TW401314B - A method for increasing the heat value of a solid fuel - Google Patents
A method for increasing the heat value of a solid fuel Download PDFInfo
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- TW401314B TW401314B TW087114010A TW87114010A TW401314B TW 401314 B TW401314 B TW 401314B TW 087114010 A TW087114010 A TW 087114010A TW 87114010 A TW87114010 A TW 87114010A TW 401314 B TW401314 B TW 401314B
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10F—DRYING OR WORKING-UP OF PEAT
- C10F5/00—Drying or de-watering peat
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D43/00—Separating particles from liquids, or liquids from solids, otherwise than by sedimentation or filtration
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B23/00—Heating arrangements
- F26B23/001—Heating arrangements using waste heat
- F26B23/007—Heating arrangements using waste heat recovered from the dried product
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/10—Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working
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Abstract
Description
經濟部中央標準局舅工消費合作社印衆 A7 B7 五、發明説明(1 ) 本發明係有關於提升固態原料的品質。 本發明雖非唯一專指但係特別有關於提升具有低熱傳 導力之固態原料的品質。 本發明更特別有關於藉從該原料中除去水份,而來提 升該固態原料的品質,其方法包括: (i) 在該原料被保持於高壓時,將其加熱至一預定高 溫;然後 (ii) 將該原料冷卻至周遭溫度。 本發明之一特殊用途係供提升碳質原料的品質,一般 如煤’以增加該碳質原料的BTU值(英國熱量單位Yinzhong A7 B7, Central Laboratories Consumers Cooperative of the Ministry of Economic Affairs 5. Description of the invention (1) The present invention relates to improving the quality of solid raw materials. The present invention, although not exclusively, refers specifically to improving the quality of solid raw materials having low thermal conductivity. The present invention is more particularly related to improving the quality of the solid raw material by removing water from the raw material, the method comprising: (i) heating the raw material to a predetermined high temperature while the raw material is maintained at a high pressure; and ( ii) Cool the material to ambient temperature. A special application of the present invention is to improve the quality of carbonaceous raw materials, such as coal, to increase the BTU value of the carbonaceous raw materials.
Koppelman之美國專利第5,290,523號案乃揭示一種同 時利用溫壓來提升煤之品質的方法。Koppelman's U.S. Patent No. 5,290,523 discloses a method for simultaneously improving the quality of coal using warm pressure.
Koppelman揭示的煤的加熱脫水,其乃在提高溫度及 麼力之狀況下來將煤加熱,導致煤中產生物理變化,俾使 該煤中之水份藉一“榨取”反應而被除去。Koppelman revealed that the heating and dehydration of coal is to heat the coal under the condition of increasing temperature and strength, resulting in physical changes in the coal, so that the water in the coal is removed by a "squeezing" reaction.
Koppelman亦揭示在該提升品質的過程中保持相當的 高壓’俾使其連帶產生的水大部份為液態而非蒸氣。Koppelman also revealed that maintaining a high pressure in the process of improving the quality, made most of the water produced by it to be liquid rather than steam.
Koppelman亦揭示供實施該提升品質方法之不同裝置 的選擇範圍。 通常’其選擇係基於在一壓力容器中來將煤加熱,該 容器包含有一倒錐狀進口,一圓筒狀本體,一錐狀出口, 及一組設在該本體内之垂直或水平佈列的熱交換管。 在一建議中,該等垂向佈列的管子及出口端乃裝滿煤 ,而以氮氣注入預定加壓的管子與該出口端。煤係被以 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) -4- I - n I-----1 I » —^1 ..... - - ..... f - ^^1 ^^1 >^1— I - - (請先閱讀背®之注意事項再填寫本页) A7 B7 五、發明説明(2 ) 來間接熱交換地加熱,該等油乃被當作熱交換流體而被送 入管子外部的圓筒狀本想中。進一步的加熱係藉在煤與該 容裝部内當作操作流體的蒸汽之間直接地熱交換來加強。 此外,該等蒸汽會將管子與出口端加壓至一所須壓力。 在該等管子與出口端之提升溫壓狀態的組合,乃會從 煤蒸發一些水份,並於嗣後凝結一些水份成液體。在水份 增加之後所產生的一部份水蒸汽,亦會由於高壓而在管子 之冷卻區域凝結成液體。未凝結的蒸汽,及超過該容器部 所需最適當之加壓蒸汽,皆必須被排除。此外,非可凝的 氣體(如一氧化碳、二氧化碳)乃被引出且必須被排除。液 體乃被周期性地從該出口端排出。 最後’於一預定停留時間之後,該容器乃被降壓,而 該等已被升質的熱煤則經由出口端被卸放到一輸送帶上, 其可將煤輪送至一濕螺鑽機,當該輸送帶將煤輸送到螺旋 錐時,會有水噴灑在該等升質的熱煤上。該等煤即在螺旋 錐中更進一步地冷卻,然後則被以薄層散佈在一儲備區而 可冷卻至室溫。 本發明之一目的係在提供一種較諸Koppelman所述者 更改良的提升煤之品質的方法及裝置。 依據本發明之第一概念,乃在提供一種提升固態原料 之品質的方法,其包括將該固態原料加熱至一高溫以除去 水份再冷卻該升質的固態原料;而該方法之特徵在於: (i)提供多數含有該等固態原料之容裝部的容器,及 一個或一個以上的熱交換迴路,俾以一熱交換流體藉熱交 --------裝------Γ訂J------沐 - - (請先聞讀背面乏注意事項再填寫本頁)Koppelman also revealed the range of options available for implementing this quality improvement method. Usually, the choice is based on heating the coal in a pressure vessel, which contains an inverted cone-shaped inlet, a cylindrical body, a cone-shaped outlet, and a set of vertically or horizontally arranged in the body. Heat exchange tube. In a proposal, the vertically arranged pipes and the outlet end are filled with coal, and a predetermined pressurized pipe and the outlet end are injected with nitrogen. The coal measure is applied to the Chinese National Standard (CNS) A4 specification (210X 297 mm) at this paper scale. -4- I-n I ----- 1 I »— ^ 1 .....