九'發明說明： 【發明所屬之技術領域】 #本發明係有關製造鞋子或鞋配件之新㈣熱塑性硬化材 貝，以及其製作上為環境方面適合的方法。 【先前技術】 鞋業用的使硬挺材質包括鞋頭和鞋跟，以及鞋内塾，側 邊強化物和鞋跟把，鞋跟框和鞋身的組合。其等已長時間 ^於摩絲款的製作方法中’絲形得以保持並使成鞋具 穿者穩n並且在鞋楦移除後具有所希的強度和回彈性。 餅製作期間通常利用熱和屋力(活化)將該等熱塑性硬化材 貝和表面材質(例如皮革)黏合，並且亦可能和内襯材質(例 如皮革或織品）黏合，使其得以和鞋楦合稱。 木材輛和白堊在此被視為是填料 德國專利案26 21 195 c說明了以扁平形式製作之硬化材 '、、’〃等於t作時塗覆有—種粉末狀，可熔融合成物 名外包含有填料的支^炫融材質尤其為聚乙 、’乙稀和乙酸乙稀醋或乙酸甲醋的共聚物。該發明的基 人為要如何找到可以增加包含粉狀可炫融合成物之混 填料的含量，而又能夠同時保有該物料適當強 :r此難題的解決之道奠基於以可炫融塑膠粉末含 ’ 、準A料的里可增加高達以體積計之⑽％，此乃當 種成份之粒子大小的分佈為可比較情況時。屆時，該 =7粉末會將各別的填料粒子完全包覆，並且此等填 般“：顯現塑料的性質’也就是說其行為如同塑料- 96714.doc 適4熱塑性的平坦構造在加工處理溫度下並不具有 保：；占合力，因而在其表面上必需有一熱熔塗層，以確 σ鞋轅要件的結合力持久。 立：：：利案183 192 Β2中說明-種適合於使鞋硬挺並可 或：:、二：材質。此種材質的特性為使用情性填料，完全 成。i可炫 H上 Γ混合有一可炼融黏合劑的合成物所組 之相對R σ 1例如可為聚己内@旨，由於其具有約6(rc 父低的熔點，因而為特別適當者。 4=二黏合劑相對填料的比例為7°到 。劑# 30到80重量％的 到500微米。 真枓令拉子大小的分佈為50 【發明内容】 本發明中，填料為不溶 ㈣化範圍則性合成材 == 之黏 當的材質為…，同；::為子二者。達此目的之尤其適 者，佶彳曰詉人才丨 …子大小的分佈必需為可並立 聚胺基甲填料的現合物得以充分地黏附。兹列舉 為改質的聚乙烯乙酸乙稀酯為黏合劑。 需使用，物料。這些二：=度，通常必 防黏紙。這些支樓材質在製；=:為不織布，織品或 化材質而言，無需添加任何額必需的。對此等硬 ::為經適當選擇時，以總塗層量為基準，== 重量0/。的填料粉末。這歧舍 』便用间達80 狀態下仍具有和,,完整、硬化材質在被削薄或剖開 又相同的點合和熱塑變形的特 967I4.doc 叫y72 性。本文所述熱熔黏合.劑在5〇到8〇〇c溫度範圍中會被軟 化，並可藉由其於表面上的黏附力和填料粒子結合。製鞋 用的強化材質亦說明於―些專利案件中。兹列舉以下公開 文件為例，不作進一步的評價，因為其等和本發明標的為 無關··申請人為英國Texon公司的w〇〇〇/41585幻和申請人 為英國Texon公司的w〇 00/53416。 根據歐洲專利183 192，這些使硬挺元素在製鞋方面的一 種較佳應用方法為將該使硬挺部件預熱，並結合其以手工 方式被適當定位於鞋轅之前和後續熱壓和/或冷壓使其變 及同步黏合之黏合劑的熱塑軟化和熔化的步驟。該預熱 或」舌化作用的進行係透過輻射或接觸熱；對熱狀態操作 而為了達到充足的機械安定性和可控制的表面黏附 性，這些蓋品皆提供-種織品支樓物，或是其表面的兩側 皆覆蓋有網眼開口式的織物，編織型的織品，不織布等等。 由於這樣的設計，對此合理的手法而言，吾人可獲得充足 的機械安定性，連同受到控制之下降的表面㈣力·加愿 下製以過知中，該黏合物會迫使通過織品的表面覆蓋物。 此種情況的一個重大缺失為織物的高成本，更重要地是織 物部份所導致無法回收利用的缺點。 必需一提地是，構成要件在從薄板衝壓和剖開(削邊)過 程中所產生，，廢料，，的量可能多達初始物料重量的30%。 熱狀態令，50-1〇〇。〇的加工.、田痒γ — /皿度範圍中伴隨小的黏性/黏 著力及優良内聚力和安定性 疋性下鞋轅之良好黏著性和以手 工定位於適當位置的需求i乞人 而水&今仍不易協調出，其要求一種 96714.doc 如上所述包含繃 °σ和塗層的多層結構，導致一合用的使硬 挺材質。此箱u , 表去的缺點為成本過高以及缺乏回收利用的 可能性。 本發明目的為找到-種適合所有製造方法用的熱熔黏合 劑/填料化合物’其同時全部符合上列參數值，無需使用多 層、’·。構，並且製造所產生像是衝壓留下的殘骸及剖開的斷 片可被100%的回收使用。 【實施方式】 本毛明之另一目的為選出包含天然形成之填料（好比木 頭木材杈，軟木產品以及例如白堊，高嶺土等惰性無機 填料），達使用者所需具最佳強度和黏著力/黏性的熱塑性聚 合物。 令人驚訝地是，頃發現滿足上述需求之熱塑性硬化材質 為一熱熔黏合劑/填料化合物，包含 1. 或右干種的熱熔黏合劑，含量為5〇到95重量❶/。，其]^17尺 值（i〇〇°c下測量，根據DIN IS0 1133為216公斤）為每ι〇 分鐘2到300立方公分，較佳為每1〇到2〇立方公分 2. -或若干種的填料，含量為测5重量％，其不溶於熱溶 黏合劑中， 並且該熱熔黏合劑/填料化合物同時滿足以下的參數值： 1. MFR值介於每10分鐘2立方公分和6立方公分之間，較佳 為3到5立方公分 2. 65°C下，根據DIN EN 14510測量之表面黏著力/黏性為至 少ion，最高可達60N，較佳為15N，尤佳為3〇1^， 96714.doc 1332972 3. 參考DIN 53 357測量，.相斟矣石t 44·餅 子表面材貝和襯裡的黏合值（抗 剝離力）為至少3〇 N/5公分， 4. 最大25%的長度伸長量，較佳為低於2〇%，係於9代下， 一受熱櫥中存放5分鐘後測量者。 根據本發明’為熱熔黏合劑/填料化合物形態之製鞋用轨 塑性硬化材質的具體特徵為組份a，該熱炫黏合劑，係由以 、下成份組成的混合物 1. 含量為75到95重量％的線形聚醋和/或含量為75到95重量 %的熱塑性聚胺基甲酸乙酯，以及 2. 結合有含量為〇·25重量％之乙烯·乙酸乙烯g|的共聚物， 其乙酸乙稀酿的量為10到40重量％ ’較佳為25到3〇重量 %，而填料係選自由無機，礦物填料，有機-蔬菜填料， 合成物料及其混合物組成的群組，為球形，粒子大小分 佈為ΚΜ000微米，較佳為45_5〇〇微米的多邊粒子，或為 纖維態者，其長度為45_1000微米，較佳為45 5〇〇微米。 填料較佳為粒子大小的分佈為45_5〇〇微米的木材粉。然 而，填料也可以是白堊，特別是工業用粒子大小分佈為 10-45微米的白堊或是一種合成物料，例如粒子大小分佈 為45-500微米的聚對苯二甲酸乙二醇酯（pet)。 65°C下，根據DINEN 14yi〇所測f寻熱熔黏合劑/填料化合 物的表面黏性值為至少10 N，最高為60 n，較佳為15 N， 特別是30 N。超過60 N的黏性值可使材質的手感性大幅下 降。 90°C下，一受熱櫥中，測量代表活化狀態下材質安定性 96714.doc ⑶2972 的長度伸長量。寬2公分長ι0公分以及厚〇 95毫米的懸吊 /則试薄片在接觸熱達5分鐘後從櫥櫃中移出，並測量長度上 的改支。以原始標記於樣品上的長度（8公分）為準，以％表 示其變量。 度下，具有2〇%之最大長度延伸量的熱溶黏合劑/ 填料化合物為最適當的材質，但書為需滿足請求項丨之所有 其他的參數。 為熱熔黏合劑/填料化合物形態之生產製鞋用熱塑性硬化 材質之適當方法的特徵在於，該熱熔黏合劑係於最高22〇艽 的溫度下被熔化，並且填料在攪拌或揉捏之同時，藉助一 计量裝置被導入該熱熔煉爐中，同時利用一除氣裝置將水 份和釋出的氣體排出，以此方式獲得之具黏性的質量作真 空除氣的處理。 