B 明説明發明 、 發五 城 薄 有的 偽宜 明適 發 、 本面 其表 尤般 。石 法理 製大 之或 材岩 石岡 造花 人的 種越 一 優 關有 有具 傑種 里明一 發出 本造 製 两 硬板 堅地 輕材 質壁 之為 性作 特用 的使 良 可 優供 他提 其且 及 ， 性材 耗石 磨造 耐人 面之 表度 、 密 度高 硬的 面強 表度 造 人 的 他 其 及 柱 頭 石 ' 料 材 築 木 土 、 料 材 築 薄 他 其·。 及材 材石 術 抟 前 先 及 0 酸 确 以 合 混 寸 尺 當 適 至 碎 壓 予 經 頭 石 然 天 知 已 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 樹脂，並硬化至成人造石材。例如日本特開昭61-101443 號案掲示一種製造人造石材之方法，該人造石材僳可予裁 切的組合之形式，其中原料，樹脂及其他均在減鼷下予以 混合，並頷入成型箱内，取出供裁切。 進一步，日本持公昭53-24447號公報建議使用原料至 特定的混合比之需求，且完全將原料壓入一成型箱内，由 天然石材顆粒及合成樹脂製造人造石材。 該等已知方法伴隨的問題偽所得的人造石材，即使使 用天然石材顆粒亦未具有適當的色調或色彩深度。 傳統的人造石材具有表面色澤必為不清爽或黯淡的缺 黏。利用習用方法相當難製出具有透明感，色彩深度及堅 實之花崗岩或大理石般的表面。 此乃因人造石材端視其構造及天然石材顆粒之尺度及 混合方式之不同，而使光在表面上會有相當不同的反射及 吸收特性。該等觀點在遇去並未被完全考量著。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 3 37225 A7 B7 經濟部中央標準局員工消費合作社印製 五、 發明説明（2 ) - 人 造 石 材 之 組 成 物 大 大 地 影 響 成 型 特 性 0 流 動 性 (在 1 I 成 型 上 之 — 重 要 因 子 )端視天然石材颗粒之尺度及比率與 1 1 I 樹 脂 黏 結 劑 在 人 造 石 材 内 之 混 合 比 率 之 不 同 將 會 喪 失 請 1 1 1 * 結 果 有 氣 泡 殘 留 於 最 終 製 品 内 9 使 得 人 造 石 材 (最終製 先 閲 讀 背 ft 之 1 1 I 品 )之品質及強度顯著的降低。 1 1 I 為 解 決 此 問 題 9 例 如 該 B 本 專 利 公 報 特 公 昭 53 -24447 >王 意 事 1 1 號 案 建 議 利 用 增 加 樹 脂 含 量 以 保 持 流 動 性 t 且 提 及 由 所 確 項 再 填 (· 裝 1 定 的 流 動 性 可 防 止 氣 泡 〇 寫 本 頁 雖 然 9 增 加 樹 脂 含 It 以 防 止 氣 泡 且 保 持 流 動 性 使 容 '—^ 1 | 易 嫌 入 成 型 箱 内 將 有 助 於 保 持 流 動 性 且 防 止 氣 泡 之 發 生 1 1 1 然 而 却 對 最 終 製 品 (人诰石材）之物理性質造成不 良 影 響 〇 1 1 訂 此 卽 意 指 使 用 大 量 的 樹 脂 可 得 樹 脂 狀 人 造 石 材 ， 且 其 單 單 意 指 在 最 終 製 品 内 之 樹 脂 中 存 在 有 天 然 石 材 顆 粒 0 以 1 1 物 理 性 質 而 t 最 終 製 品 傜 一 原 料 樹 脂 而 非 原 料 石 材 〇 換 1 | 之 • 人 造 石 材 僅 僳 其 名 稱 » 而 製 品 像 一 看 似 石 材 之 樹 脂 1 '银 製 m 0 1 I 由 而 期 望 使 用 天 然 石 材 或 其 他 顆 粒 作 為 原 料 能 實 現 消 1 1 除 該 等 間 題 且 使 得 可 能 製 出 具 有 緻 密 結 m 、 透 明 色 調 % 色 1 1 彩深度 花 岩 、 大 理 石 或 其 他 天 然 石 材 之 特 黏 、 優 越 的 1 1 成 型 I 及 製 成 板 材 棒 材 或 其 他 任 意 形 狀 之 形 成 性 的 人 造 1 石 材 〇 1 I g_ 明 槪 沭 1 本 發 明 傜 在 上 述 各 種 狀 況 下 被 提 出 〇 為 解 決 上 述 間 題 1 1 1 » 本 發 明 提 供 一 種 人 造 石 材 之 组 成 物 $ 包 括 : 1 1 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 4 37225 A7 B7 五、發明説明（3 ) 10至70篩目之無機黴細顙粒與100篩目及更小之無機 非常撤細顆粒之無機混合物，其缠量為最終製品之85重量 涔或以上及 樹脂，其量為最终製品總重量之15重量涔或以下， 其中該無機微細顆粒偽透明且經予將部分或全部顆粒 以锢別或以顆粒集合之單位被覆以無機或有機物質。 本發明進一步提供將上述组成物薄入或置入可成型人 造石材之成型箱内而成的人造石材成型品。 本發明更進一步提供表面經予研磨的人造石材成型品 〇 發昍：> 註細說明 以下更詳細説明本發明。 依本發明於人造石材中所用的原料可予區分成三群。 一群為主要成分，其為10至70篩目的無機微細顆粒。該等 為二氣化矽、橄欖石、長石、輝石、雲母或其他礦物、花 崗岩、變成岩或其他天然石、陶土、玻璃、金羼等之微细 顆粒。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 連同此等撖細顆粒被使用者為100篩目及以下的非常 微細的顆粒。此等為各種不同之天然或人造顆粒。非常微 細的顧粒為可自例如硪酸鈣、水及氣化鋁輕易《得。 至於部分非常微細的顆粒，可加入二氣化錳、二氧化 鈦、矽酸鉻、氣化鐵等，以調整色讕，及1或加入三氣化 銻、化合物、溴化物化合物等以使材料·變成耐燃性。 第三成分為樹脂。該樹脂可自熱固性或熱塑性樹脂之 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 5 37 2 25 A7 B7 經濟部中央標準局員工消費合作杜印製 五、 發明説明（ 4 ) - 廣 泛 範 騸 内 m 出 0 例 如 » 丙 烯 酸 条 樹 脂 » 甲 基 丙 烯 酸 % 樹 1 1 I 脂 不 飽 和 聚 酯 樹 脂 可 予 使 用 0 1 1 I 天 然 石 材 及 其 他 之 撤 細 顆 粒 為 決 定 所 製 得 的 人 造 石 材 1 I 請 1 之 外 觀 及 物 理 性 質 之 主 要 因 素 〇 尤 其 9 與 其 他 成 分 合 併 使 先 閲 1 I 1» 1 | 用 » 且 當 其 部 分 暴 露 時 9 其 可 供 作 表 面 上 色 彩 及 花 紋 之 主 背 面 1 I 之 1 要 因 素 〇 注 意 1 1 事 1 非 常 撇 細 的 顙 粒 較 撤 細 的 顆 粒 相 對 地 更 加 微 細 或 較 項 再 -1 100篩目相對地更加微細。 此等顆粒傷穿透微細的類粒間 爲 本 政 頁 1 空 除 t 並 燠 入 其 中 » 且 對 最 終 製 品 之 m 性 及 柔 軟 性 有 所 貢 1 獻 〇 微 細 顙 粒 對 非 常 微 細 顆 粒 之 重 量 fcb 以 0 . 5 ： 1至5 : 1為宜 1 ί 1 0 樹 脂 則 被 用 以 包 裹 撤 細 顆 粒 及 非 常 撤 細 顆 粒 > 以 致 其 訂 變 成 組 成 物 之 骨 幹 0 其 進 一 步 黏 結 所 有 材 料 f 並 賦 予 製 得 1 1 的 人 造 石 材 彈 性 或 抗 拉 強 度 〇 1 I 此 等 成 分 之 混 合 比 率 在 本 發 明 中 傷 重 要 的 〇 樹 脂 對 其 1 1 '球 他 成 分 之 比 率 特 別 重 要 0 本 發 明 之 待 欺 之 偽 提 供 — 種 具 1 有 组 密 構 造 之 高 密 度 製 品 0 於 此 説 明 書 中 ”高密度” JtiS. /Ον 指 徼 1 1 細 的 及 非 常 徵 細 的 顙 粒 以 高 密 度 存 在 於 人 造 石 材 最 終 製 1 1 品 中 0 典 型 的 密 度 水 準 僳 在 2 . 2g / C 3 或 以 上 ， 其 超 過 習 1 1 用 的 人 造 石 材 的 常 見 範 園 0 1 | 若 微 細 顆 粒 之 比 率 增 加 時 9 則 最 終 製 品 偽 非 常 接 近 天 1 I 然 石 材 0 然 而 9 若 撤 細 顙 粒 過 多 時 ， 則 最 終 製 品 將 不 夠 堅 1 1 I 硬 而 不 適 於 販 賣 0 該 製 品 之 物 理 性 質 較 差 9 且 該 製 品 利 用 1 1 1 一 般 應 用 方 法 時 將 不 適 用 0 1 1 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 6 37 225 A7 B7 經濟部中央標準局員工消費合作社印製 五、 發明説明（5 ) • 若 非 常 撤 細 的 m 粒 之 含 ft 過 高 時 將 會 引 起 問 題 例 1 I 如 該 材 料 將 不 會 固 化 0 此 外 最 終 製 品 将 失 去 光 澤 i 幾 乎 1 i I 不 能 稱 作 石 材 0 /-—. 1 I 請 1 I 於 是 » 在 製 品 中 之 黴 細 顆 粒 及 非 常 徹 细 顆 粒 之 fcb 率 傜 先 閲 1 I 讀 1 I 受 限 制 的 0 尤 其 > 此 比 率 必 須 為 85 重 量 % 或 以 上 9 以 9C 重 背 1 I 之 1 量 % 或 以 上 為 宜 0 若 該 比 率 超 過 95 重 量 % 時 » 則 製 品 變 脆 注 意 1 1 事 1 而 難 以 使 用 9 在 另 —- 方 面 » 若 此 fcb 率 小 於 85重 量 % 時 9 則 項 再 填 (1 最 終 製 品 過 於 柔 軟 f 而 不 具 有 石 材 之 性 質 > 且 應 用 範 園 並 寫 本 頁 1 不 較 樹 脂 板 為 佳 〇 1 I 此 邸 意 指 撤 細 及 非 常 細 的 顆 粒 以 外 之 成 分 > 或 樹 脂 成 1 [ 分 在 製 品 中 應 不 可 超 遇 15 重 量 % Ο 1 1 若 樹 脂 含 量 超 過 製 品 之 15 重 董 % 時 » 則 製 品 類 似 於 塑 訂 m 而 不 被 稱 作 石 材 0 在 另 一 方 面 % 若 樹 脂 含 悬 遇 低 時 « 1 1 則 製 品 在 表 面 上 可 m 得 天 然 色 彩 惟 将 會 變 脆 且 因 而 並 不 1 I 適 於 使 用 〇 由 此 等 觀 點 觀 之 > 樹 脂 比 率 僳 以 3重量涔至10 1 1 重 ft % 之 範 圍 内 為 宜 0 1 本 發 明 之 基 本 條 件 及 固 有 的 特 擞 為 本 發 明 之 物 質 組 成 1 1 物 及 製 品 中 之 上 述 無 機 微 細 顆 粒 應 為 部 分 或 全 部 屬 透 明 顆 1 1 粒 $ 且 該 顆 粒 或 其 小 集 合 均 預 先 以 無 機 或 有 機 物 質 被 覆 之 1 1 I 0 上 述 透 明 的 撇 細 顙 粒 可 以 樹 脂 予 以 被 覆 並 予 硬 化 0 或 1 1 者 1 如 水 玻 璃 、 陶 姿 用 釉 或 其 他 無 機 物 質 可 藉 由 烘 烤 方 式 1 1 1 使 其 黏 附 於 顆 粒 之 表 面 上 0 於 任 一 情 況 下 » 透 明 的 撤 細 m 1 1 1 粒 僳 被 覆 以 厚 度 為 數 & L at 至 數 十 & L η * 例 如 5 至 5 0 /j 之 範 1 1 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 7 372 25 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（6 ) 圍内，以20至30 W η為宜之膜，尤其特別的，例如丙烯酸 糸樹脂或不飽和聚酯樹脂，僳被加熱至約15010至300它， 或利用光線照射，而予以被覆及硬化至該微細的顆粒之表 面上。亦有可能黏附水玻璃，釉等至微細顆粒之表面上， 並在800至1100^之溫度烘烤以形成無機被覆層。 此被覆層大大的改善微細顆粒對整體結構之親和力， 其像扮演人造石材之聚集作用之功能。進一步，當其完全 的混合時，強度及表面硬度會增加。 更重要的，撤細顆粒僳透明的天然石材等，且其表面 如上所述般偽以堅硬薄膜被覆之。當人造石材經予研磨時 此薄膜像部分的破裂，且部分暴露的透明撤細顆粒及画繞 著微細顆粒之部分暴露匾域之被覆層之表面共同製造出反 射光線之獨特效果。 此意指光輻射線進入透明的撤細顆粒，被周困的被覆 層所反射，且經由透明的微細顆粒射回。此光傳送及反射 之現象基本上與在習用的人造石材所觀測的表面反射傺不 同的，且賦與依本發明之人造石材獮待的色彩深度。所得 的人造石材外觀上與大理石相似，為堅實者，具有色彩深 度且颶於高品質。 上述具有被覆層之透明的微細頼粒通常可逹組成物中 所含的全部無機黴細顆粒之10至100重量〆。 於本發明中有必要特定無機撤細顆粒之尺度。尤其無 機微細顆粒之尺度應為前述的10至70篩目。除在特別情況 下外，最好僅應使用相同尺度之擻細顆粒。為區分時可使 I--------Cr 裝 I-------訂—-----^ (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 8 37 225 A7 B7 五、發明説明（7 ) 用二種尺度的顆粒，例如為在上镅或下個（上使用經著色的 顆粒，一者經予著色而另一者為無色的顆粒。在此情況下 ,使用極端不同尺度之大量顆粒將會使製品之強度變差且 因而應不予使用。 非常擻細的顆粒之尺度如上所述般應為100篩目及以 下，其必須小至足夠能完全穿透入撇細顆粒間之空隙，與 微細顆粒之尺度相近者並不適宜。為予特定，尺度應在 150至250篩目為宜。 對本發明之高密度人造石材而言，除特別情況外，確 認組成物之成分均勻的分散於製品中亦靨重要的。 以研磨製品之外表面為較宜的。換言之，撤細顙粒之 被覆層如上所述般僳在至少位於製品之表面上部分的破裂 0 研磨像曝露本發明之具有色彩深度之高密度人造石材 之组密表面之可行且易於使用的方法，當然有可能研磨製 品之部分表面，以暴露出徹細顆粒，且使用在相同表面上 之經暴露出的區域與其他區域間之差異作為製品之圈樣。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁} 於製造人造石材中，決定何種天然石材應成為色調及 設計方面之檫的傺重要的。花崗岩及大理石係受歡迎的標 的，因其稀少，難以《得且具有美麗色彩及光澤。於此種 例子，色彩及光澤在決定花崗岩及大理石之價值時傜重要 的課題。天然花崗岩及大理石具有由深黑色至白色或紅色 之各種色彩。縱使色彩相同，其程度可為不同。 