TW202444258A - Oil and fat composition with enhanced beef tallow feel, beef tallow feel enhancer, method for producing the oil and fat composition with enhanced beef tallow feel, method for producing fried food, and method for enhancing fee tallow feel - Google Patents
Oil and fat composition with enhanced beef tallow feel, beef tallow feel enhancer, method for producing the oil and fat composition with enhanced beef tallow feel, method for producing fried food, and method for enhancing fee tallow feel Download PDFInfo
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- TW202444258A TW202444258A TW113107726A TW113107726A TW202444258A TW 202444258 A TW202444258 A TW 202444258A TW 113107726 A TW113107726 A TW 113107726A TW 113107726 A TW113107726 A TW 113107726A TW 202444258 A TW202444258 A TW 202444258A
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- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS OR COOKING OILS
- A23D9/00—Other edible oils or fats, e.g. shortenings or cooking oils
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/10—Natural spices, flavouring agents or condiments; Extracts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Edible Oils And Fats (AREA)
Abstract
Description
本發明係有關增強食品之牛脂感的技術。 The present invention relates to a technology for enhancing the beef fat texture of food.
牛脂係在食品容易賦予良好的風味,自以往即被廣泛使用於食品。例如,若以含有牛脂之油脂油炸烹調食品,即可對食品賦予較佳的牛脂風味。有關牛脂風味之技術,在專利文獻1中,係記載一種油脂組成物,其係混合有牛脂與氧化安定化油者,且含有亞麻油酸5重量%以下、油酸50重量%以上,並具有牛脂風味。 Beef tallow can easily give good flavor to food and has been widely used in food since ancient times. For example, if food is fried or cooked with fat containing beef tallow, a better beef tallow flavor can be given to the food. Regarding the technology of beef tallow flavor, in Patent Document 1, a fat composition is described, which is a mixture of beef tallow and oxidized stabilized oil, contains less than 5% by weight of linoleic acid and more than 50% by weight of oleic acid, and has a beef tallow flavor.
[先前技術文獻] [Prior Art Literature]
[專利文獻] [Patent Literature]
[專利文獻1]日本特開平3-35757號公報 [Patent Document 1] Japanese Patent Publication No. 3-35757
然而,近年來,因原料供應問題及健康取向之高漲,逐漸要求降低牛脂之使用量,減少牛脂之使用量時,期盼更進一步開發出具有與平常使用牛脂時相同的牛脂感之原材料。因而,本發明之目的在於提供一種可增強牛脂感之優異的原材料。 However, in recent years, due to the supply of raw materials and the rise of health trends, there is a gradual demand to reduce the amount of beef fat used. When reducing the amount of beef fat used, it is hoped that a raw material with the same beef fat feel as the usual beef fat can be developed. Therefore, the purpose of the present invention is to provide an excellent raw material that can enhance the beef fat feel.
發明人等經致力研究之結果,發現藉由對油脂施予特定之處理,可獲得在增強牛脂感之效果上優異的原材料,終於完成本發明。亦即,依據本發明,可提供:以下之牛脂感增強的油脂組成物、牛脂感增強劑、牛脂感增強的油脂組成物之製造方法、油炸食品之製造方法、及牛脂感增強方法。 As a result of the inventors' dedicated research, they found that by subjecting the fat to a specific treatment, a raw material with excellent effect of enhancing the beef fat taste can be obtained, and finally the present invention was completed. That is, according to the present invention, the following beef fat taste enhancing fat composition, beef fat taste enhancing agent, method for producing beef fat taste enhancing fat composition, method for producing fried food, and method for enhancing beef fat taste can be provided.
〔1〕一種油脂組成物,係增強含有牛脂及氧化油脂之牛脂感。 [1] A fat composition that enhances the tallow texture of fats containing tallow and oxidized fats.
〔2〕如〔1〕所述之油脂組成物,係更含有米油。 [2] The oil composition as described in [1] further contains rice oil.
〔3〕如〔1〕或〔2〕所述之油脂組成物,其中,前述氧化油脂係含有將選自植物性油脂、乳脂及微生物油脂之至少1種的油脂進行氧化處理而成的氧化油脂。 [3] The fat composition as described in [1] or [2], wherein the oxidized fat comprises an oxidized fat obtained by oxidizing at least one fat selected from vegetable fat, milk fat and microbial fat.
〔4〕如〔1〕至〔3〕中任一項所述之油脂組成物,其中,前述氧化油脂係包含前述氧化油脂藉由酵素水解而成的水解物。 [4] The fat composition as described in any one of [1] to [3], wherein the oxidized fat comprises a hydrolyzate obtained by hydrolyzing the oxidized fat by enzyme.
〔5〕如〔1〕至〔4〕中任一項所述之油脂組成物,其中,前述氧化油脂之過氧化值為15以上300以下。 [5] The fat composition as described in any one of [1] to [4], wherein the peroxide value of the oxidized fat is greater than 15 and less than 300.
〔6〕如〔4〕所述之油脂組成物,其中,前述水解物之酸值為5以上200以下。 [6] The fat composition as described in [4], wherein the acid value of the hydrolyzate is greater than 5 and less than 200.
〔7〕如〔1〕至〔6〕中任一項所述之油脂組成物,其中,前述油脂組成物中之前述氧化油脂的含量為0.001質量%以上10質量%以下。 [7] The fat composition as described in any one of [1] to [6], wherein the content of the aforementioned oxidized fat in the aforementioned fat composition is 0.001 mass % or more and 10 mass % or less.
〔8〕如〔2〕至〔7〕中任一項所述之油脂組成物,其中,前述油脂組成物中之前述米油的含量為0.05質量%以上20質量%以下。 [8] The fat composition as described in any one of [2] to [7], wherein the content of the aforementioned rice oil in the aforementioned fat composition is 0.05 mass % or more and 20 mass % or less.
〔9〕如〔1〕至〔8〕中任一項所述之油脂組成物,其中,前述氧化油脂係含有將植物性油脂進行氧化處理而成的氧化油脂, [9] The fat composition as described in any one of [1] to [8], wherein the oxidized fat comprises an oxidized fat obtained by oxidizing a vegetable fat,
將前述油脂組成物中之前述植物性油脂進行氧化處理而成的氧化油脂之含量為0.001質量%以上5質量%以下。 The content of oxidized fat obtained by oxidizing the aforementioned vegetable fat in the aforementioned fat composition is 0.001 mass % or more and 5 mass % or less.
〔10〕如〔1〕至〔9〕中任一項所述之油脂組成物,其中,前述氧化油脂係含有將乳脂進行氧化處理而成的氧化油脂, [10] The fat composition as described in any one of [1] to [9], wherein the oxidized fat comprises an oxidized fat obtained by oxidizing milk fat,
將前述油脂組成物中之前述乳脂進行氧化處理而成的氧化油脂之含量為0.001質量%以上5質量%以下。 The content of oxidized fat obtained by oxidizing the aforementioned milk fat in the aforementioned fat composition is 0.001 mass % or more and 5 mass % or less.
〔11〕如〔1〕至〔10〕中任一項所述之油脂組成物,其中,前述氧化油脂係含有將含花生四烯酸的油脂進行氧化處理而成之氧化油脂, [11] The fat composition as described in any one of [1] to [10], wherein the oxidized fat comprises an oxidized fat obtained by oxidizing an arachidonic acid-containing fat,
將前述含花生四烯酸的油脂進行氧化處理而成的氧化油脂之含量為0.0001質量%以上3質量%以下。 The content of the oxidized fat obtained by oxidizing the aforementioned arachidonic acid-containing fat is 0.0001 mass % or more and 3 mass % or less.
〔12〕如〔1〕至〔11〕中任一項所述之油脂組成物,其中,前述油脂組成物中之前述牛脂的含量為5質量%以上且未達100質量%。 [12] The fat composition as described in any one of [1] to [11], wherein the content of the aforementioned beef tallow in the aforementioned fat composition is 5% by mass or more and less than 100% by mass.
〔13〕如〔1〕至〔12〕中任一項所述之油脂組成物,其係油炸烹調用。 [13] A fat composition as described in any one of [1] to [12], which is used for frying and cooking.
〔14〕一種牛脂感增強劑,其係含有氧化油脂作為有效成分。 [14] A beef tallow enhancer containing oxidized fat as an active ingredient.
〔15〕如〔14〕所述之牛脂感增強劑,係更含有米油作為有效成分。 [15] The beef tallow enhancer as described in [14] further contains rice oil as an active ingredient.
〔16〕如〔14〕或〔15〕所述之牛脂感增強劑,其中,前述氧化油脂係含有將選自植物性油脂、乳脂及微生物油脂之至少1種的油脂進行氧化處理而成的氧化油脂。 [16] The beef fat enhancer as described in [14] or [15], wherein the oxidized fat comprises an oxidized fat obtained by oxidizing at least one fat selected from vegetable fat, milk fat and microbial fat.
〔17〕如〔14〕至〔16〕中任一項所述之牛脂感增強劑,其中,前述氧化油脂係包含前述氧化油脂藉由酵素水解而成的水解物。 [17] A beef fat enhancer as described in any one of [14] to [16], wherein the oxidized fat comprises a hydrolyzate obtained by hydrolyzing the oxidized fat with an enzyme.
