken along line 2-2 of Figure 1. As shown in Fig. 4, a ball 400 can have four layers. A first layer 412 can be an inner core layer, and a second layer 414 can be an outer core layer and can surround the first layer 412. A third layer 416 can be an inner cover layer and can surround the second layer 414. A fourth layer 418 can be an outer cover layer and can surround the third layer 416. The first layer 412 or the inner core layer and the second layer 414 or outer core layer may be considered together and referred to as the center 420. The third layer 416 or the inner cover layer and the fourth layer 414 or the outer cover layer may be considered together and referred to as a cover 422.
球心420可由一或多個高能量效率材料製成,且第一層412及第二層414之各層可由一不同配方之高效率材料製成。在某些實施例中,至少一層球心420可主要或完全由一高度中和化聚合物製成。在某些實施例中,該高度中和化聚合物可以是由E.I.DuPont de Nemours and Company取得之HPF 1000或HPF 2000。覆蓋物422可由一較低效率或和緩化材料製成。在某些實施例中,第三層416,第四層418, 或兩者可主要或完全由一熱塑性胺基甲酸酯樹脂製成。在其他實施例中,第三層416,第四層418,或兩者可主要或完全由一離子聚合樹脂製成。在某些實施例中,該離子聚合樹脂可以是由E.I.DuPont de Nemours and Company購得SURLYN®。在某些實施例中,第三層(內覆蓋層)416與第四層(外覆蓋層)418之合併厚度可以是大約2.1mm。在某些實施例中,該(等)覆蓋層以外之任何層可包括一高度中和化離子聚合物。在某些實施例中,該(等)覆蓋層以外之所有層可聚集為一在大約38mm與41mm之間的尺寸。在某些實施例中,該(等)覆蓋層以外之所有層可聚集為大約38.6mm。The core 420 can be made of one or more high energy efficient materials, and the layers of the first layer 412 and the second layer 414 can be made of a high efficiency material of a different formulation. In certain embodiments, at least one of the cores 420 can be made primarily or entirely of a highly neutralized polymer. In certain embodiments, the highly neutralizing polymer can be HPF 1000 or HPF 2000 available from E. I. DuPont de Nemours and Company. The cover 422 can be made of a less efficient or slower material. In some embodiments, the third layer 416, the fourth layer 418, Or both may be made primarily or entirely of a thermoplastic urethane resin. In other embodiments, the third layer 416, the fourth layer 418, or both may be made primarily or entirely of an ionic polymeric resin. In certain embodiments, the ionic polymeric resin can be SURLYN® available from E. I. DuPont de Nemours and Company. In some embodiments, the combined thickness of the third layer (inner cover layer) 416 and the fourth layer (outer cover layer) 418 can be about 2.1 mm. In certain embodiments, any layer other than the (equal) cover layer can comprise a highly neutralized ionic polymer. In some embodiments, all of the layers other than the (equal) cover layer can be gathered into a size between about 38 mm and 41 mm. In some embodiments, all of the layers other than the (equal) cover layer may aggregate to approximately 38.6 mm.
在第4圖中,球400已被說明及顯示為具有多數層。在某些實施例中,可添加另一層。例如,在某些實施例中,可在球心420與覆蓋物422之間添加一外殼層。在其他實施例中,可在第三層(內覆蓋層)416與第四層(外覆蓋層)418之間插入一中間覆蓋層。在其他實施例中,可在第一層(內球心層)412與第二層(外球心層)414之間插入一中間球心層。In Figure 4, ball 400 has been illustrated and shown as having a plurality of layers. In some embodiments, another layer can be added. For example, in some embodiments, an outer shell layer can be added between the core 420 and the cover 422. In other embodiments, an intermediate cover layer can be interposed between the third layer (inner cover layer) 416 and the fourth layer (outer cover layer) 418. In other embodiments, an intermediate core layer can be inserted between the first layer (inner core layer) 412 and the second layer (outer core layer) 414.