在習用方法中，使用來自天然石材等之黑色粉末製造 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 9 37 225 A7 B7 經濟部中央標準局員工消費合作社印製 五、 發明説明（8 ) - 黑 色 人 造 石 材 0 此 並 非 問 題 之 原 因 所 在 但 笛 製 造 半 色 諏 1 I 製 品 時 f 其 可 再 製 性 常 為 問 題 所 在 〇 進 一 步 m 使 可 再 製 1 1 出 色 彩 » 大 理 石 光 澤 之 再 製 困 難 的 〇 /-—V 1 I 請 1 I 例 如 染 料 及 顔 料 可 被 使 用 以 産 生 色 彩 * 惟 在 習 用 方 法 先 閲 1 I 1 | 中 其 傜 較 難 以 産 生 光 澤 及 色 彩 之 深 度 0 背 1 I 之 1 於 本 發 明 中 9 % 使 用 透 明 的 撤 細 _ 粒 0 當 欲 製 造 具 有 注 意 書 1 | 光 澤 之 人 造 石 材 9 例 如 類 似 於 花 崗 岩 或 大 理 石 時 • 經 予 壓 項 再 碎 的 天 然 石 英 石 材 之 徽 細 顆 粒 可 予 使 用 〇 本 裝 頁 j 由 壓 碎 石 英 天 然 石 材 製 得 的 微 細 顆 粒 在 表 面 上 具 有 獨 1 I 待 的 光 滑 區 域 $ 此 乃 由 於 原 料 傜 石 英 所 致 $ 其 在 多 種 狀 況 1 1 下 僳 無 色 且 透 明 的 〇 當 其 經 予 著 色 時 其 色 彩 並 非 如 此 強 1 烈 〇 邸 使 其 並 非 兀 全 透 明 9 其 亦 保 持 若 干 程 度 的 透 明 度 0 訂 由 上 述 原 料 産 生 的 製 品 之 色 彩 可 由 諝 整 在 m 細 顆 粒 上 1 I 之 被 覆 層 及 樹 脂 之 色 諝 予 以 控 制 〇 進 一 步 9 該 色 彩 可 具 有 1 I 深 度 及 光 澤 0 1 1 例 如 費 當 被 覆 層 為 含 有 白 色 顔 料 之 經 烘 烤 的 水 玻 瑰 層 1 或 經 硬 化 的 聚 酯 為 主 的 不 飽 和 樹 脂 層 » 且 使 用 於 本 發 明 之 1 1 樹 脂 像 以 聚 酯 為 主 的 不 飽 和 樹 脂 時 9 則 所 得 的 製 品 具 有 光 1 1 澤 性 之 乳 白 色 彩 9 此 乃 因 為 樹 脂 之 色 彩 通 常 為 帶 黃 的 白 色 1 1 » 類 似 於 天 然 的 乳 白 色 大 理 石 0 1 I 藉 由 在 被 覆 層 中 使 用 顔 料 染 料 或 其 他 著 色 劑 3 且 進 1 1 I 一 步 藉 由 在 樹 脂 中 * 使 用 無 機 顔 料 諸 如 二 氣 化 鈦 \ 矽 酸 1 1 I 鉻 > 二 氣 化 錳 、 氣 化 嫌 、 氣 化 鈷 或 有 機 顔 料 諸 如 偶 氮 顔 1 1 料 > 酞 青 主 成 分 之 顔 料 9 或 各 種 染 料 9 有 可 能 製 造 出 具 有 1 1 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） 10 3 7 225 A7 B7 五、發明説明（9 ) ‘ 均勻色'彩及具有光澤之獨特的色調及色彩深度之人造石材 顆 細 徹 與 中 物 成 組 之 質 物 用 材 石 造 人 之 明 發 本 依 於 而 分 成 彩 色 為 。 作彩 可色 , 之 粒品 顧製 的終 色最 箸輿 經賦 之以 度 合 尺混 同以 相予 約並 大用 分使 成以 粒予 色及 成度 達深 易彩 容色 加的 更越 可優 法有 用具 習品 以製 較又 明 ， 發象 本現 由色 is , 褚 率無 比且 何 ， 任性 在製 再 彩 澤 光 製發彩泛 以本色廣 粒為 ，較 顆作時之 烤粒法彩 烘顆方色 , 狀此自 粒末用可 穎粉使彩 細此當色 微用 。的 的使效用 明 且有使 透 ，其予 然粒棰可 天顆僳 ， 至狀 ，步 釉末粒一 用粉顆進 瓷之細。 陶彩撖障 用色分保 應欲部予 所之更 出明可 天 的 主 為 英 石 以 的 碎 壓 經 之 粒 顆 細 黴 之 〇 物 擇成 選組 以為 予作 匾若 範 的 红及用 及澤習 色光為 黑在性 則亦製 , 彩再 用色可 使在彩 以僅色 予不 一 後彩此 烤色 。 烘 。出 及題製 化問再 釉有的 在沒全 料性完 _ 製予 同再可 相可均 之彩面 材色方 石之調 然色色 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 含 包 以10 傜至 粒10 顆之 細粒 撖颗 之細 層微 覆部 被全 的之 烤董 。 烘含 的已粒 成有顆 逹具細 法 ，微 無何之 絶如中 法論物 方無成 色 組 著 於 成 已 化 強 以 合 混 予 可m 短 色 的 望 希 所 〇 得 者播 用為 使及 被虛 率 比 維m 瓷 。 陶宜 、 較 維為 鑛維 瑰鐵 玻璃 如玻 例以 , 其 用尤 使 ， 能等 可維 有鐵 。 脂 造樹 構 、 之維 品纖 製屬 的金 型 、 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 11 11 37225 A7 B7 五、發明説明（10 ) 此等短纖維通常直徑為10至100« B,且長度1至10BB, 其像以全部黴细顆粒成分之1至10重量X予以混合。 經濟部中央標準局員工消費合作社印製 型 用 非但 部侧 窄分 混，亦 面時經在 成 選 並整 内 一 狹成 的積量 平少料少 予 以 箱為 模 S 的粒 動容含 此減材減 可 予 型成 型較 式顆 流内脂 •積俟積 材 中 成地 成侧 形細 且之樹 時腥者容 石。法 為然 在放 口黴 勻箱之 箱部或之 造等方 項顯 用開 開致 均型材 型内。箱 人體型。事且 使且 半以 之成石 成當出型 度柱成宜要域 好， 在式 分少造 之。湓當 密圓的適重匾 最模 能形 成減人 材除且且 高、知較一放 如型 可之 粒以型 板空 ，， 之材已作之開 例成 有狀 顆 ，成 部的口部 調棒干視法在 ，之 亦網 細内終 内間開底 色片若被方存 時緣 ，以 撤箱最 面其之之 良板自型造定 品邊 外如 常型少 平少箱箱 優含可成製必 製放 口例 非成減 有減型型 有包法缩之指。_ 開 開或 及之以 具以成成 具 ，方壓明意分柱有 之 ， 細般 ， 用緊向升 之式型 、發此部形具 。上口 。撖述性 使靠推提 明型成型本 。一 方画置端開透、上動 當互被被 發品的縳依者之型周位頂一穿脂如流 ，相分 ，。 本製關以醑閉域成之高 了成以樹入持 C 如予成後面 依何相如.有封匾當材較除形難將倒保效例可脂型表 任 例 經面 板於 上較 物時有 材樹鑄料 成 。 己表 之位 _ 將 合同為 板 ，予材 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 12 37 225 經濟部中央標準局員工消費合作社印製 的迅結之人此少 接微且 加 賦流 具程 細 之 大而集積的因為 的之 ， ρ 被之 品過 撖«; 較異並容化且者 低量具40力物 製造 使 含 有差出内固，時 。較用模?psl壓合 單製 至 脂 具著擠知已少型 法為需上 ο 著混 簡在 工 樹 脂顯推已。為鑄 方作所上 随料 當會 加 除 樹有被用度者在 造用段配 伴材 相料 步 去 較上會使程料料 製使階後 Μ 可述 之材 一 的 分重脂需的材材 的被型其 動上 類量 進 性 成比樹僅制的較 用像成。cn^ 振之 品少 予 擇 粒因質，控入至 有箱成物f/，内 製常 可 苗 顆，輕脂經充董 種型完合kgu 中箱 型非 面 可 細時，樹至所含 一成在混00型型 成僅。表 種 擻箱時的箱較脂 另平有之gl曾 成成 面因的之 一 常型少量型僳樹 之水具脂 縮在 平，濟品 像 非成減定成量之 明，各樹為^； 壓善 如果經製 先 及一稹待縮含品 發中入與力+ 述改 諸效供型。首 細入容除壓脂製 本法鏞粒壓£0上以 對産亦成上含 —微鑄内去後樹終 為型中顆面 ί 之， 法生法，面包 1 1 ,被當為其终最 型成其細表 下上 型量方明表法 W 的其。。且最少 成縮於微用 熱箱 成大此發於方 # 然當降處，之減 縮鼷，常利 As 加型 縮的，本露關 # 顯。沈 口箱材.能 壓於具非物出g2在成。壓越失於暴相 ^ 重的開型石可 棋及合製 5 至性 優漏 粒 、 比速於成造有 C 收細混以熱 與動 有中 顆 五 ---------；-裝1--'---訂-τ-----線 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 13 3 7 225 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（12 ) 方法，例如俟成型製品自成型箱取出後利用噴射高Μ水至 成型製品之表面上，以加工表面即為有效。 此加工方法不可用受限制的方式予以說明，因該方法 之成功使用端視厚度，離噴嘴之距離，加工形狀及其他各 種條件而定，然而通常為2至20公分範圍之厚度，水® 50 至800kg/ce2僳被使用於約2至10公分高之噴嘴上。水壓偽 較加工天然石材時所用者為低。 此意指高级加工供因樹脂成分之存在而較容易連成。 用噴射高壓水之噴嘴及其条統並未予特別限制。多種 裝置為已知且可用的。 此表面加工利用噴射水刀裝置産生光滑或粗糙表面， 而能製出具有堅實及深度之人造石材。 表面不致變成雲霧狀或黯淡狀，此乃由於樹脂存在所 致，且廢棄溶液之拋棄則較化學蝕刻步驟更容易處理。 視必要時，亦有可能使用有機溶劑處理表面以軟化或 熔解部分去除之樹脂。 於此種情形，所用的有機溶劑像基於欲予去除的樹脂 成分之考量予以選用。有機溶薄I,例如可為二氰乙烷、二 氯甲烷、三氣甲烷或其他鹵化烴、醑酸酐、醋酸乙酯、醋 酸丁酯或其他羧酸或其酯化合物、丙酮、四氫呋喃、二甲 基甲醛胺、二甲基亞‘》等。 成型製品傜被浸漬入該等溶劑之一種内，或該等溶薄 之一種偽被噴佈或被滴沾在成型製品上以軟化或熔解使樹 脂自表面去以使表面變成不平坦。 ---------1 :-裝 L--'---訂 J-----寐 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 14 37225 A7 A7 經濟部中央標準局員工消費合作社印製 __B7 五、發明説明（13 ) 亦有可能利用銷絲刷或其他適當的切割装置自表面刮 除較低硬度之樹脂以使表面變成不平坦。 成形製品之表面僳利用上述各種裝置予以加工及粗化 ，且其後表面如上所述般經予研磨。在撤細顆粒上之被覆 靥僳利用研磨方式予以部分破碎，且此被覆雇及撤細顆粒 僳在製品之表面上以截面方式予以暴露出。利用此方式可 獲得具有》特深度及光澤之表面之堅實感，此乃歸功於如 上所述的光線之》特反射。 表面研磨方式並未予特別限定。有可能使用研磨石、 砂布、研磨帶或其他工具、或軟皮劑、擦拭劑或其他研磨 劑。 可予使用的研磨劑，包含纘石、硪化硼、金剛砂、氣 化鋁及結、其主要供研磨操作僳有效的、及矽藻土、白雲 石、氣化鋁、氣化鉻、二氣化鈽等。 亦可能如上所述在研磨後，進一步粗化表面以使表面 變成不平坦。於此情形下，撤細顆粒之至少一部分及其被 覆層之截面如上所述般應予暴露出。 以此方式，製出具有優越的表面及堅實感之人造石材 0 以下說明實施例。當然，此等實施例並非用以限定本 發明。 窨协例1 使用全部微細顆粒含量之50重量〆之以白色釉在約 1000¾烘烤之備有大約30« m厚表面層之10至25篩目天然 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ~ _____ I L.·裝 LII_---訂------：，球 (請先閲讀背面之注意事項再填寫本頁) A7 ___B7 _五、發明説明（14 )二氧化矽颗粒。擻細穎粒含曼及230篩目硪酸鈣傜以2:1重 之 物 成 組 部 全質 物 成製 以 合與 混料 率材 比的 Μ 得 重 9B clearly states that the inventions, and the falsification of the five cities, should be appropriate, and the appearance of the five cities should be special. The big one of the stone method or the material of the rock and the flower made by the Okanaoka is a good one. There is a masterpiece, the one that is made by Ryumi, the two hard plates, and the light material. The wall is made of special materials. It is good for him. In addition, the material consumption stone grinds the surface of the face, the density of the hard surface is strong, and the surface of the stone and the stigma are made of wood and soil, and the material is thin. Before and after the material stone surgery, the acid and the acid should be properly mixed to the crushing pressure on the scale. (Please read the precautions on the back before filling this page.) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Resin and hardened into artificial stone. For example, Japanese Patent Application Laid-Open No. 61-101443 shows a method for manufacturing artificial stone. The artificial stone can be cut in the form of a combination, in which raw materials, resins, and other materials are mixed under reduced pressure and poured into a molding box. Inside, remove for cutting. Further, Japanese Patent Publication No. 53-24447 proposes the use of raw materials to a specific mixing ratio, and the raw materials are completely pressed into a molding box to manufacture artificial stone from natural stone particles and synthetic resin. The problems associated with these known methods are that the artificial stone material obtained, even when using natural stone particles, does not have a proper hue or color depth. Traditional artificial stone has a lack of tackiness on the surface color and must not be refreshing or dull. It is quite difficult to produce a granite or marble-like surface with transparency, color depth, and solidity using conventional methods. This is due to the differences in the size of artificial stone and the size and mixing method of natural stone particles, so that light will have quite different reflection and absorption characteristics on the surface. These views have not been fully considered in the past. This paper size applies to China National Standard (CNS) A4 (210X297 mm) 3 37225 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (2)-The composition of artificial stone greatly affects the molding characteristics. 0 Flowability (in 1 I molding-important factor) depending on the size and ratio of natural stone particles and the mixing ratio of 1 1 I resin adhesive in artificial stone will be lost, please 1 1 1 * bubbles remain in the result In the final product9, the quality and strength of the artificial stone (the first product of the first reading ft 1 1 I) is significantly reduced. 1 1 I In order to solve this problem 9 For example, this B, Japanese Patent Publication No. 53-24447 > Wang Yishi 1 No. 1 proposes to increase the resin content to maintain fluidity t, and mentions refilling with the correct items ( 1 Fixed fluidity can prevent air bubbles. 0 Although written on this page, 9 resin is added to prevent air bubbles and maintain fluidity. — ^ 1 | Easy to get into the molding box will help maintain fluidity and prevent air bubbles from occurring. 1 1 1 However, it adversely affects the physical properties of the final product (human stone). 01 1 This means that resin-like artificial stone can be obtained by using a large amount of resin, and it simply means that the resin in the final product is in the resin. There are natural stone particles 0 with 1 1 physical properties and t The final product is a raw resin instead of a raw stone. 0 for 1 | of • Artificial stone only has its name »and the product looks like a tree that looks like stone Fat 1 'Silver m 0 1 I Therefore, it is expected to use natural stone or other particles as raw materials to achieve elimination 1 1 In addition to this problem and make it possible to produce a dense junction m, transparent hue% color 1 1 color depth flower rock , Marble or other natural stone special adhesion, superior 1 1 molding I and made of plate or bar or other formable artificial 1 stone 〇1 I g_ Ming 槪 沭 1 The present invention is used under the above conditions Put forward 0 In order to solve the above-mentioned problem 1 1 1 »The present invention provides a composition of artificial stone $ Including: 1 1 This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 4 37225 A7 B7 V. Description of the invention (3) Inorganic mixture of 10 to 70 mesh inorganic mold fine particles and 100 mesh and smaller inorganic non-removable fine particles, the entanglement amount is 85 weight% or more of the final product and the resin, which Or a unit of a collection of particles coated with an inorganic or organic substance of 15 wt of the total weight of the final product oozes or less, wherein the inorganic fine particles and by the dummy transparent to some or all of the other particles and indium. The present invention further provides an artificial stone molded article obtained by thinning or placing the above composition into a molding box of a moldable artificial stone. The present invention further provides an artificial stone molded article with a pre-polished surface. Hair lock: > Note for detailed description The present invention will be described in more detail below. The raw materials used in the artificial stone according to the present invention can be divided into three groups. A group is a main component, which is inorganic fine particles of 10 to 70 mesh. These are fine particles of digassed silicon, olivine, feldspar, pyroxene, mica or other minerals, granite, transformed rocks or other natural stones, clay, glass, gold tincture, and the like. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page). With these fine particles, the users are very fine particles of 100 mesh and below. These are various natural or artificial particles. Very fine particles are easily obtained from, for example, calcium gallate, water and vaporized aluminum. For some very fine particles, you can add manganese dioxide, titanium dioxide, chromium silicate, iron gas, etc. to adjust the color, and 1 or add antimony gas, compounds, bromide compounds, etc. to make the material into Fire resistance. The third component is resin. The resin can be self-curing or thermoplastic resin. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X 297 mm) 5 37 2 25 A7 B7 Printed by the consumer cooperation of the Central Standards Bureau of the Ministry of Economic Affairs. 5. Description of the invention (4 )-In a wide range, m is 0. For example, »Acrylic strip resin» Methacrylic% tree 1 1 I Fatty unsaturated polyester resin can be used. 0 1 1 I Natural stone and other fine particles are made by decision. Artificial stone 1 I Main factors of appearance and physical properties of 1 Please especially 9 Combining with other ingredients to read 1 I 1 »1 | Use» and when part of it is exposed 9 It can be used as the master of surface color and pattern Back 1 1 I 1 Factor 0 Note 1 1 Matter 1 Very finely divided grains are relatively finer or finer than finely divided grains -1100 item again relatively finer mesh. These particle wounds penetrate the fine grain-like spaces. In this page, t is removed and incorporated into it »and contributes to the m and softness of the final product. 1 The weight of fine grains to very fine particles fcb 0.5: 1 to 5: 1 is preferred 1 ί 1 0 resin is used to wrap the fine particles and very fine particles > so that it becomes the backbone of the composition 0 it further bonds all materials f and gives the system The artificial stone elasticity or tensile strength of 1 1 is obtained. 