1238083 A7 B7 五、發明説明（1 ) (請先閲讀背面之注意事項再填寫本頁) 本發明係有關被覆剝離型除濕劑，更詳細者係有關塡 入利用至少部份吸濕性物質之潮解性鹽，其表面呈難透濕 性薄膜，內側呈透濕性薄膜之雙重結構薄片之袋體，使用 時，將表面難透濕性薄膜剝離後被使用之被覆剝離型除濕 劑者。 先行技術中，提供塡入吸濕性物質於透濕性薄膜袋體 之除濕劑，而，此除濕劑之吸濕劑包裝務必充份小心者。 亦即，流通階段，若吸濕劑吸濕後，該商品價値將完全不 復存在，因此，該階段務必以難透濕性材料包裝吸濕.劑者 〇 此難透濕性材料之包裝以不同於製造除濕劑之另一步 驟進行。且被要求爲完整者，首先，以難透濕性包裝材料 作成袋子，將吸濕劑置入此袋中，再將袋口塞住之必要步 驟，惟，此步驟做爲除濕劑之成本太高。 因此，爲提供一種更經濟的除濕劑，被要求提供難透 濕性材料之包裝可以簡便之方法進行者。 經濟部智慧財產局員工消費合作社印製 本發明者爲解決該課題，進行硏討除濕劑製造之各步 驟後，發現，做爲先行除濕劑之透濕性薄膜所討論之厚度 2〇μ m〜5 0 // m之熱塑性透濕性聚胺酯薄膜，此中加 入聚醯胺或聚胺基酸取得薄膜，或於熱塑性透濕性之聚酯 中加入聚亞烷二醇後取得之薄膜其延伸率爲3 〇 〇 %以上 ，造成薄膜單獨時由薄膜滾輥抽出時薄膜已延伸，加工速 度，加工方法受限，欲使該薄膜封口部份不產生皺紋，順 暢進行塡充，製袋者爲極困難者。 -4- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 1238083 A7 B7 五、發明説明（2 ) (請先閲讀背面之注意事項再填寫本頁) 因此，本發明者發現如上述物性之薄膜通常藉由合倂 薄膜成型時成型薄膜兼袋體成型時之加工用薄膜（以下稱 成型-加工用薄膜）後，著重於加工後，利用熱塑性透濕 性薄膜之成型一做爲加工用薄膜之難透濕性薄膜後，亦可 使此於使用時進行剝離做爲難透濕性包裝者，進而完成本 發明。 亦即，本發明之特徵係爲提供一種塡入利用具有至少 一部份潮解性鹽類其表面呈難透濕性薄膜，內側呈透濕性 薄膜之雙重結構之薄片後所形成之袋體，剝離難透濕性薄 膜後再行使用之被覆剝離型除濕劑者。 〔圖面之簡單說明〕 第1圖係代表實施例1所製造之被覆剝離型除濕劑吸 濕量與經過日數相互關係之圖面者。 第2圖係代表實施例2所製造之被覆剝離型除濕劑吸 濕量與經過日數相互關係之圖面者。 經濟部智慧財產局員工消費合作社印製 第3圖係代表實施例3所製造之被覆剝離型除濕劑之 吸濕量與經過日數相互關係之圖面者。 第4圖係代表實施例4所製造之被覆剝離型除濕劑吸 濕量與經過日數相互關係之圖面者。 〔發明實施之最佳形態〕 本發明被覆剝離型除濕劑所使用之具有難透濕性薄膜 與透濕性薄膜之雙重結構薄片（以下稱「雙重結構薄片」 本紙張尺度適用中國國家標準（CNS ) A4規格（210'〆297公釐） _ 5 _ 1238083 A7 B7 五、發明説明（3 ) (請先閲讀背面之注意事項再填寫本頁) )係藉由使用如上述之透濕性薄膜成型時之做爲成型-力口 工用薄膜之難透濕性薄膜後取得者，而，並不限定僅此方 法者，利用做爲成型-加工用薄膜之非難透濕性薄膜後， 成型後剝離此薄膜，藉由後處理粘合另一難透濕性薄膜， 非難透濕性薄膜做爲成型-加工用薄膜使用後成型後，於 成型-加工用薄膜上面粘合難透濕性薄膜者亦可。 形成此雙重結構薄片之薄膜中，做爲透濕性薄膜者其 透濕度爲3 00g/m2，日以上者，特別是500〜 5 000 g/m2，日爲更佳。又，張力強度以200 kg · f/cm2 (〇 . 196Pa)以上者。 做爲具有此透濕度之薄膜者如：微多孔性薄膜，無孔 透濕性薄膜之例，而，微多孔薄膜由外部附著界面活性成 份時，降低表面張力，可能誘發滲出，因此，以無孔透濕 性薄膜爲較佳者。 做爲此無孔透濕性薄膜例者如：熱塑性尿烷薄膜、熱 塑性聚醚尿烷薄膜、熱塑性聚酯尿烷薄膜所成之薄膜例者 〇 經濟部智慧財產局員工消費合作社印製 又，於熱塑性聚胺酯或聚酯中加入改質劑後，所取得 之薄膜亦可使用之。具體之改質劑如：做爲添加於熱塑性 聚胺酯者之聚醯胺、聚胺基酸、褐藻酸之多價金屬鹽或親 水性有機天然微粉末等例，做爲添加於聚酯之改質劑之聚 環氧化物二醇等例者。 其中，做爲聚醯胺者如：聚醯胺基劑之共聚物、聚酯 醯胺、聚醚醯胺等例。又，做爲褐藻酸多價金屬鹽者如： 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） _ 6 _ 1238083 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明説明（4 ) 褐藻酸鈣、褐藻酸鋅、褐藻酸鈹、褐藻酸鋇、褐藻酸鎂、 褐藻酸鎘、褐藻酸汞、褐藻酸緦、褐藻酸鐳、褐藻酸鉛、 褐藻酸銅、褐藻酸鐵、褐藻酸鋁、褐藻酸鈷、褐藻酸鎳、 褐藻酸鉻、褐藻酸錳等例。 又，做爲親水性有機系天然微粉末者如：膠原類、海 綿粉、彈性素、角蛋白、絲粉、木棉、麻、紙漿、海藻等 例。更，做爲聚（環氧化物）二醇之例者如，聚四亞甲基 二醇、聚乙二醇、聚丙二醇等例。此等改質劑之添加量依 聚合物做適當選取之。 更且，亦可使用此等聚胺酯、聚酯及此等中添加改質 劑者與紙、不織布、符契、有孔聚薄膜相互粘合者，此等 聚胺酯、聚酯塗佈於紙、不織布等後，做成被膜化者。 取得該透濕性薄膜之方法並無特別限定，可利用先行 方法進行成型者。具體例如下記方法。 (1 )於熱塑性聚胺酯樹脂顆粒中混合1 0〜2 0 % 之聚醯胺顆粒後，藉由擠壓法（吹塑、澆鑄擠壓、共同擠 壓等）進行製膜（特開平5 - 1 1 5 4號公報）。做爲聚 醯胺之例者如：聚醯胺1 1 ( p A - 1 1 )、聚醯胺1 2 (P A — 1 2 )、聚醯胺 1 2 1 2 ( P A — 1 2 1 2 )被 利用之。 (2 )針對1 〇 〇份熱塑性聚胺酯樹脂配合〇 . 〇 ]_ 〜1 0 0份之褐藻酸多價金屬鹽後，做成樹脂組成物（特 開平9 一 1 2 7 7 4號公報）。更具體者係於聚醚聚醇及 二異氰酸酯中添加褐藻酸多價金屬鹽，加熱後製膜後被調 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） -7- ^ 壯衣 _IT. (請先閲讀背面之注意事項再填寫本頁} 1238083 A7 B7_ 五、發明説明（5 ) 製之。又，做爲理想之褐藻酸多價金屬鹽者如：0弓鹽、鋅 鹽、鏡鹽、鋇鹽等例。 (請先閲讀背面之注意事項再填寫本頁) (3 )針對9 0〜9 9重量份熱塑性聚胺_乳劑配合 1〜1 0重量份之親水性天然物蛋白質微粉末後進行製膜 (特開平6 - 1 0 2 6 8號公報）。具體例如：混合熱塑 性聚胺酯乳劑與親水性天然物蛋白質微粉末後，於脫模紙 等進行塗佈，加熱後，乾燥之後藉由製膜後被調製之。又 ’理想之親水性天然物蛋白質微粉末之例如：膠原質、彈 性體、角蛋白、絲粉等例。 (4 )使芳香族二羧酸或其低級烷酯、亞烷基二醇、 聚（環氧化物）二醇以1 : 1〜2 : 0 . 1〜〇 . 2之莫 耳比配合加熱、反應後形成聚合物，進行顆粒化後，藉由 擠壓法（吹塑、澆鑄擠壓、共同擠壓等）進行製膜（特開 平1 1 一 8 0 3 8 9號公報）。 又，透濕薄膜以「 m 〇 b i r ο η」（日淸紡紗股份公司製 )「ideaxprotein TPU薄膜」（出光石油化學（股份）製） 經濟部智慧財產局員工消費合作社印製 、「 fleclon」（日本合成化學工業（股份）製）等商品名 被市販之，亦可使用此等。 形成雙重結構薄片之薄膜中，做爲難透濕性薄膜者， 以水蒸氣滲透度1 ·〇 g / m 2，日以下者宜，特別以5 g / m 2 ’日以下者爲更能。接於此難透濕性薄膜之透濕性 薄膜之面所使用之基材於透濕性薄膜之熱熔合溫度中務必 與同薄膜實質上未熔合者，難透濕性之成型一加工用薄膜 於薄膜加工時附有張力，因此，以呈3 〇 〇 %以下延伸率 -8- 本紙張尺度適用中國國家標準（CNS ) A4規格（210XΜ?公釐） 1238083 A7 _______ B7 _ 五、發明説明（6 ) 者宜。 (請先閲讀背面之注意事項再填寫本頁) 做爲具有該性質之難透濕性薄膜例者如：延伸聚丙烯 (0 p p ) /未延伸聚丙烯（C p p )、聚乙烯對苯二甲 酸酯（P E T )、聚偏氯乙烯Kote ( K —）p E 丁、 PET/聚乙烯（pe) 、κ — ΡΕΤ/ΡΕ、Κ — 〇ΡΡ、K - Opp/cpp 'PET/CPP、Κ-PET/CPP、矽石蒸鍍（gl — ) PET、GL — PET /PE、氧化鋁蒸鍍（ν μ— ) PET、VM — PET/PE、GL- PET/CPP、VM- PET/ CPP 、延伸尼龍（〇NY) / PE 、κ — ONY/PE 等例 '由此選取熱熔合溫度中未與無孔透濕性薄膜呈熔合 性之材料者即可。 又’以非難透濕性薄膜做爲成型-加工用薄膜使用後 ’成型無孔透濕性後，藉由後處理於成型-加工用薄膜側 粘合另一難透濕性薄膜時。 使用〇PP 、K — 〇PP 、PET、K — PET、 經濟部智慧財產局員工消費合作社印製 GL — PET 、VM— PET 、〇NY 、K —〇NY 等， 使此等於成型-加工用薄膜進行層壓塑料即可。 本發明所使用之雙重結構薄片之調製係使用難透濕性 薄膜做爲成型透濕性薄膜時之成型-加工用薄膜後，可容 易進行之。亦即，熱塑性尿烷薄膜雖無物理性之孔、卻呈 透過水蒸氣之無孔透濕性薄膜者，該薄膜其延伸率極高， 因此，通常使聚烯烴於塗層紙類之成型-加工用薄膜上進 行擠壓，或與形成成型一加工用薄膜之聚合物共同進行吹 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -9 - 1238083 A7 B7 五、發明説明（7 ) 塑後，呈一體成型加工者。又，做爲其他方法者亦可採用 使聚烯烴進行塗層後作成薄膜之方法者。 (請先閱讀背面之注意事項再填寫本頁) 使用該取得之雙重結構薄片形成袋體中，將此薄片之 透濕性薄膜做爲內面，塡充吸濕成份之潮解性鹽類後，一 般之方法如藉由熱封等接合成所期待袋體之形狀即可。此 袋體之全體亦可藉由雙重結構形成者，而，一部份如：單 面做成雙重結構，亦可以不透濕性材料形成另一面者。 做爲此另一面所使用之不吸濕性材料者如：該雙重結 構薄片所使用之難透濕性薄膜中，選出雙重結構薄片內面 之無孔滲透性薄膜與呈現熱熔合性者即可。 其中’選擇做爲無孔滲透性薄膜之尿烷時，做爲不透 濕性材料者於低密度聚乙烯薄膜（L D P E )，直鏈低密 度聚乙烯薄膜（L L D P E )，中密度聚乙烯薄膜（ 經濟部智慧財產局員工消費合作社印製 M D P E )、高密度聚乙烯薄膜（H D P E )、乙烯/醋 酸乙酯共聚物（Ε V A )等聚乙烯薄膜、或此薄膜與尿烷 互不熔合之面使聚酯、尿龍、氧化鋁蒸鍍聚酯、鋁蒸鍍聚 酯、矽石蒸鍍聚酯、偏氯乙烯k 〇 t e聚酯、P V A /矽 石k o t e聚丙烯進行層壓塑料之複合薄膜之例者。此等 不透濕性材料中，預先使尿烷於熔合面進行塗層者宜，又 ，此等薄膜之聚胺酯樹脂所塗層之面中爲提昇樹脂粘著性 ，以進行電暈放電處理者佳。 做爲被覆層之聚胺酯樹脂者如：一液硬化型或二液硬 化型之聚胺酯樹脂或適應基材爲塑膠薄膜，以聚胺酯做爲 主體樹脂之印刷用聚胺酯樹脂之例者。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） _ 1238083 Α7 Β7 五、發明説明（9 ) 脂中添加氯化乙烯/醋酸乙酯共聚物、硝酸纖維素、聚酯 、聚醯胺、聚蠛、無機成份等者。此等通常係爲薄膜基材 與聚胺酯樹脂粘著性之改良、耐水性改良、耐藥性改良、 連粘性改良、發色等之目的而添加者，惟，亦易成爲降低 熱塑性聚胺酯薄膜與印刷用聚胺酯樹脂之粘著強度之因子 者。因此’欲使此等成份做成用途，期待性能時，務必在 不損及本發明熱粘著效果範圍下進行添加者。 又’此被覆薄膜中塗層聚胺酯樹脂之方法並無特別限 定’一般可藉由先行公知之棒塗層、噴霧之塗佈溶液之方 法’浸漬於溶液之方法等進行塗層者，而，比起其他塗層 法’其塗佈時間可縮短，且可巧妙調整塗佈位置，塗層厚 度’因此，以藉由印刷之塗層者爲較理想者。又，塗層面 亦可塗層熔合面全面者，亦可僅與尿烷薄膜相互·熔合部份 進行塗佈者。 被塡充於本發明被覆剝離型除濕劑之袋體內的潮解性 鹽類爲吸濕性物質者，其具體例如：氯化鈣無水鹽、二水 鹽等氯化鈣鹽、氯化鎂無水鹽、二水鹽等氯化鎂鹽等例， 可使用粒狀、片狀及粉末狀者。 此等潮解性鹽類中，潮解後之溶液中更具粘性，爲進 行凝膠化之目的下亦可配合適當之凝膠化劑。做爲此目的 所使用之凝膠.化劑者如：α化澱粉、聚丙烯醯胺、聚丙嫌 醯胺陽離子共聚物、聚丙烯醯胺陰離子共聚物、聚-正~ 乙烯基乙醯胺基之例。 又，潮解性鹽類中，必要時亦可添加增粘劑、防霉劑 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） _ 12 _ (請先閱讀背面之注意事- 4 -項再填· 裝— :寫本頁) 經濟部智慧財產局員工消費合作社印製 1238083 A7 ____ B7 五、發明説明（1〇 ) 、除臭劑等任意成份者。 (請先閱讀背面之注意事項再填寫本頁) 另外，本發明中以無孔透濕性薄膜做爲形成雙重結構 薄片之薄片使用時，袋內之潮解性鹽類藉由吸濕後出現體 積增加之現象。且，無孔透濕性薄膜爲無透氣性，因此， 混入潮解性鹽類塡充時之空氣不會外洩。因此，該吸濕現 象與藉由殘存於袋內之空氣使得體積大幅增加。藉由此體 積的增加造成袋之膨脹，爲肪止袋破、潮解性鹽類塡入袋 體時藉由真空包裝或空氣擠壓後，使袋體內空氣某種程度 排出後進行密封，亦即，進行脫氣密封者宜。特別是該袋 體之塡充後容積（m 1 ，除以所塡充之潮解性鹽類重量（ g ))其容積/重量比脫氣至1 . 5以下後進行密封者更 爲理想者。 經濟部智慧財產局員工消費合作社印製 脫氣密封法之例如：於三方被封住之袋體內使置入潮 解性鹽類用噴嘴由上方開口部呈插入狀態下塡入潮解性鹽 類，再使袋體往下方移動之同時，由兩側擠壓袋體，將內 部空氣擠出後，使上邊部份進行熔合之方法例者。又，做 爲另一方法者，如：利用空氣吸引噴嘴，排出塡入潮解性 鹽類之袋體內部空氣，再使上部進行熱熔融後之密封方法 例者。 又，袋體自體之容積依所使用潮解性鹽類種類之不同而 異，一般，如上述進行脫氣密封時，以潮解性鹽類重量（ g)之數字3 . 3倍至5 . 3倍左右之容積（ml )者宜 亦即，做爲潮解性鹽類者使用氯化15、二水鹽時，於2 5 °C，R Η 8 0 % (梅爾時一般家庭內）之環境中，平衡狀 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） -13 - 1238083 A7 B7 五、發明説明（11 ) (請先閱讀背面之注意事項再填寫本頁) 態下，吸收此氯化鈣二水鹽重量（g )之約2 . 5倍濕氣 者。且，4 0 °C，R Η 9 0 % (夏天潮濕衣櫃內等，暫時 性造成加濕狀態）之環境下同樣的吸收約4倍重量（g ) 之濕氣。惟，到達平衡狀態時之時間於透濕膜之透濕度、 透氣性容器之空隙率，除濕劑中被透濕膜之位置等所左右 ，各製品所需容積極爲多樣者。另外，透濕度極少之製品 可視爲除濕效果低之製品者。因此，該4 0 t，R Η 9 0 %，即使持續1個月之吸濕後，安全袋之容積只要把關除 濕袋體內殘存空氣量其潮解性鹽類重量（g )之數値仍爲 3 · 3倍至5 · 3倍之容積（m 1 )者。 