TW202109938A - Full color led display panel and manufacturing method thereof - Google Patents
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Abstract
Description
本發明係關於顯示面板的技術領域,尤指一種全彩LED顯示面板及其製造方法。 The present invention relates to the technical field of display panels, in particular to a full-color LED display panel and a manufacturing method thereof.
LED為目前廣泛應用之發光元件,其具有體積小、使用壽命長等優點,因而被廣泛地應用於人類的日常生活之中。LED的封裝結構類型通常根據LED的發光顏色、LED的發光亮度、電子元件的尺寸大小等特徵來分類。一般而言,超高亮度的LED的電子元件所採用的封裝結構為塑封帶引線片式載體(Plastic leaded chip carrier,PLCC),而小尺寸的LED的電子元件的封裝結構則通常為四方平面無引腳封裝(Quad flat no leads,QFN)。 LEDs are currently widely used light-emitting elements, which have the advantages of small size and long service life, so they are widely used in human daily life. LED packaging structure types are usually classified according to characteristics such as the luminous color of the LED, the luminous brightness of the LED, and the size of electronic components. Generally speaking, the packaging structure used for the electronic components of the ultra-high-brightness LED is a plastic leaded chip carrier (Plastic Leaded Chip Carrier, PLCC), while the packaging structure of the electronic components of the small-sized LED is usually a tetragonal plane. Pin package (Quad flat no leads, QFN).
隨著LED背光源被廣泛地應用至顯示器、平板電腦、與智慧型手機,LED的電子元件的尺寸被要求必須進一步地微縮至微米尺寸。Mini LED又名「次毫米發光二極體」,最早是由晶元光電(EPISTAR Corporation)所提出,晶粒的對角線長度介於50微米至60微米之間的LED。近年,微發光二極體(Micro LED)則成為新一代顯示技術,藉 由將LED晶粒進一步地微小化,使其晶粒的對角線長度小於50微米,同時透過薄膜化、陣列化與單獨驅動發光的技術來實現每個LED晶粒之圖元單獨定址。 As LED backlights are widely used in displays, tablet computers, and smart phones, the size of LED electronic components is required to be further reduced to a micron size. Mini LED, also known as "sub-millimeter light-emitting diode", was first proposed by EPISTAR Corporation. The diagonal length of the die is between 50 microns and 60 microns. In recent years, Micro LED (Micro LED) has become a new generation of display technology. The LED die is further miniaturized so that the diagonal length of the die is less than 50 microns, and at the same time, the individual addressing of the pixel of each LED die is realized through the technology of thin film, arraying and individual driving and light emission.
圖1顯示現有的微發光二極體顯示面板。目前的技術已經可以將大量的微發光二極體製成一micro LED顯示面板。例如,於圖1之中,微發光二極體顯示面板1’包括一基板10’、複數個紅光微發光二極體RLED’、複數個綠光微發光二極體GLED’、與複數個藍光微發光二極體BLED’。其中,該基板10’的表面設有複數個電性連接墊101’,用以電性連接該複數個紅光微發光二極體RLED’、該複數個綠光微發光二極體GLED’與該複數個藍光微發光二極體BLED’。熟悉顯示器之設計與製作的電子工程師必然知道,一個紅光微發光二極體RLED’、一個綠光微發光二極體GLED’與一個藍光微發光二極體BLED’構成微發光二極體顯示面板1’的一個畫素(pixel)。 Figure 1 shows a conventional micro light emitting diode display panel. The current technology can make a large number of micro light emitting diodes into a micro LED display panel. For example, in FIG. 1, the micro light emitting diode display panel 1'includes a substrate 10', a plurality of red light micro light emitting diodes RLED', a plurality of green light micro light emitting diodes GLED', and a plurality of Blue light-emitting diode BLED'. Wherein, the surface of the substrate 10' is provided with a plurality of electrical connection pads 101' for electrically connecting the plurality of red light emitting diodes RLED', the plurality of green light emitting diodes GLED' and The plurality of blue light-emitting diodes BLED'. Electronic engineers who are familiar with the design and production of displays must know that a red light emitting diode RLED', a green light emitting diode GLED' and a blue light emitting diode BLED' form a light emitting diode display. One pixel of panel 1'.
值得注意的是,解析度為4K2K的微發光二極體顯示面板1’具有4096×2160個畫素;也就是說,解析度為4K2K的微發光二極體顯示面板1’至少包含2,488萬顆微發光二極體。由此可知,如何將大量的微發光二極體(RLED’,GLED’,BLED’)排列至該基板10’之上,成為微發光二極體顯示面板1’最主要的製造方面的問題。 It is worth noting that the micro light emitting diode display panel 1'with a resolution of 4K2K has 4096×2160 pixels; that is to say, the micro light emitting diode display panel 1'with a resolution of 4K2K contains at least 24.88 million Slightly emitting diodes. It can be seen that how to arrange a large number of micro light emitting diodes (RLED', GLED', BLED') on the substrate 10' has become the most important manufacturing problem of the micro light emitting diode display panel 1'.
