TW311090B - - Google Patents
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- TW311090B TW311090B TW082110246A TW82110246A TW311090B TW 311090 B TW311090 B TW 311090B TW 082110246 A TW082110246 A TW 082110246A TW 82110246 A TW82110246 A TW 82110246A TW 311090 B TW311090 B TW 311090B
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- Taiwan
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- 239000003921 oil Substances 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 20
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 16
- 239000000194 fatty acid Substances 0.000 claims description 16
- 229930195729 fatty acid Natural products 0.000 claims description 16
- 150000004665 fatty acids Chemical class 0.000 claims description 16
- -1 carbon alcohol ester Chemical class 0.000 claims description 14
- 239000003945 anionic surfactant Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 239000003792 electrolyte Substances 0.000 claims description 8
- 238000007046 ethoxylation reaction Methods 0.000 claims description 7
- 229920006317 cationic polymer Polymers 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 5
- 239000002736 nonionic surfactant Substances 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 125000000129 anionic group Chemical group 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 229920000151 polyglycol Polymers 0.000 claims description 4
- 239000010695 polyglycol Substances 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 238000010561 standard procedure Methods 0.000 claims description 3
- 150000004820 halides Chemical class 0.000 claims description 2
- 229910001508 alkali metal halide Inorganic materials 0.000 claims 1
- 150000008045 alkali metal halides Chemical class 0.000 claims 1
- 235000019198 oils Nutrition 0.000 description 32
- 150000001875 compounds Chemical class 0.000 description 20
- 210000003491 skin Anatomy 0.000 description 15
- 239000004615 ingredient Substances 0.000 description 13
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- 239000004094 surface-active agent Substances 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 8
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- 229920000642 polymer Polymers 0.000 description 6
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 5
- 239000002202 Polyethylene glycol Substances 0.000 description 5
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- 239000000126 substance Substances 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical group CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000004166 Lanolin Substances 0.000 description 3
- 102000004882 Lipase Human genes 0.000 description 3
- 108090001060 Lipase Proteins 0.000 description 3
