TWI270532B - Method for antioxidation and antioxidative functional water - Google Patents

Abstract

A method for antioxidation comprises accelerating a reaction which decomposes molecular hydrogen contained in a dissolved hydrogen-containing water as a substrate into active hydrogen as a product through a process of reacting the dissolved hydrogen-containing water with a catalyst, to thereby convert a material in an oxidized state due to the deficiency of electrons to that in a reduced state having sufficient electrons and/or maintain a material to be prevented from being oxidized in a reduced state.

Description

1270532

V. INSTRUCTION DESCRIPTION OF THE INVENTION (1) Technical Field of the Invention The present invention relates to an anti-bombing method, an Af^m machine emulsification method, and an antioxidant function water, which is a process in a human tβf in water, which is promoted by Hydrogen storage i: 乍 is the matrix formation product active hydrogen decomposition reverse: 2 1 ! t caused by the oxidation state or anti-emulsification object to prevent oxidation can be reduced to a sufficient state of electrons. [Prior Art] ~

^ In terms of living body, oxygen is a sword with a double knife. Oxygen is used for the purpose of oxidizing the eutrophication to obtain energy, or for various oxygen addition reactions to the living body, but on the one hand, it is accompanied by various tissue disorders caused by its oxidizing power. Risky and accused. In particular, in the active oxygen called peroxide produced by metabolism, it is reduced to hydrogen peroxide by the action of a metal catalyst such as iron or copper, and it is a step-form, highly reactive hydroxyl radical, which is known to cause protein. Denatured 'degenerates the deoxyribonucleic acid strand, or oxidizes the lipid to form a peroxidized lipid as an aging. The active oxygen with such toxicity is usually removed in the living body by an enzyme called SOD (Superoxide Dismutase). But as for stress or drinking, smoking, strenuous exercise, aging, etc.

The factors that cause the body to lose balance, the shellfish S0D will decrease, causing the increase of lipid peroxide caused by reactive oxygen species, causing myocardial infarction, arteriosclerosis, diabetes, cancer, stroke, cataract, shoulder stagnation, cold , high blood pressure and Alzheimer's disease and other diseases, or the occurrence of age spots, freckles, wrinkles and other issues

1270532

Knowing that the right kind of various kinds of diseases caused by active oxygen have been used, μα (butyl methoxy methoxy benzoate (tetra) Η Β 二 (di-tert-butyl phenyl-toluene dibutyi t〇i_e) e) Eliminate antioxidants such as ascorbic acid, cysteine, and glutathione or active oxygen ft in I ^ Ξ oxidizing agents for chemical synthesis & when used in a large amount: = concerns about sexual problems. Moreover, these antioxidants have concerns about the safety of the compound to the human body. Chenghua Therefore, it is expected to develop an innovative technology that can perform the same or better antioxidant energy or eliminate the activity of the previous antioxidants, and is a high level of safety for human body. On the other hand, environmental problems at the scale of the earth have been put on the table in recent years as a result of emissions from the global environment such as industrial waste, medical waste or industrial drainage. For example, in the manufacturing process of industrial products or pharmaceutical products, when washing, etching, post-treatment, etc., chlorine or the like, a solution containing CFC, an acidic solution such as hydrochloric acid or an alkali solution, or a letter containing Or a gas containing fluorine gasified carbon for treatment. Specifically, for example, in the semiconductor substrate, particularly in the field of cleaning the ruthenium substrate, pure water or pure water and hydrochloric acid, hydrofluoric acid, sulfuric acid, nitric acid, hydrogen peroxide, ammonium water, organic alkali, etc. are used. The mixed solution was examined to perform surface treatment of the tantalum substrate. However, when such a chemical solution is used for washing or the like, a chemical compound or a fluorine-vaporized carbon compound is produced, and industrial waste which is difficult to handle is generated, and

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V. INSTRUCTIONS (3) The problem of increasing the load of industrial wastes that are difficult to handle. Therefore, it is expected that a leather can be developed which is equivalent to the use of the prior chemical treatment or because of the high level of use without using the liquid or even the amount of use. The present invention is a method for solving the problem and an antioxidant water function, which is a process in which water is formed in a state in which the hydrogen is dissolved in the hydrogen to form a product, and the active hydrogen is decomposed, and the oxidation state or the anti-oxidation is prevented. This can be expected to achieve a high level of reduction. DISCLOSURE OF THE INVENTION DISCLOSURE OF THE INVENTION Before the outline of the present invention, the latitude and longitude will be explained. (1) Thoughts of the present invention The applicant of the present invention has previously stated that the green material cited in the present application is a summary of the electrical application that can be independently controlled by the re-specialized ion index (hereinafter referred to as "pH") and oxygen "ORP". As shown below. A ready-made device that has a new environmental technology as a result of the introduction of raw water into the earth's environment, is capable of maintaining a better cleaning effect, and reduces the amplitude to reduce the environmental load. Oxygen permeation causes the catalyst to act on the molecular hydrogen contained in the hydrogen-dissolved water as a basis, and the safety of the oxidized object due to the lack of electrons can be reduced to the safety of the electron-filled human body or the environmental load is low. The content of the description is taken from WO99/1 0286, and the hydrogenation reduction potential (hereinafter referred to as the decantation and electrolyzed water generating device) is described. The electrolysis cell and the reduction potential hydrogenic chamber, the electrolysis chamber and the electricity described above are disclosed.

1270532 V. INSTRUCTIONS (4) At least one pair of electrode plates in the outdoor diaphragm (the knife is opened and attached), and the above-mentioned electric plate is placed, and the A-electrode plate is in contact with the above-mentioned barrier or through a small gap. An electrode plate provided in the Li chamber is used as a cathode, and the power supply circuit is applied between the two electrodes in the same manner as the anode. The electrolytic value of the 〇 RP value is greatly reduced, but it will change a lot, but it can generate water. Hereinafter, the heart LUi may be referred to as "the reduction electric fixed standing water generating device performs continuous water-passing electrolytic treatment at a flow rate of 1 liter per minute at a flow rate of 5 A. The m month if the raw surface is passed through the above-described reduced potential water generating device The present invention was invented by performing performance evaluation on the generated reduction water. The nH two p5 "alloy potential water system" represents a negative value of 0RP and corresponds to a predetermined value. Whether the 0RP value exceeds the predetermined value is judged by the following Nylenster type (approximation). 〇RP = - 59pH - 80(mV)···(Nylenster type). As shown, it shows that pH_RP has a proportional relationship (the more the pH is, the more negative the heart is attached). Therefore, the value corresponding to the pHuRp value exceeding the predetermined value means that the value of 0RP is smaller than the value corresponding to the above-described Nilestran formula. The water that satisfies this condition is called reduction potential water. If pH 7 is substituted into the above-mentioned Nylonite type, the 0RP is about -493 (mV). That is, at pH 7, water having a 〇Rp of about -493 (mV) or less corresponds to a reduction potential water. However, there is still a slight difference in the concentration of dissolved hydrogen in the water within the range of the original potential water as defined herein. For this point, the quantitative analysis method of the dissolved hydrogen concentration will be described in detail later.

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First, the reduction potential water contains a considerable amount of high-energy electrons. This can be known by measuring 〇Rp. 0RP is an index indicating the ratio of the presence of the vaporized substance and the reducing substance contained in the liquid to be measured, and the unit is generally (mV). In general, the 0RP meter will observe a negative 0RP value if the electrode used for the measurement is negatively charged. If the electrode used for the measurement is positively charged, a positive 0RP value will be observed. In order to negatively charge the electrode for measurement, it is necessary to contain high-energy electrons in the liquid to be measured. Therefore, if the 0RP value exhibits a negative large absolute value, it is inevitable that the liquid to be measured contains electrons having high energy. Here, in order to evaluate how much high-energy electrons are contained in the reduction potential water, a lighting test is performed using a light-emitting diode (hereinafter, abbreviated as "LED"). This is the principle of using the battery. Specifically, in the test chamber 2〇9 in which the electrodes 201 and the separators 2G3, & each having three cathode chambers and the anode chamber 207 are alternately connected, the 〇Rp is separately input in the cathode chamber. The reduction potential water of about 60 0 (mV), the tap water of about (10)p is +400UV) is placed in the anode chamber, and the electrode contacting the cathode chamber 2〇5 is connected to the anode side terminal of the LED 21 1 and the anode chamber. Connect the positive side terminal of led2i丨 and observe the continuous lighting state of LED211. This means that through the LED 211, a current flows from the anode of the chamber 2〇9 to the cathode, and further, the flow of current means that electrons are flowing. At this time, if it is considered that the cathode flowing from the cavity to the cathode of 2 〇9 flows toward the anode, the fact that the reduction potential water does contain an electron group having a high energy can be experimentally determined as a reference example in the above cavity. In the chamber 20 9 , the market was again entered in the cathode chamber. The electrolyzed water produced by the electrolyzed water generating device (for example, 〇R p 1270532 V, invention description (6) is about -50 mV) or natural mineral water, etc., the anode chamber is separately charged from water, and the cathode is the same as above. The negative side of the LED is connected to the electrode of the chamber, and the positive side terminal of the LED is connected to the anode chamber, and no UD lighting is observed. This can be considered to be due to the presence of high-energy electrons in the alkaline electrolyzed water or natural mineral water that can cause LED xenon lamps. Further, in the commercially available electrolyzed water generating apparatus, although the flow rate is concentrated to shift the 0RP value in a negative direction, the absolute value of the QRP value at the pH value of the above-mentioned Nilunsi type factory becomes smaller, Still can't observe the LED lighting, such as 'in the commercially available electrolyzed water generating device, the result of increasing the flow rate, even if the left and right sputum RP value is _500 to 600 (mV), but after subtracting the pH value: ' Λ If the electron energy is weak, it can be thought of as the above-mentioned Nilunsi Temple i. If the value of 1 or 10 is about 10 or less, the value of orp cannot fall below _67〇(mv) or so. When the structure is L 』D, there is also the above, but using the sub-potential water in each chamber as described above, it can be observed that the color is blue or green, and the diode of the voltage of 3V is required. There is continuous lighting. Sexual Yi: In the reduction potential water containing high-energy electrons used in the industry, it is found that the reduction potential water may have "potentially still right 丄 ♦ #佶. In particular, because the LED must be lit, 0RP must Tendency K: Bow 丨. Reduction potential water has a very strong reducing power, if food, agriculture, and credit should be used in a wide range of industries including medical, industrial, and automotive sources. Ming. What kind of state is it?

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Page 9 1270532 V. Description of invention (7) After ^1 such as shield ^ tap water and other ordinary water to add vitamins to resist bad, .. surface, even in the reduction potential water to add oxidant, oxygen value: 0RP: horse Λ broken reduction. This state can be considered as the negative of the reduction potential water = the lowering agent remains in the original state, and the two are in the coexistence. At this time, there is no resilience. 1 'To face the reduction potential water, even if there is an ancient ::: the bribe is very large, the electrons in the reduction potential water do not have the reaction of reducing the oxidant. Therefore, it can be considered that the magnitude of the reduced electric energy and the ease of discharge of the electrons, that is, the exertion of the reducing power, should be different. For I ίϊ to restore 1 bit of water, how can I do it? (1) The result of further research by the inventors of the present invention is to obtain the idea of applying a compounding agent. Although there are various types of catalysts, in particular, when the raw material is w, it is thought that the enzyme or the noble metal colloid described later should be used as a catalyst. : 匕二' If the enzyme is specifically mentioned, the enzyme is essentially a catalyst for chemical reactions, and the enzyme activity is measured at the rate of the catalytic reaction. In the reaction of A B , A is a matrix μ product. If this set is used in the present invention, the molecular hydrogen contained in the hydrogen-dissolved water is equivalent to the matrix, and the hydrogen is generated as the product. Moreover, the mechanism of action of the enzyme can be considered as follows. Now, the high-energy electrons contained in the reduction potential water are met with the oxidant, and the oxidant is reduced. The reduction potential contains 2 electricity.

2030-5402-PF(Nl).Ptd Page 10 1270532 V. INSTRUCTIONS (8) Moving to the oxidant' The presence of these electron groups (4) is beyond the limit: 篁 = wall. This energy barrier is commonly referred to as a "potential barrier" or "activation:"4. Therefore, the higher the amount, the higher the height of the wall that must be crossed. The energy expressed by the wall is more energy than the electron group =', so usually the electron cannot cross the ^, and as a result, it cannot move to the oxidation. That is, it is thought that the oxidizing agent cannot be reduced. Ui, if there is a catalyst such as an enzyme, it is equivalent to a wall decrease, and the result is that the electron group contained in the reduction potential water is compared with the case where there is a catalyst, and the m β emulsifier can be moved in the pot and moved in the pot. The movement is quite smooth: the % point of π is π, and the reduction potential water can reduce the oxidant. Thus, when a catalyst such as an enzyme acts, the energy electron group becomes easily discharged, and the result can be restored: The so-called reduction potential water "has potential, ', ρ, it can be said that "reduction potential water for a different way to go through various kinds of thinking, and finally finally got the "solution to the original logic? Sealed". The key to the seal of the Force is the catalyst. After understanding the latitude and longitude of the present invention, the outline of the present invention is made. (2) The general antioxidant treatment method of the present invention provides an antioxidant method according to the present invention, and the action of the chemical agent on the hydrogen-dissolving water promotes r and In order to prevent the oxidative state caused by the lack of electrons contained in the water by using the molecular hydrogen as a matrix, or to prevent the knife-reaction reaction, the oxidized anti-oxidation target

1270532 V. Description of invention (9) It is enough to restore to a state where electrons are sufficient. The inventors of the present invention are convinced that the hydrogen-soluble 0RP value such as electrolytically treated water or hydrogen bubble water exhibits a negative value in the form of hydrogen dissolved in the same water. The gas is the most reductive substance of 'and the gas is generated on the cathode side during the electrolysis process." The above convictions provide evidence. However, as the latitude and longitude of the present invention can be clearly understood, the hydrogen is dissolved in the state in which the reducing power is sealed. The oxygen of the sub-K, as defined by the method, has a reducing power for catalyzing the opening of hydrogen-dissolved water. Therefore, it has been found that the process of applying the relevant anti-agent to the hydrogen-dissolving water of the present invention is extremely important for the sealing of the solution.

