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TW513344B - Film-nonwoven laminate containing an adhesively-reinforced stretch-thinned film - Google Patents

Film-nonwoven laminate containing an adhesively-reinforced stretch-thinned film Download PDF

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Publication number
TW513344B
TW513344B TW86109726A TW86109726A TW513344B TW 513344 B TW513344 B TW 513344B TW 86109726 A TW86109726 A TW 86109726A TW 86109726 A TW86109726 A TW 86109726A TW 513344 B TW513344 B TW 513344B
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Taiwan
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film
adhesive
woven
layer
patent application
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TW86109726A
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Chinese (zh)
Inventor
Ann Louies Mccormack
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Kimberly Clark Workdwide Inc
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Abstract

The present invention is directed to film-nonwoven laminate incorporating stretch-thinned, breathable films onto which a pattern or network of adhesive areas is applied to improved durability and strength of the stretch-thinned film. The present invention has applicability in a wide variety of areas where strength, comfort, liquid impermeability and breathability are needed or desired, including without limitation, personal care absorbent articles, articles of clothing, roll goods and health care-related items.

Description

您濟部中央標準局負工消費合作社印製 A7 -------B7 五、發明説明(丄^^ ~~ 〜--此-申請索由1996年7月15日美國條款中請編號 60/021,733請求優先權。 H朗背景 本發明關於一種存在於薄膜-非織物層壓製品中之定 位、低厚度透氣性薄膜的應用。 IL明背景 薄膜-非織物層壓製品已發覺廣泛地被應用於各種不 同的申請中,包括個人看顧用吸收性物件,例如尿布、兒 童訓練用裤、失禁用衣物、婦女衛生用品、衛生棉、創傷 敷料、繃帶、以及其相似物等的外層覆蓋。薄膜,織物層 壓製品亦已被發覺有其利用價値於健康看顧用品的範圍, 此類的產品如外科手術用帳幔與長袍、清潔室衣物、以及 消毒包紮;同時亦有用於軋製物品,例如帳篷材料以及傢 俶用品、汽車與其它運輸公具等的覆罩。 特别是在個人看顧用吸收性物件的領域中,將強調低 成本薄膜-非織物層壓製品的改良,其在表現完美的視覺美 感與觸覺特質之際’能同時形成的_有效的屏^,以利體 分泌物(液體與其它的廢棄物質)的通過。一種被應用以達成 此一令人滿意、低花費之薄膜_非織物層壓製品的技術爲利 用逐漸減小尺寸或厚度的薄膜。變薄後的薄膜典型地亦擁 有較底的成本,且基於被減少的厚度,其通常具有增加的 柔軟度且在使用期間亦較爲靜謐。此較低厚度的薄膜,亦 本紙張尺度制悄A4im 筹 (請先閱讀背而之注意事項再本頁} —裝 本 、=口 -1 - I—- - · 齡| 4 3344 A7 B7 % 五、發明説明( 2 經濟部中央標準局貝工消費合作社印製Printed by A7 ------- B7 of the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs of the People's Republic of China 5. Description of the invention (丄 ^^ ~~ ~~ --This-application is requested from the US clause of July 15, 1996, please number 60 / 021,733 claims priority. H Long Background The present invention relates to the use of a positioning, low-thickness, breathable film that exists in film-nonwoven laminates. IL Bright Background Film-nonwoven laminates have been found to be widely used Used in a variety of applications including outer coverings for personal care absorbent articles such as diapers, child training pants, incontinence clothing, feminine hygiene products, sanitary napkins, wound dressings, bandages, and the like. Film Fabric laminates have also been found to have a range of uses in health care products, such as surgical tents and robes, clean room clothing, and disinfection and dressing; they are also used for rolled items, such as Tent materials and coverings for furniture, automobiles, and other transportation equipment. Especially in the field of absorbent articles for personal care, low-cost film-non-woven layer pressing will be emphasized The improvement of the product, which can simultaneously form _ effective screen ^ while expressing perfect visual beauty and tactile characteristics, to facilitate the passage of body secretions (liquid and other waste substances). One is applied to achieve this Satisfactory, low-cost film_ Non-woven laminate technology uses films that are gradually reduced in size or thickness. Thinned films typically also have a lower cost, and based on the reduced thickness, they are usually It has increased softness and is relatively quiet during use. This lower thickness film is also made by this paper standard A4im (please read the precautions on the back first, then this page) — installed, = 口 -1 -I—--· Age | 4 3344 A7 B7% V. Description of the invention (2 Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

較容易被提供具有透氣性或微孔性。 此薄的薄膜可具有一有效尺寸或厚度爲〇 6密耳或更 少,以及一基重爲每平方公尺25.0克(25 gsm)或更少。特 别的疋,當此低厚度薄膜藉由拉伸或延展(如於其機械方位) 而達成時,則此拉伸或延展作用將使位於此薄膜内的此聚 合物分子朝向於延伸的方向,因而增加了此薄膜於機械方 位上的強韌度。然而,此一相同的機械方向定位之薄膜, 其於橫跨方位上的抗張強度與捕捉撕裂特質,將轉趨變弱。 爲了彌補於此單一朝向延伸薄膜之結構的脆弱性,一 支持層(或多數支持層),例如一纖維性非織物,已被層壓形 成此薄膜層,以便形成一具有其它特性中的如提升的強韌 度與耐久性等的層壓製品。拉伸變薄之薄膜與非織物的層 壓製品,已利用熱層壓作用的技術而加以形成,其中熱與 壓力,如加熱模型滾筒及超音波皆已被應用。然而,薄膜 與非織物的的層壓作用中,用以此薄膜與非織物的聚合性 材料,其需具備熱可相容性,亦即此聚合物可以被熱粘合, 以傳送一 20克或更大的剝離強度。因此,熱層壓作用技術 限制了選擇薄膜與/或僅單就花費而言之非織造聚合物、處 理性與/或表現之標準等等的自由度。此外,甚至是熱可相 谷性的聚合物亦可能需要某一程度上的熱與壓力,其可能 造成所不欲發生的穿孔出現或位薄膜上,而造成此薄膜層 的破壞、以及/或造成層壓製品所不希望產生的剛硬性。最 後,此熱層壓的薄膜-非織物層壓製品於某些例子中,特别 是當其被應用作爲一個人看顧用吸收性物件的外覆蓋時, (讀先閱讀背面之注意事項再本頁) •裝. 訂 » 1- · - _ II- !-1 1 — ? - 11 - _ 本紙張尺度適用中國國家標準(CNS ) Λ4規格(2j〇x797公釐) C:\PATENT\Pk-001-040~~045~\Pk-001 ·0404\ρΚ-001-0404-1. ulf.doc. December 3 1, 19 9 7 5It is easier to be provided with breathability or microporosity. This thin film may have an effective size or thickness of 0.6 mils or less, and a basis weight of 25.0 grams (25 gsm) or less per square meter. In particular, when this low-thickness film is achieved by stretching or stretching (as in its mechanical orientation), then this stretching or stretching effect will cause the polymer molecules located in the film to face the direction of extension, Therefore, the toughness of the film in the mechanical orientation is increased. However, the tensile strength and tear-catching properties of the film oriented in the same mechanical direction will become weaker. In order to compensate for the fragility of the structure of the single-direction stretch film, a support layer (or most support layers), such as a fibrous non-woven fabric, has been laminated to form the film layer in order to form a layer with other characteristics such as lifting Laminated products such as toughness and durability. Stretched thin films and non-woven laminates have been formed using thermal lamination techniques, where heat and pressure, such as heating model rolls and ultrasound, have been applied. However, in the lamination of film and non-woven fabric, the polymer material using this film and non-woven fabric needs to be thermally compatible, that is, the polymer can be thermally bonded to transfer a 20 g Or greater peel strength. Therefore, thermal lamination techniques limit the freedom to choose films and / or nonwoven polymers in terms of cost alone, processing and / or performance criteria, and so on. In addition, even heat-stable valley polymers may require a certain degree of heat and pressure, which may cause unwanted perforations to appear on the film, causing damage to the film layer, and / or This results in an undesirable stiffness of the laminate. Finally, this heat-laminated film-non-woven laminate is used in some cases, especially when it is applied as an outer cover for a person's care with an absorbent article (read the precautions on the back and then the page) • Package. Order »1- ·-_ II-! -1 1 —?-11-_ This paper size applies to China National Standard (CNS) Λ4 specification (2j〇x797 mm) C: \ PATENT \ Pk-001- 040 ~~ 045 ~ \ Pk-001 0404 \ ρΚ-001-0404-1. Ulf.doc. December 3 1, 19 9 7 5

A7 B7 五 、發明説明(3 4 經濟部中央標準局員工消費合作社印褽 其所展現出不足的強韌度以及耐久性特質,造成此吸收性 物件使用期間,其中層壓製品的薄膜層發生嚴重的撕裂失 策。發明者已觀察到於此熱層壓製成的薄膜-非織物層壓製 品的撕裂失策,傾向於從熱粘合點或區域,即薄膜與非織 物層被粘結在一起的地方拓展開來。因此,存在一需求以 使薄膜-非織物層壓製品能結合一具有提升之強韌度與耐久 性特質’特别是在橫跨機械方位處的改良性單軸(亦即機械 方向)定位、低厚度的薄膜。IL明簡介 因此,本發明的一目的是基於將模型花樣或網狀結構 的粘合劑面積,施加至一纖維性非織物層之由此而生的表 面積上,藉由黏著性層壓一具有提升之強韌度與耐久性特 質之單軸定位、低厚度的薄膜,進而提供一改良的薄膜-非 織物層壓製品。 本發明的另一宗旨是提供一具有提升其強韌度與耐久 性特質’且其爲南度透氣性之低成本花費、黏著性結合的 薄膜-非織物層壓製品。 本發明尚且具有另一目標爲提供一改良之黏著性結合 的薄膜-非織物層壓製品,其將可避免用以形成此層壓製品 之薄膜與非織物層所需聚合性材料之熱相容性的需求。 以上所述的這些及其它目地的達成,是藉著申請專利 範圍第1項的此黏著性補強薄膜-非織物層壓製品,其包 含: ( cns ) A4^ (A7 B7 V. Description of the invention (3 4 The Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs printed the inadequate toughness and durability characteristics, which caused serious damage to the laminated film layer during the use of this absorbent article. Tear failure of the film. The inventors have observed that the tear failure of the film-nonwoven laminate produced by this heat lamination tends to be bonded from the thermal bonding point or area, that is, the film and the nonwoven layer There is a need to enable film-nonwoven laminates to combine an improved toughness and durability characteristics, particularly modified uniaxial (i.e., Mechanical direction) oriented, low-thickness film. Brief introduction to IL. Therefore, an object of the present invention is to apply the adhesive area of a model pattern or a network structure to the resulting surface area of a fibrous nonwoven layer. In addition, by adhesively laminating a uniaxially-oriented, low-thickness film with improved toughness and durability characteristics, an improved film-non-woven laminate is provided. Another object of the present invention is to provide a film-non-woven laminate product which has the characteristics of improving its toughness and durability, and which is a low-cost cost, adhesive combination of Nando breathability. The present invention also has another object as To provide an improved adhesive-bonded film-nonwoven laminate that will avoid the need for thermal compatibility of the film and non-woven layer with the polymeric material required to form the laminate. These and other objectives are achieved by applying this adhesive reinforcing film-non-woven laminate product under the scope of patent application No. 1 which includes: (cns) A4 ^ (

December 3 1, 19 9 7 (請先閱讀背面之注意事項再December 3 1, 19 9 7 (Please read the notes on the back before

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A7 B7 五、發明説明(4 一具有一表面的纖維性非織物層; 一具有一表面的薄膜層; 前述的薄膜層被定位於一延伸方向,並具有一有效厚 度爲0.6密耳或更少; 前述的薄膜層是由一掺合物所形成,基於此薄膜層的 總重、以一總重百分比基重爲基準,其包括由大約3〇百分 比至大約70百分比的一第一聚烯烴聚合物、由大約7〇百 分比至大約30百分比的一填充料、以及從大約〇百分比至 2〇百分比的一第二聚烯烴聚合物, 如述的薄膜層具有一水蒸氣傳輸率至少約爲每平方公 尺每24小時300克; 一模型花樣的粘合劑面積被施加於前述薄膜層的表面 上; 月IJ述之模型花樣的枯合劑面積具有一從每平方公尺大 約0.1至大約20克(0_1〜20 gsm)的添加總量、一占前述薄 膜層表面之每單位面積由大約5百分比至大約50百分比的 結合面積、以及一通常平行於前述延伸方向上之粘合劑面 積間的最大距離約爲1 ·〇英吋或更小; 如述纖維性非織物層的表面,藉由將前述之模型花樣 的枯合劑面積施加至前述薄膜層表面,而被附著至前述薄 膜層的表面上,以形成一層壓製品。 本發明其它的優異特徵、層面與詳情,將由所附之申 請專利範圍、此處的描述、以及圖式而加以證實。此處的 專利申請範圍意欲被理解爲一第一優先之非限制路徑,以 (請先閱讀背面之注意事項再A7 B7 V. Description of the invention (4-a fibrous non-woven layer with a surface; a film layer with a surface; the aforementioned film layer is positioned in an extending direction and has an effective thickness of 0.6 mil or less The aforementioned film layer is formed by a blend, based on the total weight of the film layer, based on a total weight percentage basis, which includes a first polyolefin polymerized from about 30% to about 70% Material, a filler from about 70% to about 30%, and a second polyolefin polymer from about 0% to 20%, such as a film layer having a water vapor transmission rate of at least about per square meter 300 grams per 24 hours; an adhesive pattern area of a pattern is applied to the surface of the aforementioned film layer; the area of the desiccant of the model pattern described in IJ has a range from about 0.1 to about 20 grams per square meter ( 0_1 ~ 20 gsm), a combined area per unit area of the surface of the aforementioned film layer from about 5 percent to about 50 percent, and an area generally parallel to the aforementioned extension direction The maximum distance between the mixture areas is about 1.0 inches or less; as described on the surface of the fibrous non-woven layer, the area of the mixture of the above-mentioned model pattern is applied to the surface of the film layer, and is attached to the surface The surface of the film layer is formed to form a laminate. Other outstanding features, aspects and details of the present invention will be confirmed by the scope of the attached patent application, the description herein, and the drawings. The scope of the patent application here is intended Is understood as a first priority non-restricted path, (Please read the precautions on the back before

-訂 鲤濟部中央榡準局員工消費合作社印製 表紙張尺度適用中國國家榡準(CNS ) A4規格(210X297公釐) .⑽.7 M//:d〇c 1 99: 7 川44 Α7 Β7 五 發明説明(5 便概論性地界定本發明。 麗式簡要描述 圖1爲一根據本發明所形成的黏著性補強的透氣性、 似布之薄膜-非織物層壓製品的棋橫切剖視圖。 圖2爲一被施加至根據本發明所形成的一薄膜層的表 面之任意模型花樣的熔喷粘合劑纖維的一正視圖,於其中 此薄膜層的延伸方向以線χ — χ指示。 圖3爲一被施加於根據本發明所形成之薄膜層的表面 上之肋狀印製著色的粘合劑面積的正視圖,於其中此薄膜 層的延伸方向以線x—x表示。 、 圖4爲一被施加於根據本發明所形成之薄膜層的表面 上之雲朵狀印製著色的粘合劑面積的正視圖,於其中此薄 膜層的延伸方向以線χ — χ表示。 圖5爲一具有本發明之黏著性補強薄膜_非織物層壓製 品爲外覆蓋之尿布的透視圖。-The paper size of the printed paper for the consumer cooperatives of the Central Government Bureau of the Ministry of Economic Affairs of the People's Republic of China is applicable to the Chinese National Standard (CNS) A4 (210X297 mm). ⑽.7 M //: doc 1 99: 7 Chuan 44 Α7 Β7 Five invention descriptions (5 will define the present invention in an overview. Rebecca brief description Figure 1 is a cross-sectional view of a chess-like film-non-woven laminate of adhesive-reinforced breathable, cloth-like film formed according to the present invention Fig. 2 is a front view of a meltblown adhesive fiber of any pattern applied to the surface of a film layer formed according to the present invention, in which the direction of extension of the film layer is indicated by the line χ-χ. FIG. 3 is a front view of an area of a ribbed printed colored adhesive applied to the surface of a thin film layer formed according to the present invention, wherein the extension direction of the thin film layer is indicated by line x-x. 4 is a front view of an area of a cloud-like printed colored adhesive applied to the surface of a thin film layer formed according to the present invention, in which the extension direction of the thin film layer is indicated by lines χ-χ. Figure 5 is Adhesive reinforcing sheet with the present invention A perspective view of the non-compressed product is a fabric layer of the outer cover of the diaper _.

I _發明§羊細描j术 本發明是關於—改進的薄膜_非織物層壓冑品,其利用 將厂模型花m或網#結構的枯纟劑面積施加至此層壓製品 的薄膜層_L,以增進此結合具有此薄膜的單軸定位典型 爲機械方向的薄膜與此薄膜-非織物層壓製品的耐久性與強 韌度。僅爲説明之目的,本發明將以其被作一個人看顧用 吸收性物件’其包括尿布、訓練用褲、失禁用衣物、衛生 本紙乐尺度適用 CNS ^ A4^ (2l〇x29~^'JATE^Pk'nm·^ 取 ’ December 31, 19 9 7 (請先閱讀背面之注意事項再HI本頁;> -裝 經濟部中央榡準局員工消費合作社印# 8 3344 A7 B7 經濟部中央標準局員工消費合作社印製The invention relates to an improved film_non-laminated laminate, which utilizes the area of a deadening agent applied to a plant model flower or a mesh structure to the film layer of this laminate_ L, to improve the durability and toughness of this film combined with the uniaxial positioning of the film, which is typically a mechanical direction film and this film-nonwoven laminate. For illustrative purposes only, the present invention will be used as an absorbent article for personal care, which includes diapers, training pants, incontinence clothing, hygienic paper, and paper scales applicable to CNS ^ A4 ^ (2l0x29 ~ ^ 'JATE ^ Pk'nm · ^ Take 'December 31, 19 9 7 (Please read the precautions on the back before HI this page; >-Installed by the Consumer Affairs Cooperatives of the Central Bureau of the Ministry of Economic Affairs # 8 3344 A7 B7 Central Bureau of Standards, Ministry of Economic Affairs Printed by Employee Consumer Cooperative