--... .. f-^^ 1 ^^ 1 > ^ 1— I--(Please read the notes of Back® before filling out this page) A7 B7 V. Description of the invention (2) Heating by indirect heat exchange, etc. The oil was sent to the outside of the tube as a heat exchange fluid. Further heating is enhanced by direct heat exchange between the coal and the steam used as the operating fluid in the container. In addition, the steam will pressurize the pipe and the outlet end to the required pressure. The combination of elevated temperature and pressure in these pipes and the outlet end will evaporate some water from the coal and condense some water into a liquid after being simmered. A portion of the water vapour generated after the water has increased will also condense into liquid in the cooling area of the tube due to the high pressure. Uncondensed steam and pressurized steam that exceeds the most appropriate pressure required for this container section must be excluded. In addition, non-condensable gases (such as carbon monoxide, carbon dioxide) are extracted and must be eliminated. The liquid is periodically discharged from the outlet end. Finally, after a predetermined dwell time, the container is depressurized, and the upgraded hot coal is discharged to a conveyor belt via the outlet end, which can send the coal wheel to a wet auger When the conveyor belt conveys coal to the spiral cone, water will be sprayed on the upgraded hot coal. The coal is cooled further in the spiral cone and then spread in a thin layer in a reserve area to cool to room temperature. An object of the present invention is to provide a method and an apparatus for improving the quality of coal which are more improved than those described by Koppelman. According to a first concept of the present invention, a method for improving the quality of a solid raw material is provided, which comprises heating the solid raw material to a high temperature to remove water and then cooling the upgraded solid raw material; and the method is characterized by: (i) Provide a large number of containers containing the solid-state raw materials and one or more heat exchange circuits, and use a heat exchange fluid to carry out heat transfer ---------------- -ΓOrder J ------ Mu--(Please read the lack of attention on the back before filling in this page)
五、發明説明( 3 換來使在該等在容器之容 及V. Description of the invention (3 in exchange for the contents of the container and
的固態原料加熱與冷卻 (11)衩制琢万法使其在第Heating and cooling of solid materials (11)
•n^· 〇w I 加熱循環之一個或多個階段’而在第二容器組中的固態肩 料則處於冷卻循環之一個或多個階段,且該等控制步驟告 括選擇性地連接一個或一個以上的熱交換迴路於該等容累 ,而使熱傳導能從在第一組中之至少一容器内正進行冷奋 循環的固態原料回收熱量,並將所回收的熱量傳送給在舞 一組中之至少一容器内正進行加熱循環的固態原料。 本發明之上述概念的基礎係:從在一 器中正被4 卻的固態原料中回收熱能,而再將該等熱;加熱在 一組容器中的固態原料。 於本發明之一實施例中,設有許多的熱交換迴路, 該等熱交換迴路乃選擇性地連接多對的容器,而使在各 交換迴路中之傳熱流體能冷卻在各對容器之一容器内的丨 態原料,並藉與在各對容器内之固態原料熱交換,而傳, 給在該對容器之另一容器内的固態原料。 經濟部中央標準局員工消費合作社印 在各熱交換迴路中的傳熱流趙,會在加熱與冷卻循i, 中對在各對合器内的固態原料加熱與冷卻至個別不同的公 度,而使在各容器内的固態原料可藉後來將該等熱交換驾 路連接於該谷器之—連串步驟來加熱或冷卻。 例如’-熱交換迴路將-容器内的固態原料從室温永 膝至-溫度Tl’而後來連接於該容器之另一熱交換迴路乃 將“固態原料從溫度Tl加熱至一更高的溫度τ2。同時,該 A4規格(2丨0x297^^7" 本紙張尺度適用中國 -6 經濟部中央標準局員工消費合作社印裝 401314 A7 ---"—' 五、發明説明(4 ) ----- 熱交換迴路將另一容 中的固態原料從該加熱循環的最高 溫度冷卻至一較低溫度。 最好在加熱與冷卻循環時,該容器之内容物係在高壓 狀態。 S在加及冷卻循環時,固態原料皆可被存納於同一 容器内。 或者,固態原料可在加熱循環時被置於-容器中,以 將熱傳給另-容器,而在其它容器中依照冷卻循環被冷卻 〇 該等熱交換迴路係以間接式熱交換來加熱與冷卻固態 原料為佳。 本發明的方法就可被施加於該固態原料之加熱與冷卻 循環有很大的彈性,當利用從該固態原料所回收之熱量而 得到效益時即在進行冷卻循環,當對固態原料加熱即在進 疗加熱循環。 舉例而言,該方法可被用來提升一固態原料,例如煤 的~質,其乃結合溫度及壓力的應用而以二階段將水份從 煤中除去,即: (1)在第一個“溼”的階段,水份係從煤中被“榨” 出並以液態排至該容器之較低部份;及 (ii)在第二個“乾”的階段’留存在煤中之絕大部份 的水份係被以氣態排除。 傳熱流體可為任何能以間接熱交換來傳導熱能的適當 流體。 本纸張尺度_中關家縣(CNS )八4祕(21GX 297公石 -7- 裝 ---------打------線 (請先閱讀背i之注意事項再填寫本頁) A7 ---—___B7 五、發明説明(5 ) ~ 舉例而言,該傳熱流體可為一種諸如油的流體,其在 加熱與冷卻循環之操作温度範圍内只有單一相態。 再舉例而言’該傳熱流鱧亦可為一種諸如水的流體, 其在加熱與冷卻循環之操作溫度範圍内,及在適當壓力下 ’係成為液態與氣態。 該方法可包含一種或多種額外的加熱階段以完成該加 熱循環。 該等額外的加熱階段乃可藉任何適當的手段來提供, 例如供應含氧氣體至該等容器而在容器内行氧化作用地加 熱0 該等額外的冷卻階段亦可藉任何適當的手段來提供, 例如在同樣或其它容器内直接使煤接觸乾的或溼的空氣。 最好是該方法更包含供應操作流體至該等容器中,而 與該固態原料直接熱交換來使其加熱或冷卻,並助益該等 容器内容物之加壓。 