1 I The mixing ratio of these ingredients is important in the present invention. The ratio of the resin to its 1 1 'ball other ingredients is particularly important. A kind of high-density product with a dense structure 0 "High-density" in this description JtiS. / Ον means 徼 1 1 Fine and very fine grains exist in artificial stone with high density and finally The typical density level of 0 in the 1 1 product is 2.2 g / C 3 or above, which exceeds the common range of artificial stone used in Xi 1 0 0 | If the ratio of fine particles increases, the final product is very false. Close to the day 1 I Natural stone 0 However 9 If there are too many fine particles removed, the final product will not be strong enough 1 1 I Hard and not suitable for sale 0 The physical properties of the product are poor 9 and the product uses 1 1 1 Not applicable 0 1 1 This paper size applies Chinese National Standard (CNS) A4 specifications (210X297 mm) 6 37 225 A7 B7 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (5) If the ft content of m grains is too high, it will cause problems. Example 1 I If the material will not be cured 0 In addition, the final product will lose its luster i Almost 1 i I cannot be called stone 0 / -—. 1 I Please 1 I So »fcb rate of mold fine particles and very fine particles in the product. Read first 1 I read 1 I restricted 0 especially > This ratio must be 85% by weight or more 9 to 9C heavy weight 1 1% of I or more is suitable. 0 If the ratio exceeds 95% by weight, the product becomes brittle. Note that 1 1 is 1 and difficult to use. 9 In the other aspect, if the fcb ratio is less than 85% by weight, 9 items. Refill (1 The final product is too soft and f does not have the nature of stone > and apply Fan Yuan and write this page 1 is not better than resin board 〇1 I This means to remove ingredients other than fine and very fine particles > Or the resin is 1 [It should not exceed 15% by weight in the product. 〇 1 1 If the resin content exceeds 15% by weight of the product »The product is similar to plastic m is not called stone. 0 On the other hand, if the resin content is low, «1 1 then the product can have a natural color on the surface, but it will become brittle and therefore not 1 I suitable for use. From other viewpoints > The resin ratio 宜 is preferably in the range of 3 weight 涔 to 10 1 1 ft% 0 1 The basic conditions and inherent characteristics of the present invention are the material composition of the present invention 1 1 The above-mentioned inorganic fine particles should be partially or entirely transparent particles 1 1 $, and the particles or small collections thereof are previously covered with an inorganic or organic substance 1 1 I 0 The above-mentioned transparent skimmed particles can be coated with resin and hardened 0 or 1 1 of 1 such as water glass, pottery glaze or other inorganic substances can be baked on the surface of the granules by baking 1 1 1 in any case »transparent withdrawal m 1 1 1 The grain size is covered with a thickness of & L at to dozens & L η * For example, a range of 5 to 50 / j 1 1 This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) 7 372 25 Economy Printed by A7 B7, Consumer Cooperatives of the Ministry of Standards of the People's Republic of China. 5. In the description of (6), a film with 20 to 30 W η is suitable, especially special, such as acrylic resin or unsaturated polyester resin. It is about 15010 to 300, or it is coated with light and hardened to the surface of the fine particles. It is also possible to adhere water glass, glaze, etc. to the surface of fine particles, and bake at a temperature of 800 to 1100 ^ to form an inorganic coating layer. This coating greatly improves the affinity of the fine particles for the overall structure, and it functions like an aggregate function of artificial stone. Further, when it is completely mixed, strength and surface hardness are increased. More importantly, the fine-grained, transparent natural stone is removed, and its surface is covered with a hard film as described above. When the artificial stone is pre-ground, the film is partially broken, and the partially exposed transparent fine particles and the surface of the coating covering the exposed part of the plaque area around the fine particles together create a unique effect of reflected light. This means that the light radiation enters the transparent fine particles, is reflected by the coating layer surrounded by the trap, and is reflected back through the transparent fine particles. This phenomenon of light transmission and reflection is basically different from the surface reflections observed in conventional artificial stone, and imparts a color depth to the artificial stone according to the present invention. The resulting artificial stone is similar to marble in appearance, is solid, has deep color and is of high quality. The above-mentioned transparent fine particles having a coating layer may generally contain 10 to 100 weight of all the inorganic mold fine particles contained in the composition. In the present invention, it is necessary to specify the size of the inorganic fine particles. In particular, the size of the inorganic fine particles should be the aforementioned 10 to 70 mesh. Except in special cases, it is best to use only fine particles of the same size. When distinguishing, I can make I -------- Cr install I ------- order ------- ^ (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) 8 37 225 A7 B7 V. Description of the invention (7) Two kinds of particles are used, for example, the upper or the next (colored particles are used on Pre-colored and the other colorless particles. In this case, the use of a large number of particles of extremely different sizes will worsen the strength of the product and should therefore not be used. The size of very fine particles should be as described above. For the size of 100 mesh and below, it must be small enough to completely penetrate into the space between the skimmed particles, and it is not suitable for the size of the fine particles to be close. For specificity, the size should be 150 to 250 mesh. For the high-density artificial stone of the present invention, in addition to special circumstances, it is also important to confirm that the components of the composition are uniformly dispersed in the product. It is preferable to grind the outer surface of the product. In other words, to remove the coating of fine particles As described above, the layer is fractured at least partially on the surface of the article 0 Grinding image is a feasible and easy-to-use method of exposing the dense surface of the high-density artificial stone with color depth of the present invention. Of course, it is possible to grind part of the surface of the product to expose fine particles and use it on the same surface. The difference between the exposed area and other areas is used as a sample of the product. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) In the manufacture of artificial stone, decide what kind of natural stone Stone should be important in color and design. Granite and marble are popular targets. Because of their scarcity, it is difficult to obtain beautiful colors and gloss. In this example, color and gloss determine the granite and marble. The value is an important issue. Natural granite and marble have various colors from dark black to white or red. Even if the colors are the same, the degree can be different. In conventional methods, this paper is made of black powder from natural stone and other materials. Standards apply to Chinese National Standard (CNS) A4 (210X297 mm) 9 37 225 A7 B7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. 5. Description of the invention (8)-Black artificial stone. 0 This is not the cause of the problem. However, when the flute is made of half-colored 诹 1 I, f reproducibility is often the problem. m Makes reproducible colors 1 1 »Marble gloss is difficult to reproduce 〇 / -— V 1 I Please 1 I For example, dyes and pigments can be used to produce color * But in the conventional method, read 1 I 1 | Depth of gloss and color is difficult to produce. 0 Back 1 I 1 In the present invention 9% Use of transparent fine_grain 0 When you want to make artificial stone with note 1 | gloss 9 For example, similar to granite or marble Fine particles of crushed natural quartz stone emblem can be used. Page j The fine particles made of crushed quartz natural stone have a unique smooth surface on the surface. This is due to the raw material 傜 quartz. It is colorless and transparent in various conditions. The color is not so strong when it is colored. 1 It is not completely transparent. 9 It also maintains a certain degree of transparency. 0 The color of the product produced by the above raw materials can be adjusted on the m fine particles. 1 I coating And the color of the resin to be controlled. Further 9 The color may have a depth of 1 I and a gloss of 0 1 1 For example, the coating layer of Feidang is a baked water glass layer containing white pigment 1 or a hardened polyester. Unsaturated resin layer »And when the 1 1 resin of the present invention is used as the unsaturated resin mainly composed of polyester, 9 is obtained. Milky white with light 1 1 color 9 This is because the color of the resin is usually yellowish white 1 1 »Similar to natural milky white marble 0 1 I By using pigment dyes or other colorants 3 in the coating 1 1 I step by using inorganic pigments such as titanium dioxide in the resin * Silicic acid 1 1 I Chromium > Manganese gasification, gasification, Cobalt gasification or organic pigments such as azo pigment 1 1 material > Pigment 9 or various dyes 9 which are the main components of phthalocyanine 9 It is possible to produce a paper with 1 1 paper size applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) 10 3 7 225 A7 B7 V. Description of the invention (9 ) 'Uniform color' color and the unique color tone and depth of the artificial stone with a unique luster and color depth. The color can be colored, and the final color of the grain product is the most popular. It is mixed with degrees and fits to make appointments and make great use of the color. The more the color and the color are, the better the color is. There are methods and tools to make the product more clear and clear. The present image is made of color is, and the rate of Chu is incomparable. What's more, the way of making the color is to make the color of the hair. Color baking granules are square in color, so this powder can be used to make the color finer and lighter. The effect of is clear and transparent. Its natural grains can be made into small grains, to the shape, and the glaze powder grains are used to enter the fineness of the porcelain. The color reinsurance for Tao Cai's barriers should be given by the Ministry of Justice to the more brilliant master, Ying Shiyi, the crushed and crushed grains of fine mold. The selection of the group is to be used as a plaque. Ze Xi's color light is also made in black, and using the color again can make the color of the color in the color to the different color. Bake. Questions and questions are asked to re-glaze and some are not complete. _ Prepared for the same color of the surface material and the color of the spar. (Please read the precautions on the back before filling this page) Economy The Ministry of Central Standards Bureau ’s Consumer Cooperatives printed roasted directors with a thin layer of micro-coated coatings containing 10 grains to 10 grains. The bake contains the granules, and there is a fine method, which is absolutely nothing like the Chinese and French theory. The object-free group is written by Cheng Chenghua, and it is blended with the short-colored Wang Xixi, which is used by the winners. Make up the rate of bevy m porcelain. Tao Yi and Weiwei are examples of mineral glass, such as glass. Its use is especially good, and it can wait for iron. Fatty tree structure, gold type of dimensional fiber, this paper size applies Chinese National Standard (CNS) A4 (210X297 mm) 11 11 37225 A7 B7 V. Description of the invention (10) The diameter of these short fibers is usually It is 10 to 100 «B and has a length of 1 to 10 BB, which is like mixed with 1 to 10 weight X of all mold fine particle components. The central government bureau of the Ministry of Economic Affairs' employee consumer cooperatives use not only the narrow narrow mixing on the side of the department, but also reduce the granularity of the box S by reducing the amount of material in the selection and consolidation. Material reduction can be preformed, compared with the flow of internal fat. • The accumulated land in the building material is thin and the tree is fishy. The method is to display in the box part of the homogenizing box or the manufacturing method, and open the uniform profile. Box Human body. It is necessary to make the stone into a stone and make it into a shape. The column should be good. Make it less.