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TW202348841A - plating device - Google Patents

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TW202348841A
TW202348841A TW111121135A TW111121135A TW202348841A TW 202348841 A TW202348841 A TW 202348841A TW 111121135 A TW111121135 A TW 111121135A TW 111121135 A TW111121135 A TW 111121135A TW 202348841 A TW202348841 A TW 202348841A
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substrate
anode
aforementioned
plating
ion
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TW111121135A
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TWI814428B (en
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中濱重之
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日商荏原製作所股份有限公司
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Abstract

The present invention provides a technology that can suppress uneven film thickness at the outer periphery of a substrate. The plating device 1 includes: a plating tank; an anode; a substrate holder; at least one auxiliary anode 60a-60d; the bus bar 61 has a feed portion 62 for supplying power and a plurality of connection portions 63 connected to at least one auxiliary anode and arranged in the extending direction of the auxiliary anode; and at least one ion resistance 80a-80d. The ion resistor is constructed in such a way that the resistivity of the ion resistor becomes higher the closer it extends to the feed portion.

Description

鍍覆裝置plating device

本發明係關於一種鍍覆裝置。The present invention relates to a plating device.

過去,對基板實施鍍覆處理之鍍覆裝置,習知有具備:貯存鍍覆液之鍍覆槽;配置於鍍覆槽內部之陽極;在鍍覆槽內部與陽極相對而可配置基板地構成之基板固持器;及配置於在鍍覆槽內部的陽極與基板之間,並沿著基板之外周緣而延伸的至少1個輔助陽極(輔助電極)者(例如,參照專利文獻1)。 [先前技術文獻] [專利文獻] In the past, a plating device for plating a substrate has been known to include: a plating tank that stores a plating liquid; an anode arranged inside the plating tank; and a substrate that can be arranged inside the plating tank opposite to the anode. a substrate holder; and at least one auxiliary anode (auxiliary electrode) arranged between the anode and the substrate inside the plating tank and extending along the outer periphery of the substrate (for example, see Patent Document 1). [Prior technical literature] [Patent Document]

[專利文獻1]日本特開2021-11624號公報[Patent Document 1] Japanese Patent Application Publication No. 2021-11624

(發明所欲解決之問題)(Invent the problem you want to solve)

如上述之過去的鍍覆裝置中,為了對輔助陽極供給電而使用匯流條。具體而言,該匯流條具有:供給電之饋電部位;與連接於輔助陽極,並且在該輔助陽極之延伸方向排列的複數個連接部位;並以將供給饋電部位之電經由連接部位而流入輔助陽極的方式而構成。As described above, in the conventional plating apparatus, a bus bar is used to supply electricity to the auxiliary anode. Specifically, the bus bar has: a feed portion for supplying electricity; and a plurality of connection portions connected to the auxiliary anode and arranged in the extending direction of the auxiliary anode; and the electricity supplied to the feed portion is transmitted through the connection portion. It is constructed by flowing into the auxiliary anode.

如上述之鍍覆裝置時,匯流條之連接部位的電阻值愈接近饋電部位則愈小。因而,在鍍覆處理時會有從匯流條流入輔助陽極之電量愈接近饋電部位則愈大的傾向。在此種狀況下,對基板實施鍍覆處理時,可能造成基板外周緣之膜厚不均勻。For example, in the above-mentioned plating device, the resistance value of the connection part of the bus bar is smaller as it is closer to the feed part. Therefore, during the plating process, the amount of electricity flowing from the bus bar to the auxiliary anode tends to increase as it approaches the power feeding portion. In this case, when the substrate is plated, the film thickness on the outer periphery of the substrate may be uneven.

本發明係鑑於上述情形者,目的之一為提供一種可抑制基板外周緣之膜厚不均勻的技術。 (解決問題之手段) (樣態1) In view of the above-mentioned circumstances, one of the objects of the present invention is to provide a technology that can suppress uneven film thickness at the outer periphery of a substrate. (a means of solving problems) (Pattern 1)

為了達成上述目的,本發明一個樣態之鍍覆裝置具備:鍍覆槽,其係貯存鍍覆液;陽極,其係配置於前述鍍覆槽之內部;基板固持器,其係在前述鍍覆槽之內部,與前述陽極相對而可配置基板地構成;至少1個輔助陽極,其係配置於在前述鍍覆槽內部的前述陽極與前述基板之間,並沿著前述基板之外周緣而延伸;匯流條,其係具有:供給電之饋電部位、及連接於至少1個前述輔助陽極並且在該輔助陽極之延伸方向排列的複數個連接部位,並以將供給至前述饋電部位之電經由前述連接部位流入前述輔助陽極的方式而構成;及至少1個離子電阻,其係配置於在前述鍍覆槽內部的前述輔助陽極與前述基板之間,並沿著前述輔助陽極而延伸;前述離子電阻係以在前述離子電阻之延伸方向愈接近前述饋電部位,前述離子電阻之電阻率愈高的方式而構成。In order to achieve the above object, a plating device according to one aspect of the present invention includes: a plating tank storing a plating liquid; an anode arranged inside the plating tank; and a substrate holder arranged in the plating tank. The inside of the tank is configured so that a substrate can be arranged opposite the anode; at least one auxiliary anode is arranged between the anode and the substrate inside the plating tank and extends along the outer periphery of the substrate ; The bus bar has: a feed portion for supplying electricity, and a plurality of connection portions connected to at least one of the aforementioned auxiliary anodes and arranged in the extending direction of the auxiliary anode, and for supplying electricity to the aforementioned feed portion; The auxiliary anode is formed by flowing into the auxiliary anode through the connection part; and at least one ion resistor is arranged between the auxiliary anode and the substrate inside the plating tank and extends along the auxiliary anode; The ion resistor is configured such that the resistivity of the ion resistor becomes higher as the extending direction of the ion resistor approaches the feeding point.

採用該樣態時,可抑制因為匯流條之連接部位的電阻值愈接近饋電部位則愈小,而造成基板外周緣之膜厚不均勻。 (樣態2) When this aspect is adopted, the resistance value of the connecting part of the bus bar becomes smaller as it is closer to the feeding part, causing uneven film thickness on the outer periphery of the substrate. (Pattern 2)

上述樣態1中,前述離子電阻亦可具有複數個開口,藉由在前述離子電阻之延伸方向愈接近前述饋電部位而前述離子電阻的開口率愈低,而使前述離子電阻之電阻率在前述離子電阻的延伸方向愈接近前述饋電部位則愈高。 (樣態3) In the above aspect 1, the ion resistor may also have a plurality of openings. The opening ratio of the ion resistor is lower as the extension direction of the ion resistor is closer to the feeding part, so that the resistivity of the ion resistor is within The closer the extending direction of the ion resistance is to the feeding part, the higher it is. (Pattern 3)

上述樣態1中,亦可藉由在前述離子電阻之延伸方向愈接近前述饋電部位而前述離子電阻的厚度愈厚,而使前述離子電阻之電阻率在前述離子電阻的延伸方向愈接近前述饋電部位則愈高。 (樣態4) In the above aspect 1, it is also possible to make the resistivity of the ion resistor closer to the above-described thickness in the extending direction of the ion resistor by making the thickness of the ion resistor thicker as the extending direction of the ion resistor approaches the feeding part. The higher the feed position is. (Pattern 4)

上述樣態1~3之任何一個樣態中,前述匯流條亦可具有連結部位,其係連結前述饋電部位與前述連接部位,前述連結部位具有複數個延伸部位,其係沿著前述基板之外周緣而延伸,複數個前述延伸部位配置成框狀,至少1個前述輔助陽極包含複數個前述輔助陽極,各個前述輔助陽極經由複數個前述連接部位而連接於各個前述延伸部位。 (樣態5) In any one of the above-mentioned aspects 1 to 3, the bus bar may have a connection part that connects the feed part and the connection part, and the connection part has a plurality of extension parts along the edge of the substrate. Extending from the outer periphery, a plurality of the extension parts are arranged in a frame shape, at least one of the auxiliary anodes includes a plurality of the auxiliary anodes, and each of the auxiliary anodes is connected to each of the extension parts through a plurality of the connection parts. (Pattern 5)

上述樣態1~4之任何一個樣態亦可具備收容部,其係在內部收容至少1個前述輔助陽極,前述收容部中設有朝向前述基板之方的開口,前述收容部之前述開口容許前述鍍覆液中所含之金屬離子通過,另外藉由抑制從前述輔助陽極表面產生之氧通過的隔膜而閉塞。 (樣態6) Any one of the above-mentioned aspects 1 to 4 may also be provided with a receiving portion, which stores at least one of the aforementioned auxiliary anodes inside. The aforementioned receiving portion is provided with an opening facing the direction of the aforementioned substrate, and the aforementioned opening of the aforementioned receiving portion allows The metal ions contained in the plating solution pass through, and are blocked by a separator that inhibits the passage of oxygen generated from the surface of the auxiliary anode. (Pattern 6)

為了達成上述目的,本發明一個樣態之鍍覆裝置具備:鍍覆槽,其係貯存鍍覆液;陽極,其係配置於前述鍍覆槽之內部;基板固持器,其係在前述鍍覆槽之內部,與前述陽極相對而可配置基板地構成;至少1個輔助陽極,其係配置於在前述鍍覆槽內部的前述陽極與前述基板之間,並沿著前述基板之外周緣而延伸;及匯流條,其係具有:供給電之饋電部位、及連接於至少1個前述輔助陽極並且在該輔助陽極之延伸方向排列的複數個連接部位,並以將供給至前述饋電部位之電經由前述連接部位流入前述輔助陽極的方式而構成;前述輔助陽極係以在前述輔助陽極之延伸方向愈接近前述饋電部位,前述輔助陽極與前述基板之距離愈大的方式而構成。In order to achieve the above object, a plating device according to one aspect of the present invention includes: a plating tank storing a plating liquid; an anode arranged inside the plating tank; and a substrate holder arranged in the plating tank. The inside of the tank is configured so that a substrate can be arranged opposite the anode; at least one auxiliary anode is arranged between the anode and the substrate inside the plating tank and extends along the outer periphery of the substrate ; and a bus bar, which has: a feed portion for supplying electricity, and a plurality of connection portions connected to at least one of the aforementioned auxiliary anodes and arranged in the extending direction of the auxiliary anode, so as to supply power to the aforementioned feed portion Electricity flows into the auxiliary anode through the connecting portion; the auxiliary anode is configured such that the distance between the auxiliary anode and the substrate becomes larger as the extension direction of the auxiliary anode approaches the feeding portion.

採用該樣態時,可抑制因為匯流條之連接部位的電阻值愈接近饋電部位則愈小,而造成基板外周緣之膜厚不均勻。When this aspect is adopted, the resistance value of the connecting part of the bus bar becomes smaller as it is closer to the feeding part, causing uneven film thickness on the outer periphery of the substrate.

以下,參照圖式說明本發明之實施形態。另外,以下各種實施形態就相同或對應之構成註記相同符號而適切省略說明。此外,圖式係為了容易瞭解實施形態之特徵而模式地圖示,各構成元件之尺寸比率等與實際者未必相同。一些圖式上圖示有X-Y-Z之正交座標作為參考。該正交座標中,Z方向相當於上方,-Z方向相當於下方(重力作用之方向)。Hereinafter, embodiments of the present invention will be described with reference to the drawings. In addition, in the following various embodiments, the same or corresponding components are denoted by the same reference numerals, and descriptions thereof will be omitted as appropriate. In addition, the drawings are schematically shown for easy understanding of the characteristics of the embodiments, and the dimensional ratios of each component may not be the same as the actual ones. Some drawings show the X-Y-Z orthogonal coordinates as a reference. In this orthogonal coordinate, the Z direction corresponds to the upward direction, and the -Z direction corresponds to the downward direction (the direction of gravity).