Existence. If the anti-oxidation is not effective, another important factor is that the antioxidant object does not exist, and the antioxidants related to the present invention are 0, that is, the important factor in the present invention, the first is hydrogen-dissolved water, The second is the catalyst and the third is the antioxidant target. These three elements are organically combined, and the seal of the reducing power of hydrogen potential is released, and the generalized antioxidant effect including the reducing function can be manifested. Further, the expression of the antioxidant function in the present invention means that the oxidation state due to the lack of electrons or the oxidation resistant object to be prevented from being oxidized can be reduced to a state where electrons are sufficient. Here, the magnitude of the reducing power is estimated by the state of the 0RP value (7) the stability of the measured value of Rp or the relationship with the above-described Nilenstrom type, etc., but it is necessary to pay attention to the quantitative hydrogen concentration of the reducing pigment as described later. The effective value of the dissolved hydrogen concentration DH obtained by the method is determined. Secondly, for these three elements, the invention is referred to and presumed

2030-5402-PF(Nl).ptd Page 12 1270532 V. Description of the invention (10) The technical scope of the water is dissolved (sometimes hydrogen is stored: the original can be; the water of the gas: ... the water, activated carbon Treatment of water, separation;: = fine water, cold water, natural treasure bottle water, after t 4 Μ 乂 water, pure water, ultra-pure water, city-sold hydrogen water, etc., including 'some drowning Further, in the water, a molecule is produced by chemical reaction or water of a reducing agent to be described later, and an electrolytic auxiliary is added to the water in one step, as long as a# is also within the technical scope of the present invention. More advanced, neutral 戋: two f The condition of water containing hydrogen 'whether its liquidity is acid bismuth, two = and in principle regardless of its dissolved concentration. The molecular hydrogen is replaced by::: The antioxidant function is permeated through the catalyst in the molecular form s 2 f ΐ ΐ ΐ 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠 鼠In the raw water, the alkaline electrolyzed water generated on the cathode side will be picked up, or the original off-Μ ^ aeration will be used. Up to the pressure-filled treated water. In the phase of 4 ^ h, the technical scope of the present invention also includes nitrogen-dissolved water formed by nitrogen contained in the existing continuous water-pass or batch electrolyzed water generator.丄所=水 is only the minimum example, and is not limited to this. @本,=本::匕 It is obvious that the water is not excluded, for example, body fluids such as blood or lymph ( Sometimes called

1270532 V. INSTRUCTION INSTRUCTION (11) _ Bio-water) is derived from intestinal microbes, special ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ to infer the molecular gas ice six v ^ 4 enzymes micro-sheng its origin ' The body water in which the molecular hydrogen is dissolved is also distributed in the intestines regardless of the absorption. It is considered that the intestines 4th generation τ flow in the blood is not distributed _ is sent to the liver or kidneys, etc. Each visceral Itm storage i is a meeting place. In this case, 'to use the raw material stored in the living body, as long as the enzyme such as hydrogen kinase is used as the sputum sputum as the sputum, so that the molecular makeup π, f and other enzymes or the daring metal colloid can be administered to the living body. The door-to-door knives can be activated. Soil, hydrogen dissolved water not only 0RP is a negative value, also 7...Site type, pH, (mV: water: here referred to as the reduction potential water of course package = = developed back to the original potential water generating device (in this case - The water produced by the person") is not M ^ # reduction potential aquatic, minute. 1 does not rule out the use of other sputum A, η Shi meet the above-mentioned reduction potential water 生成 斤 且 and The water-reproducing water is re-produced and the recirculation project under the original potential water generating device is only a timed dip machine to the electrolytic cell, and will be obtained as shown in Table 1 below, etc., and 5,|3# ' In the case of circulating electrolytic treatment technology, the original potential water, and the reduction potential: the concentration of hydrogen storage should be lower than the p value). It is a reference example of the hydrogen-soluble water which is expected to be compared with the water of the present invention and the water in which the hydrogen is not dissolved, and the various types of water to be used for comparison are variously related. The physical property value is used as a pipe column to treat the active π ^ , and the tap water of Fujisawa City is passed through activated carbon & treated water, and the tap water of Fujisawa City is passed through Europe.

1270532 V. INSTRUCTION DESCRIPTION 02) ' ^ The use of the ion exchange column of the Lugano Society for the treatment of the refined water of the Oruggano, and the use of the evian supplied by the Kirkby Idun Mineral Water Co., Ltd. to Japan." (registered trademark of SAdes Eaux Mineales d' Evian) is exemplified as an example of a bottle of water. The hydrogen-dissolved water after various treatments for dissolving hydrogen in the water to be compared is subjected to the electrolysis condition of 5 A solid current at a flow rate of 1 liter per minute. The first reduction H water 1 after the continuous electrolytic treatment and the same electrolysis conditions are used (the second water of the circulating water is 2 metrics, the second reduction potential water after 30 minutes of the second electrolytic treatment, and the hydrogenation treatment of the hydrogen gas) 30-grade β-grade (monthly) company electrolyzed water generating device "Mini Wate uses the electrolysis range r4 t of the thundering Μ 彳 彳 圭 圭 圭 以 以 以 以 以 以 以 以 以 以 以 以 以 验 验 验 验 验For example, the electrolysis condition is subjected to continuous electrolysis treatment, and the various physical properties of the water (5) > the electrical conductivity level is the 举 ΡΗ, the redox potential hydrogen storage concentration DH (mg / L), the water temperature τ ( In the case of the storage and rolling, the degree of D0 (mg/U, the various types of gauges used in the case of the physical properties of the seedlings) is measured by the production of these (stock) excavation yards, and the standard is used. "9620-l0D", 〇Rj^t [form as "0-13", same The needle gauge, the body type is "D-25", and the 0RP EC meter made by the excavation factory is the "stock" excavation studio & 阢^ needle form "93 00- 1 0D". The same probe type is "9382M(10)", the main body form is "D-24", D0 meter, and the main body form is "Maji DKK (share) system made by Bujiwei (stock) excavation factory, body

2030.5402-PF(Nl).ptd Page 15 "9 520, D", dh meter (dissolved hydrogen meter... 1270532 V. Invention description (13) Form "DHDI-1", the same electrode (probe) is "HE-532 1" and the repeater type are "DHM-F2", and various physical values of the water to be compared are measured using these various types of gauges.

2030-5402-PF(Nl).ptd Page 16 1270532 V. Description of invention (14) Circle _11 2030-5402-PF(Nl).ptd Page 17 1270532 V. Description of invention (15) According to Table 1, It is noted that when measuring with dissolved nitrogen, the reduction potential water generating device is used for i times, and the original potential water of DH can not only treat the water after the electrolytic treatment, that is, the first time after the human solution, 425~0.900 (mg/L) of high concentration of hydrogen dissolved in the extraction, which can also be made, can be understood that the treatment time is set to 3 〇 minutes ', ° into the device in the cycle of electrolytic reduction potential water (the first? When the concentration of hydrogen dissolved in the water at the reduction potential is compared with that of the post-water and hydrogen gas, the 可 can be stored at a high level of 1·15?~U74-/1), but the hydrogen-dissolved water is destroyed by winter as needed.醆,;^^ ^ ^ There are at least one kind of reducing agent in the group of sulfite, thiosulfuric acid and ιίίΐ as the second: and the fast one is to make the dissolved oxygen concentration in the hydrogen dissolved water as unclear as possible, in the role of catalyst The hydrogen dissolved in the water, only added to the less than just dissolved oxygen can be still 焉 仆 仆 曰 曰 、 、 、 、 、 、 、 、 、 、 、 、 In the case of the reducing agent, the dissolved milk wave degree (D0) (mg/L) can be reduced to almost 〇 (mg/L) in the hydrogen-soluble water in the action of the ruthenium catalyst, and the same amount of reducing agent is added as a comparative example. , 不合佶,交左备,曲+ ^ "You don't want to make / coexist" 辰 degree D〇(mg/L) drop so 2 疋 seal liberated hydrogen dissolved water has the original reducing power Hey, the original phase has the result that the reducing power is more strongly extracted. , Cheng:: Two belts proposed 'If the antioxidant water and the reduction day of the present invention are: 3 Γ ί ί ί , , , , ί ί ί ί ί ί ί ί Τ Τ Τ Τ Τ Τ Τ Τ Τ Τ Τ Τ Τ Τ Τ Τ Τ Τ Τ Τ Τ Τ Τ The result of τ, the original can be added

1270532 V. INSTRUCTIONS (16) The antioxidant effect is more powerful. It means that, for example, if the antioxidant antioxidant water and the reduced ascorbic acid coexist in the lower bottle, the ascorbic acid can continue to be in the antioxidant environment, so that the reduced ascorbic acid originally has antioxidant activity. The effect can be drawn more strongly. In this case, it is preferred to add an amount such as a reducing agent such as reduced ascorbic acid to reduce and neutralize an oxide such as dissolved oxygen in the coexisting system. However, it is preferable to add the ascorbic acid in an appropriate amount in consideration of the pH of the antioxidant function water or the lower limit of the recommended intake per ounce. The catalyst and the catalyst are collectively those having a catalytic function for decomposing the molecular hydrogen contained in the hydrogen-dissolved water as a matrix into a living hydrogen reaction. That is, the essence of the catalytic function of the present invention is to smoothly promote the activity of molecular hydrogen, but the function contains electrons from molecular hydrogen (by a molecular hydrogen = sex, two electrons are obtained; 2 e - + 2 H+) and the electron f obtained after even $ (including the concept of adsorption or occlusion in the catalyst), or not coupled 'to provide to the antioxidant object. The technical range of the catalyst of the present invention includes, for example, a hydroxide-reducing enzyme, further comprising a hydrogen-containing kinase, a secondary gold, and a colloid. Or at least one type of electromagnetic wave is selected from the group consisting of visible light, ultraviolet light, and electron beam. Further, the noble metal gum system assumed in the present invention comprises platinum, palladium, rhodium, ruthenium, gold, silver, rhodium, and salts of the noble metal elements, colloidal particles such as gold compounds and erroneous compounds, and the like. concept. In the manufacture or use of the relevant precious metal colloid, the Z-loaded content of the present invention can be used in the present invention. In the invention of the present application, the "Pt colloid practice and use method" by Namba, Taro, and Okura Ichiro, surface

Page 19 1270532 V. Description of invention (17) -------

Vol· 21Νο· 8( 1 983 ) 记·夕 * — The system shows essentially the valley: can be... the particles of the glue in the present invention. However, the use of = : system diameter lnm ~ °. 5 " mr" colloidal catalytic activity is improved: 乍 f precious metal colloid, in order to make the initial practice and use method, such as the above-mentioned hard wave, etc. in the paper "Pt The colloidal activity is increased to obtain the surface quality, and the particle size derived from the original nature of the precious metal and the relationship between the German and the famous Tadinger. "1〇, 1. 9 atoms are constructed by the invention. Colloid. In addition, the noble metal colloid of the present invention is for the purpose of: meaning: for the purpose of re-formation. This means that due to the surface of the metal colloid, when the particle shape is large, the molecular hydrogen contact opportunity of the spheroid is increased. ^ When the table f is large, it can be advantageous from the viewpoint of being a base. The catalytic function of the shell metal colloid is further improved, and the electron-conducting body such as the catalyst-containing compound diorganic compound is in the coenzyme and the inorganic ruthenium electron transporter. For example, bismuth oxidoreductase hydrogen kinase or noble metal 228 can have the property of electrons received as electrons and electrons in the case of hydrogen and hydrogen. In short, electronically conveyed objects Sleek delivery The following is used as the 虱 (electron) below, and the candidate of the electron carrier is listed. The body is oxidized or reduced, and the reduced electron ray propagates excess electrons, so it is easier to release the electronic version of the mouth. ) methyleneblue (methyleneblue, pass; y said that it is advantageous. Feeding von oxidized type) 1270532 V. Description of invention (18) --- Methyl sulphide only vapor, tetramethyl sulphide only gasification chemical formula = C16H18C1N3S 3 (H20) Reduced methylene blue refers to colorless methylene blue. (2) Pyocyanin Chemical formula = C13H1()N2. It is a kind of antibiotic that is produced by Pseudomonas aeruginosa. The pyocyanin can undergo a reversible redox reaction, and the oxidation = two in the form of blue under alkaline and red in acid. Further, the reduced form and the reduced type of indigo (colorless indigo) are colorless. (3) phenazine methosulfate is abbreviated as: PMS. Chemical formula = C14H14N2G04S. Phenazine sulfonate has a tendency to be easily decomposed.

(4) 1-decyloxy PMS was developed as a substitute for the above-mentioned photolabile PMS and is stable to light. (5) Iron (I I I) ion compound For example, there are various kinds of FeCl3, Fe2(S04)3, Fe(0H)3 and the like. The original system serves as a reagent for ionizing iron (I II) ions F e ( + 3 ). It is considered to be present in the blood matrix iron of hemoglobin in the human body. Also, the blood matrix iron is different in nature from the independent iron ions. In particular, if it acts in combination with ascorbic acid in vitro, it is not necessary to be an iron ion because it generates a hydroxyl radical (·0H) having a strong oxidizing power. However, in the body, if iron ions coexist with nitric oxide (N〇), there is

2030-5402-PF(Nl).ptd Page 21 1270532 V. Inventive Note (19) " One^ does not form a hydroxyl radical (· 〇H). In particular, the divalent iron Fe(2+) is a reduced form of trivalent iron Fe(3+), but although it is a reduced form, the oxidation is often excessive. In particular, when a lipid peroxide is present, it is easy to generate a radical linkage reaction. When iron (丨丨丨)Fe(3 + ) is reduced by ascorbic acid, a free radical generates a chain reaction when peroxide lipids are present. That is, most of the lipid radicals are generated, which adversely affects the organism. (6) Reduced ascorbic acid (chemical formula = q 〇 6) is present in the body, but is absorbed in vitro and is not synthesized by humans.

(Ό 胱 glutathione (chemical formula Ci () Hi7N3 〇 6S) There are many SH compounds in the living body, it is speculated that humans also have the synthesis of this gene. It is 3 amino acids (glutamine-cysteine - A polypeptide consisting of glycine = Glu-Cys-Gly) is a coenzyme of glyoxalase (gly〇xalase) and is known as an intracellular reducing agent, an anti-aging agent, etc. Further, 'glutathione It has the function of reducing oxygen (〇2) directly (non-enzymatic). 0 (8) Cysteine (Cys) is a kind of amino acid, which is a kind of other compound, which is the final product after ingesting protein and digesting and decomposing. It is a constituent element of the above glutathione, and is an amino acid having an SH group. Like, like glutathione, when two cysteines Cy s emit a hydrogen atom respectively to a disulfide bond (-s _ s _ ) will become oxidized cysteine when combined. (9) Cholesteric acid (C7 H6 02 ) is almost non-existent in the living body, but the strawberry contains about 〇 〇 5%.