- 239000004367 Lipase Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
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- 239000003205 fragrance Substances 0.000 description 3
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- 235000019421 lipase Nutrition 0.000 description 3
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- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- 241000254173 Coleoptera Species 0.000 description 2
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- 241000282372 Panthera onca Species 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
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- 235000012716 cod liver oil Nutrition 0.000 description 2
- 239000003026 cod liver oil Substances 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical group C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
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- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical class OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 2
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- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- NLMKTBGFQGKQEV-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-hexadecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO NLMKTBGFQGKQEV-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- QGVQOXWNOSEKGM-UHFFFAOYSA-N 2-hydroxyacetic acid;prop-1-ene Chemical compound CC=C.OCC(O)=O QGVQOXWNOSEKGM-UHFFFAOYSA-N 0.000 description 1
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- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- RMTFNDVZYPHUEF-XZBKPIIZSA-N 3-O-methyl-D-glucose Chemical compound O=C[C@H](O)[C@@H](OC)[C@H](O)[C@H](O)CO RMTFNDVZYPHUEF-XZBKPIIZSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 235000019489 Almond oil Nutrition 0.000 description 1
- 244000144730 Amygdalus persica Species 0.000 description 1
- 240000008791 Antiaris toxicaria Species 0.000 description 1
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- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
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- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical class CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 1
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- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
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- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
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- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- JMMWKPVZQRWMSS-UHFFFAOYSA-N isopropanol acetate Natural products CC(C)OC(C)=O JMMWKPVZQRWMSS-UHFFFAOYSA-N 0.000 description 1