所屬技術領域中具有通常知識者亦可了解的是在不偏離這些實施例之情形下,可依據一設計者之特定需要對該等實施例之任一實施例進行多數類似修改。例如,一四層球可包括一內球心層,一中間球心層,一外球心層,及一單一覆蓋層。類似地,一球四層可包括一單一覆蓋層及一內覆蓋層,一中間覆蓋層,及一外覆蓋層。所屬技術領域中具有通常知識者亦可了解具有其他數目中間層之球。因此,所示實施例在本質上是示範的,而不是要限制。It will also be appreciated by those of ordinary skill in the art that many similar modifications may be made to any embodiment of the embodiments, depending on the particular needs of the designer, without departing from the embodiments. For example, a four-layer ball may include an inner core layer, an intermediate core layer, an outer core layer, and a single cover layer. Similarly, a ball and four layers may include a single cover layer and an inner cover layer, an intermediate cover layer, and an outer cover layer. Those of ordinary skill in the art will also be aware of balls having other numbers of intermediate layers. Accordingly, the illustrated embodiments are exemplary in nature and are not intended to be limiting.
以下請參閱第5圖,顯示說明在所揭露之實施例與目前市面上販售之球之間之差異的一圖。這些球將在以下更詳細地說明。在左側y軸上的值是當以一開球木桿測試時該球之初始速度。各球係以相同條件(頭速度、打擊之角度等)以一9.5桿面傾角Nike SQ開球木桿打擊。Referring now to Figure 5, there is shown a diagram illustrating the difference between the disclosed embodiment and the currently available ball on the market. These balls will be explained in more detail below. The value on the left y-axis is the initial velocity of the ball when tested with a tee shot. Each ball system is struck with a 9.5 loft Nike SQ kicking wood under the same conditions (head speed, angle of impact, etc.).
初始速度係藉在長條圖上之各長條高度顯示在該圖中。如在該長條圖中顯示之初始速度係以英哩每小時顯示。150英哩每小時之初始速度等於大約220英呎每秒。大約170英哩每小時之初始速度等於大約250英呎每秒。The initial speed is shown in the figure by the height of each strip on the bar graph. The initial speed as shown in the bar graph is displayed in inches per hour. The initial speed of 150 miles per hour is equal to approximately 220 inches per second. The initial speed of approximately 170 inches per hour is equal to approximately 250 inches per second.
在該圖右側上之值表示該球整體之恢復係數(coefficient of restitution)。為了測量一物體之恢復係數,該物體由一空氣砲以一大約40公尺每秒之初始速度發射。一鋼板定位在距離該炮大約1.2公尺處,且一速度監測裝置設置在距離該炮大約0.6至大約0.9公尺之一距離處。該物體由該空氣炮發射,通過該速度監測裝置以便決定一初始速度。接著該物體撞擊該鋼板且反彈回來通過該速度監測裝置以便決定一返回速度。該恢復係數是該返回速度對該初始速度之比例。各球之恢復係數係由出現在該圖上之線544顯示。The value on the right side of the figure indicates the coefficient of restitution of the ball as a whole. To measure the recovery factor of an object, the object is fired by an air cannon at an initial velocity of about 40 meters per second. A steel plate is positioned about 1.2 meters from the gun, and a speed monitoring device is disposed at a distance of about 0.6 to about 0.9 meters from the gun. The object is launched by the air cannon and passed through the speed monitoring device to determine an initial velocity. The object then strikes the steel plate and bounces back through the speed monitoring device to determine a return speed. The recovery factor is the ratio of the return speed to the initial speed. The recovery coefficients for each ball are shown by line 544 appearing on the graph.