湓 When the dense and round plaque is the most suitable, it can reduce the number of people and be high, and the relatively well-formed grains are empty. The materials have been made into shaped grains and formed into mouths. The internal adjustment of the dry stick is based on the internal and internal opening of the bottom color film. If the side is stored in time, use the best board to remove the box to make the shape and make the side as usual. The box contains the formulas that can be made and must be made. The examples are non-reduction, reduction, and contraction. _ Kaikai or and it is made into a form, and the square pressure is clearly divided into columns. It is detailed, and the shape is made in a tightly rising style. Catchy The descriptive nature makes it possible to mention the explicit molding version. One side of the painting is open and moving upwards. When the shape of the person who is bound by each other is turned around, the top of the painting is permeated and separated. This system is based on the fact that the closed field is high and the tree is held. C Ruyucheng is what you follow. There is a seal plaque when the material is more difficult to remove. There are trees cast of material. Position of the table _ Use the contract as a board and material (please read the notes on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210X297 mm) 12 37 225 Central Bureau of Standards, Ministry of Economic Affairs The quick-knit people printed by employee consumer cooperatives are few and small, and they have a large and detailed flow. Because of this, ρ has been overrated. Manufactured to contain poor internal solids, sometimes. Compared with the mold? Psl compression single system to grease has a small amount of extrusion knows the method is needed ο mixing is simple in the work tree grease has been pushed. For the casting, the material will be added when the material is added. If the user has used the material in the production section, the material will be removed, and the material will be processed so that the grade M can be described. The material quality of the material is more than that of the tree. cn ^ The product of Zhen Zhen is less selective for quality. It is controlled to have a boxed product f /, the internal system can often be seedlings, and the light fat is filled with the seed type. kgu The medium box type can be thin. Contains 10% in mixed 00 type into only. The surface of the box is more fat than the other. One of the common glances has been a cause of formation. The water of the small amount of the common type of linden tree has a fat shrinkage, and the product is like a non-decreasing fixed amount. Each tree is ^ ; If the pressure is good, if the system is to be contracted and the product to be shrunk is included, the force and the power will be changed. The first method is to remove the fat and remove the fat, and the method is to make the grain pressure £ 0. It is also included in the production-the micro-casting and the tree ends in the shape of the medium noodles. The method of law, bread 1 1 is regarded as its final product. The most type is the type of the detailed formula table W under its detailed table. . And at least it is reduced in micro-use hot box into a big this hair in the party # Of course when the landing, the reduction of shrinkage, Changli As the type of shrinking, Benluguan # significantly. Sinking box material. It can be pressed into a non-material output g2. The pressure is more and more lost in the violent phase ^ The heavy open-shaped stone can be chess and combination system 5 The best quality leaks the grain, the specific speed is made with C, the fine mix is mixed with heat and the moving is made of five -------- -;-Pack 1 --'--- Order-τ ----- line (please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) 13 3 7 225 A7 B7 printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (12) Method, for example, after the molded product is taken out of the molding box, high-M water is sprayed onto the surface of the molded product to process the surface. Is effective. This processing method cannot be explained in a restricted way, because the successful use of this method depends on the thickness, distance from the nozzle, processing shape and various other conditions, but it is usually a thickness in the range of 2 to 20 cm. Water® 50 Up to 800kg / ce2 僳 is used on nozzles about 2 to 10 cm high. The water pressure is lower than that used when processing natural stone. This means that advanced processing supplies are easier to form due to the presence of resin components. Nozzles and their systems using high-pressure water are not particularly limited. A variety of devices are known and available. This surface processing uses a jet waterjet device to produce a smooth or rough surface, which can produce solid and deep artificial stone. The surface does not become cloudy or dull due to the presence of the resin, and the disposal of the waste solution is easier to handle than the chemical etching step. If necessary, it is also possible to treat the surface with an organic solvent to soften or melt the partially removed resin. In this case, the organic solvent used is selected based on the consideration of the resin component to be removed. Organic solvents, such as dicyanoethane, dichloromethane, methane, or other halogenated hydrocarbons, acetic anhydride, ethyl acetate, butyl acetate, or other carboxylic acids or their ester compounds, acetone, tetrahydrofuran, dimethyl Formaldehyde amine, dimethylene 'and the like. The molded product is immersed in one of the solvents, or the thin one is sprayed or dripped on the molded product to soften or melt the resin from the surface to make the surface uneven. --------- 1: -Load L --'--- Order J ----- 寐 (Please read the precautions on the back before filling this page) This paper size applies to Chinese National Standards (CNS ) A4 size (210X297 mm) 14 37225 A7 A7 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs __B7 V. Description of the invention (13) It is also possible