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- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-N isovaleric acid Chemical compound CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
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- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- JYTMDBGMUIAIQH-ZPHPHTNESA-N palmityl oleate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC JYTMDBGMUIAIQH-ZPHPHTNESA-N 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
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- 239000010452 phosphate Substances 0.000 description 1
- 230000001766 physiological effect Effects 0.000 description 1
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- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- SATVIFGJTRRDQU-UHFFFAOYSA-N potassium hypochlorite Chemical compound [K+].Cl[O-] SATVIFGJTRRDQU-UHFFFAOYSA-N 0.000 description 1
- 230000001012 protector Effects 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- 239000001944 prunus armeniaca kernel oil Substances 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
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- 235000011803 sesame oil Nutrition 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- KMPHTYSTEHXSTL-UHFFFAOYSA-M sodium;2-hydroxypropanoate;2-hydroxypropanoic acid Chemical compound [Na+].CC(O)C(O)=O.CC(O)C([O-])=O KMPHTYSTEHXSTL-UHFFFAOYSA-M 0.000 description 1
- ILWVKYVRVNWXHL-UHFFFAOYSA-M sodium;2-hydroxypropanoate;octadecanoic acid Chemical compound [Na+].CC(O)C([O-])=O.CCCCCCCCCCCCCCCCCC(O)=O ILWVKYVRVNWXHL-UHFFFAOYSA-M 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
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- 239000003549 soybean oil Substances 0.000 description 1
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- 239000008117 stearic acid Substances 0.000 description 1
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- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 235000020238 sunflower seed Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- JREYOWJEWZVAOR-UHFFFAOYSA-N triazanium;[3-methylbut-3-enoxy(oxido)phosphoryl] phosphate Chemical compound [NH4+].[NH4+].[NH4+].CC(=C)CCOP([O-])(=O)OP([O-])([O-])=O JREYOWJEWZVAOR-UHFFFAOYSA-N 0.000 description 1
- 239000010913 used oil Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
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- 238000005406 washing Methods 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