〔18〕一種增強牛脂感之油脂組成物的製造方法,係包含下列步驟: [18] A method for producing a fat composition for enhancing the texture of beef tallow, comprising the following steps:
將油脂進行氧化處理而得到氧化油脂之步驟; The step of subjecting the oil to oxidation treatment to obtain oxidized oil;
在包含牛脂之食用油脂中添加前述氧化油脂之步驟。 The step of adding the aforementioned oxidized fat to edible fats and oils including beef tallow.
〔19〕如〔18〕所述之油脂組成物的製造方法,係包含:在含有牛脂之食用油脂中更添加米油之步驟。 [19] The method for producing the fat composition as described in [18] comprises the step of adding rice oil to the edible fat containing beef tallow.
〔20〕一種油炸食品之製造方法,係包含使用〔1〕至〔13〕中任一項所述之油脂組成物將物料進行油炸烹調之步驟。 [20] A method for producing fried food, comprising the step of frying and cooking the material using the oil composition described in any one of [1] to [13].
〔21〕一種油炸食品之牛脂感增強方法,其係使用〔1〕至〔13〕中任一項所述之油脂組成物將物料進行油炸烹調者。 [21] A method for enhancing the beef fat taste of fried food, which comprises using the fat composition described in any one of [1] to [13] to fry the material.
依據本發明,可提供一種利用油脂之氧化處理物,而可增強牛脂感之優異的原材料。 According to the present invention, a raw material that can enhance the texture of beef tallow can be provided by using oxidation treatment of fat.
以下,更詳細說明有關用以實施本發明之形態。又,在本說明書中,表示數值範圍之上限值及下限值時係可適當組合上限值及下限值,亦揭示藉由此所得到之數值範圍者。 The following is a more detailed description of the form used to implement the present invention. In addition, in this specification, when indicating the upper limit and lower limit of the numerical range, the upper limit and lower limit can be appropriately combined, and the numerical range obtained thereby is also disclosed.
〔存在不可能/不切實際的情況〕 [There are impossible/unrealistic situations]
本發明係將油脂進行氧化處理,或者依需要而更藉由酵素進行水解處理,以此作為牛脂感增強用之有效成分者。通常,油脂之處理物係成為以極多種類之化學物質所構成的組成物,無法對所含的化學物質進行調查並逐一鑑定,或者因需要明顯龐大的經濟性支出或時間而不切實際。 The present invention is to oxidize the fat, or if necessary, hydrolyze it with enzymes, and use it as an effective ingredient for enhancing the beef fat taste. Usually, the processed fat becomes a composition composed of a large number of chemical substances, and it is impossible to investigate and identify the chemical substances contained one by one, or it is impractical because it requires significantly large economic expenditures or time.
<1.牛脂感增強之油脂組成物> <1. Oil composition with enhanced beef tallow texture>
本發明之經增強牛脂感的油脂組成物(以下,亦僅簡稱為「油脂組成物」。)係含有牛脂及氧化油脂。 The fat composition with enhanced beef tallow texture of the present invention (hereinafter, also referred to as "fat composition") contains beef tallow and oxidized fat.
在此,所謂「牛脂感」之增強通常係與發明所屬技術領域中具有一般知識者所理解者相同意義,亦即,指增強牛脂之風味或呈味。更換言之,儘管牛脂減少,在包含該牛脂之食品可充分增強牛脂之風味。更具體而言,並無特別限定,但例如,包含增強牛脂之甘甜、牛脂之肉味感、牛脂之濃郁度。 Here, the so-called enhancement of "beef fat taste" is generally the same as what is understood by those with general knowledge in the technical field to which the invention belongs, that is, it refers to enhancing the flavor or taste of beef fat. In other words, despite the reduction of beef fat, the flavor of beef fat can be fully enhanced in the food containing the beef fat. More specifically, there is no special limitation, but for example, it includes enhancing the sweetness of beef fat, the meaty taste of beef fat, and the richness of beef fat.
(氧化油脂) (Oxidized oil)
氧化油脂係使成為原料之油脂進行氧化處理而得到。就作為氧化處理之原料的油脂而言,只要形成為可飲食之油脂即可,並無特別限制,可列舉例如:菜籽油、大豆油、棕櫚油、玉米油、橄欖油、芝麻油、亞麻仁油、 紫蘇油、紅花油、葵花油、棉籽油、米油、花生油、牛油樹油脂、娑羅樹油脂(sal butter)、可可脂、棕櫚仁油、椰子油、葡萄籽油、澳洲胡桃油、月見草油等植物性油脂;豬油、乳脂、雞油、魚油等動物性油脂;微生物油脂;中鏈脂肪酸三酸甘油酯等合成油脂等。就成為氧化處理之原料的前述油脂而言,較佳係包含選自植物性油脂、乳脂、及微生物油脂之至少1種,更佳係包含選自葵花油、棕櫚系油脂、乳脂、及微生物油脂之至少1種,又更佳係選自葵花油、棕櫚系油脂、乳脂、及微生物油脂之至少1種。 Oxidized fats and oils are obtained by subjecting the raw material fats and oils to oxidation treatment. As for the raw material fats and oils for oxidation treatment, there are no particular restrictions as long as they are edible fats and oils. Examples include: vegetable fats and oils such as rapeseed oil, soybean oil, palm oil, corn oil, olive oil, sesame oil, flax seed oil, perilla oil, safflower oil, sunflower oil, cottonseed oil, rice oil, peanut oil, shea butter, sal butter, cocoa butter, palm kernel oil, coconut oil, grape seed oil, macadamia nut oil, evening primrose oil, etc.; animal fats and oils such as lard, butter, chicken oil, fish oil, etc.; microbial fats and oils; synthetic fats and oils such as medium-chain fatty acid triglycerides, etc. As for the aforementioned oils and fats used as raw materials for oxidation treatment, it is preferred that the oils and fats include at least one selected from vegetable oils and fats, milk fats, and microbial oils, and it is more preferred that the oils and fats include at least one selected from sunflower oil, palm oils and fats, milk fats, and microbial oils, and it is even more preferred that the oils and fats include at least one selected from sunflower oil, palm oils and fats, milk fats, and microbial oils.
前述葵花油並無特別限定,但較佳係佔有構成脂肪酸總量之油酸的比率為70質量%以上100質量%以下,更佳係75質量%以上95質量%以下,又更佳係80質量%以上90質量%以下。佔有構成脂肪酸總量之油酸的含量係可依據「基準油脂分析試驗法2.5.23-2013脂肪酸組成(毛細管柱氣相層析法(capillary gas chromatography)」(日本油化學會)記載的方法進行測定。 The sunflower oil is not particularly limited, but preferably the ratio of oleic acid to the total fatty acid composition is 70 mass% or more and 100 mass% or less, more preferably 75 mass% or more and 95 mass% or less, and even more preferably 80 mass% or more and 90 mass% or less. The content of oleic acid to the total fatty acid composition can be measured according to the method described in "Standard Oil Analysis Test Method 2.5.23-2013 Fatty Acid Composition (Capillary Gas Chromatography)" (Japan Oil Chemical Society).
前述棕櫚系油脂係只要為從油棕果實所得到之棕櫚系油脂即可,可為施行有分子蒸餾、分餾、脫膠、脫酸、脫色、脫臭等處理者。各處理之方法並無特別限定,通常,可採用油脂之加工/純化處理中所用的方法。棕櫚系油脂之α-胡蘿蔔素及β-胡蘿蔔素之合計含量並無特別限定,但以50質量ppm以上2000質量ppm以下為佳,50質量ppm以上1500質量ppm以下更佳,以50質量ppm以上1000質量ppm以下又更佳,以50質量ppm以上800質量ppm以下再更佳。 The aforementioned palm oil is any palm oil obtained from oil palm fruit, and may be subjected to molecular distillation, fractionation, degumming, deacidification, decolorization, deodorization and other treatments. The methods of each treatment are not particularly limited, and generally, the methods used in the processing/purification of oils can be adopted. The total content of α-carotene and β-carotene in palm oil is not particularly limited, but preferably 50 mass ppm to 2000 mass ppm, more preferably 50 mass ppm to 1500 mass ppm, more preferably 50 mass ppm to 1000 mass ppm, and more preferably 50 mass ppm to 800 mass ppm.
前述乳脂係指從生乳、牛乳、特別牛乳等所得到的油脂含量為95質量%以上100質量%以下者。可列舉例如:無水乳脂、澄清奶油等。 無水乳脂係指從牛乳等去除乳脂脂肪以外之幾乎所有成分者,有時亦表示為AMF(Anhydrous Milk Fat、Butter Oil)等。澄清奶油係指分離出奶油之脂肪分者。在本發明使用之乳脂較佳係無水乳脂或澄清奶油,更佳係無水乳脂。又,乳脂之油脂含量較佳係98質量%以上100質量%以下,更佳係99質量%以上100質量%以下。 The aforementioned milk fat refers to the fat content obtained from raw milk, cow's milk, special cow's milk, etc., which is 95 mass% or more and 100 mass% or less. Examples include anhydrous milk fat, clarified butter, etc. Anhydrous milk fat refers to the removal of almost all components other than milk fat from cow's milk, etc., and is sometimes expressed as AMF (Anhydrous Milk Fat, Butter Oil), etc. Clarified butter refers to the separation of the fat content of butter. The milk fat used in the present invention is preferably anhydrous milk fat or clarified butter, and more preferably anhydrous milk fat. In addition, the fat content of milk fat is preferably 98 mass% or more and 100 mass% or less, and more preferably 99 mass% or more and 100 mass% or less.