經濟部中央蒙赁M f靠社印製 3344 如用於此處的專門術語" 可具有雙重意義,其可表示一:一、’一物’當以單數使用時 用於此處的專門術語"層壓製σ,,70件或多數的70件。女 材料所製成、或彼此附著或:人’意指一由二或多層的㈣ 用於此處的專門術語"非織品;之材料的織物。如 織品般固定重覆之交二織:而但:並不-如針織物或 士八 、*太而,應被注意的是,銳缺 =月將”織品或非織物之關點做描述,由適當的材: 所製成的織品與/或針織品 此處之以㈣於被制來做爲如描述於 機^ ▲支持層的層㈣品。如用於此處的專門妙· =:"或_’意爲—材料或織品被製造產生之=的 …專門術語"橫跨機械方向"或 品的寬度’亦即通常垂直於MD的方向。 材科成織 维七Γ業可仔的熱塑性聚合材料可有利地被應用來製造纖 長纖,其非織物層(16)由此而形成。如用於此處的專門 ::吾聚合物"’其應包括但不限製爲均聚物、共聚物,舉例 如嵌塊、接枝、任意與交替共聚物、三元聚合物等, 乂及由此而生的摻合物與調節物。更甚者,除了特别的限 疋(外,此專門術語"聚合物"應包括所有可能的材料幾何結 構,,包括但不限制爲全同立構、間同立構任意以及 無規立構對稱。如用於此處的專門術語"熱塑性聚合物"或" 熱::聚合材料'意指一當其曝露於熱時會軟化,而冷卻 至至m時則固化的長鏈聚合物,典型的熱塑性材料包括但 不限制爲聚氣化乙埽、聚醋自、聚酿胺類、聚碳氣、聚Printed by the Central Government Department of the Ministry of Economic Affairs 3344 If the term used here " can have a dual meaning, it can mean one: one, 'one thing', a term used here when used in the singular " Layer pressing σ, 70, or most of 70. Female material is made of, or attached to each other or: a person 'means a fabric made of two or more layers of the term "non-woven". It is fixed and repeated as a fabric: but but: not-such as knitted fabrics or Shiba, * Taihe, it should be noted that sharp lack = month will be described as the point of fabric or non-fabric, Appropriate material: Fabrics and / or knitwear made here are made here as they are described in the machine ^ ▲ support layer. As specially used here =: " or _ 'means—the material or fabric produced is = ... the special term " across the mechanical direction " or the width of the product', that is, the direction generally perpendicular to the MD. The thermoplastic polymer material that can be used can be advantageously used to make long fibers, and the non-woven layer (16) is formed from it. As used here specifically :: My polymer " 'It should include but is not limited to Homopolymers, copolymers, such as block, graft, arbitrary and alternating copolymers, terpolymers, etc., and the resulting blends and regulators. Moreover, except for special restrictions (In addition, the term " polymer " shall include all possible material geometries, including but not limited to full Isotactic, syndiotactic arbitrary, and atactic symmetry. As the term used herein " thermoplastic polymer " or " Heat :: Polymeric material " means when it is exposed to heat, it will Long-chain polymers that soften and solidify when cooled down to m. Typical thermoplastic materials include, but are not limited to, polyacetate, polyacetate, polyamines, polycarbon,

ulf.doc 997 (請先閱讀背面之注意事項再本頁) 、玎 齡-------------- 513344 Α7 Β7 五、發明説明(8 栗氦丞甲酸乙酯、聚苯乙埽 策乙烯醇 經濟部中央標準局負工消費合作社印繁 …一 吁、已内酿脖、 以及述之物的共聚物。用於製造非織物層⑽可 任何適宜料態,^包括中空或固態的纖維;直或捲: 的纖維,雙組成、多組成、雙成分複合、 : 維’以及此類纖維的摻合物或混合物:勒刀複口g ,纖已== 續的,如㈣長纖。纖維的厚度可以被調^達 的特質’適合於最終使用的應用。舉例來説,於個人看顧 用吸收性物件,平均纖維直徑之典 微米至大约30微米。 1C 可被應用來做爲本發明之非織物層(16)的非織物,可 以藉由各式不同已知的成形過程而加以形成,纟包括㈣ 法、氣流舖網、或枯合梳理成形處理過程。纺枯非織物是 由熔纺長、纖所製成。如用於此處的專門術語"炫纺,,,意指小 直徑的纖維與/或長纖,其是藉由從一紡絲板上之多數細、 且通常爲捲曲的毛細f ’擠壓—㈣熱塑性材料如長纖, 其被擠壓之長纖的直徑將藉著舉例來説如非析引、或析引 4伸或其^熱知的紡粘機制,進而被快速地縮小。最後, 此熔、.方長纖以一貫質上爲任意的形式,而被沈積於一移動 的運輸皮帶或其相似物上,以形成一實質上爲連續的、且 爲隨思排列的炼纺長纖。紡粘長纖一般而言在被沈積於收 禁表面上時’是不具黏性的。紡粘非織物的產生被描述於 Ppe丨等人所申凊的美國專利編號4 340 563、Dorschner 等人所申請的美國專利編號3,692 618、Matsuki等人所申 (請先閱讀S之注意事項再U:本Ϊ 裝· 本紙張尺度適用中國國 C:\PATENT\Pk-001-<M0-(M5-\Pk-O0J-040^\ph00^CH(M^Mir.doc December 31, 19 97 η 513344 Α7 Β7 麻 經濟部中央標準局員工消費合作社印製 五、發明説明(9 ) 請的美國專利編號3,802,817、Kinney等人所申請美國專 利編號3,338’992與3,341,394、Hartman等人所中請美國 專秉利編號3,502,763 、 Levy所申請的美國專利編號 3,276,944、Peterson所申請的美國專利編號3 5〇2,538、 以及Dobo等人所申請的美國專利編號3,542,615,以上所 有皆合併於此以供參考。此熔紡長纖藉由紡粘製程而形成, 其通常爲連續的,且基於至少5次的測量値得知,具有一平 均直徑大於7微米,且更特别的是介於大約1 〇至1 〇〇微米 之間。另一經常使用的纖維或長纖直徑的表示法爲丹尼爾 (denier),其界定爲每9000公尺之纖維或長纖的克數。 此紡粘製程亦可被利用來形成雙組成紡粘非織物,舉 例來説如由併列或鞘芯線性低密度聚乙烯/聚丙烯紡粘雙組 成長纖。一適合用來形成此雙組成紡粘非織物的製程,被 描述於Pike等人所申請的美國專利編號5,418 〇45,其被 完整合併於此以供參考。簡言之,用來形成此雙組成長纖 與結果織物的此製程,其包括利用一對擠壓器,以便分别 提供此聚合組成至一雙組成紡絲板。用以產生雙組成長纖 的纺絲板已熟知於此技術領域中,故於此不多做贅述。一 般而T,此紡絲板包括一含有一紡絲組件的罩,其包括一 多數包含排列成模型開孔的垂直堆疊板,用來產生流動路 徑’以便分别地引導此高熔融溫度、與低熔融溫度的聚合 物至此位於纺絲板上的纖維-成形開孔。此紡絲板具有排列 成一或多數列的開孔,當此聚合物皮擠壓通過此紡絲板時, 將形成一向下延伸的長纖帘幕。當此長纖帘幕退出此紡絲 ---------¢-- (請先閱讀背面之注意事項真θ本ϊ 訂 ,1-1 _ -— 1- -- 11— 1 I I - C:\PATRI\n\ Plc.nm^ηΔη^.ηΔ<^\ Dunni.παπακ ^ πηι^πΑΠΛ. ι %ΑίΑητulf.doc 997 (please read the notes on the back first, then this page), 玎 Age -------------- 513344 Α7 Β7 V. Description of the invention Phenylacetate encourages Vinyl Alcohol, Central Standards Bureau, Ministry of Economic Affairs and Consumer Cooperatives to print and print ... copolymers that have been brewed, and have been blended. It can be used in the manufacture of non-woven fabrics. Any suitable material state, including hollow Or solid fibers; straight or rolled fibers: bi-component, multi-component, bi-component composite,: dimensional, and blends or mixtures of such fibers: dagger compound mouth g, fiber == continued, such as ㈣Fiber. The characteristics of the thickness of the fiber can be adjusted to suit the end-use application. For example, in personal care absorbent articles, the average fiber diameter is from the typical micron to about 30 microns. 1C can be applied to The non-woven fabric as the non-woven layer (16) of the present invention can be formed by various different known forming processes, including a method, air-laying, or a carding process. Fabrics are made of melt-spun long, fibers. As the term used here & "Hyun spinning," means small diameter fibers and / or filaments, which are extruded from a thin, and usually crimped, capillary f 'of a spinning plate-a thermoplastic material such as filament The diameter of the extruded filament will be rapidly reduced by, for example, non-extraction, or extensibility, or its well-known spunbond mechanism. Finally, this fusion, square The fibers are generally in any form and are deposited on a moving conveyor belt or the like to form a continuous spun filament that is substantially continuous and arranged in a random manner. Spunbond filaments are generally In terms of being 'non-sticky' when deposited on a banned surface, the production of spunbond nonwovens is described in US Patent No. 4 340 563 filed by Ppe 丨 et al., And US Patent No. 4 applied by Dorschner et al. No. 3,692 618, Matsuki et al. (Please read the precautions of S first, then U: this installation · this paper size applies to China C: \ PATENT \ Pk-001- < M0- (M5- \ Pk-O0J -040 ^ \ ph00 ^ CH (M ^ Mir.doc December 31, 19 97 η 513344 Α7 Β7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Explanation of the invention (9) U.S. Patent No. 3,802,817, Kinney and others applied for U.S. Patent Nos. 3,338'992 and 3,341,394, Hartman and others have requested U.S. Patent No. 3,502,763, and Levy's U.S. Patent No. 3,276,944, Peterson U.S. Patent No. 3,502,538, and U.S. Patent No. 3,542,615, applied by Dobo et al., All of which are incorporated herein by reference. This melt-spun filament is formed by a spunbond process, which is usually continuous and based on at least 5 measurements. It is known that it has an average diameter greater than 7 microns, and more particularly between about 10 to 1 〇stroms. Another commonly used representation of the diameter of a fiber or filament is denier, which is defined as the number of grams of fiber or filament per 9,000 meters. This spunbond process can also be used to form bi-component spunbond non-woven fabrics, such as spunbond double-row growth fibers made of side-by-side or sheath-core linear low density polyethylene / polypropylene. A process suitable for forming this two-component spunbond nonwoven is described in U.S. Patent No. 5,418,040, filed by Pike et al., Which is incorporated herein by reference in its entirety. Briefly, the process used to form the bi-component filaments and the resulting fabric involves the use of a pair of extruders to separately provide the polymeric composition to a bi-component spinneret. Spinning boards for producing bi-component filaments are well known in this technical field and will not be described in detail here. Generally, the spinneret includes a cover containing a spinning assembly, which includes a plurality of vertically stacked plates including a plurality of patterned holes arranged to create a flow path to guide the high melting temperature, and The low-melting-temperature polymer thus lies on the fiber-shaped openings of the spinneret. The spinneret has openings arranged in one or more rows, and when the polymer sheath is squeezed through the spinneret, a long-fiber curtain extending downward is formed. When this long-fiber curtain is withdrawn from this spinning --------- ¢-(Please read the precautions on the back first, true θ order, 1-1 _ -— 1--11— 1 II -C: \ PATRI \ n \ Plc.nm ^ ηΔη ^ .ηΔ < ^ \ Dunni.παπακ ^ πηι ^ πΑΠΛ. Ι% ΑίΑητ

513344 經濟部中央標準局員工消費合作社印製 Α7 Β7 五、發明説明(10) 板時,此長纖帘幕的一側或兩側與一驟冷空氣接觸,其至 少邵份淬冷此長纖,並且在由紡絲板延伸而來的長纖内, 發展成一潛藏性的捲曲。典型地,此驟冷的空氣通常將以 一速度從每分鐘大約30至大約1 20公尺、以及一溫度大約 爲攝氏7度(。C)至大約3 2。C的狀態下,被導引至與此長纖 的長度方向垂直。 一纖維拉引單位或吸絲器被置放於此紡絲板的下方, 以便接收此驟冷長纖。用於熔紡聚合物中的纖維拉引單位 或吸絲器已被熟知於此技術領域中。適合用於此製程之典 型的纖維拉引單位,包括一顯示於Matsuki等人所申請的美 國專利編號3,8 0 2,81 7中的線性纖維吸絲器型態、以及513344 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs A7 B7 V. Description of the invention (10) When one or both sides of this long-fiber curtain is in contact with a quench air, it should at least quench the filament And develops into a latent crimp in the filaments extending from the spinneret. Typically, this quenched air will typically be at a speed from about 30 to about 120 meters per minute, and a temperature of about 7 degrees Celsius (.C) to about 32 degrees Celsius. In the state of C, it is guided perpendicularly to the longitudinal direction of the filament. A fiber drawing unit or suction device is placed under the spinneret to receive the quenched filament. Fiber drawing units or spinnerets for use in melt-spun polymers are well known in the art. Typical fiber drawing units suitable for this process include a linear fiber suction device type shown in U.S. Patent No. 3,8 0 2,81 7 filed by Matsuki et al., And

Dorschner等人所所申請的美國專利編號3,692,61 8之析引 槍型態、以及Davies等人所申請的美國專利編號 3,423,266 ’其所揭示者被完整合併於此以供參考。此纖維 拉引單位一般具有一延長的通道貫通此被吸絲氣流拉引通 過此通道的長纖。此吸絲氣體可以是任何的氣體,例如空 氣,其將不會不利地與此長纖聚合物相互作用。一傳統結 構的加熱器施加熱的吸絲氣體至纖維拉引單位中。當此吸 絲氣體拉引此驟冷長纖與周遭空氣通過此纖維拉引單位 時,此長纖被加熱至活化此潛藏捲曲於其内的溫度。活化 /ΕΪ藏於長纖内的捲曲所需的溫度’典型地範圍將從大約 43°C至一最大溫度爲小於低熔融組成纖維的熔點。一般而 言,一較高空氣溫度將使每單位長度的長纖產生較多的捲 曲。另一選擇是,此退出紡絲板的長纖帘幕可以在一室溫 _Q:\P/iTENT\Pk-00Un4fU-/x>iir、 本紙張尺度適用中國國家標準(CNS ) Μ規格(210X297公釐) 謂謂 (請先閱讀背面之注意事項再本頁) •裝. 、11 13 ,13344 經濟部中央標準局員工消費合作社印製 A7 B7五、發明説明(U) ^ 一~一 下被拉引,接著形成一實質上爲直線或非捲曲的紡粘長纖 織物。 此被拉引且捲曲的長纖退出此纖維拉引單位,並以一 任思形式、且通常將藉助一置放於成形表面下方的眞空裝 置,而被沈積於一連續成形表面上。此眞空的目的是消除 所不欲產生之長纖的散亂散現象,且可引導長纖至此成形 表面上,以形成一均質的、非粘合的雙組成長纖非織物。 如果可望的話,此結果產生的雙組成紡粘織物,可以接受 如描述於下方之預粘合、或第二粘合作用的處理。 紡粘織物在它們被製造產生時,通常會被以某些形式 加以穩定化或凝固,以便提供此織物足夠的完整性與強韌 度,使之能經得起進一步嚴酷的製造處理過程,進而形成 最終產物。此預粘合作用的步驟,可經由將一以液態或粉 末狀之可被加熱活化的粘合劑施加至此長纖上而被完成, 或者更一般性的則是利用密實滾筒。如用於此處的專門術 語Π密實滾筒π,意爲一組位於此非織物上方與下方的滾筒, 其是藉著處理一剛被製造產生、熔紡長纖、特别是紡粘織 物,而被用來緊密此織物,以便能提供此織物充分的完整 性以承受進一步的製程,但其相對上並不如後來施加的、 即第二枯合處理,例如像是貫通空氣粘合法、熱粘合法、 超音波粘合法、以及其相似方法般的強韌。密實滾筒輕微 地壓榨此織物,以便增加織物本身的粘附性及因而產生的 完整性。 一典型的第二枯合處理利用一模型滚筒裝置,以便熱 (cnsTa^# (210x297^1 _ - 1 I · (請先閲讀背面之注意事項再本頁) -裝· -一口 ,13344 、發明説明(12) 經濟部中央標準局員工消費合作社印聚 枯合此㈣織物^此滚筒裝置典型地包括—模㈣合滾筒 及平滑站輥’其共同界定了一熱模型的粘合壓軋。另一選 擇是,此⑽在它的外表面Λ,亦可擁有—枯合模型。此 棋型滾筒藉由傳統的加熱裝置而被加熱至_適合枯結的溫 度,且藉著傳統的驅動裝置加以旋轉,如此則當此妨枯織 物通過此壓軋時,—系列的熱粘模型粘合將被形成。存在 於壓礼内部的壓乳壓力,應足以達到所可望之枯合此織物 的程度,以提供形成此織物的線性速度、粘合溫度與材料。 就此紡粘織物而言’其典型之百分比結合面積的範園,將 位於從大約1 〇百分比至20百分比之内。 熔喷纖維的形成,其是藉由擠壓熔融熱塑性材料通過 一多數微細、且通常爲捲曲的模具毛細管形成如熔融絲或 長纖,接著進入相對流動之高速、且通常被加熱的氣體流 中,諸如空氣,其將使得此熔融熱塑性材料的長纖變細, 因而降低了它的直徑,並斷裂此流體而形成小直徑的非連 續性纖維。於此之後,此熔喷纖維被沈積於一收集表面上, 以形成一任意分散之熔喷纖維的織物。此熔喷織物基於位 在織物内之個别纖維的纏繞交疊、以及同時在彼此纖維之 間具有某些程度上的熱或自身粘結性,特别是當其擠壓後 到產生收禁作用間僅爲極短距離時,而擁有其完整性。此 熔喷處理過程已被熟知,且被描述於不同的專利中並被發 表出版,其包括由Β·Α· Wendt 、 E.L. Boone以及CD Fluharty發表於NRL報告4346,標題爲”超細有機纖維的 製造”(丨Manufacture of Super -Fine Organic Fibers"); K.D. (請先閲讀背vg之注意事項再 本I) •裝· 訂 本紙張尺度適用中國國家標準(CNS ) A4規格(2l〇X297公釐) C:\PAmm\P±g〇b(M〇-.(H5~\Pk-〇〇i-n4〇4\Dk.〇oun4〇4-i.uirHnr 199: 15 5i3344 A7 B7 五、發明説明(13)An analysis of the gun type of U.S. Patent No. 3,692,61, filed by Dorschner et al., And U.S. Patent No. 3,423,266, filed by Davies et al., The disclosures of which are incorporated herein by reference in their entirety. The fiber drawing unit generally has an elongated channel passing through the filaments drawn by the suction airflow through the channel. This suction gas can be any gas, such as air, which will not adversely interact with this filament polymer. A conventional structured heater applies hot suction gas to the fiber drawing unit. When the sucking gas pulls the quenched filament and the surrounding air through the fiber pulling unit, the filament is heated to a temperature that activates the latent curl inside it. The temperature ' required to activate the crimping within the filaments ' typically ranges from about 43 ° C to a maximum temperature that is less than the melting point of the low-melting constituent fibers. In general, a higher air temperature will produce more curls per filament length. Another option is that the long-fiber curtain that exits the spinning plate can be at room temperature_Q: \ P / iTENT \ Pk-00Un4fU- / x &i; iir. 210X297 mm) Predicate (please read the precautions on the back and then this page) • equipment., 11 13, 13344 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Description (U) ^ ~~ Pulling, followed by forming a substantially straight or non-curly spunbond filament fabric. The drawn and crimped filament exits the fiber drawing unit and is deposited on a continuous forming surface in an arbitrary form and usually by means of a hollowing device placed below the forming surface. The purpose of this hollowing is to eliminate the undesired scattering of the long fibers, and to guide the long fibers to the forming surface to form a homogeneous, non-adhesive two-component long fiber nonwoven fabric. If desired, the bicomponent spunbond fabric produced by this result can be treated as described in the pre-bonding, or secondary bonding, described below. Spunbond fabrics are usually stabilized or solidified in some form when they are produced, in order to provide the fabric with sufficient integrity and toughness, so that it can withstand further harsh manufacturing processes, and The final product is formed. This pre-bonding step can be accomplished by applying a heat-activatable adhesive in liquid or powder form to the filament, or more generally using a compact roller. As used herein, the term Π compact roller π means a set of rollers above and below this non-woven fabric, which is processed by processing a newly produced, melt-spun filament, especially spunbond fabric, and It is used to compact the fabric so as to provide the fabric with sufficient integrity to withstand further processing, but it is not as good as later applied, that is, a second closing process, such as through-air bonding, heat bonding Legal, ultrasonic bonding, and similar methods. The compact roller compacts the fabric slightly to increase the adhesion of the fabric itself and the resulting integrity. A typical second dehydration process uses a model roller device to heat (cnsTa ^ # (210x297 ^ 1 _-1 I · (Please read the precautions on the back before this page))-Install · -One mouth, 13344, invention Explanation (12) The consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, a consumer cooperative, printed this fabric ^ This roller device typically includes a die bonding roller and a smoothing station roller, which together define a thermal model of bonding and rolling. Another One option is that this ⑽ can also have a deadlock model on its outer surface Λ. This chess roller is heated to a temperature suitable for deadlock by a traditional heating device, and is applied by a traditional driving device. Rotate, so that when this embarrassing fabric passes through this rolling, a series of hot-adhesive model bonding will be formed. The crimp pressure existing inside the embossing should be sufficient to achieve the desired degree of embossing of the fabric In order to provide the linear speed, bonding temperature, and materials that form this fabric. For this spunbond fabric, 'the typical percentage of bonded area's range will be from about 10% to 20%. Meltblown fiber's Formation, which is Forming extruded molten thermoplastic material through a plurality of fine and usually crimped mold capillaries, such as molten filaments or filaments, and then into a relatively high-speed, usually heated gas stream, such as air, will make this The filaments of the molten thermoplastic material become thinner, thereby reducing its diameter, and breaking the fluid to form discontinuous fibers of small diameter. Thereafter, the meltblown fibers are deposited on a collection surface to form an arbitrary A fabric of dispersed meltblown fibers. This meltblown fabric is based on the entanglement of individual fibers within the fabric, and at the same time has some degree of thermal or self-adhesion between the fibers of each other, especially when it is The integrity after extrusion is only a short distance from the time when the forbidden effect occurs. This meltblown process has been well known and has been described in different patents and published, including by Β · Α · Wendt, EL Boone, and CD Fluharty published in NRL report 4346, entitled "Manufacture of Super -Fine Organic Fibers" (K manufacturing) (Please read the precautions of the back vg before this I) • The size of the paper for binding and binding is applicable to the Chinese National Standard (CNS) A4 specification (2l0 × 297mm) C: \ PAmm \ P ± g〇b (M〇- . (H5 ~ \ Pk-〇〇i-n4〇4 \ Dk.〇oun4〇4-i.uirHnr 199: 15 5i3344 A7 B7 V. Description of the invention (13)