經濟部智慧財產局員工消費合作社印製 如上述取得之本發明被覆剝離型除濕劑，於流通階段 並未剝離外側難透濕性薄膜之狀態，亦即，難透濕性薄膜 呈密合狀態，使用時再剝開難透濕性薄膜進行使用之。爲 使此難透濕性薄膜易於剝離，而附與剝離用之摘取片（亦 即「耳」部）爲極方便者。做爲此摘取片之作法係於難透 濕性之成型-加工用薄膜外側面，周圍部粘著一小片低端 ’或熱熔合-薄膜小片端之方法例者。又，亦可熱熔合或 粘著帶亦可。 又’於成型-加工用薄膜上擠壓熱塑性無孔透濕性薄 膜之樹脂後’或使熱塑性無孔透濕性薄膜之樹脂溶液進行 塗層製膜時，只要設計熱塑性無孔透濕性薄膜樹脂之空白 帶薄膜的作成後，即可將此空白帶做成摘取片。 更於吸塑法中，可設計如下的摘取片。首先使非難透 濕性薄膜樹脂與熱塑性無孔透濕性薄膜樹脂作成吹塑雙重 -14- 本紙張尺度適用中國國家榡準（CNS ) A4規格（210X297公釐） 1238083 A7 B7 五、發明説明（12 ) (請先閲讀背面之注意事項再填寫本頁) 結構薄片。此非難透濕性之成型-加工用薄膜與透濕薄膜 之雙重結構薄片滾輥裁成適當寬度後，比裁斷寬更寬之摘 取片增加寬度之另一難透濕性薄膜於雙重結構薄片成型_ 加工用薄膜側進行層壓塑料則可呈熱塑性無孔透濕性薄膜 之空白帶，做成摘取片。 如上述所取得具摘取片之雙重結構薄片用於袋體單面 時而另一面難透濕性薄膜更形成多於雙重結構薄片之熱塑 性無孔透濕性薄膜之難透濕性薄膜摘取片之寬度，至少使 熱塑性無孔透濕性薄膜與出現熱熔合性薄膜用於熱透濕性 薄膜之熱熔合面者宜。熱熔合重疊兩薄膜之熱塑性無孔透 濕性薄膜周圍之三方後，塡充潮解性鹽類，熱熔合封口後 取得具有摘取片之袋體。此雙重結構薄片之摘取片與熱塑 性無孔透濕性薄膜設定於相同於熱熔合難透濕性薄膜之摘 取片側之後，脫離兩邊後，只要剝離成型-加工用薄膜即 可開始吸濕。 經濟部智慧財產局員工消費合作社印製 另外，以具摘取片之雙重結構薄片做爲整個袋體使用 時，只要分離兩側兩片難透濕性薄膜與內包中央潮解性鹽 類之熱塑性無孔透濕性袋之3袋則摘取片亦需要3片。首 先，以雙重結構薄片之熱塑性無孔透濕性薄膜做爲內側， 摘取片最好呈重疊配置之。熱熔合熱塑性無孔透濕性薄膜 周圍之三方後.，塡充潮解性鹽類之後，作成熱熔合封口袋 則可取得具二片摘取片之袋體，而，中央層之熱塑性無孔 透濕性薄膜之袋部上端亦設置摘取片則較易剝離兩側之成 形-加工用薄膜。如此，單面雙重結構薄片位於熱塑性無 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） -1 5 - 1238083 A7 B7 五、發明説明（13 ) (請先閱讀背面之注意事項再填寫本頁) 孔透濕性薄膜與出現熱溶合性之單面基材，或添附帶，形 成摘取片後，只要製袋，塡充後，即可設定兩面摘取代以 及中央層熱塑性無孔透濕性薄膜合計爲3片摘取片者。 以上所說明之被覆剝離型除濕劑雖可直接使用之，惟 ，由外觀，使用性等面觀之，以收納於透氣性容器內再行 使用者佳。組合具透氣性容器時，亦可做成做爲此容器型 除濕劑替代藥劑使用者。 做爲爲收納所使用之透氣性容器者可利用長方體、立 方體、三角柱體、圓角長方體、立方體、三角柱體、圓柱 體、橢圓柱體等形狀者，該形狀可合倂設定可插入不佔使 用空間之形狀，插於狹窄空隙之形狀時，及用途者。 做爲形成此透氣性容器之基材者如：各種金屬、聚乙 烯、聚丙嫌、聚酯等塑膠牛皮紙、馬尼拉麻紙板、白紙板 、刨花紙板、一般瓦楞紙等紙類。 經濟部智慧財產局員工消費合作社印製 另外’透氣性容器只要具有某種程度形狀之透氣性即 可，如：於上部，側面設置開口部或孔等類似形狀者，更 可於此開口部，孔使用各種不織布、符契、有孔聚乙烯薄 膜、有孔聚丙烯薄膜、微多孔聚乙烯薄膜、微多孔聚丙烯 薄膜等之透氣性薄片部材。 本發明被覆剝離型除濕劑中，若使用於該各構成薄膜 中塗層消臭劑，將香料做成微粒膠囊化後所擔載之薄膜， 亦可調製具有消臭、芳香功能之被覆剝離型除濕劑者。 本發明被覆剝離型除濕劑係將潮解性鹽類塡入可以一 個步驟取得，利用具有密合難透濕性薄膜與透濕性薄膜狀 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公董 1 16 - — 1238083 經濟部智慧財產局員工消費合作社印製 Α7 Β7 五、發明説明（14 ) 態之雙重結構薄片後，所形成之袋體後，剝離難透濕性薄 膜做成使用之組成後不但經濟面佳，同時於流通階段中亦 具有良好水蒸氣阻隔性者，且，只剝離難滲透性薄片即可 開始進行除濕。 又，本發明部份被覆剝離型除濕劑之袋體做成具有難 透濕性薄膜與透濕性薄膜之雙重結構薄片，其他部份以不 吸濕性材料所形成之組成，即可特定發揮吸濕功能面，可 附加阻隔性，強度等功能。使用無孔透濕性薄膜做爲此透 濕性薄膜使用則不會造成滲出吸濕之液體。更且，使用於 使爲透濕性薄膜之熱熱塑性聚胺酯或聚酯中添加改質劑後 取得之薄膜時，加上該效果可取得具有物理性強度。且具 高度透濕能力之被覆剝離型除濕劑者。 更且，使用做爲不吸濕性材料之至少一部份不透濕性 薄膜塗層聚胺酯樹脂者，其樹脂塗層部份之一部份或全部 與透濕性薄膜進行熱熔合後，形成袋體後，可製造密封強 度高之被覆剝離型除濕劑，且，使用時不會有破袋而漏水 之危險性出現。 更使袋體做成脫氣薄片後，可製造出壓製品之除濕劑 ，且’不會有破袋之危險性。更將袋體填入透氣性容器後 ，可防止掉落，或其他收納物之破袋，且防止所吸濕之水 的滲漏。加上設計摘取片於難透濕性薄膜後，使易於於使 用時之難透濕性薄膜的剝離。 〔實施例〕 本紙張尺ϋ用中國國家標準（CNS ) A4規格（2ΐ〇χ 297公釐） :17 丨丨^----------Ί——IT----- (請先閱讀背面之注意事項存填寫本頁) 1238083 A7 B7 五、發明説明（15 ) 以下藉由實施例及參考例爲例，進行本發明更詳細之 說明，惟，本發明未限於此等實施例者。 〔參考例1〕 雙重結構薄片之調製（1 ): 於（股份）topancosmo 製 G L - A E 薄膜（G L — PET、寬50 Omm、厚度3 0//m)上，使大日精化 工業股份公司製，一液型聚胺酯樹脂溶液，hymlen γ 一 2 1 〇 B進行塗層2次後做成厚度3 0 //m之薄膜者。此 時’調整塗層位置後，於兩端設置5 〇 m m之空白帶。將 此裁成2等份後取得2 5 0mm寬度之GL - PET與 2 0 〇 m m寬度之熱塑性聚胺酯薄膜（單端上具有摘取片 5 0 m m寬度之熱塑性聚胺酯薄膜之空白帶）之雙重結構 薄片。聚胺酯薄膜之透濕度爲2 8 0 0 g/m2日者。 〔參考例2〕 雙重結構薄片之調製（2 ): 於（股份）topancosmo 製 GL— AE 薄膜（GL — PET、厚度12//m)中使厚度30//m之低密度聚乙 烯（L D P E )薄膜進行乾式層壓塑料後，取得G L -PET/PE (寬度 lOOOmm、厚度 50//m)。此 者之水蒸氣滲透度約爲1 g/m2，日者。使同薄膜之P E 面做成上面，此上面由T模擠壓日淸紡製，mobiron (熱 塑性聚胺酯薄膜，聚醯胺配合）後，作成厚度3 0 // m之 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） _ 18 - (請先閱讀背面之注意事項再填寫本頁) 裝· -項再填寫太 訂 經濟部智慧財產局員工消費合作社印製 1238083 A7 B7 五、發明説明（17 ) (請先閲讀背面之注意事項再填寫本頁) 成工業公司製）做爲另一單面薄膜呈熱熔面裝入相同寬度 的P E T / G L - P E T薄膜滾輥中。製袋塡充機中送入 兩薄膜，首先，下方與兩側被熱熔合，而，具雙重結構薄 片之摘取片之一側封口位置呈熱塑性聚胺酯薄膜端，調整 未觸及未存在熱塑性聚胺酯薄膜之空白帶。由上方塡入以 質量計量1 5 0 g之氯化鈣二水鹽於此，使袋內不殘存多 量空氣，設置爲擠壓袋子的軟墊後，擠出空氣，使上部熱 熔合，切斷後作成2 0 0 m m X 2 0 0 m m之袋子。此將 置入寬8 〇mm、深6 0mm、高1 3 0mm之網狀聚丙 烯容器中蓋上蓋子後，以聚丙烯製補縮薄膜包裝後，取得 本發明被覆剝離型除濕劑1 (以下稱實施品1 )。 使用此實施to 1時，由容器內取出袋子，撕開具雙重 結構薄片之難透濕性薄膜之成型一加工用薄膜摘取片與 P E T / G L - P E T薄膜端之摘取片後，剝離成型一加 工用薄膜即可。 〔實施例2〕 經濟部智慧財產局員工消費合作社印製 被覆剝離型除濕劑的製造（2 ): 將製袋塡充機上該參考例2所調製之2 5 0 m m寬之 雙重結構薄片裝於其熱塑性聚胺酯薄膜呈熱熔合面之製袋 塡充機薄膜滾輕中。又，另一單面薄膜之〇- N Y面呈封 口面裝於寬2 7 〇mm之〇—NY/GL - P ET薄膜滾 輥中。製袋塡充機中送入兩薄膜，首先，於雙重結構薄片 寬2 0 m m，短側之G L — P E T面以粘著劑粘接薄膜小 -20- 本紙張尺度適用中周國家標準（CNS ) A4規格（210X297公釐） 1238083 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明（18 ) 片，以脈衝熱合機熔合下方與兩側，而，具有雙重結構薄 片之摘取片一側封口位置呈熱塑性聚胺酯薄膜端，調整未 觸及未存在熱塑性聚胺酯薄膜之摘取片。由上方塡入以質 量計量1 0 0 g之氯化鈣二水鹽於此，使袋內無殘存多量 空氣，設置爲擠壓袋子之軟墊，擠出空氣後，使上部熱熔 合後，切斷做成1 0 0 m m X 2 7 0 m m之袋子。將此置 入長2 0 0 m m、寬4 0 m m、深5 0 m m之網狀附蓋聚 乙烯容器，內裝聚丙烯製補縮薄膜後，取得本發明被覆剝 離型除濕劑2 (以下稱實施品2 )。 使用此實施品2時，由容器內取出袋子後，撕開雙重 結構薄片之難透濕性薄膜成型一加工用薄膜之摘取片與〇 一 N Y / G L - P E T薄膜端之摘取片後，剝離成型一加 工用薄膜即可。 〔實施例3〕 被覆剝離型除濕劑的製造（3 ): 準備2根該參考例3所調製之雙重結構薄片之滾輥與 寬5 0 m m之尼龍製不織布滾輥。首先，一方雙重結構薄 片之滾輥於具摘取片側之熱塑性聚胺酯薄膜端使寬度5〇 m m之尼龍製不織布呈2 0 m m寬重疊之熱熔合，做爲製 袋塡充之前步驟。 此單面粘貼尼龍製不織布帶，使具摘取片之雙重結構 薄片與另一熱塑性聚胺酯薄膜雙重結構薄片其摘取片呈相 同側者，熱塑性聚胺酯薄膜面呈內側裝置於製袋塡充機後 (請先閲讀背面之注意事項再填寫本頁) 裝_ 訂 •噍 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇><297公釐） -21 - 1238083 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明説明（19 ) ’進行製袋塡充步驟。製袋塡充機中送入兩薄片後，首先 ’使下方與兩側進行熱熔合，而，一邊具摘取片之熱熔合 位置使寬度5 〇 m m之尼龍不織布內端做爲中心部，至少 使各1 0 m m寬度部份進行熱熔合，調整未觸及前述尼龍 製不織布與雙重結構薄片相互熱熔合部之更外側。由上方 以質量計量7 0 g氯化鈣二水鹽塡入此中，使袋內無殘存 多量空氣’爲擠壓袋子而設置軟墊後進行擠出空氣後，使 上部進彳了熱熔合，切斷後，作成2 3 5 m m X 1 5 0 m m 之袋子。將此置入寬1 5 〇mm、深2 3mm、高1〇〇 mm全面呈網狀之整體型附蓋平坦聚胺酯薄膜製容器中， 蓋住網狀蓋子後，以聚丙烯製補縮薄膜包裝後，取得本發 被覆剝離型除濕劑3 (以下稱實施品3 )。 使用此實施品3時，由容器內取出袋子，撕開中央尼 龍不織布具摘取片之兩側雙重結構薄片難透濕性薄膜之成 型-加工用薄膜，剝離難透濕性薄膜即可。 〔實施例4〕 被覆剝離型除濕劑之製造（4 ): 使用該參考例3所調製之雙重結構薄片（聚胺酯薄膜 之透濕度爲9 0 0 g /m 2日），與實施例3同法作成內包 1 5〇g氯化鈣二水鹽之附摘取片2 〇 〇 mmx 2 〇 〇 m m之袋子，置入紙箱後，取得本發明被覆剝離型除濕劑 4 (以下’稱貫施品4)。 使用此貫施品4時，由紙箱取出袋子，撕開中央尼龍 ——^------ur^------、玎-----丨 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 22 1238083 Α7 Β7 經濟部智慧財產局員工消費合作社印製 五、發明説明（20) 不織布之附摘取片兩側雙重結構薄片難透濕性薄膜之成型 -加工用薄膜後，剝離難透濕性薄膜即可。 〔試驗例1〕 吸濕量之測定： 使該實施例1〜4所製造之實施品1〜4分別呈可使 用狀態後，實施品1及3使袋子重回容器內蓋上蓋子。實 施品2使袋子呈熱塑性聚胺酯薄膜側朝上後重回容器內上 蓋。實施品4之袋子不做處理。分別之實施品於2 5 °C ’ R Η 8 0 %之條件下放置2〜3個月。各實施例所取得之 實施品吸濕量與經過日數相互關係示於圖1至圖4 ° (結果） 本發明實施品1〜4之吸濕量分別爲2 6 5 m 1、 17〇ml 、 125ml及257ml 。由此結果各實施 品之標準除濕量分別做成2 5 0 m 1、1 5 0 m 1、 120ml、及 250 ml。 〔試驗例2〕 除濕性評定： 使用前之實施品於4 0 °C，R Η 9 0 %之恆溫層內置 4個月後測定所增加之重量，做爲各實施品之除濕性評定 (請先閱讀背面之注意事項再填寫本頁) 裝· 訂 噃 本紙張尺度適用中周國家標準（CNS ) Α4規格（210X297公釐） -23 - 1238083 A7 B7 五、發明説明（22) 封強度。 (載重試驗） 分別將熱塑性聚胺酯薄膜與聚胺酯樹脂塗層薄膜切成 1 3 5 m m X 1 0 0 m m。將相互兩薄膜之聚胺酯面合倂 ，以密封寬度1 2 m m之腳踏式熱密封機進行熱熔合三方 。該袋內塡入7 0 g之水後，儘量不混入空氣下同樣進行 熱熔合封口。將此袋置於體重計上，更平坦載重1 5 ◦ m m X 2 0 0 m m時亦放置不變形金屬製板。由板上以帶把 啤酒罐進行加壓，體重呈5 0 k g時，放置1分鐘後，判 定是否破袋。 