又,就作為氧化處理之原料的油脂而言,較佳係包含含花生四烯酸的油脂(稱為含花生四烯酸(以下,亦稱為「AA」。)之油脂。)。花生四烯酸之來源並無特別限制,市面上販售有從各種動植物、微生物、藻類等所得者,發明所屬技術領域中具有一般知識者係可適當地使用此等公知者,較佳係源自微生物。含花生四烯酸的油脂中之花生四烯酸的含量並無特別限定,但以10質量%以上為佳,以20質量%以上更佳,以30質量%以上又更佳,以40質量%以上再更佳。 In addition, as for the oil used as the raw material for oxidation treatment, it is preferably an oil containing arachidonic acid (referred to as oil containing arachidonic acid (hereinafter, also referred to as "AA"). There is no particular restriction on the source of arachidonic acid. Arachidonic acid is obtained from various animals, plants, microorganisms, algae, etc., and those with general knowledge in the technical field to which the invention belongs can appropriately use these well-known ones, preferably derived from microorganisms. The content of arachidonic acid in arachidonic acid-containing oil is not particularly limited, but preferably 10% by mass or more, more preferably 20% by mass or more, more preferably 30% by mass or more, and more preferably 40% by mass or more.
又,作為前述氧化處理之原料的油脂係可單獨一種,亦可混合二種以上。 Furthermore, the oil or fat used as the raw material for the aforementioned oxidation treatment may be a single type or a mixture of two or more types.
就氧化油脂之氧化程度而言,以過氧化值作為指標時,一般在市場流通之食用油脂的過氧化值為0至10左右,較佳係其過氧化值高達15以上300以下左右。過氧化值(Peroxide value;以下有時稱為「POV」。)之範圍係在另一態樣時,可為25以上290以下之範圍,可為40以上270以下之範圍,亦可為60以上250以下之範圍。若過氧化值未達上述範圍,會有缺乏增強牛脂感之效果的傾向。若過氧化值超過上述範圍,會有風味變差之虞。過氧化值(POV)係可依據「基準油脂分析試驗法2.5.2過氧化值」(日本油化學會)進行測定。又,供應至氧化處理之油脂係可單獨使用一 種,亦可併用二種以上,但在併用二種以上時,只要在氧化處理後之混合油整體中的過氧化值為上述範圍內即可。又,亦可分別使二種以上之油脂進行氧化處理而混合,在氧化處理後進行混合而成的混合油整體中之過氧化值只要為上述範圍內即可。 Regarding the degree of oxidation of oxidized fats and oils, when the peroxide value is used as an indicator, the peroxide value of edible fats and oils generally circulated in the market is about 0 to 10, and the best peroxide value is about 15 or more and 300 or less. The range of peroxide value (Peroxide value; sometimes referred to as "POV" below) is in another aspect, it can be in the range of 25 or more and 290 or less, in the range of 40 or more and 270 or less, or in the range of 60 or more and 250 or less. If the peroxide value does not reach the above range, there will be a tendency to lack the effect of enhancing the beef fat feel. If the peroxide value exceeds the above range, there is a risk that the flavor will deteriorate. The peroxide value (POV) can be measured according to "Standard Oil Analysis Test Method 2.5.2 Peroxide Value" (Japan Oil Chemical Society). Furthermore, the fats and oils to be subjected to oxidation treatment may be used alone or in combination of two or more kinds. However, when two or more kinds are used in combination, the peroxide value of the mixed oil after oxidation treatment as a whole is within the above range. Furthermore, two or more kinds of fats and oils may be subjected to oxidation treatment separately and then mixed. The peroxide value of the mixed oil as a whole is within the above range as long as it is mixed after oxidation treatment.
在使油脂進行氧化處理而獲得氧化油脂之步驟中,使油脂進行氧化處理之方法係只要為可在上述預定範圍之過氧化值(POV)進行氧化處理的方法即可,並無特別限制,但較佳係可列舉進行加熱處理之方法。例如,從工業上規模進行生產的觀點而言,較佳係在桶槽等適當的容器中收納原料油脂之後,以容器具備之電熱式、火焰燃燒器式、微波式、蒸氣式、熱風式等加熱手段進行。 In the step of oxidizing the fat to obtain oxidized fat, the method of oxidizing the fat is not particularly limited as long as it can be oxidized at a peroxide value (POV) within the predetermined range, but preferably a method of heating the fat is used. For example, from the perspective of industrial scale production, it is better to store the raw fat in a suitable container such as a barrel and then use a heating method such as electric heating, flame burner, microwave, steam, hot air, etc. that the container has.
就加熱處理之條件而言,並無特別限制,但,較佳係在加熱溫度50℃以上220℃以下、加熱時間為0.1小時以上240小時以下進行,更佳係在加熱溫度60℃以上160℃以下、加熱時間為1小時以上100小時以下進行。又,就加熱溫度(℃)×加熱時間(小時)之累積量的條件而言,典型上為200以上20000以下,另一態樣時,可為220以上18000以下之範圍,亦可為240以上15000以下之範圍。又,改變加熱溫度時,加熱溫度(℃)×加熱時間(小時)之累積量係可設為改變溫度前之加熱溫度(℃)×改變溫度前之加熱時間(小時)+改變溫度後之加熱溫度(℃)×改變溫度後之加熱時間(小時)、或隨著加熱時間(小時)之加熱溫度(℃)的積分值而計算出。 There is no particular limitation on the conditions for the heat treatment, but it is preferably carried out at a heating temperature of 50°C to 220°C and a heating time of 0.1 hour to 240 hours, and more preferably at a heating temperature of 60°C to 160°C and a heating time of 1 hour to 100 hours. In addition, the cumulative amount of the heating temperature (°C) × heating time (hours) is typically 200 to 20,000, and in another aspect, it can be in the range of 220 to 18,000, or in the range of 240 to 15,000. Furthermore, when the heating temperature is changed, the cumulative amount of heating temperature (℃) × heating time (hours) can be set as heating temperature before temperature change (℃) × heating time before temperature change (hours) + heating temperature after temperature change (℃) × heating time after temperature change (hours), or calculated as the integral value of heating temperature (℃) along with heating time (hours).
在加熱處理之際,藉由攪拌而從容器之開放空間取入氧或吹入氧而可供給氧(空氣)。氧源係可使用空氣等。藉由此而促進油脂之氧化。其時,就氧之供給量而言,較佳係上述油脂每1kg成為0.001至2L/分 鐘。例如,空氣之情形,較佳係上述油脂每1kg為0.005至10L/分鐘,更佳係0.01至5L/分鐘。 During the heating treatment, oxygen (air) can be supplied by stirring and taking oxygen from the open space of the container or blowing oxygen in. The oxygen source can be air, etc. This promotes the oxidation of fats and oils. At this time, the supply of oxygen is preferably 0.001 to 2 L/min per 1 kg of the above-mentioned fats and oils. For example, in the case of air, it is preferably 0.005 to 10 L/min per 1 kg of the above-mentioned fats and oils, and more preferably 0.01 to 5 L/min.
(氧化油脂藉由酵素水解而成的水解物) (Hydrolysate formed by the hydrolysis of oxidized fats by enzymes)
在本發明中未被限定的任意之態樣時,就上述氧化油脂而言,可使用將該氧化油脂進一步藉由酵素水解而成的該水解物(以下,亦僅稱為「水解物」。)。此時,水解物處理係只要在上述氧化油脂中所含的甘油脂肪酸等脂肪酸之酯化體受到藉由酵素的水解,只要使該脂肪酸進行游離以提高該脂肪酸之含量即可,並無特別限制,但,較佳係使用脂酶作為酵素。又,在本說明書中所謂「氧化油脂」亦包含如此的「水解物」之概念,又,藉由酵素而水解之程度亦包含從氧化油脂未藉由酵素水解的狀態者至充分水解的狀態者之概念。 In any form not limited in the present invention, the hydrolyzate obtained by further hydrolyzing the oxidized fat by enzyme (hereinafter referred to as "hydrolyzate") can be used for the above-mentioned oxidized fat. At this time, the hydrolyzate treatment is not particularly limited as long as the esterified fatty acids such as glycerol fatty acids contained in the above-mentioned oxidized fat are hydrolyzed by enzyme, and the fatty acids are released to increase the content of the fatty acids. However, it is preferred to use lipase as the enzyme. In addition, the so-called "oxidized fat" in this specification also includes the concept of such "hydrolyzate", and the degree of hydrolysis by enzyme also includes the concept from the state where the oxidized fat is not hydrolyzed by enzyme to the state where it is fully hydrolyzed.