Lawrence、R.T. Lukas 以及 J.A. Young 發表於 NRL 報告 5265 ,標題爲n用以形成超細熱塑性纖維的一改良式裝置 ,’(An Improved Device for the Formation of Super-Fine Thermoplastic Fibers”); Prentice所申請的美國專利編號 3,676,242 ; Buntin等人所申請的美國專利編號 3,849,241 ;以及Appel等人所申請的美國專利編號 4,720,252 ;其所有的揭示皆完整合併於此以供參考。一般 而言,包含於熔喷纖維内的熔喷纖維具有一平均纖維直徑 可咼至1 0微米’其如果有的話將具有相當少的纖維直徑超 過1 0微米。通常存在於此熔喷織物内的此纖維的平均直徑 約爲2-6微米。當此存在於熔喷織物内的纖維爲顯著地非 連續性時,此纖維通常具有一超過一般短纖的長度。 用來製造本發明之合適的非織物,亦可由粘合梳理織 物與氣流舖置織物所製成。粘合梳理織物由短纖形成,其 通常以一捆貨物的形式被購得。此捆被置放在一梳毛機中, 其將會分離此纖維。然後,此纖維被送往通過一梳毛或梳 理單位,其將進一步斷裂分離並排列此短纖於機械方向, 以形成一通常爲機械方向定位的纖維性非織物。一旦此織 物被形成,它可以如描述於此的方法而被結合。 氣流舖置是另一個熟知的處理方法,藉由此則纖維性 非織物可以被形成。於此氣流舖置處理法中,成束之具有 長度範園從大约6至大約1 9公釐(mm)的小纖維被分離,並 於提供的氣體中被運載,然後通常在一施加眞空的情況下, 將之沈積於一成形網幕上。然後此任意沈積的纖維可以利 (請先閱讀背面之注意事項再本頁) 裝· 、-t 經濟部中央標準局員工消費合作社印製 木紙張尺度適用中國國家標準(CNS ) A4規格(210X297公楚) ^:\ΡΑΤΕΝΊ\Ρ^001-040^045~\ΡΗ-001Ό4(Μ\ρ^001-0404-ΐΜΐΓ.ά〇€ I b € 99 7 16Lawrence, RT Lukas, and JA Young, published in NRL report 5265, titled "An Improved Device for the Formation of Super-Fine Thermoplastic Fibers"; "(An Improved Device for the Formation of Super-Fine Thermoplastic Fibers"); U.S. Patent No. 3,676,242; U.S. Patent No. 3,849,241 filed by Buntin et al .; and U.S. Patent No. 4,720,252 filed by Appel et al .; all of their disclosures are hereby incorporated by reference in their entirety. Generally, they are included in meltblown fibers The meltblown fibers inside have an average fiber diameter of up to 10 microns, which, if any, will have relatively few fiber diameters in excess of 10 microns. The average diameter of the fibers typically present in this meltblown fabric is about 2-6 microns. When the fibers present in the meltblown fabric are significantly discontinuous, the fibers usually have a length that exceeds that of ordinary staple fibers. Suitable non-woven fabrics for use in the present invention can also be made by bonding Carded and air-laid fabrics. Bonded carded fabrics are made of staple fibers and are usually purchased as a bundle The bundle is placed in a carding machine, which will separate the fibers. The fibers are then sent through a carding or carding unit, which will further break apart and arrange the short fibers in the mechanical direction to form A fibrous nonwoven that is usually oriented in a mechanical direction. Once the fabric is formed, it can be combined as described herein. Airlaid is another well-known processing method whereby the fibrous nonwoven can be Is formed. In this air-laying process, bundles of small fibers having a length ranging from about 6 to about 19 mm (mm) are separated and carried in the supplied gas, and then usually in a In the case of applying air pressure, it is deposited on a forming screen. Then this randomly deposited fiber can be used (please read the precautions on the back first and then this page). The size of wood-making paper is applicable to China National Standard (CNS) A4 (210X297). ^: \ ΡΑΤΕΝΊ \ Ρ ^ 001-040 ^ 045 ~ \ ΡΗ-001Ό4 (Μ \ ρ ^ 001-0404-ΐΜΐΓ.ά〇 € I b € 99 7 16

經濟部中央榡準局員工消費合作社印製 五、發明説明(14) 用已知的粘結技術,而被結合至另外其它的纖維上。 ,利用如本發明中的纖維性非織物層(16)亦可形成層壓 製品。此類的層壓製品包括如所指示的紡粘/熔喷層壓製 品、以及紡粘/熔喷/紡粘層壓製品,舉例來説,如日⑺以等 人所申請的美國專利編號4,041,2〇3中,其所揭示者被完整 合併於此以供參考。具紡粘/熔噴的層壓製品,其通常更可 望的是將此層壓製品的熔嘴部分附著至此薄膜層上。此外, 於特疋的應用中,其被可望能添加額外的層至薄膜_非織物 層壓製品,譬如舉例來説,將一第二非織物或其它的支持 層附著至相對於此薄膜層之第一或其它非織物層的表面 上。再次地,此第二支持層可以是,舉例來説爲一如描述 於此處之單一層的非織物材料或一層壓製品。 薄膜層(12)包括至少二個基本的組成:一聚烯烴聚合 物,較好疋一優勢的線性聚烯烴聚合物,例如線性低密度 聚乙烯(LLDPE)或聚丙烯,以及一填充料。這些組成被混合 在一起、加熱然後利用各式不同的、熟知於精通此薄膜生 產製造·過程技術之人士的薄膜製造處理過程中的其中一種 方法,將之擠壓形成一薄膜層。此薄膜製造過程包括,舉 例來説如鑄膜拷紋壓花、驟冷與直絲無捻鑄膜、以及吹塑 薄膜處理過程。其它的添加劑與配料可以被加入所提供的 此薄膜層(1 2)中,它們將不會明顯地干擾根據本發明所敎授 而行使其功能的此薄膜層的能力。 一般而言,基於此薄膜的總重、以一乾重基重而言, 此薄膜層(12)將包括由大約30至大約70重量百分比的聚烯 . --—-— ---C:\PATEPn\PhOO 1^040~Ό45ΛΡ^001>(Μ04\ρ^001-0404-1 ulfrlnr 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) /99, 17 (請先閱讀背面之注意事項再9本頁) •裝· 、\# 513344 A7 B7 五、發明説明(ls) 聚合物、以及由大約30至大約70重量百分比的塡充料。 於某些特殊的實施例中,它可能額外包括由大約0至大约 2〇重量百分比之另外的聚烯烴聚合物,例如像是低密度聚 乙埽。 當線性低密度聚乙烯與適宜總量的一塡充料互相摻合 而當作一薄膜基質時,其已被發覺可具有良好的表現。然 而被深信的是,任合恰當的聚烯烴聚合物皆可被利用來形 成本發明的此薄膜層(1 2),且較優異的是任何優勢的線性聚 烯烴聚合物,其可被用來形成本發明的此薄膜層(12)。如用 於此處的專門術語”線性低密度聚乙烯”,其意欲包括乙烯與 較高α烯烴類共單體的聚合物如c3 一 C12、以及由此而生的 結合物,其並且具有一根據ASTM D-1238型號D所測得的 溶流指數(Ml),從大約〇·5至大約10 (於190°C下、每1〇 分鐘的克數)。"優勢線性”意爲此主要的聚合物鏈爲直線, 其每1000乙烯單位中具有少於近5個長支鏈。長支鏈應包 括大於C12的碳鏈。對於優勢線性聚埽烴聚合物而言,其將 爲非彈性的,短支鏈(C3-C12)由於所包含的共單體之故,將 典型地被限制於每1 〇 〇 〇個乙烯單位中,具有少於2 〇個的 短支鏈,對於聚合物而言,每1〇0〇個乙埽單位具有個 或更多的短支鏈,其將爲彈性體。優勢的線性聚烯烴聚合 物的例子,包括但不限制於由下列單體所製成的聚合物: 乙烯、丙·烯、1—丁烯、4-甲基-戊烯、1 —己烯、1—辛烯以 及較咼的烯烴類、以及同時由前述所形成的共聚物與三元 聚合物。此外,乙烯與其它烯烴類的共聚物包括丁烯、4一 ~·ι· 丨丨 __ ___C:\PATENT\Pk-001 ·040—04^\Pit^nm.nAnA\ ηηι παπά t 本紙張又度適用中國國家標準(CNS ) A4規格(210X297公釐) (請先閲讀背面之注意事項再本頁)Printed by the Consumers' Cooperative of the Central Government Bureau of the Ministry of Economic Affairs. 5. Description of the invention (14) It is bonded to other fibers using known bonding techniques. The laminated product can also be formed by using the fibrous non-woven layer (16) in the present invention. Such laminates include spunbond / meltblown laminates as indicated, and spunbond / meltblown / spunbond laminates, for example, U.S. Patent No. 4,041 filed by Sundial et al. In 2003, the disclosures are fully incorporated herein for reference. With a spunbond / meltblown laminate, it is often more desirable to attach the melt nozzle portion of the laminate to the film layer. In addition, in special applications, it is expected to add additional layers to the film_non-woven laminate, such as, for example, attaching a second non-woven or other support layer to the film layer. On the surface of the first or other non-woven layer. Again, this second support layer may be, for example, a single layer of non-woven material or a laminate as described herein. The film layer (12) includes at least two basic components: a polyolefin polymer, preferably a linear polyolefin polymer of superiority, such as linear low density polyethylene (LLDPE) or polypropylene, and a filler. These components are mixed together, heated, and then extruded to form a thin film layer using one of a variety of film manufacturing processes, which are well-known to those skilled in the film production process. This film manufacturing process includes, for example, cast film embossing and embossing, quenching and straight-wire untwisted casting film, and blown film processing. Other additives and ingredients can be added to the film layer (12) provided, and they will not significantly interfere with the ability of the film layer to perform its function in accordance with the teachings of the present invention. Generally speaking, based on the total weight of the film, on a dry basis basis, the film layer (12) will include from about 30 to about 70 weight percent polyolefin. ------ --- C: \ PATEPn \ PhOO 1 ^ 040 ~ Ό45ΛΡ ^ 001 > (Μ04 \ ρ ^ 001-0404-1 ulfrlnr This paper size applies to Chinese National Standard (CNS) A4 size (210X297 mm) / 99, 17 (Please read the note on the back first Matters on this page) • Packing, ## 513344 A7 B7 V. Description of Invention (ls) polymer, and rhenium filling from about 30 to about 70 weight percent. In some special embodiments, it may be Additionally includes from about 0 to about 20 weight percent of another polyolefin polymer, such as low density polyethylene, for example. When linear low density polyethylene is blended with a suitable amount of a single charge, it is treated as one. The film substrate has been found to have good performance. However, it is believed that any suitable polyolefin polymer can be used to form the film layer (1 2) of the present invention, and the more excellent is Any advantageous linear polyolefin polymer that can be used to form this thin layer of the invention Layer (12). As the term "linear low density polyethylene" as used herein, it is intended to include polymers of ethylene and higher alpha olefinic comonomers such as c3 to C12, and combinations thereof It also has a melt flow index (Ml) measured according to ASTM D-1238 Type D, from about 0.5 to about 10 (grams per 10 minutes at 190 ° C). &Quot; Advantages "Linear" means that the main polymer chain is a straight line with less than 5 long-chain branches per 1,000 ethylene units. The long-chain branches should include carbon chains larger than C12. For the dominant linear polyfluorene polymers It will be non-elastic, short branched (C3-C12) due to the comonomers included, will typically be limited to less than 20 short units per 1,000 ethylene units Branched chains. For polymers, there are one or more short branched chains per 1,000 ethylene units, which will be elastomers. Examples of advantageous linear polyolefin polymers include, but are not limited to Polymer made from the following monomers: ethylene, propylene, 1-butene, 4-methyl-pentene, 1-hexene, 1 —Octene and relatively olefins, as well as the copolymers and terpolymers formed by the foregoing. In addition, copolymers of ethylene and other olefins include butene, 4-a ~ · ι · 丨 丨 __ ___C : \ PATENT \ Pk-001 · 040—04 ^ \ Pit ^ nm.nAnA \ ηηι παπά t This paper is again applicable to China National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back before copying this page)

^ · 、τ 經濟部中央標準局員工消費合作社印繁 18^, ΤIndustry Consumer Cooperatives, Central Standards Bureau, Ministry of Economic Affairs, Yin Fan 18

經濟部中央標準局員工消費合作社印製 13344 A7 ----- --B7 五、發明説明(16) 甲基戊烯、已烯、庚婦、辛烯、癸烯等,其亦爲優勢線性 聚烯烴聚合物的例子。 除了聚烯烴聚合物之外,此薄膜層(1 2)亦包括一塡充 料。如此處所用的"塡充料",其意欲包括微粒與其它形式的 材料,其可被添加入此薄膜聚合物的擠壓摻合物中,且與 此擠壓的薄膜間將不會起化學作用,但是卻可以均勻地分 佈於整個薄膜中。一般而言,此塡充料將以微粒的形式, 且可具有一球狀或非球狀的外形,其具有一平均粒子尺寸 範圍約爲0.1至大約7微米。有機與無機塡充料皆爲本發明 範圍内所企盼的,它們並不會與此薄膜的成形過程、或是 此薄膜層根據本發明所敎授而行使其功能的過程間相互干 擾。合適之塡充料的範例包括碳酸鈣(Cac〇3)、各種類型的 黏土、矽石(Si〇2)、礬土、碳酸鋇、碳酸鈉、碳酸鑊、滑石、 硫酸鋇、硫酸鎂、硫酸鋁、二氧化鈦(Ti〇2)、沸石、纖維素 類型的粉末、高嶺土、雲母、碳、氧化鈣、氧化鎂、氫氧 化鋁、漿粕粉末、木材粉末、纖維素衍生物、甲殼質以及 甲设免衍生物。一合適的塗覆,舉例來説如硬脂酸,亦依 其可望與否而被施加至此填充料粒子。 如此處所述及的,薄膜層(12)可以利用熟知於那些精 於薄膜形成之人士的任何一種傳統的處理過程加以形成。 此聚烯烴聚合物與塡充料,以一此處所列出之給定範圍内 的合宜比例相互混合,然後加熱並將之擠壓形成一薄膜。 爲了提供藉由此薄膜之水蒸氣傳輸率所反應出的均質透氣 性,此填充料應被均句的分佈於整個聚合性摻合物中,由 - -—____C:\PATENT\Pk-OQl-CHO—(H5-\Pk-001~〇4〇4\pk-n〇l^Q404-l ulfdoc 本紙張尺度適用中國國家標準(CNS)A4規格(210X297公釐) 〜cember 3】/99. 19 (請先閱讀背面之注意事項再^s本頁)Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 13344 A7 ----- -B7 V. Description of the invention (16) Methylpentene, hexene, heptene, octene, decene, etc., which is also a linear advantage Examples of polyolefin polymers. In addition to the polyolefin polymer, this film layer (12) also includes a roll of filler. As used herein, " 塡 Fill " is intended to include particulates and other forms of materials that can be added to the extrusion blend of this film polymer and will not It functions chemically, but can be evenly distributed throughout the film. Generally speaking, this radon filling will be in the form of particles and may have a spherical or non-spherical shape with an average particle size ranging from about 0.1 to about 7 microns. Both organic and inorganic rhenium fillings are desired within the scope of the present invention, and they do not interfere with each other in the process of forming the film or the process in which the film layer performs its function according to the teachings of the present invention. Examples of suitable rhenium fillings include calcium carbonate (Cac03), various types of clay, silica (SiO2), alumina, barium carbonate, sodium carbonate, rhenium carbonate, talc, barium sulfate, magnesium sulfate, sulfuric acid Aluminum, titanium dioxide (Ti02), zeolite, cellulose-based powder, kaolin, mica, carbon, calcium oxide, magnesium oxide, aluminum hydroxide, pulp powder, wood powder, cellulose derivatives, chitin, and chitin Free derivatives. A suitable coating, such as stearic acid, is also applied to the filler particles as desired. As mentioned herein, the thin film layer (12) can be formed using any conventional process known to those skilled in film formation. The polyolefin polymer and rhenium filler are mixed with each other at a suitable ratio within the given range listed here, and then heated and extruded to form a film. In order to provide homogeneous air permeability reflected by the water vapor transmission rate of this film, this filler should be evenly distributed throughout the polymerizable blend, from--____ C: \ PATENT \ Pk-OQl- CHO— (H5- \ Pk-001 ~ 〇4〇4 \ pk-n〇l ^ Q404-l ulfdoc This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) ~ cember 3] / 99. 19 (Please read the notes on the back before ^ s this page)

Ι.1Ι1!Μ^^Γ 經濟部中央楳隼局貝工消費合作社印策 513344 A7 一___________B7 五、發明説明(17) 一'一' 是亦廣佈於整個薄膜層本身。爲了本發明目的之故,如果 薄膜利用描述於此處的測試方法評估,具有一水蒗氣的傳 輸率至少爲每平方公尺每24小時3〇〇克(3〇〇 g/m2/24 hrs),則一薄膜將被認爲是"透氣性的"。一般而言,一旦此 薄膜被形成,它將具有一每單位面積的重量爲每平方公尺 少於約80克(80 gsm),且在延伸與變薄化之後,它每單位 面積的重量將從每平方公尺大約彳2克至大約25克。 被應用於本發明描述於下方範例中的此薄膜層爲一單 層薄膜,然而,其它類型如多層薄膜,在本發明所提供的 範圍内,其成形技術可與塡充薄膜相容者,亦可被加以考 慮。剛開始形成的薄膜通常較厚且比期望中的吵雜,當其 搖晃時,會傾向於發出”嘎嘎”的聲音。更甚者,此測量此薄 膜的水蒸氣傳輸率發現,其並不具備有足夠程度的透氣性。 因此’此薄膜被加熱至一相等於、或低於約5。C此聚烯烴 聚合物的熔點溫度,然後利用一成直線的機械方向定位 (MDO)單位’將之延伸到至少約二倍(2χ)其本身之原始長 度’以薄化此薄膜並提供其多孔性。進一步延伸此薄膜層(彳2) 至約其二倍(3X)長度、四倍(4 X)、或更多倍其原始長度,對 於本發明形成此薄膜層(12)來説,將是特别冀望的事。 薄膜層(12)在被拉伸變薄之後,應具有一"有效的”薄膜 厚度,從大約0.2密耳至大約〇.6密耳。此有效的厚度對於 存在於透氣性薄膜層内的空隙或氣體空間方面,將被列入 考量。正常而論,非填充性、非透氣性的薄膜,此薄膜實 際的厚度與有效的厚度典型地將會是相同的。然而,對於 _______ C:\PATENT\Pk-001.Q40 〜MS'pic.mi ·0404\1^-001-04〇4-1 ulf.d〇C_ 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) December 3 U 997 20 辦衣-- (寬閱讀背面之注意事項再本頁) 訂 13344 A7 B7 五、發明説明(18) 描述於此處之被拉伸變薄的塡充式薄膜而言,此薄膜的厚 度亦包括空氣的間隙。爲了忽略此附加的體積,有效厚度 將根據陳述於此處的測試方法來加以估算。 拉伸變薄過程另一附加特徵是改變了此薄膜材料的不 透明度。於形成之際,此薄膜相對上爲透明的,然而在此 薄膜延伸之後將變爲不透明。此外,當此薄膜在拉伸變薄 處理過程中變爲具方向性時,其亦變得較爲柔軟且”嘎噪·· 聲響的#程度將被降低。 此單軸、機械方向定位的薄膜,典型地於橫跨機械方 位上,並不具有良好的強韌特質,其將造成此薄膜容易沿 著機械方位(即延伸方向)被撕裂或分離。一解決存在於此拉 伸變薄之薄膜中的此”扯裂”問題所嘗試的方法是,利用熱枯 結將此薄膜層結合至一纖維性非織物或非織物層上,絶大 部分在具有此後述的纖維性支持層的補強作用,其將決定 此結果產生之薄膜·非織物層壓製品的耐久性與強韌度等特 質。然而,如此處所註明的,此熱粘合薄膜非織物層壓製 品表現出某些特定的缺失,特别是在結合被延伸高達四倍 於它原始長度之機械方向定位的填充薄膜、以增進此薄膜 微孔性或透氣性的時候。 本發明的此黏著性補強薄膜-非織物,當其與熱枯合薄 膜-非織物層壓製品相比較時,將允許熱不相容性的薄膜與 非織物,例如LLDPE薄膜與聚丙烯非織物,可有效地相互 層壓製造而成。此結果產生的層壓製品具有優異的美學特 質,諸如手感與觸感、層壓製品的強韌度、耐久性與強韌 P!s:p〇l-0404\pk-0〇l.〇4n4.1Ι.1Ι1! Μ ^^ Γ Imprinting policy of Shellfish Consumer Cooperative, Central Bureau of the Ministry of Economic Affairs 513344 A7 ___________ B7 V. Description of the invention (17) One 'one' is also widely distributed throughout the film layer itself. For the purposes of the present invention, if the film is evaluated using the test methods described herein, the transmission rate with tritium is at least 300 grams per square meter per 24 hours (300 g / m2 / 24 hrs ), A film will be considered " breathable ". Generally, once this film is formed, it will have a weight per unit area of less than about 80 grams (80 gsm) per square meter, and after stretching and thinning, its weight per unit area will From about 2 grams to about 25 grams per square meter. The film layer used in the present invention described in the following example is a single-layer film. However, other types, such as multilayer films, are within the scope of the present invention, and their forming technology is compatible with filling films. Can be considered. The first formed film is usually thicker and noisier than expected, and when it shakes, it tends to make a "quack" sound. What's more, when measuring the water vapor transmission rate of this film, it was found that it does not have a sufficient degree of air permeability. Therefore, this film is heated to an amount equal to, or lower than about 5. C. The melting point temperature of this polyolefin polymer, and then using a linear mechanical direction positioning (MDO) unit 'extended to at least about twice (2χ) its original original length' to thin the film and provide its porosity Sex. Further extending the film layer (彳 2) to about twice (3X) its length, four times (4 X), or more than its original length will be particularly important for forming the film layer (12) of the present invention. Longing for things. The film layer (12), after being stretched and thinned, should have an " effective " film thickness, from about 0.2 mils to about 0.6 mils. This effective thickness is for those present in the breathable film layer Voids or gas spaces will be considered. Normally, for non-filled, non-breathable films, the actual thickness and effective thickness of this film will typically be the same. However, for _______ C: \ PATENT \ Pk-001.Q40 ~ MS'pic.mi · 0404 \ 1 ^ -001-04〇4-1 ulf.d〇C_ This paper size applies Chinese National Standard (CNS) A4 (210X297 mm) December 3 U 997 20 Clothing-(Notes for wide reading on the back side of this page) Order 13344 A7 B7 V. Description of the invention (18) As for the stretch-thin filled film described here, this film The thickness also includes air gaps. In order to ignore this additional volume, the effective thickness will be estimated according to the test method stated here. Another additional feature of the stretch-thinning process is that the opacity of the film material is changed. When formed, the film was relatively transparent, but in the After extending the film becomes opaque. Further, when this film becomes thinner with directional stretching process, it also becomes softer and "the degree of Ga # ·· acoustic noise will be reduced. This uniaxial, mechanically oriented film, typically in a cross-mechanical position, does not have good toughness characteristics, which will cause the film to be easily torn or separated along the mechanical orientation (ie, the direction of extension). An attempted method to solve this "tearing" problem that exists in this stretched and thin film is to use thermal dead junction to bond this film layer to a fibrous nonwoven or nonwoven layer, most of which The reinforcing effect of the fibrous support layer, which will be described later, determines the characteristics such as durability and toughness of the film-nonwoven laminate produced as a result. However, as noted herein, this heat-bonded film nonwoven laminate exhibits certain specific shortcomings, particularly in combination with a filler film positioned in a mechanical orientation that is stretched up to four times its original length to enhance the film. When it is microporous or breathable. The adhesive-reinforcing film-nonwoven of the present invention, when compared with a heat-sealable film-nonwoven laminate, will allow thermally incompatible films and non-wovens, such as LLDPE films and polypropylene non-wovens. , Can be effectively laminated to each other. The resulting laminate has excellent aesthetic characteristics, such as hand and touch, the toughness, durability and toughness of the laminate P! S: p〇l-0404 \ pk-0〇l.〇4n4 .1

