六、發明說明： 【發明所屬之技術領域】 本發明是-種應用於發電機或動態不斷電系統之脫硝級 智慧型全功能柴油引擎廢氣處理系統，特別指應用於處理 發電機或動態不斷電系統所排出的引筆廢氣之脫確級智慧 型全功能柴油引擎廢氣處理系統。 ‘ 【先前技術】 應用於發電機或動態不斷電系統之柴油引擎廢氣處理系 統’是業界已知之技術’通常以下列兩種方式處理廢氣： (1) 利用黑煙過濾器處理固態的微細碳粒子（Particular) (2) 利用氧化型觸媒轉化器處理氣態的碳氫化合物 (Hydrocarbons)及一氧化碳（Carb〇n M〇n〇xide)。以下為習 知头油引擎廢氣處理系統：台灣專利公告第373688號揭露 一種改良型排氣管，其是以一倒j形管接於排氣管來形成 兩出口端，其中一出口端連接一濾煙器以濾除粒狀污染 物；台灣專利公告第M25 1021號揭露一種附微波之引擎排 氣濾心，尤指一種可藉微波之輻射直接對積置於濾心通道 内之微粒子（積碳）加熱燃燒，使其提早觸媒或擔體之工作 及反應之溫度時間，有效提高其起燃之溫度；台灣專利公 告第M299775號揭露一種柴油引擎排氣淨化裝置，一過濾 元件係橫設於該本體内部中段，可過濾由排氣管導入廢氣 中之各種微粒’ 一磁控管係插設於該本體之鎮空内部’並 可產生電磁波以振盪燃燒附著於過濾元件表面之微粒，藉 以達到排氣污染控制之功效；台灣專利公告第M3丨3 724號 140426.doc 1374971 . 揭硌一種淨煙器之後喷系統，可加裝於各種舊形柴油車 . 上，主要係由一柴油汽化裝置及一濾煙器所組成，其中， 柴油汽化裝置主要係將柴油加以汽化，而濾煙器主要在藉 由自燃及過濾而瀘'除一氧化碳、碳氫化合物、微顆粒、黑 煙及臭氣；台灣專利公告第577482號揭露一種排煙淨化改 良裝置’將-升溫控制單元之加熱器，作為觸媒轉化器因 • 引擎排氣之溫度不足，加熱補償瞬間溫升之不足；以及台 φ Θ專利公告第]VI3 1 7493號揭露一種柴油引擎排煙改善污染 後處理輔助加熱器結構，利用氣體導入排煙管的同時藉 由壓力差將燃油抽出，經空氣霧化點火後，與引擎所排放 之未完全燃燒之廢氣再次燃燒所產生的熱能，將排煙淨化 器濾芯所補捉之碳粒子加熱再次燃燒，提昇淨化器的除煙 除臭除毒之功能。 此外，關於處理毒性的氮氧化物（Ν〇χ)部份，業界已知 之技術包含以選擇性觸媒還原法（Selective Catalytic • ReC〇Very簡稱為SCR)，來處理氮氧化物（NOx)，當氮氧化 物（ΝΟχ)通過脫硝觸媒時，利用氨氣作為選擇性觸媒還原 . 法所使用的還原劑，將氮氧化物（NGx)轉化成氮氣和水。 • 以下為習知處理毒性的氮氧化物的技術：美國專利公告號 5,489,420揭露-種藉由於高溫下將還原劑添加至氮氧化物 以移除氮氧化物的技術，其中使用氨氣於95(rc或更高的 高溫下，將氮氧化物移除；，美國專利公告號5,443,8〇5與 5,536,482揭露一種藉由在9〇〇〇c至12〇〇t下，將聚合物加 入氨氣中來移除氮氧化物的方法；台灣專利公告第 140426.doc 1374971 M27 1135號揭露一種選擇性觸媒還原脫硝系統，係利用還 原法，以注入氨氣（Ammonia NH3)當還原劑，當氮氧化物 以及氨氣流經觸媒床，即將氮氧化物還原成氮氣（N〇及水 (H2〇);以及台灣專利公告第j 2485〇4號揭露一種加氨子系 統’包括氨蒸氣源、設置於進口管道十之氨注入柵網、與 於氨蒸乳源與氨注入柵網間，提供流體通道之氨蒸氣管以 及設置於氨蒸氣管中之節流閥，混合氨蒸氣之步驟還包括 藉由加氨控制器調節節流閥來控制加氨氣之速率。 一般而言，黑煙過濾器之目的在過濾固態的微細碳粒子 (Particulate)，通常使用的^：多孔性陶瓷濾材，其出入口兩 端呈現蜂巢狀。因此當黑煙廢氣經由過濾器入口端進入蜂 巢式通道後，因通道出口端被封閉，而無法穿過，碳粒子 (Paniculate)被蜂巢式濾材所捕捉，進而達到過濾黑煙廢氣 之效果。雖然黑煙過濾器確實能夠達成特定功效，但事實 上，單獨以此類傳綠過濾器處理引擎廢氣仍有許多缺點： ⑴黑煙過遽器只能過滤黑煙，而且遽材必須經常停機再 生β理以免堵塞，所以無法配合引擎長時間運轉。（2) 蜂巢壁流式陶究渡芯有很高的壓降，因此所裝設的傳統型 「黑煙過濾、器」數量亦非常龐大，系統設置費用約為使用 氧化型觸媒轉化器的5至15倍，價格非常昂貴。 氧：型觸媒轉化器一。祕⑽CaU㈣的目的在 處理風㊆碳氫化合物（Hydrc>eai<b()ns)與—氧化碳 M〇n〇Xlde) °利用氧化型觸媒披覆在陶£或金屬母材表 面’用來降低氣態的碳氫化合物（Hydr〇carb〇ns)與一氧化 140426.doc 1374971 碳（Carbon Monoxide)燃燒溫度後，再利用引擎排氣溫 度’末將廢氣中的氣態碳氫化合物（Hydrocarbons)與一氧 化碳（Carbon Monoxide)轉化成水與二氧化碳。然而，單 獨只以氧化型觸媒轉化器（Diesel 〇xidati〇n Cataiyst)處理 引擎廢氣亦有（1)無法處理引擎瞬間起動時所產生大量黑 煙° (2)無法處理低引擎負載運轉；低排氣溫度（<25〇。〇） 時所產生的氣態碳氫化合物（Hydrocarbons)與一氧化碳 (Carbon Monoxide)等缺點。 有關以選擇性觸媒還原法（SCR)，來處理毒性的氮氧化 物（N0X)。卩伤，因業界已知之柴油引擎廢氣處理技術並不 成熟，且受限於變動的引擎負載與變動的氮氧化物（Ν〇χ) 排放濃度；尤其在？丨擎無載運轉時，極低的排氣溫度（低 於250°C-3GGt)時，選擇性觸媒還原法將無法進行。選擇 以氨氣（Ammonia NHs)當還原劑時，因氨氣屬於毒性化學 物質，在排氣溫度極低時，因無法與氮氧化物（Ν〇χ)充分 有效的進行還原反應，氨氣有溢出的危 險0 雖然氨氣應用在選擇性觸媒還原法（SCR)進行脫硝 (DeNOx)時，是—個非常良好的還原劑 U-，其沸點為-33.41亦即在常溫、常厂 體方式呈現’屬於強烈毒性、腐㈣的化學氣體。在高溫 下’會分解成為可㈣氫氣與毒性氣體，火場巾儲存氨氣 的虔力容器’亦會產生破裂與爆炸的危害。因此，氨氣健 存於室内時，安全性更是必須加以慎重的考量。基於上述 140426.doc 1374971 種種限制與氨氣儲存使周上，安全性的考量，目前業界已 知之技術，針對發電機或動態不斷電系統所排出的柴油引 擎廢氣中所含毒性氮氧化物（ΝΟχ)的部份，尚無經濟、有 效的處理技術。 另外選擇性觸媒還原法（SCR)，使用氨氣作為還原劑， 為業界已知之技術，基本上分為「液態氨」及「尿素水溶 液」兩大類。如下所述，無論是液態氨或尿素水溶液，在 應用上仍有諸多缺點與不便： (一） 液態氨（Liquefied Ammonia)(NH3) 液態氨不易儲存，須以8 kg/cm2以上的壓力，將液態氨 儲存在壓力容器内，使用時再以汽化方式，先將液態氨汽 化後，再將氨氣直接喷入選擇性觸媒還原法（SCR)脫硝設 備中，其缺點為須以壓力容器儲存液態氨，且儲存液態氨 的壓力容器，放在室内的密閉空間，若氨氣發生洩漏時， 氨氣會與空氣混合，有發生爆炸的危險。 (二） 尿素水溶液（Aqueous Urea Solution)(CONH2)2 尿素在常溫、常壓下，呈現無色結晶固體形狀，可以溶 於水。傳統作法是將尿素水溶液中所含尿素濃度調整在 32.5%左右，作為選擇性觸媒還原法（SCR)處理氮氧化物 (ΝΟχ)的還原劑。當排氣溫度高於160°C時，噴入選擇性觸 媒還原法SCR脫硝設備中的尿素水溶液，會在高溫下先行 分解成為氨氣與二氧化碳，其中氨氣再與氮氧化物（ΝΟχ) 反應，將其轉變為氮氣與水後，再排放至大氣。 尿素的缺點包括：（1)尿素水溶液須先行分解成為氨氣 140426.doc 1374971 再進行脫墙反應（DeNOx)，層於間接式氨氣注入法因此 由尿素轉換為氨氣的反應速度與效率，比較難以控制；（2) 在注入喷嘴部份，經常會有固體雜質產生，造成堆積與噴 嘴堵塞’進而影響喷嘴喷霧的效果；（3)在常溫環境下 (35°C-60°C)，會有部份尿素水溶液分解成為氨氣與二氧化 碳’谷易造成氨氣外洩的危害；（4)在低溫環境下（<· ire)，尿素水溶液會產生凝結現象；以及（5)與液態氨比 較，須有相當約2.5-3倍容積空間來儲存，並且脫硝的效 果並無法與液態氨相比。 綜上，相關習知技術不外乎單獨依賴黑煙過濾器來過濾 固態的微細碳粒子（Particulate)、或是單獨依賴氧化型觸媒 轉化器（Diesel Oxidation Catalyst)來處理氣態的碳氫化合 物（Hydrocarbons)與一氧化碳（Carbon Mon〇xide)之混合 物、或是以黑煙過濾器披覆氧化型觸媒來同時處理固態的 微細碳粒子（Particulate)及碳氫化合物（Hydrocarbons)、一 氧化碳（Carbon Monoxide)、或是依賴儲存於高壓壓力容器 内的液態氨、或是利用需要大容量儲存空間、及諸多處理 技術限制的尿素水溶液，以選擇性觸媒還原法（SCR)脫硝 設備處理氮氧化物（NOx)。 不論是使用黑煙過濾器（含觸媒披覆）' 或是使用氧化型 觸媒轉化器、或是使用以液態氨或尿素水溶液為還原劑的 選擇性觸媒還原法（SCR)脫硝’設備，皆無法同時經濟、安 全、有效處理含有毒性的氮氧化物（ΝΟχ)、氣態的碳氫化 合物（Hydrocarbons)、一 氧化碳（Carbon Monoxide)與固態 140426.doc 的微細碳粒子（Pariculate)之引擎廢氣s因此實有必要提 供一種可自動偵測廢氣污染狀況，以彈性、經濟、有效地 運用碳化矽除煙陣列、固態無機鹽類氨儲存器、選擇性還 原觸媒陣列及氧化型觸媒除臭陣列，以不同於上述常見的 引擎廢氣處理習知技術，全面淨化所有引擎廢氣中的污染 物質，包括毒性的氮氧化物（Ν〇χ)、氣態的碳氫化合物 (Hydr❹b—、-氧化碳（Carb〇n M_xide)與固態㈣ 細碳粒子（particulate)，#門應用於發電機或動態不斷電系 統之柴油引擎廢氣處理系統。 【發明内容】 本發明之目的，在提供—種可克服前述f知技術缺點， 應用於發電機或動態不斷電系統，可自動偵測廢氣污染狀 況，以彈性、經濟、有效地運用碳化石夕除煙陣列、固態無 機鹽類氨儲存器、選擇性還原觸媒陣列及氧化型觸媒除臭 陣列之脫石肖級智慧型全功能柴油引擎廢氣處理系統。本發 明針對傳統黑煙過以及氧化型觸媒轉化器之缺點加以^ 合改良’並以先進的氨氣儲存供應區結合選擇性還原觸媒 陣列（SCR)’以達全功能的最佳廢氣處理效果。本發明所 採用之氨氣儲存供應區包括：固態無機鹽類氨儲存琴'氨 =量控制闕、氨氣彦生加熱器等，完全不同於傳統的液 ϋ與尿素水溶液氨氣儲存供應方心處理後的引 氣’能夠符合2_年中國非道路移動機械用柴油機排氣污 染物排放限值（中國二階段）、2〇15年歐洲eur〇 4 期、則年美國Tier 4環保四期非公路柴油引擎排放標準 140426.doc 1374971 與2004年台灣電力設施空氣污染物排放標準。6. Description of the Invention: [Technical Field] The present invention is a denitration-grade intelligent full-function diesel engine exhaust gas treatment system applied to a generator or a dynamic uninterruptible power system, particularly for processing a generator or a dynamic The exhaust-level intelligent full-function diesel engine exhaust gas treatment system of the exhaust gas discharged from the uninterruptible power system. [Prior Art] Diesel engine exhaust gas treatment systems used in generators or dynamic uninterruptible power systems are known in the industry. 'Exhaust gas is usually treated in two ways: (1) Treatment of solid fine carbon with a black smoke filter Particular (2) Treatment of gaseous hydrocarbons (hydrocarbons) and carbon monoxide (Carb〇n M〇n〇xide) using an oxidizing catalyst converter. The following is a conventional head oil engine exhaust gas treatment system: Taiwan Patent Publication No. 373688 discloses an improved exhaust pipe which is connected to an exhaust pipe by an inverted j-shaped pipe to form two outlet ends, wherein one outlet end is connected to one The filter is used to filter out particulate contaminants; Taiwan Patent Publication No. M25 1021 discloses a microwave exhaust engine filter, especially a microparticle that can be directly placed in the filter channel by microwave radiation. Carbon) heating and burning, so that the temperature of the working and reaction of the catalyst or the carrier is increased, and the temperature of the light is effectively increased; Taiwan Patent Publication No. M299775 discloses a diesel engine exhaust purification device, and a filter element is arranged horizontally. In the inner middle portion of the body, various particles introduced into the exhaust gas from the exhaust pipe can be filtered. A magnetron system is inserted