就水解物之水解的程度而言,以反映油脂中之游離脂肪酸含量的酸值作為指標時,一般在市場流通的食用油脂之酸值為0至1左右,其酸值較佳係提高至5以上200以下左右者。酸值(Acid value;以下,有時稱為「AV」。)之範圍在另一態樣時,可為10以上190以下之範圍,可為20以上180以下之範圍,亦可為30以上170以下之範圍。若酸值未達上述範圍,則有增強牛脂感之效果不足的傾向。若酸值超過上述範圍,則有風味變差之虞。酸值(AV)係可依據「基準油脂分析試驗法2.3.1酸值」(日本油化學會)進行測定。又,藉由酵素而水解之處理中所供應之氧化油脂係可單獨使用一種,亦可併用二種以上,但併用二種以上時,只要在水解處理後之混合油整體中的酸值為上述範圍內即可。又,亦可使二種以上之 油脂分別藉由酵素進行水解處理而混合,在水解處理後混合而成的混合油整體中之酸值(AV)只要為上述範圍內即可。 Regarding the degree of hydrolysis of the hydrolyzate, when the acid value reflecting the free fatty acid content in the oil is used as an indicator, the acid value of edible oils and fats generally circulated in the market is about 0 to 1, and the acid value is preferably increased to about 5 or more and 200 or less. In another aspect, the range of the acid value (Acid value; hereinafter, sometimes referred to as "AV") can be in the range of 10 or more and 190 or less, in the range of 20 or more and 180 or less, or in the range of 30 or more and 170 or less. If the acid value does not reach the above range, there is a tendency that the effect of enhancing the beef fat texture is insufficient. If the acid value exceeds the above range, there is a risk that the flavor will deteriorate. The acid value (AV) can be measured according to "Standard Oil Analysis Test Method 2.3.1 Acid Value" (Japan Oil Chemical Society). Furthermore, the oxidized fats and oils used in the hydrolysis treatment by enzymes may be used alone or in combination of two or more kinds. However, when two or more kinds are used in combination, the acid value of the mixed oil after the hydrolysis treatment is within the above range. Furthermore, two or more kinds of fats and oils may be mixed after being hydrolyzed by enzymes respectively. The acid value (AV) of the mixed oil after the hydrolysis treatment is within the above range.
就藉由酵素進行水解處理之方法而言,只要為以上述氧化油脂作為原料,並進行水解處理至上述預定範圍之酸值(AV)的方法即可,並無特別限制,較佳係可列舉使用脂酶作為酵素之方法。就所使用之脂酶而言,例如,可為源自微生物、源自動物、源自植物之任一者,並無特別限制,其中亦以使用源自微生物之脂酶為佳。就微生物而言,可列舉例如:絲狀真菌(泡盛亮黑麴黴:Aspergillus awamori、黑麴菌:Aspergillus niger、綠麴菌:Aspergillus oryzae、醬油麴菌:Aspergillus phoenicis、宇佐美麴霉:Aspergillus usamii、白地絲黴菌:Geotrichum candidum、腐質黴菌:Humicola、爪哇毛黴:Mucor javanicus、米黑毛黴菌:Mucor miehei、卡門柏青黴:Penicillium camembertii、金黃青黴:Penicillium chrysogenum、羅克福青黴菌:Penicillum roqueforti、米氏假根毛黴:Rhizornucor miehei、戴爾根黴:Rhizopus delemar、日本根黴:Rhizopus japonicus、米氏假根毛黴:Rhizomucor miehei、米根黴菌:Rhizopus niveus、酒麴菌:Rhizopus oryzae)、放射菌(Streptomyces)、細菌(產鹼菌:Alcaligenes、節桿菌:Arthrobactor、黏性染色菌:Chromobacterium viscosum、假單孢菌:Pseudomonas、黏質沙雷氏菌Serratia marcescens)、酵母(念珠菌:Candida)等。其中,以使用Candida屬之脂酶為佳。 As for the method of hydrolysis treatment by enzyme, there is no particular limitation as long as the above-mentioned oxidized fat is used as a raw material and the acid value (AV) is hydrolyzed to the above-mentioned predetermined range. Preferably, a method using lipase as an enzyme can be listed. As for the lipase used, for example, it can be any of those derived from microorganisms, animals, and plants, and there is no particular limitation. Among them, it is also preferred to use lipase derived from microorganisms. As for microorganisms, for example, filamentous fungi (Aspergillus awamori, Aspergillus niger, Aspergillus oryzae, Aspergillus phoenicis, Aspergillus usamii, Geotrichum candidum, Humicola, Mucor javanicus, Mucor miehei, Penicillium camembertii, Penicillium chrysogenum, Penicillium roqueforti, Rhizornucor miehei, Rhizopus delemar, Rhizopus japonicus, Rhizomucor miehei, Rhizopus niveus, Rhizopus oryzae), Streptomyces, bacteria (Alcaligenes, Arthrobacter, Chromobacterium viscosum, Pseudomonas, Serratia marcescens), yeast (Candida), etc. Among them, it is best to use lipase from the genus Candida.
酵素係可單獨使用一種,亦可併用二種以上。又,併用二種以上時,可在反應系同時添加複數種之酵素,添加一種酵素使其進行反應 處理,然後在其反應結束後,添加另一種酵素,藉由該酵素進行反應等依序添加。又,亦可在單獨使用一種時,將一種酵素分成複數次而添加。 Enzymes can be used alone or in combination. When two or more enzymes are used in combination, multiple enzymes can be added to the reaction system at the same time, one enzyme is added to react, and then after the reaction is completed, another enzyme is added to react with the enzyme, etc. In addition, when using one enzyme alone, one enzyme can be added in multiple times.
藉由酵素水解之反應條件而言,只要適當地選擇適用於所使用的酵素之溫度、pH、反應時間等之條件即可。典型上,例如,若在使用脂酶時,如為不使脂酶失活的溫度即可,在另一態樣時,可為20℃以上70℃以下之範圍,可為25℃以上60℃以下之範圍,亦可為30℃以上50℃以下之範圍。又,反應時間係例如,只要為0.05小時以上120小時以下即可,在另一態樣時,可為0.1小時以上72小時以下之範圍,可為0.2小時以上48小時以下之範圍,亦可為0.3小時以上30小時以下之範圍。又,酵素對氧化油脂之添加量係例如,只要為0.001質量%以上40質量%以下即可,在另一態樣時,可為0.005質量%以上30質量%以下之範圍,可為0.01質量%以上20質量%以下之範圍,亦可為0.05質量%以上10質量%以下之範圍。 As for the reaction conditions of the enzymatic hydrolysis, it is sufficient to appropriately select the conditions such as the temperature, pH, reaction time, etc. suitable for the enzyme used. Typically, for example, when using lipase, the temperature may be such that the lipase is not inactivated. In another aspect, it may be in the range of 20°C to 70°C, in the range of 25°C to 60°C, or in the range of 30°C to 50°C. In addition, the reaction time may be, for example, in the range of 0.05 hours to 120 hours. In another aspect, it may be in the range of 0.1 hours to 72 hours, in the range of 0.2 hours to 48 hours, or in the range of 0.3 hours to 30 hours. In addition, the amount of enzyme added to the oxidized fat is, for example, 0.001 mass% to 40 mass%. In another embodiment, it can be 0.005 mass% to 30 mass%, 0.01 mass% to 20 mass%, or 0.05 mass% to 10 mass%.
一般在藉由酵素水解之反應中,存在一定之水分者,會有效地引起反應之傾向。因而,在水解處理時,可在加入預定量之水分後進行。此時,藉由加水,相對於氧化油脂之100質量份,較佳係水分設為10質量份以上1000質量份以下,更佳係設為20質量份以上800質量份以下,又更佳係設為40質量份以上600質量份以下,再更佳係設為60質量份以上500質量份以下。 Generally, in the reaction of enzyme hydrolysis, the presence of a certain amount of water will effectively cause the reaction tendency. Therefore, during the hydrolysis treatment, it can be carried out after adding a predetermined amount of water. At this time, by adding water, relative to 100 parts by mass of oxidized fats and oils, it is better to set the water content to be 10 parts by mass or more and 1000 parts by mass or less, more preferably to set it to be 20 parts by mass or more and 800 parts by mass or less, more preferably to set it to be 40 parts by mass or more and 600 parts by mass or less, and even more preferably to set it to be 60 parts by mass or more and 500 parts by mass or less.
在藉由酵素水解之處理後,雖為任意,但可進行酵素之失活處理。就酵素失活處理而言,較佳係在25至110℃進行1分鐘至2小時左右之加熱處理。又,為了分開油層與水層,較佳係進行離心並回收油層。 再者,較佳亦在所回收之油層中添加淡水,並進行水洗後,進行離心以再度分開油層與水層,並回收油層。藉此,可從油層去除水溶性之雜質。 After the enzyme hydrolysis treatment, the enzyme inactivation treatment may be performed, although it is optional. For the enzyme inactivation treatment, it is preferably heated at 25 to 110°C for about 1 minute to 2 hours. In addition, in order to separate the oil layer and the water layer, it is preferably centrifuged and the oil layer is recovered. Furthermore, it is also preferable to add fresh water to the recovered oil layer, wash it with water, centrifuge it to separate the oil layer and the water layer again, and recover the oil layer. In this way, water-soluble impurities can be removed from the oil layer.