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經濟部中央標準局員工消費合作社印製 A6 B6 五、發明説明(1 ) 本發明係關於清洗姐合物。更特定地說,本發明係關於 一種所諝的”沐浴-凝膠·’姐合物,其用於清洗人體並傳 送油性成份至皮虜及/或毛髮上。 18明背I 眾所熟知使用油液可以滋潤皮慮。例如,自古便知曉將 油液添加至洗澡水中,藉著散佈油液的一部分至皮虜上Μ 得到保養。製備内含一棰或多種油液和用於形成乳液之界 面活性劑的姐合物以與洗澡水共同稀釋,也是眾所知悉的 〇 過去數十年來,基於經濟的理由,沐浴已變得逐漸流行 ,而做為清洗姐合物的所謂”沐浴-凝膠”亦趨流行。沐 浴凝膠,由於其存在著較高含量的稠化界面活性劑系统和 電解質,通常會因為具有較高的黏稠性而不同於澡液添加 物。為了防止組合物在泡沫形成Μ及污垢溶解化之前就從 皮膚上洗掉,所以沐浴凝膠的高黏稠性是必需的。 將油液包括在沐浴-凝膠的配方中是已知的•這些油液 係選自譬如矽油的相對高分子量油類*和譬如碾物油的相 對低分子量油類* Μ及譬如掠推I酸異丙酯和肉豆蔻酸異丙 酯的油性酯類。在本發明的主文中,低分子量油液是具有 低於4000的分子量者。 在譬如護手箱之類的皮虜產品中,棕相a酸異丙酯和肉豆 蔻酸異丙酯是大家热知當做濕潤劑用的。護手霜是包含著 .................................................................................:袭.......................玎.....................線 (請先閲讀背面之注意事項再埸寫本頁> 本紙張尺度適用中I國家標準(CNS)甲4規格(210X297公釐) A6 B6 ^ll〇9〇 五、發明説明(2 ) Γ#層界面g性劑,或是使用其它配伍著發泡界面活性劑之 橱化劑的非泡性,高黏稠的组合物。 在沐浴凝膠中,因為較高含量的這些油液無法與一般所 用的發泡劑併合•所Μ只能使用低含量的上述低分子量油 液。 —般相信,存在於已知沐浴-凝膠配方中之相對低分子 量濕潤油液的含量尚不足Μ達到所裔的皮嫌滋潤效果。 於是,本發明所面臨的技術性問題是,提供一種發泡姐 合物,其具有適合做為沐浴-凝膠的黏度,並包括著有效 含量的低分子量濕潤油液,且不會因為此一油液而失去產 品的结構。 發明篛诚 我們已經確定上述困難的一部份或者全部都可Μ藉由使 用一種脂肪酸單甘油聚乙二醇醚做為稠化界面活性劑,且 於至少一種譬如具有5-10 HLB值之非離子物的特定等級乳 化劑的存在下,將油性的沐浴凝膠與陰離子界面活性劑互 相配方而加Κ克服。 發明註寸 本發明提供一種水性的沐浴-凝膠组合物,其包括: a ) 10-30S:重量比的陰離子界面活性劑, b) 3-153!重量比的油性成份,該陰雄子界面活性劑對 油液的比率至少為1: 1, 本纸張尺度適用中國國家標準(CNS)甲4规格(210x 297公釐) 裝......................訂.....................線 {請先閲讀背面之注意事項再填窝本頁> 經濟部中央標準局員工消费合作杜印製 311090 經濟部中央標準局員工消费合作杜印製 A6 B6_ 五、發明説明(5 ) C) 卜5X重量比的脂肪酸單甘油聚乙二酵酸’和’ d) 1-5S!重量比的至少一種具5至10之間的HLB值的非 離子界面活性劑。 油桦成份 油性成份是根據本發明姐合物的基本元素。油性成份佔 產品的3-15X重量,其乃提供皮庸滋潤之用。油性成份的 較佳含量是產品的5-10!«重量内的範圃。 咸認為油性成份的功能之一是降低水份從角質層散失。 一般相信其乃透過兩個機轉以達到此作用。一種是將減低 蒸發速率的閉塞層散佈到皮虜的表面。其二是把會保留水 份的非閉塞性親水物質添加至角質中,並使得這些水份對 角霣能夠有效地改麥其生理性質,且產生化粧上所需要的 效果。非閉塞性濕潤物質亦可藉由增進皮虜的潤滑度而發 生作用。 閉塞性和非閉塞性的濕潤劑兩者都可Κ在本發明中生效 。濕潤劑的一些範例是長鐽的脂肪酸、液狀水溶性的聚酵 、甘油、丙烯乙二酵、山梨酵、聚乙烯乙二酵、甲基葡萄 糖的乙氧基化/丙氧基化的醚類(例如:甲基葡萄索-20 )和羊毛酯醇的乙氧併化/丙氧併化的醚類(例如:索 露朗-75 , Solulan-75 )。 一些閉塞性的濕潤劑包括白軟石_、礦物油、蜂蟈、矽 油、羊毛脂和油溶性的羊毛脂衍生物、譬如二十二碳醇, 魚肝油萜和飽和魚肝油萜的飽和及未飽和脂肪醇類、以及 ................................................................................ί裝......................訂................…線 {請先閲讀背面之注意事項再填寫本頁} 本紙張尺度適用中國國家標準(CNS)甲4規格(210x297公货) 經濟部中央標準局員工消费合作杜印製 A6 B6_ 五、發明説明(4 ) 各種的動物油或植物油,譬如杏仁油、花生油、麥芽油、 亞麻油、賀賀巴油、杏核油、胡核油、掠彳:關油、阿月渾子 油、芝麻油、.油菜子油、榴豳油、玉米油、桃核油,、嬰 粟油、松油、狸油、黃豆油、鱷梨油、紅花油、椰子油、 II實油、橄攬油、葡萄子油和向日葵子油。 油性成份較好是非-閉塞性的濕潤劑。 非-閉塞性的濕潤劑的範例包括肥酸、乳酸、油酸、硬 脂酸、異硬脂酸、肉豆蔻酸或油布酸的十六碳酯、肉亘蔻 酯、異癸酯或異丙酯· Μ及許多彼等之對應酵酯類(乳酸 異硬脂酯化納、乳酸葵酯化納)。 典型上,油性成份是一棰具有至少10個碳原子之脂肪酸 的3 - 6碳醇酯。其醇較好是側鍵醇,最好的是異丙醇。較 適宜的脂肪酸係選自肉亘蔻酸、棕招I酸以及其混合物。 上述的所有油類都具有低於40 00的分子量。較好是使用 分子是低於2000,而更好是低於1000,的油類。 最逋合的濕潤劑是棕相I酸異丙酯和肉豆蔻酸異丙酯。 這兩種形式濕潤劑的其它範例則揭示於J. Mans n er所著 之 Cosmetics & Toiletries, May 1981的”Emollients —a Critical Evaluation "中 ° 琀雔芊界而活件割 陰雔子界面活性劑是發泡界面活性劑,而且是本發明姐 合物的基本成份。 陰離子清潔劑的範例是鹽類(包括:納Η、鉀鹽、銨鹽 .................................................................................裝......................訂...................