into the inner space of the body and electromagnetic waves can be generated to oscillate and burn particles attached to the surface of the filter element. To achieve the effect of exhaust pollution control; Taiwan Patent Notice No. M3丨3 724 140426.doc 1374971. Revealing a post-steamer system that can be retrofitted to various old diesel engines The vehicle is mainly composed of a diesel vaporization device and a filter filter. The diesel vaporization device mainly vaporizes the diesel oil, and the filter is mainly used for self-ignition and filtration to remove carbon monoxide and hydrocarbon. Compounds, microparticles, black smoke and odor; Taiwan Patent Publication No. 577482 discloses a smoke purification and purification device 'heater of the heating-heating control unit as a catalytic converter because of insufficient temperature of the engine exhaust, heating compensation Insufficient temperature rise; and φ Θ 公告 公告 ] ] ] ] VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI 柴油 柴油 柴油 柴油 柴油 柴油 柴油 柴油 柴油 柴油 柴油 柴油 柴油 柴油 柴油 柴油 柴油 柴油 柴油 柴油 柴油After the air is atomized and ignited, the heat energy generated by the incomplete combustion of the exhaust gas discharged from the engine is re-burned, and the carbon particles captured by the exhaust gas purifier filter element are heated and burned again to enhance the smoke removal, deodorization and detoxification of the purifier. Features. In addition, regarding the treatment of toxic nitrogen oxides (Ν〇χ), techniques known in the art include the treatment of nitrogen oxides (NOx) by selective catalytic reduction (Selective Catalytic • ReC〇Very for short). When nitrogen oxides (ruthenium) pass through the denitration catalyst, ammonia gas is used as a reducing agent for the selective catalyst reduction to convert nitrogen oxides (NGx) into nitrogen and water. The following is a technique for the treatment of toxic nitrogen oxides: U.S. Patent No. 5,489,420 discloses the use of ammonia to remove nitrogen oxides by adding a reducing agent to nitrogen oxides at elevated temperatures. Nitrogen oxide is removed at a high temperature of rc or higher; U.S. Patent Nos. 5,443,8,5 and 5,536,482 disclose the addition of a polymer to ammonia at 9 〇〇〇c to 12 〇〇t. A method for removing nitrogen oxides; Taiwan Patent Publication No. 140426.doc 1374971 M27 1135 discloses a selective catalyst reduction denitration system which utilizes a reduction method to inject ammonia gas (Ammonia NH3) as a reducing agent. The nitrogen oxides and the ammonia gas flow through the catalyst bed, that is, the reduction of nitrogen oxides into nitrogen (N〇 and water (H2〇); and Taiwan Patent Publication No. j 2485〇4 discloses an ammonia-adding subsystem' including an ammonia vapor source, The ammonia steam injection pipe disposed in the inlet pipe ten, the ammonia vapor pipe provided between the ammonia steam source and the ammonia injection grid, the fluid passage, and the throttle valve disposed in the ammonia vapor pipe, the step of mixing the ammonia vapor further includes By adding ammonia controller Regulating the throttle valve to control the rate of ammonia addition. Generally, the purpose of the black smoke filter is to filter the solid fine carbon particles (Particulate), which is usually used as a porous ceramic filter material, which has a honeycomb shape at both ends of the inlet and outlet. Therefore, when the black smoke exhaust enters the honeycomb passage through the inlet end of the filter, the outlet end of the passage is closed and cannot pass, and the carbon particles are captured by the honeycomb filter material, thereby achieving the effect of filtering the black smoke exhaust gas. Although the black smoke filter does achieve specific effects, in fact, there are still many disadvantages to treating the engine exhaust gas with such a green filter alone: (1) The black smoke filter can only filter black smoke, and the coffin must be shut down frequently. The reason is that the number of the traditional "black smoke filters and devices" installed in the honeycomb wall is also very large. The system setup cost is about 5 to 15 times that of using an oxidizing catalyst converter, and the price is very expensive. Oxygen: Catalytic converter 1. Secret (10) CaU (IV) is designed to handle wind seven Hydrogen compounds (Hydrc > eai < b () ns) and - oxidized carbon M 〇 n 〇 Xlde) ° coated with oxidized catalyst on the surface of the ceramic or metal base material 'to reduce the gaseous hydrocarbons (Hydr 〇 Carb〇ns) and oxidize 140426.doc 1374971 Carbon Monoxide combustion temperature, then use the engine exhaust temperature 'end to convert the gaseous hydrocarbons (Hydrocarbons) and carbon monoxide (Carbon Monoxide) into water and carbon dioxide However, the engine exhaust gas is only treated by the oxidized catalyst converter (Diesel 〇xidati〇n Cataiyst). (1) It cannot handle the large amount of black smoke generated when the engine is started instantaneously. (2) It cannot handle low engine load operation; Low exhaust temperature (<25〇. 〇) The disadvantages of gaseous hydrocarbons (hydrocarbons) and carbon monoxide (Carbon Monoxide). The use of selective catalytic reduction (SCR) to treat toxic nitrogen oxides (N0X). Bruises, due to the industry's known diesel engine exhaust gas treatment technology is not mature, and is limited by varying engine loads and varying concentrations of nitrogen oxides (Ν〇χ); especially in? When the engine is running at no load and the extremely low exhaust gas temperature (less than 250 °C - 3GGt), the selective catalyst reduction method will not be possible. When ammonia (Ammonia NHs) is used as a reducing agent, ammonia is a toxic chemical. When the exhaust temperature is extremely low, the ammonia gas can not be sufficiently effectively reacted with nitrogen oxides. Danger of overflow 0 Although ammonia is used in selective catalyst reduction (SCR) for deNOx (DeNOx), it is a very good reducing agent U-, its boiling point is -33.41, that is, at normal temperature, normal plant The way is to present 'chemical gases that are strongly toxic and rot (iv). At high temperatures, it will decompose into a gas container that can (4) hydrogen and toxic gases, and the fire towel will store ammonia gas, which will also cause damage and explosion. Therefore, when ammonia is stored indoors, safety must be carefully considered. Based on the above-mentioned 140426.doc 1374971 various restrictions and ammonia storage for safety, considerations, currently