該x軸表示受測試之球。各受測試之球係經初始速度及恢復係數之測試。前九個球(編號1-9)係市面上販售之高爾夫球。這些高爾夫球各具有由一丁二烯橡膠化合物製成之一球心,該球心具有一大約40mm之直徑。對各球而言,該球心之精確配方稍微不同。各球之球心係由具有產生不同壓縮及恢復係數之不同添加劑或不同尺寸的丁二烯橡膠製成。一般相信在恢復係數與球心尺寸之間有一關連性,且可能有一強大關連性,使得球心尺寸之微小變化會對恢復係數具有一不可忽略之影響。各球之覆蓋物是大約1.4mm厚且主要是由SURLYN製成。The x-axis represents the ball being tested. Each tested ball was tested for initial speed and recovery factor. The first nine balls (numbers 1-9) are commercially available golf balls. Each of these golf balls has a spherical core made of a butadiene rubber compound having a diameter of about 40 mm. The exact formula of the ball is slightly different for each ball. The spherical core of each ball is made of a different additive or different size of butadiene rubber that produces different compression and recovery coefficients. It is generally believed that there is a correlation between the coefficient of restitution and the size of the center of the sphere, and there may be a strong correlation, such that small changes in the size of the sphere have a non-negligible effect on the coefficient of recovery. The cover of each ball is approximately 1.4mm thick and is primarily made up of SURLYN production.
另一方面,標記為10之球是一依據本實施例製成之球。標記為10之球改為具有一主要由高度中和化聚合物樹脂製成之球心,該球心之直徑大約為38mm。該球心之直徑可如大約41mm一般大。該球之覆蓋物是大約2.1mm厚,但可為如大約0.9mm一般薄之厚度。如有需要,可包括一外殼層以確使該球符合42.67mm(1.680英吋)之最小USGA尺寸規定。On the other hand, the ball labeled 10 is a ball made in accordance with this embodiment. The ball labeled 10 was changed to have a core made mainly of highly neutralized polymer resin having a diameter of about 38 mm. The diameter of the center of the ball can be as large as about 41 mm. The cover of the ball is about 2.1 mm thick, but can be as thin as about 0.9 mm. If desired, a cover layer can be included to ensure that the ball meets the minimum USGA size specification of 42.67 mm (1.680 inch).
在比較初始速度與恢復係數之關係時,應注意的是對球1-9而言,在恢復係數與初始速度之間有一大致關連性。例如,對恢復係數低於0.795之球1、2、4與5而言,該初始速度下降至低於大約150.2。對恢復係數高於0.800之球3、6、7與8而言,該初始速度高於大約150.8。對恢復係數為大約0.800之球9而言,該初始速度是大約150.5。因此,該圖顯示在該恢復係數與該初始速度之間的一大致關連性。In comparing the relationship between the initial velocity and the recovery factor, it should be noted that for the balls 1-9 there is a substantial correlation between the recovery factor and the initial velocity. For example, for balls 1, 2, 4, and 5 with a recovery factor below 0.795, the initial velocity drops below about 150.2. For balls 3, 6, 7 and 8 with a recovery factor above 0.800, the initial velocity is above about 150.8. For a ball 9 with a recovery factor of approximately 0.800, the initial velocity is approximately 150.5. Thus, the figure shows a general correlation between the recovery factor and the initial velocity.
但是,在第5圖中顯示之圖顯示球10之初始速度偏離具有一0.774之恢復係數之一習知球的預期初始速度。對球10而言,該恢復係數具有一大約0.774之值。初始速度不是如由習知球1-9所預測地低於150英哩每小時,球10之初始速度維持在150.8,這初始速度幾乎與具有一甚高於球10之恢復係數之球的初始速度一樣高。因此,藉使用上述球結構,該球恢復係數可維持比較低以便在打短桿時得到較佳傳感及旋轉性,同時保持一適當高初始速度以便以一開球木桿得到較長距離。However, the graph shown in Figure 5 shows that the initial velocity of the ball 10 deviates from the expected initial velocity of a conventional ball having a recovery factor of 0.774. For the ball 10, the coefficient of restitution has a value of approximately 0.774. The initial velocity is not less than 150 miles per hour as predicted by conventional balls 1-9, and the initial velocity of the ball 10 is maintained at 150.8, which is almost the same as the initial velocity of a ball having a recovery coefficient that is much higher than the ball 10. high. Thus, by using the ball structure described above, the ball recovery factor can be maintained relatively low to achieve better sensing and rotation while the short rod is being struck while maintaining a suitably high initial speed to achieve a longer distance with a tee shot.