圖1係本實施形態之鍍覆裝置1的整體配置圖。如圖1中例示,本實施形態之鍍覆裝置1具備:2台匣盒台102;將基板Wf之定向平面及凹槽等的位置對準指定方向之對準器104;及使鍍覆處理後之基板Wf高速旋轉而乾燥的自旋沖洗乾燥機106。匣盒台102搭載收納半導體晶圓等之基板Wf的匣盒100。在自旋沖洗乾燥機106附近設有裝載基板固持器20並進行基板Wf之裝卸的裝載/卸載站120。搬送機器人122係用於在匣盒100、對準器104、自旋沖洗乾燥機106、及裝載/卸載站120之間搬送基板Wf的機器人。FIG. 1 is an overall layout diagram of the plating device 1 of this embodiment. As illustrated in FIG. 1 , the plating apparatus 1 of this embodiment includes: two cassette stages 102; an aligner 104 for aligning the orientation plane and grooves of the substrate Wf in a specified direction; and a plating process. The spin rinse dryer 106 then spins and dries the substrate Wf at high speed. The cassette stage 102 is equipped with a cassette 100 that accommodates a substrate Wf such as a semiconductor wafer. A loading/unloading station 120 is provided near the spin rinse dryer 106 for loading the substrate holder 20 and loading and unloading the substrate Wf. The transfer robot 122 is a robot used to transfer the substrate Wf between the cassette 100 , the aligner 104 , the spin rinse dryer 106 , and the loading/unloading station 120 .

裝載/卸載站120具備沿著軌道150而在橫方向滑動自如之平板狀的裝載板152。2個基板固持器20以水平狀態並列裝載於該裝載板152上。在一方的基板固持器20與搬送機器人122之間進行基板Wf的交接後,裝載板152橫方向滑動,並在另一方的基板固持器20與搬送機器人122之間進行基板Wf的交接。The loading/unloading station 120 is provided with a flat loading plate 152 that is slidable in the lateral direction along the rail 150. Two substrate holders 20 are loaded side by side on the loading plate 152 in a horizontal state. After the substrate Wf is transferred between one substrate holder 20 and the transfer robot 122 , the loading plate 152 slides in the lateral direction, and the substrate Wf is transferred between the other substrate holder 20 and the transfer robot 122 .

此外,鍍覆裝置1具備:暫存盒124、預濕模組126、預浸模組128、第一沖洗模組130a、噴氣模組132、第二沖洗模組130b、鍍覆模組110、搬送裝置140、及控制模組170。暫存盒124進行基板固持器20之保管及暫時放置。預濕模組126將基板Wf浸漬於純水中。預浸模組128係蝕刻除去形成於基板Wf表面之晶種層等導電層表面的氧化膜。第一沖洗模組130a係與基板固持器20一起以清洗液(純水等)清洗預浸後的基板Wf。噴氣模組132係進行清洗後之基板Wf之液體去除。第二沖洗模組130b係與基板固持器20一起以清洗液清洗鍍覆處理後之基板Wf。In addition, the plating device 1 includes: a temporary storage box 124, a pre-wet module 126, a prepreg module 128, a first rinse module 130a, an air jet module 132, a second rinse module 130b, and a plating module 110. The conveying device 140 and the control module 170. The temporary storage box 124 stores and temporarily places the substrate holder 20 . The prewet module 126 immerses the substrate Wf in pure water. The prepreg module 128 is etched to remove the oxide film formed on the surface of the conductive layer such as the seed layer on the surface of the substrate Wf. The first cleaning module 130a, together with the substrate holder 20, uses cleaning liquid (pure water, etc.) to clean the pre-soaked substrate Wf. The air jet module 132 removes liquid from the cleaned substrate Wf. The second cleaning module 130b, together with the substrate holder 20, uses cleaning fluid to clean the plated substrate Wf.

鍍覆模組110例如以在溢流槽136之內部收納複數個鍍覆槽10的方式構成。各個鍍覆槽10係以在內部收納1個基板Wf,使基板Wf浸漬於保持於內部的鍍覆液中,而在基板Wf表面實施銅鍍覆等的方式構成。The plating module 110 is configured, for example, to house a plurality of plating tanks 10 inside the overflow tank 136 . Each plating tank 10 accommodates one substrate Wf inside, immerses the substrate Wf in the plating liquid held inside, and performs copper plating or the like on the surface of the substrate Wf.

搬送裝置140係採用在構成鍍覆裝置1的各設備之間與基板Wf一起搬送基板固持器20之例如線性馬達方式的搬送裝置。本實施形態之搬送裝置140的一例為具有:第一搬送裝置142及第二搬送裝置144。第一搬送裝置142在裝載/卸載站120、暫存盒124、預濕模組126、預浸模組128、第一沖洗模組130a、及噴氣模組132之間搬送基板Wf。第二搬送裝置144在第一沖洗模組130a、第二沖洗模組130b、噴氣模組132、及鍍覆模組110之間搬送基板Wf。另外,鍍覆裝置1亦可不具備第二搬送裝置144,而僅具備第一搬送裝置142。The conveying device 140 is a linear motor type conveying device that conveys the substrate holder 20 together with the substrate Wf between the various devices constituting the plating device 1 . An example of the conveying device 140 of this embodiment includes a first conveying device 142 and a second conveying device 144 . The first transport device 142 transports the substrate Wf between the loading/unloading station 120, the temporary storage box 124, the pre-wet module 126, the prepreg module 128, the first rinse module 130a, and the air jet module 132. The second transport device 144 transports the substrate Wf between the first rinse module 130a, the second rinse module 130b, the air jet module 132, and the plating module 110. In addition, the plating apparatus 1 may not be provided with the 2nd conveyance device 144, but may be provided with only the 1st conveyance device 142.

在溢流槽136之兩側配置有位於各個鍍覆槽10之內部而驅動攪拌鍍覆槽10內之鍍覆液的槳葉之槳葉驅動部160及槳葉從動部162。A blade driving part 160 and a blade driven part 162 are arranged on both sides of the overflow tank 136 and are located inside each plating tank 10 to drive a blade that stirs the plating liquid in the plating tank 10 .

控制模組170係以控制鍍覆裝置1之動作的方式構成。具體而言,本實施形態之控制模組170具備微電腦,該微電腦具備:作為處理器之CPU(中央處理單元)171;及作為永久性記憶媒體之記憶裝置172等。控制模組170藉由按照記憶於記憶裝置172之程式的指令使CPU171工作來控制鍍覆裝置1的被控制部。The control module 170 is configured to control the operation of the plating device 1 . Specifically, the control module 170 of this embodiment includes a microcomputer including a CPU (Central Processing Unit) 171 as a processor, a memory device 172 as a permanent storage medium, and the like. The control module 170 controls the controlled part of the plating device 1 by operating the CPU 171 according to the instructions of the program stored in the memory device 172 .

以下說明藉由鍍覆裝置1進行之一連串鍍覆處理的一例。首先,搬送機器人122從搭載於匣盒台102之匣盒100取出1個基板Wf,並將基板Wf搬送至對準器104。對準器104將定向平面及凹槽等之位置對準指定方向。再以搬送機器人122將位置對準該指定方向之基板Wf搬送至裝載/卸載站120。An example of a series of plating processes performed by the plating device 1 will be described below. First, the transfer robot 122 takes out one substrate Wf from the cassette 100 mounted on the cassette stage 102, and transfers the substrate Wf to the aligner 104. The aligner 104 aligns the position of the orientation plane, the groove, etc. in the specified direction. The substrate Wf positioned in the specified direction is then transported to the loading/unloading station 120 by the transport robot 122 .

在裝載/卸載站120中,以搬送裝置140之第一搬送裝置142同時握持2座收容於暫存盒124內的基板固持器20,並搬送至裝載/卸載站120。而後,將2座基板固持器20同時水平地裝載於裝載/卸載站120的裝載板152上。在該狀態下,搬送機器人122搬送基板Wf至各個基板固持器20,並以基板固持器20保持搬送之基板Wf。In the loading/unloading station 120 , the first conveying device 142 of the conveying device 140 holds two substrate holders 20 stored in the temporary storage box 124 at the same time, and transports them to the loading/unloading station 120 . Then, the two substrate holders 20 are horizontally loaded on the loading plate 152 of the loading/unloading station 120 at the same time. In this state, the transfer robot 122 transfers the substrate Wf to each substrate holder 20 and holds the transferred substrate Wf with the substrate holder 20 .

其次,以搬送裝置140之第一搬送裝置142同時握持2座保持了基板Wf的基板固持器20,並收納於預濕模組126。其次,將保持了經預濕模組126處理後之基板Wf的基板固持器20以第一搬送裝置142搬送至預浸模組128,並以預浸模組128蝕刻基板Wf上之氧化膜。接著將保持了該基板Wf之基板固持器20搬送至第一沖洗模組130a,並以收納於第一沖洗模組130a之純水來清洗基板Wf表面。Next, the first conveying device 142 of the conveying device 140 holds two substrate holders 20 holding the substrate Wf simultaneously, and stores them in the premoistening module 126 . Next, the substrate holder 20 holding the substrate Wf processed by the prewet module 126 is transported to the prepreg module 128 by the first transport device 142, and the prepreg module 128 is used to etch the oxide film on the substrate Wf. Then, the substrate holder 20 holding the substrate Wf is transported to the first rinsing module 130a, and the surface of the substrate Wf is cleaned with pure water contained in the first rinsing module 130a.

保持了清洗結束之基板Wf的基板固持器20藉由第二搬送裝置144從第一沖洗模組130a搬送至鍍覆模組110,並收納於鍍覆槽10。第二搬送裝置144依序反覆進行上述步驟,並依序將保持了基板Wf之基板固持器20收納於鍍覆模組110的各個鍍覆槽10中。The substrate holder 20 holding the cleaned substrate Wf is transported from the first rinse module 130 a to the plating module 110 by the second transport device 144 , and is stored in the plating tank 10 . The second transport device 144 sequentially repeats the above steps, and sequentially stores the substrate holder 20 holding the substrate Wf into each plating tank 10 of the plating module 110 .

各個鍍覆槽10在鍍覆槽10內的陽極與基板Wf之間施加鍍覆電壓,而在基板Wf表面實施鍍覆處理。在該鍍覆處理時,亦可藉由槳葉驅動部160及槳葉從動部162驅動槳葉,來攪拌鍍覆槽10之鍍覆液。但是,鍍覆裝置1之構成並非限定於此者,例如,鍍覆裝置1之構成亦可不具備槳葉、槳葉驅動部160及槳葉從動部162。Each plating tank 10 applies a plating voltage between the anode in the plating tank 10 and the substrate Wf, and performs plating treatment on the surface of the substrate Wf. During the plating process, the paddle driving part 160 and the paddle driven part 162 may also be used to drive the paddle to stir the plating liquid in the plating tank 10 . However, the structure of the plating device 1 is not limited to this. For example, the plating device 1 may be configured without the blades, the blade driving part 160 and the blade driven part 162 .

經過鍍覆處理後,第二搬送裝置144同時握持2座保持了鍍覆處理後之基板Wf的基板固持器20,並搬送至第二沖洗模組130b,使其浸漬於收容在第二沖洗模組130b中的純水,以純水清洗基板Wf表面。其次,藉由第二搬送裝置144將基板固持器20搬送至噴氣模組132,藉由噴吹空氣等除去附著於基板固持器20之水滴。然後,藉由第一搬送裝置142將基板固持器20搬送至裝載/卸載站120。After the plating process, the second transport device 144 simultaneously holds two substrate holders 20 holding the plated substrate Wf, and transports them to the second rinse module 130b to immerse them in the second rinse module 130b. The pure water in the module 130b is used to clean the surface of the substrate Wf with pure water. Next, the substrate holder 20 is transported to the air blow module 132 by the second transport device 144, and the water droplets attached to the substrate holder 20 are removed by blowing air or the like. Then, the substrate holder 20 is transported to the loading/unloading station 120 by the first transporting device 142 .

裝載/卸載站120藉由搬送機器人122從基板固持器20取出處理後之基板Wf,並搬送至自旋沖洗乾燥機106。自旋沖洗乾燥機106藉由高速旋轉使鍍覆處理後之基板Wf高速旋轉而乾燥。並藉由搬送機器人122將乾燥後之基板Wf送回匣盒100。The loading/unloading station 120 uses the transfer robot 122 to take out the processed substrate Wf from the substrate holder 20 and transfer it to the spin rinse dryer 106 . The spin rinse dryer 106 dries the plated substrate Wf by rotating it at high speed. The dried substrate Wf is returned to the cassette 100 by the transport robot 122 .