known in the industry, for the toxic nitrogen oxides contained in diesel engine exhaust gases from generators or dynamic uninterruptible power systems ( There is no economic and effective treatment technology in the part of ΝΟχ). In addition, selective catalyst reduction (SCR), which uses ammonia as a reducing agent, is a technique known in the industry and is basically classified into two categories: "liquid ammonia" and "urea water solution". As described below, there are still many shortcomings and inconveniences in the application of liquid ammonia or aqueous urea solution: (1) Liquid ammonia (Liquefied Ammonia) (NH3) Liquid ammonia is not easy to store and must be at a pressure of 8 kg/cm2 or more. The liquid ammonia is stored in the pressure vessel, and when it is used, the liquid ammonia is vaporized first, and then the ammonia gas is directly sprayed into the selective catalyst reduction (SCR) denitration device, and the disadvantage is that the pressure vessel is required. A pressure vessel that stores liquid ammonia and stores liquid ammonia is placed in a confined space inside the room. If ammonia gas leaks, the ammonia gas will mix with the air and there is a danger of explosion. (2) Aqueous Urea Solution (CONH2) 2 Urea is in the form of a colorless crystalline solid at normal temperature and normal pressure and can be dissolved in water. Conventionally, the concentration of urea contained in the aqueous urea solution is adjusted to about 32.5%, and the reducing agent for treating nitrogen oxides (ΝΟχ) is selected as a selective catalyst reduction method (SCR). When the exhaust gas temperature is higher than 160 °C, the urea aqueous solution injected into the SCR denitration equipment of the selective catalyst reduction method will be decomposed into ammonia gas and carbon dioxide at a high temperature, wherein the ammonia gas is further combined with nitrogen oxides. The reaction is converted to nitrogen and water and then discharged to the atmosphere. The disadvantages of urea include: (1) the aqueous urea solution must be first decomposed into ammonia gas 140426.doc 1374971 and then de-walling reaction (DeNOx), the reaction speed and efficiency of the conversion from urea to ammonia in the indirect ammonia injection method. It is more difficult to control; (2) In the injection nozzle part, there are often solid impurities, which cause accumulation and nozzle clogging' and thus affect the nozzle spray effect; (3) under normal temperature environment (35 ° C -60 ° C) There will be some urea aqueous solution decomposed into ammonia gas and carbon dioxide 'Valley easy to cause ammonia leakage; (4) in low temperature environment (<·ire), urea solution will cause condensation; and (5) and Compared with liquid ammonia, liquid ammonia must be stored in a volume of about 2.5-3 times, and the effect of denitrification cannot be compared with liquid ammonia. In summary, the related art relies on relying solely on a black smoke filter to filter solid fine carbon particles (Particulate) or to rely solely on an oxidized catalytic converter (Diesel Oxidation Catalyst) to treat gaseous hydrocarbons ( Hydrocarbons) and carbon monoxide (Carbon Mon〇xide) or a black smoke filter coated with oxidizing catalyst to simultaneously treat solid fine carbon particles (Particulate) and hydrocarbons (Hydrocarbons), carbon monoxide (Carbon Monoxide) Or relying on liquid ammonia stored in a high-pressure pressure vessel, or using a urea aqueous solution requiring a large-capacity storage space and a variety of processing techniques to treat nitrogen oxides by a selective catalytic reduction (SCR) denitration apparatus ( NOx). Whether using a black smoke filter (including catalyst coating) or using an oxidizing catalyst converter, or using a selective catalyst reduction (SCR) denitration with liquid ammonia or aqueous urea as a reducing agent Equipment, it is impossible to economically, safely and effectively treat engine exhaust gases containing toxic nitrogen oxides, gaseous hydrocarbons, carbon monoxide and solid carbon particles of the solid 140426.doc. Therefore, it is necessary to provide an automatic detection of exhaust gas pollution conditions, elastic, economical and effective use of carbonized strontium removal array, solid inorganic salt ammonia storage, selective reduction catalyst array and oxidizing catalyst deodorization The array, in addition to the above-mentioned common engine exhaust gas treatment know-how, comprehensively purifies pollutants in all engine exhaust gases, including toxic nitrogen oxides (Ν〇χ), gaseous hydrocarbons (Hydr❹b-, - carbon oxide ( Carb〇n M_xide) and solid state (4) fine carbon particles (particulate), #门 applied to generator or dynamic uninterruptible power system diesel engine exhaust gas treatment system SUMMARY OF THE INVENTION The object of the present invention is to provide a technology that can overcome the shortcomings of the above-mentioned technical problems, and can be applied to a generator or a dynamic uninterruptible power system to automatically detect exhaust gas pollution conditions, and to utilize carbon fossils in an elastic, economical and effective manner. An anti-smoke array, a solid inorganic salt ammonia storage device, a selective reduction catalyst array, and an oxidized catalyst deodorizing array, the desulfurization-class intelligent full-function diesel engine exhaust gas treatment system. The present invention is directed to conventional black smoke and The disadvantages of the oxidizing catalyst converter are improved and combined with the selective ammonia reduction storage array (SCR) to achieve the full-featured optimum exhaust gas treatment effect. The ammonia used in the present invention. The gas storage supply area includes: solid inorganic salt ammonia storage piano 'ammonia=quantity control 阙, ammonia gas yansheng heater, etc., which is completely different from traditional liquefied gas after liquid helium and urea aqueous solution storage. It can meet the emission limit of 2% of China's non-road mobile machinery diesel exhaust pollutants (China's second stage), 2-15 years of European eur〇4, then the US Tier 4 environmental protection 4 Emission Standard for Off-Highway Diesel Engines 140426.doc 1374971 and 2004 Air Pollutant Emission Standards for Taiwan Power Facilities.