本發明之油脂組成物係可含有上述牛脂及氧化油脂以外之食用油脂。就前述食用油脂而言,可列舉例如:菜籽油、大豆油、棕櫚油、棕櫚仁油、玉米油、橄欖油、芝麻油、紅花油、葵花油、棉籽油、米油、花生油、椰子油、可可油等植物性油脂;豬油、雞油、乳脂等動物性油脂;中鏈脂肪酸三酸甘油酯等。尚且,可列舉此等之分餾油(棕櫚油之中融點部分、棕櫚油之軟質分餾油、棕櫚油之硬質分餾油等)、酯交換油、氫化油等加工油脂等。就前述食用油脂而言,以包含植物性油脂為佳,更佳係包含選自菜籽油、大豆油、棕櫚油、玉米油及米油中之至少1種,又更佳係包含選自棕櫚油及米油中之至少1種,再更佳係包含米油。前述食用油脂係可一種單獨,亦可混合二種以上。又,本發明之油脂組成物包含米油時,該米油係可包含米胚芽油。 The fat composition of the present invention may contain edible fats and oils other than the above-mentioned beef tallow and oxidized fats and oils. As for the above-mentioned edible fats and oils, for example, vegetable fats and oils such as rapeseed oil, soybean oil, palm oil, palm kernel oil, corn oil, olive oil, sesame oil, safflower oil, sunflower oil, cottonseed oil, rice oil, peanut oil, coconut oil, cocoa butter, etc.; animal fats and oils such as lard, chicken oil, and butter fat; medium-chain fatty acid triglycerides, etc. Moreover, the fractionated oils (melting point part of palm oil, soft fractionated oil of palm oil, hard fractionated oil of palm oil, etc.), ester exchange oil, hydrogenated oil, etc., processed fats and oils, etc., can be listed. As for the aforementioned edible oil, it is preferred to include vegetable oil, more preferably at least one selected from rapeseed oil, soybean oil, palm oil, corn oil and rice oil, more preferably at least one selected from palm oil and rice oil, and even more preferably rice oil. The aforementioned edible oil may be a single type or a mixture of two or more types. In addition, when the oil composition of the present invention includes rice oil, the rice oil may include rice germ oil.
本發明之油脂組成物中,在無損所希望之牛脂感增強的功能性之範圍,可適當地調配一般添加於食用之助劑。就助劑而言,可列舉抗氧化劑、消泡劑、乳化劑、香料、風味賦予劑、色素、生理活性物質等。具體而言,可列舉例如:抗壞血酸脂肪酸酯、木脂素、輔酶Q、γ-穀維素、生育酚、矽樹脂等。 In the oil composition of the present invention, additives generally added to food can be appropriately formulated within the scope of not damaging the desired functionality of enhancing the beef fat texture. As additives, antioxidants, defoaming agents, emulsifiers, spices, flavoring agents, pigments, physiologically active substances, etc. can be listed. Specifically, for example, ascorbic acid fatty acid esters, lignans, coenzyme Q, γ-glutenin, tocopherol, silicone resin, etc. can be listed.
本發明之油脂組成物中之前述氧化油脂的含量並無特別限定,惟以0.001質量%以上10質量%以下為佳,以0.005質量%以上10質量%以下更佳,以0.01質量%以上10質量%以下又更佳,以0.03質量%以上7質量%以下再更佳,又以0.05質量%以上5質量%以下為佳,以0.1 質量%以上3質量%以下更佳,以0.15質量%以上2質量%以下為特佳。又,較佳係在油脂組成物中以充分分散之狀態含有氧化油脂。 The content of the aforementioned oxidized fat in the fat composition of the present invention is not particularly limited, but preferably 0.001 mass% to 10 mass%, more preferably 0.005 mass% to 10 mass%, even more preferably 0.01 mass% to 10 mass%, even more preferably 0.03 mass% to 7 mass%, even more preferably 0.05 mass% to 5 mass%, even more preferably 0.1 mass% to 3 mass%, and particularly preferably 0.15 mass% to 2 mass%. In addition, it is preferred that the oxidized fat is contained in the fat composition in a fully dispersed state.
本發明之油脂組成物中包含植物性油脂進行氧化處理而成的氧化油脂時,油脂組成物中之前述植物性油脂進行氧化處理而成的氧化油脂之含量並無特別限定,惟以0.001質量%以上5質量%以下為佳,以0.01質量%以上5質量%以下更佳,以0.02質量%以上4質量%以下又更佳,以0.03質量%以上3質量%以下再更佳,以0.04質量%以上2質量%以下又再更佳,以0.05質量%以上1質量%以下為特佳。又,植物性油脂為選自葵花油及棕櫚系油脂中之至少1種時的較佳含量亦與上述相同。 When the oil composition of the present invention contains oxidized oils and fats obtained by oxidation of vegetable oils and fats, the content of the oxidized oils and fats obtained by oxidation of the vegetable oils and fats in the oil composition is not particularly limited, but preferably 0.001% by mass to 5% by mass, more preferably 0.01% by mass to 5% by mass, more preferably 0.02% by mass to 4% by mass, more preferably 0.03% by mass to 3% by mass, more preferably 0.04% by mass to 2% by mass, and particularly preferably 0.05% by mass to 1% by mass. In addition, the preferred content of vegetable oils and fats when they are at least one selected from sunflower oil and palm oils and fats is the same as above.
本發明之油脂組成物中包含乳脂進行氧化處理而成的氧化油脂時,油脂組成物中之前述乳脂進行氧化處理而成的氧化油脂之含量並無特別限定,惟以0.001質量%以上5質量%以下為佳,以0.01質量%以上5質量%以下更佳,以0.02質量%以上4質量%以下又更佳,以0.03質量%以上3質量%以下再更佳,又以0.04質量%以上2質量%以下為佳,以0.05質量%以上1質量%以下為特佳。 When the fat composition of the present invention contains oxidized fats obtained by oxidation of milk fat, the content of the oxidized fats obtained by oxidation of milk fat in the fat composition is not particularly limited, but preferably 0.001% by mass to 5% by mass, more preferably 0.01% by mass to 5% by mass, more preferably 0.02% by mass to 4% by mass, more preferably 0.03% by mass to 3% by mass, more preferably 0.04% by mass to 2% by mass, and particularly preferably 0.05% by mass to 1% by mass.
本發明之油脂組成物中包含微生物油脂進行氧化處理而成的氧化油脂時,油脂組成物中之前述微生物油脂進行氧化處理而成的氧化油脂之含量並無特別限定,惟以0.0001質量%以上3質量%以下為佳,以0.001質量%以上1質量%以下更佳,以0.002質量%以上0.5質量%以下又更佳,以0.003質量%以上0.3質量%以下再更佳,以0.005質量%以上0.1質量%以下為特佳。 When the fat composition of the present invention contains oxidized fats obtained by oxidation of microbial fats, the content of the oxidized fats obtained by oxidation of the microbial fats in the fat composition is not particularly limited, but preferably 0.0001% by mass to 3% by mass, more preferably 0.001% by mass to 1% by mass, more preferably 0.002% by mass to 0.5% by mass, more preferably 0.003% by mass to 0.3% by mass, and particularly preferably 0.005% by mass to 0.1% by mass.
本發明之油脂組成物中包含含花生四烯酸的油脂進行氧化處理而成的氧化油脂時,油脂組成物中之前述含花生四烯酸的油脂進行氧化處理而成的氧化油脂之含量並無特別限定,惟以0.0001質量%以上3質量%以下為佳,以0.001質量%以上1質量%以下更佳,以0.002質量%以上0.5質量%以下又更佳,以0.003質量%以上0.3質量%以下再更佳,以0.005質量%以上0.1質量%以下為特佳。 When the oil composition of the present invention contains oxidized oils obtained by oxidation of oils containing arachidonic acid, the content of the oxidized oils obtained by oxidation of the oils containing arachidonic acid in the oil composition is not particularly limited, but is preferably 0.0001% by mass to 3% by mass, more preferably 0.001% by mass to 1% by mass, more preferably 0.002% by mass to 0.5% by mass, more preferably 0.003% by mass to 0.3% by mass, and particularly preferably 0.005% by mass to 0.1% by mass.
本發明之油脂組成物中包含水解物時,油脂組成物中之前述水解物的含量並無特別限定,惟以0.001質量%以上10質量%以下為佳,以0.005質量%以上10質量%以下更佳,以0.01質量%以上10質量%以下又更佳,以0.02質量%以上5質量%以下再更佳,又以0.03質量%以上3質量%以下為佳,以0.05質量%以上2質量%以下更佳,以0.1質量%以上1質量%以下為特佳。又,較佳係在油脂組成物中以充分分散之狀態含有水解物。 When the oil composition of the present invention contains a hydrolyzate, the content of the aforementioned hydrolyzate in the oil composition is not particularly limited, but preferably 0.001 mass% to 10 mass% is preferred, 0.005 mass% to 10 mass% is more preferred, 0.01 mass% to 10 mass% is even more preferred, 0.02 mass% to 5 mass% is even more preferred, 0.03 mass% to 3 mass% is even more preferred, 0.05 mass% to 2 mass% is even more preferred, and 0.1 mass% to 1 mass% is particularly preferred. In addition, it is preferred that the hydrolyzate is contained in the oil composition in a fully dispersed state.