這對半挖起桿打擊特別重要。利用一較低恢復係數球,高爾夫球員將傾向於較硬地,即,以一較高球桿頭速度打擊該球,以得到與一具有較高恢復係數之球相同之距離。該較硬之打擊(較高球桿頭速度)對該球賦予更多旋轉。因此,一高爾夫球員可具有一在打短桿時有良好初始速度及開球距離但旋轉性較高之較低恢復係數球。This is especially important for half-trick strikes. With a lower recovery factor ball, the golfer will tend to hit the ball harder, i.e., at a higher club head speed to achieve the same distance as a ball with a higher recovery factor. This harder hit (higher club head speed) gives the ball more rotation. Therefore, a golfer can have a lower recovery coefficient ball that has a good initial speed and a teeing distance when the short rod is hit but has a higher degree of rotation.
可在現有球與本發明之球之間比較之另一特徵可在第6圖中看到。第6圖是一顯示在各種球及球心之壓縮量與恢復係數之間之關係的圖。在x軸上之值表示該球之內球心層之壓縮量。該壓縮量係以一在所屬技術領域中習知之方式決定。該球形球心及/或球被放在一10kg之初始負載下。通常是毫米之該球直徑的測量值係在一或多點取得,例如在該或該等球極,該接縫,或一任意點處。記錄一單一值或該等值之平均。該負載增加至130kg且亦是毫米之該球直徑的第二測量值係在一相同點或多數相同點取得。記錄在該較大負載下之單一值或該等值之平均。該等記錄值之間呈毫米之差為壓縮量。Another feature that can be compared between the existing ball and the ball of the present invention can be seen in Figure 6. Fig. 6 is a graph showing the relationship between the compression amount and the recovery coefficient of various balls and centers. The value on the x-axis represents the amount of compression of the core layer within the ball. The amount of compression is determined in a manner well known in the art. The spherical center and/or the ball is placed under an initial load of 10 kg. The measurement of the diameter of the ball, typically millimeters, is taken at one or more points, such as at the or the ball pole, the seam, or an arbitrary point. Record a single value or an average of the values. The second measurement of the diameter of the ball, which is increased to 130 kg and is also millimeters, is taken at the same point or at most the same point. Record a single value or an average of the values under the larger load. The difference in millimeters between the recorded values is the amount of compression.
在y軸上之值表示所考慮之四個物件之各物件的恢復係數(coefficient of restitution)。線650代表在一直徑大約38mm且由丁二烯橡膠化合物製成之球心之壓縮與恢復係數之間的關係。這橡膠球心趨勢線之式是用下式表示The value on the y-axis represents the coefficient of restitution of each of the four objects under consideration. Line 650 represents the relationship between the compression and recovery coefficients of a core made of a butadiene rubber compound having a diameter of about 38 mm. This rubber ball trend line is expressed by the following formula
y=0.7531-0.0128x2 +0.055x 式1y=0.7531-0.0128x 2 +0.055x Equation 1
其中x是該內球心壓縮且y是該對應恢復係數。Where x is the inner core compression and y is the corresponding recovery coefficient.
線660代表在包括覆蓋線650中所示球心之一覆蓋物之一球之該壓縮與恢復係數之間的關係。這線之式是用下式表示Line 660 represents the relationship between the compression and recovery coefficients of a ball including one of the cores shown in cover line 650. This line is expressed by
y=0.6794-0.0179x2 +0.0831x 式2y=0.6794-0.0179x 2 +0.0831x Equation 2
其中x是該球心之壓縮且y是該球整體之恢復係數。在該球心之相對恢復係數與該球之恢復係數之間的差係在大約0.035與大約0.037之間的範圍內。Where x is the compression of the sphere and y is the recovery factor of the sphere as a whole. The difference between the relative recovery coefficient of the center of the sphere and the recovery factor of the sphere is in the range between about 0.035 and about 0.037.