另外,上述圖1所說明之鍍覆裝置1的構成為本發明之其中一實施樣態,鍍覆裝置1之構成並非限定於圖1之構成者。In addition, the structure of the plating device 1 illustrated in FIG. 1 is one embodiment of the present invention, and the structure of the plating device 1 is not limited to the structure of FIG. 1 .

接著詳細說明鍍覆裝置1中之鍍覆槽10的周邊構成。另外,由於本實施形態之複數個鍍覆槽10的構成相同,因此就1個鍍覆槽10之周邊構成作說明。Next, the peripheral structure of the plating tank 10 in the plating device 1 will be described in detail. In addition, since the plurality of plating tanks 10 in this embodiment have the same structure, the peripheral structure of one plating tank 10 will be described.

圖2係顯示本實施形態1之鍍覆裝置1中的1個鍍覆槽10周邊構成之模式剖面圖。圖2中例示之鍍覆裝置1的一例為將基板Wf之面方向(沿著面的方向)形成上下方向,而使基板Wf浸漬於鍍覆液Ps的鍍覆裝置(亦即,浸漬型鍍覆裝置)。FIG. 2 is a schematic cross-sectional view showing the peripheral configuration of one plating tank 10 in the plating device 1 according to the first embodiment. An example of the plating apparatus 1 illustrated in FIG. 2 is a plating apparatus in which the surface direction of the substrate Wf (the direction along the surface) is set in the up-down direction and the substrate Wf is immersed in the plating liquid Ps (that is, a immersion type plating device). cover device).

但是,鍍覆裝置1之具體實施例並非限定於此者。舉例來說,鍍覆裝置1亦可係將基板Wf之面方向形成水平方向,而使基板Wf浸漬於鍍覆液Ps之鍍覆裝置(亦即,杯式的鍍覆裝置)。However, the specific embodiment of the plating device 1 is not limited to this. For example, the plating device 1 may be a plating device (that is, a cup-type plating device) in which the surface direction of the substrate Wf is set in a horizontal direction and the substrate Wf is immersed in the plating liquid Ps.

如圖2所例示,鍍覆槽10亦可藉由上部有開口之有底的容器而構成。在鍍覆槽10之內部貯存有鍍覆液Ps。鍍覆液Ps只要是包含構成鍍膜之金屬元素的離子之溶液即可,其具體例並非特別限定者。本實施形態中,鍍覆處理之一例為使用銅鍍覆處理,鍍覆液Ps之另一例為使用硫酸銅溶液。As illustrated in FIG. 2 , the plating tank 10 may also be configured as a bottomed container with an opening at the upper part. The plating liquid Ps is stored inside the plating tank 10 . The plating solution Ps only needs to be a solution containing ions of metal elements constituting the plating film, and specific examples thereof are not particularly limited. In this embodiment, one example of the plating treatment is copper plating treatment, and another example of the plating solution Ps is a copper sulfate solution.

鍍覆裝置1在鍍覆槽10之內部具備陽極30。陽極30電性連接於電源。陽極30之具體種類並非特別限定者,亦可係不溶解陽極,亦可係溶解陽極。本實施形態之陽極30的一例為使用不溶解陽極。該不溶解陽極之具體種類並非特別限定者,可使用鉑及氧化銥等。The plating device 1 includes an anode 30 inside the plating tank 10 . The anode 30 is electrically connected to the power source. The specific type of anode 30 is not particularly limited. It may be an insoluble anode or a soluble anode. As an example of the anode 30 of this embodiment, an insoluble anode is used. The specific type of the insoluble anode is not particularly limited, and platinum, iridium oxide, etc. can be used.

鍍覆裝置1如圖2所例示,亦可在鍍覆槽10之內部具備:陽極盒40、隔膜50、陽極遮罩45。陽極盒40係用於在內部收容陽極30之構件(收容構件)。在陽極盒40中與基板Wf相對之部分設有開口40a。隔膜50係以閉塞該開口40a之方式而設。在陽極盒40之內部貯存有鍍覆液Ps。As shown in FIG. 2 , the plating device 1 may also include an anode box 40 , a diaphragm 50 , and an anode shield 45 inside the plating tank 10 . The anode box 40 is a member (accommodating member) for accommodating the anode 30 inside. An opening 40a is provided in a portion of the anode box 40 facing the substrate Wf. The diaphragm 50 is provided to block the opening 40a. The plating liquid Ps is stored inside the anode box 40 .

隔膜50藉由容許鍍覆液Ps所含之金屬離子(例如硫酸銅中之銅離子)通過,另外抑制從陽極30表面產生的氧通過之膜而構成。此種隔膜50例如可使用中性隔膜。The separator 50 is constituted by a film that allows metal ions (for example, copper ions in copper sulfate) contained in the plating solution Ps to pass through and suppresses the passage of oxygen generated from the surface of the anode 30 . For example, a neutral separator can be used as the separator 50 .

採用本實施形態時,如上述,由於將陽極30收容於陽極盒40內部,並藉由隔膜50閉塞該陽極盒40之開口40a,因此,即使鍍覆處理時從陽極30表面產生氧時,仍可抑制該產生之氧侵入陽極盒40外側的鍍覆液Ps。藉此,可抑制因為侵入該陽極盒40外側之鍍覆液Ps的氧而造成基板Wf之鍍覆品質惡化。In this embodiment, as described above, the anode 30 is housed inside the anode case 40 and the opening 40 a of the anode case 40 is blocked by the separator 50 . Therefore, even if oxygen is generated from the surface of the anode 30 during the plating process, The generated oxygen can be suppressed from invading the plating solution Ps outside the anode box 40 . This can prevent the plating quality of the substrate Wf from deteriorating due to oxygen intruding into the plating solution Ps outside the anode box 40 .

陽極遮罩45配置於陽極30與基板Wf之間。具體而言,本實施形態之陽極遮罩45配置於陽極盒40的內部。陽極遮罩45在陽極遮罩45之中央具有在陽極30與基板Wf之間移動的離子等可通過之孔45a。The anode mask 45 is arranged between the anode 30 and the substrate Wf. Specifically, the anode mask 45 of this embodiment is arranged inside the anode box 40 . The anode shield 45 has a hole 45 a in the center of the anode shield 45 through which ions and the like moving between the anode 30 and the substrate Wf can pass.

基板固持器20係用於保持作為陰極之基板Wf的構件。基板固持器20在鍍覆槽10內部,係以與陽極30相對而可配置基板Wf的方式構成。具體而言,對基板Wf實施鍍覆處理時,基板固持器20係以基板Wf之表面與陽極30相對的方式而保持基板Wf。更具體而言,本實施形態之基板固持器20係以基板Wf之面方向形成上下方向的方式而保持基板Wf。藉由鍍覆處理而在基板Wf之被鍍覆面(與陽極30相對之面)上形成鍍膜。The substrate holder 20 is a member for holding the substrate Wf serving as the cathode. The substrate holder 20 is configured to face the anode 30 inside the plating tank 10 so that the substrate Wf can be disposed. Specifically, when the substrate Wf is subjected to a plating process, the substrate holder 20 holds the substrate Wf such that the surface of the substrate Wf faces the anode 30 . More specifically, the substrate holder 20 of this embodiment holds the substrate Wf so that the surface direction of the substrate Wf forms an up-down direction. A plating film is formed on the surface to be plated (the surface facing the anode 30 ) of the substrate Wf by the plating process.

圖3係基板Wf之模式前視圖。具體而言,圖3係圖示從基板Wf之被鍍覆面的法線方向辨識基板Wf之情形。基板Wf之具體形狀並非特別限定者,不過如圖3所例示,亦可係具有複數個邊之角形基板。基板Wf之邊的數量並非特別限定者,亦可係3個,亦可係4個,亦可係5個以上。Fig. 3 is a schematic front view of the substrate Wf. Specifically, FIG. 3 illustrates a state in which the substrate Wf is identified from the normal direction of the plated surface of the substrate Wf. The specific shape of the substrate Wf is not particularly limited, but as shown in FIG. 3 , it may also be an angular substrate with multiple sides. The number of sides of the substrate Wf is not particularly limited, and may be 3, 4, or 5 or more.

本實施形態的基板Wf之邊的數量之一例係4個。亦即,本實施形態之基板Wf係具有:邊90a、邊90b、邊90c、及邊90d的四方形基板。邊90a及邊90b彼此相對,邊90c及邊90d彼此相對。在邊90a與邊90c之間設有角落部91a,在邊90a與邊90d之間設有角落部91b,在邊90b與邊90d之間設有角落部91c,在邊90b與邊90c之間設有角落部91d。An example of the number of sides of the substrate Wf in this embodiment is four. That is, the substrate Wf of this embodiment is a square substrate having sides 90a, 90b, 90c, and 90d. The side 90a and the side 90b are opposite to each other, and the side 90c and the side 90d are opposite to each other. A corner 91a is provided between the side 90a and the side 90c, a corner 91b is provided between the side 90a and the side 90d, a corner 91c is provided between the side 90b and the side 90d, and a corner 91c is provided between the side 90b and the side 90c. Corner portion 91d is provided.

此外,一例為本實施形態之基板Wf的各個邊之長度彼此相等。亦即,本實施形態之基板Wf從正面觀看具有正方形的形狀。但是,基板Wf之構成並非限定於此者,例如,基板Wf各個邊之長度亦可彼此不同。In addition, as an example, the lengths of the respective sides of the substrate Wf in this embodiment are equal to each other. That is, the substrate Wf of this embodiment has a square shape when viewed from the front. However, the structure of the substrate Wf is not limited to this. For example, the lengths of the respective sides of the substrate Wf may also be different from each other.

此外,本實施形態中,係從基板Wf之各個邊對基板Wf供給電。具體而言,本實施形態之基板Wf係從基板Wf之各個邊經由接觸構件(無圖示)而供給電。但是,並非限定於該構成者,例如,供給至基板Wf之電亦可從基板Wf的彼此相對之2邊供給。Furthermore, in this embodiment, power is supplied to the substrate Wf from each side of the substrate Wf. Specifically, in the substrate Wf of this embodiment, electricity is supplied from each side of the substrate Wf through contact members (not shown). However, the invention is not limited to this structure. For example, the electricity supplied to the substrate Wf may be supplied from two opposite sides of the substrate Wf.

再度參照圖2,本實施形態之鍍覆裝置1在鍍覆槽10內部具備至少1個輔助陽極。亦即,鍍覆裝置1亦可僅具備1個輔助陽極,亦可具備複數個輔助陽極。本實施形態之鍍覆裝置1的一例為具備複數個輔助陽極(輔助陽極60a、60b、60c、60d)。Referring again to FIG. 2 , the plating device 1 of this embodiment includes at least one auxiliary anode inside the plating tank 10 . That is, the plating apparatus 1 may be provided with only one auxiliary anode, or may be provided with a plurality of auxiliary anodes. An example of the plating apparatus 1 of this embodiment includes a plurality of auxiliary anodes (auxiliary anodes 60a, 60b, 60c, and 60d).

輔助陽極60a~60d配置於在鍍覆槽10內部的陽極30與基板Wf之間的部分。具體而言,圖2所例示之輔助陽極60a~60d配置於基板Wf與後述中間遮罩70之間的部分。此外,本實施形態之輔助陽極60a~60d收容於後述收容部71之內部。The auxiliary anodes 60a to 60d are arranged in a portion between the anode 30 and the substrate Wf inside the plating tank 10. Specifically, the auxiliary anodes 60a to 60d illustrated in FIG. 2 are arranged between the substrate Wf and the intermediate mask 70 described below. In addition, the auxiliary anodes 60a to 60d of this embodiment are accommodated inside the accommodation part 71 which will be described later.