線 (請先閲讀背面之注意事項再蜞寫本頁) 本紙張尺度適用中國國家標準(CNS)甲4規格(210x297公釐) A6 B6 311090 五、發明説明(5 ) 和受取代的銨鹽),譬如9至20個碳之烷基笨磺酸鹽的、 8至22個碳之一级或二级烷磺酸鹽的、8至24個碳之鏈稀 磺酸盥的、磺醢化之聚羧酸(其係藉由將驗土金颺檸様酸 鹽的高溫分解產物予Μ磺醣化而製得,如英國專利說明書 1,08 2,179號中所描述的、8至22®碳之烷基硫酸鹽的、 8至24個碳之烷基聚乙二酵-魅-硫酸鹽的、羧酸鹽的、 和-磷酸鹽(含有多至10荑耳的環氧乙烷)的單-、二-和三乙醸胺鹽類更多的範例乃記載 較佳的陰離子界面活性劑係選自;烷基醚硫酸鹽、脂肪 酸皂、烷基硫酸鹽、烷基磺酸鹽、羥乙磺酸衍生物及其混 合物。一種特別適宜的非皂性陰離子劑是未受取代的 Ca-C22烷基羥乙碩酸鹽。可Μ藉由將鹼金鼷羥乙磺酸鹽與 混合的,且具有8至22個碳的脂性脂肪酸反應而製得這些 酯類。最好的陰離子界面活性劑是烷基醚硫酸鹽*因為含 此成份之组合物的柔順性的緣故。 陰離子界面活性劑的較佳含量是在10-20¾重量的範圍。 陰離子界面活性劑:油液的比率較好是在1: 1至2〇:1’ 更好是1: 1至5: 1的範圍。 笛一非雔孑件界而活性蜊 非離子性界面活性劑,其具有5-10範圃内的HLB值·是 當做油性成份的乳化劑,而且它的存在是實施本發明所必 需的。 適合的非離子性界面活性劑包括脂肪酵乙氧基化物’其 本紙張尺度適用中國國家標準(CTS)甲4规格(210x297公釐) 裝......................訂.....................線 {請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 經濟部中央標準局員工消費合作社印製
A6 B6 五、發明説明(6 ) 具有展琨特定範圍内之HLB值的烷基鍵畏度和乙氧基化值 〇 較好的脂肪醇乙氧基化物是具有CIO - C16的鏈長度和3 -7的乙氧基化值。由於在市面上可用的自由酵之低含量 的緣故*所Μ較高的鐽長度,C12和K上者乃是特別逋合 的。該成份的較佳比率是使得非離子性乳化劑對油液的比 率落在1:10至10:1的範画内。 —般而言,包含相對低含量之乳化劑的比率會形成具有 較大液滴的乳劑,這些通常是不透明或拜狀的。這些乳劑 •其具有1:10至約3:10乳化劑:油液的比率範圍,會顯現 出油液之於皮虜的良好散佈性質。 較高含量的乳化劑,典型上在乳化劑:油液的比率達3 :10 Μ上時•會導致透明的姐合物。對任何特定的姐合物 而言•從蓀狀變為澄清的實際轉換點乃部份取決於電解質 含量。 透明的组合物是較受歡迎的。 第二非雜孑袢界而沃袢劑 脂肪酸單甘油聚乙二酵醚是做為稠化界面活性劑,並且 是該姐合物的第四種基本成份。 脂肪酸單甘油聚乙二醇醚具有下面的结構·· R-C0-0-CHa-CH.OH-CH2-〇-(CH2-CH2-0)„-H 裝......................ir.....................線 {請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)甲4规格(210X297公釐) A6 B6 經濟部中央標準局員工消费合作社印製 五、發明説明(7 ) 其R是直鍵或側鏈的烷基團,鏈長度為8-16碳•較好是約 12碳,而n是1 - 5,較好是約3。 雷解1 —般而言,本發明的姐合物將包括多至約4¾:重量比含量 的電解質。適合的電解質是鹸金鼷鹵化物,較好是氯化納 或氛化鉀、也可以使用其它的譬如硫酸鹽的鹽類,雖然上 述的氛化物是較好的。 電解質的存在,以及其含量,將影響產品的黏度。 根據本發明的產品在藉由操作者手冊所描述的標準方法 而使用一種Haake (TM)旋轉式黏度計Μ測得於秒分之一的 切變速率下的黏度是3000-12000,較好是3000 - 7000微帕 斯(m P a s )。 其它 本發明的姐合物可K包含一種視情況需要的聚合性皮膚 感覺及柔順促進劑。 可用於本發明的聚合性皮虜感覺及柔順促進劑是使用在 化粧品領域的陽離子、陰離子、兩性的、以及非離子性的 聚合物。MUnion Carb 丨 de 於 1977 之” Polymer JR for· Skin Care”報告中的陽離子和非離子性形式聚合物的貼片 測試法實施減低皮膚刺激性之優點的評估。陽離子物因為 能提供較好的皮膚感覺優越性而較其它的種類更受歡迎。 裝......................ΤΓ...............::4 <諳先閲讀背面之注意事項再填窝本頁} 本紙張尺度適用中國國家標準(CNS)甲4規格(210x297公釐) 311090 A6 B6 經濟部中央標準局員工消費合作社印$! 五、發明説明(8 ) 用於本發明姐合物的聚合性皮膚感覺及柔順促進劑的含 量是約0.01¾至約5S!。 可K使用其它種類的高分子量聚合性皮虜感覺及柔順促 進劑,譬如:非離子性的瓜拉膠*由Merck & Co, Inc.製 造的 Merquats (TM)100和 550 ;由 Stein Hall 製造的 Jaguar C-14-S;由 Miranol Chemical Company, Inc.製造 的 Mirapol (TM) A15;以及由 Henkel, Inc.製造的 Galactasol (TM) 811;加上其它者。該聚合物也提供增強 的乳霜性皮虜滋潤。 可用的非雜子性聚合物包括非雔子性的聚糖精•例如: 由Celanese Corp.供應的非離子性羥丙基瓜拉膠。一種較 佳的非離子性羥丙基瓜拉膠是具有約0.6的莫耳取代性的 Jaguar11 HP-60 。其它可用的非離子物等级是纖維素非離 子性聚合物,例如HEC和CMC。 本發明所使用的陽雛子聚合物也能夠提供一種滑溜,柔 軟•平順的使用感。用於本發明的較佳含量是組合物的 0.卜5:«。有理由相信帶正電的陽離子聚合物可以與皮虜上 帶負電的部位結合K便在使用之後提供一種皮庸柔軟的感 覺。無需附帶任何理論地,一般便認為陽離子聚合物的帶 電強度越大,則其皮虜的滋潤效果越好。 特別適宜的是佔產品0.0卜35K重量比含量的Jaguar (TM)或 Po1ymer JR (TM)。 本發明的姐合物包含0-10¾重量比的共同-界面活性劑 ,較好是一種兩性的或雙離子性的清潔劑。適合的共同- 裝.......................