本發月係關於一種包括一廢氣流動區之脫硝級智慧型全 功能柴油引擎廢氣處理系統，用來處理引擎所排出之引擎 廢氣。該廢氣流動區包括：—用以供引擎廢氣導入廢氣流 動區之中間聯絡管、至少一氧化型觸媒除臭陣列、至少— 選擇性還原觸媒陣列、至少—碳切除煙陣列及一排氣主 管。該至少-氧化型觸媒除臭陣列與中間聯絡管直接或間 接相通，以處理來自中間聯絡管之碳氫化合物 (Hydrocarbons)或一氧化碳（Carb〇n M〇n〇xide)廢氣。該至 少-選擇性還原觸媒陣列與中間聯絡管直接或間接相通， 以處理來自t間聯絡管之氮氧化物⑽χ)廢氣。該至少一This issue is about a denitration-grade intelligent full-featured diesel engine exhaust gas treatment system that includes an exhaust gas flow zone to treat engine exhaust from the engine. The exhaust gas flow region comprises: an intermediate communication pipe for introducing the engine exhaust gas into the exhaust gas flow region, at least one oxidation type catalyst deodorizing array, at least - a selective reduction catalyst array, at least a carbon cut tobacco array, and an exhaust gas Supervisor. The at least-oxidized catalyst deodorizing array is in direct or indirect communication with the intermediate communication tube to treat hydrocarbons (Hydrocarbons) or carbon monoxide (Carb〇n M〇n〇xide) from the intermediate communication tubes. The at least-selective reduction catalyst array is in direct or indirect communication with the intermediate communication tube to treat the nitrogen oxide (10) χ exhaust gas from the t-contact tube. At least one
碳化石夕除煙陣列與中間聯絡管直接或間接相通，以過遽來 自中間聯絡g含有固_微細碳粒子的廢氣n氣主管與 該碳切除煙陣列間接或直接相通，以將經由碳化石夕除煙 陣列顧後之廢氣排放至大氣。該廢氣流動區界定出第— 廢氣處理路徑及一第二廢氣處理路徑。該第一廢氣處理路 2及第二廢氣處料徑均延伸於該巾間聯絡管及該排氣主 S之間，且在„玄第一廢氣處理路徑中廢氣先後通過該中 間聯絡管、該至少一碳化矽除煙陣列、該至少一氧化型觸 媒除臭陣列、該至少一選擇性還原觸媒陣列，及該排氣主 管；而在該第二廢氣處理路徑中’廢氣先後通過該中間聯 絡管、該至少一氧化型觸媒除臭陣列、該至少一選擇性還 原觸媒陣列、該消音器及該排氣主管。該廢氣流動區可在 其適當位置處藉-排氣偵測裝置偵測一引擎廢氣資料，因 140426.doc -11· 此田該引擎廢氣經由中間聯絡管進入該脫硝級智慧型全功 此柴油引擎氣處理系統後，該脫硝級智慧型全功能柴油引 擎廢虱處理系統可利用一微電腦控制器對該引擎廢氣資料 做出最佳賴’以決定將㈣廢氣^丨通過第—廢氣處理 路徑或第二廢氣處理路徑處理後，再排放至大氣。 根據本發明，排氣侧裝置設於該等廢氣處理路徑中， 以全方位地連續偵則擎所排出之廢氣排氣資料，如溫 度、壓力、流量、不透光率、碳氫化合物、一氧化碳、硫 氧化物、氮氧化物等。微電腦控制器再根據排氣資料判斷 引擎廢氣污染程度，下達指令選擇適當的廢氣處理路徑， 以達最佳處理效果’使引擎廢氣的黑煙顆粒、碳氫化合 物' 氮#1化物及-氧化碳’經過碳化碎除煙陣列及氧化型 觸媒除臭陣列及選擇性還原觸媒陣列處理。 此外本毛明進一步建議該碳化石夕除煙陣列採用自動再 生之加熱型黑煙過渡器，該氧化型觸媒除臭陣列採用低溫 型觸媒轉化器’並以固態無機鹽類氨儲存器取代傳統的液 態氨、尿素水溶液等氨氣儲存供應方式。加熱型黑煙過濟 益之優點在於高效率處理黑煙、且渡材可自動再生；而低 溫觸媒轉化器之優點在於購置成本低廉、零操作費用、可 在低排氣溫度下，處理碳氫化合物、—氧化碳及部份里 煙、引擎可以連續運轉’不須要停機。固態無機鹽類氨儲 存器’具有在常溫㈣下，能夠安全無害的儲存供應高純 度氨氣（Amm°nia NH3)以及只需要極小室内儲存空間的優 點。以上三種襄置經由本發明之系統整合後，可獲得一不 140426.doc 12 /1 可預期之功效 【實施方式】 圖1所示為本發明之水平對稱配置結構之實施例該圖 所示脫硝級智慧型全功能柴油引擎廢氣處理系統i大致包 括：-由元件編號為 10, 20, 3〇, 40, 5〇, 6〇, 7〇, 8〇, 等構件組成之廢氣流動區、一由元件編號為16〇， 1 62等構件組成之氨氣儲存供應區、—微電腦控制器 及連接於廢,氣流動區、|氣儲存供應區及微電腦 控制器100之間之排氣偵測裝置n〇。 廢氣流動區如上所述，較佳包括：—中間聯絡管1〇、至 ;-下集管20、至少一氧化型觸媒除臭陣列3〇、至少一中 間集管40、至少一碳化矽除煙陣列5〇、至少一上集管、 -排氣主管70、一消音器8〇、及至少一選擇性還原觸媒陣 列150 T間聯絡；· H)具有_人σ飢，其連接至引擎排氣口以 接納由引擎排出之未處理廢氣。該至少一下集管2〇使中間 聯絡管10與該至少-氧化型觸媒除臭陣列30、及至少一選 擇性還原觸媒陣列150相連通。該至少一中間集管4〇使中 間聯絡官10與該至少一碳化矽除煙陣列5〇相連通。藉此， 中間聯絡管可與該至少—氧化型觸媒除臭陣列3Q、及至 少-選擇性還原觸媒陣列15〇或至少一碳化石夕除煙陣列5〇 溝通。氧化型觸媒除臭陣列3〇、及至少一選擇性還原觸媒 陣列150與碳化矽除煙陣列5〇之間可透過中間集管相互 溝通。 140426.doc •13· 每個氧化型觸媒除臭陣列3 Ο ’較佳由至少一個低溫型觸 媒轉化器所組成，在處理引擎低負載、低排氣溫度所產生 的一氧化碳及碳氫化合物之廢氣時，可得最理想之處理功 效。每個碳化矽除煙陣列50，較佳由至少一個加熱型黑煙 過渡器所組成’在高效率過遽黑煙、且滤材可自動再生， 可得最理想之處理功效》 氨氣儲存供應區’較佳由至少一個固態無機鹽類氨儲存 器16〇、至少一氨氣定量控制閥161、至少一氨氣產生加熱 态162所組成。氨氣儲存供應區在常溫常壓下，可以安全 無害的方式，將高純度的氨氣（Ammonia ΝΗ3)，釋放出並 注入選擇性還原觸媒陣列150中，藉此在處理氮氧化物 (NOx) ’可最得理想之處理功效。 每組氧化型觸媒除臭陣列30較佳包括1至2〇個低溫型觸 媒轉化器，而氨氣儲存供應區，較佳包括i至2〇個固態無 機鹽類氨儲存器160、1至20個氨氣定量控制閥16ι、以及1 至20個氨氣產生加熱器162 ^每組碳化矽除煙陣列5〇、較 佳包括1至20個加熱型黑煙過濾器，而每組選擇性還原觸 媒陣列150、較佳包括！至2〇個脫硝觸媒轉化器（De Ν〇χ Catalyst)。如圖！所示，在本較佳實施例中，構組脫硝級 智慧型全功能柴油引擎廢氣處理系統〗時，係以對稱方式 分別配置氧化型觸媒除臭陣列3 〇 '固態無機鹽類氨儲存器 160、氨氣定量控制閥161、氨氣產生加熱器162、選擇性 還原觸媒陣列150及碳化石夕除煙陣列5〇0 至少一上集官60使至少一碳化矽除煙陣列5〇與排氣主管 140426.doc 1374971 70相連通，如此經由碳化矽除煙陣列5〇之處理過之淨化氣 體可流通至排氣主管70。消音器8〇之一端透過中間聯絡= 10及中間集管40與該至少一氧化型觸媒除臭陣列3〇、選： 性還原觸媒陣列150溝通，並可提供消音功能。 尤特別的是，如圖2所示，廢氣流動區界定出一第—廢 氣處理路徑A及-第二廢氣處理路b，以處理不同污染 程度之廢氣》該第-廢氣處理路徑A及第二廢氣處理路: .B均延伸於财間聯絡管職該排氣主管70之間。如圖β 圖2所示，第-廢氣處理路徑Α，通過至少—碳切除煙陣 列50、至少-氧化型觸媒除臭陣列3〇與至少一選擇性還原 觸媒陣列15G 〇該第二廢氣處理路徑Β則通過至少—氧化型 觸媒除臭陣列3G與至少—選擇性還原觸媒陣列15〇。各引 擎廢氣自中間聯絡管10進入脫硝級智慧型全功能柴油^擎 廢氣處理系統1後’微電腦控制器_可根據引擎廢氣污染 程度」來選擇較佳之廢氣處理路徑，即第一廢氣處理路徑 Α或第^廢氣處理路徑Β ’以進行最佳廢氣處理後，再排 放至大4 L實驗證明，處理後的引擎廢氣，能夠符合 2009年中國非道路移動機械用柴油機排氣污染物排放限值 (中國二階段）、2015年歐洲職〇 4環保四期、2〇11年美國 k 4環保四期非公路柴油W擎排放標準與2_年台灣電 力設施空氣污染物排放標準。 一此外脫確級智慧型全功能柴油引擎廢氣處理系統1進 一步包括:安裝於中間聯絡管1〇及排氣主管7〇之間適當位 置處之路徑選擇控制閥9〇。該路徑選擇控制闕列受該微電 140426.doc -J5- 腦t制器1 00控制，自動選擇第一+ _ 氣處理路#6，以選擇最佳方式來處理^擎廢^或第—廢 第=:I智慧型全功能柴油引擎廢氣處理系統】安排之 隹理路徑A中’廢氣先後通過中間聯絡管⑺'下 =#7化矽除煙陣列50、氧化型觸媒除臭陣列3〇與選 =原觸媒陣列150、及排氣主管7〇。在第二廢氣處理 :中，廢氣先後通過該中間聯絡管10、氧化型觸媒除 、與130:選擇性還屌觸媒陣列150、消音器8〇、及排氣 主官7〇°碳化砂除煙陣列5〇’較佳為至少一個加熱型黑煙 過遽器。氧化型觸媒除臭陣列3〇,較佳為至少一個低溫型 觸媒轉化器。選擇性還原觸媒陣列15〇 硝觸媒轉咖―…達到最佳 效，’乳氣健存供應區’較佳由至少-固態無機鹽類氨儲 存器160、至少一氨氣定量控制閥161及至少—氨氣產生加 熱器16 2所組成β 排氣偵測裝置110設於該中間聯絡管1〇，以全方位地連 續偵測進入第一廢氣處理路徑、第二廢氣處理路徑前之引 擎排氣資料，諸如溫度、壓力、流量、不透光率、碳氫化 δ物、一氧化碳、硫氧化物、氮氧化物等。 兹就排氣偵測裝置110如何偵測廢氣排氣資料，提供給 微電腦控制器100選擇適當之廢氣處理路徑，例舉說明如 後： 1 ·根據本發明之較佳實施例，當排氣偵測裝置丨10，測 得排氣溫度超過250。(：時，脫硝級智慧型全功能柴油引擎 140426.doc -16- 1374971 廢氣處理系統！會選擇第二廢氣處理路徑B，亦即先後通過 中間聯絡管10、氧化型觸媒除臭陣3〇、選擇性還原觸媒= 列15〇、消音器80、及排氣主管7〇,而後將廢氣排放至大 氣。若排氣偵測裝置110，測得排氣溫度低於25〇t時脫 硝級智慧型全功能柴油引擎廢氣處理系統丨會選擇第一廢 氣處理路徑A，亦即先後通過中間聯絡管1〇、下集管2〇、 碳化石夕除煙陣列50,氧化型觸媒除臭陣列3〇、選擇性還原 觸媒陣列150、及排氣主管7〇，而後將處理後的廢氣排放 至大氣。 2.根據本發明之較佳實施例，當排氣谓測裝置ιι〇,測 得排氣系統壓力超過引擎最大容許排氣塵力（Μ3χ_ Engine Allowab】e Back ^叫時，脫破級智慧型全功能 柴油引擎廢氣處理系統！會選擇第二廢氣處理路徑B，亦即 先後通過中間聯絡管10、氧化型觸媒除臭陣列％、選擇性 還原觸媒陣列150、消音器，、及排氣主管7〇,而後將處 理後的廢氣排放至大氣。當排氣偵測裝置ιι〇，測得排 系統屡力低於引擎最大容許排氣屋力時，脫石肖級智慧型全 功能柴油引擎廢氣處理系統i會選擇第一 二即先後通過中間聯絡管10、下集管2。、碳化彻陣列 氧化型觸媒除臭陣⑽、選擇性還原觸媒陣列150、 排氧主管70’而後將處理後的廢氣排放至大氣。 二發明之較佳實施例，當排氣谓測裝置U。，測 氣處超過2〇%時，脫石肖級智慧型全功能柴油引擎廢 處系統1會選擇第-廢氣處理路徑心亦即先後通過中 140426.doc 17 卜集m碳化石夕除煙障_， 除臭陣列30、選擇性谨屌館拔陆 媒 而㈣★ 還原觸媒陣列150、及排氣主管70, ·=::的廢氣#至大氣。而若排氣偵測裝置-， γ 200/0時，脫石肖級智慧型全功能柴油引擎 會選擇第二廢氣處理路徑Β，亦即先後通過 _。、消音㈣、及::主了、_^ 氣排至大氣。 w而後將處理後的廢 二·根據本發明之較佳實施例，當排氣價測裝置ιι〇，測 付石反風化合物低於12〇 ^ p時脫硝級-智慧型全功能柴油 引擎廢氣處理系統1會選擇第二廢氣處理路徑B，亦即先後 通過中間聯絡管j 〇、童〆卜 $㈣觸媒除臭P車列30、選擇性還原 、：列150 '肖音态8〇、及排氣主管7〇 ’而後將淨化後 之廢乳排放至大氣。當排氣偵測裝置110，測得碳氫化合 超過120 ppm時’㈣級智慧型全功能柴油引擎廢氣處 理线！會選擇第-廢氣處理路徑A’亦即先後通過中間聯 絡官10、下集管20、破化石夕除煙陣列5〇，氧化型觸媒除臭 陣列3〇、選擇性還原觸媒陣列15〇、及排氣主管7〇,而後 將淨化後之廢氣排放至大氣。 5.根據本發明之較佳實施例’當排氣積測裂置ιι〇，測 得一氧化碳低於300 ppm時，脫確級智慧型全功能柴油引 擎廢氣處理系統1會選擇第二廢氣處理路徑B，亦即先後通 過中間聯絡官10、氧化型觸媒除臭陣列3〇、選擇性還原觸 媒陣列150、消音器8〇、及排氣主管7〇而後將淨化後之廢 J 4〇426,doc 1374971 氣排放至大氣。當排氣偵測裝置110，測得—氧化 300 ppm時，脫硝級智慧型全功能柴油引擎廢氣處理系統i 會選擇第-廢氣處理路徑A ’亦即先後通過中間聯絡管 1〇、下集管20、碳化矽除煙陣列5〇’氧化型觸媒除臭陣列 3〇、選擇性還原觸媒陣列15〇、及排氣管7〇,而後將淨化 後之廢氣排放至大氣。 