依據本發明之第一概念,乃在提供一種提升固態原料 5ζ 品質的裝置,其包含有: (a) 多數的容器可容納數個在溫壓提升狀態下的固態 — 經濟部中央標準局員工消費合作社印製 •餐: (請先閱讀背面之注意事項再填寫本頁) 原料容裝部; (b) —個或多個熱交換迴路,可藉傳熱流體以熱交換 來加熱及冷卻在該等容裝部中的固態原料; (c) 連接該各熱交換迴路至容器的裝置,可使在一組 容器内之固態原料能被該傳熱流體按照一預定的加熱循環 來加熱,而在另一組容器内之固態原料可被該傳熱流體按 -8 - 本紙張尺度適用中國國家標準(CNS ) Α4規格(210x297^T7 經濟部中央標準局員工消費合作社印裝 A7 B7 五、發明説明(6) 照一預定的冷卻循環來冷卻,且所使用的或各該熱交換迴 路係連接於容器,而使各熱交換迴路可從至少一容器内之 固態原料除去熱能,並將所獲取之熱能傳導給在至少另一 容器内的固態原料;及 (d)在該等熱交換迴路與容器間選擇性地改變其連接 的裝置,可依據該等加熱及冷卻循環而加熱與冷卻在各容 器内的固態原料。 該熱交換迴路係可為任何適當的構造。 最好該熱交換迴路包含有: (i) 設在該等容器中之熱交換總成;及 (11)可使傳熱流體在該等容器中之熱交換總成内部及 其相互之間循環迴流的裝置。 尤其最好是該各容器之熱交換總成包含有: (0 一熱交換板組件具有一或多個設在該容器内的傳 熱流體之通道; (ii) 一入口可供應傳熱流體至該等通道;及 (iii) 一出口可從該等通道排出傳熱流體。 最好該等熱交換板具有最小的熱質。 最好在該等熱交換迴路與容器之間作選擇性地改變其 連接之裝置乃包含一適當的控制裝置。 依據本發明之一第二概念,乃在提供一種提升固態原 料品質的方法,其包含有: (1)將固態原料填入一容器中,並在該容器内形成一 固態原料容裝部; 本紙張尺度適用中國國家標準(CNS ) Λ4規格(210X297公Ϊ7 -9- ^^1 —^^1 ^^^1 ^^^1 1^1 f —^n ^^^1 ml m* ^^4 ^^^1 ^^^1 i maf I u? , - /-口·" (請先閱讀背面之注意事項再填寫本頁) ~ A7 B7 經濟部中央標準局員工消費合作社印製 401314 五、發明説明(7 (11)將該固態原料加熱並加壓以除去其水份,該加熱 步驟包含利用傳熱流體以間接熱交換來加熱該固態原料; (iii) 在加壓下將該固態原料冷卻;及 (iv) 卸出已被冷卻的升質之固態原料。 本發明之别述第二概念的基礎係形成一多功能的容器 ,其可承裝填入該固態原料,然後將該固態原料納存於一 容裝部中而歷經所有的加熱與冷卻循環。 本發明之上述方法與裝置有一可觀的優點係:使用多 功能容器,對熱固態原料之材料處理,相較於K〇ppei刪 所須者乃可減至最少。 另一優點係該等多功能容器乃已將卸空、裝填、增壓 、降壓等所用的循環時間’相較於KGppel_所須者減至 最少。 最好是其加熱步驟更包含用一操作流體以直接熱交 來對該固態原料加熱。 本發明之回收熱能的第—概念,乃可以使用或者不 用本發明之第二概念的多功能容器來完成。 同樣地,本發明之第二概念的多功能容器,亦可使 或者不使用本發明回收熱能的第一概念。 在本發明第—概念之—實施财,有五個含有煤之 裝部的容nA、B、c、D、E,其係在—藉除去煤之水 以提升其品質之方法中,處於加熱與冷卻循環中的不同 段及高壓下。該方法之加熱循環乃包含: ⑴在該方法之第- “涯”階段中,傳熱給煤而使:• n ^ · 〇w I one or more stages of the heating cycle 'while the solid shoulder material in the second container group is in one or more stages of the cooling cycle, and the control steps include selectively connecting one Or more than one heat exchange circuit in such capacity, so that the heat conduction energy can recover heat from the solid raw materials that are undergoing a cold cycle in at least one container in the first group, and transfer the recovered heat to Mai Mai At least one of the containers in the group is a solid raw material undergoing a heating cycle. The above-mentioned concept of the present invention is based on recovering thermal energy from the solid raw materials that are being depleted in one container, and then heating the same, and heating the solid raw materials in a group of containers. In one embodiment of the present invention, a plurality of heat exchange circuits are provided. The heat exchange circuits are selectively connected to a plurality of pairs of containers, so that the heat transfer fluid in each exchange circuit can be cooled in each pair of containers. The raw materials in one container are transferred to the solid raw materials in the other container of the pair of containers by heat exchange with the solid raw materials in each pair of containers. The heat transfer currents printed in each heat exchange circuit by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs will heat and cool the solid materials in each coupler to different degrees in the heating and cooling cycle i. And the solid raw materials in each container can be heated or cooled by connecting the heat-exchange driving circuit to the valley device in a series of steps. For example, the '-heat exchange circuit changes the solid raw material in the container from room temperature to -temperature Tl' and another heat exchange circuit connected to the container later heats the "solid material from temperature Tl to a higher temperature τ2 . At the same time, the A4 specification (2 丨 0x297 ^^ 7 " This paper size applies to China-6 Ministry of Economic Affairs Central Standards Bureau employee consumer cooperative printed 401314 A7 --- "-'V. Description of the invention (4) --- -The heat exchange circuit cools the solid materials in the other volume from the highest temperature of the heating cycle to a lower temperature. It is best to keep the contents of the container under high pressure during the heating and cooling cycles. During the cooling cycle, the solid materials can be stored in the same container. Alternatively, the solid materials can be placed in a-container during the heating cycle to transfer heat to another-container, and in other containers are cooled according to the cooling cycle Cooling 〇 These heat exchange circuits preferably heat and cool solid materials by indirect heat exchange. The method of the present invention can be applied to the heating and cooling cycles of the solid