December 3 1, 1 9 9 7 (請先閱讀背面之注意事項再 —裝I 本頁December 3 1, 1 9 9 7 (Please read the precautions on the back first—install this page

、1T 經濟部中央標準局貝工消費合作社印製 21 經濟部中央標準局員工消費合作社印製 513344 A7 B7 五、發明説明(19) 度等性、以及咼度的透氣性,不會因爲因爲在熱粘合過程 中的過度加熱與/或是壓力,而於此薄膜層中造成不希望出 現的脆弱點或穿孔。 如用於此處的專門術語"枯合劑",意指任何合適的熱熔 祖、水或,谷劑爲主態的粘合劑,其可以一需求的模型花樣 或網狀結#的枯合劑面積(]8) ϋ施加至此薄膜層(巧2) 的一表面(14)上,以形成本發明的此薄膜_非織物層壓製 品。因此,適合的粘合劑包括有傳統的熱熔體粘合劑、壓 敏性粘合劑以及反應的粘合劑(亦即聚氨基甲酸乙酯)。更特 引的疋,嵌塊共聚物類型的結構粘合劑,乙烯酯酸乙酯 (fvA)—爲基質的粘合劑(例如18〜3〇重量百分比的醋酸乙 酉口)、以及要疋形的α共聚物及三元聚合物爲基質的粘合 劑,其在用來形成本發明的此薄膜_非織物層壓製品時,可 具有良好的表現。所有的這些粘合劑型態可以被公式化爲 包含塑性材料與增黏劑,以改善其處理製造過程、或熱黏 性、或柔軟度。 、此被應用之粘合劑施加的處理過程,必須適於所使用 (特殊型態的枯合劑,如此則此薄膜層與非織物層被黏著 达地枯口在-起,而產生_剝離強度爲2Q克或更大。舉例 =説,此枯合劑可以利用_模型花樣或網狀結構的十字交 0任思分散的熔喷粘合纖維而被施加於其中。此熔喷粘 口纖維典型地具有平均直徑範圍,從大約5微米至大約 微米。如用於此處的專門術語••溶喷粘合纖維",其傾向於包 括非連續性與連績性的枯合纖維。用來施加炫喷纖維至一 ( CNS} Α~^ 21〇χ~—^ “度丨 *2^ December 31, 1 99 7 (請先閲讀背面之注意事項再本頁) —裝Printed by 1T Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 21 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 513344 A7 B7 V. Description of the invention (19) The degree of equality and the degree of breathability will not be because of Excessive heating and / or pressure during thermal bonding can cause unwanted fragile points or perforations in the film layer. As used herein, the term " depleting agent " means any suitable hot-melt ancestor, water, or cereal-based adhesive, which can be a desired model pattern or mesh knot. The desiccant area () 8) is applied to one surface (14) of the film layer (2) to form the film-nonwoven laminate of the present invention. Therefore, suitable adhesives include traditional hot-melt adhesives, pressure-sensitive adhesives, and reactive adhesives (that is, polyurethanes). More specifically, structural adhesives of the block copolymer type, ethyl vinyl acetate (fvA) —adhesives based on the matrix (eg, 18 to 30 weight percent ethyl acetate), and to be shaped The α-copolymer and terpolymer-based adhesive can have good performance when used to form the film-nonwoven laminate of the present invention. All of these adhesive types can be formulated to include plastic materials and tackifiers to improve their processing and manufacturing processes, or thermal tack, or softness. The treatment process of the applied adhesive must be suitable for the used (special type of desiccant, so that the film layer and the non-woven layer are adhered to each other, and the peel strength is generated. It is 2Q grams or more. For example, this desiccant can be applied to the melt-blown adhesive fibers dispersed in a cross pattern of a pattern or network structure. The melt-blown adhesive fiber is typically Has an average diameter range from about 5 microns to about microns. As the term is used herein • melt-blown fibers ", it tends to include discontinuous and continuous fibers. Used to apply Hyun spray fiber to the first (CNS) Α ~ ^ 21〇χ ~ — ^ "degree 丨 * 2 ^ December 31, 1 99 7 (Please read the precautions on the back before this page) —install

、1T ,13344 A7 B7 經濟部中央梯準局員工消費合作社印掣 五、發明説明(20) 移動基質上的處理過程已被熟知,如藉由Appe丨等人所申請 的美國專利編號4,720,252代表性的範例説明,所揭示者合 併於此以供參考。 其它適合用來將枯合劑施加至此薄膜層(12)的處理過 程包括,舉例來説’喷灑的或渦旋的熱溶體粘合劑面積、 以及枯合劑面積的篩網或凹版印製。此熔體喷灑與粘合劑 印製處理過程已被熟知於此技術領域中,因此在此處將不 多贅述。粘合劑的施加,特别是著色的粘合劑,其利用此 印制處理過程以提供附加的美學價値,例如此粘合劑模型 花樣可以利用一幾何或非幾何的形式、以及重覆或非重覆 的外貌、連續或非連續的線條、新奇或恣意的設計、符號 或物件、或甚至是文件或字體。顯示於圖3與4中的粘合劑 模型花樣圖解説明了此類印製的粘劑模式。 特定的印製處理過程,例如篩網印製,需要導引此篩 網與被印製之基質間的接觸。印製特殊型態的粘合劑,例 如某些壓敏性粘合劑,可檢驗其由於此粘合劑在室溫下的 高黏度或附著程度所造成的問題。然而,此類粘合劑的篩 網印制可藉著將此粘合劑印製於一合適的鬆解表面,舉例 來說如一鬆解紙張,並且繼而在將此薄膜層(1 2)粘結至非織 物層(16)<前,將此被印製的粘合劑由此鬆解的表面上轉移至此薄膜層(12)。 不論所應用來形成此黏著性補強薄膜_非織物層壓製 品的特殊粘合劑施加處理過程爲何,發明者已發現此粘合 劑必須被直接地或間接地施加至此薄膜層(12)的一表面 (請先閱讀背面之注意事項再 —裝-- 本 κ、 1T, 13344 A7 B7 Printed by the Consumer Cooperatives of the Central Elevator Bureau of the Ministry of Economic Affairs. 5. Description of the invention (20) The processing process on the mobile substrate is well known, such as represented by US Patent No. 4,720,252 applied by Appe 丨 et al. The example description of the disclosure is incorporated herein by reference. Other processes suitable for applying a desiccant to this film layer (12) include, for example, a 'sprayed or vortexed hot melt adhesive area, and screen or gravure printing of the desiccant area. This melt spraying and adhesive printing process is well known in this technical field and will not be described in detail here. The application of adhesives, especially colored adhesives, utilizes this printing process to provide additional aesthetic value. For example, the adhesive model pattern can use a geometric or non-geometric form, as well as repeated or non- Repeated appearance, continuous or discontinuous lines, novel or deliberate designs, symbols or objects, or even documents or fonts. The adhesive model patterns shown in Figures 3 and 4 illustrate this type of printed adhesive pattern. Certain printing processes, such as screen printing, need to guide the contact between this screen and the substrate being printed. Special types of adhesives, such as some pressure-sensitive adhesives, can be printed to check for problems caused by the high viscosity or adhesion of the adhesive at room temperature. However, the screen printing of such adhesives can be achieved by printing the adhesive on a suitable release surface, such as a release paper, and then adhering the film layer (1 2). Before bonding to the non-woven layer (16) <, the printed adhesive is transferred from this loosened surface to the film layer (12). Regardless of the special adhesive application process used to form the adhesive reinforcement film_non-woven laminate, the inventors have discovered that the adhesive must be applied directly or indirectly to a layer of the film layer (12) Surface (please read the precautions on the back first—install-this κ

• 11 —II —^ϋ ί m · ‘紙張尺度適用中國國家標準(CNS ) A4規格侧〜 23 A7 B7 五、發明説明(21) 上’而非被施加至此非織物層(16)。當其被施加至此非織物 層(1 6)的一表面時,基於非織物的纖維本性,所獲得用以補 強此薄膜層(1 2)之粘合劑的均質性將被降低。粘合劑可穿透 進入、並通過介於此非織物層(16)之個别纖維間的空隙,因 此降低粘合劑的連續性進而可補強薄膜層(彳2)。特别是關於 篩網或模型花樣的印製粘合劑,將粘合劑施加至非織物層 結果造成一模型花樣的圖形界定不明確、降低了此處粘合 劑印製處理過程中原有之美學層面的優異性。藉著將粘合 劑(18)施加至薄膜層(12)的表面句上,薄膜層補強作用所 能獲得的枯合劑總量、以及粘合劑施加的.形式皆可被有效 地加以控制。更甚者,粘合劑(1 8)的施加應實質地與薄膜層 (1 2)的長度與寬度共同延伸,以便能確保應用此薄膜層(12) 之黏著性補強薄膜的非織物層壓製品,在強韌度與耐久性 特質方面能具備其均質性,並且降低於使用薄膜-非織物層 壓製品(10)期間,此薄膜層(12)與非織物層(16〉間離層現象 的發生。 枯合劑面積的一主要的功能是補強此低厚度的薄膜― 非織物層壓製品、或其被延展薄膜層。如此處所註明的, 被高度定位(2X或更多倍)於此機械方向(MD)的薄膜,其在 遭觉檢跨機械方向(C D)的抗張外力時,傾向於被沿著機械 方向”扯裂π。發明者已觀察到,一根據本發明而被施加至此 一薄膜的任意分佈、十字交錯網狀結構的熔喷粘合劑面積, 於提供一 n破裂—終止”,以抵抗因藉由CD抗張負載量而被 施加至此薄膜所造成的薄膜破裂現象,因此增強了此機械 本紙張尺度適用中國國家標準(CNS ) A4規格(21〇χ297公釐) D…199 (請先閱讀背面之注意事項再 裝- 本• 11 —II — ^ ϋ ί m · ‘Paper size applies to Chinese National Standard (CNS) A4 specification side ~ 23 A7 B7 V. Description of invention (21) 'is not applied to this non-woven layer (16). When it is applied to one surface of the non-woven layer (16), based on the non-woven fiber nature, the homogeneity of the adhesive obtained to reinforce the film layer (12) will be reduced. The adhesive can penetrate into and pass through the spaces between the individual fibers of this non-woven layer (16), thereby reducing the continuity of the adhesive and thus strengthening the film layer (彳 2). Especially for the printing adhesive of the screen or the pattern, the application of the adhesive to the non-woven layer results in an unclear definition of the pattern of the pattern, which reduces the original aesthetics of the adhesive printing process here. Level of excellence. By applying the adhesive (18) to the surface sentence of the thin film layer (12), the total amount of the desiccant that can be obtained by the reinforcing effect of the thin film layer and the form of the adhesive applied can be effectively controlled. Furthermore, the application of the adhesive (18) should be substantially coextensive with the length and width of the film layer (12), so as to ensure the non-woven lamination of the adhesive reinforcing film of this film layer (12) The product can have its homogeneity in terms of toughness and durability characteristics, and reduces the phenomenon of delamination between the film layer (12) and the nonwoven layer (16) during the use of the film-nonwoven laminate (10) One of the main functions of the desiccant area is to reinforce this low-thickness film-a non-woven laminate, or its stretched film layer. As noted here, it is highly positioned (2X or more) on this machine Directional (MD) film, which tends to be "teared" in the mechanical direction when subject to tensile external forces across the mechanical direction (CD). The inventors have observed that an The random distribution of a film with a cross-staggered network structure of the meltblown adhesive area provides an n-break-stop "to resist film breakage caused by the CD tensile load applied to the film, So this machine is enhanced This paper size applies Chinese National Standard (CNS) A4 specification (21 × 297 mm) D ... 199 (Please read the precautions on the back before loading-this

'1T 經濟部中央標準局員工消費合作社印製 24 513344 £、發明説明(22) :向定位薄膜的耐久性與強勃度。更特别的是,此網狀站 薄<任意分佈、十字交錯的熔喷粘合劑面積,包二 燦噴枯合纖維,其在此MD内爲"相當都近地被分開"。〇 處所用的專門術語"相當鄰近地被分開的枯合劑面積",二 的是枯合劑面積以-通常平行於延伸方向、介於個别: 合劑面積間的最大距離约爲“英叶(25 4叫而被分開, ,别是一最大距離爲〇.25英吋(6 35 mm),且甚至更特二的 是—最大距離爲0.125英叶(3 18 _)。如用於此處 門 術語"通常平行於延伸方向",意爲一沿著枯合劑面積之間距 勺’’泉條’其與延伸方向上的一線條間所測量得到的—内角, 將少於或等於30。。藉著限制存在於此薄膜層延伸方位上介 於個别粘合劑面積間的最大距離,舉例來説,此機械方位, 至—特定的範固,則存在於薄膜層(12)内之孔洞的形成與擴 展將會被降低,且此薄膜層(12)在此橫跨機械方向上承受被 扯裂或撕離前的延長總量,可以被提升。換另_種陳述方 式則是,藉由增加位於此粘合劑模型花樣或網狀結構内個 别粘合劑面積的聯結性與接近程度,薄膜層(1 2)的扯裂現象 經濟部中央標準局貝工消費合作社印製 將有效地被降低。 雖然一任意分散的、十字交錯之網狀結構的粘合劑面 ^例如炼喷粘合纖維,可被有效地應用以形成本發明黏 著性補強薄膜非織物層壓製品,如此處所註明的,其它粘 $ Μ的;^加模式與方法亦同樣可被利用。舉例來説,通常 爲平行的、連續的與/或非連續的、延伸或定位於橫跨機械 ' 且以一添加總量百分比結合面積位於此處特定的 本紙^29Ί 公靡·琴- 25 A7 五 、發明説明(23) 範圍内’而被印製於薄 層被枯結至本發明之\表面(14)上’其在被薄膜 潯膜-非織物層壓製品的非織物層(16, 用人:促進提升所產生之薄膜層(12)的強韌度與耐久性。利 …”占合施加方式,將因它們的特性而被限制,以控 ^斤使用的粘合劑的添加總量、此粘合劑面積的百分比結 Z面積、介於位處延伸方向(MDU之個㈣合劑面積間的 瑕大距離,並且在此#合劑料此薄膜· 具有足夠的黏度時,將此薄膜層枯合至此非織物層,以: 遞^離強度爲20克或更大。帅合劑添加總量應被設限 疒從每平方Α尺大約〇」至大約2〇克的範圍,更特别的是 從每平万A尺大約〇·25至5.G克,^甚至更特别的是從每 平方a尺大約〇·5至大約,5克。降低此添加總量將減少製 造產生此薄膜_非織物層壓製品的花f,且降低了損及此薄 膜層之透氣性的危險。!备由對照顯示,較高的粘合劑添加 總量,將提供一更持久耐用的薄膜,織物層壓製品,其爲 適於多次使用的終端產物。 s其與一連續塗覆的粘合劑,則藉著施加一如描述於 此處之模型花樣或網狀結構的粘合劑面積,舉例來説,其 薄膜-非織物層壓製品的微孔性與透氣性,並沒有明顯地被 降低。一連續的粘合劑塗覆,對於其被用來形成本發明的 此薄膜-非織物層壓製品而言,基於它對此結果產生的層壓 製品所造成之物理特性(例如懸垂性與杯壓榨)的影響,更進 而被發明者認爲並不適合。此薄膜層(12)的表面(14)上,其 粘合劑面積(18)被施加的總面積部分,可以被表示爲一百分 (請先閱讀背面之注意事項再本頁)'1T Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 24 513344 £, Description of Invention (22): Durability and robustness of positioning films. More specifically, this mesh station is thin < arbitrarily distributed, crisscrossed meltblown adhesive area, including two spunbond fibers, which in this MD are " quite pretty close apart ". 〇The special term " area of the mixture which is separated quite close to each other ", the second is that the area of the mixture is-usually parallel to the direction of extension, between the individual: the maximum distance between the mixture areas is about "English leaves" (25 4 are called and separated, not to mention a maximum distance of 0.25 inches (6 35 mm), and even more special-the maximum distance is 0.125 inches (3 18 mm). If used for this The term "usually parallel to the direction of extension" means that the internal angle measured from the distance between the "spring bar" along the area of the drying agent and a line in the direction of extension-the inner angle will be less than or equal to 30. By limiting the maximum distance that exists between the individual adhesive areas in the extension orientation of this film layer, for example, this mechanical orientation, to a specific range, exists in the film layer (12) The formation and expansion of the internal holes will be reduced, and the film layer (12) can withstand the total amount of extension before tearing or tearing in the cross-machine direction. It can be improved. Yes, by adding a pattern or mesh structure located on this adhesive model The connection and proximity of the individual adhesive areas within the film, the tearing of the film layer (12) will effectively reduce the printing by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. Although an arbitrarily scattered, cross-staggered Adhesive surfaces of a network structure, such as spray-bonded fibers, can be effectively applied to form the adhesively reinforced film non-woven laminates of the present invention, as noted herein, other adhesives of $ M; The method can also be used. For example, it is usually parallel, continuous and / or discontinuous, extending or positioned across the machine ', and a specific percentage of the total area of the paper is added here. Ί29Ί Gong Qin-25 A7 V. The description of the invention (23) is printed on a thin layer and dried on the surface of the invention (14). It is coated on a film-non-woven laminate Non-woven layer (16, Employment: Promote the improvement of the toughness and durability of the film layer (12) produced. Advantages ... "The application method of occupancy will be limited due to their characteristics. The total amount of adhesive added, this adhesive surface The percentage of Z area, the distance between the extension direction of the bit (the gap between the area of the MDU admixture), and here # 合 料 料 THIS FILM · When the viscosity is sufficient, this film layer is dried to this non-woven layer In order to: Removal strength is 20 grams or more. The total amount of Shuai mixture should be set to a limit, ranging from about 0 "to about 20 grams per square A feet, more particularly from 10 thousand square feet per square foot. About 0.25 to 5.G grams, ^ even more specifically from about 0.5 to about 5 grams per square foot a. Reducing the total amount of this addition will reduce the production of flowers that produce this film_non-woven laminate f, and reduces the risk of impairing the breathability of this film layer.! As shown by the comparison, a higher total amount of adhesive added will provide a more durable film, fabric laminate, which is suitable for Multi-use end product. With a continuously applied adhesive, by applying the adhesive area of a pattern or mesh structure as described herein, for example, the micropores of its film-nonwoven laminate Performance and breathability are not significantly reduced. A continuous adhesive coating for which the film-nonwoven laminates of the present invention are used to form the physical properties (such as drape and cup) of the laminates resulting from this result (Pressing), and further considered by the inventors unsuitable. On the surface (14) of the film layer (12), the total area of the adhesive area (18) to which it is applied can be expressed as one hundred points (please read the precautions on the back before this page)

、1T 經濟部中央標準局員工消費合作社印製 _^\PATENT\Pk-〇〇l-〇40~.〇4Fi~\ Plr.nnι.ηαηΔ\ ι.παπλ. ί, 1T Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs _ ^ \ PATENT \ Pk-〇〇l-〇40 ~ .〇4Fi ~ \ Plr.nnι.ηαηΔ \ ι.παπλ. Ί