以此方式處理的黏性質量可根據所有熱塑處理的已知技 術作進一步的加工處理，以製得使鞋硬挺的部件。 表1中列舉本發明適用之熱熔黏合劑/填料化合物的混合 物。測量值顯示該等化合物作為使鞋硬挺材質的安定性。β 配方 90°C+5"冷 壓對微纖 維質人造 皮革的黏 著活化度 [N/5公分] 長度的變量 [%] (熱安定性） 表1 100°C，21.6 公斤下的 MFR值 /黏度/ [立方公分 /10分鐘] 接合點斷 裂的主要 類型 材質的適 當性 直徑為考 公分之' 圓形樣 品的黏 性[N]Nine' invention description: [Technical field to which the invention pertains] # The present invention relates to a new (four) thermoplastic hardened material for the manufacture of shoes or shoe accessories, and a method suitable for environmentally friendly production thereof. [Prior Art] The stiffening material for the footwear industry includes a toe and a heel, and a combination of a shoe upper, a side reinforcement and a heel handle, a heel frame and a shoe body. It has been for a long time. In the manufacturing method of the mousse, the wire shape is maintained and the wearer is stabilized and has the strength and resilience after the shoe last is removed. During the making of the cake, the thermoplastic hardened material shells and the surface material (for example, leather) are usually bonded by heat and house strength (activation), and may also be bonded to the lining material (for example, leather or fabric) to make it fit with the shoe. Said. Wood and chalk are considered to be fillers. German Patent No. 26 21 195 c describes a hardened material made in a flat form, ', '〃 is equal to t when coated with a powder, and the name of the meltable composite is outsourced. The material containing the filler is especially a copolymer of polyethylene, 'ethylene and ethyl acetate or methyl acetate. The basic person of the invention is how to find the content of the mixed filler which can be added to the powdery condensable fusion product, and at the same time, the material can be kept at the same time: r The solution to this problem is based on the inclusion of the fused plastic powder. ', the amount of quasi-A material can be increased by up to (10)% by volume, which is when the particle size distribution of the ingredients is comparable. At that time, the =7 powder will completely coat the individual filler particles, and these fill-in ": the properties of the plastic" means that it behaves like a plastic - 96714.doc 4 thermoplastic flat structure at processing temperature There is no guarantee: occupies force, so there must be a hot melt coating on the surface to ensure that the bonding strength of the 辕 shoe lasting member is durable. Li::: 183 192 Β 2 Description - suitable for making shoes Stiff and can be::, 2: material. The characteristics of this material is the use of erotic filler, complete. i can H H mixed with a smelting adhesive composition of the relative R σ 1 for example It is especially suitable because it has a melting point of about 6 (rc father low. 4 = ratio of two binders to filler is 7° to. Agent # 30 to 80% by weight to 500 μm The distribution of the size of the true scorpion is 50. [Invention] In the present invention, the filler is insoluble (four), and the material of the synthetic material == is made of..., the same; The purpose is especially suitable, the talents are... the