materials with great flexibility. When the heat recovered by the material is beneficial, the cooling cycle is performed, and the solid material is heated during the treatment heating cycle. For example, this method can be used to improve the quality of a solid material, such as coal. Combined with the application of temperature and pressure, the water is removed from the coal in two stages, namely: (1) In the first "wet" stage, the water is "squeezed out" from the coal and discharged to the liquid in a liquid state. The lower part of the vessel; and (ii) during the second "dry" stage, the majority of the water remaining in the coal is removed in the gaseous state. The heat transfer fluid can be any that can be indirectly heat exchanged A suitable fluid to conduct thermal energy. This paper scale_Zhongguanjia County (CNS) Eighty-fourth Secret (21GX 297 Gongshi-7-pack --------- hit ------ line (please Read the precautions on the back of this page before filling in this page) A7 ------- B7 V. Description of the Invention (5) ~ For example, the heat transfer fluid can be a fluid such as oil, which operates in the heating and cooling cycle There is only a single phase state in the temperature range. For another example, the heat transfer stream can also be a fluid such as water, which is heated and cooled Within the operating temperature range of the ring, and under appropriate pressure, they are 'liquid and gaseous. This method may include one or more additional heating stages to complete the heating cycle. These additional heating stages may be achieved by any suitable means. Provide, for example, supply of oxygen-containing gas to the containers and heat them in the vessel for oxidation. The additional cooling stages can also be provided by any suitable means, such as directly contacting coal in a same or other container with dry or Wet air. Preferably, the method further includes supplying an operating fluid to the containers, and directly exchanging heat with the solid raw material to heat or cool it, and to help pressurize the contents of the containers. According to the present invention The first concept is to provide a device that enhances the quality of 5ζ solid materials, which includes: (a) Most containers can hold several solids under elevated temperature and pressure-printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs • Meal: (Please read the notes on the back before filling out this page) Raw material container; (b) — One or more heat exchange circuits, which can be borrowed by heat transfer flow The solid materials in the container are heated and cooled by heat exchange; (c) The device connecting the heat exchange circuits to the container can enable the solid materials in a group of containers to be processed by the heat transfer fluid. A predetermined heating cycle is used for heating, and the solid raw materials in another group of containers can be heated by the heat transfer fluid according to -8-This paper size applies to China National Standard (CNS) Α4 specifications (210x297 ^ T7 employees of the Central Standards Bureau of the Ministry of Economic Affairs Printed by the consumer cooperative A7 B7 V. Description of the invention (6) Cool according to a predetermined cooling cycle, and the heat exchange circuit used or connected to the container, so that each heat exchange circuit can be removed from at least one container The solid material removes thermal energy and conducts the obtained thermal energy to the solid material in at least another container; and (d) a device for selectively changing the connection between the heat exchange circuit and the container, which can be based on the heating And cooling cycle to heat and cool the solid raw materials in each container. The heat exchange circuit may be of any suitable construction. Preferably, the heat exchange circuit includes: (i) heat exchange assemblies provided in the containers; and (11) a heat transfer fluid that can circulate inside and between the heat exchange assemblies in the containers Backflow device. It is particularly preferred that the heat exchange assembly of each container includes: (0 a heat exchange plate assembly having one or more channels for heat transfer fluid provided in the container; (ii) an inlet for supplying the