但是,包括主要或完全由一高度中和化聚合物製成之一球心之該球之相對恢復係數的比較顯示一不同之差。線670代表在直徑大約38mm且主要或完全由一高度中和化聚合物製成之一球心之該壓縮與恢復係數之間的關係。這線之式是用下式表示However, a comparison of the relative recovery coefficients of the sphere comprising one of the spheres made primarily or entirely of a highly neutralized polymer shows a difference. Line 670 represents the relationship between this compression and recovery factor at a core of approximately 38 mm in diameter and made primarily or entirely of a highly neutralized polymer. This line is expressed by
y=0.7951-0.0121x2 +0.0416x 式3y=0.7951-0.0121x 2 +0.0416x Equation 3
其中x是該球心之壓縮且y是該對應恢復係數。Where x is the compression of the center of the sphere and y is the corresponding recovery factor.
線680代表在包括覆蓋線670中所示球心之一覆蓋物之一球之該壓縮與恢復係數之間的關係。該覆蓋物是與由線650決定之球之覆蓋物相同的覆蓋物結構。這線之式是用下式表示Line 680 represents the relationship between the compression and recovery coefficients of a ball including one of the cores shown in cover line 670. The cover is the same cover structure as the cover of the ball determined by line 650. This line is expressed by
y=0.6511-0.024x2 +0.1165x 式4y=0.6511-0.024x 2 +0.1165x Equation 4
其中x是該球心之壓縮且y是該球整體之恢復係數。在該球心之相對恢復係數與該球之恢復係數之間的差係在大約0.026與大約0.031之間的範圍內。Where x is the compression of the sphere and y is the recovery factor of the sphere as a whole. The difference between the relative recovery coefficient of the center of the sphere and the recovery factor of the sphere is in the range between about 0.026 and about 0.031.
因此,如在第6圖中清楚所示,對一給定內球心壓縮而言,具有一橡膠球心之一球將具有比具有一HNP(高度中和化聚合物)球心之一球更低的一恢復係數。此外,為使該和緩化材料之效果達到最大,在該球心之恢復係數與該球之恢復係數之間的差應為至少0.026,但是可顯著地更高,例如0.037,0.05,0.1或甚至更高。該球之恢復係數越低,該球越會旋轉,因此會需要具有例如至少0.037或至少0.05之一較高恢復係數差的一球。由於當設有一和緩化覆蓋物時該球整體之恢復係數可仍在最高性能範圍內,所以如上所述地依據本發明製成之球心之比較高恢復係數可使在選擇覆蓋物材料方面有顯著彈性。Thus, as clearly shown in Figure 6, for a given inner core compression, one of the balls having a rubber core will have a ball than a sphere having a HNP (highly neutralized polymer) A lower recovery factor. Furthermore, in order to maximize the effect of the retarding material, the difference between the coefficient of recovery of the sphere and the coefficient of recovery of the sphere should be at least 0.026, but can be significantly higher, such as 0.037, 0.05, 0.1 or even higher. The lower the coefficient of recovery of the ball, the more the ball will rotate, so a ball having a higher recovery coefficient difference of, for example, at least 0.037 or at least 0.05 may be required. Since the overall coefficient of recovery of the ball can still be within the highest performance range when a gentle and grading cover is provided, the relatively high recovery factor of the spherical core made in accordance with the present invention as described above can be used in selecting the covering material. Significantly flexible.
這些好處係更簡單地顯示在第7圖中,其中橡膠球心趨勢線762顯示對一給定恢復係數而言,比HNP球心趨勢線760一致地更低之內球心壓縮。HNP球心球趨勢線764(具有一HNP球心之一完整球的趨勢線)係顯示供參考。These benefits are more simply shown in Figure 7, where the rubber centerline trend line 762 shows a spherical core compression that is consistently lower than the HNP centerline trend line 760 for a given recovery factor. The HNP Ball Heart Trend Line 764 (a trend line with one complete sphere of a HNP center) is shown for reference.