本發明之油脂組成物中包含米油時,油脂組成物中之米油的含量並無特別限定,惟以0.05質量%以上20質量%以下為佳,以0.1質量%以上15質量%以下更佳,以0.3質量%以上10質量%以下又更佳,以0.5質量%以上5質量%以下再更佳,以0.8質量%以上3質量%以下為特佳。 When the oil composition of the present invention includes rice oil, the content of rice oil in the oil composition is not particularly limited, but preferably 0.05% by mass to 20% by mass, more preferably 0.1% by mass to 15% by mass, more preferably 0.3% by mass to 10% by mass, more preferably 0.5% by mass to 5% by mass, and particularly preferably 0.8% by mass to 3% by mass.
本發明之油脂組成物中之牛脂的含量並無特別限定,惟以未達100質量%者為佳,以90質量%以下更佳,以70質量%以下又更佳,以50質量%以下再更佳,以40質量%以下為特佳。又,油脂組成物中之 牛脂之含量係例如,可為5質量%以上、8質量%以上、10質量%以上、15質量%以上、20質量%以上等。 The content of beef tallow in the fat composition of the present invention is not particularly limited, but preferably less than 100% by mass, more preferably less than 90% by mass, more preferably less than 70% by mass, more preferably less than 50% by mass, and particularly preferably less than 40% by mass. In addition, the content of beef tallow in the fat composition may be, for example, more than 5% by mass, more than 8% by mass, more than 10% by mass, more than 15% by mass, more than 20% by mass, etc.
本發明之油脂組成物之形態並無特別限定。更具體而言,例如,調配賦形劑、助劑、乳化劑、pH調整劑等,藉由公知之手法,可成為液體狀、粉末狀、膏狀等任意之形態的油脂組成物。亦即,例如,通常發明所屬技術領域中具有一般知識者依據周知之製劑的技術,可調配於以油脂成分作為主體之液體油脂、人造奶油、抹醬、酥油、粉末油脂等,或者,可調配於油脂成分之調配量少的溶液狀、粉末狀、凝膠狀、顆粒狀等,可任意採用其等形態。又,例如,進行粉末化時,可使用玉米糖漿等助劑,再者,添加乳化劑而調製乳化原料之後,可將此進行粉末化。粉末化之手段係可列舉噴霧乾燥、冷凍乾燥等。 The form of the fat composition of the present invention is not particularly limited. More specifically, for example, by mixing with a formulator, an auxiliary agent, an emulsifier, a pH adjuster, etc., a fat composition in any form such as a liquid, a powder, or a paste can be obtained by a known method. That is, for example, a person with general knowledge in the technical field to which the invention belongs can be mixed with liquid fats, margarine, spreads, ghee, powdered fats, etc. with fat components as the main body according to the known preparation technology, or it can be mixed with a solution, powder, gel, granular, etc. with a small amount of fat components, and any form thereof can be adopted. In addition, for example, when powdering, an auxiliary agent such as corn syrup can be used. Furthermore, after adding an emulsifier and mixing the emulsified raw materials, it can be powdered. The methods of powderization include spray drying, freeze drying, etc.
(牛脂感增強的油脂組成物之製造方法) (Method for producing a fat composition with enhanced beef tallow texture)
本發明之牛脂感增強的油脂組成物之製造方法係包含下列步驟:將油脂進行氧化處理而獲得氧化油脂之步驟;及,在包含牛脂之食用油脂中添加前述氧化油脂之步驟。在獲得前述氧化油脂之步驟中,將油脂進行氧化處理之方法係如前述。在添加前述氧化油脂之步驟中,添加氧化油脂之方法並無特別限定,而可藉由混合、溶解、分散、乳化、注入等任意之方法添加。 The method for producing the fat composition with enhanced beef tallow texture of the present invention comprises the following steps: a step of oxidizing fat to obtain oxidized fat; and a step of adding the oxidized fat to edible fat containing beef tallow. In the step of obtaining the oxidized fat, the method of oxidizing the fat is as described above. In the step of adding the oxidized fat, the method of adding the oxidized fat is not particularly limited, and the oxidized fat can be added by any method such as mixing, dissolving, dispersing, emulsifying, and injecting.
本發明之牛脂感增強的油脂組成物之製造方法較佳係包含牛脂之食用油脂中更添加米油之步驟。在添加前述米油之步驟中,添加米油之方法並無特別限定,可藉由混合、溶解、分散、乳化、注入等任意之方法進行添加。 The method for producing the fat composition with enhanced beef tallow flavor of the present invention preferably includes the step of adding rice oil to the edible fat of beef tallow. In the step of adding the rice oil, the method of adding the rice oil is not particularly limited, and the rice oil can be added by any method such as mixing, dissolving, dispersing, emulsifying, and injecting.
<2.牛脂感增強劑> <2. Beef fat enhancer>
本發明之牛脂感增強劑係含有氧化油脂作為有效成分。本發明之牛脂感增強劑較佳係更含有米油作為有效成分。 The beef fat enhancer of the present invention contains oxidized fat as an active ingredient. The beef fat enhancer of the present invention preferably contains rice oil as an active ingredient.
前述氧化油脂係如前述「1.經增強牛脂感之油脂組成物」所述。較佳係含有選自植物性油脂、乳脂、及微生物油脂之至少1種的油脂進行氧化處理而成之氧化油脂。 The aforementioned oxidized fat is as described in the aforementioned "1. Fat composition with enhanced beef fat texture". Preferably, it is an oxidized fat containing at least one type of fat selected from vegetable fat, milk fat, and microbial fat, which is oxidized.
前述氧化油脂較佳係包含前述氧化油脂藉由酵素水解而成的水解物。前述水解物係如前述「1.經增強牛脂感之油脂組成物」所述。 The aforementioned oxidized fat preferably includes a hydrolyzate formed by hydrolyzing the aforementioned oxidized fat by enzyme. The aforementioned hydrolyzate is as described in the aforementioned "1. Fat composition with enhanced beef tallow texture".
本發明之牛脂感增強劑中,在無損所希望之牛脂感增強的功能性之範圍,可適當地調配一般添加於食用之助劑。就助劑而言,可列舉如:抗氧化劑、消泡劑、乳化劑、香料、風味賦予劑、色素、生理活性物質等。具體而言,可列舉例如:抗壞血酸脂肪酸酯、木脂素、輔酶Q、γ-穀維素、生育酚、矽樹脂等。 In the beef fat enhancer of the present invention, additives generally added to food can be appropriately formulated within the scope of not impairing the desired beef fat enhancement functionality. As for additives, they can include antioxidants, defoaming agents, emulsifiers, spices, flavoring agents, pigments, physiologically active substances, etc. Specifically, they can include ascorbic acid fatty acid esters, lignans, coenzyme Q, γ-glutenin, tocopherol, silicone resin, etc.
就本發明之牛脂感增強劑中之氧化油脂的含量而言,並無特別限定,惟以0.1質量%以上為佳,以1質量%以上更佳,以2質量%以上又更佳,以5質量%以上再更佳,以10質量%以上為特佳。又,可為100質量%以下、99質量%以下、98質量%以下、90質量%以下、80質量%以下、70質量%以下、60質量%以下、50質量%以下等。又,前述之提供氧化油脂的原材料本身可構成前述牛脂感增強劑。 There is no particular limitation on the content of oxidized fat in the beef tallow enhancer of the present invention, but it is preferably 0.1% by mass or more, more preferably 1% by mass or more, even more preferably 2% by mass or more, even more preferably 5% by mass or more, and particularly preferably 10% by mass or more. In addition, it can be less than 100% by mass, less than 99% by mass, less than 98% by mass, less than 90% by mass, less than 80% by mass, less than 70% by mass, less than 60% by mass, less than 50% by mass, etc. In addition, the raw material for providing oxidized fat itself can constitute the beef tallow enhancer.
本發明之牛脂感增強劑中包含水解物時,牛脂感增強劑中之前述水解物的含量並無特別限定,惟以0.1質量%以上為佳,以1質量%以上更佳,以2質量%以上又更佳,以5質量%以上再更佳,以7質量%以上 為特佳。又,可為100質量%以下、99質量%以下、98質量%以下、90質量%以下、80質量%以下、70質量%以下、60質量%以下、50質量%以下等。又,前述之提供水解物的原材料本身可構成前述牛脂感增強劑。 When the beef fat enhancer of the present invention contains hydrolyzate, the content of the aforementioned hydrolyzate in the beef fat enhancer is not particularly limited, but preferably 0.1% by mass or more, more preferably 1% by mass or more, even more preferably 2% by mass or more, even more preferably 5% by mass or more, and particularly preferably 7% by mass or more. In addition, it can be less than 100% by mass, less than 99% by mass, less than 98% by mass, less than 90% by mass, less than 80% by mass, less than 70% by mass, less than 60% by mass, less than 50% by mass, etc. In addition, the raw material for providing the hydrolyzate itself can constitute the aforementioned beef fat enhancer.