透過高準度的設備將巨量的微米等級的LED 晶粒佈置在一背板之上,此一程序被稱為巨量轉移(Mass transfer)。例如,美國專利公開號2018/0053742A1即揭示一種巨量轉移電子元件之方法。依據終端產品的不同,Micro LED顯示面板所採用的背板也不同。更詳細地說明,中小型電視、顯示器、筆記型電腦之顯示螢幕、平板電腦之顯示螢幕通常採用玻璃基板作為所述背板,而大型電視或戶外看板則以PCB基板為基礎。然而,實際使用過巨量轉移電子元件之方法的半導體元件工程師應該知道,在應用習知的巨量轉移製程的過程中,有部分的LED晶粒因受到外來應力的作用而損壞。 Through high-precision equipment, a large number of micron-level LEDs The die is arranged on a backplane, and this process is called Mass transfer. For example, US Patent Publication No. 2018/0053742A1 discloses a method for transferring a large amount of electronic components. Depending on the end product, the backplane used in the Micro LED display panel is also different. In more detail, small and medium-sized TVs, monitors, display screens of notebook computers, and display screens of tablet computers usually use a glass substrate as the backplane, while large-scale TVs or outdoor signage are based on PCB substrates. However, semiconductor device engineers who have actually used the method of mass transfer of electronic components should know that in the process of applying the conventional mass transfer process, some LED dies are damaged by external stress.
簡單地說,現有已知的巨量轉移電子元件之方法在實務應用上仍具有難以克服的缺陷。有鑑於此,本案之發明人係極力加以研究發明,而終於研發完成本發明之一種全彩LED顯示面板及其製造方法。 Simply put, the existing known methods for transferring a large amount of electronic components still have insurmountable shortcomings in practical applications. In view of this, the inventor of this case tried his best to research and invent, and finally developed and completed a full-color LED display panel of the present invention and its manufacturing method.
本發明之主要目的在於提出一種全彩LED顯示面板及其製造方法。所述製造方法係藉由一二維材料的使用而能夠在覆有二維材料層(例如:石墨烯)的一玻璃基板之上製作複數個發光結構。特別地,本發明之製造方法於每個發光結構之上形成一容置杯以容置量子點。如此設計,容置有紅光量子點的容置杯與一個發光結構便組成一個紅色子畫素,容置有綠光量子點的容置杯與一個發光結 構便組成一個綠色子畫素,且未容置有任何量子點的容置杯與一個發光結構便組成一個藍色子畫素。易於理解的,一個所述紅色子畫素、一個所述綠色子畫素與一個所述藍色子畫素係共同組成一個畫素),且整個全彩LED顯示面板則包括M×N個畫素。 The main purpose of the present invention is to provide a full-color LED display panel and a manufacturing method thereof. The manufacturing method uses a two-dimensional material to fabricate a plurality of light-emitting structures on a glass substrate covered with a two-dimensional material layer (for example, graphene). In particular, the manufacturing method of the present invention forms a containing cup on each light-emitting structure to contain the quantum dots. In this design, the containing cup containing the red light quantum dots and a light-emitting structure form a red sub-pixel, and the containing cup containing the green light quantum dots and a light-emitting junction The structure constitutes a green sub-pixel, and the receiving cup without any quantum dots and a light-emitting structure constitute a blue sub-pixel. It is easy to understand that one red sub-pixel, one green sub-pixel and one blue sub-pixel together form one pixel), and the entire full-color LED display panel includes M×N pictures Vegetarian.