to scrape off the surface with a wire brush or other appropriate cutting device. Hard resin to make the surface uneven. The surface of the shaped product is processed and roughened using the various devices described above, and the rear surface is ground as described above. The coating on the fine particles 部分 is partially broken by grinding, and the coating and fine particles 僳 are exposed on the surface of the product in a cross-section manner. Using this method, you can obtain a solid feel with a "special depth and glossy surface, thanks to the special reflection of light" as described above. The surface polishing method is not particularly limited. It is possible to use abrasive stones, abrasive cloths, abrasive tapes or other tools, or soft skins, wipes or other abrasives. The abrasives that can be used include vermiculite, boron tritium, corundum, gasified aluminum and cement, which are mainly used for grinding operations, and effective diatomite, dolomite, gasified aluminum, gasified chromium, and two gases. Huayao et al. It is also possible to further roughen the surface after grinding as described above to make the surface uneven. In this case, at least a part of the fine particles and the cross-section of the covering layer should be exposed as described above. In this way, an artificial stone having an excellent surface and a solid feel is produced. 0 Examples are described below. Of course, these embodiments are not intended to limit the present invention. Example 1 Use 50% by weight of all fine particles. Bake with white glaze at about 1000 ¾. 10 to 25 meshes with about 30 «m thick surface layer. Natural paper size applicable to Chinese National Standard (CNS) A4 Specifications (210X297mm) ~ _____ I L. · Install LII _--- Order ------: Ball (Please read the precautions on the back before filling this page) A7 ___B7 _V. Description of the invention (14) Silicon dioxide particles.擞 Fine granules contain mannite and 230 mesh calcium 硪 calcium 傜. It is made of 2: 1 weight material, and the whole quality is made.
量 S f 1 S 1* 及 脂 樹 酯 甲 酸 烯 丙 基 甲 聚 量 所化 ,硬 後〆 然量 板 之 度 厚 B E 5 1X 約 成 形 且 。 内 料箱 材型 狀成 漿入 砂鑄 成被 形傜 以物 合成 混組 勻此 均 剤 被部 的之 烤粒 烘颗 經細 有微 具及 。 層 磨覆 研被 以的 予烤 劑烘 磨經 研其 砂出 0 0 金暴 用粒 使顆 像細 面徽 .表之 0 層 材 覆 色 白 乳 的 般 石 理 大 似 類 且 厚 深 出 示 顯 材 石 造 人 的 〇 得 面所 截 分 tf 1 S 比 得 以 試 測 以 予表 。12如 勻71性 均K-特 造 S 他 構JI其 且格 。 ，規〆 泡業13 氣工 ο 無本為 並日率 其依水 cβ吸 澤品 ， 光製29 及 2 彩 為 示 所 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作杜印製 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） 6 1Χ 3 7 225 經濟部中央標準局員工消費合作社印製 38B749 五、發明説明（15 ) 表 1 項 目 結 果 澜試條 件 抗曲強度 31.30kgf/ci 依J IS A5209之規定 Μ縮強度 1400kgf/c·2 十字頭速度0 . 5··/ in負載元2噸 耐衝擊強度 4 . 58kgf · C B / C 通 2 擺錘型衝擊測試器 硬 度 1021kgf/b·2 依JIS Z-2244維克斯 硬度之規定 線膨脹僳數 0.65(x 10'6k) Τ Μ A ( 3 0 至 1 0 0 t：) 耐磨耗性 0.03s JIS Α-1452砂落型耐 磨耗試驗 酸及齡試驗偽利用將製品浸漬入3知塩酸溶液内8小時 及3〆氫氣化鈉溶液内8小時。未發現有不正常現象。 由而裂得的製品僳被使用作建築物之牆板，可發現其 變成具有深度的美觀大理石壁。 〇-裝|~.—丨訂----丨…k (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準·（ CNS ) A4規格（210X297公釐） 17 37 225 經濟部中央標準局員工消費合作社印製 888749 五、發明説明（16 ) 窨旃俐2 於 實 施 例 1中， 徹細顆粒含量及非常撖細顆粒含置之 V 合 計 董 像 被 設 定 成 93涔 » 且 表 面 經 烘 烤 層 之厚度偽被選擇 成 20 U η 〇 樹脂之含量則被設定成δ涔 0 當 使 用 實 施 例 1之相同操作步驟時， 可製出高品質之 人 造 石 材 0 壓 縮 強 度 為 1251 k g / c η 2 硬 度 980kgf/mn2〇 此 製 顯 示 出 具 有 深 度 之 優 越 的 大 理 石 狀 表 面。 s_ 旃 例 3 將 具 有 藍 釉 5 μ η 厚 之 被 覆 層 烘 烤 於 天 然二氣化矽全部 數 S 之 1 5 % 表 面 上 f 此 二 氣 化 矽 偽 被 使 用 作徹細顆粒成分 〇 使 用 此 10 至 5 0筛 百 撤 細 顆 粒 以 如 實 施 例1所述的相同 步 驟 製 得 板 材 製 品 〇 此 製 品 使 用 氣 化 鋁 AmL 貉 研 磨 劑 予 以 研 磨 0 由 而 可 製 得 具 有 深 度 之 美 觀 的 帶 藍 的 白色表面。 其 物 理 性 質 傜 與 實 施 例 1製得的製品者近乎相等。此 製 品 像 適 合 作 為 建 築 用 之 高 品 質 人 造 石 材 〇 育 旃 例 4 取 65〆 10 至 50篩 百 天 然 二 氣 化 矽 (使用作為撤細顆粒 成分），以含有鈷藍（顔料藍28)顔料之聚甲基丙烯酸甲_ 樹脂之約50 w m薄膜予以塗覆。 此材料如實施例3所述相同方法予以成型，且表面經 予研磨。由而可製出具有混合藍色及乳白色深度之美觀的 表面。 --------裝L--.---訂------踩 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 18 37 225 388749 a7 B7 五、發明説明（17 ) 經濟部中央標準局員工消費合作社印製 此 人 造 石 材 之 比重 為2 . 29 , 抗 曲 強 度 30.55k ；g f / C Μ , m 缩 強 度 1305kg ：f / c酿2， 及硬度950 k8 ；f / * ι2〇 hh 較 例 丄 於 實 施 例 1中， 使用5至 20篩 巨 微 細 顆 料。 所 得 的成型 製 品 欠 缺 強 度 及 均 勻構 造。 fcL 較 例 2 於 實 施 例 1中， 分別使用微細顆粒對非常撇细顆粒之 重 董 比 為 0 . 2 ： 1及6 :1， 製得 人造 石 材 0 於 任一 情 況 ,製品 均 未 具 有 均 勻 的 結 構， 且其 強度 並 不 足 夠 至供 實 用 程度。 hL 較 例 3 於 實 施 例 3中， 樹脂含量像被設定成全部原料之20重 量 % 0 此 製 品 顯 示 出較 差的 硬度 9 且 容 易 受損 參 其 外觀不 似 天 然 石 材 % 且 容 易被 分辨 此製 品 係 塑 睡 〇 hh 較 例 4 於 實 施 例 4中， 省略在黴細顆粒上之被覆層且綠色顔 色 係 被 混 入 樹 脂 内 。製 品换 強烈 地 帶 有 綠 色， 且 表 面上欠 缺 天 然 石 材 之 外 觀 〇 育 m 例 5 含 有 印 第 安 紅 (以氣化鐵為主） 顔 料 之 水玻 璃 傷 被烘烤 於 10 至 50篩 百 天 然 二氣 化矽 之上 使 厚 度 成 約30 a 疆〇 約80 % 傜 由 上 述 烘 m 有 水玻 璃之 天然 二 氣 化 矽 _粒 所 組 成之微 細 二 氣 化 矽 顙 粒 含 置， 像與 由50允 100至350篩 百 m 化鈣及 50涔 氫 氣 化 鋁 所 組 成之 非常 撤細 顆 粒 含 量 相混 合 至 重董比 2:1。然後此混合物最後舆含有紅色顔料之不飽和聚酯樹 ---------Γ-裝-------訂------綵 ....... (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 19 37225 38G749 A7 B7 五、發明説明（18 ) 脂混合，混合比率為前者像全部所得的材料之90〆。 此材料像被鑄入成型箱内且在表面壓力l〇kg f/c·2下 予以成型。製品之表面僳利用金刪砂研磨劑予以研磨。 本發明人等製出非常優越色調及深度之人造石材。其 強度及其他物理性能均令人滿惠；其抗曲強度為3 2.05 kgf /c·,藶缩強度為 1405kgf/cn2，硬度為 1 062kgf/mm2。 如上所述般，本發明提供一種具有深色與光澤之優越 色調之高密度人造石材，其在以往並未被實現且具有良好 物理性能。本發明之製品具有一種在天然石材難以發現的 均勻性。進一步，該等優越製品不霈使用非常昂貴的設備 邸可製得。 依本發明之人造石材僳特別適用於製造花崗岩或大理 石狀製品，且此製品可與天然石材般以相同方式予以使用 〇 此製品為具有深色之高级製品，且可被使用作壁材、 地板材、柱材等，其應用範園較天然製品者為廣。 ---------^裝L--.---訂------i泳 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消费合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 20 3 7 225The amount of S f 1 S 1 * and the amount of the allyl methyl formate of the resin formic acid is determined by the thickness of the hard board. The thickness of the plate is B E 5 1X. The shape of the inner box is shaped into slurry, cast into the sand, and formed into a quilt. The material is mixed and mixed, and the baking grains of the quilt are fine. The layer grinding is ground with a pre-baking agent. After grinding, the sand produces 0 0 gold storm grains to make the grains look like fine-faced emblems. Table No. 0 The layer is covered with white milk and is similar to a stone with a thick appearance. The ratio of tf 1 S cut by the human face can be tested and shown. 12 If uniformity, uniformity, K-specialization, other structure, JI, etc. ， 〆〆 泡 业 13 工 工 ο Nothing is the same as the daily rate of cβ absorbent products, light system 29 and 2 color is shown (Please read the precautions on the back before filling this page) Central Bureau of Standards, Ministry of Economic Affairs Dumplings printed by employees are printed in accordance with Chinese National Standards (CNS) A4 specifications (210 × 297 mm) 6 1 × 3 7 225 Printed by employee consumer cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 38B749 5. Description of the invention (15) Table 1 Project results Lan test conditions: flexural strength 31.30kgf / ci according to J IS A5209 M shrink strength 1400kgf / c · 2 cross head speed 0.5 ·· / in load element 2 ton impact resistance 4. 