玎....................._ <請先閲讀背面之注意事項再墣寫本頁} - 10 - 本紙張尺度適用中國國家標準(CNS)甲4规格(210x297公釐) A6 B6 經濟部中央標準局員工消費合作社印製 五、發明説明(9 ) 界面活性劑的範例是N -烷基胺酸類、甜菜鹼、硫併甜菜鹼 、以及脂肪酸蛋白質水解物的凝縮產物。較好的共同-界 面活性劑是甜菜鹼。 根據本發明姐合物的其它非基本的,但是為典型的成份 則可Μ選自下列之中的一種或多種:不透明劑*較好是 0.2-2.Οίί重量;防腐劑•較好是0.2-2.0¾重量;和芳香劑 •較好是0.5-2.0«重量。視情況需要的成份包括:賦色劑 、殺菌劑、潤飾劑、保濕劑、抗氧化劑和防腐蜊。 較佳的姐合物是安定、黏稠、透明、水性的沐浴-凝膠 姐合物,其包括: a) 10-15%重量比的陰離子界面活性劑, b) 5-10¾重量比的油性成份, c) 1-5¾重量比的脂肪酸單甘油聚乙二醇醚, d) 1-5¾重量比的,至少一種具5至10之間的HLB值的 非離子界面活性劑, e) 卜4¾重量比的電解質,和 f ) 0 . 01-1¾的陽離子聚合物。 本發明特別適合的設計包含了: a) 10-15¾重量比的的乙氧基化竹陰離子界面活性劑, b) 5-10X重量比的内含10 - 20個碳原子的脂肪酸之3 -6碳醇酯, c) 卜5¾重量比的C8-C16脂肪酸單甘油聚乙二醇醚,具 有1 - 5個乙氧基化值基團, 裝......................訂.....................線 (請先閱讀背面之注意事項再填寫本頁) - 11 - 本紙張尺度適用中國國家標準(CNS)甲4規格(210x297公釐) 311090 A6 B6 經濟部中央標準局員工消费合作社印製 五、發明説明(10 ) d> 卜5¾重量比的脂肪酵乙氧基化物,其具有{:10一 C16的碳鍵,和3 - 7個乙氧差忆值, e) 1-4¾重量比的電解質,和 f ) 〇 . 01-1X的限離子聚合物。 所述的姐合物係呈一種清激、水性的膠體,其經由標準 方法而使用一種Haake旋轉式黏度計Μ測得於秒分之一的 切變速率下的黏度為3000 - 7000微帕斯UPas)。 為求更能理解本發明•乃參照下面的實施例而描述於後 奮倫例 下面的物質係使用於實施例中: SLES: Genapol ZRO (RTM ex. Hoechst)陰雔子界面 活性劑。 N 0 N I : R e w 〇 d e r m U S 7 5 或 L I S 8 0 (R T M e X . R e w 〇 ), 脂肪酸單甘油聚乙二醇醚。 POLY: Carbopol 980/981 (RTM ex. Goodrich)聚丙 烯酸盥,稠化劑。 EMUL: Cenapol UD-030 (RTM ex. Hoechst)具有 C11 之鐽長度、3之乙氧基化值和8之HLB值的脂肪 醇乙氧基化物。 BRIJ: BRIJ-58 (RTM ex. Atlas)具有 C16之鏈長度 、3之乙氧基化值和10M上之HLB值的脂肪酵 乙氧基化物。 - 12 - 本紙張尺度適用中國國家標準(CNS)甲4規格(210x297公釐) 裝......................訂.....................線 {請先閲讀背面之注意事項再填窝本頁) A6 B6 經濟部中央標準局g工消费合作杜印製 五、發明説明(Ί 1 ) I P P :様神3 酸異丙醋(ex. Unicheraa) 。_ JAG: Jaguar-C13S (ex. Mayhall),瓜拉膝基質 的陽離子聚合物。 鹽: 氯化納。 Pres:山梨酸(ex. Hayes)和三納棒檬酸鹽(ex BDH),含有效量做為防腐劑。 Pe「l:用做珠光劑的次乙基乙二醇單-硬脂酸鹽 (ex. Albright 和 Wilson)。 Perf:市售的化粧用芳香劑。 根據下面的方法製備根據本發明的姐合物和相當的實施 例: 在4010及切轉操作之下,將油性成份與非離子界面活性 乳化劑併合。緩慢地加入水份Μ形成一種乳劑,並將陰離 子界面活性劑與該乳劑併合,此方法會得到一種細腻的乳 劑。接著添加鹽份和稠化劑。當使用EG MS時,便在較高的 溫度中(60t)實施本方法|而且於第一階段加入EGMS。在 持鑛切轉操作下,將防腐劑添加至熱混合物中,彼於加入 芳香劑之前,須先予Μ冷卻。 在攝氏20ΤΜ室溫)及37。(體溫)下,Μ發生可見的 相分離之前的儲存時間評估组合物的安定性。在規定條件 下能保持至少三個月安定性的姐合物即視為是足夠安定的 Ο 除非另有註明,否則所有的數據記錄都表示成產品的重 裝.......................ΤΓ......................^ (請先閱讀背面之注意事項再填寫本頁) - 13 - 本纸張尺度適用中國國家標準(CNS)甲4規格(210x297公釐) A6 B6 五、發明説明(12 ) 量%。 下面的表1顯示出本發明實施的範例。表示於S-20和 S-37的數據是如上述的儲存安定性。黏度(vise)是Μ秒分 之一的切變速率予Μ測量•並表為帕斯(Pascals)。 裝.......................玎......................#. (請先閲讀背面之注意事項再填寫本頁) 經濟部中夬標準局員工消费合作社印製 - 14 - 本紙張尺度適用中國國家標卓(C—NS丁甲—4"规格(210 X 297公釐) Λ五 A6 B6 經濟部中央標準局員工消費合作杜印製