本發明之牛脂感增強劑中包含米油時,牛脂感增強劑中之米油的含量並無特別限定,惟以1質量%以上為佳,以5質量%以上更佳,以10質量%以上又更佳,以20質量%以上再更佳,以30質量%以上為特佳。又,可為未達100質量%、99.9質量%以下、99質量%以下、90質量%以下等。 When the beef fat enhancer of the present invention contains rice oil, the content of rice oil in the beef fat enhancer is not particularly limited, but preferably 1% by mass or more, more preferably 5% by mass or more, more preferably 10% by mass or more, more preferably 20% by mass or more, and particularly preferably 30% by mass or more. In addition, it may be less than 100% by mass, less than 99.9% by mass, less than 99% by mass, less than 90% by mass, etc.
<3.油脂組成物或牛脂感增強劑之應用> <3. Application of fat compositions or beef tallow enhancers>
本發明之油脂組成物或牛脂感增強劑之使用形態並無特別限制。例如,將前述油脂組成物或前述牛脂感增強劑對食品之原料或製造步驟之中間物等以任意之時點藉由進行添加、混合、塗佈、溶解、分散、乳化、注入等,即可增強所得到的食品之牛脂感。又,不僅對原料或製造步驟之中間物之添加等,在食品之烹調、加工、或者製造等之後,藉由將前述油脂組成物進行撒布或塗覆等,即可添加於該食品中。再者,藉由食品之烹調、加工、或者製造等中之鬆散油、炊飯油、炸物油、炒菜油等烹調用油、拌菜油、噴油及風味油等調味用油等含有前述油脂組成物或前述牛脂感增強劑而使用等,可添加於該食品中。本發明之油脂組成物或牛脂感增強劑較佳係使用於烹調用油,更佳係使用於油炸烹調用油。藉由將本發明之油脂組成物或牛脂感增強劑使用於油炸烹調用油,可增強所得到的油炸食品之牛脂感。因此,本發明之油脂組成物係可使用來作為食品之牛脂感增強用烹調用油。 The use form of the fat composition or the beef fat enhancer of the present invention is not particularly limited. For example, the fat composition or the beef fat enhancer can be added, mixed, applied, dissolved, dispersed, emulsified, injected, etc. to the raw materials or intermediates of the manufacturing process of food at any time to enhance the beef fat taste of the obtained food. In addition, the fat composition can be added to the raw materials or intermediates of the manufacturing process. After the food is cooked, processed, or manufactured, the fat composition can be added to the food by spreading or coating. Furthermore, the aforementioned fat composition or the aforementioned beef fat enhancer can be added to the food by using the cooking oil, cooking oil, frying oil, cooking oil, cooking oil, seasoning oil, such as loose oil, cooking oil, spray oil, and flavoring oil in the cooking, processing, or manufacturing of the food. The fat composition or beef fat enhancer of the present invention is preferably used in cooking oil, and more preferably in deep-frying cooking oil. By using the fat composition or beef fat enhancer of the present invention in deep-frying cooking oil, the beef fat feel of the obtained deep-fried food can be enhanced. Therefore, the fat composition of the present invention can be used as a cooking oil for enhancing the beef fat feel of food.
可應用本發明之食品並無特別限定,但,可列舉例如:蛋糕、麵包等烘焙食品;玉米湯、清肉湯等湯品類;燉牛肉、奶油燉菜等燉物類;奶飲料等飲料;燒肉、叉燒等肉品加工食品;魚板、魚肉香腸等水產加工食品;炸麵包、炸咖哩包、皮羅什基(piroshki)、美式熱狗、麵包丁、炸米菓、零食、包衣炸物類、炸豬排、鹽酥雞、香雞排、天婦羅、可樂餅、炸肉餅、炸馬鈴薯、炸雞塊、薯餅等油炸食品等。較佳係應用於油炸食品。 The food to which the present invention can be applied is not particularly limited, but examples thereof include: baked food such as cakes and bread; soups such as corn soup and broth; stews such as beef stew and stewed vegetables; beverages such as milk drinks; processed meat food such as grilled meat and barbecued pork; processed seafood food such as fish cake and fish sausage; fried bread, fried curry buns, piroshki, American hot dogs, bread cubes, fried rice cakes, snacks, coated fried food, fried pork chops, fried chicken, fried chicken chops, tempura, croquettes, fried meat cakes, fried potatoes, fried chicken nuggets, potato cakes and other fried foods. It is preferably applied to fried foods.
又,可應用本發明之食品的範圍並不限定於人類用者,亦可應用於動物用之餌或飼料等。 Furthermore, the scope of food to which the present invention can be applied is not limited to that for human use, but can also be applied to bait or feed for animals, etc.
(油炸食品之製造方法) (Method for producing fried food)
本發明之油炸食品之製造方法係包含下列步驟:使用包含前述油脂組成物或前述牛脂感增強劑之炸物油將物料進行油炸烹調之步驟。油炸烹調之方法等並無特別限定,可依照油炸食品之種類而適當地決定烹調方法、加熱溫度、加熱時間等。 The method for producing fried food of the present invention comprises the following steps: using frying oil containing the aforementioned fat composition or the aforementioned beef fat enhancer to fry the material. The frying cooking method is not particularly limited, and the cooking method, heating temperature, heating time, etc. can be appropriately determined according to the type of fried food.
(油炸食品之牛脂感增強方法) (Methods to enhance the beef fat texture of fried foods)
本發明之油炸食品的牛脂感增強方法其特徵係使用包含前述油脂組成物或前述牛脂感增強劑之炸物油將物料進行油炸烹調者。包含前述油脂組成物或前述牛脂感增強劑之炸物油係成為增強有牛脂感的炸物油,故可藉由油炸烹調而增強含有該炸物油之油炸食品的牛脂感。 The method for enhancing the beef fat taste of fried food of the present invention is characterized in that the material is fried in frying oil containing the aforementioned fat composition or the aforementioned beef fat taste enhancer. The frying oil containing the aforementioned fat composition or the aforementioned beef fat taste enhancer becomes a frying oil with enhanced beef fat taste, so the beef fat taste of fried food containing the frying oil can be enhanced by frying.
[實施例] [Implementation example]
以下,列舉試驗例而更具體地說明本發明,但此等試驗例並非限定本發明之範圍者。 The following test examples are given to more specifically illustrate the present invention, but these test examples do not limit the scope of the present invention.
以下,呈示使用於試驗之材料。 The following are the materials used in the test.
<原料油脂> <Raw material oils and fats>
‧牛脂:MIYOSHI油脂股份有限公司製「食用牛脂」 ‧Beef tallow: "Edible beef tallow" produced by MIYOSHI Oils & Fats Co., Ltd.
‧棕櫚油:J-OILMILLS股份有限公司製「棕櫚油酸IV67」 ‧Palm oil: "Palm oleic acid IV67" manufactured by J-OILMILLS Co., Ltd.
‧米胚芽油:築野食品工業股份有限公司製「米胚芽油」 ‧Rice germ oil: "Rice germ oil" manufactured by Tsukuye Food Industry Co., Ltd.
‧無水乳脂:丸和油脂股份有限公司製「BUTTER OIL CML」(油脂含量99.8質量%) ‧Anhydrous milk fat: "BUTTER OIL CML" manufactured by Maruwa Oil Co., Ltd. (oil content 99.8% by mass)
‧含花生四烯酸的三酸甘油酯(AATG):日本水產股份有限公司製「SUNTG ‧Arachidonic acid-containing triglycerides (AAT-): "SUNTG" manufactured by Nippon Suisan Co., Ltd.
A40S」(源自微生物的花生四烯酸、AA純度40至45%、三酸甘油酯純度95%以上。又,該AATG係相當於前述含花生四烯酸的油脂及前述微生物油脂。) A40S" (Arachidonic acid derived from microorganisms, AA purity of 40 to 45%, triglyceride purity of more than 95%. In addition, the AATG is equivalent to the aforementioned arachidonic acid-containing oil and the aforementioned microbial oil.)
‧高油酸葵花油:J-OILMILLS股份有限公司製「高油酸葵花油NS」(佔有構造脂肪酸總量之油酸含量83.7質量%) ‧High oleic sunflower oil: "High oleic sunflower oil NS" manufactured by J-OILMILLS Co., Ltd. (oleic acid content accounts for 83.7% by mass of the total structural fatty acids)
‧紅色棕櫚油:CAROTINO公司(CAROTINO SDN BHD)製「CAROTINO PURE OLEIN」(α-胡蘿蔔素及β-胡蘿蔔素之合計含量411質量ppm) ‧Red palm oil: "CAROTINO PURE OLEIN" manufactured by CAROTINO SDN BHD (total content of α-carotene and β-carotene 411 mass ppm)
〔調製例1〕氧化油脂之調製 [Preparation Example 1] Preparation of oxidized fats and oils
將油脂240至250g置入燒杯中,在其中供給0.20至0.25L/分鐘之量的空氣,同時在油浴中,以攪拌速度200rpm一邊攪拌,一邊以表1所示的溫度及時間之條件對各油脂施行加熱處理。依據「基準油脂分析試驗法2.5.2過氧化值」(日本油化學會)測定所得到的氧化油脂之過氧化值 (POV)。在表1中係呈示對各油脂之氧化處理的條件及所得到的氧化油脂之POV的測定結果。 240 to 250 g of fat was placed in a beaker, and 0.20 to 0.25 L/min of air was supplied therein. At the same time, the fat was heated in an oil bath at a stirring speed of 200 rpm at the temperature and time conditions shown in Table 1. The peroxide value (POV) of the oxidized fat was measured according to "Standard Fat Analysis Test Method 2.5.2 Peroxide Value" (Japan Oil Chemical Society). Table 1 shows the conditions for the oxidation treatment of each fat and the results of the POV measurement of the oxidized fat.
