TW381030B - A sprayable deodorizing aqueous emulsion - Google Patents

Abstract

A sprayable aqueous emulsion to treat the air of premises and/or to be applied directly, the emulsion being characterized in that it comprises:a. an emulsifying agent comprising an acrylic acid of a hydrophobically modified cross-linked polymer; and b. One or more compounds selected from the group comprising: a deodorant comprising a divalent metal ion complex having sp3 hybridization and two molecules each having two groups selected from hydroxy, carboxyl, and aldehyde groups; an insecticide that is insoluble or poorly soluble in water; a bacterio-static agent that is insoluble or poorly soluble in water; and a fragrance that is insoluble or poorly soluble in water.

Description

A7 B7 V. Description of the invention () In summary, the present invention provides a sprayable water emulsion for treating air and / or direct spraying on specific occasions. The emulsion has: (Please read the precautions on the back before filling (This page) a. — An emulsifier composed of propionic acid that is a hydrophobically modified cross-linked polymer; and b. — Or more compounds selected from the following: * — a bivalent metal ion complex with SP3 hybridization Compound and two deodorants each having a molecule selected from the group consisting of a hydroxyl group, a carbonyl group, and an aldehyde group; * an insoluble or low water-solubility insecticide; * an insoluble or low water-solubility inhibitor; and * Insoluble or low water-soluble fragrance. According to its particularly favorable sprayability, its viscosity is between 10 centipoise (CPs) and 1,000 cPs, preferably between 10 cps and 200 cPs, and between 50 cps and 150 cPs. good. The emulsion printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs may contain surfactants such as cetyl dimethyl polysiloxane copolyol at a concentration of 0.1% to 1%. The addition of this agent results in a decrease in surface tension which will reduce the viscosity of the emulsion accordingly. As for the deodorant, the molecule of the pseudohydroxycarbonyl acid family of the molecule is preferably 12-hydroxy-octa- [9-bronic acid (ricinoleic acid). The deodorant preferably has a pseudo concentration of 0.05% to 30%, more preferably 0.05% to 3%, and most preferably 0.5% to 1.5% of the bis- (12-hydroxy-octa- [9] -nonenoate zinc (M zinc linoleate). In addition, the concentration of emulsifier should be between 0.05% and 2%, preferably 0.05% to 0.4%, and most preferably 0.1% to 0.2%. -6- Paper Zhang scale is applicable to Chinese National Standards (CNS) A4 specifications (210 × 297 mm) A7 B7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (1) The invention relates to a vapor or smoked state (gas phase) Treatment of evaporable water emulsion for specific occasions such as hotels, office rooms or outdoor. The present invention also relates to a method of using the water emulsion in the gas phase and introducing the water emulsion into the gas phase. The emulsion determines its removal due to its raw materials. Odor and / or insecticidal and / or bactericidal functions. For deodorizing treatment, there are two main types of substances with scenting stool effect. Aroma substances, such as fragrances, can provide fragrance, and deodorants can also be used. Provides the effect of removing odor. The former masks the odor and the latter traps the odor. Sexual substances are generally dispersed into granules by means of spray pumps or aerosol cans. The withdrawn particles are temporarily suspended in the air, but will sink due to their own weight, because the particles are faked by the liquid phase of the substance. Non-gaseous composition "This type of fluid suspension is suitable for local processing, because a large amount of material can be concentrated in a smaller volume. Conversely, when large volumes are to be processed, this technology is not suitable for use, and substances cannot be used. Ideally dispersed in the air, and at the same time a large amount of material is consumed due to the firm drop of the particles. The device shown in the EP-A-0 401 0S0 patent case is different from the simple spraying technology, using a manual pump started by a motor device The particle spray liquid is sprayed on the surface of the golden urn. The surface of the golden urn is heated to a temperature above the evaporation temperature of the fluid, so that the fluid residence is evaporated to a gas state, that is, the state changes. In the text, "烟 壎 (fumigation The term ") means a dispersed substance of this type. Because the fluid changes into a gas phase, it is more effectively dispersed in the atmosphere than the way aerosols generate suspended particles in the air. Compared with aerosol, less material can be used to achieve the same effect (Avogadro's Law), which is not only lower in cost but also applicable to Chinese national standards for human health and the environment. CNS) 8 specifications (210X297 mm) (Please read the precautions on the back before filling this page)

V. Description of the invention () Ammonium sulfonate and ammonium hydrogen sulfonate are preferred in the printing of employee cooperatives of the Central Bureau of Standards of the Ministry of Economics because they can be thermally decomposed into harmless substances as follows: (HHi) zC〇3-> 2NH3 + COa + HaO NH4HCO3-> NHs + COa > H2〇 All reaction products are environmentally friendly gases. In any case, the above neutralizers are not the only ones available. Any substance capable of extracting protons from a carboxylic acid group is suitable. The degree of neutralization agent is between 0.01% and 2%, preferably 0.05% to more preferably, (K1% to 0.5% is the best. Deodorant is suitable for the aqueous emulsion emulsion-like zinc ricinoleate of the present invention, which is Zn2. * The complex of ions with two molecules that neutralize M linoleic acid. Its chemical name is 12-hydroxy-octadecyl- [9] -nonenedioic acid. The chemical formula is C18H34〇3. Zinc ricinoleate is harmless to the environment Its deodorizing properties. Zinc itself is not harmful to the environment. Castor oil acid is obtained from the fatty acid of castor oil. The preparation of free acid is made by separating the original fatty acid and glycerol after the hydrolysis of sesame oil. Finally, the original acid It is purified by various appropriate technologies. Ricinoleic acid is a kind of special acid, which is a kind of fatty acid that accepts hydroxyl groups on its main store. Hydroxy fatty acids are found in all living things in nature, but the amount is extremely rare.