58kgf · CB / C pass 2 Pendulum impact tester hardness 1021kgf / b · 2 According to JIS Z-2244 Vickers hardness linear expansion coefficient 0.65 (x 10'6k) ΤΜ A (30 to 10 0 t :) 0.03s JIS A-1452 sand-type abrasion test acid and age test pseudo-impregnation of the product in a 3 cimic acid solution for 8 hours and a 3 volt sodium hydroxide solution for 8 hours. No abnormalities were found. The cracked product was used as a wall panel of the building, and it was found that it turned into a beautiful marble wall with depth. 〇- 装 | ~ .— 丨 order ---- 丨 ... k (Please read the precautions on the back before filling this page) This paper size applies to Chinese National Standards · (CNS) A4 specifications (210X297 mm) 17 37 225 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 888749 V. Description of the Invention (16) 窨 旃 2 2 In Example 1, the total V-total image of the fine particle content and the very fine particle content was set to 93 涔 » And the thickness of the baked layer on the surface is selected to be 20 U η 〇 The content of the resin is set to δ 涔 0. When the same operation steps as in Example 1 are used, a high-quality artificial stone can be produced. The compressive strength is 1251 kg / c η 2 hardness 980kgf / mn2〇 This system shows a superior marble-like surface with depth. s_ 旃 Example 3 A coating layer with a blue glaze thickness of 5 μ η is baked on 15% of the total number S of natural silicon dioxide. f This silicon dioxide is used as a fine particle component. Use this 10 To 50 sieve hundred fine particles to produce a sheet product in the same steps as described in Example 1. This product is ground using aerated aluminum AmL 貉 grinding agent 0, so that a beautiful blue with white with depth surface. Its physical properties are almost equal to those of the product made in Example 1. This product looks like a high-quality artificial stone suitable for construction. Example 4 Take 65〆10 to 50 sieve hundred natural digassed silicon (used as a fine particle component) to contain cobalt blue (Pigment Blue 28) pigment. An approximately 50 wm thin film of polymethacrylate resin was applied. This material was shaped in the same manner as described in Example 3, and its surface was ground. As a result, an aesthetically pleasing surface with a mixed blue and milky depth can be produced. -------- Install L --.--- Order ------ Step on (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 specifications ( 210X297 mm) 18 37 225 388749 a7 B7 V. Description of the invention (17) The proportion of the artificial stone printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs is 2.29, the flexural strength is 30.55k; gf / C Μ, m shrink Strength 1305kg: f / c2, and hardness 950k8; f / * ι20hh Comparative Example 丄 In Example 1, 5 to 20 sieve large and fine particles were used. The resulting molded product lacks strength and is uniformly constructed. fcL Comparative Example 2 In Example 1, the weight ratios of fine particles to very skimmed particles were 0.2: 1 and 6: 1, respectively, and artificial stone was produced. In either case, the product did not have a uniform Structure, and its strength is not sufficient for practical use. hL Comparative Example 3 In Example 3, the resin content is set to 20% by weight of all raw materials. 0 This product shows poor hardness 9 and is easily damaged. Its appearance is not like natural stone% and it is easy to distinguish this product. Plastic sleep 0hh Comparative Example 4 In Example 4, the coating layer on the mold fine particles was omitted and the green color was mixed into the resin. The product is strongly greenish and lacks the appearance of natural stone on the surface. Example 5 Water glass wounds containing Indian red (mainly gasified iron) pigments are baked at 10 to 50 sieve 100% natural silicon dioxide. The thickness is about 30a and about 80%. 傜 The fine digassed silicon granules composed of the above-mentioned dried natural glassy silicon granules with water glass are contained, like 50 to 100 to 350 sieve. The content of very fine particles composed of 100m calcium and 50% aluminum hydride are mixed to a weight ratio of 2: 1. Then this mixture finally contains unsaturated polyester tree containing red pigment --------- Γ-pack --------- order -------- color ... (please Please read the notes on the back before filling this page) This paper size applies Chinese National Standard (CNS) A4 specification (210X297mm) 19 37225 38G749 A7 B7 V. Description of the invention (18) Fat mixing, mixing ratio is obtained by the former like all 90% of the material. This material was cast into a molding box and formed under a surface pressure of 10 kg f / c · 2. The surface of the product is polished with a gold-removing abrasive. The inventors have produced artificial stone with very superior color and depth. Its strength and other physical properties are full of benefits; its flexural strength is 3 2.05 kgf / c ·, its shrinkage strength is 1405 kgf / cn2, and its hardness is 1062 kgf / mm2. As described above, the present invention provides a high-density artificial stone having superior shades of dark color and gloss, which has not been realized in the past and has good physical properties. The article of the invention has a uniformity which is difficult to find in natural stone. Further, these superior products can be made without the use of very expensive equipment. The artificial stone 僳 according to the present invention is particularly suitable for making granite or marble-like products, and this product can be used in the same way as natural stone. This product is a high-quality product with dark colors and can be used as wall materials and floors Materials, pillars, etc., are more widely used than natural products. --------- ^ Install L --.--- Order ------ i-yong (Please read the precautions on the back before filling this page) Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs This paper size applies to China National Standard (CNS) A4 (210X297 mm) 20 3 7 225