distribution of sub-sizes is necessary The present compound which can be used as a parallelizable polyurethane filler is fully adhered. It is listed as a modified polyethylene vinyl acetate as a binder. It is required to use materials. These two: = degree, usually must be prevented from sticking paper. These branches are made of materials; =: for non-woven fabrics, fabrics or materials, no need to add any necessary amount. For these:: When properly selected, based on the total coating amount, == weight 0 Filler powder. This is a 967I4.doc that is still and has a hardened material that is thinned or split and the same point and thermoplastic deformation is called y72. The hot-melt adhesive described in this paper will be softened in the temperature range of 5 〇 to 8 〇〇c, and can be combined with the filler particles by the adhesion on the surface. The reinforced material for shoes is also stated in ― In the case of some patents, the following public documents are listed as examples, and no further evaluation is made because they are not related to the subject matter of the invention. The applicant is W〇〇〇/41585 of the British Texon Company and the applicant is the Texon Company of the United Kingdom. 〇00/53416. According to European Patent 183 192, these A preferred application of the stiffening element in the manufacture of shoes is to preheat the stiffening member and combine it to be properly positioned in front of the last by hand and subsequent hot pressing and/or cold pressing to cause it to be synchronously bonded. The step of thermoplastic softening and melting of the adhesive. The preheating or "tongue" is carried out by radiation or contact heat; for thermal operation, in order to achieve sufficient mechanical stability and controllable surface adhesion, the covers All kinds of fabrics are provided with fabrics, or the sides of the surface are covered with mesh-open fabrics, woven fabrics, non-woven fabrics, etc. Due to this design, for this reasonable approach, we Sufficient mechanical stability can be obtained, along with a controlled surface (4) force, which is known to force the surface covering through the fabric. A major deficiency in this situation is the high cost of the fabric and, more importantly, the disadvantages of the fabric portion that cannot be recycled. It must be noted that the constituent elements are produced during the stamping and slitting (cutting) of the sheet, and the amount of waste may be as much as 30% of the weight of the initial material. The thermal state is ordered, 50-1〇〇.加工 processing, 田 γ γ — / with a small viscosity / adhesion in the range of the degree of good adhesion and good cohesiveness and stability, the good adhesion of the last and the need to manually position in the appropriate position Water & is still not easily harmonized today, which requires a multi-layer structure containing a sigma and a coating as described above, resulting in a combination of stiffening materials. The disadvantages of this box u are that the cost is too high and the possibility of recycling is lacking. SUMMARY OF THE INVENTION The object of the present invention is to find a hot-melt