輔助陽極60a~60d之具體種類並非特別限定者,亦可係不溶解陽極,亦可係溶解陽極。本實施形態之輔助陽極60a~60d的一例為使用不溶解陽極。該不溶解陽極之具體種類並非特別限定者,可使用鉑、氧化銥、及鈦等各種金屬。本實施形態之輔助陽極60a~60d的一例為藉由板狀之鈦而構成,並在該鈦之表面塗布有氧化銥。The specific types of the auxiliary anodes 60a to 60d are not particularly limited. They may be insoluble anodes or soluble anodes. As an example of the auxiliary anodes 60a to 60d of this embodiment, an insoluble anode is used. The specific type of the insoluble anode is not particularly limited, and various metals such as platinum, iridium oxide, and titanium can be used. An example of the auxiliary anodes 60a to 60d in this embodiment is composed of plate-shaped titanium, and the surface of the titanium is coated with iridium oxide.

再度參照圖2,鍍覆裝置1具備:中間遮罩70、與隔膜51。圖4係中間遮罩70之周邊構成的模式立體圖。參照圖2及圖4,中間遮罩70配置於陽極30與基板Wf之間。具體而言,本實施形態之中間遮罩70係配置於陽極盒40與基板Wf之間。中間遮罩70之中央具有離子可移動之孔70a。Referring again to FIG. 2 , the plating device 1 includes an intermediate mask 70 and a diaphragm 51 . FIG. 4 is a schematic perspective view of the peripheral structure of the intermediate mask 70 . Referring to FIGS. 2 and 4 , the intermediate mask 70 is disposed between the anode 30 and the substrate Wf. Specifically, the intermediate mask 70 of this embodiment is disposed between the anode box 40 and the substrate Wf. The middle mask 70 has an ion movable hole 70a in the center.

本實施形態中,中間遮罩70之孔70a的一例為多邊形孔,並具有分別對應於基板Wf之複數個邊的複數個邊(邊72a、72b、72c、72d)。具體而言,邊72a對應於基板Wf之邊90a,邊72b對應於基板Wf之邊90b,邊72c對應於基板Wf之邊90c,邊72d對應於基板Wf之邊90d。此外,邊72a在邊90a之延伸方向延伸,邊72b在邊90b之延伸方向延伸,邊72c在邊90c之延伸方向延伸,邊72d在邊90d之延伸方向延伸。In this embodiment, an example of the hole 70a of the intermediate mask 70 is a polygonal hole, and has a plurality of sides (sides 72a, 72b, 72c, 72d) respectively corresponding to a plurality of sides of the substrate Wf. Specifically, the side 72a corresponds to the side 90a of the substrate Wf, the side 72b corresponds to the side 90b of the substrate Wf, the side 72c corresponds to the side 90c of the substrate Wf, and the side 72d corresponds to the side 90d of the substrate Wf. In addition, the side 72a extends in the extending direction of the side 90a, the side 72b extends in the extending direction of the side 90b, the side 72c extends in the extending direction of the side 90c, and the side 72d extends in the extending direction of the side 90d.

在本實施形態之中間遮罩70與基板Wf相對之面設有用於收容輔助陽極60a~60d的收容部71。收容部71具有朝向基板Wf之方而開口的開口71a。In this embodiment, a receiving portion 71 for accommodating the auxiliary anodes 60a to 60d is provided on the surface of the intermediate mask 70 facing the substrate Wf. The accommodating portion 71 has an opening 71a that opens toward the substrate Wf.

隔膜51閉塞收容部71之開口71a。在收容部71之內部貯存有鍍覆液Ps。隔膜51可使用與前述之隔膜50同樣者。亦即,本實施形態之隔膜51容許鍍覆液Ps所含之金屬離子(例如硫酸銅中之銅離子)通過,另外藉由膜抑制從輔助陽極表面產生之氧通過而構成。此種隔膜51例如可使用中性隔膜。The diaphragm 51 blocks the opening 71a of the receiving part 71. The plating liquid Ps is stored inside the accommodating part 71 . The diaphragm 51 can be the same as the diaphragm 50 mentioned above. That is, the separator 51 of this embodiment is configured to allow metal ions (for example, copper ions in copper sulfate) contained in the plating solution Ps to pass through, and to inhibit the passage of oxygen generated from the surface of the auxiliary anode through the membrane. For example, a neutral separator can be used as the separator 51 .

採用本實施形態時,如上述,由於係將輔助陽極60a~60d收容於收容部71,並藉由隔膜51閉塞該收容部71之開口71a,因此,即使在鍍覆處理時從輔助陽極60a~60d表面產生氧時,仍可抑制該產生之氧侵入收容部71外側的鍍覆液Ps。藉此,可抑制因為侵入該收容部71外側之鍍覆液Ps的氧造成基板Wf之鍍覆品質惡化。In this embodiment, as described above, the auxiliary anodes 60a to 60d are accommodated in the accommodating portion 71, and the opening 71a of the accommodating portion 71 is blocked by the diaphragm 51. Therefore, even during the plating process, the auxiliary anodes 60a to 60d are received. Even when oxygen is generated on the surface of 60d, the generated oxygen can still be suppressed from intruding into the plating liquid Ps outside the accommodating portion 71. This can prevent the plating quality of the substrate Wf from deteriorating due to oxygen intruding into the plating liquid Ps outside the housing portion 71 .

參照圖2,本實施形態之鍍覆裝置1在鍍覆槽10內部具備:匯流條61、及至少1個離子電阻。本實施形態之鍍覆裝置1的一例為具備複數個離子電阻(離子電阻80a、80b、80c、80d)。Referring to FIG. 2 , the plating device 1 of this embodiment includes a bus bar 61 and at least one ion resistor inside the plating tank 10 . An example of the plating apparatus 1 of this embodiment is provided with a plurality of ion resistors (ion resistors 80a, 80b, 80c, and 80d).

圖5係匯流條61及輔助陽極60a~60d之模式前視圖。另外,圖5中亦以二點鏈線圖示有基板Wf做為參考。此外,圖5中,電流動之方向(亦即,電流方向)係以「I」來例示。圖6係離子電阻80a~80d之模式前視圖。另外,圖6中,亦以二點鏈線圖示有匯流條61及輔助陽極60a~60d做為參考。圖7係輔助陽極60a之周邊構成的模式側視圖。FIG. 5 is a schematic front view of the bus bar 61 and the auxiliary anodes 60a to 60d. In addition, the substrate Wf is also shown as a two-point chain line in FIG. 5 as a reference. In addition, in FIG. 5 , the direction of current flow (that is, the current direction) is exemplified by “I”. Fig. 6 is a schematic front view of the ion resistors 80a to 80d. In addition, in FIG. 6 , the bus bar 61 and the auxiliary anodes 60 a to 60 d are also shown as a two-point chain line for reference. FIG. 7 is a schematic side view of the peripheral structure of the auxiliary anode 60a.

如圖5所例示,本實施形態之輔助陽極60a~60d的數量與基板Wf之邊的數量一致。此外,輔助陽極60a~60d係以包圍指定之空間區域A1周圍的方式而配置。具體而言,本實施形態之輔助陽極60a~60d從基板Wf之被鍍覆面的法線方向來看,係以包圍基板Wf之外周緣的方式而配置。另外,本實施形態中,該空間區域A1係指相對於基板Wf往陽極30之一側,且相對於陽極30往基板Wf之一側的區域。As illustrated in FIG. 5 , the number of auxiliary anodes 60 a to 60 d in this embodiment is consistent with the number of sides of the substrate Wf. In addition, the auxiliary anodes 60a to 60d are arranged to surround the designated space area A1. Specifically, the auxiliary anodes 60a to 60d of this embodiment are arranged to surround the outer periphery of the substrate Wf when viewed from the normal direction of the plated surface of the substrate Wf. In addition, in this embodiment, the space region A1 refers to a region toward the anode 30 side with respect to the substrate Wf and toward the substrate Wf side with respect to the anode 30 .

輔助陽極60a~60d沿著基板Wf之外周緣而延伸。具體而言,本實施形態之各個輔助陽極60a~60d係以與基板Wf之各個邊對應的方式而配置,並在基板Wf之各個邊的延伸方向而延伸。The auxiliary anodes 60a to 60d extend along the outer peripheral edge of the substrate Wf. Specifically, the auxiliary anodes 60a to 60d of this embodiment are arranged corresponding to the respective sides of the substrate Wf, and extend in the extending direction of the respective sides of the substrate Wf.

更具體而言,如圖5所例示,輔助陽極60a對應於基板Wf之邊90a,並在邊90a之延伸方向(Y方向)延伸。輔助陽極60b對應於邊90b,並在邊90b之延伸方向(Y方向)延伸。輔助陽極60c對應於邊90c,並在邊90c之延伸方向(Z方向)延伸。輔助陽極60d對應於邊90d,並在邊90d之延伸方向(Z方向)延伸。More specifically, as illustrated in FIG. 5 , the auxiliary anode 60 a corresponds to the side 90 a of the substrate Wf and extends in the extending direction (Y direction) of the side 90 a. The auxiliary anode 60b corresponds to the side 90b and extends in the extending direction of the side 90b (Y direction). The auxiliary anode 60c corresponds to the side 90c and extends in the extending direction of the side 90c (Z direction). The auxiliary anode 60d corresponds to the side 90d and extends in the extending direction of the side 90d (Z direction).

參照圖5,匯流條61係用於對輔助陽極60a~60d供給電之構件。匯流條61之具體構成並非特別限定者,不過,本實施形態之匯流條61例如係藉由如鈦之電導率佳的材質而構成。此外,本實施形態之匯流條61的一例為藉由平板狀之構件而構成。另外,匯流條61為了有效抑制鍍覆液Ps造成之腐蝕,亦可利用包覆材料將其表面進行包覆。Referring to FIG. 5 , the bus bar 61 is a member for supplying electricity to the auxiliary anodes 60 a to 60 d. The specific structure of the bus bar 61 is not particularly limited. However, the bus bar 61 in this embodiment is made of a material with good electrical conductivity such as titanium. In addition, an example of the bus bar 61 in this embodiment is composed of a flat member. In addition, in order to effectively suppress corrosion caused by the plating liquid Ps, the surface of the bus bar 61 can also be coated with a coating material.

本實施形態之匯流條61具備:饋電部位62、複數個連接部位63、及連結部位64。饋電部位62係與電源200電性連接,並從該電源200供給電之方式而構成的部位。The bus bar 61 of this embodiment includes a power feeding portion 62, a plurality of connecting portions 63, and a connecting portion 64. The power feeding portion 62 is electrically connected to the power supply 200 and is configured to supply power from the power supply 200 .

參照圖5及圖7,連接部位63係連接於輔助陽極60a~60d之部位(亦即,連接支柱(Boss))。具體而言,本實施形態之連接部位63形成突起狀,而連結輔助陽極60a~60d與連結部位64之後述的延伸部位66a~66d。圖5中,就複數個連接部位63賦予#1~#12的編號。如圖5所例示,複數個連接部位63在與鄰接的連接部位63之間以間隔排列於輔助陽極60a~60d的延伸方向。Referring to FIGS. 5 and 7 , the connection portion 63 is a portion connected to the auxiliary anodes 60 a to 60 d (that is, the connection support (Boss)). Specifically, the connection portion 63 of this embodiment is formed in a protrusion shape, and connects the auxiliary anodes 60a to 60d to the extension portions 66a to 66d of the connection portion 64 described below. In FIG. 5 , the plurality of connection sites 63 are numbered #1 to #12. As illustrated in FIG. 5 , a plurality of connection portions 63 are arranged at intervals in the extending direction of the auxiliary anodes 60 a to 60 d between adjacent connection portions 63 .

連結部位64係為了連結饋電部位62與連接部位63而構成的部位。如圖5所例示,本實施形態之連結部位64具備:導入部位65、及延伸部位66a~66d。導入部位65係連結延伸部位66a~66d與饋電部位62,並將饋電部位62之電導入延伸部位66a~66d的方式而構成之部位。The connection portion 64 is a portion configured to connect the power feeding portion 62 and the connection portion 63 . As illustrated in FIG. 5 , the connecting portion 64 of this embodiment includes an introduction portion 65 and extension portions 66a to 66d. The introduction portion 65 is a portion configured to connect the extension portions 66a to 66d and the power feeding portion 62, and to introduce electricity from the power feeding portion 62 into the extension portions 66a to 66d.