因此,為了達成上述本發明之主要目的,本案之發明人係提供所述全彩LED顯示面板的一實施例,包括:一基板;一二維材料層,形成於該基板之上;一緩衝層,形成於該二維材料層之上;複數個發光結構,形成於該緩衝層之上,且每一個發光結構包括:一第一半導體材料層,形成於該緩衝層之上;一主動層,形成於該第一半導體材料層之上;及一第二半導體材料層,形成於該主動層之上;複數個表面電流擴散層,分別形成於各該第二半導體材料層之上;複數個有機容置件,分別形成於各該表面電流擴散層之上,使得每一個所述有機容置件皆隔著所述表面電流擴散層而位於該第二半導體材料層的上方;複數個第一電極層,分別形成於各該第一半導體材料層之上;以及複數個第二電極層,分別透過各該表面電流擴散層而形 成於各該第二半導體材料層之上;其中,該複數個有機容置件之一第一部分係用以容置複數個紅光轉換材料,該複數個有機容置件之一第二部分係用以容置複數個綠光轉換材料,且該複數個有機容置件之剩餘部分則未容置所述紅光轉換材料或所述綠光轉換材料;其中,容置有所述紅光轉換材料的一個所述有機容置件、一個所述表面電流擴散層、一個所述發光結構、一個所述第一電極、與一個所述第二電極係組成一個紅色子畫素;其中,容置有所述綠光轉換材料的一個所述有機容置件、一個所述表面電流擴散層、一個所述發光結構、一個所述第一電極、與一個所述第二電極係組成一個綠色子畫素;其中,未容置有所述紅光轉換材料或所述綠光轉換材料的一個所述有機容置件、一個所述表面電流擴散層、一個所述發光結構、一個所述第一電極、與一個所述第二電極係組成一個藍色子畫素。 Therefore, in order to achieve the above-mentioned main purpose of the present invention, the inventor of this case provides an embodiment of the full-color LED display panel, which includes: a substrate; a two-dimensional material layer formed on the substrate; and a buffer layer , Formed on the two-dimensional material layer; a plurality of light-emitting structures formed on the buffer layer, and each light-emitting structure includes: a first semiconductor material layer formed on the buffer layer; an active layer, Formed on the first semiconductor material layer; and a second semiconductor material layer formed on the active layer; a plurality of surface current diffusion layers formed on each of the second semiconductor material layers; and a plurality of organic The accommodating elements are respectively formed on each of the surface current diffusion layers, so that each of the organic accommodating elements is located above the second semiconductor material layer via the surface current diffusion layer; a plurality of first electrodes Layers, respectively formed on each of the first semiconductor material layers; and a plurality of second electrode layers, respectively formed through each of the surface current diffusion layers Is formed on each of the second semiconductor material layers; wherein, a first part of the plurality of organic accommodating members is used for accommodating a plurality of red light conversion materials, and a second part of the plurality of organic accommodating members is Used for accommodating a plurality of green light conversion materials, and the remaining part of the plurality of organic accommodating parts does not accommodate the red light conversion material or the green light conversion material; wherein, the red light conversion material is accommodated One said organic accommodating part, one said surface current diffusion layer, one said light-emitting structure, one said first electrode, and one said second electrode of materials constitute a red sub-pixel; wherein, the housing There is one said organic container, one said surface current diffusion layer, one said light-emitting structure, one said first electrode, and one said second electrode with said green light conversion material to form a green sub-picture Element; wherein, one of the organic accommodating member that does not contain the red light conversion material or the green light conversion material, one of the surface current diffusion layer, one of the light-emitting structure, one of the first electrode , And a second electrode system to form a blue sub-pixel.
並且,本案之發明人係同時提供一種全彩LED顯示面板的製造方法,其包括以下步驟:(1)利用乾式轉移技術將一二維材料層自一初始基板轉移至一基板之上;(2)利用原子層沉積技術形成一緩衝層於該二維材料層之 上;(3)利用濺鍍技術形成一第一半導體材料層於該緩衝層之上;(4)利用原子層沉積技術形成一主動層於該第一半導體材料層之上;(5)利用原子層沉積技術形成一第二半導體材料層於該主動層之上;(6)利用濺鍍技術形成一表面電流擴散層於該第二半導體材料層之上;(7)執行至少一蝕刻處理,以於該緩衝層之上定義出複數個發光結構;其中,各所述發光結構包括一部份所述第一半導體材料層、一部份所述主動層、一部份所述第二半導體材料層、以及一部份所述表面電流擴散層,且各所述發光結構的該第一半導體材料層具有一露出的電極設置台面,而各所述發光結構的該表面電流擴散層具有一露出窗;(8)形成一第一電極層於各所述發光結構的該第一半導體材料層的該電極設置台面之上,且透過所述露出窗形成一第一電極層於各所述發光結構的該第二半導體材料層之上;以及(9)於各所述第二半導體材料層之上形成一有機容置件,且令該複數個有機容置件之一第一部分容置複數個紅光轉換材料,令該複數個有機容置件之一第二部分容置複數個綠光轉換材料,且該複數個有機容置件之剩餘部分未容置 所述紅光轉換材料或所述綠光轉換材料。 