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V. INSTRUCTION OF THE INVENTION (20) Basically, the reducing agent 'has a function of converting a hydroxyl radical into a non-enzymatic and effective water. '(10) p-Amino-benzoic acid (c7h7no2) (11) Gallic acid (C7H6 05 ) (3,4,5-tri-perbenzoic acid) is widely found in leaves, stems, roots, etc. It is generally used as a hemostatic agent or a food antioxidant (food additive). Its alkaline aqueous solution has a particularly strong reducing power. Has a tendency to react easily with milk. Further, the catalysts exemplified herein are merely illustrative and are not limited thereto. Therefore, it should be understood that the catalytic reaction assumed by the present invention does not use, for example, a physical external force such as temperature, ultrasonic or stirring, or the like, or a hydrogen-soluble water. In addition, the hydrogen-soluble enzyme (hydrogen-activated ★ shell metal colloidal electron transporter 4 in the group of electron-transmitting rays, and γ-extracted, the active hydrogen-based product contains the original and hydride ions (Hydride) Furthermore, the catalysts described herein may individually require a 'moderate combination of multiple uses. Basically, the catalyst-antioxidant object is electronically transmitted in the order, and hydrogen may also be assumed. Dissolved water-enzyme (hydrogen kinase)-antioxidant water-sinking electron carrier-antioxidant object, hydrogen-soluble water-enzyme) electron-transmitting body-antioxidant object, hydrogen-dissolved water--antioxidant object, or hydrogen-soluble water-precious metal colloid — The order of antioxidant targets, etc. is communicated electronically. Further, the alignment may be used in combination with at least one type of electromagnetic wave selected from visible light, ultraviolet light, and electrons. Antioxidant

1270532 V. INSTRUCTIONS (21) Hydrogen kinase-dissolved water 'catalyzed sputum potential potentiation for the chemical system. The atomic antioxidant object that is converted into a solution is a preventable state or to prevent oxidation. The object is a phenomenon of electrons such as oxygen, heat, light, pH, and ions. Further, in the present invention, for example, there are bio-organic cells, foods, quasi-medicine redox dyes, and water-based substances in various industrial fields such as precision washing, and the water-based objects are only the minimum examples. From the viewpoint of the catalyst, 0 (i) hydroxide-reducing enzyme (the present invention is a catalytic kinase that catalyzes hydrogen production of active hydrogen, or a noble metal gel, which is considered to be in the gastrointestinal tract, such as in the case of a kinase such as a hydrogen kinase. When an oxidizing agent such as active oxygen is present, there is a fruit juice or a vitamin-reducing potential water in the presence of an antioxidant. The action of hydrogen is due to the hydrogenation of hydrogen kinase and activation, so that the oxidation caused by the lack of electrons is generated. Oxidation refers to the object of anti-oxidation in the technical range from the object of direct or indirect action, or the object to be washed, the product to be washed, the vitamin, and the like, and the pharmaceutical product. Piles, feed, body, etc. Again, the antioxidants listed here should be understood without limitation. Discuss the relationship between catalysts and antioxidants. The molecular hydrogen matrix contained in the body is decomposed into a reagent such as a hydroxide-reducing enzyme, a hydrogenation reducing enzyme added to hydrogen water, a hydrogen-based system in a weakly alkaline reduction potential water, and a somatic cell (anti-gasification target). When the oxidant is reduced, and other additives (anti-gasification target), y: τ, will be used as the additive to suppress the decomposition of the original potential water into two atomic hydrogen (Η ·) , and the hydrogen (Η ·) will be divided in the presence of water

1270532 V. INSTRUCTIONS (22) Protons and electrons, and thus electrons Μ A (reduction of antioxidant targets). The broken k will be provided to the anti-cracking pair. In addition, the reduction potential water Yin can be added to the precious metal colloid. For example, when drinking a body of a reducing alkaline water-platinum for weak alkaline, the body cells of the gastrointestinal system such as the gastrointestinal tract (the antioxidants are immediately used as an antioxidant): Total: juice or vitamins are present Other additives (antioxidant:, the two original potential water in the coexistence of platinum colloidal conditions, will be: 逛 逛 逛 岔 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 还原 还原 还原 还原 还原 还原 还原 还原 还原 还原 还原 还原 还原 还原 还原 还原The hydrogen decomposition of the colloid dissociates into two atomic hydrogen knives (H · ) and is activated, so the generated atomic hydrogen (h ·) is divided into protons and electrons in the water, so it is born. The electron is considered to be an antioxidant object (reduction of anti-oxidation target). Stomach % Volt π The antioxidant function is a combination of hydrogen-soluble water such as reduction potential water and hydroxide hydroxide-reducing hydrogenase or noble metal colloid as a catalyst, and digestion ^There are three anti-oxidation objects such as compact body. In other words, the reducing power is exhibited only when it is necessary, and it does not play any role when it is not needed. Also, when paying attention to its chemical composition, for example, reducing potential water only It is the ordinary water obtained by electrolyzing the raw water. Therefore, it can be emphasized that even after exhibiting the reducing power, it is still ordinary water, and there is no adverse effect on the living body. In other words, the positive effect of the target can be obtained. However, the negative effect, that is, the g W sword function 70 does not exist at all - this is a decisive difference from the previous antioxidant or active oxygen scavenger. Here, 'Citation of Qikou Fang, Associate Professor, Graduate School of Science, Kyoto University Research Institute

1270532 V. INSTRUCTIONS (23) : 沦 = "Hydro-reduction enzymes χ line structure k ΠΓ.7 V〇1,4 N〇·4 JULY ^ : u is called hydrogen kinase, a wide range It is found in the protein shell of bacteria. It is a protein with a metal such as iron or nickel, but it has recently been discovered to be completely novel hydrogen kinase. This molecule is used to decompose various hydrogen redox reactions in bacteria. The concentration of protons inside and outside the membrane on the surface of the membrane is considered to be an important work of the enzymes in the bacteria related to the enzymes: the results of the study. The Yanhai people in other papers "using radiation to multi-wave ^ hanging / knife scattered In the analysis of the X-ray crystal structure of hydrogen kinase, a central enzyme in which a series of reaction systems for obtaining energy is a sputum 2 lyase. It is known to control the proton concentration inside and outside the cell membrane in order to activate the enzyme. Proportion. Hydrogenase has the effect of redox catalysis of knife-like nitrogen around the membrane protein membrane present in the surface layer of the cell membrane. That is, the hydrogen kinase directly dominates the ratio of proton concentration inside and outside the membrane, and controls the synthesis of decomposing enzymes. Therefore, hydrogen kinase has the potential to make the bioenergy metabolism system smooth. The understanding of the three-dimensional structure of hydrogen kinase has the important meaning to explain the relationship between the structure and function of the most important energy metabolism in the life-sustaining mechanism. Research results. The inventors of the present invention have the effect of "hydrogen kinase directly governing the ratio of proton concentration inside and outside the membrane" and controlling the action of purine synthesis and decomposing enzymes. Therefore, hydrogen kinase has the possibility of functioning as a vital function for smoothing the bioenergy metabolism system. Zhuo see special attention. This is because hydrogen kinase can be expected to be effective for living organisms because of the anti-oxidation method, antioxidant function water or will be produced by the present invention.

2030-5402-PF(Nl).ptd Page 26 1270532 V. INSTRUCTIONS (24) Applicable water is suitable for use in supporting slippage promotion. Therefore, the present invention has a rapid property for dripping and dialysis of hydrogen as a medicine for the tissue or the organ. Here, the damage of the living body will occur. The principle of the reaction is the nature of intestinal invasion. Simple white matter, only the phenomenon is called the opening of a drug to reach the fat can be used for the same or the operation of the hydrogen and oxygen injury parts. In order to apply to foreign resistance, if the body is rich in tolerant body, the combination of the antioxidant function at the cell level and the like, the ratio of proton concentration is improved, and the energy metabolism system is clarified by the hydroxide hydroxide, hydrogen kinase or precious metal. Glue/macrophage function related or caused by the disease, special cell function can be caused by or reduced, related to or caused by the disease, dysfunction or pathological prevention, improvement or treatment. The specifics are as follows. In other words, in general, water is fed into the body part of the living body which is damaged by all the living oxygen such as the plasma membrane two-cell membrane or the blood-brain barrier, and the hydroxide hydroxide-reducing hydrogenase or the precious metal colloidal disk is separately injected by injection. In order to realize the healing effect of the damaged part, and to reduce the absorption of the small intestine by the injecting epidemic institution, the original inducing the small intestine, and the principle of enzyme hydrogen and spot identification. The principle of anti-intake is based on the principle that the clinically applied kinase is used, and the dialysis enzyme is not only the tolerance of the original substance, that is, the substance, but the protein may be self-initiated when it is supposed to be sent to its peer-to-peer operation. The oral wideness of an antigen-antibody organism means that an immunotolerance is established for an egg that is an antigen that is not responsive to oral/menstrual sputum/sputum cells, and this attempt is made for treatment. Therefore, it is necessary to open the antioxidant

2030-5402-PF(Nl).ptd 1270532 V. New treatment strategy for inventions (25). (ii) Electron rays containing visible, ultraviolet or X-rays. The present invention catalyzes a reaction of decomposing a molecular hydrogen matrix contained in hydrogen-dissolved water into active hydrogen of a product, for example, containing visible, ultraviolet light or X-rays. Electron ray. 'Now, consider using the reduction potential to make use. Specifically, for example, in the semi-surface treatment process, the electrolytic solution is added to the electrolyte to be treated to reduce the potential water, and the ultraviolet light is dissolved in the water at a wavelength of 15 〇 nm to 300 nm. As a result, it is possible to prevent the reduction of the sulfhydryl group. In addition, it is water-repellent at the time of washing. The reason is that the oxide film can be removed from the ruthenium substrate by the original potential water from the viewpoint of safety and corrosion of the ruthenium substrate. Moreover, if it is produced by the recycling technique of the present invention, the reduction potential water can be obtained, so that the effect of reducing the potential water can be improved. In the water, for example, ultraviolet light is used as a catalyst conductor substrate, especially in the ruthenium substrate engineering. The sealing plate (antioxidation target) which reduces the electrocatalytic reduction power of hydrogen by the electrocatalytic reduction of the electrocatalyst is used as the object to be cleaned in the pure water Oxidation or use of p Η 7~1 3 reduction potential with Ρ high 的 value of the solution, due to problems with the human body, and use ΡΗ7 to 13 are also residual fluorine and can be prevented from being applied to the ruthenium substrate. Using a circulating potential Hydrogen-rich and a lower 0RP reduction power exerts a good reducing power, so it can be expected to wash

The anti-oxidation function is synthesized by combining the ultraviolet rays of the catalyst with the catalyst, the water of the original potential water, and the object of the anti-oxidation of the soil.

1270532 V. INSTRUCTIONS (26) In other words, the reducing power is only shown when necessary and will not be used when it is not needed. Moreover, when paying attention to the chemical composition, for example, the water is merely ordinary water obtained by electrolyzing raw water. Therefore, even after showing the reducing power, it is still ordinary water, and there will be any adverse effect on the washing of the stone substrate*. Furthermore, @the reduction can be: the production of the stone oxides does not produce electrical properties that may be caused during the componentization: : water glass, ▼ is expected to achieve the previous water mixture with a variety of acid: The same treatment effect is obtained. Moreover, compared with the previous method, the amount of product used can also be reduced. From this point of view, the safety of the process is ensured, and the amount of use is reduced, and the simplification of the project is possible. The invention provides an antioxidant function 纟 which is characterized in that 分子, the molecular hydrogen matrix contained in the valley water is decomposed into a ruthenium noble metal colloid which is active hydrogen. An enzyme, for example, which is added with ruthenium kinase or the antioxidant water having the composition contains the hydrogen-dissolved water and the catalyst in the weight of the present invention, so that as long as anti-oxidation is encountered; The seal with the reducing power can be liberated, and the two unique antioxidant functions. |七明 However, if the antioxidant water of the above composition is used for drinking 昉 = when the large intestine is used as an anti-oxidation target, if the hydrogen potential is before the large intestine: the 丄 original force has been almost released, there will be no The problem of achieving the original goal. Therefore, for the oxidoreductase of the catalyst as a catalyst, the shell metal colloid, Xiao Jia, needs to adjust the reaction time of the catalyst.

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Or operation. The treatment or operation of a catalyst reaction time of 1 °C, for example, the first, the second, including the hydrogen kinase or precious metal colloid to reach the small intestine or the large intestine, etc.! "Day! ί is the original catalyst to start the action < target time, The temperature of the hydrogen-activated capsule or the anti-oxidation function water into which the hydrogen kinase is placed is also within the range that can inhibit the inactivation of the enzyme hydrogen kinase activity. Hydrogen kinase is considered to have an optimum pH of about g, and an optimum temperature is about 49 ° C. Moreover, all treatments or operations for adjusting the reaction time of the catalyst for hydrogen kinase or the like or its surroundings are within the technical scope of the present invention. On the other hand, when using precious gold lip colloid as a catalyst, when it is applied to a living body, it is necessary to guarantee safety. Specifically, the bio-affinity including the toxicity of the precious metal itself must be considered. For example, Even if people take platinum, they can be quickly excreted in the form of urine through the kidneys, and they are recognized by the Department of Health as food additives, and it is considered that there is no problem of bio-affinity. Another question to consider Yes, in order to stabilize and uniformly disperse the precious metal colloid in the antioxidant function water, it is possible to add a certain dispersing agent. For example, in drinking or cosmetic use, as long as it is approved by the Department of Health as a food additive' It is sufficient to select a function having a dispersing agent. In this case, for example, a low-irritant sucrose fatty acid ester or the like which is used for cosmetic or pharmaceutical use is suitable. The antioxidant water can be considered, for example, in the following. Application development in the industrial field. 'The first is applied in the field of medicine and pharmacy. For example, it can be used for infusion

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1270532 V. INSTRUCTIONS (29) Lack of oxidative state caused by electrons or to prevent oxygen from being restored to a state where electrons are sufficient, and high levels of object energy or environmental load are reduced. (4) Safety of the human body [Embodiment] Best Mode for Carrying Out the Invention Hereinafter, embodiments of the present invention will be described with reference to the drawings. First, referring to FIG. 4', the semiconductor substrate of the semiconductor substrate-washing conductor substrate cleaning system is covered with a surface portion == a cleaning solution such as a mixed solution for surface-treating the oxide film. The water, particularly the reduction potential, uses the hydrogen-dissolved conductor substrate of the present invention, and the object of the present invention is an anti-oxidation object of the present invention as shown in Fig. 4, which is a cleaning method; The water generating device η and the sputum generating device 13 and the reducing electric pure water u are supplied to the inlet port 111 of the water generating device 11 generated by the water generating device 13 Bit water 15. Further, the voltage of the reduction potential electrode 15 is electrolyzed to form a reduction electric substrate (wafer), and the reduction potential water 15 is introduced into the semiconductor wafer cassette 17, or the crystal is not introduced into the processing tank. The circle W is held in the crystal gas mixed with dust or oxygen. The tank 16 is provided with a sealable cover 18 to prevent rolling from large & In particular, in the present embodiment, the ultraviolet light lamp 19 is provided in the reduction potential water treatment tank 16, and the wafer W in the cleaning of the reduction potential water is irradiated with ultraviolet rays to perform the action on G.

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(Invention) (30) In this way, in the reduction potential of the present embodiment, the hydrostatic potential water exhibits a reducing power only when necessary, and the effect obtained by the reduction in the setting of "1" is noted. The potential water is only obtained by electrolyzing the raw water and, for example, the 'reduction of the reduction, even after exhibiting the reducing power, is still: 1 water. Therefore, the substrate can be free from any adverse effects. The water that is passed through can prevent the generation of cerium oxide from being washed, and the water glass which is degraded by the reduction effect can be expected to have the same treatment effect as that which may have been previously treated with the electric characteristic liquid. 1 ff acid-alkali water mixed season 乂柰 (10) can also be reduced in use. From this point of view, it is possible to reduce the amount of medicines and the like, and to simplify the engineering. Wang Yong, and i are the same as the chlorine acid acid container. By opening the valve 21, the hydrofluoric acid solution in the hydrofluoric acid container 20 is arbitrarily added to the reduction potential (10) + to remove the oxide film on the Si Xi wafer w. In the same figure, 22 is a gas-liquid separation device. Do not mix the gas into the reduction potential water The reduction potential water generating device n is described in detail with reference to Fig. 5. The reduction potential water generating device of the present embodiment is obtained by introducing the raw water inlet port 111 such as pure water and the generated reduction potential water. The electrolysis chamber 113 is formed between the introduction port 111 and the outlet port 112. The reduction potential water generating device of the present example is placed on the bottom surface of the outer casing 丨i 4 in the figure. In the vertical direction of the paper surface, the inlet port 111 of the raw water introduction is formed on the top surface of the outer surface, and the outlet port 112 for the electrolyzed water is formed in the vertical direction opposite to the surface of the drawing. The left and right side walls of the generating device 11 are provided with a porous

2030-5402-PF (ND.Ptd Page 33 1270532 V. INSTRUCTION DESCRIPTION (31) Separator 11 5, the electrode plates are placed in contact with each other outside the diaphragm 115. The opposite electrode plate 11 7 The main surface is disposed in the electrolysis chamber 113 facing the side electrode plate 116. The two pairs of electrode plates 1 16 and 1 17 are connected with a DC power source 12, and are separated by a diaphragm 1 15 and opposite one pair. One side of the electrode plates 1 1 6 and 1 1 7 is supplied with an anode voltage' and the other side of the electrode plate is subjected to a voltage of a cathode. For example, when the reduction potential water is generated in the electrolysis chamber 113, as shown in Fig. 5, The electrode plate 1 17 disposed in the electrolysis chamber I 1 3 is connected to the cathode of the direct current power source, and the electrode plate 11 6 disposed outside the electrolysis chamber II 3 is connected to the anode of the direct current power source. Further, electrolytic oxidation is generated in the electrolysis chamber 113. In the case of water, as shown in Fig. 5, the electrode plate 11 7 provided in the electrolysis chamber 11 3 is connected to the anode of the direct current power source, and the electrode plate 11 6 provided outside the electrolysis chamber 11 3 is connected to the cathode of the direct current power source. In the example, the diaphragm 1 15 is used so that the water flowing in the electrolysis chamber 1 1 3 can easily penetrate, and the water flowing in is difficult to drip. Preferably, the reduction potential water generating device 本i of the present embodiment forms a water film in the separator 丨丨5 itself and a very small gap s between the separator 115 and the electrode plate 116 in electrolysis, and transmits the water film through the water film. There is a current flow between the electrodes between 1 16 and 1 17 . Therefore, it is an important problem to increase the electrolysis efficiency by sequentially changing the water constituting the water film. Further, the water which penetrates the diaphragm 115 is a diaphragm. The leakage between the 115 and the electrode plate 116 must be treated so that it has a high degree of impartability so that the water to be infiltrated does not drip. However, when the solid electrolyte membrane is used as the separator, the electrolyte membrane itself has electrical conduction. Therefore, in this case, a small gap s between the diaphragm 115 itself and the diaphragm 115 and the electrode plate 116 can be omitted. One example of the diaphragm 11 is, for example, a polyester non-woven fabric or polyethylene.