經濟部中央榡準局貝工消費合作社印策 13344 A7 B7 五、發明説明(24· 比結合面積。被用於此處的專門術語"百分比結合面積n,指 的是此薄膜層(12)表面(14)上被粘合劑面積(18)所占據的 總平面面積的部分。此百分比結合面積可以藉由多種不同 的傳統技術加以測量,包括此處所描述的影像分析。藉由 限制此此粘合劑面積的百分比結合面積至一範圍,從被施 加之粘合劑面積占有每平方面積的薄膜層(12)表面(14)大 約5百分比至大約50百分比,並控制此施加之粘合劑面積 的最大間距、以及同時此粘合劑添加總量,則被用以形成 薄膜-非織物層壓製品的低厚度黏著性補強、拉伸變薄化的 透氣塡充式薄膜,可在不影響此結果產生之層壓製品之透 氣性的情況下而被完成。 雖然本發明的此黏著性補強薄膜-非織物層壓製品在 此處被描述成一單軸定位或單軸延展的薄膜層,本發明的 益處與優點同時亦可被應用在雙軸定位或雙軸延展的薄 膜。同樣地,雖然粘合劑面積(18)旖加至此薄膜層(彳2)的一 表面(14)已被描述於此,粘合劑面積亦可被施加至相對於此 薄膜層(12)之表面(14)的另一相對表面上,於此其中位於薄 膜層相對表面上的粘合劑面積,其於延伸方向上的百分比 結合面積與最大間距,以添加總量而言,可以相等的或不 同的。 本發明的此黏著性補強薄膜-非織物層壓製品,具有一 廣泛不同之末端使用的應用層面,其包括一作爲個/看顧 用吸收性物件,例如顯示於圖5中之可棄式尿布(2〇)的外罩 材料。尿布(20),如大多數典型的個人看顧用吸收性物件,Instruction 13344 A7 B7 by the Central Bureau of Standards, the Ministry of Economic Affairs, Shellfish Consumer Cooperative, V. Description of the invention (24 · Specific bonding area. The term used here " Percent bonding area n, refers to this film layer (12) The portion of the total planar area occupied by the adhesive area (18) on the surface (14). This percentage combined area can be measured by a variety of different conventional techniques, including the image analysis described here. By limiting this to this Adhesive area percentage Bonding area to a range from about 5 percent to about 50 percent of the surface (14) of the film layer (12) per square area applied to the applied adhesive area, and control the applied adhesive The maximum area pitch and the total amount of this adhesive added at the same time are used to form a film-non-woven laminate with low-thickness adhesive reinforcement and stretch-thinning breathable filling film that can be used without affecting This result is achieved without the air permeability of the laminate. Although the adhesive reinforcing film-nonwoven laminate of the present invention is described herein as a uniaxial positioning or uniaxial The benefits and advantages of the present invention can also be applied to biaxially oriented or biaxially stretched films. Similarly, although the adhesive area (18) is added to one surface of the film layer (2) (14) As described herein, the adhesive area can also be applied to the other opposite surface of the film layer (12) on the opposite surface (14), where the adhesion on the opposite surface of the film layer is applied. The area of the agent, its percentage in the extending direction, the combined area and the maximum distance, can be equal or different in terms of the total amount of addition. The adhesive reinforced film-non-woven laminate of the present invention has a wide difference The end-use application layer includes a cover material as a personal / care absorbent, such as the disposable diaper (20) shown in Figure 5. The diaper (20), as most typical personal care Absorbent articles,

經濟部中央標準局員工消費合作社印製 513344 A7 ------_ 五、發明説明(25) ~~ 包括一滲液體側襯墊(24)、以及一不滲液外罩(22),其中的 外罩(22)包含本發明的此黏著性補強薄膜-非織物層壓製 品。各式不同的織物、非織物以及穿孔的薄膜材料,皆可 被用來作爲體側襯墊(24)。舉例來説,此體側襯墊可以是由 一聚烯烴的熔喷或紡粘非織物、一天然或合成纖維的枯合 梳理織物所製成。 ° 被置放於襯墊(24)與外罩(22)之間的是一吸收芯 (26),舉例來説,其是由一親水性纖維素木粕漿絨毛纖維、 與南吸收性膠凝粒子(例如超吸收性材料)所形成。吸收芯 (26)通常爲可壓縮的、舒適的、且對於穿戴者而言爲非刺激 性的,其亦可吸收並保留體分泌液體。爲了本發明的目地 之故,吸收芯(26)可包含一單一、完整材料片,或爲多數個 别分開的材料片。吸收芯(26)的尺寸大小與吸收能力應可相 配合於企圖利用它的使用者、以及使用此尿布(2〇)的穿戴者 所排出的液體負載量。尿布合適的結構與裝置包括有如描 述的襯墊、外罩以及吸收性結構,舉例來説,如Latimer 等人所申請的美國專利編號5,429,629,其所揭示者將完整 合併於此以供參考。 一彈性構件可以選擇性地被置放在鄰近每一尿布(2〇) 的縱向邊緣(28)。此彈性構件可以被安排用以相對依靠穿戴 者腿部’進而拉引並固定此尿布(20)的側邊緣(28)。因此, 一彈性構件亦可被置放在鄰近於此尿布(20)的其中一個或 二個末端邊緣(3〇),以提供一具彈性的腰帶。 尿布(20)可進一步包括圍堵襟片(32),其是由體侧襯墊 ------------ ----C:\PATEN7\Pk-00 】-Q40~,045~\Pk-001 -0404\pk-00 】-0404- ] .ulf.doc 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) i>ecember ;99: 28 (請先閱讀背面之注意事項再本頁) —裝. 太 B7 五、發明説明(26) (2 4)製成或附著至體側襯墊上。尿在之合宜的的結構與排列 裝置,包含描述於此的圍堵襟片,舉例來説如κ En丨〇e所 申請的美國專利編號4,704,1 16所揭示,其將完整合併於此 以供參考。 爲了將此尿布(20)固定於穿戴者身上,此尿布將具有 某些型態的固^裝置附著於此。如圖5所顯示的,此緊固裝 置爲一鉤與%的緊固系統,其包括粘附於位處此尿布 是腰帶邛位之外罩(22)表面的内部或外部的鉤元件(34),以 及個或多個位處此尿布(20)前腰帶部位之外罩(22)外表 面的環元件或嵌片(34)。 本發明已描述某些特定的實施例,一系列樣本的黏著 =補強薄膜非織物層壓製品被形成,以進一步説明本發明。 這些測試的結果、以及所使用的·測試過程,將公佈陳述於 下方。 測試過程 接下來的測試過程將被用來分析描述於此處 材 料。 經濟部中央標準局員工消費合作社印製 有效厚麼_ ^ ^薄膜材料的有效厚度,藉著此薄膜基重除以形成此 茸膜之聚口物與塡充料的密度而加以估算獲得。爲了獲得 :薄膜材料之以英Μ單位的有效厚度,所測得之以每平 万碼盘司(〇Sy)爲單位的重量被乘以請】咖(—公制相對 本紙張尺度適用中—家樟準(cNS ) Λ4規格(2丨〇χ^公f 〜_制叫麵彻-威Printed by the Employees' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 513344 A7 ------_ V. Description of the Invention (25) ~~ Including a liquid-permeable side gasket (24) and a liquid-impermeable outer cover (22), of which The outer cover (22) contains the adhesive reinforcing film-non-woven laminate of the present invention. A variety of woven, non-woven, and perforated film materials can be used as bodyside pads (24). By way of example, the bodyside pad may be made of a polyolefin meltblown or spunbond non-woven fabric, a natural or synthetic fiber carded fabric. ° Placed between the pad (24) and the outer cover (22) is an absorbent core (26). For example, it is made of a hydrophilic cellulose wood pulp pulp fluff fiber, gelled with the south absorbent Formed by particles such as superabsorbent materials. The absorbent core (26) is generally compressible, comfortable, and non-irritating to the wearer, and it can also absorb and retain body secretion fluids. For the purposes of the present invention, the absorbent core (26) may comprise a single, complete piece of material, or it may be a plurality of separate pieces of material. The size and absorption capacity of the absorbent core (26) should be compatible with the load of liquid discharged by the user who is trying to use it and the wearer using the diaper (20). Suitable structures and devices for diapers include pads, covers, and absorbent structures as described, for example, U.S. Patent No. 5,429,629 filed by Latimer et al., The disclosure of which is incorporated herein by reference in its entirety. An elastic member can be selectively placed adjacent the longitudinal edge (28) of each diaper (20). The elastic member may be arranged to pull and secure the side edge (28) of the diaper (20) relative to the wearer's leg '. Therefore, an elastic member can also be placed adjacent to one or both end edges (30) of the diaper (20) to provide an elastic waistband. The diaper (20) may further include an apron flap (32), which is composed of a body-side pad ------------ ---- C: \ PATEN7 \ Pk-00】 -Q40 ~ , 045 ~ \ Pk-001 -0404 \ pk-00】 -0404-] .ulf.doc This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) i >ecember; 99: 28 (Please read first (Notes on the back page)-Packing. Too B7 V. Description of the invention (26) (2 4) Made or attached to the body side cushion. A suitable structure and arrangement of urine, including the containment flaps described herein, for example, as disclosed in U.S. Patent No. 4,704,116 filed by κ En 丨 e, which is incorporated herein in its entirety to for reference. In order to fix the diaper (20) to a wearer, the diaper has a fixing device having some types attached thereto. As shown in Figure 5, the fastening device is a hook and percent fastening system that includes hook elements (34) attached to the surface of the diaper which is the surface of the outer cover (22) of the waistband. And one or more ring elements or inserts (34) located on the outer surface of the outer cover (22) of the front waistband portion of the diaper (20). The present invention has described certain specific embodiments, and a series of samples of adhesive = reinforcing film non-woven laminates were formed to further illustrate the present invention. The results of these tests, as well as the testing procedures used, will be announced below. Testing Process The following testing process will be used to analyze the materials described here. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. Effective thickness _ ^ ^ The effective thickness of the film material is estimated by dividing the film basis weight by the density of the aggregates and tritium fillings that form the velveteen film. In order to obtain: the effective thickness of the film material in British M units, the measured weight per square yards (0Sy) per square is multiplied by please] coffee (—Metric is applicable to this paper size—Home Zhang Jun (cNS) Λ4 specifications (2 丨 〇χ ^ 公 f ~ ~ system called noodles Toru-wei

December 3 1, 19 9 7 .13344 A7 B7 五、發明説明(27 於英制的轉換係數),並將此結果被除以此以每立方公分克 數(g/cc)爲單位之聚合物化學式的密度。 p- flnflflnflfl 經濟部中央#準局員工消費合作社印製 &_張强度W伸度) 用來做爲抗張強度與伸度的剝離測試方法,其測量一 材料在破裂之前的斷裂負載量以及百分比伸度。這些測邊 在此材料遭受—以—單方向、於―固^速率之仲度的連与 增加負載量時被測量獲得。 對於每一樣品薄膜非織物層壓製品材料而言,3個指 品被以一 3英吋(76 mm)寬的精準切割器,切割成每一樣本 具有一 3英吋(76 mm)寬與6英吋(152 mm)長的尺寸,其; 尺寸將平行於測試與外力施加的方向。每一樣本的整個宽 度被置於在一固定延展速率的測試器的箝夾内部,此測载 器如由明尼蘇達州,Eden Prairie的MTS系統股份有限公 司(MTS System Corporation 〇f Eden prairie)所製造的 Sintech系統2電腦整合測試系統(s丨·ntech System ^ ComputeMntegrated Testing System)。每一樣本的長度或 長尺寸僅可能地被置於幾乎平行於此外力施加的方向。一 連續負載量以設定於每分鐘300公釐的十字頭速度,而被 施加至此樣本上,直到此樣本被撕裂爲止。所需的此峰負 載量與峰應變力剛好在扯裂每一樣本之前被測量獲得,且 將其平均値記錄於此處。 水蒸氣僂輸率 (請先閱讀背面之注意事項再本頁j 、-u .1 - - 1-1 1-- > • ! m 1 i In · C, \PATENT\Pk-001 -a40~-045~\Pk-001-0404\pk-001-0404-1. ulf.doc 本紙張尺度適用中國國家標準(CNS ) A4規格(2I〇X297公釐)December 3 1, 19 9 7 .13344 A7 B7 V. Description of the invention (27 conversion factor in English) and divide the result by the chemical formula of the polymer in grams per cubic centimeter (g / cc) density. p-flnflflnflfl Printed by the Central Ministry of Economics # quasi-station employee consumer cooperative & tensile strength W elongation) Used as a peel test method for tensile strength and elongation, which measures the breaking load of a material before breaking and Percent stretch. These edge measurements are obtained when the material is subjected to-in one direction, at a mid-range connection at -solid rate and increased load. For each sample film non-woven laminate material, 3 fingers were cut with a 3 inch (76 mm) precision cutter to each sample with a 3 inch (76 mm) width and 6 inches (152 mm) long, which; the dimensions will be parallel to the direction of the test and the application of external force. The entire width of each sample is placed inside the jaws of a fixed extension rate tester, such as manufactured by MTS System Corporation of Eden Prairie, Eden Prairie, Minnesota Sintech System 2 Computer Integrated Test System (s 丨 · ntech System ^ ComputeMntegrated Testing System). The length or long dimension of each sample is only possible to be placed almost parallel to the direction in which the external force is applied. A continuous load was applied to the sample at a crosshead speed of 300 mm per minute until the sample was torn. The required peak load and peak strain force are measured just before tearing each sample, and the average 値 is recorded here. Water Vapor Transmission Rate (Please read the precautions on the back first, then this page j, -u.1--1-1 1-- > •! M 1 i In · C, \ PATENT \ Pk-001 -a40 ~ -045 ~ \ Pk-001-0404 \ pk-001-0404-1. Ulf.doc This paper size applies to China National Standard (CNS) A4 (2I × 297mm)

December 3 1, J 9 - 30 ,13344 Α7 Β7 五、發明説明(28) * ; ,: 對於每一樣品材料的水蒸氣傳輸率(WVTR),其將根據 美國試驗與材料協會ASTM標準E96—80而被評估得到。從 每一個測試材料、以及一由紐澤西州,s〇mmervM|e的 Hoechst Celanese 股份有限公司得到的 CELGARD(g)25〇〇 薄膜控制組上,切割下直徑爲3英吋的圓形樣品。 C ELGAR D⑧2 5 00薄膜爲一微孔性聚丙烯薄膜。每一種材料 備有3個樣品。此測試盤爲一由賓夕法尼亞州,費城的 Thwing-Albert儀器公司所販售的編號6〇一 1 Vap〇meter蒸 氣計淺盤。每一個Vapometer蒸氣計淺盤中,被倒入1〇〇 耄升(m丨)的蒸館水’且此測試材料與控制組中的個别樣品, 被置放在橫跨每一個别淺盤的開口頂部。此螺旋的凸緣被 ^緊旋轉固定住’以便沿著一淺盤(不使用密封潤滑劑)的邊 緣形成一密封,而使得曝露留在周遭空氣中相關之測試材 料或控制組材料,超過6.5公分(cm)直徑的圓形,其具有一 曝露面積接近於33· 1 7平方公分。此淺盤被稱重,然後將之 置放於一設定在37°C溫度下的施力空氣烘箱中。此烘箱爲 一但溫烘箱,其具有外部空氣循環通過,以預防水蒸氣被 積存於内部。一適合的施力空氣烘箱,舉例來説,如伊利 語州,藍島的藍Μ電氣公司(Blue M Electric Company ofDecember 3 1, J 9-30, 13344 A7 B7 V. Description of the invention (28) *;,: For each sample material, the water vapor transmission rate (WVTR) will be in accordance with ASTM Standard E96-80 It was evaluated. From each test material and a CELGARD (g) 2500 film control set from Hoechst Celanese Co., Ltd. of Shoemmerv, New Jersey, a 3-inch diameter circular sample was cut. . C ELGAR D⑧2 5 00 film is a microporous polypropylene film. Three samples are available for each material. This test dish was a 60 1 Vapometer gas meter pan sold by Thwing-Albert Instruments, Philadelphia, PA. In each Vapometer tray, 100 liters (m 丨) of steaming water was poured into the dish and individual samples in the test material and control group were placed across each individual dish. Top of the opening. The spiral flange is tightly rotated and fixed 'so as to form a seal along the edge of a shallow plate (without the use of a sealing lubricant), so that the relevant test material or control group material left in the surrounding air is exposed, exceeding 6.5 A circle with a diameter of centimeters (cm) has an exposed area close to 33.17 square centimeters. The tray is weighed and placed in a forced air oven set at 37 ° C. This oven is a warm oven with external air circulating through it to prevent water vapor from being trapped inside. A suitable forced air oven, such as the Blue M Electric Company of Blue Island, Ill.

Blue Island, Illinois)所販售的藍 M 動力一〇一Matic 60 (Blue M Power—〇一Matic 60)。於24小時之後,此淺盤被從此烘 箱中移出被再次稱重。此初步的測試水蒸氣傳輸率値,被 計算如下: WVTR = (24小時損失的克數)χ 315.5 請 先 閲 讀 背 面 冬 事 項 再Blue Island, Illinois (Blue M Power—010 Matic 60). After 24 hours, the tray was removed from the oven and weighed again. The preliminary test water vapor transmission rate, 値, is calculated as follows: WVTR = (grams lost in 24 hours) χ 315.5 Please read the winter item on the back first

頁 訂 經濟部中央標隼局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X297公釐) CL\PATF.NT\Pk-nni-n40—n4.^^\ Pff· pm.nAnA\pi-.nni.nana.i I 1 , 199: 31 3344 A7 B7 .<§|;5· 五、發明説明(29 ) g/m2/24 hrs 存在於此烘箱内部的相對濕度並未被特别地控制。 在初步設定的狀態100。F (32°C)、以周遭相對濕度下, CELGARD® 2500控制組薄膜的此WVTR已被測定爲每平 方公尺每24小時5000克。因此,此控制組樣品將執行每 一個測試,且此初步的測試値利用下列的程式而被校正爲 設定狀態: WVTR = (測試 WVTR/控制 WVTR)X 5000 g/m2/24 hrs g/m2/24 hrs 流體靜壓測試 此流體靜壓測試,將在低液體靜壓的狀態下,測量非 織物材料對水穿透力的抵抗力。此測試過程是根據方法 5514-聯邦測試方法標準編號191A ,AATCC測試方法 127—89以及INDA測試方法80.4-92。 經濟部中央標準局員工消費合作社印聚 一獲自南加利福尼亞州,在Spartanburg設有辦公室 的Schmid股份有限公司之Textest FX-300液體靜壓高差 測試器的測試頭,被純化的水所填滿。此純化的水被保持 於一溫度介於65°F與85°F之間(18.3與29_4°C),即存在 於正常室溫[約73°F (23°C)及約50%的相對濕度]的範圍 内’於此狀態下此測試被執行。一 8英叶X 8英忖(20 3 cm X 20.3 cm)正方形的此薄膜-非織物層壓製品樣品,其所具 有的非織物層被定位在相對於此測試頭内的水表面,如此 置放使得測試頭被完全地覆蓋住。此樣品將遭受一標準化 的水壓,以一固定速率被增加,直到洩漏現象被觀察發生Page order printed by employees of the Central Bureau of Standards, Ministry of Economic Affairs, Consumer Cooperatives. The paper size is applicable to the Chinese National Standard (CNS) Α4 specification (210X297 mm) CL \ PATF.NT \ Pk-nni-n40—n4. ^^ \ Pff · pm .nAnA \ pi-.nni.nana.i I 1, 199: 31 3344 A7 B7. < § |; 5. 5. Description of the invention (29) g / m2 / 24 hrs The relative humidity existing inside the oven and Not specifically controlled. 100 in the initial setting. This WVTR of CELGARD® 2500 control film at ambient relative humidity of F (32 ° C) has been determined to be 5000 grams per square meter per 24 hours. Therefore, this control group sample will perform each test, and this preliminary test is calibrated to the set state using the following program: WVTR = (Test WVTR / Control WVTR) X 5000 g / m2 / 24 hrs g / m2 / 24 hrs Hydrostatic Pressure Test This hydrostatic pressure test measures the resistance of non-woven materials to water penetration under low hydrostatic pressure conditions. This test procedure is based on Method 5514-Federal Test Method Standard Number 191A, AATCC Test Method 127-89, and INDA Test Method 80.4-92. The Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, Yin Juyi, obtained the test head of the Textest FX-300 hydrostatic pressure difference tester from Schmid Co., Ltd., which has an office in Spartanburg, Southern California, and was filled with purified water. . This purified water is maintained at a temperature between 65 ° F and 85 ° F (18.3 and 29_4 ° C), which is present at normal room temperature [about 73 ° F (23 ° C) and about 50% relative Humidity] This test is performed in this state. An 8-inch leaf x 8-inch (20 3 cm X 20.3 cm) square sample of this film-nonwoven laminate has a non-woven layer positioned on the water surface relative to the inside of the test head. Put the test head completely covered. The sample will be subjected to a standardized water pressure and will be increased at a constant rate until leakage is observed

A7 •'^^泛.:? 經濟部中央標準局員工消費合作社印製A7 • '^^ 泛.:? Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs