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 -25- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐）1238083 A7 B7 V. Description of the invention (1) (Please read the precautions on the back before filling out this page) The present invention is related to the coating and peeling type dehumidifier, and the more detailed is related to the deliquescent of at least part of the hygroscopic substance The surface of the bag is a double-layered thin bag with a moisture-impermeable film on the surface and a moisture-permeable film on the inside. When in use, a coated peel-off dehumidifier is used after the surface of the moisture-impermeable film is peeled off. In the prior art, a dehumidifying agent having a hygroscopic substance in a moisture-permeable film bag is provided, and the hygroscopic packaging of this dehumidifying agent must be performed with care. That is, in the circulation stage, if the hygroscopic agent absorbs moisture, the commodity price will no longer exist at all. Therefore, at this stage, the hygroscopic material must be packaged with a moisture-impermeable material. Another step is different from making a desiccant. If it is required to be complete, first, make a bag with impervious packaging material, put the hygroscopic agent in this bag, and then plug the mouth of the bag. However, the cost of this step as a dehumidifier is too high. high. Therefore, in order to provide a more economical dehumidifier, packaging which is required to provide a poorly moisture-permeable material can be easily performed. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs in order to solve this problem, the inventors discussed the various steps of dehumidifier manufacturing, and found that the thickness of the moisture-permeable film discussed as the first dehumidifier was 20 μm ~ 50 0 // m thermoplastic moisture permeable polyurethane film, in which polyamine or polyurethane is added to obtain the film, or the film obtained after adding polyalkylene glycol to the thermoplastic moisture permeable polyester has an elongation rate It is more than 300%, which causes the film to be stretched when it is pulled out by the film roll when the film is alone, and the processing speed and processing method are limited. If the sealing part of the film is not to be wrinkled, the filling is performed smoothly. Difficult people. -4- This paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm) 1238083 A7 B7 V. Description of the invention (2) (Please read the precautions on the back before filling this page) Therefore, the inventor found The above-mentioned physical properties of the film are usually formed by combining the film formed during the molding of the film and the processing film (hereinafter referred to as the molding-processing film) during the molding of the bag body. After the film is a moisture-impermeable film for processing, it can be peeled off during use as a moisture-impermeable package to complete the present invention. That is, the feature of the present invention is to provide a bag body formed by using a sheet having a double structure with at least a part of deliquescent salts whose surface is a moisture-impermeable film and whose inside is a moisture-permeable film. Covered release type dehumidifier that is used after peeling off the difficult-to-moisture film. [Brief description of the drawing] Fig. 1 is a drawing showing the relationship between the moisture absorption and the elapsed days of the coated peeling type dehumidifier manufactured in Example 1. Fig. 2 is a graph showing the relationship between the moisture absorption and the elapsed days of the coated peeling type dehumidifier manufactured in Example 2. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. Figure 3 is a graph showing the correlation between the moisture absorption and the elapsed days of the coated peeling dehumidifier manufactured in Example 3. Fig. 4 is a graph showing the relationship between the moisture absorption and the elapsed days of the coated peeling type dehumidifier manufactured in Example 4. [Best form of implementation of the invention] The double-structured sheet having a hardly water-permeable film and a moisture-permeable film used in the coated peeling type dehumidifier of the present invention (hereinafter referred to as "dual-structured sheet") This paper applies Chinese national standards (CNS) ) A4 size (210'〆297mm) _ 5 _ 1238083 A7 B7 V. Description of invention (3) (Please read the precautions on the back before filling this page)) It is formed by using the moisture-permeable film as mentioned above It is sometimes obtained as a difficult-to-moisture film of a molding-relief film, but is not limited to this method. The non-hard-to-moisture film used as a molding-processing film is peeled off after molding. This film can be bonded to another film with poor moisture permeability by post-treatment. Non-moisture-permeable film can be used as a molding-processing film. After molding, it can also be bonded to the molding-processing film. . Among the films forming this double-structured sheet, the moisture permeability of the film having a moisture permeability of 300 g / m2 is more than 500 g / m2, and the day is more preferable. The tensile strength is 200 kg · f / cm2 (0.196 Pa) or more. Examples of films having such a moisture permeability are: microporous films, non-porous moisture permeable films, and when a microporous film is adhered with an interface active ingredient from the outside, the surface tension may be reduced and oozing may be induced. A porous moisture-permeable film is preferred. Examples of non-porous moisture-permeable films are: thermoplastic urethane films, thermoplastic polyether urethane films, and thermoplastic polyester urethane films. Examples are printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, After the modifier is added to the thermoplastic polyurethane or polyester, the obtained film can also be used. Specific modifiers, such as polyamines, polyamines, alginic acid, polyvalent metal salts or hydrophilic organic natural powders added to thermoplastic polyurethanes, are examples of modifiers added to polyesters. Examples are polyepoxide diols and the like. Among them, examples of polyamines include copolymers of polyamines, polyesters, polyethers, and the like. In addition, as the alginic acid polyvalent metal salt, such as: This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) _ 6 _ 1238083 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (4) Calcium Alginate, Zinc Alginate, Beryllium Alginate, Barium Alginate, Magnesium Alginate, Cadmium Alginate, Mercury Alginate, Alginate Alginate, Radium Alginate, Lead Alginate, Copper Alginate, Iron Alginate , Aluminum alginate, cobalt alginate, nickel alginate, chromium alginate, manganese alginate and the like. In addition, examples of natural fine powders of hydrophilic organic type include collagens, sponge powder, elastin, keratin, silk powder, kapok, hemp, pulp, and seaweed. Examples of the poly (epoxide) glycol include polytetramethylene