因此,用具有一特定恢復係數之一樹脂球心取代具有相同特定恢復係數之一橡膠球心可使該球及該球心之相對恢復係數有很大的差。這在該樹脂球心恢復係數超過由該橡膠球心趨勢線所給予之恢復係數且其中該球具有一小於用下式表示之恢復係數之恢復係數時特別為真Therefore, replacing the rubber core having one of the same specific recovery coefficients with one of the resin cores having a specific recovery coefficient makes the relative recovery coefficient of the sphere and the center of the sphere greatly different. This is especially true when the resin core recovery coefficient exceeds the recovery factor given by the rubber core trend line and wherein the ball has a recovery factor less than the recovery factor expressed by
y=-0.0103x+0.8419 式5y=-0.0103x+0.8419 Equation 5
其中y是該恢復係數且x是一內球心壓縮。Where y is the recovery factor and x is an inner spherical compression.
這通常可藉使至少一內層(非覆蓋層)由一高度中和化 離子聚合物/聚合物來達成。該覆蓋物之性質在該丁二烯橡膠球心與該高度中和化聚合物球心之間不必改變。但是,在該球心與該球之間之恢復係數的差在使用該高度中和化聚合物球心時是少至少大約0.004。這使具有一較高恢復係數之一球可用相同之覆蓋物材料製成。This can usually be achieved by at least one inner layer (non-cover layer) being neutralized by a height. Ionic polymer/polymer to achieve. The nature of the cover does not have to change between the butadiene rubber core and the highly neutralized polymer core. However, the difference in the coefficient of restitution between the center of the sphere and the sphere is at least about 0.004 less when using the height to neutralize the polymer core. This allows one of the balls having a higher recovery factor to be made of the same covering material.
當遵循高度中和化聚合物球心及以高度中和化聚合物球心製成之球之上述恢復係數趨勢線時,會需要觀察其他限制。例如,一合格球將具有低於用式5或,更保守地,用下式表示之趨勢的一恢復係數Other limitations may need to be observed when following the above-mentioned coefficient of recovery trend line of highly neutralized polymer spheres and spheres made of highly neutralized polymer spheres. For example, a qualified ball will have a recovery factor that is lower than the trend expressed by Equation 5 or, more conservatively, as shown below.
y=-0.0103x+0.8299 式6y=-0.0103x+0.8299 Equation 6
其中y是該恢復係數且x是一內球心壓縮。因此一設計者會想要給遵循式4之一球之恢復係數定上限,使得該恢復係數不會超過用式6表示之恢復係數。Where y is the recovery factor and x is an inner spherical compression. Therefore, a designer would like to set an upper limit on the recovery coefficient of a ball following Equation 4 so that the recovery coefficient does not exceed the recovery coefficient expressed by Equation 6.
在以上揭露之範圍內製成的一球被認為具有較佳性質。這種球被認為具有比可預期者更高之初始速度。這種球亦可使用更多種覆蓋物材料,特別地包括具有較低成本者。這種球可提供一高爾夫球員一較不昂貴之球,且該球具有比其他球更長之軌跡。A ball made within the scope of the above disclosure is considered to have better properties. Such a ball is considered to have a higher initial velocity than expected. Such balls can also use a wider variety of covering materials, particularly those with lower cost. Such a ball can provide a golfer with a less expensive ball and the ball has a longer trajectory than the other balls.
該多層物品之其他構造亦可增進這些好處。例如,一高爾夫球可依據本發明與在名稱為“具有有特定模數及硬度之多數層的高爾夫球(Golf Ball Having Layers with Specified Moduli and Hardnesses)”且在2010年8月20日申請之美國申請案第12/860,785號中所述之物品的教示製成,且該美國申請案之揭露在此全部加入作為參考。Other configurations of the multilayer article may also enhance these benefits. For example, a golf ball may be applied in accordance with the present invention and in the United States under the name "Golf Ball Having Layers with Specified Moduli and Hardnesses" and applied for on August 20, 2010. The teachings of the articles described in the application Serial No. 12/860,785, the disclosure of which is incorporated herein by reference.