Μ -------Β7 五、發明説明(31) 起始點至65 mm端點間記錄其數據。斷而此以克爲單位、 使此薄膜層由此非織層貞脱層分離的平均的剝離強度將被 記錄爲結合強度,其指出欲分離此二層之以克爲單位的剌 離強度或負載量。以克爲單位的一最大、最小標準參數、 以及平均値亦被加以測量。 Μη 1壓榷測試 此杯壓榨測試將藉著利用此峰負載量、以及由一固定 延伸速率的抗張機械而來的能量單位,而被用來測量材料 柔軟度。較低的峰負載量値顯示較柔軟的材料。 此測試的過程在一控制的狀態下被執行,其中的溫度 约爲73°F且相對濕度約爲50百分比。樣品將利用一獲自 在北卡羅莱納州,Cary擁有辦公室之§jntech股份有限公 司的一 Sintech系統2電腦整合的測試系統,且杯壓榨標準 是獲自位於威斯康辛州,Neenah的金百利克拉克股份有 限公司本質保證部門(Kimberly-Clark Corporation QualityΜ ------- B7 V. Description of the invention (31) Record the data from the starting point to the endpoint of 65 mm. The average peel strength in grams that separates this film layer from the non-woven layer will be recorded as the bond strength, which indicates the detachment strength in grams or Load. A maximum and minimum standard parameter in grams and an average radon are also measured. Μη 1 crush test This cup crush test will be used to measure the softness of the material by using this peak load and an energy unit derived from a tensile machine with a fixed elongation rate. Lower peak loadings show softer materials. The process of this test is performed under a controlled condition where the temperature is approximately 73 ° F and the relative humidity is approximately 50 percent. Samples will use a Sintech System 2 computer-integrated test system obtained from §jntech Co., Ltd., an office in Cary, North Carolina, and the cup squeeze standard is obtained from Kimberly-Clark, Neenah, Wisconsin 1. Kimberly-Clark Corporation Quality

Assurance Department in Neenah, Wisconsin),其包括一 經濟部中央標準局員工消費合作社印製 型模型1 1足、一模型31鋼環、一底板、一模型41杯裝配 零件、以及一校準組。 此鋼環被置放於此成形滚筒上,且一 9 X 9英忖(22.9 cm X 22,9cm)的樣品被放置在此成形滚筒的中央。此成形 杯滑過此成形筒滾,直到此樣品環繞此鋼環而被挾在此成 形滾筒與此鋼環之間。此成形杯被置放在負載測定池之底 板的上方,並且穩定地固定在此底板的邊緣。足以設定在 _ __________C:\PATEN7\Pk-00 卜040 〜045~\Pk-〇〇 I 1-0404· 1 fdnr 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) Decemb" 3 i, j 99 34 5jl3344 S'\ A7 _ B7Assurance Department in Neenah, Wisconsin), which includes a model 11 feet printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, a model 31 steel ring, a base plate, a model 41 cup assembly parts, and a calibration group. The steel ring was placed on the forming drum, and a sample of 9 X 9 inches (22.9 cm X 22,9 cm) was placed in the center of the forming drum. The forming cup is rolled through the forming cylinder until the sample surrounds the steel ring and is held between the forming drum and the steel ring. The forming cup is placed above the bottom plate of the load cell and is firmly fixed to the edge of the bottom plate. It is enough to set in _ __________ C: \ PATEN7 \ Pk-00 040 040 ~ 045 ~ \ Pk-〇〇I 1-0404 · 1 fdnr This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) Decemb " 3 i , j 99 34 5jl3344 S '\ A7 _ B7

經濟部中央標準局員工消費合作社印製 五、發明説明(32 ) ' 每分鐘400公釐的十字頭速度,而被機械化地降低至此成 形杯中,在此固定延伸速率的抗張測試機械測試其以克爲 單位的峰載量、以及壓榨此樣品所需之以克—公釐爲單位的 能量時,壓榨此樣品。由每一樣品薄膜—非織物層壓製品材 料而來之3個樣本的峰負載量平均値及能量,被公佈於此。 进-歷捕集撕裂强麼 織品或材料的此梯形捕集撕裂強度,藉由以平行於此 測試材料長度的方向(長尺度),施加一固定增加的負載量。 此測試主要是直接以抗張負載量測量個别纖維之間的粘合 度或嵌鎖力及強韌度。完全撕裂此測試樣品所需的外力被 測知,其較咼的數値表示具有一較大的抗撕裂程度,故爲 一較強韌的材料。 從每一個被測試的樣品上切割下六個3 X 6英吋(76 X 152 mm)的測試樣本,其中三個樣本在朝向於cD方位上, 具有較長的尺寸,而另外三個樣本則是在朝向M D的方位上 具有較長的尺寸。一材料的梯形樣板,具有平行邊的長度 分别爲四英吋與一英吋,被置放在每一樣本上方,其平行 邊與此樣本的長度排成一列。以一製作筆將此梯形的外園 描繪於此樣本上。樣本中的撕裂是藉著從此梯形較短邊的 中央點延伸向内橫跨此樣本,製造一 5/8英吋(15 9 mm)的 長度切割而成。 沿著此非平行邊之此樣本的整個宽度,被置放在一固 疋延伸速率測試器的箝夾内部,此測試器例如由明尼蘇達 本紙張尺度適用中國國家標準(CNS )八4規格(21〇χ297公楚 nAn^T>%m\ nt. Λ/it r\Af\^ r\AC^\ nt. λλ t λ/h παπα i ..irPrinted by the Consumers 'Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. 5. Description of the Invention (32)' The crosshead speed of 400 mm per minute was mechanized lowered into this forming cup, and a tensile test machine with a fixed extension rate tested it. The peak load in grams and the energy in grams-mm needed to squeeze the sample squeeze the sample. The peak load average energy and energy of the three samples from each sample film-non-woven laminate material are disclosed here. Progressive Trap Tear Strength This trapezoidal trapped tear strength of a fabric or material is applied in a direction (long scale) parallel to the length of the test material by applying a fixed increase in load. This test is mainly used to directly measure the adhesion or interlocking strength and tenacity between individual fibers by the tensile load. The external force required to completely tear the test sample was measured. A higher number indicates that it has a greater degree of tear resistance and is therefore a stronger material. Cut six 3 x 6 inch (76 x 152 mm) test specimens from each of the specimens tested, three of which had longer dimensions in the cD orientation, while the other three were It has a long size in the direction toward MD. A material-like trapezoidal template, with parallel sides of four inches and one inch in length, is placed above each sample with its parallel sides aligned with the length of the sample. This trapezoidal outer garden is drawn on this sample with a production pen. The tear in the sample was cut across a 5/8 inch (15 9 mm) length by extending inward from the center point of the shorter side of the trapezoid. The entire width of the sample along this non-parallel edge is placed inside the jaws of a solid extension rate tester. This tester, for example, is based on the Chinese National Standard (CNS) 8-4 specification (21 〇χ297 公 Chu nAn ^ T >% m \ nt. Λ / it r \ Af \ ^ r \ AC ^ \ nt. Λλ t λ / h παπα i ..ir

December 31, 1997 35 il3344 A7 ----------B7 rrfeI^ 經濟部中央標準局員工消費合作社印製 五、發明説明(33 ) 州,Eden Prairie的MTS系統股份有限公司所生產的 Smtech系統2電腦整合測試系統。樣本内的切割是介於此 箝夹中央部位。-連續負載量以_十字頭速度爲12英对/ 分鐘,而被施加至此樣本,造成此切割橫跨此樣本寬度拓 展。元全撕裂此樣本所需的外力以英磅(外力)數記錄之,且 被換算成克數。根據ASTM標準測試D 1117—14,當其與 最低及最高負載量平均値比較時,撕裂負載量被計算爲第 -與最南峰載量記錄的平均^。於所有其它層面,此梯形 撕裂測試遵守ASTM標準測試D 1117一14的説明書所述。 含劑結合面積測試/最大距離 此粘合劑結合面積測試,將測量此薄膜層表面的一單 位積被施加一模型花樣之粘合劑面積的部分。此最大距離 測試則是測量介於位處此薄膜延伸方位上之枯合劑面積間 的相隔間距測量値。 從每一測試的樣品材料上切割下來之四至六個5~6平 方英忖(32〜39平方公分)的樣本。每一個樣本被置放於一小 錫罐内,並且利用-具有液體體積接近一加命(3 785 χ 1〇3 立方公尺)的玻璃乾燥器,而以四氧化餓(〇s〇4)蒸氣沾染一 段爲期16 +時的時間。此四氧化餓是由CA,Reddjng的Ted PeNa股份有m所提供。此四氧化蛾並不溶解於水中。 此被沾染過的層壓製品以手剝離開,而將被沾染的粘 合劑留在每—層壓製品的薄膜層表面上。此四氧化鐵去黏 性且爲交聯(強化的)的枯合劑,將促進此薄膜與非織物層的 本紙張尺度適用中國國家標準(CNSy^^^^297公冼·⑽冰-咖H·卜tfrfnr 敬) December 31 1997 36 五、發明説明(34 ) 離層作用。 此被沾染過的粘合劑利用一可獲自伊利諾州, Deerfleld之莱卡的廣M420巨型儀器,以一 FOSTEC纖維 光學環光’而將之映像於反射光中。影像可從一直接進入 普林斯頓伽瑪科技(紐澤西州的普林斯頓)|mag jstTM系統、 獲自印地安那州,密西根城之Dage MT丨的一型號爲CCD-72單色光照像機系統而加以取得。此影像照像機的手動控 制被加以利用,如此則在影像密度方面,將不會因爲自動 獲取控制補償作用,而產生不同的差異。此影像被臨界値 化、二元化,並且利用普林斯頓伽瑪科技影像分析軟體加 以分析。此結果產生的影像被列印於一惠普Packard PaintjetTM印表機。此百分比結合面積與介於位處範例薄膜_ 非織物層壓製品材料1〜5方向上的粘合劑面積間之此最大 距離平均値,被公佈於此處。 範例 一共有5個黏著性補強的薄膜非織物層壓製品的樣品 被陳述於下方。此黏著性補強的薄膜非織物層壓製品的樣 品’被設計以説明本發明特殊的實施例,且將指導精於此 技術的人士能進而完成本發明。December 31, 1997 35 il3344 A7 ---------- B7 rrfeI ^ Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of Inventions (33) Produced by MTS Systems Co., Ltd., Eden Prairie, State Smtech System 2 Computer Integrated Test System. The cut in the sample is centered on this jaw. -A continuous load was applied to the sample at a crosshead speed of 12 inches per minute, causing the cut to extend across the width of the sample. The external force required by Yuanquan to tear this sample is recorded in pounds (external force) and converted to grams. According to ASTM Standard Test D 1117-14, when it is compared with the minimum and maximum load averages, the tear load is calculated as the average of the -th and the southernmost peak load records ^. At all other levels, this trapezoidal tear test complies with the specifications of ASTM Standard Test D 1117-14. Agent-bonded area test / maximum distance This adhesive-bonded area test measures the area of a unit product on the surface of the film layer to which a patterned adhesive area is applied. The maximum distance test is to measure the separation distance between the areas of the cumulant in the extension direction of the film. Four to six 5-6 square-square (32-39 cm2) samples were cut from each sample material tested. Each sample was placed in a small tin can and used a glass desiccator with a liquid volume close to one plus (3 785 x 103 cubic meters), while starved with tetroxide (〇s〇4) The vapor contaminates for a period of 16+ hours. This starvation was provided by CA, Reddjng's Ted PeNa shares. This tetraoxide moth is not soluble in water. The stained laminate was peeled off by hand while leaving the stained adhesive on the surface of the film layer of each laminate. This iron tetraoxide is detackifying and is a cross-linked (reinforced) desiccant, which will promote the application of this national paper standard (CNSy ^^^^ 297 冼, ⑽ 冰 -HH) · Bu Tfrfnr) December 31 1997 36 V. Description of the invention (34) Delamination. This stained adhesive was reflected in reflected light with a FOSTEC fiber optical ring light 'using a wide M420 giant instrument available from Leica, Deerfleld, Illinois. Images can be directly entered from Princeton Gamma Technology (Princeton, New Jersey) | mag jstTM system, a model obtained from Dage MT, Michigan City, Indiana, a model of CCD-72 monochrome light camera system And get it. The manual control of the image camera is used, so that in terms of image density, there will be no difference due to the automatic acquisition of control compensation. This image was critically binarized, binary, and analyzed using Princeton Gamma Technology image analysis software. The resulting image was printed on an HP Packard PaintjetTM printer. The maximum distance between this percentage bonding area and the area of the adhesive in the direction of 1 to 5 of the example film_non-woven laminate material is averaged, and is published here. Examples A total of 5 samples of adhesively reinforced film non-woven laminates are stated below. This sample of adhesively reinforced film non-woven laminate is designed to illustrate a particular embodiment of the present invention and will guide those skilled in the art to complete the present invention.

範例I 根據本發明的一黏著性補強的薄膜非織物層壓製品被 製造形成。以此薄膜重量爲基準的一總重量百分比基重, __ ,___C:\PATENT\Pk001 040-045~\Pk-001-0404\Dk-001.n4n4.1ulf dor 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) December 3 I,J 9 9 37 丨13344 A7 B7 五、發明説明(35 ) 此薄膜層包含50%的Dowlex® NG3347A線性低密度聚乙 烯,其具有一熔流指數爲2.3 (在190。C下每10分鐘的克 數)、與一密度爲每立方公分0.917克(g/cc),以及5%的 Dow® 640支鏈低密度聚乙烯,其具有一熔流指數爲2〇 (在 190°C下每10分鐘的克數)、與一密度爲〇 922 g/cc。聚乙 稀聚合物的摻合物具有一熔流指數爲1 85 (19〇〇C下每 分鐘的克數)、與一密度爲1.452 g/cc。此Dowlex®與Dow® 可由密西根州,Midland的Dow化學U.S.A·獲得。此薄膜 層藉由English China Supercoat™總重爲準更進而包含 45%以1%的硬脂酸塗覆的碳酸鈣(Cac〇3),其具有1微米 的平均粒子大小、以及一 7微米的頂切割。此碳酸鈣是由 ECC國際的一分部、位於阿拉巴馬州,syiacauga的ECCA 碳產品股份有限公司所獲得。此薄膜的公式化是在一 333。F (168°C)的熔融溫度被吹塑成一單層的薄膜,以產生一具有 一起始未延展厚度約爲1β5密耳(約54 gsm)的薄膜。此薄 膜被加熱至一溫度約爲160。F (71。〇,且此薄膜利用可獲 自 Rhode 島,Providence 的 Marshall & Williams,型號 經濟部中央標準局員工消費合作社印製 7200的一機械方向定位(md〇)單位,操控於一線性速度爲 每分鐘500英呎(每分鐘152公尺),而被拉伸變薄至約4 〇 倍於它原來的長度,以至形成一有效厚度約爲〇 46密耳(約 1 8 gsm)。此薄膜在一溫度爲21 5°F (1 〇3°C)下被緩冷韌化。 此薄膜藉由公佈於下方表中的VVVTR數據指出,其爲透氣 性的。 此非織物層爲一大約〇_6 osy (約20 gsm)的紡粘織 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐)Example I An adhesive-reinforced thin film non-woven laminate according to the present invention is manufactured. A total weight percentage basis weight based on the weight of this film, __, ___ C: \ PATENT \ Pk001 040-045 ~ \ Pk-001-0404 \ Dk-001.n4n4.1ulf dor The paper dimensions are applicable to Chinese national standards (CNS ) A4 size (210X297 mm) December 3 I, J 9 9 37 丨 13344 A7 B7 5. Description of the invention (35) This film layer contains 50% Dowlex® NG3347A linear low density polyethylene, which has a melt flow index of 2.3 (grams per 10 minutes at 190 ° C), a density of 0.917 grams per cubic centimeter (g / cc), and 5% Dow® 640 branched low-density polyethylene, which has a melt flow index It is 20 (grams per 10 minutes at 190 ° C) and a density of 0922 g / cc. The blend of polyethylene polymers has a melt flow index of 1 85 (grams per minute at 1900C) and a density of 1.452 g / cc. This Dowlex® and Dow® are available from Dow Chemical U.S.A., Midland, Michigan. This film layer is based on the total weight of English China Supercoat ™ and further comprises 45% calcium carbonate (Cac03) coated with 1% stearic acid, which has an average particle size of 1 micron and a 7 micron Top cut. This calcium carbonate was obtained by ECCA Carbon Products, Inc. of Syiacauga, Alabama, a division of ECC International. This film is formulated at 333. The melting temperature of F (168 ° C) is blown into a single-layer film to produce a film having an initial unstretched thickness of about 1β5 mils (about 54 gsm). The film is heated to a temperature of about 160. F (71.0), and this film utilizes a mechanical orientation positioning (md〇) unit printed by 7200 printed on Rhode Island, Providence's Marshall & Williams, Central Standards Bureau Employees Consumer Cooperative of the Ministry of Economics, and controlled in a linear The speed was 500 feet per minute (152 meters per minute), and it was stretched to become thinner to about 40 times its original length, resulting in an effective thickness of about 0,46 mils (about 18 gsm). This film is slowly cooled and toughened at a temperature of 21 5 ° F (103 ° C). This film is indicated by the VVVTR data published in the table below, which is breathable. This non-woven layer is a The size of spunbond paper of about 〇_6 osy (about 20 gsm) is applicable to China National Standard (CNS) A4 (210X297 mm)

SlSPATBm\Pk-〇〇l.〇40-.〇45~\Pk-0〇l-〇404\Dk-001-0404-7 yiff 997 38 5i3344 A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明(36 ) 物’其是由丙埽與乙埽單體的一任意共聚物之可擠壓的熱 塑性塑樹脂所形成,此單體包含約3 3%重量百分比的乙烯 單體、以及96.7%重量百分比的丙烯單,其可獲自在德克 薩斯州的Houston擁有辦公室的shell Oi丨公司,產品命名 真6D43。此紡粘長纖實質上在自然情況下爲連績性的,且 具有一平均纖維尺寸爲2 2 dpf。利用一不連續的結合點型 式將此纺枯織物做熱預結合,其並具有一百分比的結合面 積約爲每單位面積此織物的1 5 〇/0。 此薄膜與非織物層利用一無規立構聚丙烯粘合劑的丁 烯共聚物,而被層壓在一起,此無規立構的聚丙烯可獲自 德克薩斯州,達拉斯的Rexene股份有限公司,產品命名爲 Rextac RT2730。此粘合劑以一任意分佈之熔喷粘合纖維 的形式,利用傳統的熔喷裝置,而被施加至此薄膜層,此 裝置實質上如描述於美國專利編號4,720,252中者,其合併 於此以供參考。此粘合劑被加熱至約350〇F (177°C),並且 在一空氣溫度約爲430°F (221°C)、一空氣壓力約爲20 psig (每平方公分1.41公斤)、一成形高度約爲3.0英吋(76.2 mm)、以及一線性速度約爲每分鐘300英呎(每分鐘91公尺) 的情況下,而被施加至此薄膜。此承載有枯合劑的薄膜層 與非織物層藉著通過一壓軋而被粘合在一起,此壓軋是由 反轉的平滑滚筒所形成。施加至此薄膜層上的粘合點與枯 合壓軋之間的距離,其中其有粘合劑的薄膜層與非織物層 被粘合在一起約1 3英叶(33.0 cm)。此粘合劑添加總量約爲 1.5gsm,且於此薄膜層延延方向上的此粘合劑面積的距離 ---Q\MT:ENT\Pk-001-(M0二… (請先閱讀背面之注意事項再本頁) 裝· 、\呑 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐)SlSPATBm \ Pk-〇〇l.〇40-.〇45 ~ \ Pk-0〇l-〇404 \ Dk-001-0404-7 yiff 997 38 5i3344 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Description of the invention (36) The object 'is formed from an extrudable thermoplastic resin of an arbitrary copolymer of acrylonitrile and ethylammonium monomer, and this monomer contains about 33% by weight of ethylene monomer, and 96.7 % By weight propylene sheet, which is available from Shell Oi 丨, which has an office in Houston, Texas. The product name is true 6D43. This spunbond filament is essentially continuous in nature and has an average fiber size of 2 2 dpf. A discontinuous bonding point pattern is used to thermally pre-bond this spun dry fabric, and it has a percentage bonding area of about 15/0 per unit area of the fabric. The film and non-woven layer are laminated together using a butene copolymer of an atactic polypropylene adhesive. The atactic polypropylene is available from Rexene, Dallas, Texas. Co., Ltd. The product name is Rextac RT2730. This adhesive is applied to the film layer in the form of an arbitrary distribution of meltblown adhesive fibers using a conventional meltblown device. This device is substantially as described in US Patent No. 4,720,252, which is incorporated herein by reference. for reference. The adhesive is heated to approximately 350 ° F (177 ° C) and has an air temperature of approximately 430 ° F (221 ° C), an air pressure of approximately 20 psig (1.41 kg per square centimeter), and a molding The film was applied at a height of approximately 3.0 inches (76.2 mm) and a linear velocity of approximately 300 feet per minute (91 meters per minute). The desiccant-bearing film layer and the non-woven layer are bonded together by a press roll, which is formed by an inverse smooth roll. The distance between the bonding point applied to this film layer and the dry rolling, in which the film layer with the adhesive and the non-woven layer were bonded together for about 13 inches (33.0 cm). The total amount of this adhesive is about 1.5gsm, and the distance of the area of this adhesive in the direction of extension of the film layer --- Q \ MT : ENT \ Pk-001- (M0 二 ... (Please read first Note on the back page again) The size of this paper is applicable to China National Standard (CNS) A4 (210X 297 mm)