2030-5402-PF(Nl).ptd Page 34 1270532 V. Description of invention (32) Screen ^ 'The film material is vaporized ethylene or polyvinylidene fluoride and titanium oxide or polygas B, etc., thickness is 0·b多孔· 3 mm, a porous membrane having an average pore diameter of 〇·05·1·0, a water permeability of 1·Occ/cm 2 ·min or less, or a solid electrolyte membrane. When a cation exchange membrane is used as the separator crucible 5, for example, a cation exchange-based perfluorosulfonic acid membrane based on polytetrafluoroethylene as a base material of a Nafon (NAFI0N) membrane manufactured by DuPont can be used, or as A copolymer of cation exchange vinyl ether and tetrafluoroethylene of Fulai Ming film made by Asahi Kasei.

On the other hand, the distance between the plates of the pair of electrode plates 1 1 6 and 11 7 which are opposed to each other via the diaphragm Π 5 is 〇mm 〜5· 〇mm, preferably 丨.5_. Here, the distance between the plates of the electrode plates 116 and 117 is 0 mra, which means that, for example, an electrode film which directly forms a grooveless electrode is used on both main faces of the separator 115, and has substantially the thickness of the separator 115. The grooveless electrode may be formed only on the main surface of the separator 丨丨5 side. Further, when such a grooveless electrode is used, it is desirable to provide holes or gaps for gas generated from the surface of the electrode to the back side opposite to the separator 115 on the electrode plates 116, 17. Further, the hole or gap formed on the electrode plates 116, 117 may be an electrode plate provided on the electrolytic cell as shown in Fig. 5. Further, the distance between the plates of the electrode plates 116 and 117 provided in the electrolytic chamber 113 is not particularly limited, but is 0 mm 5 mm to 5 mm, preferably imm.

When the reduction potential water is generated by the reduction potential water generating device having the side composition, first, the two electrode plates 116 provided in the electrolysis chamber 113 are connected to the negative electrode (-) of the DC power source 12, and at the same time, The two electrode plates 116 and 117 disposed outside the electrolysis chamber 连接3 are connected to the positive electrode (+) of the DC power source 12, and are respectively opposed to the two pairs of electrode plates 丨丨6 and 丨丨7 for the separator 117. Voltage. And, the pure water is introduced from the inlet 11 1 to electrolyze the electrolysis chamber.

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For the reaction, 2H20 + 2e_ - 2 〇 H' + H2 are generated on the surface of the electrode plate 117 and in the vicinity thereof. Further, a reaction of H20-2e--2H++ι/2〇 is generated between the electrode plate 116 and the separator 115 on the surface of the electrode 116 outside the electrolytic chamber 113 of the separator 115. _ The H+ ion is stored in the separator 丨丨5 while receiving electrons e- from the cathode plate 117 through a part thereof, and hydrogen is dissolved in the generated electricity on the cathode side. Thereby, the electrolyzed water generated on the cathode side (i.e., in the electrolysis chamber 丨丨3) 7 becomes a reduction potential water lower than the oxidative potential (0RP) previously used for the electrolyzed water generated by the membrane technique. Further, since the excess H+ after passing through the separator 115 is returned to the water by the 0H-reaction in the electrolysis chamber 113, the reduction potential water generated in the electrolysis chamber 113 is slightly neutral. That is, a reduction potential water having a pH which is not very high but has a low 〇rp can be obtained. The reduction potential water containing hydroxide ions thus formed is supplied from the outlet port 112. Further, in the case where the reduction potential water obtained by the electrolytic treatment is at a desired pH value, for example, the pH of the raw water may be prepared by using a pH buffer such as citrate, phosphate or borate as a salt solution. Since the reduction potential water generating device 11 does not greatly change the pH of the raw water. Specifically, for example, if the pH is to be alkalinized because it is to be used as a cleaning or beverage for the substrate, it is only necessary to adjust the pH of the raw water to be alkaline, and if it is to be used as a beverage or injection. Liquid, drip or dialysate, if the pH is about neutral, the pH of the raw water should be adjusted to the neutral vicinity for management and modulation.

2030-5402.PF(Nl).ptd Page 36 1270532 V. Description of invention (34) " ' — ~ — Can be further 'If it is to be used as a cosmetic material, if you want to make ρ 弱 weakly acidic, just put the raw water The pH adjustment can be managed and modulated in the vicinity of weak acidity. Incidentally, the above embodiment describes the reduction potential water forming apparatus shown in Fig. 5, but the apparatus is also suitable for the case of generating oxidation potential water. In this case, the two electrode plates 117 117 disposed in the electrolytic chamber 丨丨3 are connected to the anode (+) of the DC power source 12, and at the same time, the two electrode plates 116 and i16 disposed outside the electrolytic chamber 113 are connected to the DC. The cathode (1) of the power source 12 is provided with a voltage applied to the two pairs of electrode plates opposed to each other via the diaphragm 115.

Further, when pure water or the like is introduced from the introduction port 111, hydration in the electrolysis chamber is electrolyzed to produce a reaction of H20-2e_-2H+ + 1/2 · 02 on the surface of the electrode plate 117 and its vicinity. Further, the surface of the electrode plate 116 outside the electrolytic chamber 113 of the separator 115, that is, the reaction of 2H20 + 2e - 20H - + H2 t between the electrode plate 116 and the separator 115. The 0H-ion is deposited on the surface of the separator 1 15 and passes through the surface, and is vertically divided into electrons e_ from the cathode plate 1 17 to become dissolved in oxygen.

Decontamination. Thereby, on the anode side (i.e., in the electrolysis chamber 丨丨3, the water can become an oxidation potential water which is more than the electrolytic reduction potential (0RP) previously generated by the membrane technology. The generated electrolysis water is higher shoulders. After the separator 115 passes, the excess OH-ion changes back to water due to the H+ reaction, so the ", (3) & and electrolysis to 1 pH produced in the electrolysis chamber 丨丨3 will be slightly neutral. That is, the pH is not obtained. Very oxidized potential leeches are very low, but 0RP high oxygen

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Potentiometric water. The oxidation potential water containing hydrogen ions thus generated is supplied from the outlet 11 2 .

Incidentally, the two cathode plates 1 1 7 and 11 7 which are not in the electrolytic chamber 11 are connected to the cathode (-) of the DC power source 12 by using the reduction potential water generating device ii shown in Fig. 5, and at the same time, The two electrode plates 116 and 116 outside the electrolysis chamber 113 are connected to the anode (+) of the DC power source 12 (the effective area of the electrode plate ldm2), and the tap water of Fujisawa City having a pH of 7.9, 0RP + 473 mV is 1 liter per minute. The flow rate was subjected to continuous water-passing electrolysis treatment under the electrolysis condition of 5 A fixed current. At this time, the non-encapsulated cation exchange membrane manufactured by DuPont was used as the separator 115, and the distance between the electrode plates 116 and 117 was 1.2 mm. The distance between the electrode plates 11 7 and 11 7 in the chamber 113 is 1 · 4 mm. As a result, at the instant after the electrolytic treatment, a reduction potential water Η of ρ Η = 9·03 and 〇 RP = -72 〇 mV can be obtained. The reduction potential was allowed to stand in water, and the pH and 0RP were measured after 5 minutes, 1 minute, and 3 minutes later. After 5 minutes, pH = 8, ORP = -706 mV, after 10 minutes, PH = 8.11, 0RP = -71 〇mV, after 30 minutes, pH = 8.02, ORP two-707mV.

At the instant of the electrolytic treatment, although the p Η of the treated water exceeds 9, the ρ η drops rapidly and settles near the ΡΗ8. This is considered to be because the chemical ions generated in the vicinity of the water film between the separator 丨丨5 and the anode 161 are moved to the electrolysis chamber 丨丨3 through the separator 丨丨5, and are neutralized with the OH- ions in the same electrolysis chamber 113. The reaction is returned to water, and the neutralization reaction is promoted at any time even after the reduction potential of the electrolytic treatment is allowed to stand until the chemical equilibrium at the concentration is established. Reducing activity/free radicals of hydrogen-soluble water in the catalyst of the boy's metal rubber i. Evaluation test for the following conditions. Adding a noble metal colloid catalyst to the hydrogen-dissolved water of the present invention

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V. Inventive Note (36) (: Colloid/Palladium Colloid) When the chemical activity contained in the hydrogen-dissolved water is reduced by the activation = active molecular hydrogen, or the free radical elimination activity test, respectively, examples and references example. In the above two evaluation tests, the reduction activity evaluation test was conducted by using anthraquinone (tetramethylsulfide only gasification; Ci6Hi8C1N3S ·3 (Μ)) as an antioxidant and an evaluation of free radical elimination activity. Is used in aqueous solution " free radical DPPH free radical (1,1 - dibum?? + as an antioxidant target. Benyl-2-di- succinyl amide) Here, the pair belongs to redox In the case of the pigment category, the original activity evaluation principle of the methylene blue two object is explained, and the oxidation: the liquid (absorption maximum wavelength; about 665 nm, the following Τ二水命日甲士蓝) is presented: Λ色, but becomes reduced type Blue blue (colorless methylene blue), Huya sex' is the reducing power. In addition, the reduced methylene blue dissolves into the original living hall, but if it is reoxidized, it becomes the original oxygen white blue. The coloring helmet of the methylene blue aqueous solution is reversible when it is changed back to the bar. In addition, the DPPH free radical is used as the anti-oxidation/study principle to explain the DPPH free water-water and water-reducing activity. Around 52〇nm, the following sometimes absorbs the maximum wavelength; color, when D When the PPH is reduced by the reduced radical, 11 罙 red methylene blue) appears dark red to evaluate the radical elimination activity, that is, the color of the color will fade. The color reaction of the fading aqueous solution is irreversible and oxidizing. In addition, DpPH swims the description of the evaluation test to add (1) Tujia, (2) to Aachen.

1270532 V. INSTRUCTIONS (37) The color change of blue is used to evaluate the reduction activity of hydrogen-dissolved water (degassing treatment + argon sealing treatment) with platinum colloid/palladium colloid catalyst, and (3) the color of methylene blue The change is performed by adding a platinum colloidal catalyst to electrolytically treat water (addition after electrolytic treatment/addition after electrolytic treatment), and (4) the color change of DppH radical is used as an antioxidant activity of the platinum colloidal catalyst for electrolytic treatment of water. (5) The color change of the DPPH radical is used in the order of evaluation of the antioxidant activity of the catalyst hydrogen-dissolved water (degassing treatment + hydrogen encapsulation treatment). _ (1) Evaluation of reduction activity of electrolytically treated water by addition of platinum colloidal catalyst with color change of yttrium blue (1 - A); Test procedure for evaluation of reducing power: Standard buffer 6 manufactured by Wako Pure Chemical Industries Co., Ltd. · 8 6 (aqueous phosphate solution) and 9·18 (borate aqueous solution) were diluted with purified water to obtain a pH buffered aqueous solution. Hereinafter, the two types of dilution water are referred to as basic water 6.86" and "basic water 918", respectively. Further, a solution of #胶4% solution 田·6g of Tanaka Precious Metal dissolved in distilled water of Wako Pure Chemical Industries Co., Ltd. was referred to as a "Pt reference liquid". Further, the turbulent concentration C (Pt) of the reference liquid was determined to be 48 mg/mL from the count-up formula c(pt) = 0·6 χ 〇·〇4/5〇〇mL. Substitutes, using the above two basic waters (10) and ^ "with reference liquids" to prepare a total of 8 kinds of sample aqueous solutions, as shown below. 1 · Basic water (6. 8 6) 1 1 · basic water ( 6· 86 ) 1 494 mL of pt reference solution 6 mL of platinum-containing colloidal aqueous solution iii · Aqueous solution of basic water (6.86) after electrolytic treatment

Page 40 1270532 V. Description of the invention (38) iv·Basic water (6·86) 1 494 mL of Pt reference solution 6 mL is added to prepare a platinum-containing colloidal aqueous solution, and then the aqueous solution is subjected to electrolytic treatment of the aqueous solution v. Basic water ( 9. 18) vi·Basic water (9.18) 14941^ added? 1; reference solution 611 ^ containing platinum colloidal aqueous solution vii · aqueous solution after basic water (9 · 18) electrolytic treatment vi ii · basic water (9 · 18) 1 494mL added Pt reference solution 6mL containing The aqueous solution of the platinum colloid and the aqueous solution after the electrolytic solution is further subjected to the pH, ORP (mV), temperature T (°C), and platinum colloid concentration in a total of eight aqueous solutions of the above i~vi ii In Table 2 below. Table 2 Sample No. Basic Water 6.86 Basic Water 9.18 i ii ««肇111 iv V vi vii viii PH 7.0 7.0 7.1 7.1 9.1 9.1 9.5 9.5 ORP(mV) 186 186 -625 624 130 130 -745 •745 Platinum Concentration (pg/ L) 0 192 0 192 0 192 0 192 Temperature (°C) 20 20 20 20 20 20 20 20 To check the reduction activity of a total of 8 aqueous solutions of each of the above i~viii, add methylene blue to 35 mL of each aqueous solution. (lg/L concentration) solution 10 m L 'The methylene blue concentration was adjusted to 7 4 · 4 // Μ, and the absorbance of the indigo blue of each sample aqueous solution was measured by a spectrophotometer (Α589; absorbance at a wavelength of 589 nm) . (1 - B); Revelation of Reference Example and Embodiment (Reference Example 1)