分子 A molecule with multiple cabinet electrons, which has a hydroxyl group and a carboxyl group. Ricinoleic acid is a hydroxycarboxylic acid. M zinc linoleate is a preferred deodorant in the present invention, but there are other deodorants with different chemical formulas. .M zinc linoleate There are complexes of divalent metal ions, especially 傺 Zη2 * and two molecules of ricinoleic acid ion. The " 11-nm I ϋ nn HI n 丨 peak ^ 丁 3 ^ 言 (Please read the precautions on the back before (Fill in this page) This paper size applies the Chinese National Standard (CNS) Λ4 specification (2 丨 0X297 mm) The A7 _B7_ printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. The invention description (2) is more advantageous. In addition, spray cloth The microparticles generated are instantaneously evaporated on the heating surface, so the fluid can not retain all its properties due to thermal degradation during the evaporation process. Furthermore, the pseudo expansion number (the volume of gas produced by the evaporation of the liquid at the boiling point) is known. The ratio to the initial volume of the liquid will increase as the molecular weight of the substance decreases. Since the molecular weight of water is only 13, it is best to use a substance with a high percentage of water. This is the use of emulsions to provide very high water content. The reason. According to the simple theory of the ideal gas law, the swelling number of the emulsion is 1,530, but only 585 of them contain 25% water and 65% surface active solubilizer. In addition to the high emulsion, which does not contain organic volatile compounds that are harmful to the environment and the human body, it meets the requirements for protecting the environment. In terms of the viscosity of the swelling volume, it is also ideal for use at high temperatures. The persistence of cross-sectional area is greatly increased when the substance is converted from the liquid phase to the gas phase. Therefore, the benefits of using soot technology will be more effective when using highly water-based substances. It is an object of the present invention to provide water with extremely high water content for the above purposes An emulsion with a minimum amount of emulsifier at the same time. Another object of the present invention is to provide an aqueous emulsion that does not leave any residue on the heating surface of the smoking device. The emulsion of the present invention can be spray-applied to applications such as household Places that smell bad, such as garbage chutes. The emulsion should have good stability for long-term storage ^ The emulsion must also be easy to spray, and only a small amount of pressure can be used to make the emulsion sprayed. (Please read the precautions on the back before filling out this page.) This paper size applies to Chinese national standards (CNS> A4 specification (210X297 mm)

Metal ions and molecules printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs can be changed, and the conditions must correspond to a high degree of pending demand. The metal ion must be a polyvalent metal ion, but a divalent gold sulfonium ion with SP3 hybridization is preferable. A metal ion with SP3 hybridization can bond four ligands, which means that the bonding force has the same characteristics as the ligands. For example, a zinc atom has thirty electrons, and the two outermost electrons are in a non-hybrid state in the 4s orbit. When the second europium electron of 4s orbital is ionized, Zn europium ion will be formed. The favorability of Zn2t ions: the energy of the 4p orbital is lower than that of the 3d orbital. As a result, the Zn "ion can cooperate with Sijian's molecules with multiple europium electrons. Although the s and p orbital energies are different, quantum mechanics requires the sp 3 hybridization of the tetrapyramidal orbital to have the same energy level That is, the reason that Zn2 + ions can provide coordination bonds with four identical coordination matrices. However, the Zη "ion is not the only one with sp3 hybrids. Shop and mercury also meet the above conditions. Nevertheless, this metal is extremely harmful to the environment and human beings, so it is quite difficult to apply it to the deodorant for spraying cloth of the present invention. Shop or mercury can be used in closed systems for external regeneration. D2sP-type crosses such as those occurring in specific transition metals such as cobalt, iron, chromium, and thallium may also occur. Therefore, all gold ions with sp3 or d2sp3 hybridization can be used in the complex of deodorant. In order to make the explanation of hybridization clearer, the following will explain the distribution of electrons in the orbits of the broken atom and the column showing the master atom. {Is} {2s} {2px} (2py) (2pZ) Non-hybrid master atoms Φ 丄 杂交 Hybrid ya atoms j j -12 -12- This paper is again suitable for China National Engine (CMS) Α4 Specifications (210x297 mm) (Please read the precautions on the back before filling out this page) Pack. -St

A7 B7 V. Description of the invention () In summary, the present invention provides a sprayable water emulsion for treating air and / or direct spraying on specific occasions. The emulsion has: (Please read the precautions on the back before filling (This page) a. — An emulsifier composed of propionic acid that is a hydrophobically modified cross-linked polymer; and b. — Or more compounds selected from the following: * — a bivalent metal ion complex with SP3 hybridization Compound and two deodorants each having a molecule selected from the group consisting of a hydroxyl group, a carbonyl group, and an aldehyde group; * an insoluble or low water-solubility insecticide; * an insoluble or low water-solubility inhibitor; and * Insoluble or low water-soluble fragrance. According to its particularly favorable sprayability, its viscosity is between 10 centipoise (CPs) and 1,000 cPs, preferably between 10 cps and 200 cPs, and between 50 cps and 150 cPs. good. The emulsion printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs may contain surfactants such as cetyl dimethyl polysiloxane copolyol at a concentration of 0.1% to 1%. The addition of this agent results in a decrease in surface tension which will reduce the viscosity of the emulsion accordingly. As for the deodorant, the molecule of the pseudohydroxycarbonyl acid family of the molecule is preferably 12-hydroxy-octa- [9-bronic acid (ricinoleic acid). The deodorant preferably has a pseudo concentration of 0.05% to 30%, more preferably 0.05% to 3%, and most preferably 0.5% to 1.5% of the bis- (12-hydroxy-octa- [9] -nonenoate zinc (M zinc linoleate). In addition, the concentration of emulsifier should be between 0.05% and 2%, preferably 0.05% to 0.4%, and most preferably 0.1% to 0.2%. -6- Paper The Zhang scale is applicable to the Chinese National Standard (CNS) A4 specification (210 × 297 mm) Λ7 η 7 V. Description of the invention () Non-hybrid state sulfon atoms can be combined with other molecules or atoms such as hydrogen atoms to form carbene c Η 2 . It is a pity that the molecule is extremely active. Common species pseudo CH «, 卽 methane. The reason for this phenomenon is that the two electrons in the 2s orbital are separated and one of them rises to the 2pz orbital. This will consume energy. , But is completely compensated by the generation of two additional CH bonds. Therefore, the CH4 molecule is formed. Each orbit has two electrons and is in its inert gas structure. All orbits and all bonds have the same energy. The formation has equal energy Order hybrids: this 卽 SP3 hybridization. Some ligands with paired free electrons can account for The empty orbit of the system with a few electrons, in other words, once the system has a pair of extra electrons in common, its energy is higher. Even if the complexes produced are completely different, the total charge remains. Unchanged. One example is pseudo Zti "ions. If Zn 2 ♦ ions have several additional occupied orbitals, their energy is more absorbable. Systems such as HH3, H3S, CN-, or SNC · can provide a pair Electrons. The pair of electrons will then occupy the empty orbits of the Z η 2 f ions. Four orbitals can be occupied: one s orbital and three orbital P orbitals. All orbitals are arranged to have the same energy: this also constitutes One of the factors of the hybridization of SP3. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs—1. —— m J—-III id I. n. F (Please read the precautions before filling this page) Divalent metal (SP3) or trivalent metal (d2sp3) -bound molecules also need to meet certain conditions. In theory, any ion or molecule with excess electrons can be coordinated with the aforementioned coordination metal ion, such as Z η 2 * Ions can absorb nitrogen, Sulfur, oxygen, phosphorus, gas, bromine, gas, iodine, boron, tellurium, selenium, arsenic, or antimony, etc. This absorption is an exchange process. To achieve an effective exchange, the original Z η 2 * The complex must be based on the use of the original with a weaker stability constant. 1 3- This paper size is applicable to China National Standards (CNS) Λ4 present (210X297). Printed by the staff of the Central Bureau of Standards, Ministry of Economic Affairs, for consumer cooperation. A7 B7 V. Description of the invention (4) The concentration of the pesticide 傺 is between 0.001% to 10%, preferably 0.01% to 1%, and it is best to fake 0.1% to 0.5 %. The concentration of fragrance is between 0.Q1% and 30%. The concentration of the bacteriostatic agent is between 0.05% and 5%, preferably 0.1% to 1.0%, and most preferably 0.5%. According to the effective properties of the present invention, the emulsion may contain a concentration of 0.0190 to 2%, preferably 0.05% to 1%, and most preferably a pseudo-0.1% to 0.5% neutralizer. The neutralizing agent is preferably ammonium sulfonate or ammonium hydrogen sulfonate. The invention also provides the use of the emulsion in a soot device, which is suitable for converting the emulsion into a gas phase in the atmosphere for air treatment in the place. In addition, the present invention describes a method for introducing the emulsion into a gas phase, wherein the emulsion is sprayed on a surface heated above the evaporation temperature of the emulsion. The invention will be described in detail below, including the ingredients of the emulsion, the specific manner in which the emulsion is used, and the equipment available for the application of the emulsion. Emulsifier The emulsifier used in the present invention 傜 hydrophobically neutralizes the acrylic resin of improved resin. Resin-based polymers make the emulsifier a polymer emulsifier. Polymer emulsifiers of this type will obtain very low viscosity emulsions with very small amounts of emulsifiers. This emulsifier is hereinafter referred to as "emulsifier". The concentration of emulsifier is between 0.05% and 2%. However, a range of 0.1% to 0.2% is preferred. The resulting emulsion is pseudo-highly stable emulsion. Emulsifier 僳 is made in the form of gel containing 0.2% emulsifier and the rest is water. Emulsifiers are like sponges that absorb water. The gel is divided by the water-stained gel. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) ΙΊ--II--nn -r * I-:-! Order (please read the note on the back first) Please fill in this page again for details) Α7 Β7 Year 5. Description of invention () (Please read the notes on the back before filling in this page) The weak coordination matrix of the child. The stability of most complexes is greater than that of hydrogen-containing complexes, so gas atoms are the most appropriate. This is the first condition that the coordination matrix must meet. The conditions that the coordination matrices must meet: they must remain entangled with zinc coordination ions after the exchange process. A suitable coordination matrix must be a molecule with two sites that can bind to Zri coordination ions. This is the second condition that the coordination matrix must meet. In theory, several molecules are suitable for this condition: * hydrocarbon carboxylic acids; * dicarboxylic acids; * glycols. Another condition is that the exchange of the coordinating matrix after an exchange action stops, and it is not suitable to form a second exchange body. This is the third condition that the coordination matrix must meet. Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs In addition, the final complex formed is best to be non-negatively charged. In this case, diols and dicarboxylic acid esters are considered unsuitable because they injure negatively charged persons. As a result, a dioxycarboxylic acid ester was the most suitable. Ricinoleate actually belongs to this category, as does lactic acid salts. In combination with the above conditions, only long-chain hydrocarbon carboxylic acids can function normally. There are only a few suitable molecules on the market, and ricinoleic acid is the most important in terms of commercial value. Therefore, zinc ricinoleate is the most desirable molecule, but from a molecular point of view, there are still other suitable ones. Therefore, it is preferable to use 0.05% to 30%, 0.05% to 3%, and it seems that zinc ricinoleate at a concentration of 0.5% to 1.5% is used in the aqueous emulsion of the present invention. Can be made at the optimal concentration (0.5% to 1.5%). Easy to print. The paper size is applicable to China National Standards (CNS) Λ4 specifications (210X 297 mm). A7 B7 Printed by the Consumers' Cooperative of the China Standards Bureau of the Ministry of Economic Affairs. V. Description of the invention (5) The form of a substantially viscous liquid composed of agglutination of 1 1 seeds exists. Traditional milk 1 1 can be used to prepare oil emulsions in water, while those which are pseudo-water-soluble. Emulsions made with milk emulsifier are insoluble in water> Only the emulsifiers and water can be used. 1. Gel dissolves. It forms a water-containing molecule that can be combined with oil at the same time. Read 1 I Read I Combined water-repellent emulsifier a So oil, 'τώ; m will be trapped between the gel molecules. Back fir 1 | In order to understand how the viscosity of emulsifiers and emulsions is reduced according to the present invention > Note 1 | It is necessary to analyze the chemical structure of the emulsifier used in more detail. Copolymer consisting of a block and an alkyl methacrylate block. This polymer will be completely soluble in water without going through other procedures 9. No · Page 1 I However * Add a third raw material during the polymerization process * Wait for %% Crosslinking agent to form a three-way 1 lattice »Make it no longer complete dissolve in water 0 but make 1 f in this way The particles contain a large amount of hydrophilic matrix * Although the resin formed is no longer completely soluble in water, it is quite hydrophilic > absorbs water and is like a sponge 0 acrylic is pseudo-hydrophilic * carboxylic acid groups pass through It is more hydrophilic after the 〇1 1 each carboxylate anion can bind to about 20 値 water molecules. Although there are also> s ^ sp 1 Ⅰ all hydrophobic methacrylate block exists. When the 1 1 antimony 1 hydrophobic substance, such as oil droplets, and the block m of the academic methacrylate are connected to Am m, it will be blocked from moving. Therefore, 9 oil droplets will be covered by gel particles. 