heat transfer fluid to The channels; and (iii) an outlet can discharge the heat transfer fluid from the channels. It is preferred that the heat exchange plates have minimal thermal mass. It is desirable to selectively change between the heat exchange circuits and the container. The connected device includes an appropriate control device. According to a second concept of the present invention, a method for improving the quality of solid materials is provided, which includes: (1) filling solid materials in a container, and A solid raw material container is formed in the container; the paper size is in accordance with the Chinese National Standard (CNS) Λ4 specification (210X297) 7 -9- ^^ 1 — ^^ 1 ^^^ 1 ^^^ 1 1 ^ 1 f — ^ n ^^^ 1 ml m * ^^ 4 ^^^ 1 ^^^ 1 i maf I u?,-/-口 · " (Please read the notes on the back before filling this page) ~ A7 B7 Economy Printed by the Ministry of Standards and Staff ’s Consumer Cooperative 401314 V. Description of the invention (7 (11) The solid raw material is heated and pressurized to remove its water. The steps include heating the solid raw material by indirect heat exchange with a heat transfer fluid; (iii) cooling the solid raw material under pressure; and (iv) discharging the cooled solidified solid raw material. The basis of the second concept is to form a multifunctional container that can be filled with the solid raw material, and then store the solid raw material in a container and go through all heating and cooling cycles. The above method of the present invention There is a considerable advantage with the device: the use of multi-functional containers, the processing of hot solid raw materials, compared to Köppei, the need can be reduced to a minimum. Another advantage is that these multi-functional containers have been unloaded The cycle time 'for emptying, filling, pressurizing, depressurizing, etc.' is reduced to a minimum compared to KGppel_. It is preferable that the heating step further comprises heating the solid raw material with a process fluid by direct heat transfer. The first concept of recovering heat energy of the present invention can be completed with or without the multifunctional container of the second concept of the present invention. Similarly, the multifunctional container of the second concept of the present invention can also be used or not. Use the first concept of recovering thermal energy in the present invention. In the first concept of the present invention, there are five capacity nA, B, c, D, and E of the loading section containing coal, which are used to remove coal water. In the method to improve its quality, it is under different stages and high pressure in the heating and cooling cycle. The heating cycle of the method includes: ⑴ In the "Ya" stage of the method, heat is transferred to the coal to:
A7 ----- B7 五、發明説明(8 ) ' 内的水份得以液態被排除;及 (ii)在該方法之第二“乾,,階段中,傳熱給煤使留存 其中之至少一部份水份以氣態被蒸發,然後將煤加熱至一 最終的產品溫度。 在各容裝部中的煤乃被傳熱流體以間接熱交換加熱然 後冷卻,該傳熱流體係被泵經後續地連接於各對容器之熱 交換迴路。該各對容器之熱交換迴路乃在各容器内包含一 熱交換板組件,其具有一或多個傳熱流體之通道,並在該 對容器中包含一裝置可使該傳熱流體流經該熱交換總成來 循環。有一對容器及熱交換迴路之設計乃示於第1圖中。 在該圖中,容器3a含有一煤的容裝部其係在一加熱循環中 ’而容器3b含有一煤的容裝部其係在一冷卻循環中。該等 容器中的熱交換板乃以標號5來示出。其熱傳導循環裝置 包括管線與泵乃以標號7及9示之。 該容器與熱交換迴路係可為任何適當型式的壓力容器 ’例如在國際專利申請案之PCT/AU98/00005 ‘‘反應器” ,PCT/AU98/00142之“處理一載料之製程容器與方法” ,PCT/AU98/00204之“液體/氣體/固體之分離,,,及 PCT/AU98/00324 ‘‘強化式熱傳導器”與澳洲暫時申請案 P08767號等所述者,係皆由本申請人所申請。在該等專 利申請案中所揭露者乃可併供本案參考。 在該等容器中之煤的加熱與冷卻,係可藉對該容器内 之谷裝部供應操作流體而更為增益。該等操作流體乃可: (1)藉著煤與該操作流體之間,及在操作流體與該熱 本紙張尺度適用中賴家標準(CNS ) A4規格(2獻297公釐)_ - --------^>--------1Τ------沐 - ί (諳先閱讀背面-之注意事項再填寫本頁j -II - 經濟部中央標準局員工消費合作社印繁 401314 A7 ------ -B7 五、發明説明(9 ) -- 交換迎路的傳熱流體之間的直接熱交換來使煤加熱或冷卻 •,及 (ϋ)增助對容器内容物的加壓。 在第1圖中操作流髏循環迴路乃以標號11示之。 *等…、父換迴路對谷器的連接係被選擇,以使傳熱流 體能從-内裝煤而正進行冷卻循環的容器回收熱能,然後 將熱能傳給另—内裝煤而正進行加熱循環的容器。