2050-5^02-PF(Nl).ptd Page 41 1270532

-^ f 11 ί ^ ^ ^ ^6,86) f ^ The result is expressed in "Aka" (A589) as Reference Example 1, (Reference Example 2) with the addition of aqueous solution of sample water ii (basic water 6. 86 + h basis $ Example 2 m blue aqueous solution its methylene blue absorbance (a589) as a reference example 2 'The result is shown in Fig. 6. (Reference Example 3) Electrolyzed water (basic water) with no added catalyst of sample water iii ^ 8 6+ electrolytic treatment), the aqueous solution of methylene blue was added, and the absorbance of the indigo blue (5 8 9 ) was taken as Reference Example 3. The results are shown in Fig. 6. (Example 1) Electrolytic treatment with catalyst added with sample water iv Water (basic water 6·86 + electrolytic treatment + Pt, reference liquid) was added to the aqueous solution of methylene blue, and the methylene blue absorbance (A589) was used as Example i, and the result was compared with Reference Example 3, and the figure is shown. ' (Reference Example 4) The methylene blue absorbance (A 5 8 9 ) of the aqueous solution after adding methylene blue to the sample water v-free catalyst aqueous solution (basic water 9·18) was taken as Reference Example 4, and the results were not shown. 7 (Reference Example 5) Adding a catalyst aqueous solution (basic water g · 1 8 + pt reference solution) to sample water V i The methylene blue absorbance (A58 9 ) of the aqueous solution after adding methylene blue was referred to as Reference Example 5, and the results are shown in Fig. 7. 1270532 V. Inventive Note (40) (Reference Example 6) No catalyst added to the sample water Vi i The water absorption of the aqueous solution of methylene blue in the electrolytically treated water (basic water 6·86 + electrolytic treatment) was as reference example 6, and the results are shown in Fig. 7. (Example 2) Taking sample water ν iii The methylene blue absorbance (A 5 8 9 ) of the aqueous solution of methylene blue added to the electrolytically treated water (basic water 5.18 + electrolytic treatment + pt standard solution) before adding the catalyst was taken as Example 2, and the results were compared with Reference Examples 4 to 6. For comparison, the results are not shown in Fig. 7. (1 - C); Investigation of Examples The results of Examples 1 and 2 were compared with Reference Examples 1 to 6 and examined. It can be said that the catalysts of Examples 1 and 2 were added. Compared with the reference example 丨6, the treated water can be reduced by the specificity of the indigo blue, and only the electrolytically treated water added with the catalyst shows a large reducing activity. Present blue for visual confirmation, only examples The addition of the catalyst to the electrolyzed water of the catalyst was colorless and transparent, and it was recognized that the color of the 曱I was disappeared. Further, the reference examples 1 to β could not visually recognize that the blue color of the sub-aged Asian disappeared. Further, Example 1 Adding catalyst hydrogen storage solution can be used to visually confirm the presence of a large amount of white precipitate (reduced methylene blue). (2) Adding platinum colloid/palladium colloidal catalyst dissolved water in the color change of methylene blue (Degassing treatment + hydrogen encapsulation treatment) reduction activity evaluation gas (2 - A ); reduction power evaluation test procedure sold by 曰本 gene (share) company, and Wako Pure Chemical Industries Co., Ltd. special injection lMTris-HCl ( pH7·4) and the same lMTris-HC1 (pH9. 〇A)

2050-5^02-PF(Nl).ptd Page 43 1270532 V. Description of Invention (41) A 50 mM aqueous solution of Tris-HCl was prepared by diluting 2 times with distilled water manufactured by Wako Pure Chemical Industries, Ltd. The two types of diluted water are referred to as "basic water 7 · 4" and "basic water 9 · 〇". Further, a solution of 0.6 g of a palladium colloidal 4% solution made by Tanaka Takashi was dissolved in 500 mL of steamed water of Wako Pure Chemical Industries Co., Ltd., and it was called "Pd reference liquid". Further, the pd reference solution was obtained by the same calculation method c(pd) = Q 6 χ 0.04/500 mL as that of the lapped body, and was 48 mg/mL.

Next, 84 mL of each of the basic water 7.4 and the basic water -9 采取 was taken, and 4 mL of an MB aqueous solution of lg/L concentration was added thereto to prepare a basic water 7.4 and a basic water 9.0 containing a concentration of 121 7/M. Then, the basic and basic waters containing ruthenium were respectively taken from each of the degassing bottles by 5〇111 [, and after the vacuum pump was degassed for 10 minutes, the operation of enclosing the hydrogen gas was repeated three times. Further, the purpose of this operation is to remove the gas components other than hydrogen in the hydrogen-dissolved water. In order to avoid the completion of the completion of the encapsulation of hydrogen containing MB basic water 7.4, basic water 9 · 0 each 3mL, and in a closed system into the quartz colorimetric tube that has been previously replaced by hydrogen, and then measured Pt reference solution, Pd reference solution, Pt reference, f Pd reference liquid molar ratio of the mixture solution was added to the quartz

Methylene blue absorbance change in the colorimetric tube (AA572; absorbance change at a wavelength of 572 nm). (2-B); disclosure of embodiment (Example 3)

The amount of Pt reference solution added in the solution containing Μβ-hydrogen dissolved water (containing MB basic water 7.4 + degassing treatment + hydrogen encapsulation treatment) is only to make the platinum colloid concentration 190 //g/L.

2030-5402-PF(Nl).ptd Page 44 1270532 V. Inventive Note (42) The water/liquid mixture has a methylene blue absorbance change (A 5 7 2 ) as Example 3, and the results are shown in Fig. 8 respectively. Figure 9. (Example 4) The amount of Pt reference liquid added in the solution containing MB hydrogen-containing water (containing basic water 9 〇 + degassing treatment + hydrogen encapsulation treatment) is only to make the platinum colloid concentration 19 〇" The blue absorbance change (A572) was taken as Example 4, and the results are shown in Fig. 8 in comparison with Example 3. Further, the water of each sample of Example 3 and Example 4 differs in pH (Example 5) In the Μβ-hydrogen-soluble water (including MB basic water 7.4 + degassing treatment + hydrogen sealing), the amount of Pt reference liquid added is only to make the platinum colloid concentration " "g/L, the liquid its sub- The blue absorbance change (A572) was taken as Example 5, and the result of the comparison of I ΐ Γ 3 is shown in Fig. 9. Further, each of the sample waters of Example 3 and Example 5 differs in the platinum colloid concentration. (Example 6) β-capacity water (including 0 basic water 7.4+ degassing treatment + hydrogen sealing) The amount of the quasi-liquid added is only the implementation of the palladium colloid concentration of 444 #g/L·M absorbance change (A572) Example 6, the result of the knife is not shown in Figure 10, Figure 11. (Example 7) Treatment / medium 3pH wind quasi-existing water (including 0 basic water 9. 〇 + degassing treatment + hydrogen seal population incorporation Example 6 and Example 7 2C30〇4〇2-PF(Nl).ptd Page 45 1270532: 'ΪΐΪ^(43) ' --------- The difference in the sample water is ΡΗ. (Example 8) The amount of the reference liquid containing MB hydrogen-soluble water (containing Μβ basic water 7.4 + degassing treatment + hydrogen sealing = tc, /, Pd) is only to make the winning body concentration 111 #g/ L #1 = liquid its methylene blue absorbance change (A572) as Example 8, and its comparison example 6 is shown in the figure. In addition, Example 6 differs from Example 8 sample water in that Colloidal concentration. (Example 9) In s Μβ gas-soluble water (including MB basic water 7.4 + degassing treatment + hydrogen sealing

Γ ^中, + Add Pt reference solution and 1^ reference solution with molar ratio of about 1 mixed solution, water solution 'to make the mixed solution only add the precious metal (platinum +, 'colloid> length 1 6〇^ g/L, the aqueous solution indigo absorbance change 7 2 ) is shown in Example 9, and the results are shown in Fig. 1 and Fig. 3, respectively. (Example 1 〇) In the MB-containing water-soluble water (containing MB basic water 9.0 + degassing treatment + hydrogen sealing 1), the same mixed solution as in Example 9 was added to form an aqueous solution, and the mixed oral liquid was added for only The precious metal mixed (platinum + palladium) colloid concentration is 〆g 'the water ^ liquid liquid indigo blue absorbance change (A572) as Example 1,

The comparison between Fig. 9 and Fig. 9 is shown in Fig. 12. Further, Example 9 differs from the sample water of Example 1 in that it is different. (Example 1 1 ) In a solution containing MB hydrogen-containing water (containing hydrazine base water 7.4 + degassing treatment + hydrogen gas-filled ground), the same mixed solution as that of Bayer's Example 9 was forced into an aqueous solution to cause mixing. /Into the liquid addition, only the precious metal is mixed (platinum + palladium) colloid concentration is 8 0 //

2030-5402-PF(Nl).ptd Page 46 1270532 V. Inventive Note (44) g/L, the aqueous solution methylene blue absorbance change (A572) is taken as Example 11, and the result is shown in comparison with Example 9. 1 3 picture. Further, the difference between the water of each sample of Example 6 and Example 8 lies in the colloidal concentration of noble metal (platinum + palladium). (2 - C); Investigation of Examples Comparative Example 3, Figure 8 of Figure 8 shows that MB-reducing water is added to the hydrogen-soluble water of the platinum colloid added with ρΗ7·4 and ρΗ9·0. According to the same figure, it is not seen that the MB reducing activity due to the difference in pH is greatly different, and both show high MB reducing activity. In the ninth embodiment of Comparative Examples 3 and 5, in the platinum colloid concentration of 95 //g/L and 95 // g/L, the hydrogen-soluble water added to the surface colloid showed MB reducing activity. According to this figure, the MB reduction activity also becomes high when the concentration of the colloid is high. This can be considered to be effective in improving the concentration of the platinum colloid when the MB is to be used. _ , = The first graph of the examples 6 and 7 shows the MB reducing activity in the nitrogen-soluble water of the platinum colloid added with ρΗ7·4 and ρΗ9·0. According to the same figure, it can not be seen that there is a big difference in MB reduction activity due to "not, and both show high Μβ ^ K. Examples 6 and 8 of Figure 11 in platinum colloid concentration 11 1 #g /L· and # 8 a, the hydrogen-dissolved water to which the palladium colloid was added showed MB reducing activity. According to ^ : MB reduction activity is also high when the concentration of dicha colloid is high. This can be considered to be effective in increasing the palladium colloid concentration when the secondary activity is increased. In the eleventh figure of the metal examples 9, 10, the hydrogen-dissolved water of the colloidal body of the pH 7.4 and the addition of ρΗ9·〇 has a hydrazine reduction activity. The reduction activity of the ruthenium produced by the difference of 3 is very different, and both of them have no high MB reduction activity.

2C50〇-i〇2-PF(Nl).ptd Page 47 1270532 V. Inventive Note (45) Comparative Example 9, 11 of Figure 1 3 in Precious Metal Mixed (Platinum + Palladium) Colloidal Concentration 80 /zg / L And 160/zg/L of the precious metal mixed (platinum + palladium) colloidal hydrogen-dissolved water showed MB reducing activity. According to this figure, the MB reduction activity also becomes high when the precious metal mixed (platinum + palladium) colloid concentration is high. This is considered to be effective in increasing the colloidal concentration of the noble metal mixed (platinum + palladium) in order to increase the MB reducing activity.

Further, comparing Fig. 8 (Examples 3 and 4; MB reduction activity of adding platinum colloidal hydrogen-dissolved water) with the second diagram (Examples 6, 7; MB reduction activity of adding palladium colloidal hydrogen-dissolved water) It can be understood that although the concentrations of Examples 3 and 4 are lower, the MB reduction activities equivalent to those of Examples 6 and 7 are shown. Furthermore, if the molar concentration (/ζΜ) of the two is compared, the colloid is 0·98 and the colloid is 4 · 1 7 /ζ Μ, which is lower in platinum colloid. Thus, it can be said that the platinum colloid is superior to the palladium colloid in that the desired MB reduction activity of the noble metal catalyst of the present invention is obtained by obtaining the same MB reduction activity.

On the other hand, Figure 8 (Examples 3 and 4; addition of MB-reducing activity of platinum colloidal hydrogen-dissolved water) and Figure 2 (Example 9, 1 〇; mixed precious metal mixed (face + handle) colloid Comparing with the reduction activity of hydrogen-soluble water, it can be understood that both of them show good MB reduction activity. Comparing the molar concentrations (#M) of the two, the platinum colloid is 〇 · 9 8 // Μ and the precious metal mixed (platinum + palladium) colloid is 丨〇 7 Μ ‘ both are about the same. Thus, the noble metal of the present invention is converted into a two-body; the activity can be said to be mixed with a precious metal (refilling) gel 2 2 Γ f blue color change is added to the platinum colloidal catalyst electrolytic treatment water (before electrolysis treatment) Reduction activity after addition/electrolysis treatment)

2030-5402-PF(Nl).ptd Page 48 1270532 V. INSTRUCTIONS (46) (3-A); Reductive force evaluation test procedure The basic water of 6.86 2000 mL is prepared in the same manner as in (1 - A) above, and 4 mL of the Pt reference solution was added to 1000 mL of the solution to prepare a basic solution of platinum-containing colloids of about 6.86 liters. In addition, 1000mL should not be added to the initial colloid. Accordingly, the basic water containing no starting colloid is prepared to be 6.86 to 1 liter, and the basic water containing the tumbling body is 6 · 8 6 to 1 liter. - Secondly, the two samples were separately electrolyzed to obtain electrolytically treated water (gas-soluble water), which only took 2 · 8 6 m L, and was put into a quartz colorimetric tube that had been previously replaced with hydrogen, and then measured as a Pt standard. The methylene blue absorbance change (AA5 7 2; absorbance change at a wavelength of 572 ηπ) when the mixed solution of the liquid, the Pd reference solution, the pt reference solution, and the Pd reference liquid molar ratio is added to the quartz ratio _ color tube. Then, only lg/L〇·14 mL of the aqueous solution of indigo blue which had been previously degassed and hydrogenated was added to the colorimetric tube of the non-colloidal colloid. Place the two colorimetric tubes in the spectrophotometer and stand by. In the case of a platinum-free colloidal colorimetric tube, the concentration is 48 mg/L, and the body solution 2 "L, $ is added to the colorimetric tube containing the platinum colloid. The blue solution is 1 g/L0. 14mL, and start using

Body i; 2 2 about colorimetric solution. Further, the conjugate of the conjugate which is added to the two colorimetric tubes is about 182/zg/L. (3-B); Revelation of the Example (Example 1 2) Adding the borrowing/μ7 to add the sagittal body) in the =彳 electrolytic treatment of water (containing bismuth basic water "6+electrolysis" 疋 began to 30 points Azure blue absorbance

1270532

1270532 V. INSTRUCTION OF THE INVENTION (48) Similarly, it is preferable to add a catalyst before the treatment from the viewpoint of obtaining a higher MB reducing activity. (4) Evaluation of the antioxidant activity of the electroplated water treated with platinum colloidal catalyst by changing the color change of the DPPH radical (4 - A ); the test procedure for evaluating the antioxidant activity is the same as that of the above-mentioned (1-A) Check the antioxidant activity of each of the 8 samples of sample i~viii shown in Table 2. Add 16 mL of DPPH (0.16 g/L concentration) solution to 16 mL of an aqueous solution to adjust the DPPH molar concentration to 81. 1 5 ( // M), and after adding DPPH 3 minutes, the DPPH absorbance change (ΛΑδΜ; absorbance change at a wavelength of 54 0 nm) of each sample aqueous solution was measured by a spectrophotometer. (4 - B); Reference Example and Disclosure of Reference Example (Reference Example 7) The difference in DPPH absorbance (ΔASW) of the aqueous solution after adding DPPH to the aqueous solution of sample water without adding catalyst (basic water 6 · 8 6 ) was taken as Referring to Example 7, the results are shown in Fig. 15. Further, the DPPH absorbance change (Δ A 5 4 0 ) in the same figure indicates the absorbance with respect to the sample 丨 (background value), and the difference in absorbance between the samples i to viii (^^540). Therefore, the DPPH absorbance change (ΔΑ540) of Reference Example 7 was zero. (Reference Example 8) The DPPH absorbance of the aqueous solution obtained by adding DPPH to the aqueous solution of the sample water (basic water 6·8 6 + pt) was changed as Reference Example 8, and the results are shown in Fig. 15. Reference example 9)

2030-5402-PF(Nl).ptd Page 51 1270532 * ---- V. Description of invention (49) " ------ Electrolytic treatment of water with no added catalyst for sample water 11 i (basic water 6 86+ Electrolytic treatment) The DPPH absorbance change (ΛΑδΑΟ) of the aqueous solution after the addition of DPPH was designated as Reference Example 9, and the results are shown in Fig. 15. (Example 1 4) The DppH absorbance k (ΔΑ540) of the aqueous solution obtained by adding DppH to the electrolytically treated water (basic water 6.86 + electrolytic treatment + Pt standard solution) of the sample water 1 ν was taken as Example 14, The results are compared with Reference Examples 7 to 9, and are shown in Fig. 15. (Reference example 1 0)

The DppH absorbance change of the aqueous solution after adding DPPH to the sample water v without adding catalyst electrolyzed water (basic water 9.18) (as a reference example ίο, the result is shown in Fig. 16. Again, the same figure tDPPH absorbance change ( ΔA540) indicates the absorbance of the sample v (background value) and the absorbance difference (AAWO) of the samples i to viii. Therefore, the change in absorbance (ΔΑ540) of Reference Example 1 is 〇 (Reference Example 11).