7， N 1 1 U » /βThe carbonized fossil ash array is directly or indirectly connected to the intermediate communication tube, and the exhaust gas n gas main pipe containing the solid-fine carbon particles from the intermediate contact g is indirectly or directly communicated with the carbon cut tobacco array to pass through the carbon carbide eve Exhaust gas from the smoke array is discharged to the atmosphere. The exhaust gas flow zone defines a first exhaust gas treatment path and a second exhaust gas treatment path. The first exhaust gas treatment path 2 and the second exhaust gas flow path extend between the inter-toilet communication pipe and the exhaust main S, and the exhaust gas passes through the intermediate communication pipe in the first exhaust gas treatment path. At least one carbonization enthalpy removal array, the at least one oxidation type catalyst deodorization array, the at least one selective reduction catalyst array, and the exhaust gas line; and in the second exhaust gas treatment path, the exhaust gas passes through the middle a contact tube, the at least one oxidation type catalyst deodorizing array, the at least one selective reduction catalyst array, the muffler and the exhaust main pipe. The exhaust gas flow area can be borrowed at an appropriate position Detecting an engine exhaust gas data, because the engine exhaust gas enters the denitration-grade intelligent full-duty diesel engine gas treatment system through the intermediate communication pipe, the denitration-grade intelligent full-function diesel engine The waste disposal system can utilize a microcomputer controller to optimize the exhaust gas data of the engine to determine (4) that the exhaust gas is processed through the first exhaust gas treatment path or the second exhaust gas treatment path, and then discharged to the atmosphere. According to the present invention, the exhaust side device is disposed in the exhaust gas processing paths to continuously detect the exhaust gas exhaust data discharged from the engine, such as temperature, pressure, flow rate, opacity, hydrocarbon, Carbon monoxide, sulfur oxides, nitrogen oxides, etc. The microcomputer controller then judges the degree of engine exhaust pollution based on the exhaust data, and issues an appropriate exhaust gas treatment path to achieve the best treatment effect 'black smoke particles and carbon of the engine exhaust gas. The hydrogen compound 'nitrogen #1 compound and carbon monoxide' is processed through a carbonized ash removal array and an oxidizing catalyst deodorization array and a selective reduction catalyst array. Further, the present invention further suggests that the carbonization ash elimination array is automatically used. Regenerated heating type black smoke transition device, the oxidation type catalyst deodorizing array adopts a low temperature type catalytic converter' and replaces the traditional liquid ammonia, urea aqueous solution and the like with a solid inorganic salt ammonia storage device. The advantage of the type of black smoke is that the high-efficiency treatment of black smoke and the ferry material can be automatically regenerated; and the low-temperature catalyst converter has the advantages of low purchase cost. Low cost, zero operating cost, can handle hydrocarbons, carbon monoxide and some smoke in low exhaust temperature, the engine can run continuously 'no need to stop. Solid inorganic salt ammonia storage' has at normal temperature (four) It can safely and harmably store high-purity ammonia (Amm°nia NH3) and only requires minimal indoor storage space. The above three devices can be integrated through the system of the present invention to obtain a temperature of 140426.doc 12 /1 [Embodiment] Figure 1 shows an embodiment of a horizontally symmetric configuration of the present invention. The denitration-grade intelligent full-featured diesel engine exhaust gas treatment system i shown in the figure generally comprises: - by component number 10, 20 , 3〇, 40, 5〇, 6〇, 7〇, 8〇, the exhaust gas flow area composed of components, an ammonia gas storage supply area consisting of components such as 16〇, 1 62, etc.—microcomputer controller And an exhaust gas detecting device connected between the waste gas flow region, the gas storage supply region and the microcomputer controller 100. The exhaust gas flow zone preferably includes: - an intermediate communication pipe 1 〇, to; a lower header pipe 20, at least one oxidation type catalyst deodorizing array 3 〇, at least one intermediate header 40, at least one carbonization enthalpy a stack of smoke, at least one upper header, - an exhaust main 70, a muffler 8A, and at least one selective reduction catalyst array 150 T; H) has a _ human stagnation, which is connected to the engine The exhaust port receives the untreated exhaust gas discharged by the engine. The at least one lower header 2 communicates the intermediate communication tube 10 with the at least oxidized catalyst deodorizing array 30 and the at least one selective reduction catalyst array 150. The at least one intermediate header 4 interconnects the intermediate liaison officer 10 with the at least one niobium strontium removal array 5A. Thereby, the intermediate communication pipe can communicate with the at least-oxidation type catalyst deodorizing array 3Q, and at least the selective reduction catalyst array 15 or at least one carbonized fossil array. The oxidizing catalyst deodorizing array 3 and the at least one selective reduction catalyst array 150 and the tantalum carbide degassing array 5 are communicated with each other through the intermediate header. 140426.doc •13· Each Oxidation Catalyst Deodorization Array 3 Ο 'It is preferably composed of at least one low temperature catalyst converter to treat carbon monoxide and hydrocarbons produced by low engine load and low exhaust gas temperature. The best treatment effect is obtained when the exhaust gas is used. Each of the niobium removal arrays 50 is preferably composed of at least one heating type black smoke transitioner. 'In high efficiency, black smoke, and the filter material can be automatically regenerated, and the best treatment effect can be obtained." Ammonia storage supply The zone 'preferably consists of at least one solid inorganic salt ammonia reservoir 16 〇, at least one ammonia gas quantitative control valve 161, and at least one ammonia gas produced heating state 162. The ammonia storage supply zone can release high-purity ammonia (Ammonia ΝΗ3) into the selective reduction catalyst array 150 in a safe and harmless manner at normal temperature and pressure, thereby treating nitrogen oxides (NOx). ) 'The best processing power. Each set of oxidizing catalyst deodorizing array 30 preferably comprises 1 to 2 low temperature type catalytic converters, and the ammonia storage supply area preferably comprises 1 to 2 solid inorganic salt ammonia storages 160, 1 Up to 20 ammonia gas quantitative control valves 16ι, and 1 to 20 ammonia gas generating heaters 162 ^ each group of carbonized strontium