延伸部位66a~66d沿著輔助陽極60a~60d而延伸。具體而言,延伸部位66a在輔助陽極60a之延伸方向延伸,延伸部位66b在輔助陽極60b之延伸方向延伸,延伸部位66c在輔助陽極60c之延伸方向延伸,延伸部位66d在輔助陽極60d之延伸方向延伸。The extension portions 66a to 66d extend along the auxiliary anodes 60a to 60d. Specifically, the extension portion 66a extends in the extension direction of the auxiliary anode 60a, the extension portion 66b extends in the extension direction of the auxiliary anode 60b, the extension portion 66c extends in the extension direction of the auxiliary anode 60c, and the extension portion 66d extends in the extension direction of the auxiliary anode 60d. extend.

延伸部位66a與延伸部位66d為電性串聯連接。延伸部位66c與延伸部位66b為電性串聯連接。而且延伸部位66a、66d與延伸部位66c、66b為電性並聯連接。因此輔助陽極60a與輔助陽極60c係以電性並聯之方式來配置,輔助陽極60d與輔助陽極60b係以電性並聯之方式來配置。The extension portion 66a and the extension portion 66d are electrically connected in series. The extension portion 66c and the extension portion 66b are electrically connected in series. Moreover, the extension parts 66a and 66d and the extension parts 66c and 66b are electrically connected in parallel. Therefore, the auxiliary anode 60a and the auxiliary anode 60c are arranged in an electrical parallel connection, and the auxiliary anode 60d and the auxiliary anode 60b are arranged in an electrical parallel connection.

此外,延伸部位66a~66d係以包圍指定之空間區域A1周圍的方式而配置。具體而言,本實施形態之延伸部位66a~66d從基板Wf之被鍍覆面的法線方向來看,係以包圍基板Wf之外周緣的方式而配置。此外,本實施形態之延伸部位66a~66d彼此連結而配置成框狀。具體而言,本實施形態之延伸部位66a~66d的一例為多邊形(本實施形態之一例為四方形)的框狀。In addition, the extension portions 66a to 66d are arranged so as to surround the designated space area A1. Specifically, the extending portions 66a to 66d of this embodiment are arranged to surround the outer peripheral edge of the substrate Wf when viewed from the normal direction of the plated surface of the substrate Wf. In addition, the extension portions 66a to 66d of this embodiment are connected to each other and arranged in a frame shape. Specifically, an example of the extending portions 66 a to 66 d in this embodiment is a polygonal (an example in this embodiment is a square) frame shape.

各個輔助陽極60a~60d經由複數個連接部位63而連接於各個延伸部位66a~66d。具體而言,輔助陽極60a經由#1~#3之連接部位63而連接於延伸部位66a。輔助陽極60b經由#10~#12之連接部位63而連接於延伸部位66b。輔助陽極60c經由#7~#9之連接部位63而連接於延伸部位66c。輔助陽極60d經由#4~#6之連接部位63而連接於延伸部位66d。Each of the auxiliary anodes 60a to 60d is connected to the respective extension portions 66a to 66d via a plurality of connection portions 63. Specifically, the auxiliary anode 60a is connected to the extension portion 66a via the connection portions 63 of #1 to #3. The auxiliary anode 60b is connected to the extension portion 66b via the connection portions 63 of #10 to #12. The auxiliary anode 60c is connected to the extension portion 66c via the connection portions 63 of #7 to #9. The auxiliary anode 60d is connected to the extension portion 66d via the connection portions 63 of #4 to #6.

從電源200經由饋電部位62而供給至匯流條61的電,流經連結部位64後,再流經連接部位63而供給至輔助陽極60a~60d。具體而言,供給至饋電部位62之電,流經連結部位64之導入部位65後,分別流入連結部位64之延伸部位66a及延伸部位66c。流經延伸部位66a之電,流經延伸部位66d,流經延伸部位66c之電,流經延伸部位66b。延伸部位66a之電,經由連接部位63而流入輔助陽極60a,延伸部位66b之電,經由連接部位63而流入輔助陽極60b。延伸部位66c之電,經由連接部位63而流入輔助陽極60c,延伸部位66d之電,經由連接部位63而流入輔助陽極60d。The electricity supplied from the power supply 200 to the bus bar 61 via the power feeding part 62 flows through the connection part 64 and then flows through the connection part 63 and is supplied to the auxiliary anodes 60a to 60d. Specifically, the electricity supplied to the feeding part 62 flows through the introduction part 65 of the connection part 64 and then flows into the extension part 66a and the extension part 66c of the connection part 64 respectively. The electricity flowing through the extension part 66a flows through the extension part 66d, and the electricity flowing through the extension part 66c flows through the extension part 66b. The electricity in the extension portion 66a flows into the auxiliary anode 60a via the connection portion 63, and the electricity in the extension portion 66b flows into the auxiliary anode 60b via the connection portion 63. The electricity in the extension portion 66c flows into the auxiliary anode 60c via the connection portion 63, and the electricity in the extension portion 66d flows into the auxiliary anode 60d via the connection portion 63.

此處,匯流條61之連接部位63的電阻值係愈接近饋電部位62之處則愈小(反之而言,離饋電部位62愈遠則愈大)。另外,所謂「接近饋電部位62」,具體而言,是指「離饋電部位62之電性距離短」。Here, the resistance value of the connection part 63 of the bus bar 61 is smaller as it is closer to the power feeding part 62 (conversely, the resistance value is larger as it is further away from the power feeding part 62). In addition, "close to the power feeding part 62" specifically means "the electrical distance from the power feeding part 62 is short".

例如列舉將100(mA)之電流流入匯流條61時各連接部位63的電阻值之一例時,#1係8(mΩ),#2係10(mΩ),#3係12(mΩ),#4係12(mΩ),#5係13(mΩ),#6係15(mΩ),#7係8(mΩ),#8係10(mΩ),#9係12(mΩ),#10係13(mΩ),#11係14(mΩ),#12係15(mΩ)。For example, when taking an example of the resistance value of each connection part 63 when a current of 100 (mA) flows into the bus bar 61, #1 is 8 (mΩ), #2 is 10 (mΩ), #3 is 12 (mΩ), and # 4 series 12 (mΩ), #5 series 13 (mΩ), #6 series 15 (mΩ), #7 series 8 (mΩ), #8 series 10 (mΩ), #9 series 12 (mΩ), #10 series 13 (mΩ), #11 is 14 (mΩ), #12 is 15 (mΩ).

如此,匯流條61之連接部位63的電阻值愈接近饋電部位62則愈小的結果,在鍍覆處理時,從匯流條61流入輔助陽極60a~60d之電量(亦即電流值)有愈接近饋電部位62則愈大的傾向。因而,若未設後述之離子電阻80a~80d時,基板Wf外周緣之膜厚可能愈接近饋電部位62之處則愈厚。具體而言,參照圖3,可能基板Wf之角落部91a周邊的膜厚最厚。為了應付該問題,本實施形態係具備以下說明之離子電阻80a~80d。In this way, the resistance value of the connecting part 63 of the bus bar 61 is smaller as it is closer to the feeding part 62. During the plating process, the amount of electricity (that is, the current value) flowing from the bus bar 61 to the auxiliary anodes 60a to 60d is smaller. The tendency is greater closer to the power feeding part 62. Therefore, if the ion resistors 80 a to 80 d described below are not provided, the film thickness of the outer peripheral edge of the substrate Wf may become thicker as it approaches the power feeding portion 62 . Specifically, referring to FIG. 3 , the film thickness may be thickest around the corner portion 91 a of the substrate Wf. In order to cope with this problem, this embodiment includes ion resistors 80a to 80d described below.

參照圖2、圖6、及圖7,離子電阻(離子電阻80a~80d)係在鍍覆液Ps中對離子之移動發揮阻力功能的構件,具體而言,係藉由具有比鍍覆液Ps之電阻高的電阻之構件而構成。只要是具有此種功能者即可,離子電阻80a~80d之具體材質並非特別限定者,例如,宜使用陶瓷等對鍍覆液Ps之耐腐蝕性能高的材質。Referring to FIGS. 2, 6, and 7, the ion resistors (ion resistors 80a to 80d) are members that exert a resistance function on the movement of ions in the plating liquid Ps. It is composed of components with high resistance. As long as it has such a function, the specific material of the ion resistors 80a to 80d is not particularly limited. For example, a material with high corrosion resistance to the plating liquid Ps such as ceramics is preferably used.

此外,離子電阻80a~80d配置於鍍覆槽10內部的輔助陽極60a~60d與基板Wf之間。具體而言,本實施形態之離子電阻80a~80d如圖2所例示,係配置於收容部71之內部,具體而言,係配置於輔助陽極60a~60d與隔膜51之間的區域。離子電阻80a~80d藉由指定之安裝構件(無圖示)而安裝於鍍覆槽10內部。In addition, the ion resistors 80a to 80d are arranged between the auxiliary anodes 60a to 60d inside the plating tank 10 and the substrate Wf. Specifically, as shown in FIG. 2 , the ion resistors 80 a to 80 d of this embodiment are arranged inside the accommodating portion 71 , specifically, in the area between the auxiliary anodes 60 a to 60 d and the separator 51 . The ion resistors 80a to 80d are installed inside the plating tank 10 through designated installation members (not shown).

離子電阻80a~80d之「厚度t1(具體而言,從陽極30朝向基板Wf之方向的長度(mm))」並非特別限定者,不過,係形成離子電阻80a~80d不致與隔膜51及輔助陽極60a~60d接觸之值。亦即,本實施形態之離子電阻80a~80d係以在與隔膜51之間具有空間,且在與輔助陽極60a~60d之間亦具有空間的方式而配置。此外,如圖7所例示,本實施形態之離子電阻80a~80d的厚度t1之一例為在離子電阻80a~80d的整個延伸方向為相同值(亦即一樣)。The "thickness t1 (specifically, the length (mm) in the direction from the anode 30 toward the substrate Wf)" of the ion resistors 80a to 80d is not particularly limited. However, the ion resistors 80a to 80d are formed so as not to interfere with the separator 51 and the auxiliary anode. 60a~60d contact value. That is, the ion resistors 80a to 80d of this embodiment are arranged to have a space between the separator 51 and the auxiliary anodes 60a to 60d. In addition, as illustrated in FIG. 7 , an example of the thickness t1 of the ion resistors 80 a to 80 d in this embodiment is the same value (that is, the same) in the entire extending direction of the ion resistors 80 a to 80 d.

如圖6所例示,離子電阻80a~80d沿著輔助陽極60a~60d而延伸。具體而言,離子電阻80a在輔助陽極60a之延伸方向延伸,離子電阻80b在輔助陽極60b之延伸方向延伸。此外,離子電阻80c在輔助陽極60c之延伸方向延伸,離子電阻80d在輔助陽極60d之延伸方向延伸。As illustrated in FIG. 6 , the ion resistors 80 a to 80 d extend along the auxiliary anodes 60 a to 60 d. Specifically, the ion resistor 80a extends in the extending direction of the auxiliary anode 60a, and the ion resistor 80b extends in the extending direction of the auxiliary anode 60b. In addition, the ion resistor 80c extends in the extending direction of the auxiliary anode 60c, and the ion resistor 80d extends in the extending direction of the auxiliary anode 60d.

此外,離子電阻80a係以與輔助陽極60a相對之方式配置,離子電阻80b係以與輔助陽極60b相對之方式配置。離子電阻80c係以與輔助陽極60c相對之方式配置,離子電阻80d係以與輔助陽極60d相對之方式配置。此外,此等離子電阻80a~80d係以包圍空間區域A1周圍之方式而配置。具體而言,本實施形態之離子電阻80a~80d從基板Wf之被鍍覆面的法線方向來看,係以包圍基板Wf之外周緣的方式而配置。In addition, the ion resistor 80a is arranged to face the auxiliary anode 60a, and the ion resistor 80b is arranged to face the auxiliary anode 60b. The ion resistor 80c is arranged to face the auxiliary anode 60c, and the ion resistor 80d is arranged to face the auxiliary anode 60d. In addition, the plasma resistors 80a to 80d are arranged to surround the space area A1. Specifically, the ion resistors 80a to 80d of this embodiment are arranged to surround the outer periphery of the substrate Wf when viewed from the normal direction of the plated surface of the substrate Wf.