The DPPH absorbance change (ΔA540) of the aqueous solution obtained by adding DPPH to the catalyst water (basic water 9, 18 + p t standard solution) added to the sample water v i was used as a reference example 11', and the result is shown in Fig. (Reference Example 1 2) The DppH absorbance change (ΔA540) of the aqueous solution after adding DPPH to the sample water vii without added catalyst electrolyzed water (basic water 9·18 + electrolytic treatment) was used as a reference example 12 ' Figure μ. (Embodiment 1 5)

2030-5402-PF(Nl).Ptd Page 52 1270532 V. Inventions (50) After adding DPPH to the electrolytically treated water (basic water 9·18+electrolytic treatment + Pt standard solution) of sample water viii The DppH absorbance change (?A540) of the aqueous solution was taken as Example 15, and the results were compared with Reference Examples 10 to 12 and shown in Fig. 16. (4-C); Investigation of the examples

Comparing the results of Examples 1 and 4 with Reference Examples 7 to 12 and examining the addition of catalyst electrolyzed water of Examples 14 and 15 in both basic water 6.86 and basic water 9·18, and reference examples Comparison of 7 to 12 shows that the DPPH radical-specific elimination and non-small antioxidant activity or radical elimination activity. Incidentally, the platinum colloidal catalyst is added before the electrolytic treatment. Further, as shown in Fig. 5, the reference example 9 is considered to have DPPH radical elimination activity although it is treated with no added catalyst electrolyzed water. This is considered to suggest that in the electrolytically treated water having a high concentration of hydrogen, depending on the pH and the like, it is expected that the antioxidant activity can be exhibited even without the catalyst. (5) Evaluation of antioxidant activity of the catalyst with hydrogen addition of D P P Η free radical (gas removal treatment + hydrogen encapsulation treatment) (5 - A ); evaluation procedure of antioxidant activity evaluation

Prepare "Basic Water 74" and "Basic Water 9 〇" in the same manner as in the above (2-A). Then, take 40 6 DPPH solution and 5 〇 mL each of the basic water 7 4 and 9.0 9.0 to degas the vacuum pump. Repeat 1 / 7 after 1 = = The purpose of this operation is to remove the degassing in the gas-soluble water: basic water 7.4 and basic water 9 ·. two

1270532 V. INSTRUCTIONS (51) Quartz colorimetric tube replaced with hydrogen gas, measured by spectrophotometer in the cross-eight-different measurement and not added in the same colorimetric tube. Reference: 2 points DPPH absorbance change (AA540; wavelength 54) The wavelength change at 〇nm is both (5 - B), and the disclosure of the examples (Reference Example 1 3) is not strong = ΐ ί water (basic water 7.4 + degassing treatment + hydrogen encapsulation treatment) = plus y The aqueous solution of the reference solution has a change in absorbance of DppH (Μ Test 13, and the result is shown in Fig. 17. ^ As a reference (Example 16)

Pf beauty: ί dissolved water (basic water 7.4 + degassing treatment + hydrogen encapsulation treatment), the amount of soil quasi-liquid added is only to make the platinum colloid concentration 丨9{) its deleted absorbance change (Α54.) as implementation Example 16, the result: liquid example = indicated in the figure. Further, Reference Example 13 and Example 16:: The second point is whether or not a platinum colloid is added. (Reference Example 1 4) The absorbance change (Α540) of the DPPH of the aqueous solution of the I reference solution in the immersed water (basic water 9 〇 + degassing treatment + hydrogen encapsulation treatment) is taken as a reference example 1 4 ' Results are shown in the first 8 (Example 1 7) In the hydrogen-dissolved water (basic water 9 · 〇 + degassing treatment + hydrogen encapsulation treatment), the addition of 1 in the night is only an aqueous solution having a platinum colloid concentration of 190 "g/L, The change in absorbance (A54〇) was taken as Example 17, and the result was inconsistent with that of Reference Example 14 in Fig. 8. Further, the reference example was different from Example 7 in the presence or absence of the addition of a platinum colloid.

2030-5402-PF(Nl).ptd Page 54 1270532 V. Description of the Invention (52) (5 - C); Investigation of the Example: Addition: i::? Compared with Example 16, Figure 17 shows There is no added r r pH7.4, the hydrogen dissolved water has a clear time to determine the time. 0 points) 丄 ί = f f3 : 14 can only be seen in the colloidal examples 16, 17 observable: f production: DPPH radical elimination activity. Also == The secret of the secret color is the difference between the base and the activity. 4 It is seen that there is a difference in pH due to the deletion of water in the second; the example shows that the inactive molecular hydrogen in the chlorination of the present invention is exhibited: : The chemical price test contained in the hydrogen-dissolved water is added to the precious metal @,^性# price. Reduction activity evaluation Similarly, the reduction activity evaluation principle was used using the reduced oxidation color reduction activity because the I I was used as an antioxidant target. At this time, the same is true, so the repetition of the day is omitted; the dissolution of the precious metal colloidal catalyst has been described: Ϊ : : + / gas color change for the addition of the catalyst enzyme hydrogen kinase hydrogen (r; reduction of live 'di = 丄; reduction activity evaluation In the same way as the above (2-A), the standard is "〇", and the basic water is 4 4 and the water is 7.4", and the basic water is 9. U/L of the MB aqueous solution 4 mL; Add concentrated water 7.4 and basic water 9 〇. Complex a "clothing / Chen degree 121 · 7 mM containing MB basic 9 · 〇 each 5 〇 mL, with vacuum help,, ^, ^ take MB basic water L4 And the basic water ^ 'self degassing 10 points, repeated 3 times to enclose hydrogen

1270532 V Description of invention (53) 1 operation. Moreover, the purpose of this operation is to remove gas components other than hydrogen in the hydrogen-dissolved water. Further, the hydrokinase having a concentration of 125 was diluted 4 times with distilled water, and then it was put into a microcapsule for 1 mL, and nitrogen (inactive gas) was sealed in the same capsule to remove oxygen. According to the obtained, the leopard-based basic water 7.4 and the basic water 9·0 each obtained by completing the hydrogen gas are charged into a quartz colorimetric tube which has been previously subjected to hydrogen replacement in a closed state, and is measured and adjusted as described above. The change in absorbance of methylene blue when the hydrogen kinase solution is added to the colorimetric collimator of quartz (AA572). (6-B); Reference Example and Disclosure of Example (Example 18) To add hydrogen as prepared above in MB-containing hydrogen-containing water (containing mb basic water 7.4 + degassing treatment + hydrogen encapsulation treatment) The aqueous solution of the kinase solution 1 〇# L had a change in the absorbance of the indigo blue (A572) as Example 18, and the results are shown in Fig. 19. (Reference Example 1 5) The change in the absorbance of the indigo blue (Α5 72 ) as a reference in an aqueous solution containing no hydrogen kinase solution in the solution containing MB hydrogen-soluble water (containing Μβ basic water 7.4 + degassing treatment + hydrogen encapsulation treatment) Example 15, the results of which are shown in Fig. 19 in comparison with Example 18. Further, Example 丨8 differs from the sample water of Reference Example 5 in the presence or absence of the addition of a hydrogen kinase enzyme. (Example 1 9 ) The methylene blue absorbance change of an aqueous solution obtained by adding a hydrogen kinase solution 1 〇 # L prepared as described above to a solution containing MB hydrogen-soluble water (containing Μβ basic water 9. degassing treatment + hydrogen sealing treatment) Α 572 ) as Example 19, the results are shown in the

1270532 V. Description of invention (54) Figure 20. (Reference Example 1 6) Into the production of water in the solution of hydrogen-containing water (containing hydrazine basic water 9·0+ degassing treatment + hydrogen sealing (A572) hydrogenation kinase solution, the absorbance of the indigo blue 20 map. Further, the second test example 丨6, the result of which is shown in comparison with the embodiment 19 is that the presence or absence of hydrogen addition:::1 is different from the sample water of the reference example 16 in (6 - C); Investigate, the results of 9 can be compared with reference examples 15 and 16 and 1 5, 16 compared with ^ 1 : Adding catalyst hydrogen dissolved water and reference example reduction, and only add force = 沦 its PH difference It can be used for the specificity of methylene blue. In addition, it shows high reductive activity for the gas in the J J agent. In the case of Example 18, 1 9 = whether the solution is blue or not, it is only visually confirmed. The hydrogen-dissolved water of the catalyst of methylene blue is colorless and transparent, and it can be seen that the color of methylene blue is lost, and the test of the kite is not able to dissolve the water by visual observation; the target; f. Example ^, 19 added catalyst blue). It is confirmed by the eyes that there are a large number of white sediments (reduced type of concentrating 广 詈 詈 电解 电解 电解 电解 电解 ( ( ( ( ( ( ( ( ( ( ( 开发 开发 开发 开发 开发 开发 开发 开发 开发 开发 开发 开发 开发 开发 开发 开发 开发 开发 开发 开发 开发 开发The reason why the nitrogen in the cathodic reaction wave is dissolved can be used to determine how much U is in the exhaust gas meter __ but here is the total

2030-5402-PF(Nl).ptd Page 57 1270532 V. Description of the invention (55) The measurement is generally due to the fact that the amount of hydrogen stored in the meter is converted into an external factor such as the determination of water and liquidity. The oxidation of water without oxidation is added to the oxidized type of indigo, etc., and the addition of the presenting agent, which is unique to the electrolyzed treatment water, can show that the pigment is redoxed in the reduction reaction, and the oxidative reaction is carried out. It is found that the reddish dyed blue is added to the electrolyzed water of the test reagent repeatedly, and the redox dye added by adding the catalyst is compared with the redox dye methylene blue of the latter. From this point of view, the inventors and the like have thought of adding a catalyst (dissolved nitrogen concentration) by quantitative analysis by oxidation. (B) Experimental purpose The measurement principle of the concentration of hydrogen dissolved in the electrochemical substance in the electrolysis reaction depends on the deviation of the measured value. In the description of the examples, the catalyst is electrolyzed without adding a catalytically added catalyst, and the pigment does not change color even if the original dye (antioxidation target) is added. On the other hand, if the catalyst is added to the electrolytic treatment water, the pigment is added. , the reaction color changes uniquely. In other words, the oxidation is also observed by observation (the color change of the electrolysis liquid to which the catalyst is added is observed. In the examination, the inventors noticed that the addition of the catalytic holding power is greater, the more the redox pigment subcolor change reaction proceeds. The tendency of fasting. The solution of the water to maintain the reducing power and the reducing power to be used to reduce the total reduction of f blue, the difference between the magnitude of the reduction force and the 1 & 'change reaction speed seems to have some kind of Related, industrial utilization, after deliberate research, the redox reaction of the reduced pigment, whether it can be electrolytically treated with water has obvious antioxidant power

1270532 V. INSTRUCTIONS (56) It is confirmed by the following experiment that the solution containing hydrogen dissolved in a predetermined concentration of oxidized or chemically treated water no longer shows a reduction color reaction, until ^', until the drop The scale of quantitative analysis. Coincidence of cold oxygen storage (potential antioxidant power) (c) Quantitative analysis method of dissolved hydrogen concentration in effect is the analysis of the effective amount of catalyst added to Taihuan (antioxidant power), that is, the quantitative 1 ^ The original force = go: as a catalyst, in addition, with indigo blue as oxygen blue redox titration. 〃 ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) Catalyst (platinum colloid): quotient; treatment under the droplet of methylene blue. Moreover, the correlation between the effective value of the dissolved hydrogen concentration obtained from the total methylene blue and the shellfish value obtained by the dissolved hydrogen meter is compared. Quantitative::: ί has t目关', it can be considered that the methylene blue redox titration is the concentration of the T: the concentration 'and the key substance that shows the antioxidant function is Luo Cunzhen, can be Objectively and properly verified. The material, production depends on the quantity, first, prepare to be prepared as the Pt reference liquid 4 〇 ΐ ί = ρ times Handu Pt reference liquid. The 40 times concentration pt reference liquid molybdenum into two / chen and t ) is calculated by the formula C(Pt) = 24gx 0.04/500mL

2030-5402-PF(Nl).ptd Page 59 1270532

192 mg / L 〇 Next, prepare lg / L concentration (volume molar concentration; 2677 4 / 1 〇 曱 曱 blue water > gluten and l 〇 g / L concentration (volume concentration; 26773 · 8 Asia A blue aqueous solution. Two different concentrations of methylene blue are prepared here because a solution of different methylene blue concentration is added according to the hypothetical determination of the concentration of hydrogen dissolved in water: to reduce the addition amount of the solution, and as a result, an experiment can be expected However, the platinum concentration of the Pt reference liquid and the MB concentration of the methylene blue aqueous solution are not limited thereto, and may be appropriately adjusted depending on the hydrogen concentration which is supposedly dissolved in the water to be measured.

Next, '50 mL of the 40-fold concentration pt reference solution prepared as described above and 5 mL of each of the two kinds of methylene blue aqueous solutions having different concentrations, respectively, were taken into separate degassing bottles, and then degassed by a vacuum pump for 1 minute. The nitrogen encapsulation operation was repeated to prepare a 4 〇 concentration pt reference solution and a methylene blue aqueous solution after nitrogen substitution. The purpose of this operation is to remove gas components other than nitrogen (inactive gas) in each solution.