rod removing arrays 5 〇, preferably including 1 to 20 heating type black smoke filters, and each group is selected The sexual reduction catalyst array 150 preferably includes! Up to 2 denitration catalyst converters (De Ν〇χ Catalyst). As shown! As shown, in the preferred embodiment, when the denitration-grade intelligent full-function diesel engine exhaust gas treatment system is constructed, the oxidized catalyst deodorizing array 3 〇 'solid inorganic salt ammonia storage is separately arranged in a symmetrical manner. The apparatus 160, the ammonia gas quantitative control valve 161, the ammonia gas generating heater 162, the selective reduction catalyst array 150, and the carbonization stone removing array 5〇0, at least one upper collecting unit 60, at least one carbonized rod removing the smoke array 5〇 In communication with the exhaust mains 140426.doc 1374971 70, the treated purge gas via the tantalum carbide degassing array 5〇 can be circulated to the exhaust mains 70. One end of the muffler 8〇 communicates with the at least one oxidation type catalyst deodorizing array 3〇, the selective reduction catalyst array 150 through the intermediate contact=10 and the intermediate header 40, and provides a silencing function. In particular, as shown in FIG. 2, the exhaust gas flow region defines a first exhaust gas treatment path A and a second exhaust gas treatment path b to treat exhaust gases of different pollution levels. The first exhaust gas treatment path A and the second Exhaust gas treatment road: .B extends between the financial supervisory authority and the exhaust supervisor 70. As shown in FIG. 2, the first exhaust gas treatment path Α passes through at least the carbon cut tobacco array 50, the at least oxidized catalyst deodorizing array 3〇, and the at least one selective reduction catalyst array 15G. The processing path is then passed through at least the oxidizing catalyst deodorizing array 3G and at least the selective reducing catalyst array 15A. Each engine exhaust gas enters the denitration-grade intelligent full-function diesel engine exhaust gas treatment system 1 from the intermediate communication pipe 10, and the 'microcomputer controller _ can select the preferred exhaust gas treatment path according to the degree of engine exhaust pollution”, that is, the first exhaust gas treatment path Α or the second exhaust gas treatment path Β 'for the best exhaust gas treatment, and then discharged to the large 4 L experiment proves that the treated engine exhaust gas can meet the emission limit of China's non-road mobile machinery diesel exhaust pollutants in 2009 (China's second phase), 2015 European job 4 environmental protection phase IV, 2-11 years US k 4 environmental protection phase IV non-road diesel W engine emission standards and 2 years Taiwan electrical facilities air pollutant emission standards. Further, the off-level intelligent full-function diesel engine exhaust gas treatment system 1 further includes: a path selection control valve 9〇 installed at an appropriate position between the intermediate communication pipe 1〇 and the exhaust main pipe 7〇. The path selection control queue is controlled by the micro-electric 140426.doc -J5- brain t-control device 100, and the first +_ gas processing road #6 is automatically selected to select the best way to deal with the control waste ^ or the first - Waste ==I intelligent full-featured diesel engine exhaust gas treatment system] Arranged in the path A of the exhaust gas, the exhaust gas passes through the intermediate communication pipe (7)' under = #7 矽 矽 矽 阵列 array 50, oxidized catalyst deodorant array 3 〇 and select = original catalyst array 150, and exhaust supervisor 7 〇. In the second exhaust gas treatment: the exhaust gas passes through the intermediate communication pipe 10, the oxidizing type catalyst, and 130: the selective catalyst array 150, the muffler 8〇, and the exhaust main officer 7〇° carbonized sand. The smoke removing array 5' is preferably at least one heated black smoke filter. The oxidizing catalyst deodorizing array 3 is preferably at least one low temperature type catalytic converter. The selective reduction catalyst array 15 〇 触 触 转 ― ― ... ... 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到And at least the ammonia generating heater 16 2 is composed of the β exhaust detecting device 110 disposed in the intermediate connecting pipe 1 〇 to continuously detect the engine entering the first exhaust gas processing path and the second exhaust gas processing path in an all-round manner. Exhaust data such as temperature, pressure, flow, opacity, hydrocarbon δ, carbon monoxide, sulfur oxides, nitrogen oxides, and the like. How the exhaust gas detecting device 110 detects the exhaust gas exhaust data is provided to the microcomputer controller 100 to select an appropriate exhaust gas processing path, as exemplified as follows: 1. According to a preferred embodiment of the present invention, when exhaust gas is detected The measuring device 丨10 measures the exhaust gas temperature over 250. (:, denitration-grade intelligent full-featured diesel engine 140426.doc -16-1374971 exhaust gas treatment system! The second exhaust gas treatment path B will be selected, that is, through the intermediate communication pipe 10, the oxidizing catalyst deodorizing array 3 〇, selective reduction catalyst = column 15 〇, muffler 80, and exhaust main pipe 7 〇, and then exhaust gas to the atmosphere. If the exhaust gas detecting device 110, the exhaust gas temperature is measured below 25 〇t The nitr-class intelligent full-featured diesel engine exhaust gas treatment system will select the first exhaust gas treatment path A, that is, through the intermediate communication pipe 1〇, the lower header 2〇, the carbonization stone elimination array 50, and the oxidized catalyst. The odor array 3, the selective reduction catalyst array 150, and the exhaust main unit 7〇, and then the treated exhaust gas is discharged to the atmosphere. 