9 None 1 I method combined with other oil droplets 〇 They In fact, they are separated by each other. This process is called 1 stabilizing by 1 * the oil droplets are prevented from moving 1 1 by the gel particles anchored by each other. The oil droplets are stabilized to a certain extent. 9 In other words, 01 forms a water emulsion. 1 | It has been found that this type of emulsifier has a second retention characteristic that is in contrast to the geometric structure of the gel particles. 1 It assumes the form of a non-crosslinkable polymer chain. 0 1 1 This bond structure will not be possible. Avoid making -8 the chain connection. 01 1 1 1 1 This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm). Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. A7 B7. 5. Description of the invention (6) Generally speaking, the source of emulsification of the oil body and the specific emulsifier has two sources: three-dimensional stabilization and anchoring between particles. Therefore, the emulsification capacity 傜 is determined by the three-dimensional stability and the degree of entanglement. So far it is unknown how many "entangled bonds" are present in the gel structure. However, it is known that at least a minimum amount of such a bond is necessary to provide an emulsion. The relationship between the gel particles and the oil droplets, and between the gel particles themselves, can be expressed as follows:

One of them can directly determine the parameter 傜 viscosity of particles' mutual falsehood; the more the number of entangled bonds, the higher the viscosity. The viscosity can then be influenced by changing the number of bonds between the gel particles. However, if the number of particles is excessively reduced, the emulsion will lose its stability. In order to reduce the number of entangled bonds, the present invention describes a method that uses the moderate mixing of the emulsifier to achieve the effect of breaking the entangled bonds of the entangled portion. This can be large -9- This paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) Ι m »1 -I-II ----- I- 1 Yiyi I --- 1 --- ...... ..... (Please read the notes on the back before filling out this page) A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (7) 1 1 Decrease The viscosity of the emulsion can then be carried out in 11 spraying operations at a pressure close to atmospheric pressure. 1 In addition, the sprayability of the 9 emulsion is another important feature of the present invention. 1 Please change it > Limit spraying The particle size of the particles is also very important in a narrow range. Read 1 I Read 1 0 The particle size distribution is pseudo-Gaussian. ♦ The width is mainly determined by two parameters. Back 1 I 1 卽 1 viscosity and surface tension. Invention 傜 Add a surfactant to the emulsion. Note 1 to reduce the surface tension of the bottom »Especially like Th. G c Id SC hnidt company manufactures and sells the item I and 1 I ABI L HM90 cetyl dimethicone copolyol. This kind of substance can reduce 1 surface tension while maintaining the stability of the emulsion. This copolymerization Alcohol also has page 1 I Two effects can repair part of the broken head in a mountain ridge mixing operation m bond 0 1 1 So using the above stirring operation can destroy the entanglement bond, and then add a surfactant to make Repair of the same m-bond part * Can accurately measure the viscosity of the emulsion. The degree of order 9 can also reduce its surface tension9. Therefore, the particle size of the particles is limited to a very small range < 5 1 1 Agent $ insecticide * or bacteriostatic emulsion for surface 1 1 active agent concentration in the range of 0% to 0.296 9 and for milk containing deodorant! 1 line i liquid 9 The concentration is in the range of 0.3% to 0 Λ%.% Of the present invention. A special neutralizer is added to the emulsion to provide the function of the type of neutralizer used. ≫ The pH of the emulsion The value is adjusted to 6 to 8! 1 Range 0 The effect of using a neutralizer is to increase its ability to absorb water. Macro 1 1 In terms of view »This can greatly reduce its viscosity. 1 and agent> but it has a small amount of diethanolamine 9 can form 1 commonly known as nitrosoamine 1 1 nitrogen-containing concentrate * 傜 a local carcinogen. The present invention chooses to use m 1 1 acid m (caustic soda ） »M ammonium acid» or type of neutralizer such as nitrogen carbonate paper 〇 1 1 -10- 1 1 1 This paper size applies to China National Standard (CNS) A4 specification (210X297 mm)

V. Description of the invention () Ammonium sulfonate and ammonium hydrogen sulfonate are preferred in the printing of employee cooperatives of the Central Bureau of Standards of the Ministry of Economics because they can be thermally decomposed into harmless substances as follows: (HHi) zC〇3-> 2NH3 + COa + HaO NH4HCO3-> NHs + COa > H2〇 All reaction products are environmentally friendly gases. In any case, the above neutralizers are not the only ones available. Any substance capable of extracting protons from a carboxylic acid group is suitable. The degree of neutralization agent is between 0.01% and 2%, preferably 0.05% to more preferably, (K1% to 0.5% is the best. Deodorant is suitable for the aqueous emulsion emulsion-like zinc ricinoleate of the present invention, which is Zn2 * The complex of ions with two molecules that neutralize M linoleic acid. Its chemical name is 12-hydroxy-octadecyl- [9] -nonenedioic acid. The chemical formula is C18H34〇3. Zinc ricinoleate is harmless to the environment Its deodorizing properties. Zinc itself is not harmful to the environment. Castor oil acid is obtained from the fatty acid of castor oil. The preparation of free acid is made by separating the original fatty acid and glycerol after the hydrolysis of sesame oil. Finally, the original acid It is purified by various appropriate technologies. Ricinoleic acid is a kind of special acid, which is a kind of fatty acid that accepts hydroxyl groups on its main store. Hydroxy fatty acids are found in all living things in nature, but the amount is extremely rare.分子 A molecule with multiple cabinet electrons, which has a hydroxyl group and a carboxyl group. Ricinoleic acid is a hydroxycarboxylic acid. M zinc linoleate is a preferred deodorant in the present invention, but there are other deodorants with different chemical formulas. .M zinc linoleate There are complexes of divalent metal ions, especially 傺 Zη2 * and two molecules of ricinoleic acid ion. The " 11-nm I ϋ nn HI n 丨 peak ^ 丁 3 ^ 言 (Please read the precautions on the back before (Fill in this page) This paper size applies to Chinese National Standard (CNS) Λ4 specification (2 丨 0X297 mm)