Next, 200 mL of the water to be measured was placed in an airtightness tester made of acrylic together with a stirrer for a magnetic stirrer. The tester was fabricated for the purpose of the experiment. The structure is a piston-type sealing structure, and the circular plate is made of acrylic at the end of one end in the direction of the long axis of the cylindrical hollow tube made of acrylic. In order to form the bottom surface, the open side is freely movable in the long axis direction by a pin formed by a very small diameter circular plate which is smaller than the inner diameter of the tube. The side wall of the tester is such that the bottom of the tester is separated from the bottom side, the inner side wall and the detents of the water to be tested, and the external environment is injected into the 40-fold concentration Pt reference liquid or ΜB in an isolated state. The solution 'in the tester is placed outward in the radial direction by pressure

2030-5402-PF(Nl).ptd Page 60 Ϊ270532

The hollow tube is a fixed-water Pt chamber in which the syringe needle is removed according to the composition of the syringe, and the syringe is used as the most suitable stone storage chamber. The test state for the insertion is such that the indoor production can seal the reference liquid system, and the needle of the lysing needle can be quieted. The outer chamber can be protected. The external loop can be operated by the solution of the rubber stopper. The isolation and the indigo blue liquid should be injected into the ground as much as possible, and the mixture should be stirred as long as it can be placed in the environment, the airtightness, and the isolation. The 40-fold concentrated water storage chamber that has been replaced by nitrogen is fully stirred, and the amount of the aqueous solution is reduced when the amount of the syringe is increased by a small amount of the concentration of the syringe.增五、发明说明(58) The cylinder-shaped liquid injection part of the gram force cylinder is designed to put the water to be measured into the water state in which the tester is not subjected to the test. In addition, when the rubber to be measured is taken in the gas phase of 40°, the tester disclosed is only gas, the volume of water to be measured is variable, and the Pt reference liquid or mb water storage chamber is tested. The other containers are stirred, and the mixing table is applied to the upper mixing tray, and then the upper tube is injected into the test tube, and then the upper side is visually measured for the dissolved hydrogen in the water to be colorless, but the sub-injection portion. Moreover, the solution can be freely inserted and removed. It will be installed after the quiet filling in the water storage chamber. Therefore, the test solution for the external environment is used to test the liquid in the solution injection portion. In addition, the raw material in the space is not allowed to pass through. The measured water storage chamber is liquid-tight and the temperature is 40 times. The conditions are measured. The magnetic Pt reference liquid imL can also be placed under the bottom surface. An aqueous solution of indigo blue is injected successively. If it is reduced by 'Methylene Blue', it will be added.

1270532 V. INSTRUCTIONS (59) The dissolved hydrogen in the indigo and the water to be measured will be offset from each other. In the end, it will not be observed that the indigo blue changes from blue to colorless. At this time, J: From the concentration of methylene blue of the blue aqueous solution and the combined yttrium of the methylene blue water J solution, the dissolved hydrogen concentration of the water to be measured 汕 can be obtained. (E) The effective dissolved hydrogen concentration In the method of adding 'ϊ, the addition of ϊ to the aqueous solution of methylene blue in the water to be measured indicates the calculation formula of the measured water + ° and the derivative of the calculation formula: the meaning of the hydrogen storage concentration 卯DH. The dissolved hydrogen concentration m Ϊ ί, ί I in the description of the measured water volume is set to 200mL, plus the measured water of the methylene blue aqueous solution 1 Aa 曱 the A / fnnl / τ, $ ^ from eight ^ Τ The concentration of the base volume is set to N ( //mol/L). In addition, the total amount of the solution is A (mL) until the equivalent point is reached, then the methylene blue is added to the 1 The total B (mol) of the knife is changed to B = N · A ( //mol / L x mL) = N · A (m / zmo 1) · (1) - J will: the chemical formula of the alpha f molecule For MBC1, the chemical formula of the hydrogen molecule = the reaction of the colloid-activated hydrogen molecule with the methylene blue molecule in aqueous solution can be expressed by the following reaction formula 1. H2 + MBC1 - HC1 + MBH · (Reaction 1) ,〗 ΐΐ Salt ; for the reduction of methylene blue. According to the reaction formula 1 '1 Moer molecule and 1 More armor; f punishment & Tian Hao eight 2, fighting reaction, will generate 1 Mo's original i- Supervise the knife. To illustrate the separation of the electronic transfer type into two, as follows: Word reaction with + reaction

1270532 1. Invention description (60) "" --- H2 - H+ + (H+ + 2e-) ···(semi-reactive formula i) MB+ + (『+ 2e〇— MBH ··•(semi-reactive 2) The meaning of the semi-reactive formula 1 is that the hydrogen molecule emits 2 moles of electrons, and the meaning of the reaction formula 2 is methylene blue cations, ie, methylene blue 1 mole, which accepts 2 moles of electrons. At the point, the A molecule i Mo is 2 gram equivalent because of the Mo Er electron, but the methylene blue cation is Mo, ie, the methylene blue 1 Mo, because it accepts 2 Mo Er, it is 2 g. The result is that the hydrogen knife and the yttrium blue cation, that is, the gram equivalent of methylene blue, are both the same, so the reaction between the hydrogen molecule and the methylene blue molecule in the molar ratio is 丨Accordingly, the total amount of methylene blue added to the above-mentioned water to be measured is also the total amount of hydrogen molecules consumed. Therefore, by setting the total amount of hydrogen molecules to be tested (m # mo 1) to c, the formula 1 is obtained. OB = N · A (m //mo 1 ) · (2) In addition, the volume of water to be measured is 200 mL, and the molar concentration of water in the measured water is H2 (mol/L). Molar number C (mol) divided by volume (m The value of L) is obtained. H2(mol/L)-C/20 0 (m //mol/mL) -C/200 ( //mol/L) · (3) Further, the unit is converted into mass At the concentration (g/L), if the concentration of hydrogen molecules is equivalent to D, then the hydrogen molecule H2 is substituted in the formula of 1 mol / 2 g of diH 2 (mmol / L) / D (Expression 4). 4

2030-5402-PF(Nl).ptd Page 63 1270532 V. Description of invention (61) D 2C/200 C //g/L) = C/ 1 00 (// g/L)... (Formula 5) This is the mass concentration of the effective hydrogen molecule contained in 200 mL of water to be measured. Further, the mass concentration of the above-mentioned effective hydrogen molecule is in the order of micrograms, but if it is converted to the milligram level, it is sufficient to multiply the numerator and the denominator by 1 〇 〇 。. D = C · 1 0 00 / 1 00 - 1 000 (mg/L) = C · 1 Ο -5 (mg/L) ... (Formula 6) So [due to the relationship of Equation 2, the hydrogen molecule of Formula 6 The number of ears c can be replaced by the total amount B of methylene blue, so Equation 7 will be established. D = N · A (m / mol) l 〇 -5 (nig / L) · · · (Formula 7) * From Equation 7, you can understand the mass of the effective hydrogen molecule contained in the water to be measured ί ^ ^ ^ ^ ^ ^ ^ ^N(mm〇l/L) , The total amount of methylene blue aqueous solution (mL) to be added by U. However, in the water to be measured, not only is there a solution for quantification of the knife, but also a variety of ions and oxygen molecules (Yin Zi, Xenon Carbon (carbonated gas), etc.), in which the spleen, sputum, and scorpion knives (虱 rolling) or the name of the substance of the second oxidation; tongue] water and redox reaction phase acid salt and hypochlorous acid, etc.;; = oxygen molecule, owe chlorous acid as an oxidant, except in part by emulsification reduction In the reaction, it is usually the main one. In particular, as described here, sub:; the lower part is not used as a reducing agent: it is used as an oxidizing agent, and does not cause; in the reduction test, the oxygen atom blue oxidation becomes oxidized type Blue. 7 encounters the original, but will reduce the methylene blue of the reduced methylene original, although it is activated by the molecular hydrogen. It exists as it is, but it is used to 'or white: _一__ Special /, storage, will be reduced 2030-5402-PF (Nl).ptd page 64 1270532 V, invention description (62) methylene blue is again oxidized back to the original oxidized methylene blue. Also, because even Hydrogen molecules that do not pass through methylene blue^ will also react directly with oxygen, etc. The equivalent hydrogen molecule has a reducing power, so that a considerable amount of methylene blue cannot be reduced. That is, as shown in Fig. 21 and Fig. 22, when an oxide such as an oxygen molecule is coexisted in the hydrogen-dissolved water, a considerable amount of hydrogen is present. The molecular weight will be consumed, and the total amount of methylene blue added to the equivalent point will decrease with the amount of oxide. If this is considered, the dissolved hydrogen concentration measured by the quantitative analysis method of methylene blue can be said to be subtracted. The effective dissolved hydrogen concentration after the hydrogen concentration of the portion consumed by the oxidant such as oxygen is dissolved. & (F) Reference example and the disclosure of the examples (Reference Example 1

Alkaline electrolyzed water after continuous electrolysis treatment using electrolysis conditions of electrolysis range "4" at a standard amount of water using a "mini-wate" (with activated carbon filter) manufactured by Metz Co., Ltd. In the water, the above-mentioned nitrogen-replaced 40-times Pt reference liquid 1 mL was injected into the water-receiving chamber to be measured with a syringe, and the mixture was thoroughly stirred and mixed, and then the lg/L concentration was observed by visually observing the color change of the water to be measured. Volumetric molar concentration; 26 77· 4 #M) The aqueous solution of indigo blue was injected into the water to be measured in a small amount in a syringe. The total injection amount of the aqueous methylene blue solution reached the equivalent point was 1 mL, and the measured value of the dissolved hydrogen concentration DH obtained by substituting each value into the above formula 7 was 〇·〇3 (mg/L). Reference Example 1 7 Water-related P Η, redox potential 〇rp (mv), electrical conductivity EC (mS/m), water temperature T (°C), dissolved oxygen concentration D〇 (mg/L) The measured value (mg/L) of the dissolved hydrogen concentration DH and the measured value (mg/L) of the dissolved hydrogen concentration DH obtained by substituting each value into the above formula 7 are shown in Table 3, and

Sa as 1270532 V. INSTRUCTIONS (63) The measured values and effective values are shown in Figure 23. Further, the same type of meter used in measuring various physical property values is the same as described above. (Reference example 1 8)

After the purified water of the Fujisawa City tap water is passed through the ion exchange tube made by the Uruguato Society, the hydrogen is bubbled and the temperature is cooled to 20 ° C to be used as the water to be measured. In the measured water 2 〇〇 mL, '1 mL of the 4 〇 concentration of the platinum colloid reference liquid substituted with nitrogen gas was injected into the water storage chamber to be measured with a syringe, and the mixture was thoroughly stirred and mixed, and then visually observed on one side. Under the change of color of water, a methylene blue aqueous solution having a concentration of 1 〇g / L (volume molar concentration; 2 6 7 7 3 · 8 μ Μ) was injected into the water to be measured in a small amount in a syringe. The total injectable amount of the aqueous methylene blue solution reached the equivalent point was 6.2 mL', and the value of the dissolved hydrogen concentration determined by substituting each value into the above formula 7 was 1.66 (mg/L). The various values of the water to be measured in Reference Example 19 are shown in Table 3' and the measured values and effective values of DH are shown in Fig. 23. (Example 20) The continuous water-passing electrolysis treatment was carried out under the electrolysis conditions of a fixed current of 5 A at a flow rate of 1 liter per minute of the sample water i, and the solution was treated as water to be measured. In the 2 mL of the water to be measured, 1 mL of the platinum colloidal reference liquid of 4 〇 times the amount of the above-mentioned nitrogen-substituted reference water was injected into the water storage chamber with a syringe, and the mixture was thoroughly stirred and mixed, and then visually observed on one side. Under the change of the color of the measured water, a methylene blue aqueous solution having a concentration of l〇g/L·volume (volume molar concentration; 26 773·8 /zM) was injected into the water in a small amount in a syringe. The total injection of the methylene blue aqueous solution up to the equivalent point is 9 mL, and the value of the dissolved hydrogen concentration dh obtained by substituting each value into the above formula 7 is 1270532. 5. The invention description (64) has a value of 1.58. (mg/L). The various physical property values of the water to be measured in Reference Example 20 are shown in Table 3, and the measured values and effective values of DH are shown in Fig. 23. (Example 2 1 ) Electrolyzed water subjected to continuous water-passing electrolytic treatment under the electrolysis condition of 5 A fixed current at a flow rate of 1 liter per minute of the sample water v as the water to be measured In the 2 mL of the water to be measured, 1 mL of the 40-fold concentration of the platinum colloid reference liquid, which was replaced with nitrogen, was injected into the water-receiving chamber to be measured with a syringe, and the mixture was thoroughly stirred and mixed, and then visually observed on one side. Under the change of color of water, a methylene blue aqueous solution having a concentration of 1 〇g/L (volume molar concentration; 2 6 7 7 3 · 8 // Μ) was injected into the water to be measured in a small amount in a syringe. The total injection amount of the aqueous methylene blue solution reached the equivalent point was 5 · OmL, and the measured value of the dissolved hydrogen concentration obtained by substituting each value into the above formula 7 was 1 · 34 (mg/L). The various physical property values of the water to be measured in Reference Example 21 are shown in Table 3, and the measured values and effective values of DH are shown in Fig. 23. (Embodiment 2 2 )

The standard buffer prepared by Wako Pure Chemical Industries Co., Ltd. 4·〇1 (aqueous solution of citrate) was diluted 10 times with purified water, and the pH buffer was electrolyzed at a flow rate of 5 A per minute. Under the condition, the electrolyzed water after continuous water treatment is used as the water to be measured, and in the water to be measured 2 〇〇 mL : Ϊ ΐ = ” replaced 40 times the concentration of the colloid reference liquid syringe injection is measured After the water storage chamber is fully stirred and mixed, the color change of the measured water is visually observed on one side. 1 η / τ, the curve is .9β77, 8 ^ bar branching, 1〇g/L) The methylene blue aqueous solution with a small amount (volume molar concentration, 26773·8 = M) is injected into the water in a small amount with a syringe. The total injection amount of the aqueous solution of the same indigo blue is equivalent to ^

2030-5402-PF(Nl).ptd Page 67 1270532 V. Description of the invention (65) A 3 mL, and the value of the dissolved hydrogen obtained by substituting each value into the above formula 7 is 1.69 (mg/L). The reference water of each of the reference examples 22 is shown in Table 3, and the measured value and the effective value of the enthalpy are shown in the 23rd graph value (Example 23). The basic water of the sample water i is 6 86 per Circulating liters, 5 A fixed current under electrolysis conditions, continuous water circulation type (circulation, lower ^ think 〇 · 8 liters), electrolytic treatment of water after 3 minutes of electrolytic treatment for 7 = determination of water, and In the 2 mL of the water to be measured, 1 mL of the 40-fold concentration of the platinum colloid reference liquid, which was placed under a nitrogen gas, was injected into the water to be measured with a syringe, and the mixture was stirred and mixed, and the water to be measured was visually observed on one side. Under the pressure, the concentration of 10g / L (volume concentration; 26773 · 8 "M) = aqueous solution into the water to be measured in a small amount of syringe. To reach the equivalent point: with the Asian water / valley The total amount of liquid injected is g · 6 [, and the measured value of the dissolved hydrogen concentration Μ obtained by substituting each value into the above formula 7 is 2 57 (mg/L). This reference example 23 measures various physical properties related to water. The values are shown in Table 3, and each measured value and effective value is shown in Fig. 2, (Example 2 4) Basic water of water v 9·18 Circulating electrolyzed water after electrolytic treatment for 3 minutes at a flow rate of 1 liter per minute at a constant current of 5 A in a continuous water circulation type (circulating water volume of 〇·8 liters) In the measured water 2 〇〇m] L, the above-mentioned nitrogen-substituted 40-fold concentration colloid reference liquid 丨mL is injected into the water-receiving chamber to be sufficiently stirred and mixed by a syringe. 'On the one side, visually observe the color change of the water to be measured', the molecular weight of 10g / L (volume concentration; 26773.8 / ^) of methylene blue

2030-5402-PF(Nl).ptd Page 68 1270532 V. INSTRUCTIONS (66) The aqueous solution is injected into the water to be measured in a small amount by a syringe. The total injection amount of the aqueous methylene blue solution reached the equivalent point was 12.3 mL, and the measured value of the dissolved hydrogen concentration DH obtained by substituting each value into the above formula 7 was 3·29 (mg/L). The various physical property values associated with the water measured in Reference Example 24 are shown in Table 3, and the measured values and effective values of DH are shown in Fig. 2 . (Example 2 5) The same pH buffer aqueous solution as in Example 2 2 was subjected to a continuous water circulation type (circulating water amount of 0·8 liter) under an electrolysis condition of 5 A fixed current at a flow rate of 1 liter per minute. The circulating electrolyzed water after the minute electrolysis treatment is used as the water to be measured, and 1 mL of the 40-fold concentration of the platinum colloid reference liquid substituted with nitrogen gas is injected into the water to be measured by the syringe in the water to be measured. After the chamber was thoroughly stirred and mixed, the aqueous solution of indigo blue at a concentration of l〇g/L (volume molar concentration; 26773.8 //M) was injected into the syringe in a small amount on the one side by visual observation of the color change of the water to be measured. It is measured in water. The total injection amount of the aqueous methylene blue solution reached the equivalent point was 12·4 mL, and the measured value of the dissolved hydrogen concentration DH obtained by substituting each value into the above formula 7 was 3·3 2 (mg/L). The various physical property values of the water to be measured in Reference Example 25 are shown in Table 3, and the measured values and effective values of DH are shown in Fig. 23.