[表1]
〔調製例2〕氧化油脂之水解物之調製 [Preparation Example 2] Preparation of hydrolyzate of oxidized fats and oils
對於在調製例1-1及1-3得到的氧化油脂施行藉由脂酶的水解處理。具體而言,係將氧化油脂20g、水12g、及脂酶0.1至0.3g(表2所示的酵素添加量)置入50mL之管體中並蓋上,將該管體置入於設定在40℃之恆溫槽中,一邊以攪拌速度150rpm振盪,一邊以表2所示的時間條件施行藉由脂酶的水解處理。又,調製例2-1係脂酶分成3次各添加0.1g(第0小時、第3.5小時、第5小時)。經過反應時間後,將管體從恆溫槽中取出,在24℃施予離心(3000rpm、5分鐘),採集上層(油層)之10至15g。將所採集的處理物置入於附蓋子的管體中並浸泡於油浴中,在80℃下處理1小時使酵素失活。依據「基準油脂分析試驗法2.5.2過氧化值」(日本油化學會)測定所得到的水解物之過氧化值(POV),依據「基準油脂分析試驗法 2.3.1酸值」(日本油化學會)測定酸值(AV)。在表2中,呈示對各氧化油脂之脂酶處理的條件及所得到的水解物之POV及AV的測定結果。 The oxidized fats and oils obtained in Preparation Examples 1-1 and 1-3 were subjected to hydrolysis treatment by lipase. Specifically, 20 g of oxidized fats and oils, 12 g of water, and 0.1 to 0.3 g of lipase (the amount of enzyme added as shown in Table 2) were placed in a 50 mL tube and covered. The tube was placed in a thermostatic bath set at 40°C, and the tube was subjected to hydrolysis treatment by lipase under the time conditions shown in Table 2 while being shaken at a stirring speed of 150 rpm. In Preparation Example 2-1, 0.1 g of lipase was added three times (0 hour, 3.5 hours, and 5 hour). After the reaction time, the tube was taken out of the thermostatic bath, centrifuged at 24°C (3000 rpm, 5 minutes), and 10 to 15 g of the upper layer (oil layer) was collected. The collected treated material was placed in a tube with a cap and immersed in an oil bath, and treated at 80°C for 1 hour to inactivate the enzyme. The peroxide value (POV) of the obtained hydrolyzate was measured according to "Standard Oil and Fats Analysis Test Method 2.5.2 Peroxide Value" (Japan Oil and Chemical Society), and the acid value (AV) was measured according to "Standard Oil and Fats Analysis Test Method 2.3.1 Acid Value" (Japan Oil and Chemical Society). Table 2 shows the conditions for lipase treatment of each oxidized oil and fat and the results of the POV and AV of the obtained hydrolyzate.
[表2]
〔試驗例1〕 [Test Example 1]
1)油脂組成物之調製 1) Preparation of oil and fat compositions
以表3及表4所示的調配混合原料油脂,獲得各實施例及比較例之油脂組成物。 The oil compositions of each embodiment and comparative example are obtained by mixing the raw oils and fats as shown in Tables 3 and 4.
2)炸薯條之製造 2) French fries production
將所得到的各油脂組成物700g加熱至180℃為止,並將薯條(HEINZ日本股份有限公司製「薄切的薯條Shoe string」)50g油炸烹調3分鐘。油炸烹調後,在炸薯條上撒上食鹽(相對於馬鈴薯50g,食鹽0.3g)。 Heat 700 g of each obtained oil and fat composition to 180°C, and fry 50 g of French fries ("Thin-cut French fries Shoe string" manufactured by HEINZ Japan Co., Ltd.) for 3 minutes. After frying, sprinkle salt on the French fries (0.3 g of salt per 50 g of potato).
3)評定 3) Assessment
專門品評人員4名趁著所得的炸薯條尚溫熱之際(油炸烹調後10分以內)品嘗,依據以下基準對炸薯條之牛脂的甘甜、牛脂之肉味感、及牛脂之濃郁度進行評定。各評定項目之評分點數係以專門品評人員4名之平均點數表示,牛脂風味之綜合評定(牛脂之甘甜、牛脂之肉味感、及牛脂之濃郁 度的各平均點數之合計點數除以3的評分點數)為2點以上設為合格。表3及表4中呈示評定結果。 Four expert tasters tasted the French fries while they were still warm (within 10 minutes after frying) and evaluated the sweetness of the beef fat, the meaty taste of the beef fat, and the richness of the beef fat according to the following criteria. The score for each evaluation item is expressed as the average score of the four expert tasters, and the overall evaluation of the beef fat flavor (the total score of the average score of the sweetness of the beef fat, the meaty taste of the beef fat, and the richness of the beef fat divided by 3) is 2 points or more, which is considered to be acceptable. The evaluation results are shown in Tables 3 and 4.
(評定基準:牛脂之甘甜) (Evaluation criteria: sweetness of beef fat)
5點:感受到與對照例1(以牛脂100%之炸物油經油炸烹調時)同等之甘甜 5 points: The same sweetness is felt as in control example 1 (when deep-fried in 100% beef fat frying oil)
4點:雖不及對照例1,但強烈感受到牛脂之甘甜 4 points: Although not as good as control example 1, the sweetness of beef fat is strongly felt.
3點:感受到牛脂之甘甜 3 points: Feel the sweetness of beef tallow
2點:感受到略有牛脂之甘甜 2 points: Feel the sweetness of beef fat
1點:稍微感受到牛脂之甘甜,但與對照例1有明顯差距 1 point: Slightly sweet beef fat, but significantly different from control example 1
0點:完全感受不到牛脂之甘甜 0 points: The sweetness of beef fat is totally undetectable
(評定基準:牛脂之肉味感) (Evaluation criteria: meaty taste of beef fat)
5點:感受到與對照例1(以牛脂100%之炸物油經油炸烹調時)同等之肉味感 5 points: The same meaty taste is felt as in control example 1 (frying in 100% beef fat frying oil)
4點:雖不及對照例1,但強烈感受到牛脂之肉味感 4 points: Although not as good as control example 1, the beef fat flavor is strongly felt.
3點:感受到牛脂之肉味感 3 points: Feel the meaty flavor of beef fat
2點:感受到略有牛脂之肉味感 2: Feel the slight beef fat flavor
1點:稍微感受到牛脂之肉味感,但與對照例1有明顯差距 1 point: Slightly felt the meaty taste of beef fat, but significantly different from control example 1
0點:完全感受不到牛脂之肉味感 0 points: No beef fat flavor at all
(評定基準:牛脂之濃郁度) (Evaluation criteria: concentration of beef tallow)
5點:感受到與對照例1(以牛脂100%之炸物油經油炸烹調時)同等之濃郁度 5 points: The same richness is felt as in control example 1 (when deep-fried in 100% beef fat frying oil)
4點:雖不及對照例1,但強烈感受到之濃郁度 4 points: Although not as good as control example 1, the concentration is strongly felt
3點:感受到牛脂之濃郁度 3 points: Feel the richness of the beef tallow
2點:感受到略有牛脂之濃郁度 2 points: Feel the slight richness of beef tallow
1點:稍微感受到牛脂之濃郁度,但與對照例1有明顯差距 1 point: The richness of the beef fat can be slightly felt, but there is a clear difference compared to control example 1.
0點:完全感受不到牛脂之濃郁度 0 points: The richness of the beef fat is not noticeable at all
[表3]
[表4]
其結果,如表3及表4所示,以各實施例之油脂組成物經油炸烹調的炸薯條之牛脂風味的綜合評定,係比牛脂之含量為同等的各比較例更優異。因此,以包含牛脂及氧化油脂的炸物油進行油炸烹調食品,可確認出增強油炸食品之牛脂風味(比較例2對實施例1、比較例3對實施例2至13、比較例4對實施例14、比較例5對實施例15至17、比較例6對實施例18)。 The results, as shown in Tables 3 and 4, show that the overall evaluation of the beef fat flavor of the French fries fried with the fat compositions of each embodiment is better than that of the comparative examples with the same beef fat content. Therefore, frying food with frying oil containing beef fat and oxidized fat can enhance the beef fat flavor of fried food (Comparative Example 2 vs. Example 1, Comparative Example 3 vs. Examples 2 to 13, Comparative Example 4 vs. Example 14, Comparative Example 5 vs. Examples 15 to 17, Comparative Example 6 vs. Example 18).
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