In addition, the inventor of this case also provides a method for manufacturing a full-color LED display panel, which includes the following steps: (1) Using dry transfer technology to transfer a two-dimensional material layer from an initial substrate to a substrate; (2) ) Using atomic layer deposition technology to form a buffer layer on the two-dimensional material layer (3) Using sputtering technology to form a first semiconductor material layer on the buffer layer; (4) Using atomic layer deposition technology to form an active layer on the first semiconductor material layer; (5) Using atoms Layer deposition technology to form a second semiconductor material layer on the active layer; (6) use sputtering technology to form a surface current diffusion layer on the second semiconductor material layer; (7) perform at least one etching process to A plurality of light-emitting structures are defined on the buffer layer; wherein each of the light-emitting structures includes a part of the first semiconductor material layer, a part of the active layer, and a part of the second semiconductor material layer And a part of the surface current diffusion layer, and the first semiconductor material layer of each of the light-emitting structures has an exposed electrode setting mesa, and the surface current diffusion layer of each of the light-emitting structures has an exposure window; (8) A first electrode layer is formed on the electrode setting mesas of the first semiconductor material layer of each light-emitting structure, and a first electrode layer is formed on the light-emitting structure through the exposure window. On the second semiconductor material layer; and (9) forming an organic accommodating member on each of the second semiconductor material layers, and allowing one of the plurality of organic accommodating members to accommodate a plurality of red light conversion Material, so that the second part of one of the plurality of organic accommodating parts accommodates a plurality of green light conversion materials, and the remaining part of the plurality of organic accommodating parts is not accommodated The red light conversion material or the green light conversion material.
於前述本發明之全彩LED顯示面板及其製造方法的實施例中,該初始基板為一藍寶石基板,且該基板可為下列任一者:玻璃基板、電路板、或軟性電路板。 In the foregoing embodiment of the full-color LED display panel and the manufacturing method thereof of the present invention, the initial substrate is a sapphire substrate, and the substrate can be any of the following: a glass substrate, a circuit board, or a flexible circuit board.
於前述本發明之全彩LED顯示面板及其製造方法的實施例中,該二維材料層之製造材料可為下列任一者:石墨烯(graphene)、矽烯(silicene)、鍺烯(germanene)、錫烯(stanene)、磷烯(phosphorene)、硼烯(borophene)、過渡金屬硫族化物(Transition-metal dichalcogenides,TMDCs)、或氮化硼(BN)。 In the foregoing embodiments of the full-color LED display panel and the manufacturing method thereof of the present invention, the manufacturing material of the two-dimensional material layer can be any of the following: graphene, silicene, germanene ), stanene, phosphorene, borophene, transition-metal dichalcogenides (TMDCs), or boron nitride (BN).
於前述本發明之全彩LED顯示面板及其製造方法的實施例中,該紅光轉換材料包括複數個紅光量子點,且該綠光轉換材料包括複數個綠光量子點。 In the foregoing embodiments of the full-color LED display panel and the manufacturing method thereof of the present invention, the red light conversion material includes a plurality of red light quantum dots, and the green light conversion material includes a plurality of green light quantum dots.
於前述本發明之全彩LED顯示面板及其製造方法的實施例中,該緩衝層之製造材料可為下列任一者:未摻雜的氮化鎵(undoped GaN)、氮化鋁(AlN)、或氧化鋅(ZnO)。 In the foregoing embodiments of the full-color LED display panel and the manufacturing method thereof of the present invention, the material of the buffer layer can be any one of the following: undoped GaN, aluminum nitride (AlN) , Or zinc oxide (ZnO).
於前述本發明之全彩LED顯示面板及其製造方法的實施例中,該第一半導體材料層之製造材料為N型氮化鎵(n-type gallium nitride,n-GaN),且所述第二半導體材料層之製造材料為P型氮化鎵(p-type gallium nitride,p-GaN)。 In the foregoing embodiments of the full-color LED display panel and the manufacturing method thereof of the present invention, the manufacturing material of the first semiconductor material layer is n-type gallium nitride (n-GaN), and the first semiconductor material layer is n-type gallium nitride (n-GaN), and the first semiconductor material layer is n-type gallium nitride (n-GaN). The manufacturing material of the two semiconductor material layers is p-type gallium nitride (p-GaN).
於前述本發明之全彩LED顯示面板及其製造方法的實施例中,該主動層於該第一半導體材料層與該第二半 導體材料層之間形成一個多重量子井結構,且該多重量子井結構為一未摻雜的氮化鎵(undoped GaN)層與一氮化銦鎵(InxGa1-xN)層的多重交互堆疊結構。 In the foregoing embodiment of the full-color LED display panel and the manufacturing method of the present invention, the active layer forms a multiple quantum well structure between the first semiconductor material layer and the second semiconductor material layer, and the multiple quantum well The structure is a multiple alternate stacked structure of an undoped GaN layer and an indium gallium nitride (In x Ga 1-x N) layer.