Metal ions and molecules printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs can be changed, and the conditions must correspond to a high degree of pending demand. The metal ion must be a polyvalent metal ion, but a divalent gold sulfonium ion with SP3 hybridization is preferable. A metal ion with SP3 hybridization can bond four ligands, which means that the bonding force has the same characteristics as the ligands. For example, a zinc atom has thirty electrons, and the two outermost electrons are in a non-hybrid state in the 4s orbit. When the second europium electron of 4s orbital is ionized, Zn europium ion will be formed. The favorability of Zn2t ions: the energy of the 4p orbital is lower than that of the 3d orbital. As a result, the Zn "ion can cooperate with Sijian's molecules with multiple europium electrons. Although the s and p orbital energies are different, quantum mechanics requires the sp 3 hybridization of the four europium orbitals to be the same and have the same energy level. That is, the reason that Zn2 + ions can provide coordination bonds with four identical coordination matrices. However, the Zη "ion is not the only one with sp3 hybrids. Shop and mercury also meet the above conditions. Nevertheless, this metal is extremely harmful to the environment and human beings, so it is quite difficult to apply it to the deodorant for spraying cloth of the present invention. Shop or mercury can be used in closed systems for external regeneration. D2sP-type crosses such as those occurring in specific transition metals such as cobalt, iron, chromium, and thallium may also occur. Therefore, all gold ions with sp3 or d2sp3 hybridization can be used in the complex of deodorant. In order to make the explanation of hybridization clearer, the following will explain the distribution of electrons in the orbits of the broken atom and the column showing the master atom. {Is} {2s} {2px} (2py) (2pZ) Non-hybrid master atoms Φ 丄 杂交 Hybrid ya atoms j j -12 -12- This paper is again suitable for China National Engine (CMS) Α4 Specifications (210x297 mm) (Please read the notes on the back before filling this page). -St Λ7 η 7 V. Description of the invention () The sulfon atom in the non-hybrid state can be combined with other molecules or atoms such as hydrogen atoms. Combined to form carbene c Η 2. Unfortunately, the molecule is extremely active. Common species Pseudo-CH «, Methane. The reason for this phenomenon is that the two electrons in the 2s orbit are separated and one of them rises to the 2pz orbit. This consumes energy, but is completely compensated by the generation of two additional CH bonds. The CH4 molecule is thus formed. Each orbit now has two electrons and is in its inert gas structure. All orbits and all bond bodies have the same energy. Formation of hybrids with equal energy levels: This 卽 SP3 hybridizes. Some coordination matrices with pairs of free electrons can occupy empty orbits of the system with a few electrons, in other words, the system has a higher energy once it has a pair of extra electrons in common, even if the error Compounds with completely different materials still have the same total charge. One example is a pseudo Zti "ion. If the Zn 2 ion has several additional occupied orbitals, its energy is more absorbable. Systems such as HH3, H3S, CN-, or SNC · can provide a pair of electrons. The The pair of electrons will occupy the empty orbits of the Z η 2 f ion. There are four orbitals to occupy: one s orbital and three orbital P orbitals. All orbitals are arranged to have the same energy: this is also the SP3 hybrid One factor. Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs—1. —— m J—-III id I. n. F (Please read the precautions before completing this page) Metal (SP3) or trivalent metal (d2sp3) -bound molecules also need to meet certain conditions. In theory, any ion with excessive electrons or the molecule itself can be coordinated with the aforementioned coordination metal ion, such as Z η 2 * ions can be absorbed Substances containing nitrogen, sulfur, oxygen, phosphorus, gas, bromine, gas, iodine, boron, tellurium, selenium, arsenic, or antimony, etc. The absorption effect is an exchange process. To achieve an effective exchange effect, the original Z η 2 * Complex must be weaker based on use The original value of the stability constant-1-This paper size is applicable to China National Standards (CNS) Λ4 is present (210X297). Α7 Β7 Year 5. Description of the invention () (Please read the notes on the back before filling in this Page) Weak coordination bases. Most of the complexes are more stable than hydrogen-containing complexes, so the gas atom is the most appropriate. This is the first condition that the coordination base must meet. The conditions that the matrix must meet: after the exchange process, they must be entangled with zinc coordination ions. A suitable coordination matrix must be a molecule with two sites that can bind to Zri coordination ions. This is the coordination matrix The second condition that must be met. In theory, there are several molecules suitable for this condition: * hydrocarbon carboxylic acid; * dicarboxylic acid; * diol. Another condition is that the ligand stops the exchange after an exchange action. It is not appropriate to form a second exchange body. This is the third condition that the coordination matrix must meet. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. In addition, the final complex formed is preferably a non-negative charge. In this case Due to glycols and dicarboxylic acid esters Those who are negatively charged are considered unsuitable. As a result, dioxycarboxylic acid esters are the most suitable ones. Castor oleate actually belongs to this category, as is the salt of lactic acid. Based on the above conditions, only long-chain hydrocarbon carboxylic acids can be used. Normal. There are only a few suitable molecules on the market. Ricinoleic acid is the most important in terms of commercial value. Therefore, zinc ricinoleate is the most desirable molecule, but from a molecular point of view, there are still other suitable ones. 0.05% to 30%, 0.05% to 3% is preferable, and zinc ricinoleate is preferably used in the aqueous emulsion of the present invention at a concentration of 0.5% to 1.5%. At the optimal concentration (0.5% to 1.5) %) Can be made easy to spray this paper size suitable for China National Mou (CNS) Λ4 specifications (210X 297 mm)

A7 _B7___ 5. Description of the invention (l2) Water emulsion of cloth, and water emulsion containing more than 10% of zinc linoleate is suitable for storage and subsequent dilution (explained in detail below).爰 Refer to the following theoretical diagram to illustrate the retention effect of the deodorant (M zinc linoleate).