adhesive/filler compound which is suitable for all production methods, which all comply with the above listed values, without the use of multiple layers. The structure, and the resulting fragments, such as those left by stamping and cut-away fragments, can be recycled 100%. [Embodiment] Another purpose of the present invention is to select natural fillers (such as wood rafts, cork products, and inert inorganic fillers such as chalk, kaolin, etc.) to achieve the best strength and adhesion/adhesion for users. Sexual thermoplastic polymer. Surprisingly, it has been found that the thermoplastic hardening material meeting the above requirements is a hot melt adhesive/filler compound comprising a hot melt adhesive of 1. or right dry, in an amount of from 5 to 95 weight percent. , its ^17 ft. value (measured at i〇〇 °c, 216 kg according to DIN IS0 1133) is 2 to 300 cubic centimeters per 〇 ,, preferably every 1 〇 to 2 〇 cm ^ 2. - or Several kinds of fillers, the content is 5% by weight, which is insoluble in the hot-melt adhesive, and the hot-melt adhesive/filler compound simultaneously satisfies the following parameter values: 1. The MFR value is between 2 cubic centimeters per 10 minutes and Between 6 cubic centimeters, preferably 3 to 5 cubic centimeters 2. At 65 ° C, the surface adhesion/viscosity measured according to DIN EN 14510 is at least ion, up to 60 N, preferably 15 N, especially preferably 3〇1^, 96714.doc 1332972 3. Measured according to DIN 53 357, the phase of the stone and the lining of the cake (the peel resistance) is at least 3〇N/5 cm. The maximum elongation of 25%, preferably less than 2%, is measured under the 9th generation and stored in a hot cabinet for 5 minutes. According to the present invention, the specific feature of the rail plastic hardening material for the form of a hot-melt adhesive/filler compound is component a, which is a mixture of the following components: a content of 75 to 95% by weight of a linear polyester and/or a thermoplastic polyurethane having a content of 75 to 95% by weight, and 2. a copolymer having a content of 〇·25% by weight of ethylene·vinyl acetate g| The amount of ethyl acetate is from 10 to 40% by weight 'preferably from 25 to 3% by weight, and the filler is selected from the group consisting of inorganic, mineral fillers, organic-vegetable fillers, synthetic materials and mixtures thereof, which are spherical. The particles having a particle size distribution of ΚΜ000 μm, preferably 45 Å to 5 μm, or a fiber state, have a length of 45 to 1000 μm, preferably 45 5 μm. The filler is preferably a wood powder having a particle size distribution of 45 mm to 5 μm. However, the filler may also be chalk, especially for industrial grades having a particle size distribution of 10-45 microns or a synthetic material such as polyethylene terephthalate (pet) having a particle size distribution of 45-500 microns. . The surface viscosities of the hot-melt adhesive/filler compound according to DIN EN 14 〇 measured at 65 ° C are at least 10 N, up to 60 n, preferably 15 N, especially 30 N. A viscosity value of more than 60 N can greatly reduce the feel of the material. At 90 ° C, in