於前述本發明之全彩LED顯示面板及其製造方法的實施例中,該表面電流擴散層的製造材料可為下列任一者:氧化銦錫(Indium tin oxide,ITO)、銻摻雜二氧化錫(Antimony-doped tin oxide,ATO)、氟摻雜二氧化錫(Fluorine-doped tin oxide,FTO)、氧化銦鋅(Indium zinc oxide,IZO)、鎵摻雜氧化鋅(Gallium doped zinc oxide,GZO)、鋁摻雜氧化鋅(Aluminum-doped zinc oxide,AZO)、石墨烯、或奈米銀線。 In the foregoing embodiments of the full-color LED display panel and the manufacturing method thereof of the present invention, the surface current diffusion layer can be made of any one of the following: indium tin oxide (ITO), antimony-doped dioxide Tin (Antimony-doped tin oxide, ATO), Fluorine-doped tin oxide (FTO), Indium zinc oxide (IZO), Gallium doped zinc oxide (Gallium doped zinc oxide, GZO) ), aluminum-doped zinc oxide (AZO), graphene, or silver nanowires.
於前述本發明之全彩LED顯示面板及其製造方法的實施例中,該有機容置件係由一有機光阻材料(Organic photoresist material)製成。 In the foregoing embodiments of the full-color LED display panel and the manufacturing method thereof of the present invention, the organic accommodating member is made of an organic photoresist material.
於前述本發明之全彩LED顯示面板及其製造方法的實施例中,所述第一電極與所述第二電極的製造材料可為下列任一者:鋁(Al)、銀(Ag)、鈦(Ti)、鎳(Ni)、金(Au)、銅(Cu)、鉻(Cr)、鉑(Pt)、前述任兩者之組合、或前述任兩者以上之組合。 In the foregoing embodiments of the full-color LED display panel of the present invention and the manufacturing method thereof, the manufacturing materials of the first electrode and the second electrode can be any one of the following: aluminum (Al), silver (Ag), Titanium (Ti), nickel (Ni), gold (Au), copper (Cu), chromium (Cr), platinum (Pt), a combination of any two of the foregoing, or a combination of any two or more of the foregoing.
<本發明> <The present invention>
1‧‧‧全彩LED顯示面板 1‧‧‧Full-color LED display panel
10‧‧‧基板 10‧‧‧Substrate
10i‧‧‧初始基板 10i‧‧‧Initial substrate
10C‧‧‧銅膜 10C‧‧‧Copper film
10A‧‧‧熱解膠層 10A‧‧‧Pyrolytic adhesive layer
11‧‧‧二維材料層 11‧‧‧Two-dimensional material layer
12‧‧‧緩衝層 12‧‧‧Buffer layer
13‧‧‧表面電流擴散層 13‧‧‧Surface current spreading layer
131‧‧‧露出窗 131‧‧‧Exposing the window
14‧‧‧有機容置件 14‧‧‧Organic container
L1‧‧‧第一半導體材料層 L1‧‧‧First semiconductor material layer
L2‧‧‧主動層 L2‧‧‧Active layer
L3‧‧‧第二半導體材料層 L3‧‧‧Second semiconductor material layer
Lr‧‧‧第一發光結構 Lr‧‧‧First light-emitting structure
Lg‧‧‧第二發光結構 Lg‧‧‧Second light-emitting structure
Lb‧‧‧第三發光結構 Lb‧‧‧Third light-emitting structure
E1‧‧‧第一電極層 E1‧‧‧First electrode layer
E2‧‧‧第二電極層 E2‧‧‧Second electrode layer
RM‧‧‧紅光轉換材料 RM‧‧‧Red light conversion material
GM‧‧‧綠光轉換材料 GM‧‧‧Green light conversion material
S1-S9‧‧‧步驟 S1-S9‧‧‧Step
<習知> <Learning>
RLED’‧‧‧紅光微發光二極體 RLED’‧‧‧Red light micro-emitting diode
GLED’‧‧‧綠光微發光二極體 GLED’‧‧‧Green Micro-Light Emitting Diode
BLED’‧‧‧藍光微發光二極體 BLED’‧‧‧Blue light micro-emitting diode
1’‧‧‧顯示面板 1’‧‧‧Display panel
101’‧‧‧電性連接墊 101’‧‧‧Electrical connection pad
10’‧‧‧基板 10’‧‧‧Substrate
圖1顯示現有的微發光二極體顯示面板; 圖2顯示本發明之一種全彩LED顯示面板的示意性立體圖;圖3A顯示第一發光結構之示意性立體圖;圖3B顯示第二發光結構之示意性立體圖;圖3C顯示第三發光結構之示意性立體圖;圖4A與圖4B顯示本發明之一種全彩LED顯示面板的製造方法之流程圖;圖5A至圖5H顯示步驟S1的示意性製造流程圖;以及圖6A至圖6J顯示本發明之全彩LED顯示面板的示意性製造流程圖。 Figure 1 shows a conventional micro light emitting diode display panel; Figure 2 shows a schematic perspective view of a full-color LED display panel of the present invention; Figure 3A shows a schematic perspective view of a first light-emitting structure; Figure 3B shows a schematic perspective view of a second light-emitting structure; Figure 3C shows a schematic perspective view of a third light-emitting structure Fig. 4A and Fig. 4B show a flow chart of a manufacturing method of a full-color LED display panel of the present invention; Figs. 5A to 5H show a schematic manufacturing flow chart of step S1; and Figs. 6A to 6J show the present invention A schematic manufacturing flow chart of a full-color LED display panel.