J S-20 1 Perf 1 Perl 1 Pres 蠹 1 JAG 1 IPP 1 EMUL NONI 1 SLES 1 1 -------------------------------^ m ιοο%--------------------------------- 1 Μ I ο 0J 1 〇l u> UJ h-^ s 1 LO 1 Η1 1 ο <1 0J o (-Π u» UJ NJ 1 σ\ 1 Μ ι ο to o H1 to OJ 1 〇\ 1 Μ 1 ο UJ o M CO OJ CsJ 办 1 αι 1 Η1 1 ο OJ o U1 CO Ln NJ Μ NJ ο CSJ 1 u> u> <T\ Η-1 Μ εο ο Ό OJ 1 M ua OJ Η* Μ 办 Μ CO ο -4 OJ 1 H1 u» 00 σ\ c σ\ Η NJ ο OJ 1 I-1 OJ 二 VO σ\ ο Csj Η1 Μ I UJ 1 to (jj <1 Ln M — Η* OJ ν·〇 Η* to 1 1 H-1 CO OJ 二 M 5 11 {請先Μ讀背面之注意事項再埸寫本頁) -裝 線 釐 公 7 9 2 X 10 2 格 規 4 甲 CNS 準 標 家 國 中 用 適 度 尺 張 紙 本 311090 經濟部中央標準局員工消費合作社印製 五、發明説明(14 ) 在上述表格中所列舉的某些姐合物(例如配方3 )是透 明的。 下面的表2顯示出不具備所需安定性的比較實施例。表 示於S-20和S-37的數據是如上述的儲存安定性。黏度 (” vise”)是Μ秒分之一的切變速率予以測量,並表為帕斯 (P a s c a 1 s )。安定性的期間是表為小時或天。在一些情況 下,產品於實驗人員雔開的幾個小時之後就變得不安定, 而使用約略的"小時”予以表示。在一些實施例中,乃使 用聚合物當做稠化界面活性劑的替代品。在其它的實施例 中•是使用具有不同HLB值之非離子物以取代乳化性非離 子物。 6 ii ^......................、玎.....................線 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)甲4規格(210X297公釐) 311090 A6 B6 五 經濟部中央標、準总員工消费合作社印製 卜37 l S-20 a? m 1 Perf 1 Perl 1 Pres m 1 IPP 1 BRIJ 1 EMUL 1 POLY 1 NONI 1 SLES m m 〇 m 1 ----------------------------------調至 100%---------------------------------- 1 M H* O NJ 1 CO 1 N·) 庄; > 頷 〇 m 1 to o -J CO 1 CO I to CO > CO U1 \ H1 to o -0 u> 1-* 1 to I CO U) > to 12h 1 H1 N) o -J CO l CO U1 1 ΟΊ > CO CO a 办 to o to — 1 to l UJ c U1 > m cn a 1 I-1 CsJ o <1 M 1 1 OJ t; CO > m σ\ a i M to o \ UJ 1 〇J UD > m σ\ a 1 H1 to o -o DO t I 〇J 10A a 1 h-4 to o -J CO I 1 to 二 11A O 14d I 1 (-1 CO o U» <J1 1 ui o CO u> 7 格 規 4 5- vs c' 準 標 家 國 國 中 用 適 度 尺 張 紙 本
釐 公 7 9 2 X
Claims (1)
- 荦82110246號專利审請案 311 文由請專利範圍修正本(86年5月) A8 B8 C8 D8告 K /V 經濟部中央標準局員工消費合作社印製 、申專利範圍 本 1. 一種水性沐浴-凝膠組合物,包含: a ) 1 0 - 3 0重量的陰離子界面活性劑, b) 3-15重量3:的油性成份,其係具有10至20個碳原子 之脂肪酸的3-6碳醇酯.,該陰離子界面活性劑相對 油的比率至少為1 : 1, c ) 1 - 5重量X C S - C 1 6的脂肪酸S甘油聚二醇键,和, d) 1 - 5重量%至少一種H L B值介於5到1 0之間的非離子界 面活性劑, e) 1-4重量ί:選自鹼金屬鹵化物之電解質·,及 剩餘者為水。 2 根據申請專利範圍第1項之組合物,其更進一步包含 〇 . (Π - 1重量5:之陽離子聚合物。 3. 根撺申請專利範圍第1項之組合物,其中該油性成份 (b)具有低於4000的分子量。 4 根搏串請專利範圍第1項之組合物,其中成份(d ): (b)的比率落在1:10至10:1的範圍内。 5. 根撺申請專利範圍第1項之組合物*其中成份(a ): (b )的比革落在1 : 1至2 0 : 1的範圍内。 a 根撺申請專利範圍第1項之組合物,其使用標準方法而 Μ —種H a a k e旋轉式黏度計測量於秒分之一之切寒速率 下的黏度為3000- 7000Mpas。 7. 根據申請專利範圍第1項之組合物,包含: a) 10-15重最%的乙氧基化陰離子界面活性劑, b) 5-10垂最ί;含10 - 20個碳原子的脂肪酸之3 - 6碳醇 本纸張尺度適用中國國家標準(CNS )八4規格(210X297公釐) ---J-------装------1T------.it , ~ I (請先閏讀背面之注意事項再:^寫本頁) 311090 部 C8 D8 六、申請專利範圍 酷, c) 1-5重量%C8-C16的脂肪酸單甘油聚乙二醇醚,其具 有1-5的乙氧基化值, d) 1-5重量2:的醇乙氧基化.物,其具有CIO - C16的鐽長 和3 - 7的乙氧基化值, e) 1-4重量X的電解質, f ) 0.01-U的陽離子聚合物,和 剩餘者為水, 該組合物偽呈一種清澈、水性凝膠形式,其使用搮準方 法而Μ —種H a a k e旋轉式黏度計測量於秒分之一之切要 速荽下的黏度為3000- 7000MPas。 ---^------1------'訂------0 | -(請先閣讀背面之注意事項再>寫本頁) 經濟部中央標準局員工消費合作社印製 2 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐)
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ZA951012B (en) * | 1994-02-14 | 1996-08-08 | Colgate Palmolive Co | Composition |
DE4416566A1 (de) * | 1994-05-11 | 1995-11-16 | Huels Chemische Werke Ag | Wäßrige viskoelastische Tensidlösungen zur Haar- und Hautreinigung |
GB9414572D0 (en) * | 1994-07-19 | 1994-09-07 | Unilever Plc | Soap composition |