A7 ----- B7 5. The water in the description of invention (8) 'is removed in liquid state; and (ii) in the second "dry," stage of the method, heat is transferred to the coal to keep at least one of them Part of the water is evaporated in the gaseous state, and the coal is heated to a final product temperature. The coal in each container is heated by a heat transfer fluid and then cooled by indirect heat exchange. The heat transfer flow system is pumped through It is subsequently connected to the heat exchange circuit of each pair of containers. The heat exchange circuit of each pair of containers includes a heat exchange plate assembly in each container, which has one or more channels for heat transfer fluid, and is in the pair of containers. Contains a device that allows the heat transfer fluid to circulate through the heat exchange assembly. The design of a pair of containers and heat exchange circuits is shown in Figure 1. In this figure, the container 3a contains a coal container. It is connected to a heating cycle 'and the container 3b contains a coal containing portion which is connected to a cooling cycle. The heat exchange plates in these containers are shown with reference numeral 5. Its heat conduction cycle device includes pipelines and pumps It is indicated by reference numerals 7 and 9. The container and the heat exchange circuit are For any suitable type of pressure vessel 'for example in the international patent application PCT / AU98 / 00005 "Reactor", PCT / AU98 / 00142 "Process Containers and Methods for Processing a Carrier", PCT / AU98 / 00204 "Liquid / Gas / Solid Separation," and PCT / AU98 / 00324 "Enhanced Thermal Conductor" and Australian Provisional Application No. P08767 are all applied by the applicant. Those disclosed in these patent applications are available for reference in this case. The heating and cooling of coal in these containers can be further enhanced by supplying operating fluid to the grain filling section in the container. These operating fluids are: (1) between coal and the operating fluid, and in the application of the operating fluid and the thermal paper size in the CNS A4 specification (2 297 mm) _-- ------- ^ > -------- 1Τ ------ Mu- ί (谙 Please read the precautions on the back-before filling out this page j -II-Central Bureau of Standards, Ministry of Economic Affairs Employee Consumer Cooperatives Co., Ltd. 401314 A7 ------ -B7 V. Description of the invention (9)-Direct heat exchange between the heat transfer fluids on the way to exchange coal for heating or cooling •, and (ϋ) increase It helps pressurize the contents of the container. The operation of the cross flow circuit in Figure 1 is shown by the number 11. * etc ..., the connection system of the parent circuit to the valley device is selected so that the heat transfer fluid can be changed from- The container that is filled with coal and is undergoing a cooling cycle recovers heat energy, and then the heat energy is transferred to another container that is filled with coal and is undergoing a heating cycle.
一序列單一熱交換迴路連接於各對容器A、B、C、D 、E之例子係示於第2圖1此乃為_單段式熱能回收循 環之例子。 第2圖係表示’當容器A含有—煤之容器部在37it^ 最終所需之產品溫度,而容器D含有一煤之容裝部在25^ 的室溫,以熱交換迴路連接容器A與D乃會導致: ⑴使容器A中之煤從37TC冷卻至23(rC ;及 (11)將谷器D中之煤藉著從容器a中回收的熱能以間 接熱交換從25。(:加熱至185。(:。 上述容器A與D之容裝部的導熱連接,乃使各容裝部 接近一共同的接近溫度,此係決定於相對的熱含量及任何 的熱量損失。 第2圓亦示出對容器A#D後續提供的額外冷卻及加熱 ’分別導致; (i)使容器A中之煤從230°C更加冷卻至室溫;及 (π)使容器D中之煤進一步加熱至371〇c的最後所需 產品溫度。 本紙張尺度適用中國國家標準(CNS) A4規格(2丨Gx297公 Ί ;; '訂 ^ (請先閲讀背面之注意事項再填寫本買) 』 -12- 經濟部中央標準局員工消費合作社印製An example of a series of single heat exchange circuits connected to each pair of containers A, B, C, D, E is shown in Fig. 2 This is an example of a single-stage heat recovery cycle. The second figure shows' when container A contains-the container part of coal is at 37it ^ the final product temperature required, and container D contains a coal containing part at a room temperature of 25 ^, and the container A and the container are connected by a heat exchange circuit. D will cause: (1) to cool the coal in container A from 37TC to 23 (rC; and (11) to indirectly heat exchange the coal in grain container D from 25 through the heat energy recovered from container a. (: Heating To 185. (: The heat-conducting connection of the containing parts of the containers A and D mentioned above makes each containing part close to a common approach temperature, which is determined by the relative heat content and any heat loss. The second circle is also It is shown that the subsequent additional cooling and heating provided to container A # D 'cause respectively; (i) the coal in container A is further cooled from 230 ° C to room temperature; and (π) the coal in container D is further heated to The final required product temperature of 371〇c. This paper size is applicable to China National Standard (CNS) A4 specifications (2 丨 Gx297); 'Order ^ (Please read the precautions on the back before filling in this purchase) ”-12- Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs
A7 _____B7五、發明説明(10 ) — 該等額外的冷卻及加熱乃可由一冷凍器及一煮沸器或 任何其它適當的裝置來提供。 由以上說明及第2圖乃可很容易瞭解,將加熱與冷卻 容器A與D中的煤之熱交換迴路,配合第2圖的部份圖表所 示的順序,選擇性地連接於其它各對容器A、B、c、D、 E,並如前述對容器A與D般地選擇性提供對容器之額外加 熱及冷卻,乃會使在該等容器中的煤同樣地加熱及冷卻。 對前述之方法與裝置乃有許多變化彳被實施用以提升 固態原料的品質,但仍不超出本發明之精神及範圍。 舉例而。本發明之第一概念並非僅限於有關第1圖 所示之五個反應器的單段式熱能回收循環。舉例而言該 等一概念乃延伸至二段式熱能回收循環,及在三個容器中 的額外加熱與冷卻。以此設計,其加熱與冷卻階段係以相 反時間來安排,且其有二個接近溫度,典型為24〇<)(::與15〇 C。更詳而言之,該二段式熱能回收循環係如下。有一熱 容器A其係剛完成一加熱循環乃被連接於一較冷的容器B 而傳導熱能,其會在加熱的第二階段使容器B加熱。當達 到度之較高者,容器A乃連接至一冷的容器C而 傳導其會在加熱的第—階段使容器c加熱。最後, 當達到較低的接近溫度,容器A乃連接一冷凍器以使其内 的煤完全冷卻並送出最後的冷煤。容器6則在第二加熱階 段被加熱至—較高的接近溫度,再連接於一蒸汽供應迴路 而使其内的煤完成加熱循環。應可很容易瞭解,此等具有 新穎的煤之容裝部的容器,其加熱與冷卻之順序係可重 本紙張尺度適用中 (請先閲讀背面-之注意事項再填寫本頁) 丨 裝--Γ—__.L丨訂---- ----\-------:-- I— In ·A7 _____B7 V. Description of the Invention (10)-The additional cooling and heating may be provided by a freezer and a boiler or any other suitable device. From the above description and the second figure, it is easy to understand that the heat exchange circuit of the coal in the heating and cooling vessels A and D is selectively connected to the other pairs in accordance with the sequence shown in the partial diagram of the second figure. Containers A, B, c, D, E, and optionally providing additional heating and cooling of the containers as previously described for containers A and D, will cause the coal in these containers to be heated and cooled equally. There are many changes to the aforementioned methods and devices, which are implemented to improve the quality of solid materials, but still do not exceed the spirit and scope of the present invention. For example. The first concept of the present invention is not limited to the single-stage heat recovery cycle of the five reactors shown in FIG. This concept extends, for example, to a two-stage heat recovery cycle and additional heating and cooling in three vessels. With this design, the heating and cooling phases are arranged at opposite times, and it has two approximate temperatures, typically 24 ° <) (:: and 15 ° C. More specifically, the two-stage thermal energy The recycling cycle is as follows. There is a hot container A which is just connected to a colder container B to conduct heat just after completing a heating cycle. It will heat the container B in the second stage of heating. When the higher degree is reached Vessel A is connected to a cold vessel C and conducting it will heat vessel c in the first stage of heating. Finally, when a lower approach temperature is reached, vessel A is connected to a freezer to make the coal in it completely. Cool and send the final cold coal. The container 6 is heated to a higher approach temperature in the second heating stage, and then connected to a steam supply circuit to complete the heating cycle of the coal inside it. It should be easy to understand that this For containers with a novel coal container, the order of heating and cooling can be re-applied in the paper size (please read the precautions on the back-then fill out this page) 丨 Packing --Γ —__. L 丨Order ---- ---- \ -------:-I— In ·
*I - II A7 B7 提高 五、發明説明(11) 的。 圖式簡要說明 第1圖係為依據本發明之第一個方面^^種用以提高 固態物料之品質的裝置之一具體例的示意圖f 第2圖例示依據本發明之第一個方面的 固態物料之品質的方法之一具體例。 元件標號對照 3a...容器 3b...容器 5...熱交換板 7…管線 9".泵 11…操作流體循環迴路 ----------襄 — (請先聞讀背面之注意事Is再填寫本頁) 經沪部中决榀^而以工消費合作衫印繁 本紙張尺度賴中_家縣(⑽)M規格(2似297公隹) -14、* I-II A7 B7 increase 5. Description of invention (11). BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic diagram of a specific example of a device for improving the quality of solid materials according to the first aspect of the present invention f FIG. 2 illustrates a solid state according to the first aspect of the present invention A specific example of the method of material quality. Comparison of component numbers 3a ... container 3b ... container 5 ... heat exchange plate 7 ... line 9 " .pump 11 ... operating fluid circulation circuit ---------- Xiang— (please read and read first Note on the back is to fill in this page again.) The Ministry of Shanghai has decided to print the complicated paper with the industrial and consumer cooperation shirts. The paper size depends on _Jiaxian (⑽) M size (2 like 297 kilometers) -14,