為了能夠更清楚地描述本發明所提出的一種全彩LED顯示面板及其製造方法,以下將配合圖式,詳盡說明本發明之較佳實施例。 In order to be able to more clearly describe a full-color LED display panel and its manufacturing method proposed by the present invention, the preferred embodiments of the present invention will be described in detail below in conjunction with the drawings.
全彩LED顯示面板之結構 Structure of full-color LED display panel
請參閱圖2,其顯示本發明之一種全彩LED顯示面板的示意性立體圖。如圖2所示,本發明之全彩LED顯示面板1的結構包括:一基板10、形成於該基板10之上的一二維材料層11、形成於該二維材料層11之上的一緩衝層12、複數個發光結構(Lr,Lg,Lb)、複數個表面電流擴散層13、複數個有機容置件14、複數個第一電極層E1、以及複數個第
二電極層E2。
Please refer to FIG. 2, which shows a schematic perspective view of a full-color LED display panel of the present invention. As shown in FIG. 2, the structure of the full-color
必須先行強調的是,圖2中係以填滿效果表示不同的材料層,目的僅在區隔任二相鄰的材料層,並非是用以表示各材料層之外型或顏色。本發明係以玻璃基板作為所述基板10,但不限於此。在可行的實施例中,該基板10也可以是電路板或軟性電路板。另一方面,在示範性的實施例中,該二維材料層11的製造材料為石墨烯(graphene)。然而,在可行的實施例中,該二維材料層11的製造材料也可以是矽烯(silicene)、鍺烯(germanene)、錫烯(stanene)、磷烯(phosphorene)、硼烯(borophene)、過渡金屬硫族化物(Transition-metal dichalcogenides,TMDCs)、或氮化硼(BN)。補充說明的是,所述過渡金屬硫族化物具有分子式MX2,其中M為IVB-VIB族之中的任一種過渡金屬,且X為VIA族(chalcogen)之中的硫、硒、或碲。再者,該緩衝層12之製造材料可為下列任一者:未摻雜的氮化鎵(undoped GaN)、氮化鋁(AlN)、或氧化鋅(ZnO)。
It must be emphasized first that the filling effect in Figure 2 shows different material layers. The purpose is only to separate any two adjacent material layers, not to show the shape or color of each material layer. The present invention uses a glass substrate as the
請同時參閱圖3A、圖3B、與圖3C,其中圖3A顯示第一發光結構之示意性立體圖,圖3B顯示第二發光結構之示意性立體圖,而圖3C顯示第三發光結構之示意性立體圖。依據本發明之設計,該複數個發光結構(Lr,Lg,Lb)包括:複數個第一發光結構Lr、複數個第二發光結構Lg、與複數個第三發光結構Lb。並且,由圖3A、圖3B、與圖3C 可知,各該第一發光結構Lr、各該第二發光結構Lg、與各該第三發光結構Lb皆包括:形成於該緩衝層12之上的一第一半導體材料層L1、形成於該第一半導體材料層L1之上的一主動層L2、以及形成於該主動層L2之上的一第二半導體材料層L3。較佳地,該第一半導體材料層L1之製造材料為N型氮化鎵(n-type gallium nitride,n-GaN),且所述第二半導體材料層L2之製造材料為P型氮化鎵(p-type gallium nitride,p-GaN)。並且,該主動層L2於該第一半導體材料層L1與該第二半導體材料層L3之間形成一個多重量子井結構,且該多重量子井結構為一未摻雜的氮化鎵(undoped GaN)層與一氮化銦鎵(InxGa1-xN)層的多重交互堆疊結構。 Please refer to FIGS. 3A, 3B, and 3C at the same time, in which FIG. 3A shows a schematic perspective view of the first light-emitting structure, FIG. 3B shows a schematic perspective view of the second light-emitting structure, and FIG. 3C shows a schematic perspective view of the third light-emitting structure . According to the design of the present invention, the plurality of light-emitting structures (Lr, Lg, Lb) include: a plurality of first light-emitting structures Lr, a plurality of second light-emitting structures Lg, and a plurality of third light-emitting structures Lb. And, as can be seen from FIGS. 3A, 3B, and 3C, each of the first light-emitting structure Lr, each of the second light-emitting structure Lg, and each of the third light-emitting structure Lb includes: formed on the buffer layer 12 A first semiconductor material layer L1, an active layer L2 formed on the first semiconductor material layer L1, and a second semiconductor material layer L3 formed on the active layer L2. Preferably, the manufacturing material of the first semiconductor material layer L1 is n-type gallium nitride (n-GaN), and the manufacturing material of the second semiconductor material layer L2 is p-type gallium nitride (p-type gallium nitride, p-GaN). Moreover, the active layer L2 forms a multiple quantum well structure between the first semiconductor material layer L1 and the second semiconductor material layer L3, and the multiple quantum well structure is an undoped GaN (undoped GaN) Layer and an indium gallium nitride (In x Ga 1-x N) layer in multiple alternate stacked structure.
熟悉LED之元件設計與製作的工程師應該知道,由一未摻雜的氮化鎵(undoped GaN)層與一氮化銦鎵(InxGa1-xN)層的多重交互堆疊而成的主動層L2主要用以發出一藍色光。進一步地,如圖2、圖3A、圖3B、與圖3C所示,本發明還在各該第二半導體材料層L3之上設有一表面電流擴散層13,且該表面電流擴散層13的製造材料可為下列任一者:氧化銦錫(Indium tin oxide,ITO)、銻摻雜二氧化錫(Antimony-doped tin oxide,ATO)、氟摻雜二氧化錫(Fluorine-doped tin oxide,FTO)、氧化銦鋅(Indium zinc oxide,IZO)、鎵摻雜氧化鋅(Gallium doped zinc oxide,GZO)、鋁摻雜氧化鋅(Aluminum-doped zinc oxide,AZO)、
石墨烯、或奈米銀線。
Engineers who are familiar with the design and manufacture of LED components should know that the active material is composed of an undoped gallium nitride (undoped GaN) layer and an indium gallium nitride (In x Ga 1-x N) layer. The layer L2 is mainly used to emit a blue light. Further, as shown in FIGS. 2, 3A, 3B, and 3C, the present invention also provides a surface
特別地,本發明於各該第二半導體材料層L3之上同時設有一有機容置件14;其中,各該有機容置件14係由一有機光阻材料(Organic photoresist material)製成,且令各該有機容置件14皆隔著所述表面電流擴散層13而位於該第二半導體材料層L3的上方。進一步地,如圖2、圖3A、圖3B、與圖3C所示,本發明還令該複數個有機容置件14之一第一部分容置複數個紅光轉換材料RM,令該複數個有機容置件14之一第二部分容置複數個綠光轉換材料GM,且該複數個有機容置件14之剩餘部分未容置所述紅光轉換材料RM或所述綠光轉換材料GM。如此設計,容置有所述紅光轉換材料RM的一個所述有機容置件14、一個所述表面電流擴散層13、一個所述發光結構、一個所述第一電極E1、與一個所述第二電極E2係組成一個紅光LED發光元件以作為一紅色子畫素(Sub pixel)。並且,容置有所述綠光轉換材料GM的一個所述有機容置件14、一個所述表面電流擴散層13、一個所述發光結構、一個所述第一電極E1、與一個所述第二電極E2係組成一個紅光LED發光元件以作為一個綠色子畫素(Sub pixel)。同時,未容置有所述紅光轉換材料RM或所述綠光轉換材料GM的一個所述有機容置件14、一個所述表面電流擴散層13、與各所述發光結構、一個所述第一電極E1、與一個所述第二電極E2係組成一個紅光LED
發光元件以作為一個藍色子畫素(Sub pixel)。依據本發明之設計,該紅光轉換材料包括複數個紅光量子點,且該綠光轉換材料包括複數個綠光量子點。簡單地說,本發明特別設計令一個所述紅色子畫素、一個所述綠色子畫素與一個所述藍色子畫素係共同組成一個畫素(Pixel),且整個全彩LED顯示面板1則包括M×N個畫素。
In particular, in the present invention, an organic accommodating