參照圖6,離子電阻80a~80d在延伸方向之長度(L1)並非特別限定者,亦可比輔助陽極60a~60d在延伸方向之長度長,亦可比其短,亦可相同。本實施形態之一例為離子電阻80a~80d之長度(L1)係在輔助陽極60a~60d之長度的80%以上,130%以下的範圍內,具體而言,係在輔助陽極60a~60d之長度的90%以上,120%以下的範圍內。另外,離子電阻80a~80d之長度(L1)宜與輔助陽極60a~60d之長度相同,或是比輔助陽極60a~60d長。Referring to FIG. 6 , the length (L1) of the ion resistors 80a to 80d in the extending direction is not particularly limited, and may be longer, shorter, or the same than the length of the auxiliary anodes 60a to 60d in the extending direction. An example of this embodiment is that the length (L1) of the ion resistors 80a to 80d is within the range of 80% to 130% of the length of the auxiliary anodes 60a to 60d. Specifically, the length (L1) of the ion resistors 80a to 80d is within the range of 80% to 130% of the length of the auxiliary anodes 60a to 60d. In the range of above 90% and below 120%. In addition, the length (L1) of the ion resistors 80a-80d is preferably the same as the length of the auxiliary anodes 60a-60d, or longer than the auxiliary anodes 60a-60d.

此外,離子電阻80a~80d之寬度(L2)並非特別限定者,亦可比輔助陽極60a~60d之寬度長,亦可比其短,亦可相同。本實施形態之一例為離子電阻80a~80d之寬度(L2)係在輔助陽極60a~60d之寬度的80%以上,120%以下的範圍內。In addition, the width (L2) of the ion resistors 80a to 80d is not particularly limited, and may be longer, shorter, or the same than the width of the auxiliary anodes 60a to 60d. An example of this embodiment is that the width (L2) of the ion resistors 80a to 80d is in a range from 80% to 120% of the width of the auxiliary anodes 60a to 60d.

圖8係複數個離子電阻80a~80d中之1個離子電阻(具體而言係離子電阻80a)的模式前視圖。參照圖6及圖8,離子電阻80a~80d係以在離子電阻80a~80d之延伸方向愈接近饋電部位62,離子電阻80a~80d之電阻率(Ω‧cm)愈高的方式而構成。具體而言,離子電阻80a之電阻率在圖6係愈朝向Y方向則愈高。離子電阻80b之電阻率在圖6係愈朝向Y方向則愈高。離子電阻80c之電阻率在圖6係愈朝向Z方向則愈高。離子電阻80d之電阻率在圖6係愈朝向Z方向則愈高。FIG. 8 is a schematic front view of one of the plurality of ion resistors 80a to 80d (specifically, the ion resistor 80a). Referring to FIGS. 6 and 8 , the ion resistors 80 a to 80 d are configured such that the resistivity (Ω·cm) of the ion resistors 80 a to 80 d becomes higher as the extension direction of the ion resistors 80 a to 80 d approaches the feed portion 62 . Specifically, the resistivity of the ion resistor 80a is higher toward the Y direction in FIG. 6 . The resistivity of the ion resistor 80b is higher toward the Y direction in FIG. 6 . The resistivity of the ion resistor 80c is higher toward the Z direction in FIG. 6 . The resistivity of the ion resistor 80d in Figure 6 is higher toward the Z direction.

更具體而言,如圖8所例示,本實施形態之離子電阻80a~80d分別具有複數個開口81。而離子電阻80a~80d之開口率(亦即,開口81部分之面積占離子電阻每單位面積的比率),係以在離子電阻80a~80d之延伸方向愈接近饋電部位62則愈低的方式構成。藉此,採用本實施形態時,可以簡單之構成使離子電阻80a~80d之電阻率愈接近饋電部位62則愈高。More specifically, as illustrated in FIG. 8 , the ion resistors 80 a to 80 d of this embodiment each have a plurality of openings 81 . The aperture ratio of the ion resistors 80a to 80d (that is, the ratio of the area of the opening 81 to the ion resistor per unit area) is lower in the extending direction of the ion resistors 80a to 80d as it approaches the feed portion 62 composition. Therefore, according to this embodiment, it is possible to simply configure the resistivity of the ion resistors 80a to 80d to be higher as it approaches the power feeding portion 62.

另外,離子電阻80a~80d之各個開口81的大小宜為在鍍覆處理中從輔助陽極60a~60d產生之氣泡(具體而言係由氧構成之氣泡)可通過該開口81。採用該構成時,可有效抑制從輔助陽極60a~60d產生之氣泡滯留在離子電阻80a~80d與輔助陽極60a~60d相對之面。另外,該構成在離子電阻80a~80d係在水平方向延伸之方式而配置時,可發揮特別高的效果。In addition, the openings 81 of the ion resistors 80a to 80d are preferably sized such that bubbles (specifically, bubbles composed of oxygen) generated from the auxiliary anodes 60a to 60d during the plating process can pass through the openings 81. With this structure, it is possible to effectively suppress bubbles generated from the auxiliary anodes 60a to 60d from remaining on the surfaces of the ion resistors 80a to 80d facing the auxiliary anodes 60a to 60d. In addition, this structure can exhibit a particularly high effect when the ion resistors 80a to 80d are arranged to extend in the horizontal direction.

此外,各個離子電阻80a~80d之全部電阻率亦可彼此相同。具體而言,離子電阻80a之全部電阻率(離子電阻80a之一端至另一端的總電阻率)、離子電阻80b之全部電阻率、離子電阻80c之全部電阻率、及離子電阻80d之全部電阻率彼此亦可係等值。In addition, all resistivities of the respective ion resistors 80a to 80d may be the same as each other. Specifically, the total resistivity of the ion resistor 80a (the total resistivity from one end of the ion resistor 80a to the other end), the total resistivity of the ion resistor 80b, the total resistivity of the ion resistor 80c, and the total resistivity of the ion resistor 80d. They can also be equivalent to each other.

或是,各個離子電阻80a~80d之全部電阻率亦可彼此不同。此時,宜為以配置於饋電部位62附近之離子電阻之全部電阻率比遠離饋電部位62而配置之離子電阻高的方式而構成。Alternatively, the total resistivities of the respective ion resistors 80a to 80d may be different from each other. In this case, it is preferable to configure it so that the total resistivity of the ion resistor arranged near the feeding part 62 is higher than that of the ion resistor arranged far away from the feeding part 62 .

具體而言,宜為離子電阻80a之全部電阻率比離子電阻80d高。換言之,離子電阻80a之遠離饋電部位62側之端部(「遠位端(圖6係-Y方向側之端部)」)的電阻值,宜比離子電阻80d之接近饋電部位62側之端部(「近位端(圖6係Z方向側之端部)」)的電阻值高。此外,離子電阻80c之全部電阻率宜比離子電阻80b高。換言之,離子電阻80c之遠位端(圖6係-Z方向側之端部)的電阻值,宜比離子電阻80b之近位端(圖6係Y方向側之端部)的電阻值高。Specifically, it is preferable that the total resistivity of the ion resistor 80a is higher than that of the ion resistor 80d. In other words, the resistance value of the end of the ion resistor 80a far away from the feeding part 62 (the "distal end (end on the Y direction side in Figure 6)") is preferably higher than that of the ion resistor 80d close to the feeding part 62. The resistance value of the end ("the proximal end (the end on the Z direction side in Figure 6)") is high. In addition, the overall resistivity of the ion resistor 80c is preferably higher than that of the ion resistor 80b. In other words, the resistance value of the distal end of the ion resistor 80c (the end on the -Z direction side in FIG. 6) is preferably higher than the resistance value of the proximal end of the ion resistor 80b (the end on the Y-direction side in FIG. 6).

採用如以上說明之本實施形態時,由於係以離子電阻80a~80d之電阻率愈接近饋電部位62則愈高的方式而構成,因此可抑制因為匯流條61之連接部位63的電阻值愈接近饋電部位62則愈小而造成基板Wf外周緣之膜厚不均勻。亦即,採用本實施形態時,可謀求基板Wf外周緣之膜厚均勻化。結果,亦可謀求基板Wf面內之膜厚均勻化。 (實施形態1之修改例) In the present embodiment as described above, since the resistivity of the ion resistors 80a to 80d is configured to be higher as it is closer to the feeding portion 62, it is possible to suppress the increase in the resistance value of the connecting portion 63 of the bus bar 61. The closer to the power feeding portion 62, the smaller the thickness becomes, resulting in uneven film thickness on the outer periphery of the substrate Wf. That is, according to this embodiment, the film thickness at the outer peripheral edge of the substrate Wf can be made uniform. As a result, the film thickness within the surface of the substrate Wf can also be made uniform. (Modification of Embodiment 1)

離子電阻80a~80d之構成並非限定於圖8所說明之構成者。離子電阻80a~80d之其他一例亦可使用以下者。圖9(A)及圖9(B)係用於說明實施形態1之修改例的鍍覆裝置1A之離子電阻80a~80d的模式圖。具體而言,圖9(A)係本修改例之1個離子電阻(離子電阻80a)的模式前視圖,圖9(B)係本修改例之1個離子電阻(離子電阻80a)的模式側視圖。The structure of the ion resistors 80a to 80d is not limited to the structure illustrated in FIG. 8 . As another example of the ion resistors 80a to 80d, the following ones can be used. 9(A) and 9(B) are schematic diagrams for explaining the ion resistors 80a to 80d of the plating apparatus 1A according to the modified example of the first embodiment. Specifically, FIG. 9(A) is a model front view of one ion resistor (ion resistor 80a) in this modified example, and FIG. 9(B) is a model side view of one ion resistor (ion resistor 80a) in this modified example. view.

本修改例之離子電阻80a~80d係以離子電阻80a~80d之厚度t1在離子電阻80a~80d之延伸方向愈接近饋電部位62則愈厚的方式而構成(參照圖9(B))。The ion resistors 80a to 80d in this modified example are configured such that the thickness t1 of the ion resistors 80a to 80d becomes thicker as the thickness t1 of the ion resistors 80a to 80d approaches the feeding portion 62 in the extending direction of the ion resistors 80a to 80d (see FIG. 9(B) ).

具體而言,參照圖9(B)及前述之圖6,本修改例之離子電阻80a的厚度t1,在離子電阻80a之延伸方向愈朝向Y方向則愈厚。本修改例之離子電阻80b的厚度t1,亦為在離子電阻80b之延伸方向愈朝向Y方向則愈厚。本修改例之離子電阻80d的厚度t1,在離子電阻80d之延伸方向愈朝向Z方向則愈厚。本修改例之離子電阻80c的厚度t1,亦為在離子電阻80 c之延伸方向愈朝向Z方向則愈厚。Specifically, referring to FIG. 9(B) and the aforementioned FIG. 6 , the thickness t1 of the ion resistor 80a in this modification becomes thicker toward the Y direction in the extending direction of the ion resistor 80a. The thickness t1 of the ion resistor 80b in this modification is also thicker toward the Y direction in the extending direction of the ion resistor 80b. The thickness t1 of the ion resistor 80d in this modification becomes thicker toward the Z direction in the extending direction of the ion resistor 80d. The thickness t1 of the ion resistor 80c in this modification is also thicker toward the Z direction in the extending direction of the ion resistor 80c.

此外,如圖9(A)所例示,本修改例之離子電阻80a~80d亦可具有複數個開口81。此時,如圖9(A)所例示,本修改例之離子電阻80a~80d的開口率不論從饋電部位62起之電性距離為何,亦可皆同。In addition, as illustrated in FIG. 9(A) , the ion resistors 80a to 80d of this modification may also have a plurality of openings 81. At this time, as illustrated in FIG. 9(A) , the aperture ratios of the ion resistors 80 a to 80 d of this modified example may be the same regardless of the electrical distance from the power feeding portion 62 .