The left side of the figure shows Zη ions that are bound to two molecules of ricinoleic acid. The end of each ricinoleic acid molecule is terminated by a hydroxyl group and a carboxyl group. R3N | represents a odorous molecule with a base skeleton bonded to a nitrogen atom.氤 傜 Using three electrons to combine with the three 艏 matrix R, so a free electron pair remains, represented by the straight line after H. Matrix R alkyl or other matrix which can be combined with a single nitrogen electron. One example is triethylamine which pseudo-smell. Referring to the right part of the figure, a portion of one end of the M linoleic acid molecule and the Zn2 + ion bond has been broken and replaced by an odor molecule bound to the Zn2f ion through a free electron pair of a nitrogen atom. Because the gas atom of the hydroxyl or carboxyl-bonded ion provides a weaker ligand than the nitrogen in the odorous molecule R3H, the Chinese national standard (CNS) A4 specification (210X297 mm) is applicable to this paper size. &Quot; : N. —, Form JII — III —rw (Please read the notes on the back before filling out this page) Printed by the Employees' Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs Printed by the Consumers ’Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs Printed A7 B7 5. Description of the invention (l3) is the result of the exchange effect. The retention effect of ricinoleic acid group is very effective, because one molecule of ricinoleic acid can bind to a group of odorous molecules. Insecticides Any insoluble or low-water-soluble insecticides mixed with emulsified moth can be used. However, it is best to use environmentally friendly pesticides. A particularly suitable insecticide is 2- (4-ethylaminophenyl) -2-methylpropyl-3-phenylaminobenzyl ether. This compound contains only sulphur, hydrogen, and gas atoms, and does not contain coffin toxicity and extremely low toxicity to 晡 milk animals. This chemical formula is c35H28〇3. The compounds are only slightly soluble or completely insoluble in water, making their solubility less than one part per billion. The above-mentioned insecticide or other appropriate insecticide may be mixed at a concentration of 0.001% to 10%, preferably 0.01% to 1%, and preferably at a concentration of 0.1% to 0.5%. Aqueous emulsion Aqueous emulsion made of deodorant or the above-mentioned insecticide and emulsifier at a specific concentration has a low viscosity of as low as 10 CPS, so that the aqueous emulsion can be sprayed with small droplets. For example, an aqueous emulsion with 1% zinc ricinoleate and 0.2% emulsifier (the remainder is water) is completely suitable for spraying applications. However, water emulsions containing more than about 10% zinc ricinoleate and 0.2% of the emulsifier are not suitable for spraying, but are only available for storage for subsequent dilution. This retentivity is very important because it keeps the volume of the water emulsion small during lotus infusion and storage. Aqueous emulsions need only be diluted with a suitable diluent during use. This reduction in cross-products has commercial value. According to the present invention, the above-mentioned aqueous emulsion may contain emulsified emulsion of undetermined concentration. The size of the paper is applicable to China National Standard (CNS) A4 (210X297 mm) I .-----------, ¾ ---- --- Order ------ line (please read the precautions on the back before filling this page) Printed by A7 _B7 ___, the consumer cooperation of the Central Procurement Bureau of the Ministry of Economic Affairs V. Description of the invention (14) Gel of the agent Diluted, the emulsifier has the hydrophobic neutralizing modified acrylic polymer that has been used in the above-mentioned aqueous emulsion. For example, a typical gel composition has the emulsifier of 0.2¾ and the rest is water. The ability of a gel-diluted aqueous emulsion is an advantageous feature of the present invention, which can be used to store the aqueous emulsion at a high concentration. It is assumed that the existing aqueous emulsion contains 10% of pesticides or zinc ricinoleate and 0.1%. 2% of the emulsifier. To obtain a diluted water emulsion with no more than 1% pesticide or zinc ricinoleate, one part of the 10% water emulsion and nine parts of the gel containing 0.2% of the emulsifier and the rest Blended for water. Diluted water emulsions can only be used without any pending equipment It is made by mixing its components. General mixing equipment such as a stirrer is used. Therefore, the aqueous emulsion of the present invention can be diluted under the condition of little difference in emulsifier ingredients, that is, the emulsifier concentration is between about 0.2% to 〇 4%. In addition, the present invention not only prepares an aqueous emulsion made of a specific emulsifier and deodorant, but also an aqueous emulsion made of the same emulsifier and fragrance or bacteriostatic agent. The fragrance is sufficiently hydrophobic, Aqueous emulsions with aromatics can be made by using the emulsifier. In this way, aqueous emulsions of aromatics with low viscosity as low as 1QcPs can be made. The aqueous emulsion can then be sprayed with fine droplets. Can be made Fragrance aqueous emulsions with 0.01% to 30% fragrance. However, the fragrance concentration in the final aqueous emulsion that is available for use should preferably be between 4% and 5%. As for the bacteriostatic agent, terpineol can be used, especially傜 Mutinol, a kind of sesqui.terpene, which is not heavy in taste, is not noticeable when combined with an aqueous emulsion containing fragrances. The concentration of mutinol can range from 0.5% to A range of 5%, preferably from 0.01% to 1.0%, False -17-~ __ _ —. This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) I: ---_-- r ------ ί ------ : Order I ------ Line I {Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs A7 _B7 _ V. Invention