Claims (1)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AUPO8766A AUPO876697A0 (en) | 1997-08-25 | 1997-08-25 | A method and an apparatus for upgrading a solid material |
Publications (1)
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TW401314B true TW401314B (en) | 2000-08-11 |
Family
ID=3803052
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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TW087114010A TW401314B (en) | 1997-08-25 | 1998-08-25 | A method for increasing the heat value of a solid fuel |
Country Status (16)
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JP (1) | JP2001513431A (en) |
KR (1) | KR20010023326A (en) |
CN (1) | CN1094777C (en) |
AU (1) | AUPO876697A0 (en) |
CA (1) | CA2301768C (en) |
CO (1) | CO5040163A1 (en) |
CZ (1) | CZ301172B6 (en) |
GE (1) | GEP20032917B (en) |
HU (1) | HU224249B1 (en) |
PL (1) | PL338809A1 (en) |
SK (1) | SK2152000A3 (en) |
TR (1) | TR200000518T2 (en) |
TW (1) | TW401314B (en) |
UA (1) | UA50845C2 (en) |
WO (1) | WO1999010079A1 (en) |
ZA (1) | ZA987735B (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
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AUPO876797A0 (en) * | 1997-08-25 | 1997-09-18 | Technological Resources Pty Limited | Heating with steam |
AU2001293486B2 (en) | 2000-09-26 | 2006-11-09 | Evergreen Energy Inc. | Upgrading solid material |
CN100342364C (en) * | 2003-03-05 | 2007-10-10 | 广达电脑股份有限公司 | Transmission device for remote display of computer screen |
DE10332564A1 (en) | 2003-07-11 | 2005-01-27 | Celon Ag Medical Instruments | Surgical device for coagulation or ablation of tissue, comprising hollow shaft accommodating cooling duct and two ring-shaped electrodes |
US8021445B2 (en) * | 2008-07-09 | 2011-09-20 | Skye Energy Holdings, Inc. | Upgrading carbonaceous materials |
Family Cites Families (4)
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US4477257A (en) * | 1982-12-13 | 1984-10-16 | K-Fuel/Koppelman Patent Licensing Trust | Apparatus and process for thermal treatment of organic carbonaceous materials |
US4733478A (en) * | 1985-10-07 | 1988-03-29 | Kawasaki Jukogyo Kabushiki Kaisha | Method of dewatering brown coal |
US5290523A (en) * | 1992-03-13 | 1994-03-01 | Edward Koppelman | Method and apparatus for upgrading carbonaceous fuel |
AUPO663297A0 (en) * | 1997-05-07 | 1997-05-29 | Technological Resources Pty Limited | Enhanced heat transfer |
-
1997
- 1997-08-25 AU AUPO8766A patent/AUPO876697A0/en not_active Abandoned
-
1998
- 1998-08-25 WO PCT/AU1998/000689 patent/WO1999010079A1/en not_active Application Discontinuation
- 1998-08-25 TR TR2000/00518T patent/TR200000518T2/en unknown
- 1998-08-25 UA UA2000021105A patent/UA50845C2/en unknown
- 1998-08-25 CZ CZ20000457A patent/CZ301172B6/en not_active IP Right Cessation
- 1998-08-25 CA CA002301768A patent/CA2301768C/en not_active Expired - Fee Related
- 1998-08-25 ZA ZA987735A patent/ZA987735B/en unknown
- 1998-08-25 HU HU0002762A patent/HU224249B1/en not_active IP Right Cessation
- 1998-08-25 CO CO98048483A patent/CO5040163A1/en unknown
- 1998-08-25 GE GEAP19985275A patent/GEP20032917B/en unknown
- 1998-08-25 JP JP2000507456A patent/JP2001513431A/en active Pending
- 1998-08-25 PL PL98338809A patent/PL338809A1/en unknown
- 1998-08-25 SK SK215-2000A patent/SK2152000A3/en unknown
- 1998-08-25 CN CN98808426A patent/CN1094777C/en not_active Expired - Fee Related
- 1998-08-25 TW TW087114010A patent/TW401314B/en not_active IP Right Cessation
- 1998-08-25 KR KR1020007001962A patent/KR20010023326A/en not_active Application Discontinuation
Also Published As
Publication number | Publication date |
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WO1999010079A1 (en) | 1999-03-04 |
HU224249B1 (en) | 2005-07-28 |
UA50845C2 (en) | 2002-11-15 |
CN1094777C (en) | 2002-11-27 |
HUP0002762A3 (en) | 2001-02-28 |
SK2152000A3 (en) | 2000-09-12 |
CO5040163A1 (en) | 2001-05-29 |
JP2001513431A (en) | 2001-09-04 |
CZ2000457A3 (en) | 2000-09-13 |
PL338809A1 (en) | 2000-11-20 |
CZ301172B6 (en) | 2009-11-25 |
TR200000518T2 (en) | 2000-07-21 |
CA2301768A1 (en) | 1999-03-04 |
AUPO876697A0 (en) | 1997-09-18 |
HUP0002762A2 (en) | 2000-12-28 |
KR20010023326A (en) | 2001-03-26 |
GEP20032917B (en) | 2003-03-25 |
CN1268902A (en) | 2000-10-04 |
ZA987735B (en) | 1999-02-25 |
CA2301768C (en) | 2007-02-13 |
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