2030-5402-PF(Nl).ptd Page 69 1270532

OBJECTS OF THE INVENTION (68) However, in the case of the present invention, the concentration can be increased as much as possible, and the dissolved hydrogen can be dissolved therein, as in the case of the application of the method. It is important in antioxidant activity. The degraded pigment is dissolved in hydrogen, and the dissolved water in Dingdan is determined by the oxidation viewpoint of the present invention. The effective value of the dissolved enthalpy concentration 求 is better, and further $ \X1 f '谷存水 has not been L3 or more DH effect Values above, u or above:; 9 two above: upper, 15 or more, 16 or more, u is 2.3 or more, 2.4 or more, 2\, 2.0 or more, 2.1 or more, 2.2 or more, upper, 2. 9 or more, 3 or more / 2.6, j, 2.7 or more, 2.8 in place are me/M order.1 or more, 3. upper, 3.3 or more (single good. ^), and the higher the effective value of dissolved hydrogen concentration DH, the more antioxidant The machine-I is expected to combine the hydrogen-dissolved water of the present invention with a catalyst. The reduction activity and antioxidant activity of the present invention can exhibit high denier and eight soils = for hydrogen concentration in hydrogen-dissolved water containing electrolytically treated water = Two kilograms/and the same hydrogen-soluble water have significant antioxidant capacity re-raise = t two and two relative to the dissolved hydrogen concentration in the existing dissolved hydrogen meter = 1, the measurement step or treatment reported cumbersome and measured At the point of accuracy, it is not sufficient, i, and the cost is very high. The redox color II of the present invention is used. 'Bonding step quantification method of measuring deposit money of hydrogen or a relatively simple process, and: oxidizing species can be removed to be measured contained in the water, because the number of particles with the chemical through the molecular gas with the oxidation-reduction element on the accuracy of measurement

Page 71 1270532

The principle of direct quantitative analysis of the reaction is high precision and low cost. Further, the embodiments described above are described in order to facilitate understanding of the present invention and are not intended to limit the present invention. Therefore, each element disclosed in the above embodiments also includes all of the design two or equivalents belonging to the technical scope of the present invention. β β 欠 具体 具体 具体 具体 具体 具体 具体 具体 具体 具体 具体 具体 具体 具体 例如 具体 例如 例如 例如 例如 例如 例如 例如 例如 例如 例如 例如 例如 例如 例如 例如 例如 例如 例如 例如 例如 例如 例如 例如 例如 例如 例如 例如 例如 例如 例如 例如 例如 例如 氢氧化In the case where, for example, the Shishi substrate is used as an object of oxidation resistance, ultraviolet rays are applied to the reduction potential water, but the present invention is not limited to this embodiment. In other words, it is also possible to use a living body cell as an antioxidant object to cause an electromagnetic wave containing ultraviolet rays to act on a reduction potential water or to combine an electromagnetic wave containing ultraviolet rays with a hydroxide reductase, a hydrogen kinase or a noble metal colloid to reduce potential water. Further, for example, when a ruthenium substrate is used as an anti-oxidation target, a hydroxide-reducing enzyme, a hydrogen kinase or a noble metal colloid is allowed to act on a reduction potential water, or a hydroxide-reducing enzyme, a hydrogen kinase or a noble metal colloid is combined with an electromagnetic wave containing ultraviolet rays to be reduced. Potential water is of course also possible. In the embodiment of the present invention, the reference example, or the description of the examples, the indigo blue is exemplified as the redox dye, but the redox dye is not limited to this example, and for example, new methylene blue or the like may be suitably used. Sexual red, indigocalmine, acid red, saffron, phenol red, capri blue, nalene blue, diphenylamine, xylene, nitrodiamine, etc. Ferroin, N-phenyl anthranilic acid, and the like. Finally, the antioxidant method of the present invention is suitable for, for example, treatment of a patient's disease

2030-5402-PF(Nl).ptd Page 72 1270532 V. INSTRUCTIONS (70) Modifications during treatment. Describe the treatment of hydrogen repression. First, an inventive catalyst solution such as a platinum colloid is fed through an injection or a drip operation at a portion of the patient's treatment target. Next, the patient is observed in the re-pressure chamber which is generally used for the treatment of phlegm and other snoring diseases, and the patient's appearance is observed from the inside or the outside, and the pressure of the re-compression chamber is gradually increased. At this time, the component partial pressure ratio of the gas supplied into the re-pressure chamber is adjusted to about 20% of hydrogen divination. And in the case of, for example, hydrogen gas, oxygen gas, nitrogen gas (other gas components, such as a very small amount of cold, partial pressure ratio, 2, 3, 3, and 3 atmospheres of absolute pressure) Looks like the patient is inside the room from the room, or the flower is longer than the time of the boost, slow (antioxidant), j, in the patient's body, the treatment of i,: to Γu, Through the patient's lung respiration or skin respiration, the strangeness of the 4th place (the bathing water) is recognized as the raw material - i禺, the material η, ♦ 4 and the catalyst that has been fed in advance will be in the middle of the body fluid ", the same The subject part is generally given to the electrons. According to the phase method of the part, it is expected that the material* 遨 卞 卞 丁 丁 Θ虱 Θ虱 Θ虱 Θ虱 Θ虱 * * * * * * * * * * * * 〜 〜 〜

Page 73 2030-5402.PF(Nl).ptd l27〇532 Brief description of the diagram Figure 1 shows the diagram of the Nielen-Site model. = An illustration of the lighting test sample. Fig. 3 is an explanatory view showing an application example of the present invention. Fig. 4 is a schematic view showing the use of the present cleaning system 100. The semiconductor substrate of the anti-oxidation method is shown in Fig. 5 to show the semi-conducting 本 本 逛 原 原 原 原 原 原 原 原 原 原 原 原 原 原 彳 彳 彳 彳 彳 彳 基板 基板 基板 基板 基板 基板 基板 基板 基板 基板 基板 基板 基板 基板 基板 基板In the form of a mica soil, it is a longitudinal section of the symplectic. Electrolytic treatment of the catalyst 1 | Color change is carried out by adding Pt colloid. The 8th to 9th diagrams show the addition of P t wins (4) to the change of color change in the methane storage of the methane: The figure of 10~U is shown as the result of the test of the H. H. The hydrogen-soluble water of the ruthenium catalyst is added to the color change of the decaying color. The Pdt gel is added to the 12th to 13th sheets to show the results of the evaluation of the activity of the original dryness and the original activity. (P just) colloidal blue color change to add precious gold fruit. Wind, trough water, its reduction activity evaluation test knot Figure 14 shows the 7-dot electrolytic treatment of water π color change to add Pt colloid The original activity evaluation test results are solved. The treatment is added / after the electrolytic treatment is added) The 15th to 16th diagrams are _ a pt ^ ^ catalytic L hydrogen: the map is:: the evaluation evaluation test results" (degassing ~ seal Into 2030-5402-PF(Nl).ptd Page 74 1270532

BRIEF DESCRIPTION OF THE DRAWINGS Fig. 19 to Fig. 20 are graphs showing the results of the evaluation of the activity of the hydrogen-soluble water (defluorination treatment + gas-sealing treatment) of the enzyme-added hydrogenase catalyst by the change of the color change of the ytterbium. 〃 $ Figure 2 1 to 2 2 is a method for quantitative analysis of dissolved hydrogen concentration by redox titration of redox pigment. Figure 2 3 is a comparison of the actual effect values of dissolved hydrogen concentrations (10) for various sample waters. ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, UV lamp; 2 1 , 2 3 ~ valve; 1 0 0 ~ semiconductor substrate cleaning system 112 ~ outlet; 1 1 4 ~ outer box; 11 6 ~ electrode plate; 2 0 1 ~ electrode; 2 0 5 ~ cathode chamber 20 9 ~ chamber; S ~ gap; 1 2 ~ DC power supply; 1 4 ~ pure water; 1 6 ~ treatment tank; 18 ~ cover; 2 〇 ~ hydrofluoric acid container; 22 ~ gas-liquid separation device; Π ~ introduction port; 1 1 3 ~ electrolysis chamber; 1 1_ 5 ~ diaphragm; 1 1 7 ~ electrode plate; 203 ~ diaphragm; 2 0 7 ~ anode chamber; 21 b LED.

Claims (1)

Sixth, the scope of application for patents is characterized in that, by the process of making the noble metal colloid, the decomposition reaction of the active hydrogen which forms the product in the hydrogen-dissolved water is promoted, and the oxidation state or the oxidation resistance is prevented. 1 . An anti-oxidation method in which a catalyst acts on a molecular hydrogen contained in a hydrogen-dissolved water as a matrix to reduce a target due to lack of electrons to an electron sufficient. 2. The antioxidant method according to the first aspect of the patent application, wherein The shell metal colloid includes uranium, plutonium, ruthenium, M ^ verbose, ruthenium, gold, silver, ruthenium and the salt of the noble powder, alloy compound, colloidal particles of the wrong compound or a mixture thereof. An anti-oxidation method according to the first aspect of the patent application, wherein the above-mentioned ϊ ΐΐ ΐΐ is that all of the water containing hydrogen' comprises alkaline electrolyzed water formed on the cathode side when the raw water is electrolyzed between the anode and the cathode through the separator, or In the raw water, the hydrogen is foamed (aerated) or even subjected to pressure filling treatment. 4, the anti-oxidation method of any one of the patent scopes, wherein the solution is a negative value. ORP, and corresponds to the pH value, the value is higher than that of the Nissan; ORP=_59pH_80 (mV):: The reduction potential water with a low P. 5. The anti-oxidation method according to item 4 of the patent application, wherein the reduction potential water system generates an electrolytic reduction potential water using a reduction potential water generating device, the reduction potential water generating device comprising: an electrolysis chamber for introducing the electrolyzed raw water , one or more diaphragms separating the electrolysis chamber from the electrolysis chamber, 1270532 The pair of plates are respectively disposed in the electrolysis chamber case No. 9Π371Μ6, between the inside and outside of the patent application range, and the power circuit 'the electrode set in the electrolysis chamber, the electrode plate provided in the electrolysis chamber' Instead, it is a negative voltage to form a power supply circuit. The two poles are interposed between the two electrodes, such as the electrode plates of the foregoing electrolysis chamber, which are in contact with or only intervene. The film system is set to be mutually 6. As described in the scope of the patent application, the hydrogen storage water is characterized by a normal temperature and a large-scale method, which uses a redox dye to hold a hydrogen concentration. Store water with a hydrogen content of 1.3 mg/L hydrogen concentration or more. In the above-mentioned hydrogen-dissolved water in any of the above-mentioned patent scopes, in the above-mentioned hydrogen-dissolved water, the acid salt, ascorbic acid, ascorbate a salt, thio Agent. A, at least one kind of reduction 8. As in the third paragraph of the patent application scope, the above-mentioned antioxidant object is a method of oxidizing the electrons by the electrons, and the entire object of the object is a living body cell. An anti-oxidant function water. A noble metal colloidal catalyst, which catalyzes the reaction of adding a matrix into the active hydrogen of the product in the valley water, because of the molecular hydrogen state or The anti-oxidation object to be oxidized is promoted by the aforementioned catalyst to oxidize an antioxidant function having a sufficient electron reduction state. Into the reaction, and 10. In the case of the anti-oxidation function water of item 9 of the patent scope, 1270532 ---- Case No. 91137152__一车贝__日修正 ____ 6. Patent scope = precious metal colloids including Gu, palladium, ruthenium, osmium, iridium, gold, silver, ruthenium and the salt of the precious metal The alloy compound, the colloidal particles of the wrong compound itself or a mixture thereof. ^ 1 1 · For the antioxidant function water of the 10th item of the patent application scope, wherein the nitrogen-dissolved water is all water containing hydrogen, including the cathode through the separator to electrolyze the raw water between the anode and the cathode. The alkaline electrolyzed water produced on the side, or the water in which the hydrogen is bubbled (aerated) or even pressurized and filled in the raw water. 12. The antioxidant water according to any one of the items 9 to 5, wherein the hydrogen-dissolved water system has a negative value of 〇Rp, and the 0RP value corresponding to pH is higher than the Nillent type. ; 〇 Rp = one "such as a "chemical" to obtain a lower value of the reduction potential water. 1, 3 · as claimed in the scope of the patent scope of the antioxidant water, the use of the aforementioned reduction potential water system The reduction potential water generating device generates electric/de-reduction potential water'. The reduction potential water generating device includes: an electrolysis chamber that is introduced into the electrolyzed raw water, and a separator that separates at least one or more electrodes in the electrolysis chamber and the electrolysis chamber. The pair of plates are respectively disposed between the foregoing diaphragms and the inside of the separators::: the electrode plates disposed in the electrolysis chamber are used as the dangerous poles, and the electrode plates provided for electrolysis to the outside are used as anodes, and the poles are a voltage to form a power supply circuit, 1 ^ force 17 wherein the electrode plate of the above-mentioned f-outset and the aforementioned diaphragm are set to each other 2030-5402-PFl(Nl).ptc Page 78 Ϊ270532 ------- Case No. 91137152____ VI. Patent application scope ^^-—Jfe Contact or only intervene in the gap v U·If the patent application scope is 9th Item ~ shang n hall 乂月 b water, which is the antioxidant machine l 3mg / L of any of the above-mentioned hydrogen storage water Tetbei (using redox pigment 22; J two temperature and atmospheric capacity) The actual value of the hydrogen concentration is more than the above. The quantitative analysis method of the gas is changed to 1 5 · As in the scope of the patent application, item 9 '~ the first water, the above-mentioned hydrogen-soluble water is based on the anti-oxidant salt and thio Sulfate, ascorbic acid = σ has a reducing agent containing sulfurous acid. Among the ascorbate groups, at least 16 · a biologically applicable liquid is selected, which is characterized by · γ g ^ / · 第 ^ ^ ^ 顼 乂 乂 乂 乂 乂 乂 乂 乂 乂 乂 乂 乂 乂 乂 乂 乂 乂 乂 乂邙 邙 ^ ^ ^ Feng main components, used for modulation. / Main shot, drip, dialysis, make-up 2030-5402-PFl(Nl).ptc第79页