glycol, polyethylene glycol, and polypropylene glycol. The addition amount of these modifiers is appropriately selected according to the polymer. Furthermore, it is also possible to use these polyurethanes, polyesters, and those in which modifiers are added to paper, non-woven fabrics, covenants, and porous poly films. These polyurethanes and polyesters are coated on paper and non-woven fabrics. After waiting, it is made into a film. The method for obtaining the moisture-permeable film is not particularly limited, and it can be formed by a prior method. Specific examples are as follows. (1) After mixing 10 to 20% of polyurethane particles in thermoplastic polyurethane resin particles, film formation is performed by extrusion (blow molding, casting extrusion, coextrusion, etc.) (Japanese Patent Laid-Open No. 5-1 1 5 4). Examples of polyamides are: polyamide 1 1 (p A-1 1), polyamide 1 2 (PA — 1 2), polyamide 1 2 1 2 (PA — 1 2 1 2) Be used to it. (2) A resin composition is prepared by blending 100 parts of alginic acid polyvalent metal salt with 100 parts of thermoplastic polyurethane resin (Japanese Patent Application Laid-Open No. 9-12). More specifically, polyalcohol and diisocyanate are added with alginic acid polyvalent metal salt. After heating, the film is adjusted and the paper size is adjusted to Chinese National Standard (CNS) A4 (210X 297 mm) -7- ^ Zhuangyi _IT. (Please read the precautions on the back before filling out this page} 1238083 A7 B7_ V. Description of the invention (5). Also, as an ideal alginic acid polyvalent metal salt, such as: 0 bow salt, Examples of zinc salt, mirror salt, barium salt, etc. (Please read the precautions on the back before filling this page) (3) For 90 to 9 9 parts by weight of thermoplastic polyamine_emulsion with 1 to 10 parts by weight of hydrophilicity Film formation of natural protein fine powder (Japanese Unexamined Patent Publication No. 6-10 2 68). For example, a thermoplastic polyurethane emulsion and a hydrophilic natural protein powder are mixed, and then coated on a release paper or the like, and heated. Then, after drying, it is prepared by film formation. It is also an example of an ideal hydrophilic natural protein powder such as collagen, elastomer, keratin, silk powder, etc. (4) Aromatic dicarboxylic acid Or its lower alkyl ester, alkylene glycol, poly (epoxide) The diol is heated at a molar ratio of 1: 1 to 2: 1 to 0.1 to 0.2 to form a polymer after reaction. After pelletization, the diol is subjected to extrusion (blow molding, casting extrusion, coextrusion). Etc.) for film formation (Japanese Patent Application Laid-Open No. 1 1-8 0 389). The moisture-permeable film is "m 〇bir ο η" (manufactured by Nissei Spinning Co., Ltd.) and "ideaxprotein TPU film" (Idemitsu Petroleum Chemical (shareholding system) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs and trade names such as "fleclon" (manufactured by Japan Synthetic Chemical Industry (shares)) are also commercially available. They can also be used. For those who are difficult to permeate the film, the water vapor permeability is 1.0 g / m2, which is suitable for those who are less than day, especially those who are less than 5 g / m2 for the day. The substrate used for the surface of the moisture-permeable film must be substantially unfused with the same film at the heat fusion temperature of the moisture-permeable film. The film that is difficult to moisture-permeability is formed with a tension during the processing of the film. Therefore, with an elongation below 300% -8 Chinese National Standard (CNS) A4 specification (210XM? Mm) 1238083 A7 _______ B7 _ V. Invention description (6) should be appropriate (Please read the precautions on the back before filling this page) as a difficulty of this nature Examples of moisture-permeable films are: stretched polypropylene (0 pp) / unstretched polypropylene (C pp), polyethylene terephthalate (PET), polyvinylidene chloride Kote (K —) p E Ding, PET / polyethylene (pe), κ — PET / PE, K — OPP, K-Opp / cpp 'PET / CPP, K-PET / CPP, silica evaporation (gl —) PET, GL — PET / PE , Alumina evaporation (ν μ—) PET, VM — PET / PE, GL-PET / CPP, VM-PET / CPP, extended nylon (〇NY) / PE, κ — ONY / PE, etc. Any material that is not fused to the non-porous moisture-permeable film at the heat fusion temperature may be used. In addition, after the use of a non-different moisture-permeable film as a molding-processing film, and after forming the non-porous moisture-permeability, a second moisture-impermeable film is bonded to the molding-processing film side by post-treatment. Use 〇PP, K — 〇PP, PET, K — PET, GL — PET, VM — PET, 〇NY, K — 〇NY, etc. printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs to make this equal to the film for molding and processing Laminated plastic is sufficient. The preparation of the dual structure sheet used in the present invention can be easily performed after the use of a moisture-impermeable film as a molding-processing film when forming a moisture-permeable film. That is, although a thermoplastic urethane film has no physical pores, but it is a non-porous moisture-permeable film that transmits water vapor, the film has an extremely high elongation. Therefore, polyolefins are usually molded on coated paper- Extrusion on the processing film, or blown together with the polymer forming a processing film. The paper size is applicable to China National Standard (CNS) A4 (210X297 mm) -9-1238083 A7 B7 V. Description of the invention ( 7) After molding, it is a one-piece processor. In addition, as another method, a method in which a polyolefin is coated and formed into a film may be used. (Please read the precautions on the back before filling this page.) Use the obtained double-structured sheet to form the bag body, and use the moisture-permeable film of this sheet as the inner surface, after filling with hygroscopic salts of hygroscopic ingredients, A general method may be to synthesize the desired shape of the bag body by heat sealing or the like. The whole of the bag body can also be formed by a double structure, and a part of the bag body can be a double structure on one side, or the other side can be formed by a water-impermeable material. As the non-hygroscopic material used on the other side, for example, among the poorly moisture-permeable films used in the double-structured sheet, select the non-porous and permeable film on the inner surface of the double-structured sheet and the one exhibiting heat fusion. . Among them, when choosing urethane as a non-porous and permeable film, those who use it as a