a heated cabinet, the measured elongation of the material in the activated state is 96714.doc (3) 2972. The width of 2 cm long and ι0 cm and the thickness of the 95 mm suspension / test sheet were removed from the cabinet after 5 minutes of contact heat, and the length of the change was measured. The length of the original mark on the sample (8 cm) is taken as the standard, and its variable is expressed in %. The hot-melt adhesive/filler compound having a maximum length extension of 2% is the most suitable material, but the book is all other parameters that satisfy the requirements. A suitable method for producing a thermoplastic hardening material for shoes in the form of a hot-melt adhesive/filler compound is characterized in that the hot-melt adhesive is melted at a temperature of up to 22 Torr and the filler is stirred or kneaded. And the metering device is introduced into the hot melting furnace, and at the same time, the moisture and the released gas are discharged by using a degassing device, and the viscous mass obtained in this manner is used for vacuum degassing. The viscous mass treated in this manner can be further processed in accordance with all known techniques of thermoplastic processing to produce a component that stiffens the shoe. Table 1 lists the mixtures of hot melt adhesives/filler compounds to which the present invention is applicable. The measured values show the stability of these compounds as a stiffening material for the shoe. β Formula 90°C+5"Adhesion activation of microfiber-based artificial leather [N/5 cm] Length variable [%] (thermal stability) Table 1 MFR value at 100 ° C, 21.6 kg / Viscosity / [cubic centimeters / 10 minutes] The main type of joint breakage The appropriate diameter of the material is the centimeter's 'sticky viscosity' [N]
96714.doc96,714.doc
表格中所用縮寫的意義如下： η·η·(1) _無法檢驗，因為該材質太不安定，不可能將其預 活化’例如將其作熱加工處理 η.η·(2) _由於織品的内含物而無法測量 n-g· -未經測量 不元全的接合’黏著分界線（即兩種材質間，化合 物和表面材質）上有材質分離的現象 CF _内聚力破壞，意指化合物之内有分離的現象 配方1-14包含下列組份： 1·平均分子量為每莫耳80.000克之70重量％的聚⑻己内 酯和30重量％之粒子大小分佈為5〇_5〇〇微米的木材粉 或纖維（Pinus pinea)。 2.平均分子量為每莫耳8〇·〇〇〇克之8〇重量％的聚⑷己内 醋和20重量％之粒子大小分佈為】5()_5⑽微米的木材粉 或纖維（Pinus pinea)。 3. 平均分子量為每莫耳_〇克之7〇重量％的聚⑻己内 酯和30重量％之粒子大小分佈為15()_別微米的木材粉 或纖維（Pinus pinea)。 4. 平均分子量為每莫耳80·_克之6〇重量％的聚⑻己内 96714.doc 1332972 酯和40重量％之粒子大小分佈為15〇_5〇〇微米的木材粉 或纖維（Pinus pinea)。 5.平均分子量為每莫耳80·000克之65重量％的聚（ε)己内 酯，5重量％的乙烯乙酸乙烯酯和3〇重量％之粒子大小分 佈為150-500微米的木材粉或纖維。 6_ MFR值為每10分鐘2〇到35立方公分（係於19(Γ(：下測量 並且負載為10公斤）之7 〇重量％的熱塑性聚胺基甲酸乙 酯和30重量％之粒子大小分佈為15〇5〇〇微米的木材粉 或纖維。 7·平均分子量為每莫耳8〇.〇〇〇克之7〇重量％的聚（ε)己内 酯和30重量％市售來自〇mya&司之平均粒子大小為45 微米的工業用白垒。 8. 平均分子量為每莫耳80.000克之7〇重量％的聚（句己内 酯和30重量％粒子大小分佈為5〇 5〇〇微米之作為填料 的研磨聚對苯二甲酸乙二醇酯（ΡΕτ)。 9. MFR值為每1〇分鐘2〇到35立方公分（係於190〇c下測量 並且負載為10公斤）的熱塑性聚胺基曱酸乙酯。 10·平均分子量為每莫耳80.000克的聚（句己内酯。 11. 平均分子量為每莫耳40.〇〇〇克的聚0)己内酯。 12. 乙酸乙烯酯含量為28重量％的乙烯乙酸乙烯酯，其]^^ 值為每10分鐘15〇克，係於19〇。(：/2· 16公斤下測量者。 13. 根據德國專利26 21 195 C的物料。 14. 根據歐洲專利1 83 1 92 C 1，實例2的物料。 結果之總結： 96714.doc -12- 1332972 古適合本發明之物料1,3,5和8具吸引力，因為其滿足所 種標準所希的數據，其等位於所謂的"產品視窗” t 然而就純原料卜^丨和⑴以及根據歐洲專利⑻⑼ 和德國專利26 21 195之物料13和14而言，至少_個標準有 偏差，無支擇而為不堪使用者，因此落在產品視窗之外。 表1進-步顯示，合成物料也是在有條件情況下適 =料者，但由於平滑表面之故，而具有非常低的 製造方法 平均分子量為每莫耳80._克的熱熔黏合劑聚⑷己内醋 於約18(TC的溫度下熔化。