DE19500799A1 (de) * | 1995-01-13 | 1996-07-18 | Henkel Kgaa | Elektrolytsalzfreie wäßrige Tensidformulierungen |
FR2736830B1 (fr) * | 1995-07-20 | 1997-10-10 | Fabre Pierre Dermo Cosmetique | Composition cosmetique pour hygiene corporelle sous la forme d'une emulsion huile dans l'eau |
KR100461943B1 (ko) * | 1997-04-07 | 2005-04-06 | 주식회사 태평양 | 화장제거용고형인체세정제조성물 |
DE19824359A1 (de) * | 1998-05-30 | 1999-12-02 | Henkel Kgaa | Duschgel |
US6051541A (en) * | 1998-12-16 | 2000-04-18 | Unilever Home & Personal Care, Division Of Conopco, Inc. | Process for preparing pourable, transparent/translucent liquid detergent with continuous suspending system |
US6362156B1 (en) | 1998-12-16 | 2002-03-26 | Unilever Home & Personal Care, Usa, Division Of Conopco, Inc. | Pourable transparent/translucent liquid detergent composition with suspended particles |
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CA2122272A1 (en) * | 1991-11-22 | 1993-05-27 | Susan C. Wivell | Combined personal cleansing and moisturizing compositions |
-
1992
- 1992-11-09 GB GB929223439A patent/GB9223439D0/en active Pending
-
1993
- 1993-11-04 EP EP93924593A patent/EP0668754B1/en not_active Revoked
- 1993-11-04 BR BR9307411A patent/BR9307411A/pt not_active IP Right Cessation
- 1993-11-04 ES ES93924593T patent/ES2161722T3/es not_active Expired - Lifetime
- 1993-11-04 WO PCT/EP1993/003098 patent/WO1994010975A1/en not_active Application Discontinuation
- 1993-11-04 AU AU54208/94A patent/AU5420894A/en not_active Abandoned
- 1993-11-04 KR KR1019950701842A patent/KR100322357B1/ko not_active IP Right Cessation
- 1993-11-04 JP JP51168494A patent/JP3644960B2/ja not_active Expired - Lifetime
- 1993-11-04 DE DE69330565T patent/DE69330565T2/de not_active Revoked
- 1993-11-08 US US08/148,444 patent/US5393450A/en not_active Expired - Lifetime
- 1993-11-08 MY MYPI93002341A patent/MY109562A/en unknown
- 1993-11-08 PH PH47223A patent/PH29944A/en unknown
- 1993-11-09 ZA ZA938356A patent/ZA938356B/xx unknown
- 1993-12-04 TW TW082110246A patent/TW311090B/zh active
Also Published As
Publication number | Publication date |
---|---|
AU5420894A (en) | 1994-06-08 |
KR100322357B1 (ko) | 2002-07-27 |
ZA938356B (en) | 1995-05-09 |
KR950703930A (ko) | 1995-11-17 |
JP3644960B2 (ja) | 2005-05-11 |
JPH08503201A (ja) | 1996-04-09 |
GB9223439D0 (en) | 1992-12-23 |
ES2161722T3 (es) | 2001-12-16 |
BR9307411A (pt) | 1999-06-29 |
DE69330565D1 (de) | 2001-09-13 |
MY109562A (en) | 1997-02-28 |
EP0668754A1 (en) | 1995-08-30 |
US5393450A (en) | 1995-02-28 |
PH29944A (en) | 1996-09-16 |
DE69330565T2 (de) | 2001-11-22 |
WO1994010975A1 (en) | 1994-05-26 |
EP0668754B1 (en) | 2001-08-08 |
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