water-impermeable material are low-density polyethylene film (LDPE), linear low-density polyethylene film (LLDPE), and medium-density polyethylene film ( Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (MDPE), high-density polyethylene film (HDPE), ethylene / ethyl acetate copolymer (E VA) and other polyethylene films, or the surface of this film that does not fuse with urethane Laminated polyester, uron, alumina vapor-deposited polyester, aluminum vapor-deposited polyester, silica vapor-deposited polyester, vinylidene chloride, polyester, PVA / silica kote polypropylene Case. Of these moisture-impermeable materials, it is desirable to coat the urethane on the fusion surface in advance, and the surface coated with the polyurethane resin of these films is to improve the adhesion of the resin for corona discharge treatment. good. Examples of the polyurethane resin used as the coating layer include one-hardened or two-liquid hardened polyurethane resins, or an example of a printing polyurethane resin using polyurethane as the main resin as the main substrate. This paper size applies Chinese National Standard (CNS) A4 (210X297mm) _ 1238083 A7 B7 V. Description of the invention (9) Adding vinyl chloride / ethyl acetate copolymer, nitrocellulose, polyester, polyfluorene to the fat Amine, polyfluorene, inorganic ingredients, etc. These are usually added for the purpose of improving the adhesion of film substrates and polyurethane resins, improving water resistance, improving chemical resistance, improving adhesion, color development, etc., but they are also easy to reduce thermoplastic polyurethane films and printing. Use the factor of the adhesive strength of polyurethane resin. Therefore, if these ingredients are to be used, and performance is expected, they must be added within a range that does not impair the thermal adhesion effect of the present invention. The method of coating the polyurethane resin in the coating film is not particularly limited. Generally, the coating method can be performed by a method of dipping in a solution such as a rod coating method and a spray coating solution known in advance. From other coating methods' the coating time can be shortened, and the coating position can be adjusted cleverly, so the coating thickness by printing is the ideal one. In addition, the coating surface may be the one having the full coating fusion surface, or the coating may be performed only on the mutual fused portion with the urethane film. The deliquescent salt filled in the bag of the coated peeling type desiccant of the present invention is a hygroscopic substance, and specific examples thereof include calcium chloride anhydrous salts, calcium chloride salts such as dihydrate salts, anhydrous magnesium chloride salts, and Examples of magnesium chloride salts such as water salts include those in the form of granules, flakes, and powders. Among these deliquescent salts, the deliquescent solution is more viscous, and an appropriate gelling agent may be added for the purpose of gelation. The gel used for this purpose. Chemical agents such as: alpha starch, polypropylene ammonium, polypropylene cationic amine copolymer, polypropylene ammonium anionic copolymer, poly-n-vinylacetamido Example. In addition, in deliquescent salts, tackifiers and antifungal agents can be added if necessary. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) _ 12 _ (Please read the precautions on the back-4 -Item refilling and filling—: Write this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, 1238083 A7 ____ B7 V. Invention Description (1〇), deodorant and other components. (Please read the precautions on the back before filling in this page) In addition, in the present invention, when a non-porous moisture-permeable film is used as a sheet forming a double-structured sheet, the deliquescent salts in the bag appear to have a volume after absorbing moisture Increase phenomenon. In addition, since the non-porous moisture-permeable film is non-breathable, air will not leak out when mixed with deliquescent salts. Therefore, the hygroscopic phenomenon and the air remaining in the bag greatly increase the volume. As a result of the increase in volume, the bag swells. When the bag is broken, the deliquescent salts are poured into the bag and sealed by vacuum packaging or air extrusion. It is advisable to perform degassing and sealing. In particular, the volume (m 1, divided by the weight of the deliquescent salt (g)) of the bag body after its filling is more desirable than the volume / weight ratio of the bag after degassing to 1.5 or less. For example, the degassing sealing method printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, for example, puts the deliquescent salt nozzle in the sealed bag of the three parties, and inserts the deliquescent salt in the state from the upper opening, and then While moving the bag body downward, squeeze the bag body from both sides, squeeze out the internal air, and fuse the upper part. As another method, for example, an air suction nozzle is used to discharge the air inside the bag body into which deliquescent salts are poured, and then the upper part is heat-sealed. In addition, the volume of the bag body varies depending on the type of deliquescent salt used. Generally, when degassing and sealing as described above, the number of the deliquescent salt (g) is 3.3 times to 5.3. The volume (ml) should be doubled. That is, when using chlorinated 15, dihydrate salt as deliquescent salt, the temperature should be 25 ° C, R Η 80% (in ordinary households in Mels). In the balance, the size of this paper applies the Chinese National Standard (CNS) A4 specification (210X297 mm) -13-1238083 A7 B7 V. Description of the invention (11) (Please read the precautions on the back before filling this page). Those who absorb about 2.5 times the weight of this calcium chloride dihydrate salt (g). In addition, it also absorbs about 4 times the weight (g) of moisture under the environment of 40 ° C, R Η 90% (wet in the wardrobe etc. in the summer, temporarily causing humidification). However, the time when the equilibrium state is reached is affected by the moisture permeability of the moisture-permeable membrane, the porosity of the air-permeable container, and the position of the moisture-permeable membrane in the dehumidifier, and the required volume of each product is extremely diverse. In addition, products with very little moisture permeability can be considered as products with low dehumidifying effect. Therefore, the 40 t, R Η 90%, even after one month of