2. According to a preferred embodiment of the present invention, when the exhaust gas pre-measurement device is ιι, When the exhaust system pressure exceeds the maximum allowable exhaust dust force of the engine (Μ3χ_ Engine Allowab) e Back ^, the off-class intelligent full-function diesel engine exhaust gas treatment system will select the second exhaust gas treatment path B, that is, Oxidation through the intermediate communication tube 10 The catalyst deodorizing array%, the selective reduction catalyst array 150, the muffler, and the exhaust main pipe 7〇, and then discharging the treated exhaust gas to the atmosphere. When the exhaust detecting device is ιι〇, the measuring system is repeatedly measured. When the force is lower than the maximum allowable exhaust force of the engine, the desulfurization-class intelligent full-featured diesel engine exhaust gas treatment system i will select the first two, that is, the intermediate communication pipe 10 and the lower header 2, respectively. The catalyst deodorizing array (10), the selective reduction catalyst array 150, the oxygen discharging main unit 70', and then discharging the treated exhaust gas to the atmosphere. In a preferred embodiment of the invention, when the exhaust gas pre-measuring device U., the gas measuring portion When more than 2〇%, the Shishixiao-level intelligent full-featured diesel engine waste system 1 will select the first-exhaust gas treatment path, that is, it will pass through 140426.doc 17 and the carbonization will eliminate the smoke barrier _, deodorization Array 30, selective 屌 屌 陆 陆 而 而 (4) ★ reduction catalyst array 150, and exhaust mains 70, · =:: exhaust # to the atmosphere. And if the exhaust detection device -, γ 200 / 0 , the Shishi Xiao-level intelligent full-featured diesel engine will choose the second exhaust gas treatment path Β, that is, successively passed _., silenced (four), and:: main, _^ gas discharged to the atmosphere. w and then treated waste II. According to a preferred embodiment of the present invention, when the exhaust gas price measuring device ιι 〇, when the anti-wind compound is less than 12〇^ p, the denitration-intelligent full-featured diesel engine exhaust gas treatment system 1 will select the second exhaust gas treatment path B, that is, through the intermediate communication pipe j 〇, nursery rhyme卜 $ (4) Catalyst deodorization P train 30, selective reduction, column 150 'sound state 8 〇, and exhaust main 7 〇 ' and then the purified waste milk is discharged to the atmosphere. When the exhaust detection device 110, measured the '(four) level intelligent full-featured diesel engine exhaust gas treatment line when the hydrocarbon is more than 120 ppm! The first-exhaust gas treatment path A' will be selected, that is, through the intermediate liaison officer 10, the lower header 20, the broken shixi smoke removal array 5〇, the oxidized catalyst deodorizing array 3〇, and the selective reduction catalyst array 15〇. And the exhaust main pipe 7 〇, and then the purified exhaust gas is discharged to the atmosphere. 5. According to a preferred embodiment of the present invention, when the exhaust gas is measured and ruptured, and the carbon monoxide is less than 300 ppm, the second-class exhaust gas treatment system 1 selects the second exhaust gas treatment path. B, that is, through the intermediate liaison officer 10, the oxidizing catalyst deodorizing array 3 〇, the selective reduction catalyst array 150, the muffler 8 〇, and the exhaust main pipe 7 〇 and then the purified waste J 4 〇 426 , doc 1374971 The gas is released to the atmosphere. When the exhaust gas detecting device 110 measures - 300 ppm oxidation, the denitration-grade intelligent full-function diesel engine exhaust gas treatment system i selects the first-exhaust gas treatment path A', that is, through the intermediate communication pipe 1〇, the lower set The tube 20, the niobium carbide removing array 5〇' oxidizing type catalyst deodorizing array 3〇, the selective reducing catalyst array 15〇, and the exhaust pipe 7〇, and then discharging the purified exhaust gas to the atmosphere. 7, N 1 1 U » /β
得氮氧化物超過235 ppm時，脫确級智慧型全功能柴油弓 擎廢氣處理系W會選擇第二廢氣處理路徑B，亦即先後赶 過中間聯絡管10、氧化型觸媒除臭陣列3G、選擇性還原箱 媒陣列150、消音器80、及排氣主管7〇，而後將 廢氣排放至大氣。當排氣谓測裝置UG,測得氮氧化物伯 於出Ppm時，脫硝級智慧型全功能柴油引擎廢氣處理系 統1會選擇第-廢氣處理路徑A，亦即先後通過中間聯絡管 10、下集管2G、碳化錢煙陣列5G，氧化型觸媒除臭陣列When the nitrogen oxides exceed 235 ppm, the exhaust-level intelligent full-function diesel engine exhaust gas treatment system W will select the second exhaust gas treatment path B, that is, the intermediate communication pipe 10 and the oxidizing catalyst deodorizing array 3G. The selective reduction tank media array 150, the muffler 80, and the exhaust main pipe 7〇 are then exhausted to the atmosphere. When the exhaust gas pre-measurement device UG detects that the nitrogen oxides are emitted from the Ppm, the denitration-grade intelligent full-function diesel engine exhaust gas treatment system 1 selects the first exhaust gas treatment path A, that is, passes through the intermediate communication pipe 10 Lower header 2G, carbonized cigarette array 5G, oxidized catalyst deodorization array
6.根據本發明之較佳實施例 3〇、選擇性還原觸媒陣列15〇、排氣管7〇，而後將淨化後 之廢氣排放至大氣。 根據本發明之較佳實施例，當排氣伯測裝置HO，測 得氮氧化物超過235 Ppm時，脫硝級智慧型全功能柴油引 擎廢氣處理系統1 ’會起動氨氣產生加熱器162，將該固雜 無機鹽類氨儲存ϋ⑽適當加熱後，釋放出高純度的錢 (Ammonia ΜΗ;) ’氨氣定量控制閥161以自動定量的方式注 入脫硝級智慧型全功能柴油引擎廢氣處理系統中的選擇性 還原觸媒陣列15〇’以處理氮氧化物（Ν0χ)，將其還原為氣 140426.doc 氣與水後，排入大氣 綜上所述，排氣偵測裝置1 10，將該等排氣資料傳輸至 微電腦控制器100 ’供微電腦控制器100判別污染程度後， 再由脫硝級智慧型全功能柴油引擎廢氣處理系統1決定應 令廢氣通過第一廢氣處理路徑A或第二廢氣處理路徑B來 達成淨化廢氣之目的。 圖2所示為本發明之脫確級智慧型全功能柴油引擎廢氣 處理系統1用來處理引擎廢氣之流程之示意圖。如圖i所 示’當引擎廢氣由入口端IL進氣、導入中間聯絡管1〇後， :排氣偵測裝置110將廢氣之排氣資料傳送至微電腦控制 器1〇〇,用以判斷廢氣應導入第一廢氣處理路徑八或第二廢 氣處理路徑B。 若廢氣導入第-廢氣處理路徑八，經由下集管2〇通心 化石夕除煙陣列5G，氧化型觸媒除臭陣列30、選擇性還原j 媒陣列15(^碳化矽除煙陣列 ' 干幻）U連接至一由一控制盤1201 勒之再生加熱器（未顯示）及一： —山 工風絮庙（未不）以必要時i 订石反化矽除煙陣列再生杳 _ 在廢氣經氧化型觸媒除臭 k擇性還原觸媒陣列1 $ Q $ U5〇及碳化矽除煙陣列50淨1 !過上集管60，由排翁b m 由排矾主管70之出口端ol排出。 右廢氣導入第二廢氣處 陣列進入氧化型觸媒除1 選擇丨生還原觸媒陣列1 5 0 /•上 過消音ϋ、^ 讀氣處理，而後ϋ 控制閥90可安裝於 而〇L排丨。路徑選招 J X农A甲間聯絡管1 〇愈## 位置，較佳，、排虱主官70之間之適售 权佳&又於消音器8〇與排 徘乱主官70之間。脫硝級智« 140426.doc 1374971 型：：能柴油引擎廢氣處系統1會令微電腦控制器100進行 I*取佳處理路徑選擇。路徑選擇控制閥90亦可如圖2所 ’、又；氧化型觸媒除臭陣列3 〇、選擇性還原觸媒陣列1 % 與消音器80之間。 此外，控制盤120較佳同時由一UPS電源（不冑電電源） U〇及一緊急電源140控制，可由一設於控制盤120内之微 4理控制$自動選擇電源種類，避免脫輕智慧型全功能 Φ 柴油引擎廢氣處理系統1因跳電而無法操作。 圖3所示是本發明技術思想建構而成之另一實施例，其 顯示本心明採垂直對稱配置結構之實施狀態。如圖3所 不脫硝級智慧型全功能柴油引擎廢氣處理系統丨,大致包 括.一由元件編號為 1〇_ 2〇.，3〇’，4〇,，5〇_，6〇‘，，7〇..， 8〇，150等構件組成之廢氣流動區、一微電腦控制器 由元件編號為160，1 61，162等構件組成之氨氣 储存供應區、及一連接於廢氣流動區、氨氣儲存供應區、 # 微電腦控制器1〇〇•之間之排氣偵測裝置丨1〇,。此外，一左 集官41及一右集管42.分別架設於上集管6〇，、下集管2〇.之 間、並各位於中間集管40,之左右側。 本發明亦可以其他的特定形式來實施，而不脫離本發明 之精神和重要特性。因此上文所列之實施例在各方面都應 認為是例示性而非限制性，而所有之改變只要合乎申請專 利圍之意義和範圍或其等效者，均應包含在本發明的範 疇之内。 【圖式簡單說明】 140426.doc -21· 1374971 圖i係本發明脫硝級智慧型全功能柴油引擎廢氣處理系 統採水平對稱配置結構之一實施例。 圖2顯示圖1實施例之示意圖。 圖3係本發明脫硝級智慧型全功能柴油引擎廢氣處理系 統採垂直對稱配置結構之另一實施例。 