December 3 1, 1 9 ! 39 B344 A7 B7 經濟部中央標準局員工消費合作杜印製 五、發明説明(37) 約爲〇·5英叶(12.7mm)。此平均分比結合面積約$ 百八 比。此結果產生的薄膜-非織物層壓製品具有— 刀 〇sy (約爲 40.8 gsm)。 土重爲 1·22 HJL2 一根據本發明的黏著性補強的薄膜_非織物層壓製品 被加以製造形<。以此薄膜重量爲基準的一總重百分比: 重而言,此薄膜層包含此薄膜層包含45%的D〇w丨以⑧ NG3347A線性低密度聚乙烯,以及55〇/〇總重的Eng丨^December 3 1, 1 9! 39 B344 A7 B7 Printed by the consumer cooperation of the Central Bureau of Standards of the Ministry of Economic Affairs. 5. Description of the invention (37) Approximately 0.5 Yingye (12.7mm). This average fractional combined area is approximately $ one hundred eighty. The resulting film-non-woven laminate has-knife sy (about 40.8 gsm). Soil weight is 1.22 HJL2. An adhesive-reinforced film according to the present invention_non-woven laminate is manufactured in the shape <. A percentage of the total weight based on the weight of the film: In a word, the film layer contains 45% of the film layer, including D0w 丨 NG3347A linear low-density polyethylene, and a total weight of 55 // Eng ^

China SupercoatTM碳酸鈣(CaC〇3),二者皆被詳細描述於 上方的範例1中。此薄膜被公式化爲在一熔融溫度爲36〇7 (182°C)下鑄模成一單層的薄膜,以產生一具有一起始未延 伸厚度約爲1·5密耳(約54 gsm)的薄膜。此薄膜被加熱至 一溫度約爲160<Τ (71。〇,且利用一如描述於範例,中的 M D〇單位,在一線性速度爲每分鐘500英呎(每分鐘152公 尺)的狀態下,被延展變薄化至約4_7倍於它本身的長度, 以形成一有效厚度約爲〇·46密耳(約18 gsm)。此薄膜在一 溫度爲200。F (93°C)下被緩冷韌化。此薄膜藉由公佈於下 方表中的WVTR數據指出,其爲透氣性的。 此非織物層與描述於上方範例1中者相同。 此薄膜與非織物層利用一著色的嵌段共聚物壓敏粘合 劑,而被層壓在一起,此壓敏粘合劑可獲自在紐約州 Bridgewaer具有辦公室的國際澱粉與化學股份有限公司, 產品命名爲Dispomelt® NS34-561 0。此粘合劑可以被施加 ____C:\PATENT\Pk-Q01-(MO-045~\Pk-001-04(M\Dk-001-0404-1.ulf.dnr 本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ297公釐〉 (請先閲讀背面之注意事項再頁) -裝. 40 經濟部中央標準局員工消費合作社印製 ^?AT^^\Pk-0〇U〇4〇^〇4S^\pk.〇〇i.〇4〇4\pk-001^04Q4-lMlf.doc ψ· I Α7 m 五 " ^此薄膜層,其所使用的方法是先藉著將此粘合劑以一如 丨 冑示於圖4中之雲朵的模型花樣,印製於一合適鬆解的紙張 "、:後再利用一傳統的篩網印製法與轉移處理,將此粘 :劑轉印至此薄膜表面上。此粘合劑在一線性速度約爲每 分鐘25〜50英叶(每分鐘7 6〜15 2公尺)的狀態下,被施加 j此鬆解的紙張,且此枯合劑在一線性速度爲每分鐘_ I ★吋(每刀鐘91公尺)的情況下,被轉移至此薄膜上。此承 載有,合劑的薄膜層與非織物層,藉由通過一由反轉的平 、袞筒所形成的壓軋而被枯合在_起。此枯合劑的添加總 ,約爲9.〇gSm,且於此薄膜延伸方向上之粘合劑面積間的 =大距離約爲1.0英叶(25.4 mm)。此平均百分比枯合面積 、、’勺爲1 2百分比。此結果產生的薄膜—非織物層壓製品具有 一基重約爲47.0 gSm。 $g m 3 根據本發明之一黏著性補強的薄膜·非織物層壓製品 被製造形成。此薄膜與非織物層二者皆如上方範例2所描 述。 此薄膜與非織物層,利用如描述於範例2中之相同的 粘合劑而被粘合在一起。此粘合劑被施加至此薄膜層,其 方法是首先將如顯示於圖3中之肋狀模型花樣的粘合劑印 製於一合宜的鬆解紙張上,然後再將粘合劑以如描述於範 例2中的方式轉印至此薄膜層表面。此粘合劑在一線性速度 、.勺爲每刀鐘25〜50 4对(每分鐘7.6〜15·2公尺)的狀態下, 本紙張尺度適用中國國家標準(CNS ) a4規格(210Χ 297公釐) 997China SupercoatTM calcium carbonate (CaCO3), both of which are described in detail in Example 1 above. This film was formulated as a single layer film molded at a melting temperature of 3607 (182 ° C) to produce a film with an initial unstretched thickness of about 1.5 mils (about 54 gsm). The film was heated to a temperature of about 160 < T (71.〇, and using the MD0 unit as described in the example, at a linear velocity of 500 feet per minute (152 meters per minute). It is stretched and thinned to about 4-7 times its length to form an effective thickness of about 0.46 mils (about 18 gsm). The film is at a temperature of 200 ° F (93 ° C) It is slowly toughened. This film is indicated by the WVTR data published in the table below, which is breathable. This non-woven layer is the same as described in Example 1 above. This film and non-woven layer utilize a colored Block copolymer pressure sensitive adhesives, which are laminated together, are available from International Starch & Chemical Corporation, based in Bridgewaer, New York, under the product name Dispomelt® NS34-561 0. This adhesive can be applied to ____ C: \ PATENT \ Pk-Q01- (MO-045 ~ \ Pk-001-04 (M \ Dk-001-0404-1.ulf.dnr) This paper size applies to Chinese national standards ( CNS) Α4 specification (210 × 297 mm) (Please read the precautions on the back before the next page)-Packing. 40 Central Standards of the Ministry of Economic Affairs Printed by the employee consumer cooperative ^? AT ^^ \ Pk-0〇U〇4〇 ^ 〇4S ^ \ pk.〇〇i.〇4〇4 \ pk-001 ^ 04Q4-lMlf.doc ψ · I Α7 m 5 " ^ The method of this film layer is to first print this adhesive on a suitable loose paper by the pattern of the clouds as shown in Fig. 4 ",: Then use a traditional screen printing method and transfer process to transfer this adhesive to the surface of the film. The adhesive is at a linear speed of about 25 to 50 inches per minute (7 6 to 15 per minute). Under the condition of 2 meters), the loose paper was applied, and the desiccant was transferred to the film at a linear speed of _I * inches per minute (91 meters per knife clock). The film layer and the non-woven layer carrying the mixture are dried up by pressing through a flat roll formed by a reversing flat tube. The total addition of this mixture is approximately 9. gSm, and the distance between the adhesive areas in the film extension direction = a large distance of about 1.0 inch leaf (25.4 mm). The average percentage dead area, and the spoon is 12%. The thin —Non-woven laminates have a basis weight of approximately 47.0 gSm. $ Gm 3 An adhesive-reinforced film according to the invention is made from a non-woven laminate. Both the film and the non-woven layer are as in the example above Described in 2. This film and non-woven layer are bonded together using the same adhesive as described in Example 2. This adhesive is applied to this film layer by first displaying as shown in the figure The adhesive of the rib-shaped pattern in 3 is printed on a suitable release paper, and then the adhesive is transferred to the surface of the film layer as described in Example 2. This adhesive is in a linear speed, 25 to 50 spoons per knife clock (7.6 to 15.2 meters per minute), the paper size is applicable to the Chinese National Standard (CNS) a4 specification (210 × 297 Mm) 997

41 經濟部中央標準局員工消費合作社印製 ^:S^^^T\Pk-001-040-~0^5~\Pk-001-040^\pk-001-0404- Ι.ύίΓ.ήη, 5【3344 . Α7 _______Β7_ IL· 五、發明説明(39) ~- 被施加至此鬆解的紙張,且此粘合劑在一線性速度爲每分 鐘300英吋(每分鐘91公尺)的情況下,被轉移至此薄膜上。 | 此承載有粘合劑的薄膜層與非織物層,藉由通過一由反轉 的平滑滾筒所形成的壓軋而被粘合在一起。此粘合劑的添 加總量約爲17.0 gsm ,且於此薄膜延伸方向上之粘合劑面 積間的最大距離約爲〇.25英吋(6 35 mm)。此平均百分比粘 I 合面積約爲22百分比。此結果產生的薄膜一非織物層壓製 品具有一基重約爲56 3 m。 範例4 根據本發明的一黏著性補強的薄膜_非織物層壓製品 被製造形成。此薄膜層與描述於上方範例2中者相同。此非 織物層爲一約0.5 osy (約17 gsm)的紡粘織物,其是由可 擠壓的熱塑性聚丙烯纖維所形成,可獲自在德克薩斯州, Houston擁有辦公室的Exxon股份有限公司,產品命名爲 3 4 4 5。此結枯長纖先天上實質爲連續性的,且具有一平均 纖維尺寸爲2.2 dpf。此紡粘織物爲熱預粘合的,其是利用 一分離模式的粘合點所形成,並具有一百分比粘合面積約 爲每單位面積此織物的1 5〇/0。 此薄膜與非織物層利用乙烯—醋酸乙烯酯粘合劑之 1 8 /。醋酸乙烯脂共聚物而被層壓在一起,此枯合劑可獲自達 拉威州 ’ Wilmington 的 Ε·Ι· DuPont de Nemours,其產品 命名爲Elvax 41 0。此粘合劑直接地以顯示於圖3中的模型 才匕樣’而被篩網印製於此薄膜層上。此粘合劑在一線性速 本紙張尺度逋财關料轉(CNS ) A4規格(21GX297公釐) Π , 19 9;41 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs ^: S ^^^ T \ Pk-001-040- ~ 0 ^ 5 ~ \ Pk-001-040 ^ \ pk-001-0404- Ι.ύίΓ.ήη, 5 【3344. Α7 _______ Β7_ IL · V. Description of the Invention (39) ~-At the linear velocity of 300 inches per minute (91 meters per minute) Is transferred to this film. | The adhesive-laminated film layer and the non-woven layer are bonded together by a nip formed by an inverse smooth roller. The total added amount of this adhesive is approximately 17.0 gsm, and the maximum distance between the adhesive areas in the film extension direction is approximately 0.25 inches (6 35 mm). This average percentage sticking area is approximately 22%. The resulting film-laminated laminate has a basis weight of about 56 3 m. Example 4 An adhesive-reinforced film_non-woven laminate according to the present invention is manufactured. This thin film layer is the same as that described in Example 2 above. This non-woven layer is a spunbond fabric of about 0.5 osy (about 17 gsm), which is formed from extrudable thermoplastic polypropylene fibers and is available from Exxon Inc., an Houston-based office in Texas. The product is named 3 4 4 5. This dead filament is inherently continuous in nature and has an average fiber size of 2.2 dpf. The spunbond fabric is thermally pre-bonded, which is formed using bonding points in a separation mode, and has a percentage bonding area of about 150/0 per unit area of the fabric. The film and the non-woven layer use an ethylene-vinyl acetate adhesive. Laminated together with vinyl acetate copolymers, this cumulant is available from E.I. DuPont de Nemours, wilmington, dalawi, under the product name elvax 4100. The adhesive was directly printed on the film layer in the form of the model shown in Fig. 3 '. This adhesive is a linear paper scale (CNS) A4 size (21GX297 mm) Π, 19 9;

42 5i334442 5i3344

經濟部中央標準局員工消費合作社印策 A7 B7 五、發明説明(40 ) 度约爲每分鐘25〜50英吋(每分鐘 丁 、 ’·6〜1 5·2公尺)的狀熊 下’被施加至此薄膜層。此承載有姑 ^ ..,^ 執百枯合劑的薄膜層與非織 物層,藉由通過一由反轉的平滑涪 “ 干有滾靖所形成的壓軋而被粘 合在一起。施加至此薄膜層上的枯人 、# 祁口點、與承載有粘合劑 又涛膜層與此非織物層被接合在一知b 伐口在起的粘合壓軋之間的距 離約爲2 3英对(5 8 · 4 c m)。此枯人赛丨沾、# ’才口蜊的添加總量約爲1.0至 2.0 gsm,且於此薄膜延伸方向上之鉍 〈枯合劑面積間的最大距 離約爲0.25英吋(6.35 _)。此平均百分比枯合面積約爲 2 2百分比。此結果產生的薄膜_非織物層壓製品具有—基重 約爲 3 7.3 g s m。 範例5 根據本發明的一黏著性補強的薄膜_非織物層壓製品 被製造形成。所使用的此薄膜層、非織物層以及粘合劑, 與描述於上方範例2中者相同,除了此粘合劑爲未著色者之 外。 此枯合劑利用一控制塗覆TM(c〇ntr〇| c〇atTM)喷麗枯合 劑模型施加器’而被施加至此薄膜層上,此施加器可獲自 在喬治亞州,No「cross擁有辦公室的Nordson股份有限公 司,其產品命名爲計量式控制塗覆施加器(Metered Control CoatTM Applicator)。此粘合劑被加熱至 350cF (177。C),並 在空氣溫度約380°F (193°C)、一空氣壓力約爲80 psig —.63 kg/cm2)、一成形高度約爲1 ·〇英吋(25.4 mm)、以及 (5 線 性速度約爲每分鐘400英吋(每分鐘120公尺)的狀態 C:\PATENT\Pk-00J -040-045~\Pk-001-0404\pk-001-0404-1 .ulf.doc 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) ib &lt; 9 9; 請 先 閱 讀 背 ιέ 之 注 意 事 項 再Imprint A7 B7, Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Description of the invention (40) The degree is about 25 ~ 50 inches per minute (min., '· 6 ~ 1 5 · 2 meters)' Applied to this thin film layer. The film layer and the non-woven layer carrying the ^^ .., ^ Zhibaiku mixture are bonded together by a rolling formed by a reverse smooth 涪 "drying and rolling." Applied here The distance between the dry layer on the film layer, the #qikou point, the adhesive layer and the non-woven layer carrying the adhesive layer, and the non-woven layer are joined at a distance of about 2 3 British pair (5 8 · 4 cm). The total added amount of this dry man race 丨 Zhan, # 'caikou clam is about 1.0 to 2.0 gsm, and the maximum distance between the area of bismuth <the mixture agent in the direction of the film extension About 0.25 inches (6.35 mm). This average percentage dead area is about 22%. The resulting film_non-woven laminate has a basis weight of about 3 7.3 gsm. Example 5 Adhesive-reinforced film_Non-woven laminate is manufactured. The film layer, non-woven layer, and adhesive used are the same as those described in Example 2 above, except that the adhesive is an uncolored one. The cumulant mixture uses a controlled coating TM (c〇ntr〇 | coatTM) spray cumulant model applicator Applied to this film layer, this applicator is available from Nordson Corporation, which owns an office in No. Cross, Georgia. Its product is named Metered Control CoatTM Applicator. This adhesive Is heated to 350cF (177 ° C), and has an air temperature of about 380 ° F (193 ° C), an air pressure of about 80 psig to .63 kg / cm2), and a forming height of about 1.0 inches ( 25.4 mm), and (5 linear speed of about 400 inches per minute (120 meters per minute) C: \ PATENT \ Pk-00J -040-045 ~ \ Pk-001-0404 \ pk-001-0404 -1 .ulf.doc This paper size applies to China National Standard (CNS) A4 (210X 297 mm) ib &lt; 9 9; Please read the precautions before reading

頁 訂 43Page Order 43

I I 11 ZLZ 3 3 A7 B7 五、發明説明(41 ) 下,被施加至此薄膜上。此承載有枯合劑的薄膜層與非織. 物層,藉著通過一由反轉平滑滾筒所形成的壓軋而被粘合 在一起。施加至薄膜層的枯合點、與此承載有枯合劑之薄 膜層與此非織物層接合在一起的粘合壓軋之間的距離約爲 23英吋(58·4 cm)。此粘合劑添加總量約爲2.0 gsm,且此 位於此薄膜層延伸方向上枯合劑面積之間的最大距離約爲 0.1英吋(2.54 mm)。此平均百分比粘合面積約爲15百分 比。此結2果產生的薄膜-非織物層壓製品具有一基重約爲 42.4 gsm 〇I I 11 ZLZ 3 3 A7 B7 5. In the description of the invention (41), it is applied to this film. The film layer and the non-woven layer carrying the desiccant are bonded together by a nip formed by a reverse smooth roller. The distance between the desiccation point applied to the film layer and the bonding press bonded to the film layer carrying the desiccant and this nonwoven layer was approximately 23 inches (58.4 cm). The total amount of this adhesive added is about 2.0 gsm, and the maximum distance between the area of the desiccant in the direction of extension of this film layer is about 0.1 inches (2.54 mm). This average percentage bonded area is about 15 percent. The resulting film-nonwoven laminate has a basis weight of approximately 42.4 gsm.

表I 請 閱 讀 背 面 I 事 項 再 .經濟部中央標準局員工消費合作社印製 範例 MD 抗張強度 (克數) MD斷裂伸 度百分比 (%) CD 抗張強度 (克數) CD斷裂伸 度百分比 (%) VWTR (g/m2/24 小時) 水頭 (cm) 1 8260 75 4120 75 890 170 2 8928 58 3371 84 3563 140 3 9836 75 4101 93 2892 159 4 8118 47 4603 43 180 5 1 0893 83 3873 82 3876 177 C:\PATENT\Pk-001-040-045~\Pk-001-0404\pk-001-0404-l.ulf.docTable I Please read item I on the back again. Example printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economics MD tensile strength (grams) MD elongation at break (%) CD tensile strength (g) CD break elongation percentage ( %) VWTR (g / m2 / 24 hours) Head (cm) 1 8260 75 4120 75 890 170 2 8928 58 3371 84 3563 140 3 9836 75 4101 93 2892 159 4 8118 47 4603 43 180 5 1 0893 83 3873 82 3876 177 C: \ PATENT \ Pk-001-040-045 ~ \ Pk-001-0404 \ pk-001-0404-l.ulf.doc

December 3 1, 19 9 7 本紙張尺度適用中國國家標準(CNS ) A4規格(210'〆 297公釐) 44 令13344 U ΑΊ &quot; Β7December 3 1, 19 9 7 This paper size applies Chinese National Standard (CNS) A4 specification (210'〆 297 mm) 44 Order 13344 U ΑΊ &quot; Β7

五、發明説明(42V. Description of the invention (42

表II 範例 剝離強度 (克數) 560 杯壓榨能量 (克數/mm) 1649 杯壓榨負載量 (克數) 84 MD捕禁撕離 強度(克數) MD捕集撕離 強度(克數) 3677 1662 2 1328 987 57 2815 1440 3 ΝΑ, 1255 66 3985 1580 4 130 1117 58 2137 995 5 254 1465 74 3285 1768 請 先 閱 讀 背 之 注 意 事 項 再 頁 * N A所意指薄膜與非織物層可以被手動式地分離。 做爲比較之目的,且更特别的是將存在於此合併至本 發明薄膜-非織物層壓製品上之此薄膜層強度與耐久性的粘 合劑補強作用的衝突獨立出,則對於此薄膜層、以及同時 可獲自商業上吸收性物件的一薄膜-非織物層壓製品之薄膜 層的數據,將被集合描述於此處範例1 -5中。Table II Example peel strength (grams) 560 cup crushing energy (grams / mm) 1649 cup squeeze load (grams) 84 MD trapping tear strength (grams) MD trapping tear strength (grams) 3677 1662 2 1328 987 57 2815 1440 3 Ν, 1255 66 3985 1580 4 130 1117 58 2137 995 5 254 1465 74 3285 1768 Please read the notes on the back and then the page * NA means that the film and non-woven layer can be manually Separation. For comparison purposes, and more particularly, the conflict between the strength of this film layer and the durable adhesive reinforcement effect that is incorporated into the film-nonwoven laminate of the present invention is independent, then for this film The data for the layers, and the film layers of a film-nonwoven laminate, which are also available from commercially available absorbent articles, will be collectively described in Examples 1-5 herein.