moisture absorption, as long as the volume of the safety bag is turned off, the amount of deliquescent salt (g) in the bag is still 3 · 3 times to 5 · 3 times the volume (m 1). The consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs printed the coated peeling dehumidifier of the present invention obtained as described above, and did not peel off the outer moisture-impermeable film in the circulation stage, that is, the moisture-impermeable film was in a close state. Peel off the poorly permeable film before use. In order to make the difficult-to-moisture film easy to peel off, it is extremely convenient to attach a peeling sheet (that is, an “ear” portion) for peeling. The method of extracting the film is to exemplify a method of attaching a small piece of a low end ′ or a heat-fusion-film small piece end to the outer side of a film that is difficult to penetrate and mold and process. Alternatively, heat-sealing or adhesive tape may be used. Also, "after extruding the resin of the thermoplastic non-porous moisture-permeable film on the molding-processing film" or coating the resin solution of the thermoplastic non-porous moisture-permeable film, as long as the thermoplastic non-porous moisture-permeable film is designed, After the resin blank tape is made, the blank tape can be made into a picking piece. In addition, in the blister method, the following extraction tablets can be designed. First, make the non-different moisture-permeable film resin and the thermoplastic non-porous moisture-permeable film resin into a blow molding double -14- This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) 1238083 A7 B7 V. Description of the invention ( 12) (Please read the notes on the back before filling in this page) Structure sheet. This non-moisture-permeable forming-processed film and moisture-permeable film of the double-structured sheet roll are cut to an appropriate width, and a pick-up sheet wider than the cutting width is used to increase the width of another difficult-to-moisture film formed on the double-structured sheet. _ Laminated plastic on the side of the processing film can be a blank strip of thermoplastic non-porous moisture-permeable film, which can be made into a pick-up sheet. When the double-structured sheet with a pick-up sheet obtained as described above is used on one side of the bag body, and the other side has a poorly moisture-permeable film, it is more difficult to remove a difficult-to-moisture film than a thermoplastic non-porous moisture-permeable film with a double-structured sheet. The width of the sheet should preferably be at least a thermoplastic non-porous moisture permeable film and a thermally fusible film used for the thermally fused surface of the thermally permeable film. The three sides of the thermoplastic non-porous and moisture-permeable film with two films overlapped by heat fusion are filled with deliquescent salts, and the bag body with the extracted piece is obtained after heat fusion sealing. The pick-up sheet and the thermoplastic non-porous moisture-permeable film of the dual-structure sheet are set to the same side as the pick-up sheet of the heat-fusion hardly moisture-permeable film, and after being detached from both sides, as long as the forming-processing film is peeled, moisture absorption can be started. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economy For three non-porous moisture-permeable bags, three tablets are also needed for picking tablets. First, a thermoplastic non-porous, moisture-permeable film with a dual structure sheet is used as the inner side, and the pick-up sheets are preferably arranged in an overlapping manner. After heat-melting the thermoplastic non-porous moisture-permeable film around the three sides. After filling with deliquescent salts, making a heat-sealing pocket can obtain a bag body with two extracted pieces, and the central layer of thermoplastic non-porous The upper end of the bag portion of the wet film is also provided with a pick-up sheet, which makes it easier to peel off the forming and processing films on both sides. In this way, the single-sided double-structured sheet is located on the thermoplastic non-paper scale and is applicable to the Chinese National Standard (CNS) A4 specification (210X 297 mm) -1 5-1238083 A7 B7 V. Description of the invention (13) (Please read the notes on the back first (Fill in this page again.) Porous moisture-permeable film and single-sided substrate with thermal fusion, or added, after forming the pick-up sheet, as long as the bag is made and filled, you can set the double-sided pick-up replacement and the central layer thermoplastic. A total of three non-porous moisture-permeable films were taken. Although the coated peeling type dehumidifier described above can be used directly, it is preferable for the user to store it in a breathable container from the aspects of appearance and usability. When combined with a breathable container, it can also be used as a container-type desiccant instead of a medicament user. As a breathable container for storage, you can use shapes such as cuboids, cubes, triangular cylinders, rounded cuboids, cubes, triangular cylinders, cylinders, elliptical cylinders, etc. The shape can be set to fit and can be inserted without occupying The shape of the space, when inserted in the shape of a narrow gap, and those who use it. As the base material for forming the air-permeable container, such as: various metals, polyethylene, polypropylene, polyester and other plastic kraft paper, Manila linen paper, white paperboard, particleboard, general corrugated paper and other papers. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, as long as the air-permeable container has a certain shape of air permeability, for example, if an opening or a hole is provided on the upper side and the side, similar shapes can be used in this opening. For the pores, various air-permeable sheet materials such as non-woven fabrics, charms, porous polyethylene films, porous polypropylene films, microporous polyethylene films, and microporous polypropylene films are used. In the coating and peeling type dehumidifier of the present invention, if the coating deodorizing agent is used in each of the constituent films, the perfume is made into a thin film carried by encapsulated particles, and a coating and peeling type having deodorizing and aromatic functions can also be prepared. Dehumidifier. The coated peeling dehumidifier of the present invention can be obtained in one step by injecting deliquescent salts. It has a tightly permeable film and a permeable film. The paper size is applicable to Chinese National Standard (CNS) A4 (210X297). Dong 1 16-1238083 Printed by the Consumers' Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (14) After the double structure sheet is formed, the formed bag body is peeled off and the moisture-impermeable film is peeled off to make up the composition Those who not only have good economic performance, but also have good water vapor barrier properties in the circulation stage, and can start dehumidification only by peeling off the impervious sheet. In addition, the bag of the partially-coated peeling dehumidifier of the present invention is made It has a double-structured sheet with a difficult-to-moisture film and a moisture-permeable film. The other parts are composed of non-hygroscopic materials, which can specifically exert the function of moisture absorption, and can add barrier properties, strength and other functions. Porous and moisture-permeable films used for this moisture-permeable film will not cause the exudation of hygroscopic liquids. Furthermore, they are used to make heat-permeable thermoplastic polyurethanes or polymers that are moisture-permeable films. When a film obtained after adding a modifier is added, this effect can be used to obtain a coating peel-off dehumidifier with physical strength and high moisture permeability. Furthermore, it is used as at least one of non-hygroscopic materials. For those partially impermeable film-coated polyurethane resins, a part or all of the resin coating layer is thermally fused with a moisture-permeable film to form a bag, and a coating peel-off type dehumidifier with high sealing strength can be manufactured. And, there is no danger of water leakage when the bag is broken. When the bag body is made into a degassed sheet, a dehumidifier for pressed products can be manufactured, and there is no danger of bag breakage. Filling the bag into the air-permeable container can prevent falling or broken bags of other storage items, and prevent leakage of the absorbed water. In addition, the design of the pick-up sheet on the difficult-to-moisture film makes it easy Peeling of the difficult-to-moisture film at the time of use. [Example] The paper size is in accordance with Chinese National Standard (CNS) A4 (2ΐ〇χ 297 mm): 17 丨 丨 ^ -------- --Ί——IT ----- (Please read the precautions on the back and fill in this page) 1238083 A 7 B7 V. Description of the Invention (15) The following describes the present invention in more detail by taking the examples and reference examples as examples, but the present invention is not limited to those examples. [Reference Example 1] Modulation of a double-structured sheet (1): On the GL-AE film (GL — PET, width 50 Omm, thickness 30 // m) made by (share) topancosmo, make a one-liquid polyurethane resin solution, made by Dainichi Seika Chemical Industry Co., Ltd., hymlen γ A 2 1 0B is coated twice to make a film with a thickness of 30 // m. At this time, after adjusting the coating position, a 50 mm blank tape is set at both ends. Cut this into 2 equal parts Then, a double-structured sheet of GL-PET with a width of 250 mm and a thermoplastic polyurethane film with a width of 200 mm (a blank tape with a strip of thermoplastic polyurethane film with a width of 50 mm on one end) was obtained. The moisture permeability of polyurethane film is 280 g / m2 day. [Reference Example 2] Preparation of a double-structured sheet (2): A low-density polyethylene (LDPE) having a thickness of 30 // m in a GL-AE film (GL-PET, thickness 12 // m) made by TOPANCOSMO (stock) After the film was dry-laminated plastic, GL-PET / PE (width 1000 mm, thickness 50 // m) was obtained. The water vapor permeability is about 1 g / m2 in Japan. Make the PE surface of the same film as the upper surface, and the upper surface is made of T-die extrusion sundial spinning, mobiron (thermoplastic polyurethane film, combined with polyurethane), and then made into a thickness of 3 0 // m. This paper size is applicable to Chinese national standards (CNS) A4 specifications (210X297 mm) _ 18-(Please read the notes on the back before filling out this page) Install ·-and then fill out Taiding Printed by the Intellectual Property Bureau Staff Consumer Cooperatives of the Ministry of Economic Affairs 1238083 A7 B7 V. Invention Note (17) (Please read the precautions on the back before filling this page) Made by Sung Kogyo Co., Ltd.) As another single-sided film with a hot-melt surface, load it into a PET / GL-PET film roll of the same width. Two films are fed into the bag making and filling machine. First, the lower and sides are thermally fused, and one side of the picking piece with the double structure sheet is sealed with a thermoplastic polyurethane film at the side. The adjustment does not touch the non-existent thermoplastic polyurethane film. Blank strip. The calcium chloride dihydrate salt with a weight of 150 g is poured in from above, so that a large amount of air does not remain in the bag. After being set as a cushion for squeezing the bag, the air is squeezed out and the upper part is thermally fused. Make a bag of 200 mm X 2000 mm. In this case, a net polypropylene container with a width of 80 mm, a depth of 60 mm, and a height of 130 mm was put on the lid, and then packed with a polypropylene shrink film to obtain the coated peeling dehumidifier 1 (hereinafter Weigh implement 1). When using this implementation to 1, take out the bag from the container, tear the moisture-impermeable film with a double-structured sheet, mold the film pick-up sheet for processing, and the PET / GL-PET film-end pick-up sheet, then peel and mold. One film can be used for processing. [Example 2] Manufacturing of coated peel-off type dehumidifier by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (2): A double-structured sheet of 2.5 mm width prepared by the reference example 2 on a bag making and filling machine The bag making and filling machine film of which the thermoplastic polyurethane film has a heat fusion surface is light in weight. In addition, the 0-N Y side of the other single-sided film is a sealed surface and is mounted in a 0-NY / GL-P ET film roll having a width of 270 mm. Two films are fed into the bag making and filling machine. First, the width of the double structure sheet is 20 mm, and the short side of the GL — PET side is bonded with an adhesive. The film size is -20. ) A4 size (210X297 mm) 1238083 A7 B7 Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (18). The bottom and sides are fused by a pulse heat sealer. The sealing