雖然本發明之各種實施例已說明過了,但是該說明是用來示範,而不是限制且所屬技術領域中具有通常知識者將了解的是在本發明之範疇內可有更多實施例及實施方式。因此,除了依據附加申請專利範圍及其等效物以外,本發明不受限制。此外,可在附加申請專利範圍之範疇內進行各種修改及變化。Although various embodiments of the invention have been described, the description is illustrative, and not restrictive, and those of ordinary skill in the art will understand that many embodiments and implementations are possible within the scope of the invention. the way. Therefore, the invention is not limited except in the scope of the appended claims and their equivalents. In addition, various modifications and changes can be made within the scope of the appended claims.
100...球100. . . ball
102...外表面102. . . The outer surface
200...球200. . . ball
202...外表面202. . . The outer surface
204...球心204. . . Heart
206...覆蓋物206. . . cover
300...球300. . . ball
304...球心304. . . Heart
308...內覆蓋層308. . . Inner cover
310...外覆蓋層310. . . Outer cover
400...球400. . . ball
412...第一層412. . . level one
414...第二層414. . . Second floor
416...第三層416. . . the third floor
418...第四層418. . . Fourth floor
420...球心420. . . Heart
422...覆蓋物422. . . cover
第1圖是依據本發明之一高爾夫球之側視圖;Figure 1 is a side view of a golf ball in accordance with the present invention;
第2圖是依據本發明之一球之一實施例的橫截面圖;Figure 2 is a cross-sectional view of one embodiment of a ball in accordance with the present invention;
第3圖是依據本發明之一球之另一實施例的橫截面圖;Figure 3 is a cross-sectional view of another embodiment of a ball in accordance with the present invention;
第4圖是依據本發明之一球之另一實施例的橫截面圖;Figure 4 is a cross-sectional view of another embodiment of a ball in accordance with the present invention;
第5圖是比較當以一開球木桿測試時之初始速度與該球之恢復係數的圖;Figure 5 is a graph comparing the initial velocity of a ball with a kick-off wood and the recovery factor of the ball;
第6圖是比較兩球及它們之對應球心之恢復係數及壓縮的圖;及Figure 6 is a comparison of the recovery coefficients and compression of the two spheres and their corresponding spheres; and
第7圖是顯示來自第5與6圖之各種球心之各種趨勢線的圖。Figure 7 is a diagram showing various trend lines from the various spheres of Figures 5 and 6.
200...球200. . . ball
204...球心204. . . Heart
206...覆蓋物206. . . cover
Claims (20)
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US37577510P | 2010-08-20 | 2010-08-20 | |
US13/198,554 US20120064998A1 (en) | 2010-08-20 | 2011-08-04 | Golf Ball Having High Initial Velocity |
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TWI457160B true TWI457160B (en) | 2014-10-21 |
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EP (1) | EP2420297B1 (en) |
JP (1) | JP5779445B2 (en) |
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US20130210552A1 (en) * | 2011-08-23 | 2013-08-15 | Nike, Inc. | Golf ball having high initial velocity |
US20140045622A1 (en) * | 2012-08-13 | 2014-02-13 | Nike, Inc. | Golf Ball With Two Soft Layers And One Hard Layer |
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US20100179001A1 (en) * | 2009-01-12 | 2010-07-15 | Feng Tay Enterprises Co., Ltd. | Golf ball |
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- 2011-08-04 US US13/198,554 patent/US20120064998A1/en not_active Abandoned
- 2011-08-12 JP JP2011176520A patent/JP5779445B2/en not_active Expired - Fee Related
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TW201223594A (en) | 2012-06-16 |
AU2011213701B2 (en) | 2012-11-15 |
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EP2420297A3 (en) | 2012-03-07 |
CN102371053A (en) | 2012-03-14 |
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