比較牲範例 fcb較範例I 經濟部中央標隼局員工消費合作社印製 此薄膜層與描述於範例1中者相同,但其並沒有粘合 劑面積的施加。 比較範例2 此薄膜層範例1中所描述的相同,具有與範例1中所 描述之相同的粘合劑類型與施加的模型花樣。 Ρ\ΡΑΤΕΝΤ\Ρ)ζ-001·040-045ΛΡ^001·0404\ρ}(:-001-0404- l.ulf.docComparative example fcb Comparative example I Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs This film layer is the same as described in Example 1, but without the application of adhesive area. Comparative Example 2 The same as described in Example 1 of this film layer, with the same adhesive type and applied pattern as described in Example 1. Ρ \ ΡΑΤΕΝΤ \ Ρ) ζ-001 · 040-045ΛP ^ 001 · 0404 \ ρ} (:-001-0404- l.ulf.doc

December 3 1, 19 9 7 本紙張尺度適用中國國家標準(CNS ) Μ規格(210X 297公釐) 45 13344 A7 B7 五、發明説明(43 H:較範例3 此薄膜層與範例2所描述的相同,但其不具有粘合劑 面積的施加。 比較範例4 此薄膜層與範例2所描述者相同,具有描述於範例2 中相同的粘合劑類型與施加的模型花樣。 比較範例5 此薄膜層與範例3所描述者相同,具有與描述於範例3 中相同的粘合劑類型與施加的模型花樣。 比較範例6 此薄膜層與範例5所描述者相同,具有與描述於範例5 中相同的粘合劑類型與施加的模型花樣。 比較範例7 經濟部中央標準局員工消費合作社印製 此非透氣性薄膜層可獲自一在商業上由金百利克拉克 股份有限公司(Kimberly-Clark Corporation),即發明的受 託者,所販售之可棄式尿布的此薄膜-非織物層壓製品外 罩,其產品命名爲Huggies® Ultratrim尿布。沒有枯合劑 被施加至此薄膜層上。此薄膜層具有一有效厚度約爲 密耳。 CVMrEmPfc-OOl· 0^〇-〇45-\Pk-0〇l.〇404\pk-001.〇4(M-]Mli.doc 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐)December 3 1, 19 9 7 This paper size applies Chinese National Standard (CNS) M specifications (210X 297 mm) 45 13344 A7 B7 V. Description of the invention (43 H: Compared with Example 3 This film layer is the same as described in Example 2 , But it does not have the application of adhesive area. Comparative Example 4 This film layer is the same as described in Example 2, with the same adhesive type and applied pattern described in Example 2. Comparative Example 5 This film layer Same as described in Example 3, with the same adhesive type and applied pattern as described in Example 3. Comparative Example 6 This film layer is the same as described in Example 5, with the same properties as described in Example 5. Type of adhesive and applied pattern. Comparative Example 7 This non-breathable film layer printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs is commercially available from Kimberly-Clark Corporation The film-non-woven laminate cover of the disposable diaper sold by the trustee of the invention, named Huggies® Ultratrim diapers. No deadening agent was applied So far, the film layer has an effective thickness of about mils. CVMrEmPfc-OOl · 0 ^ 〇-〇45- \ Pk-0〇l.〇404 \ pk-001.〇4 (M-) Mli. doc This paper size applies to China National Standard (CNS) A4 (210X297 mm)

December 31, 1997 46 3344 * A7 B7 五、發明説明(Φ4)December 31, 1997 46 3344 * A7 B7 V. Description of Invention (Φ4)

表III 比較 範例 MD 抗張強度 (克數) MD斷裂伸 度百分比 (%) CD 抗張強度 (克數) CD斷裂伸 度百分比 (%) WVTR (g/m2/24 小時) 1 4850 150 830 500 1240 2 6300 162 870 550 3 8444 135 698 265 3800 4 6212 101 525 323 3471 5 6800 114 669 427 3827 6 5448 96 585 517 3631 7 2500 180 840 450 70 (請先閱讀背面之注意事項再填寫本頁) 比較性範例1 -6的數據,清楚地説明了描述於此處之 粘合劑面積對於此薄膜層的強度與韌性或耐久性所造成的 衝擊應用。特别是在橫跨機械方向上,位單軸、機械方向 定位上的薄膜,其典型上不具有良好的強韌性度或耐久性, 原始未處理的薄膜與那些相同但是施加有粘合劑面積的薄 膜間,在斷裂時百分比延長量的增加値,説明了此粘合劑 面積的補強作用。 最後,對於比較範例7數據,其證實了被結合至本發 明之薄膜-非織物層壓製品中的黏著性補強薄膜層,在強度 與韌性方面至少與商業上可得的薄膜層可相比擬。 被可望的是,此一根據本發明所結構成的黏著性補強 薄膜-非織物層壓製品,可依那些精於此技術的人士而加以 裁製與調飾,以包容各種不同程度的表現,提供於使用期 C:\PATENT\Pk.001 ·040 〜045~\Pk-001 -0404\pk-001 -0404-1 .ulf.doc 本紙張尺度適用中國國家標準(CNS ) A4規格(21 ΟΧ 公釐) 、v$ 經濟部中央標準局員工消費合作社印製Table III Comparative Examples MD Tensile Strength (grams) MD Fracture Elongation (%) CD Tensile Strength (grams) CD Fracture Elongation (%) WVTR (g / m2 / 24 hours) 1 4850 150 830 500 1240 2 6300 162 870 550 3 8444 135 698 265 3800 4 6212 101 525 323 3471 5 6800 114 669 427 3827 6 5448 96 585 517 3631 7 2500 180 840 450 70 (Please read the notes on the back before filling this page) Compare The data of property examples 1 to 6 clearly illustrate the impact application of the adhesive area described herein on the strength and toughness or durability of this film layer. In particular, films that are positioned in uniaxial and mechanical directions across the mechanical direction typically do not have good toughness or durability. The original untreated films are the same as those with the adhesive area applied. The increase in percentage elongation between films during breakage, 値, illustrates the reinforcing effect of this adhesive area. Finally, for the data of Comparative Example 7, it was confirmed that the adhesive reinforcing film layer incorporated into the film-nonwoven laminate of the present invention was at least comparable in strength and toughness to commercially available film layers. It is expected that the adhesive reinforcement film-non-woven laminate structure constructed according to the present invention can be tailored and decorated according to those skilled in this technology to accommodate various levels of performance , Provided during the use period C: \ PATENT \ Pk.001 · 040 ~ 045 ~ \ Pk-001 -0404 \ pk-001 -0404-1 .ulf.doc This paper size is applicable to China National Standard (CNS) A4 specification (21 Οχ mm), v $ Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs

December 3 1, 19 9 7 47December 3 1, 19 9 7 47

A7 B7 五、發明説明(45) 間所需。因此,當本發明藉由某些特定的實施例與範例加 以描述時,應被了解的是本發明將可有進一步的調節應用。 由是本申請案意圖函蓋任何依循此處所述之_般性原則對 於本發明所做之不同形式的應用或改造,並包括此由本發 明揭示所衍生出者,且包含於此技術的慣例實習與知識範 園内,其本發明將隸屬並侷限於所附之申請專利範園的限 制内。 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局貝工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) C:\PATEm\Pk-001-040~-045~\Pk-001-0404\pk-001-0404-l.ulf.docA7 B7 V. Description of invention (45). Therefore, when the present invention is described by some specific embodiments and examples, it should be understood that the present invention will have further adjustment applications. It is the intention of this application to cover any form of application or modification made to the invention in accordance with the general principles described herein, and includes the practice derived from the disclosure of this invention and included in this technology In the field of internship and knowledge, the invention will be affiliated and limited to the scope of the attached patent application park. (Please read the precautions on the back before filling out this page) The paper size printed by the Central Standards Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperative Co., Ltd. The paper size applies to the Chinese National Standard (CNS) A4 specification (210X 297 mm) C: \ PATEm \ Pk-001 -040 ~ -045 ~ \ Pk-001-0404 \ pk-001-0404-l.ulf.doc

December 3 1, 19 9 7 48 3344 ;·ρ^^' . 經濟部中央梂準局員工消費合作社印裝 A7 B7 五、發明説明(46) 圖式簡單説明 28. 尿布(20)的縱向邊緣 10. 黏著性補強薄膜-非織物層壓製品 12. 薄膜層 14. 薄膜層表面 16. 非織物(層) 18. 粘合劑面積 20. 可棄式尿布 22. 不滲液外罩 24. 滲液體側襯墊 26. 吸收芯 30. 末端邊緣 32. 園堵襟片 34. 鉤元件 36. 環元件或嵌片 (請先閱讀背面之注意事項再填寫本頁) C:\PATBNT\Pk-001-040~-045~\Pk-001-0404\pk-001-0404-l.ulf.docDecember 3 1, 19 9 7 48 3344; · ρ ^^ '. Printed by A7 B7, Consumer Cooperatives of the Central Procurement Bureau of the Ministry of Economic Affairs 5. Explanation of the invention (46) Simple illustration of the drawing 28. Longitudinal edges of the diaper (20) 10 Adhesive reinforcement film-non-woven laminate 12. Film layer 14. Surface of film layer 16. Non-woven (layer) 18. Adhesive area 20. Disposable diaper 22. Liquid-impermeable cover 24. Liquid-permeable side Liner 26. Absorbent core 30. End edge 32. Round blocking flap 34. Hook element 36. Loop element or insert (please read the precautions on the back before filling this page) C: \ PATBNT \ Pk-001-040 ~ -045 ~ \ Pk-001-0404 \ pk-001-0404-l.ulf.doc

December 3 1, 19 9 7 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 49December 3 1, 19 9 7 This paper is sized for China National Standard (CNS) A4 (210X297 mm) 49

Claims (1)

J 丄 J)J 丄 J) 1 . 經濟部If 2. 種黏奢性補強的薄膜_ 供非織物層壓製品,其包含: 一具有一表面的第一纖維性非織物層; 一具有一第一表面的薄膜層; 前述的薄膜層被定位於延伸 心,%夂伸的万向,且具有一有效厚度 爲〇 _ 6密耳或更小; 則述的薄膜層由一摻合物所形成,此摻合物以此薄膜屛 的總重爲基準的-總重量百分比基重,包括由30百: 比至70百分比的一第_聚烯烴聚合物由7〇百分比 至30百分比的塡充料、以及由〇纟2〇百分比的—第 一聚埽經聚合物; 則述的薄膜層具冑一水蒸氣傳輸率至少爲每平方公尺 每24小時300克; 一模型花樣的粘合劑面積被施加至前述薄膜層的第— 表面上; 則述模型花樣的粘合劑面積具有一添加總量從每平方 A尺0_1至20克、一百分比粘合面積從前述薄膜層表 面之每單位面積的5百分比至5〇百分比、以及一二於 通常平行於前述延伸方向上之&amp;合劑面積間的最大距 離爲0.1英对或更小; 則述纖維性非織物層的表面,藉著將前述模型花樣的粘 合劑面積施加至前述的薄膜表面,而被粘附至前述薄膜 層的表面上,進而形成一層壓製品。 如申請專利範圍第,項的黏著性補強薄膜,織物層壓 製品,其中所提及的層壓製品具有一橫跨機械方向4抗 本、我張尺度適用中(CNS)A~4^MTno χ 297公釐)1. Ministry of Economic Affairs If 2. A kind of viscous and reinforced film _ for a nonwoven laminate, comprising: a first fibrous nonwoven layer having a surface; a film layer having a first surface; the aforementioned The film layer is positioned at the extension center, with a universal extension, and has an effective thickness of 0-6 mils or less. The film layer is formed of a blend, and the blend is based on the film. The total weight of rhenium is based on the total weight percentage basis, including from 30 to 70 percent of the first polyolefin polymer from 70 to 30 percent of rhenium filling, and from 0.02 to 20 percent. -The first polymer is a polymer; the film layer has a water vapor transmission rate of at least 300 grams per square meter per 24 hours; a patterned adhesive area is applied to the first film layer — On the surface; the adhesive area of the model pattern has an added amount from 0 to 20 grams per square foot A-1, a percentage of adhesive area from 5 to 50 percent per unit area of the surface of the film layer, And one or two are generally parallel to the aforementioned extension The maximum distance between the &amp; mixture areas is 0.1 inches or less; the surface of the fibrous non-woven layer is adhered by applying the adhesive area of the aforementioned model pattern to the aforementioned film surface. Onto the surface of the aforementioned film layer to form a laminate. For example, the adhesive reinforcement film and item of the scope of the patent application, the laminated fabric, the mentioned laminated product has a cross-machine direction, 4 resistance, and our standard application (CNS) A ~ 4 ^ MTno χ 297 mm) -----------裝--------訂---------· (請先閱讀背面之注音?事項再填寫本頁) 申請專利範圍 經 濟 部 智 慧 財 產 局 員 工 消 費 合 社 印 制 張強度至少爲3000克。 3.如申請專利範圍帛1項的黏著性補強薄膜_非織物層壓 製品,其t所提及的層壓製品具有一在斷裂時之橫跨= 械方向的伸度至少爲35%。 4·如申請專利範目帛1項的黏著性補強薄膜·非織物層壓 製品,其中所提及的層壓製品具有一水蒸氣傳輸率ϋ 爲每平方公尺每24小時1 000克。 如申請專利範圍第1項的黏著性補強薄膜_非織物層壓 製品,其中所提及的層壓製品具有—剝離強度至爲 1 0 0 克。 如申請專利範圍第1項的黏著性補強薄膜_非織物層壓 製品,其十所提及的層壓製品具有一杯壓榨負載量少於 100 克。 ' 如申請專利範圍第1項的黏著性補強薄膜_非織物層壓 製品,其中所提及的層壓製品具有一橫跨機械方向:二 撕離強度至少爲950克。 如申請專利範圍第1項的黏著性補強薄膜-非織物層壓 製品,其中所提及通常平行於前述延伸方向上之粘合劑 面積間的最大距離爲0.25英吋或更小。 如申請專利範圍第1項的黏著性補強薄膜-非織物層壓 製品,其中所提及通常平行於前述延伸方向上之粘合劑 面積間的最大距離爲〇 . 1 25英付或更小。 1〇·如申請專利範圍第1項的黏著性補強薄膜_非織物層壓 製品,其中所提及的粘合劑添加總量爲由每平方公尺 度適用中標準(CNS)A4規格(Π〇 X 297公爱) 5. 6. 訂 8. 9. # 513344 A8 B8 C8 ___ D8 六、申請專利範圍 0.25 至 5.〇 克。 1 1 ·如申請專利範圍第1項的黏著性補強薄膜-非織物層壓 製品,其中所提及的粘合劑添加總量爲由每平方公尺 0·5 至 1.5 克。 1 2_如申請專利範圍第1項的黏著性補強薄膜-非織物層壓 製Λ,其中所提及的百分比結合面積從5百分比至35 百分比。 ’ 13·如申請專利範圍第彳項的黏著性補強薄膜_非織物層壓 製品,其中所提及的第一纖維性非織物層包含—層^ = 品。 14. β如申請專利範圍第13項的黏著性補強薄膜-非織物層 壓製品,其中所提及的第一非織物層包含一紡粘-熔喷_ 紡粘層壓製品。 、 15. 如申請專利範圍第13項的黏著性補強薄膜-非織物層 壓製品,其中所提及的第一非織物層包含一紡粘_熔喷 層壓製品。 〃 經濟部智慧財產局員工消費合作社印製 16. 請專利範圍第彳項的黏著性補強薄膜_非織物層壓 製印,進一步包含一具有一表面的第二纖維性非織物 層,其中前述的第二纖維性非織物層被粘合至相對於前 述薄膜層第一纖維性非織物層的第二表面上。 17·如申請專利範圍第1項的黏著性補強薄膜-非織物層壓 製品,其中所提及的第—聚烯烴聚合物包含一優勢=線 性聚烯烴聚合物。 。 18.如申請專利範目帛17 ,員的黏著性補強薄膜_非織物 513344 A8 B8 C8 D8 t、申請專利範圍 壓製品,其中所提及的優勢線性聚烯烴聚合物包含線性 低密度聚乙烯。 1 9. 一種吸收性物件,其包含: 一襯墊; 一背板; 一被置放在前述襯墊與背板之間的吸收芯; 前述的背板包含申請專利範圍第1項的此黏著性補多 薄膜-非織物層壓製品。 20. 一種衣服的物件,其包含申請專利範圍第1項的黏著 性補強薄膜-非織物層壓製品。 2 1 . —種外科手術用垂幔,其包含申請專利範圍第1項的 黏著性補強薄膜-非織物層壓製品。 22. —種滅菌的包裹,其包含申請專利範圍第1項的黏著 性補強薄膜-非織物層壓製品。 (請先閱讀背面之注意事填寫本頁) 丨裳 -----訂---------- 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐)----------- Install -------- Order --------- · (Please read the phonetic on the back? Matters before filling out this page) Ministry of Economic Affairs The printed sheet strength of the Intellectual Property Bureau employee consumer cooperative is at least 3,000 grams. 3. The adhesive reinforced film as described in the scope of the patent application (1) _Non-woven laminate, the laminate mentioned in t has an elongation at break of at least 35% in the mechanical direction. 4. The adhesive reinforced film and non-woven laminates according to item 1 of the patent application, wherein the laminates mentioned above have a water vapor transmission rate of 1,000 grams per square meter per 24 hours. For example, the adhesive reinforced film_Non-woven Laminated Product of Patent Application Scope 1, wherein the mentioned laminated product has a peel strength of 100 grams. For example, the adhesive reinforced film_non-woven laminate of the first patent application range, the laminate mentioned in the ten has a cup press load of less than 100 grams. 'As the adhesive reinforcement film of the first patent application range_non-woven laminates, the laminates mentioned above have a cross-mechanical direction: two peel strength of at least 950 grams. The adhesive reinforcing film-non-woven laminate according to item 1 of the patent application, wherein the maximum distance between the adhesive areas mentioned in the direction generally parallel to the aforementioned extending direction is 0.25 inch or less. For example, the adhesive reinforcing film-non-woven laminate according to the first patent application range, wherein the maximum distance between the adhesive areas mentioned in the direction generally parallel to the aforementioned extending direction is 0.125 or less. 10. The adhesive reinforcement film _ non-woven laminates according to item 1 of the scope of patent application, in which the total amount of the added adhesive is determined by applying the CNS A4 specification (Π〇 per square meter). X 297 public love) 5. 6. Order 8. 9. # 513344 A8 B8 C8 ___ D8 6. Apply for a patent ranging from 0.25 to 5.0 grams. 1 1 · The adhesive reinforced film-non-woven laminate according to item 1 of the patent application, wherein the total amount of the added adhesive is from 0.5 to 1.5 grams per square meter. 1 2_ The adhesive reinforcing film-non-woven laminate Λ according to item 1 of the scope of patent application, wherein the percentage bonding area mentioned is from 5% to 35%. '13. The adhesive reinforcing film according to item 范围 of the patent application_non-woven laminate, wherein the first fibrous non-woven layer mentioned includes -layer ^ = product. 14. β The adhesive reinforcing film-non-woven laminate according to item 13 of the application, wherein the first non-woven layer mentioned includes a spunbond-meltblown_spunbond laminate. 15. The adhesive reinforced film-non-woven laminate according to item 13 of the patent application, wherein the first non-woven layer mentioned above comprises a spunbond-meltblown laminate.印 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 16. The adhesive reinforcement film of item 彳 of the patent is required to be embossed with a non-woven layer, and further includes a second fibrous non-woven layer with a surface. The two fibrous nonwoven layers are bonded to the second surface of the first fibrous nonwoven layer with respect to the aforementioned film layer. 17. The adhesive reinforced film-non-woven laminate according to item 1 of the patent application scope, wherein the first-mentioned polyolefin polymer includes an advantage = linear polyolefin polymer. . 18. According to Patent Application No. 17, Adhesive Reinforcement Films for Non-wovens 513344 A8 B8 C8 D8 t, Patent Application Scope Compressed products, where the mentioned advantageous linear polyolefin polymers include linear low density polyethylene. 1 9. An absorbent article, comprising: a pad; a back sheet; an absorbent core placed between the pad and the back sheet; the aforementioned back sheet includes the adhesive of item 1 of the patent application Sexual make up film-non-woven laminates. 20. An article of clothing comprising an adhesive reinforcing film-non-woven laminate according to item 1 of the patent application. 2 1. A drape for surgery, which comprises the adhesive reinforcing film-non-woven laminate of the first patent application. 22. A sterilized package comprising the adhesive reinforcing film-non-woven laminate of the first patent application. (Please read the cautions on the back and fill in this page first) 丨 Shang ----- Order --------- Printed by the Consumers' Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs This paper is printed in accordance with Chinese National Standards (CNS) A4 size (210 X 297 mm)
TW86109726A 1996-07-15 1997-07-10 Film-nonwoven laminate containing an adhesively-reinforced stretch-thinned film TW513344B (en)

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Cited By (2)

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TWI405660B (en) * 2009-02-24 2013-08-21 Tredegar Film Prod Corp Elastic film laminates with tapered point bonds
US11447902B2 (en) 2017-11-13 2022-09-20 Berry Global, Inc. Multi-component fibers with improved inter-component adhesion

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008044982B4 (en) * 2008-08-29 2012-12-06 W. L. Gore & Associates Gmbh Layer structure with a barrier layer, garment with such a layer structure and method for producing such a layer structure
KR101584546B1 (en) * 2009-01-06 2016-01-22 엘지전자 주식회사 Washing mahcine
SE533843C2 (en) * 2009-06-15 2011-02-08 Moelnlycke Health Care Ab Wound pad comprising a body of compressed open cell foam material
US20110146900A1 (en) * 2009-12-18 2011-06-23 Marcille Faye Ruman Manufacture And Assembly Of Absorbent Articles With Multiple Printed Components

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI405660B (en) * 2009-02-24 2013-08-21 Tredegar Film Prod Corp Elastic film laminates with tapered point bonds
US11447902B2 (en) 2017-11-13 2022-09-20 Berry Global, Inc. Multi-component fibers with improved inter-component adhesion
TWI795248B (en) * 2017-11-13 2023-03-01 美商比瑞全球股份有限公司 Nonwoven fabrics including multi-component fibers with improved inter-component adhesion and methods of forming the same

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ID17602A (en) 1998-01-15
RU2160801C2 (en) 2000-12-20
MY131797A (en) 2007-09-28
ZA975984B (en) 1998-01-30

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