採用本修改例時,藉由離子電阻80a~80d之厚度t1在離子電阻80a~80d之延伸方向愈接近饋電部位62則愈厚的簡單構成,可愈接近饋電部位62則愈提高離子電阻80a~80d的電阻率。 (實施形態2) When this modification is adopted, the thickness t1 of the ion resistors 80a to 80d becomes thicker in the extending direction of the ion resistors 80a to 80d as it approaches the feed portion 62, so that the ion resistance can be increased as it approaches the feed portion 62. Resistivity of 80a ~ 80d. (Embodiment 2)

接著說明實施形態2之鍍覆裝置1B。圖10係顯示本實施形態之鍍覆裝置1B中的1個鍍覆槽10周邊構成之模式剖面圖。本實施形態之鍍覆裝置1B與圖2所例示之鍍覆裝置1不同之處為不具備離子電阻80a~80d。Next, the plating apparatus 1B of Embodiment 2 is demonstrated. FIG. 10 is a schematic cross-sectional view showing the peripheral configuration of one plating tank 10 in the plating apparatus 1B of this embodiment. The plating apparatus 1B of this embodiment differs from the plating apparatus 1 illustrated in FIG. 2 in that it does not include the ion resistors 80a to 80d.

圖11係本實施形態之1個輔助陽極(輔助陽極60a)周邊構成的模式側視圖。圖12係用於比較彼此鄰接之一對輔助陽極的模式圖。參照圖11、圖12、及前述圖5,本實施形態之輔助陽極60a~60d與前述實施形態之輔助陽極(參照圖7)不同之處為,係以在輔助陽極60a~60d之延伸方向愈接近饋電部位62,則輔助陽極60a~60d與基板Wf之距離D1愈大的方式而構成。本實施形態之輔助陽極60a~60d的其他構成與前述實施形態之輔助陽極相同。Fig. 11 is a schematic side view of the peripheral structure of one auxiliary anode (auxiliary anode 60a) in this embodiment. FIG. 12 is a schematic diagram for comparing a pair of auxiliary anodes adjacent to each other. Referring to Figures 11, 12, and the aforementioned Figure 5, the difference between the auxiliary anodes 60a to 60d of this embodiment and the auxiliary anodes of the aforementioned embodiment (refer to Figure 7) is that the auxiliary anodes 60a to 60d are arranged in an extending direction. The distance D1 between the auxiliary anodes 60a to 60d and the substrate Wf becomes larger as the distance D1 approaches the power feeding portion 62. Other structures of the auxiliary anodes 60a to 60d of this embodiment are the same as those of the aforementioned embodiment.

具體而言,本實施形態之輔助陽極60a係以愈朝向Y方向則輔助陽極60a與基板Wf(具體而言係邊90a)之距離D1愈大的方式而構成。本實施形態之輔助陽極60b亦係以愈朝向Y方向則輔助陽極60b與基板Wf(具體而言係邊90b)之距離D1愈大的方式而構成。本實施形態之輔助陽極60c係以愈朝向Z方向則輔助陽極60c與基板Wf(具體而言係邊90c)之距離D1愈大的方式而構成。本實施形態之輔助陽極60d亦係以愈朝向Z方向則輔助陽極60d與基板Wf(具體而言係邊90d)之距離D1愈大的方式而構成。Specifically, the auxiliary anode 60a of this embodiment is configured so that the distance D1 between the auxiliary anode 60a and the substrate Wf (specifically, the tie edge 90a) becomes larger toward the Y direction. The auxiliary anode 60b of this embodiment is also configured so that the distance D1 between the auxiliary anode 60b and the substrate Wf (specifically, the tie edge 90b) becomes larger as the auxiliary anode 60b faces the Y direction. The auxiliary anode 60c of this embodiment is configured so that the distance D1 between the auxiliary anode 60c and the substrate Wf (specifically, the tie edge 90c) becomes larger as the auxiliary anode 60c faces the Z direction. The auxiliary anode 60d of this embodiment is also configured so that the distance D1 between the auxiliary anode 60d and the substrate Wf (specifically, the tether edge 90d) becomes larger as the auxiliary anode 60d faces the Z direction.

此外,如圖12所例示,比較在電流動方向觀看彼此鄰接之一對輔助陽極時,配置於接近饋電部位62位置之輔助陽極,與配置於遠離饋電部位62位置的輔助陽極比較,輔助陽極與基板Wf之距離的平均值D1a宜大。In addition, as shown in FIG. 12 , when a pair of auxiliary anodes adjacent to each other is compared in the direction of current flow, the auxiliary anode disposed close to the feeding part 62 is compared with the auxiliary anode disposed far away from the feeding part 62 . The average value D1a of the distance between the anode and the substrate Wf should be large.

具體而言,如圖12所例示,比較彼此鄰接之輔助陽極60a與輔助陽極60d時,輔助陽極60a與基板Wf之距離的平均值D1a宜比輔助陽極60d與基板Wf之距離的平均值D1a大。同樣地,比較彼此鄰接之輔助陽極60c與輔助陽極60b時,輔助陽極60c與基板Wf之距離的平均值D1a宜比輔助陽極60b與基板Wf之距離的平均值D1a大。Specifically, as shown in FIG. 12 , when comparing the auxiliary anode 60a and the auxiliary anode 60d that are adjacent to each other, the average value D1a of the distance between the auxiliary anode 60a and the substrate Wf is preferably larger than the average value D1a of the distance between the auxiliary anode 60d and the substrate Wf. . Similarly, when comparing the auxiliary anode 60c and the auxiliary anode 60b adjacent to each other, the average value D1a of the distance between the auxiliary anode 60c and the substrate Wf is preferably larger than the average value D1a of the distance between the auxiliary anode 60b and the substrate Wf.

此外,此時,輔助陽極60a與基板Wf之距離的平均值D1a亦可與輔助陽極60c與基板Wf之距離的平均值D1a相同。同樣地,輔助陽極60d與基板Wf之距離的平均值D1a亦可與輔助陽極60b與基板Wf之距離的平均值D1a相同。In addition, at this time, the average value D1a of the distance between the auxiliary anode 60a and the substrate Wf may be the same as the average value D1a of the distance between the auxiliary anode 60c and the substrate Wf. Similarly, the average value D1a of the distance between the auxiliary anode 60d and the substrate Wf can also be the same as the average value D1a of the distance between the auxiliary anode 60b and the substrate Wf.

採用本實施形態時,由於係以在輔助陽極60a~60d之延伸方向愈接近饋電部位62則輔助陽極60a~60d與基板Wf之距離D1愈大的方式而構成,因此可抑制因為匯流條61之連接部位63的電阻值愈接近饋電部位62則愈小,而造成基板Wf外周緣之膜厚不均勻。 (實施例) In this embodiment, since the distance D1 between the auxiliary anodes 60a to 60d and the substrate Wf becomes larger as the extension direction of the auxiliary anodes 60a to 60d approaches the feeding portion 62, it is possible to suppress the occurrence of the bus bar 61 The resistance value of the connection portion 63 becomes smaller as it approaches the power feeding portion 62, resulting in uneven film thickness on the outer periphery of the substrate Wf. (Example)

經實驗已確認關於上述實施形態之作用效果。就此作說明。首先,準備前述實施形態1之鍍覆裝置1作為實施例的鍍覆裝置。此外,準備除了不具備離子電阻之外,具有與實施例之鍍覆裝置1相同構成的鍍覆裝置,作為比較例之鍍覆裝置。The effect of the above embodiment has been confirmed through experiments. Explain this. First, the plating apparatus 1 of the above-mentioned Embodiment 1 is prepared as a plating apparatus of an example. In addition, a plating device having the same structure as the plating device 1 of the Example except that it does not have an ion resistance was prepared as a plating device of a comparative example.

而後,分別使用實施例之鍍覆裝置1及比較例之鍍覆裝置,在相同鍍覆處理條件下,對基板Wf實施鍍覆處理,量測該鍍覆處理後之基板Wf的膜厚。具體而言,參照圖3,量測鍍覆處理後之基板Wf的鍍膜外周緣之膜厚。更具體而言,係將最接近饋電部位62之角落部91a的周邊膜厚作為「起點」,而在圖3中箭頭指示之方向(順時鐘的方向)量測膜厚。該膜厚之量測結果顯示於圖13。Then, the plating device 1 of the embodiment and the plating device of the comparative example were respectively used to perform plating treatment on the substrate Wf under the same plating treatment conditions, and the film thickness of the substrate Wf after the plating treatment was measured. Specifically, referring to FIG. 3 , the film thickness of the outer peripheral edge of the coating on the substrate Wf after the plating process was measured. More specifically, the peripheral film thickness of the corner portion 91a closest to the power feeding portion 62 is used as the "starting point", and the film thickness is measured in the direction indicated by the arrow in FIG. 3 (clockwise direction). The measurement results of the film thickness are shown in Figure 13.

圖13之橫軸顯示從「起點」之距離(mm)。圖13之縱軸顯示基板Wf之膜厚(亦即,形成於基板Wf之鍍膜的膜厚(μm))。從圖13瞭解,使用比較例之鍍覆裝置對基板Wf實施鍍覆處理時,在基板Wf之外周緣中,接近饋電部位62之角落部91a周邊的膜厚最厚,遠離饋電部位62之角落部91c周邊的膜厚最薄。而比較例時,基板Wf之鍍膜外周緣的膜厚分布以「Range/2Ave(亦即,(膜厚之最大值-最小值)/(膜厚之平均值×2))」量測時係6.8%。The horizontal axis of Figure 13 shows the distance (mm) from the "starting point". The vertical axis of FIG. 13 shows the film thickness of the substrate Wf (that is, the film thickness (μm) of the plating film formed on the substrate Wf). As can be understood from FIG. 13 , when the substrate Wf is plated using the plating apparatus of the comparative example, the film thickness around the corner portion 91 a close to the feed portion 62 is the thickest on the outer periphery of the substrate Wf, and the film thickness is the thickest away from the feed portion 62 The film thickness around the corner portion 91c is the thinnest. In the comparative example, the film thickness distribution at the outer periphery of the coating on the substrate Wf is measured as "Range/2Ave (that is, (maximum value of film thickness - minimum value)/(average value of film thickness × 2))" 6.8%.

相對而言,使用實施例之鍍覆裝置1對基板Wf實施鍍覆處理時,整體觀察時,雖然在基板Wf上接近饋電部位62之角落部91a周邊的膜厚最厚,遠離饋電部位62之角落部91c周邊的膜厚最薄,不過角落部91a周邊之膜厚的厚度與比較例比較為小。結果,實施例時,與比較例作比較,基板Wf外周緣之膜厚整體地均勻化。舉出具體數值時,實施例時,基板Wf外周緣之膜厚分布係5.5%(Range/2Ave),與比較例作比較其數值變小。亦即,實施例與比較例作比較,可謀求基板Wf外周緣之膜厚分布的均勻化。Relatively speaking, when the substrate Wf is plated using the plating device 1 of the embodiment, when viewed as a whole, although the film thickness is thickest around the corner portion 91 a of the substrate Wf close to the power feeding portion 62 , it is far away from the power feeding portion. The film thickness around the corner 91c of corner 62 is the thinnest, but the film thickness around the corner 91a is smaller than in the comparative example. As a result, in the Example, compared with the Comparative Example, the film thickness of the outer peripheral edge of the substrate Wf was uniform throughout. When specific numerical values are given, in the Example, the film thickness distribution at the outer periphery of the substrate Wf was 5.5% (Range/2Ave), and the numerical value was smaller compared with the Comparative Example. That is, comparing the Example with the Comparative Example, it is possible to achieve uniform film thickness distribution at the outer peripheral edge of the substrate Wf.

另外,前述實施形態1之修改例的鍍覆裝置1A、及實施形態2之鍍覆裝置1B皆係在與實施形態1時同樣的條件下對基板Wf實施鍍覆處理來量測膜厚。結果,鍍覆裝置1A及鍍覆裝置1B中仍與實施例之鍍覆裝置1時同樣地,其基板Wf外周緣之膜厚分布獲得5.5%(Range/2Ave)之值。前述實施形態之效果藉由實驗確認如上。In addition, in both the plating apparatus 1A of the modified example of the first embodiment and the plating apparatus 1B of the second embodiment, the substrate Wf is plated under the same conditions as in the first embodiment to measure the film thickness. As a result, in the plating apparatus 1A and the plating apparatus 1B, the film thickness distribution at the outer periphery of the substrate Wf obtained a value of 5.5% (Range/2Ave), just like the plating apparatus 1 of the Example. The effects of the aforementioned embodiments were confirmed experimentally as described above.