Description (i5) 5%. Due to the above-mentioned search and mixing process and the surfactants and neutralizers that may be added, a pesticide water emulsion with a viscosity in the range of 2QcPs to 1QQcPs can be obtained. Another surprising feature of the present invention is that the aqueous emulsion of a deodorant further comprises a stable mixture of a fragrance aqueous emulsion and an emulsifier. Two aqueous emulsions can be combined, one of which has a deodorizing effect, and the other has an off-gas, and the concentration of the emulsifier used in the condition is not much different. In addition, the above-mentioned aqueous emulsion may further include a dilute and stable mixture containing an emulsifier for diluting the aqueous emulsion. The upper water emulsion can also include the following stable mixtures: * water emulsion containing fragrance and emulsifier; * water emulsion containing bacteriostatic and emulsifier, and * dilute gel containing water and emulsifier. The aqueous emulsion of the present invention can be mixed together and diluted with a gel. The only condition that must be met: The added water emulsion and diluted gel should use the same emulsifier at the same concentration. When using the same emulsifier, especially the above-mentioned polymer emulsifier, several types of water emulsions can be made: 1 / an aqueous emulsion containing zinc ricinoleate and the emulsifier; 2 / —a fragrance containing the emulsifier and the emulsifier Water emulsion; 3 /-a water emulsion containing a bacteriostatic agent and the emulsifier; 4 / a water emulsion containing a pesticide and the emulsifier; and 5 /-a diluted gel containing the emulsifier and water . In the above four kinds of water emulsions and gels, the concentration of emulsifier is about 2.0%. _ 18 _ This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) I! IIIIIIIIIII Order — III line (please Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 0 U <; 〇 Α7 _Β7 ___ V. Description of invention (Ιό). Using these five substances (four aqueous emulsions and one gel), a combined emulsion with a uniform structure can be prepared. The four aqueous emulsions can be made with high concentrations of zinc ricinoleate, fragrance, bacteriostat, and insecticide, and the diluted gel is used as a diluent to reduce and set the zinc ricinoleate, fragrance, and inhibitor. The concentration of the bactericide and insecticide is to reach a predetermined value. Therefore, starting from the above four types of aqueous emulsions, only a mixture of each aqueous emulsion and a diluted gel can be used to make a combined aqueous emulsion. EXAMPLES It is assumed that there are three types of shrinking emulsions, namely water emulsions for storage and lotus infusion, which respectively contain: * 10% zinc ricinoleate; * 20% fragrance; and * 5% bacteriostatic agent. If you want to prepare an aqueous emulsion containing: »1% zinc ricinoleate; * 4% fragrance; and« 0.2% bacteriostatic agent. It can be made by mixing 10 parts of zinc ricinoleate-containing water emulsion, 20 parts of fragrance-containing water emulsion, and 4 parts of bacteriostatic agent-containing water emulsion, together with 6S parts of diluted gel. This example shows that varying the amounts of the basic aqueous emulsion and gel can be made into a combined aqueous emulsion that provides the aforementioned uses. The same method is also applicable to a combination of an aqueous emulsion containing an insecticide and an aqueous emulsion containing a fragrance or a bacteriostatic or deodorant. Contains only zinc ricinoleate and / or fragrance and / or bacteriostat or insecticide-19-(Please read the precautions on the back before filling out this page) This paper size applies to China National Standard (CNS) Α4 size (210 '乂 297mm） t) OU t > 1 / A7 _ B7 _ V. Description of the invention (17) The diluted water emulsion of the agent has a lower viscosity due to the emulsifier and search technology used, so it can be combined Water emulsion was sprayed. The aqueous emulsion can be sprayed by any spraying device such as a pump or an aerosol valve. Spray water emulsions can be applied directly to places that emit odors, such as household waste bins or parts to be disinfected. The effect of spraying water emulsion is to eliminate the odor emitted from the site or to eliminate insects. However, one of the more preferable uses of the present invention is to apply an aqueous emulsion, and a water emulsion containing a deodorant and / or fragrance to a soot device, which can be turned into a gas phase to diffuse into the air for air deal with. A suitable smoking device is described in EP-A-0 0 0 0 0 0 60 or French patent application No. FR-95 01037. The cigarette smoke device pseudo-sprays the water emulsion in a separated manner onto a selling surface heated above the evaporation temperature of the water emulsion, so that the water emulsion is immediately evaporated into a gaseous state, that is, a change in phase state. For zinc ricinoleate, for example, the evaporation temperature must exceed 250 ° C. The benefit of using the aqueous emulsion of the present invention is that it is highly aqueous. The water emulsion in the above example contains nearly 95% of water, and it is known that the expansion coefficient of water is 1,530. Therefore, zinc ricinoleate, fragrance, and bacteriostatic agent can be widely diffused into the air of the treated place. Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) The advantage of the present invention is not limited to the water emulsion itself and the mixing ability of the water emulsion with other water emulsions with the same emulsifier It also includes the benefits of the water emulsion or combination water emulsion in a fumigation device. ^ In the above content and the scope of the following patent applications, all percentages refer to weight percentages. -20-This paper size applies to China National Standard (CNS) Α4 specification (210 × 297 mm)