攪拌和揉捏之同時，利用一呀旦 裝置，將量為5-30%，粒子大小分佈為i5〇_5〇〇微米的填料里 木材粉/纖維的混合物加入該熱熔煉物令，並用一除氣裝置 將水份和散出的氣體排除。獲得一黏質體，其於真空下被 進一步地除氣。最後，將依此方式處理的黏質體導入一多 層的滚動架中，其中該滚動架各別層的溫度為一遞減形式 者，始於，止於201滾動架令，該黏質體會滚平， 並且冷卻後其會以薄片材的形式從滾動架中移除。依此方 式獲得之平的薄片材可以慣用的方式，利用衝壓和剖開的 技術作進-步的加工處$，以形成鞋用的部件（鞋身/鞋 跟）。收集衝壓和剖開過程產生的廢料，並且廢料在粗分裂 (刹碎）後可被再次導入該製程中，或可作為粉末技術中之粉 末態的原料使用，以供製造硬化材質之用。 然而，該熱熔黏合劑/填料化合物也可是顆粒狀者，並且 該粒狀物再次被溶化後可進一步以擠製的方式加工，或是 967I4.doc • 13 1332972 該粒狀物再次被熔化後可進一步以擠製的 輾滾成扁平的箔狀物。 或是 製造根據本發明之熱熔黏合劑/填料化合物的另—適杏 方法為注模的技術，可制該技術製造為注射模製部= 態之使硬挺的部件。 也可以將根據本發明之熱熔黏合劑/填料化合物磨成細 微的粉末，其粒子大小分佈為5〇_1〇〇〇微米，並且可用來製 知·使硬挺的#件。再者，可使用該熱熔黏合劑/填料化合 物，根據已知的粉末加工技術製造立體的使硬挺的部件。 使用該熱溶黏合劑/填料化合物或是根據各種不同方法 製作之硬挺材質或使硬挺部件製成的鞋子具有特別令人滿 意的合穿性。 96714.docThe meaning of the abbreviations used in the table is as follows: η·η·(1) _ can not be tested, because the material is too unstable, it is impossible to pre-activate it 'for example, it is processed by heat processing η.η·(2) _ due to fabric Inclusions cannot be measured ng· - unmeasured joints 'adhesive boundaries (ie between two materials, compounds and surface materials) are separated by material CF _ cohesive force destruction, meaning within the compound Formulations with separation 1-14 contain the following components: 1) 70% by weight of poly(8) caprolactone per mole of 80.000 grams of mol and 30% by weight of wood having a particle size distribution of 5〇_5〇〇 microns Powder or fiber (Pinus pinea). 2. The average molecular weight is 8% by weight of poly(4) hexyl vinegar per mole of 〇 〇〇〇 〇〇〇 and 20% by weight of wood powder or fiber (Pinus pinea) having a particle size distribution of 5 () _ 5 (10) μm. 3. The average molecular weight is 7% by weight of poly(8) caprolactone per mole and 30% by weight of wood powder or fiber (Pinus pinea) having a particle size distribution of 15 (). 4. The average molecular weight is 6 〇g of 8% by weight of poly(8) hexene 96714.doc 1332972 ester and 40% by weight of wood powder or fiber having a particle size distribution of 15 〇 5 〇〇 micron (Pinus pinea ). 5. The average molecular weight is 65% by weight of poly(ε) caprolactone per mol of 80.000 grams, 5% by weight of ethylene vinyl acetate and 3% by weight of wood powder having a particle size distribution of 150-500 microns or fiber. 6_ MFR value is 2〇 to 35cm3 every 10 minutes (7% by weight of thermoplastic polyurethane and 19% by weight particle size distribution at 19(Γ(: measured and load 10kg)) It is a 15 〇 5 〇〇 micron wood powder or fiber. 7. The average molecular weight is 8 〇 per gram of gram. 7 〇 % by weight of poly(ε) caprolactone and 30% by weight commercially available from 〇mya& The average particle size of the industrial white barrier is 45 micrometers. 8. The average molecular weight is 80.000 grams per mole of arsenic lactone and 30% by weight of the particle size distribution is 5 〇 5 〇〇 micron. Ground polyethylene terephthalate (ΡΕτ) as a filler. 9. MFR value is 2 to 35 cubic centimeters per 1 minute (measured at 190 °c and loaded with 10 kg) of thermoplastic polyamine Ethyl phthalate 10. The average molecular weight is 80.000 g per mole of poly(sodium caprolactone. 