position on one side of the sheet is the end of the thermoplastic polyurethane film, and the pick-up sheet that does not touch the non-existent thermoplastic polyurethane film is adjusted. Calcium chloride dihydrate salt with a mass of 100 g is poured in from above, so that there is no residual air in the bag. It is set as a cushion for squeezing the bag. After the air is squeezed out, the upper part is thermally fused and cut. It is broken into bags of 100 mm X 270 mm. This was placed in a polyethylene container with a net shape of 200 mm in length, 40 mm in width, and 50 mm in depth, and a polypropylene shrink film was contained therein to obtain the coated peeling type dehumidifier 2 (hereinafter referred to as Implement 2). When using this implementation product 2, after taking out the bag from the container, tear off the double-layered sheet of the difficult-to-moisture film forming a processing film extraction sheet and 〇NY / GL-PET film end extraction sheet, It is sufficient to peel-mold and process the film. [Example 3] Production of coated peeling type dehumidifier (3): Two rolls of a double-structured sheet prepared in the reference example 3 and a non-woven roll made of nylon with a width of 50 mm were prepared. First, a roller of a double-structure sheet is thermally fused by overlapping a non-woven fabric of 50 mm in width with a width of 20 mm at the end of the thermoplastic polyurethane film on the side of the picking sheet, as a pre-packing step. This single-sided non-woven nylon tape is attached, so that the double-structured sheet with the pick-up sheet and another thermoplastic polyurethane film double-structured sheet have the pick-up sheet on the same side, and the thermoplastic polyurethane film side is inside. (Please read the precautions on the back before filling out this page) Binding _ Binding • The size of this paper applies the Chinese National Standard (CNS) A4 specification (21〇 > < 297 mm) -21-1238083 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (19) ′ The bag making and filling steps are performed. After the two sheets are fed into the bag making and filling machine, first, the bottom and the sides are thermally fused, and the thermal fusion position of the picking piece on one side is to use the inner end of the nylon non-woven fabric with a width of 50 mm as the center, Each 10 mm width portion was thermally fused, and adjusted so as not to touch the outer side of the thermal fusion fused portion of the nylon nonwoven fabric and the double structure sheet. From the top, 70 g of calcium chloride dihydrate salt was poured into it from the top so that there is no residual air in the bag. After the cushion is set for squeezing the bag and the air is squeezed out, the upper part is heat-fused. After cutting, a bag of 2 35 mm X 150 mm was made. This was placed in an integrated flat polyurethane film container with a lid of 150 mm in width, 23 mm in depth, and 100 mm in height. After covering the net lid, it was packed in a polypropylene shrink film. Then, the coating-type peeling dehumidifier 3 (hereinafter referred to as "exemplary product 3") was obtained. When using this embodiment 3, the bag is taken out from the container, and the double-layered thin structure moisture-impermeable film on both sides of the center nylon non-woven fabric pick-up sheet is formed into a processing film, and the moisture-impermeable film may be peeled off. [Example 4] Production of coated peeling type dehumidifier (4): The double-structured sheet prepared by the reference example 3 (the polyurethane film has a water vapor permeability of 90 g / m 2 days) was used in the same manner as in Example 3. A bag containing 150 g of calcium chloride dihydrate salt with an extract of 2000 mm x 2000 mm was prepared and placed in a cardboard box to obtain the coated peeling type dehumidifier 4 (hereinafter referred to as a “consistent application”). 4). When using this Guan Shi 4, remove the bag from the carton and tear open the central nylon —— ^ ------ ur ^ ------, 玎 ----- 丨 (Please read the precautions on the back first (Fill in this page again) This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 22 1238083 Α7 Β7 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economy After forming and processing the side double-structured thin film having poor moisture permeability, the moisture resistant film may be peeled off. [Experimental Example 1] Measurement of moisture absorption: After implementing the products 1 to 4 manufactured in Examples 1 to 4 in a usable state, the products 1 and 3 returned the bag to the container and covered the lid. In Example 2, the bag was placed with the thermoplastic polyurethane film side facing up, and then returned to the inner lid of the container. The bag of implement 4 is not treated. The respective products were left at 2 ° C ′ R Η 80% for 2 to 3 months. The relationship between the moisture absorption of the implements obtained in each example and the elapsed days is shown in Fig. 1 to Fig. 4 (Result) The moisture absorptions of the implements 1 to 4 of the present invention are 2 6 5 m 1, 17 ml , 125ml and 257ml. From this result, the standard dehumidification amount of each product was made 250 m 1, 150 m 1, 120 ml, and 250 ml, respectively. [Experiment 2] Dehumidification evaluation: The weight of the implemented product was measured at 40 ° C, R Η 90% in the thermostatic layer for 4 months, and the increased weight was measured as the dehumidification evaluation of each product (please Please read the notes on the back before filling this page.) Binding and binding The paper size applies the National Standard (CNS) A4 specification (210X297 mm) -23-1238083 A7 B7 5. Description of the invention (22) Seal strength. (Load test) The thermoplastic polyurethane film and the polyurethane resin-coated film were cut into 135 mm x 100 mm respectively. The polyurethane surfaces of the two films are bonded to each other, and the three sides are thermally fused by a foot-type heat sealer with a sealing width of 12 mm. After pouring 70 g of water into the bag, heat-sealing the same as far as possible without mixing with air. Place this bag on a weight scale for a flatter load of 15 ◦ m m X 200 m. Also place a non-deformable metal plate. When the beer can was pressurized with a belt from a board and the weight was 50 kg, it was left to stand for 1 minute and it was judged whether the bag was broken. (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -25- This paper size applies to China National Standard (CNS) A4 (210X 297 mm)