Claims (1)

The Central Bureau of Standards, Ministry of Economic Affairs, Shellfish Consumer Cooperation Du Yin ¾ Patent No. 85111174 Amends the scope of patent application on July 88, Republic of China 1. A sprayable deodorant water emulsion, which is used to treat air in specific places and / Or a direct applicator, the aqueous emulsion is pseudo-characterized by the following composition: a.-An emulsifier composed of acrylic acid of a hydrophobically modified cross-linked polymer; and b.-Or more compounds selected from the group consisting of: * A deodorant composed of a bivalent metal ion complex with sp 3 hybridization and two molecules each having a dibasic group selected from a hydroxyl group, a carbonyl group, and an aldehyde group; * an insoluble or low water-soluble insecticide; * Insoluble or low water-soluble bacteriostatic agents; and * Insoluble or low water-soluble fragrances. 2. The water emulsion described in item 1 of the patent application, whose viscosity 傺 is in the range of 10 centipoise (cPs) to 1,000 cPs. It is preferable to use lOcPs to 200 cPs, and it is best to hurt 50 cPs to 150 cPs. 3. The aqueous emulsion as described in item 1 or 2 of the scope of the patent application, further comprising a surfactant, such as cetyl dimethyl polysilazane copolyol. 4. The water emulsion as described in item 3 of the scope of patent application, where the table-1-(please read the precautions on the back before drawing) -¾. 丨 order --fi ^ I ------ ----------I This paper size is applicable to China National Standard (CNS) M specifications (210X297 mm) The Central Bureau of Standards, Ministry of Economic Affairs, Shellfish Consumer Cooperation Du Yin ¾ Patent No. 85111174 Amends the scope of patent application on July 88, Republic of China 1. A sprayable deodorant water emulsion, which is used to treat air in specific places and / Or a direct applicator, the aqueous emulsion is pseudo-characterized by the following composition: a.-An emulsifier composed of acrylic acid of a hydrophobically modified cross-linked polymer; and b.-Or more compounds selected from the group consisting of: * A deodorant composed of a bivalent metal ion complex with sp 3 hybridization and two molecules each having a dibasic group selected from a hydroxyl group, a carbonyl group, and an aldehyde group; * an insoluble or low water-soluble insecticide; * Insoluble or low water-soluble bacteriostatic agents; and * Insoluble or low water-soluble fragrances. 2. The water emulsion described in item 1 of the patent application, whose viscosity 傺 is in the range of 10 centipoise (cPs) to 1,000 cPs. It is preferable to use lOcPs to 200 cPs, and it is best to hurt 50 cPs to 150 cPs. 3. The aqueous emulsion as described in item 1 or 2 of the scope of the patent application, further comprising a surfactant, such as cetyl dimethyl polysilazane copolyol. 4. The water emulsion as described in item 3 of the scope of patent application, where the table-1-(please read the precautions on the back before drawing) -¾. 丨 order --fi ^ I ------ ----------I This paper size is applicable to China National Standard (CNS) M specification (210X297 mm). The concentration of E6 F6 surfactant is in the range of 0.1% to 1%. (Please read the precautions on the back before drawing) 5. The water emulsion as described in item 1 of the aforementioned patent application, where the molecule is a molecule of the hydroxycarboxylic acid family, preferably 12-hydroxy-octa- [9 ] -Nonenoic acid (S linoleic acid). 6. The aqueous emulsion as described in item 1 of the aforementioned patent application range, wherein the deodorant is bis- (12-hydroxy-octa- [9-bronenyl bis (zinc) (castor oil p-zinc). The aqueous emulsion according to item 1 of the scope of the patent application, wherein the concentration of the emulsifier is in the range of 0.05% to 2%, preferably 0.05% to 0.4%, and more preferably 0.1% to 0.2%. The water emulsion according to item 1 or 6 of the scope of the patent application, wherein the concentration of the deodorant is in the range of 0.05% to 30%, preferably 0.05% to 3%, and most preferably 0.5% to 1.5%. Printed by the Ministry of Standards and Staff ’s Consumer Cooperatives 9. The water emulsion as described in item 1 of the aforementioned patent application range, where the concentration of the pesticide is pseudo range between 0.001% and 10%, preferably between 0.01% and 1% Preferably, it is 0.1% to 0.5%. 1 10. The water emulsion according to item 1 or 9 of the aforementioned patent application scope, wherein the insecticide is 2- (4-ethoxyphenyl) -2-methyl Propyl 3-benzyloxy benzyl ether. -2- This paper size applies to China National Standards (CNS) A4 (210X297 mm) E6 F6 in its liquid IU? Water. 1 ¾ 30th to Fan% Li 01 Special 0. Please be as strong as possible before applying for the introduction. 11 doses of Xiangfang Di to Fan %% J 5 0 «ο ^ Special ο.π Please be false. The former degree is as strong as possible. Take 12 doses which can inhibit the bacteria.% 1 ο 1-to liquid% of milk 1 water S of the range described in the item ¾ suppress the liquid milk 2 2 of the range Fan Li special request. Shen Jingru oil. Pine 3 i 1 Vulgar concentration of vulgar agent is concentrated to% Wei Fanli / 6. Special 2 agents please go to He Shen ¾ before 01 ο% as in 5. Introduction 丨(Please read the precautions on the back first, and then draw the picture.) Packing. The items to the package are good, the most liquid, and the milk can be compared with the above. ¾ The liquid and milk in the above mentioned item 4 1- No. Ammonium vanadic acid is specially requested or applied for ammonium as acid. Master 15 series agent, and ιτο printed by the Central Standards Bureau of the Ministry of Economic Affairs, Consumer Cooperatives, this paper is printed in accordance with China National Standards (CNS) A4 specifications (210 > < 297 mm)