【主要元件符號說明】 1，1' 脫硝級智慧型全功能柴油引擎廢氣處理 糸統 10，10' 中間聯絡管 20，20' 下集管 30，30' 氧化型觸媒除臭陣列 40，40' 中間集管 41 左集管 42' 右集管 50，50' 碳化矽除煙陣列 60，60' 上集管 70，70' 排氣主管 80，80' 消音器 90 » 90' 路徑選擇控制閥 100，100' 微電腦控制器 110，110' 排氣偵測裝置 120，120' 控制盤 130 UPS電源 140 緊急電源6. According to a preferred embodiment of the present invention, the catalyst array 15 is selectively reduced, and the exhaust gas is exhausted to the atmosphere. According to a preferred embodiment of the present invention, when the exhaust gas detecting device HO detects that the nitrogen oxides exceed 235 Ppm, the denitration-grade intelligent full-function diesel engine exhaust gas treatment system 1' activates the ammonia generating heater 162. The solid inorganic salt ammonia storage enthalpy (10) is appropriately heated to release high-purity money (Ammonia ΜΗ;) 'Ammonia gas quantitative control valve 161 is injected into the denitration-grade intelligent full-function diesel engine exhaust gas treatment system in an automatic quantitative manner. The selective reduction catalyst array 15〇' to treat the nitrogen oxides (Ν0χ), reduce it to gas 140426.doc gas and water, and then discharge into the atmosphere, the exhaust gas detection device 10, The exhaust gas data is transmitted to the microcomputer controller 100 for the microcomputer controller 100 to determine the degree of pollution, and then the denitration-grade intelligent full-function diesel engine exhaust gas treatment system 1 determines that the exhaust gas passes through the first exhaust gas treatment path A or The exhaust gas treatment path B is used for the purpose of purifying the exhaust gas. Fig. 2 is a schematic view showing the flow of the exhaust gas processing system 1 of the present invention for treating the exhaust gas of the engine. As shown in Figure i, after the engine exhaust gas is introduced into the intermediate communication pipe by the inlet end IL, the exhaust gas detecting device 110 transmits the exhaust gas data of the exhaust gas to the microcomputer controller 1 to determine the exhaust gas. The first exhaust gas treatment path eight or the second exhaust gas treatment path B should be introduced. If the exhaust gas is introduced into the first-exhaust gas treatment path eight, through the lower header 2, the core fossil de-smoke array 5G, the oxidizing catalyst deodorizing array 30, and the selective reduction j-media array 15 (the carbonized enthalpy removing array) Fantasy) U is connected to a regenerative heater (not shown) by a control panel 1201 and a: - Shangong Fengmiao Temple (not) when necessary, the stone is reversing and removing the smoke array. Oxidation-type catalyst deodorization k Selective reduction catalyst array 1 $ Q $ U5〇 and tantalum carbide de-smoke array 50 net 1 ! Over the header 60, discharged from the outlet end ol of the drainage main 70 by the drainage bm . The right exhaust gas is introduced into the second exhaust gas array to enter the oxidizing type catalyst. In addition, the twin reducing catalyst array 1 5 0 /• is silenced, the gas is read, and the rear control valve 90 can be installed. . Path selection JX Nong A A contact pipe 1 Healing ## Location, better, and the right to sell between the main officer 70 and between the silencer 8〇 and the row of chaos master 70 . Denitrification class «140426.doc Type 1374971:: The diesel engine exhaust system 1 will allow the microcomputer controller 100 to make an I* selection path. The path selection control valve 90 can also be between Fig. 2, the oxidizing catalyst deodorizing array 3, the selective reducing catalyst array 1%, and the muffler 80. In addition, the control panel 120 is preferably controlled by a UPS power supply (not powered) U〇 and an emergency power supply 140, and can be controlled by a micro-control device disposed in the control panel 120 to automatically select a power source type to avoid light wisdom. The full-featured Φ diesel engine exhaust gas treatment system 1 cannot be operated due to power jump. Fig. 3 is a view showing another embodiment of the technical idea of the present invention, which shows an implementation state of the vertical symmetrical arrangement structure. As shown in Figure 3, the denitrification-class intelligent full-featured diesel engine exhaust gas treatment system is roughly included. The component number is 1〇_ 2〇.,3〇',4〇,,5〇_,6〇', , an exhaust gas flow zone composed of components such as 7〇.., 8〇, 150, a microcomputer controller consisting of an ammonia gas storage supply zone composed of components such as 160, 1 61, 162, and a gas flow connection zone, The exhaust gas detection device between the ammonia storage supply area and the #microcomputer controller 1丨. Further, a left collector 41 and a right header 42 are respectively disposed between the upper header 6〇 and the lower header 2〇, and are located on the left and right sides of the intermediate header 40, respectively. The invention may be embodied in other specific forms without departing from the spirit and scope of the invention. The above-disclosed embodiments are to be considered in all respects as illustrative and not restrictive. Inside. [Simple description of the drawing] 140426.doc -21· 1374971 Fig. 1 is an embodiment of the horizontally symmetric arrangement structure of the denitration-grade intelligent full-function diesel engine exhaust gas treatment system of the present invention. Figure 2 shows a schematic view of the embodiment of Figure 1. Fig. 3 is another embodiment of the vertical symmetrical configuration of the denitration-grade intelligent full-function diesel engine exhaust gas treatment system of the present invention. [Main component symbol description] 1,1' Denitration-grade intelligent full-function diesel engine exhaust gas treatment system 10, 10' intermediate communication pipe 20, 20' lower header 30, 30' oxidation type catalyst deodorization array 40, 40' intermediate header 41 left header 42' right header 50, 50' carbonized carbide smoke removal array 60, 60' upper header 70, 70' exhaust main 80, 80' silencer 90 » 90' path selection control Valve 100, 100' microcomputer controller 110, 110' exhaust detection device 120, 120' control panel 130 UPS power supply 140 emergency power supply
140426.doc -22· 1374971 150，150， 選擇性還原觸媒陣列 160，160' 固態無機鹽類氨儲存器 161，16Γ 氨氣定量控制閥 162 ， 162' 氨氣產生加熱器 A 第一廢氣處理路徑 B 第二廢氣處理路徑 IL 入口端 OL 出口端 140426.doc •23·140426.doc -22· 1374971 150,150, selective reduction catalyst array 160,160' solid inorganic salt ammonia storage 161,16Γ ammonia gas quantitative control valve 162, 162' ammonia gas generation heater A first exhaust gas treatment Path B Second exhaust gas treatment path IL inlet end OL outlet end 140426.doc •23·