以上,詳述了本發明之實施形態,不過本發明並非限定於該特定之實施形態者,在記載於申請專利範圍之本發明的要旨範圍內,可進一步進行各種修改及變更。The embodiments of the present invention have been described in detail. However, the present invention is not limited to the specific embodiments, and various modifications and changes can be made within the scope of the invention described in the patent claims.

1,1A,1B:鍍覆裝置 10:鍍覆槽 20:基板固持器 30:陽極 40:陽極盒 40a:開口 45:陽極遮罩 45a:孔 50:隔膜 51:隔膜 60a,60b,60c,60d:輔助陽極 61:匯流條 62:饋電部位 63:連接部位 64:連結部位 65:導入部位 66a,66b,66c,66d:延伸部位 70:中間遮罩 70a:孔 71:收容部 71a:開口 72a,72b,72c,72d:邊 80a,80b,80c,80d:離子電阻 81:開口 90a,90b,90c,90d:邊 91a,91b,91c,91d:角落部 100:匣盒 102:匣盒台 104:對準器 106:自旋沖洗乾燥機 110:鍍覆模組 120:裝載/卸載站 122:搬送機器人 124:暫存盒 126:預濕模組 128:預浸模組 130a:第一沖洗模組 130b:第二沖洗模組 132:噴氣模組 136:溢流槽 140:搬送裝置 142:第一搬送裝置 144:第二搬送裝置 150:軌道 152:裝載板 160:槳葉驅動部 162:槳葉從動部 170:控制模組 171:CPU 172:記憶裝置 200:電源 A1:空間區域 D1:距離 D1a:平均值 L1:長度 L2:寬度 Ps:鍍覆液 t1:厚度 Wf:基板 1,1A,1B: plating device 10:Plating tank 20:Substrate holder 30:Anode 40:Anode box 40a:Open your mouth 45:Anode mask 45a:hole 50: Diaphragm 51: Diaphragm 60a, 60b, 60c, 60d: auxiliary anode 61:Bus bar 62: Feeding part 63:Connection parts 64:Connection parts 65:Introduction part 66a, 66b, 66c, 66d: extension part 70: Middle mask 70a:hole 71: Containment Department 71a: Open your mouth 72a,72b,72c,72d: side 80a, 80b, 80c, 80d: ion resistance 81:Open your mouth 90a,90b,90c,90d: side 91a,91b,91c,91d: Corner 100:Box 102:Box table 104:Aligner 106: Spin rinse dryer 110: Plating module 120:Loading/unloading station 122:Transport robot 124: Temporary box 126: Pre-wet module 128:Prepreg module 130a: First flushing module 130b: Second flushing module 132:Jet module 136:Overflow tank 140:Conveying device 142: First conveying device 144: Second conveying device 150:Orbit 152:Loading plate 160:Paddle drive part 162:Paddle driven part 170:Control module 171:CPU 172:Memory device 200:Power supply A1: Space area D1: distance D1a: average L1:Length L2: Width Ps: plating solution t1:Thickness Wf: substrate

圖1係實施形態1之鍍覆裝置的整體配置圖。 圖2係顯示實施形態1之鍍覆裝置中的1個鍍覆槽周邊構成之剖面示意圖。 圖3係實施形態1之基板的前視示意圖。 圖4係實施形態1之中間遮罩周邊構成的立體示意圖。 圖5係實施形態1之匯流條及輔助陽極的前視示意圖。 圖6係實施形態1之離子電阻的前視示意圖。 圖7係實施形態1之輔助陽極周邊構成的側視示意圖。 圖8係實施形態1之離子電阻的前視示意圖。 圖9(A)及圖9(B)係用於說明實施形態1之修改例的鍍覆裝置之離子電阻的示意圖。 圖10係顯示實施形態2之鍍覆裝置中的1個鍍覆槽周邊構成之剖面示意圖。 圖11係實施形態2之輔助陽極周邊構成的側視示意圖。 圖12係用於比較實施形態2之彼此鄰接的一對輔助陽極之示意圖。 圖13係顯示膜厚的量測結果圖。 FIG. 1 is an overall layout diagram of the plating apparatus according to Embodiment 1. FIG. 2 is a schematic cross-sectional view showing the peripheral structure of a plating tank in the plating apparatus according to Embodiment 1. Fig. 3 is a schematic front view of the substrate according to Embodiment 1. 4 is a schematic perspective view of the peripheral structure of the intermediate mask according to Embodiment 1. FIG. 5 is a schematic front view of the bus bar and auxiliary anode according to the first embodiment. FIG. 6 is a schematic front view of the ion resistor according to the first embodiment. 7 is a schematic side view of the peripheral structure of the auxiliary anode in Embodiment 1. Fig. 8 is a schematic front view of the ion resistor according to the first embodiment. 9(A) and 9(B) are schematic diagrams for explaining the ion resistance of the plating apparatus according to the modification of the first embodiment. FIG. 10 is a schematic cross-sectional view showing the peripheral configuration of one plating tank in the plating apparatus according to Embodiment 2. Fig. 11 is a schematic side view of the peripheral structure of the auxiliary anode in Embodiment 2. FIG. 12 is a schematic diagram of a pair of adjacent auxiliary anodes in Embodiment 2 for comparison. Figure 13 is a graph showing the measurement results of film thickness.

1:鍍覆裝置 1: Plating device

60a,60b,60c,60d:輔助陽極 60a, 60b, 60c, 60d: auxiliary anode

61:匯流條 61:Bus bar

62:饋電部位 62: Feeding part

80a,80b,80c,80d:離子電阻 80a, 80b, 80c, 80d: ion resistance

A1:空間區域 A1: Space area

L1:長度 L1:Length

L2:寬度 L2: Width

Claims (6)

一種鍍覆裝置,係具備: 鍍覆槽,其係貯存鍍覆液; 陽極,其係配置於前述鍍覆槽之內部; 基板固持器,其係在前述鍍覆槽之內部,與前述陽極相對而可配置基板地構成; 至少1個輔助陽極,其係配置於在前述鍍覆槽內部的前述陽極與前述基板之間,並沿著前述基板之外周緣而延伸; 匯流條,其係具有:供給電之饋電部位、及連接於至少1個前述輔助陽極並且在該輔助陽極之延伸方向排列的複數個連接部位,並以將供給至前述饋電部位之電經由前述連接部位流入前述輔助陽極的方式而構成;及 至少1個離子電阻,其係配置於在前述鍍覆槽內部的前述輔助陽極與前述基板之間,並沿著前述輔助陽極而延伸; 前述離子電阻係以在前述離子電阻之延伸方向愈接近前述饋電部位,前述離子電阻之電阻率愈高的方式而構成。 A plating device equipped with: Plating tank, which stores plating liquid; Anode, which is arranged inside the aforementioned plating tank; a substrate holder, which is inside the plating tank and is configured to be opposite to the anode and capable of arranging the substrate; At least one auxiliary anode is arranged between the anode and the substrate inside the plating tank and extends along the outer periphery of the substrate; A bus bar has: a feed portion for supplying electricity, and a plurality of connection portions connected to at least one of the aforementioned auxiliary anodes and arranged in the extending direction of the auxiliary anode, and for supplying electricity to the aforementioned feed portion via The aforementioned connecting portion is formed in such a manner that the aforementioned auxiliary anode flows into the aforementioned auxiliary anode; and At least one ion resistor is arranged between the auxiliary anode and the substrate inside the plating tank and extends along the auxiliary anode; The ion resistor is configured such that the resistivity of the ion resistor becomes higher as the extending direction of the ion resistor is closer to the feeding point. 如請求項1之鍍覆裝置,其中前述離子電阻具有複數個開口, 藉由在前述離子電阻之延伸方向愈接近前述饋電部位而前述離子電阻的開口率愈低,而使前述離子電阻之電阻率在前述離子電阻的延伸方向愈接近前述饋電部位則愈高。 The plating device of claim 1, wherein the aforementioned ion resistor has a plurality of openings, Since the aperture ratio of the ion resistor is lower as the extending direction of the ion resistor is closer to the feeding portion, the resistivity of the ion resistor is higher as the extending direction of the ion resistor is closer to the feeding portion. 如請求項1之鍍覆裝置,其中藉由在前述離子電阻之延伸方向愈接近前述饋電部位而前述離子電阻的厚度愈厚,而使前述離子電阻之電阻率在前述離子電阻的延伸方向愈接近前述饋電部位則愈高。The plating device of claim 1, wherein the thickness of the ion resistor becomes thicker as the extending direction of the ion resistor is closer to the feeding position, so that the resistivity of the ion resistor becomes thicker in the extending direction of the ion resistor. The closer to the aforementioned feed position, the higher it is. 如請求項1之鍍覆裝置,其中前述匯流條具有連結部位,其係連結前述饋電部位與前述連接部位, 前述連結部位具有複數個延伸部位,其係沿著前述基板之外周緣而延伸, 複數個前述延伸部位配置成框狀, 至少1個前述輔助陽極包含複數個前述輔助陽極, 各個前述輔助陽極經由複數個前述連接部位而連接於各個前述延伸部位。 The plating device of claim 1, wherein the aforementioned bus bar has a connecting portion that connects the aforementioned feeding portion and the aforementioned connecting portion, The aforementioned connecting portion has a plurality of extending portions, which extend along the outer periphery of the aforementioned substrate, A plurality of the aforementioned extension parts are arranged in a frame shape, At least one of the aforementioned auxiliary anodes includes a plurality of the aforementioned auxiliary anodes, Each of the aforementioned auxiliary anodes is connected to each of the aforementioned extending portions via a plurality of the aforementioned connecting portions. 如請求項1之鍍覆裝置,其中具備收容部,其係在內部收容至少1個前述輔助陽極, 前述收容部中設有朝向前述基板之方的開口, 前述開口藉由隔膜堵塞而容許前述鍍覆液中所含之金屬離子通過,另外抑制從前述輔助陽極之表面產生的氧通過。 For example, the plating device of claim 1 is provided with a receiving portion that accommodates at least one of the aforementioned auxiliary anodes inside, The aforesaid receiving part is provided with an opening facing the above-mentioned substrate, The opening is blocked by the diaphragm to allow the metal ions contained in the plating solution to pass through, and also suppresses the passage of oxygen generated from the surface of the auxiliary anode. 一種鍍覆裝置,係具備: 鍍覆槽,其係貯存鍍覆液; 陽極,其係配置於前述鍍覆槽之內部; 基板固持器,其係在前述鍍覆槽之內部,與前述陽極相對而可配置基板地構成; 至少1個輔助陽極,其係配置於在前述鍍覆槽內部的前述陽極與前述基板之間,並沿著前述基板之外周緣而延伸;及 匯流條,其係具有:供給電之饋電部位、及連接於至少1個前述輔助陽極並且在該輔助陽極之延伸方向排列的複數個連接部位,並以將供給至前述饋電部位之電經由前述連接部位流入前述輔助陽極的方式而構成; 前述輔助陽極係以在前述輔助陽極之延伸方向愈接近前述饋電部位,前述輔助陽極與前述基板之距離愈大的方式而構成。 A plating device equipped with: Plating tank, which stores plating liquid; Anode, which is arranged inside the aforementioned plating tank; a substrate holder, which is inside the plating tank and is configured to be opposite to the anode and capable of arranging the substrate; At least one auxiliary anode is arranged between the anode and the substrate inside the plating tank and extends along the outer periphery of the substrate; and A bus bar has: a feed portion for supplying electricity, and a plurality of connection portions connected to at least one of the aforementioned auxiliary anodes and arranged in the extending direction of the auxiliary anode, and for supplying electricity to the aforementioned feed portion via The aforementioned connection part is formed in such a manner that it flows into the aforementioned auxiliary anode; The auxiliary anode is configured such that the distance between the auxiliary anode and the substrate becomes larger as the extending direction of the auxiliary anode is closer to the power feeding portion.
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