11. The average molecular weight is 40. gram of poly 0) caprolactone. Ethylene vinyl acetate having an ester content of 28% by weight, which has a value of 15 g per 10 minutes and is at 19 〇. (:/2· 13. Measured under 16 kg. 13. Material according to German patent 26 21 195 C. 14. Material according to European Patent 1 83 1 92 C 1, Example 2. Summary of results: 96714.doc -12- 1332972 Ancient suitable for the present invention The materials 1, 3, 5 and 8 are attractive because they meet the data of the standard, which are located in the so-called "product window" t. However, the pure raw materials are (1) and according to the European patent (8) (9) and For materials 13 and 14 of German Patent No. 26 21 195, at least _ standards have deviations, no choice and are unacceptable to users, so they fall outside the product window. Table 1 shows in step-by-step, synthetic materials are also in condition In the case of suitable materials, but because of the smooth surface, and has a very low manufacturing method, the average molecular weight is 80._ grams of hot melt adhesive poly (4) caprolactone melted at about 18 (TC temperature) While stirring and kneading, a mixture of wood powder/fiber in a filler having a particle size distribution of i5 〇 _5 〇〇 micron is added to the hot smelting material by using a one-to-one device, and the amount is 5-30%. A degassing device removes moisture and dissolved gases. a viscous body which is further degassed under vacuum. Finally, the viscous body treated in this manner is introduced into a multi-layered rolling frame, wherein the temperature of each layer of the rolling frame is a decreasing form Starting at stop 201, the viscous body will be flattened, and after cooling, it will be removed from the rolling frame in the form of a sheet. The flat sheet obtained in this way can be used in a conventional manner. The stamping and splitting technique is used to advance the processing section to form the shoe component (shoe/heel). The waste generated by the stamping and dissection process is collected, and the scrap can be re-introduced into the process after coarse splitting (brake breaking), or can be used as a raw material in the powder state for the production of hardened materials. However, the hot melt adhesive/filler compound may also be granulated, and the granules may be further melted and then processed in an extruded manner, or 967I4.doc • 13 1332972. The extruded crucible can be further rolled into a flat foil. Alternatively, another method of making the hot-melt adhesive/filler compound according to the present invention is injection molding, which can be made into a molded part of the injection molding section. It is also possible to pulverize the hot-melt adhesive/filler compound according to the present invention into a fine powder having a particle size distribution of 5 〇 1 〇〇〇 μm and which can be used to make and make a stiff piece. Further, the hot melt adhesive/filler compound can be used to produce a three-dimensional stiffened component in accordance with known powder processing techniques. The use of the hot-melt adhesive/filler compound or a stiff material made according to various methods or a shoe made of a stiff component has a particularly satisfactory fit. 96,714.doc