特別說明的是,本發明並未限定所述紅光LED發光元件、所述綠光LED發光元件以及所述藍光LED發光元件的尺寸大小。各所述LED發光元件之晶粒的對角線長度可以介於50微米至60微米之間,以成為Mini LED發光元件。或者,各所述LED發光元件之晶粒的對角線長度可以小於50微米,以成為Micro LED發光元件。另一方面,圖2、圖3A、圖3B、與圖3C還顯示,複數個第一電極層E1分別形成於各該第一半導體材料層L1之上,且複數個第二電極層E2,分別透過各該表面電流擴散層13而形成於各該第二半導體材料層L3之上。易於理解的,透過該第一電極層E1與該第二電極層E2,外部驅動電路能夠選擇性地驅動一個或多個所述紅色子畫素(亦即,第一發光結構Lr)、一個或多個所述綠色子畫素(亦即,第二發光結構Lg)、及/或一個或多個所述藍色子畫素(亦即,第三發光結構Lb)進行發光。在可行的實施例中,所述第一電極與所述第二電極的製造材料可為下列任一者:鋁(Al)、銀(Ag)、鈦(Ti)、鎳(Ni)、 金(Au)、銅(Cu)、鉻(Cr)、鉑(Pt)、前述任兩者之組合、或前述任兩者以上之組合。 In particular, the present invention does not limit the size of the red LED light emitting element, the green LED light emitting element, and the blue LED light emitting element. The diagonal length of the die of each LED light-emitting element can be between 50 μm and 60 μm to become a Mini LED light-emitting element. Alternatively, the diagonal length of the die of each LED light-emitting element may be less than 50 microns to become a Micro LED light-emitting element. On the other hand, FIGS. 2, 3A, 3B, and 3C also show that a plurality of first electrode layers E1 are formed on each of the first semiconductor material layers L1, and a plurality of second electrode layers E2, respectively Each of the surface current diffusion layers 13 is formed on each of the second semiconductor material layers L3. It is easy to understand that through the first electrode layer E1 and the second electrode layer E2, an external driving circuit can selectively drive one or more of the red sub-pixels (that is, the first light-emitting structure Lr), one or A plurality of the green sub-pixels (that is, the second light-emitting structure Lg) and/or one or more of the blue sub-pixels (that is, the third light-emitting structure Lb) emit light. In a feasible embodiment, the manufacturing materials of the first electrode and the second electrode can be any of the following: aluminum (Al), silver (Ag), titanium (Ti), nickel (Ni), Gold (Au), copper (Cu), chromium (Cr), platinum (Pt), a combination of any two of the foregoing, or a combination of any two or more of the foregoing.
全彩LED顯示面板的製造方法 Manufacturing method of full-color LED display panel
請參閱圖4A與圖4B,其顯示本發明之一種全彩LED顯示面板的製造方法之流程圖。如圖4A所示,本發明之全彩LED顯示面板的製造方法係首先執行步驟S1:利用乾式轉移技術(Dry release transfer)將一二維材料層11自一初始基板10i轉移至一基板10之上。請同時參閱圖5A至圖5H,其顯示步驟S1的示意性製造流程圖。執行步驟S1之時,如圖5A所示,首先在一初始基板10i之上鍍覆一層銅膜10C,其中所述初始基板10i可以是一藍寶石基板。接著,如圖5B所示,利用化學氣相沉積技術(Chemical vapor deposition,CVD)於該銅膜10C接著形成一二維材料層11,例如:石墨烯(graphene)層。繼續地,如圖5C和圖5D所示,貼附一熱解膠層10A在該二維材料層11之上,且透過施力於該熱解膠層10A的方式將銅膜10C及二維材料層11與該初始基板10i分離。接著,如圖5E和圖5F所示,使用蝕刻液移除該銅膜10C,而後將該熱解膠層10A及該二維材料層11貼附至一基板10(例如玻璃基板)之上。最終,如圖5G和圖5H所示,在透過加熱的方式移除該熱解膠層10A之後,即獲得表面覆有石墨烯(graphene)層的一個玻璃基板。
Please refer to FIG. 4A and FIG. 4B, which show a flowchart of a manufacturing method of a full-color LED display panel of the present invention. As shown in FIG. 4A, the manufacturing method of the full-color LED display panel of the present invention first executes step S1: using dry release transfer technology to transfer a two-
繼續地參閱圖4A與圖4B,並請同時參閱圖6A至圖
6J,其顯示本發明之全彩LED顯示面板的示意性製造流程圖。如圖6A所示,完成步驟S1之後,即獲得表面覆有二維材料層11的基板10。接著,如圖4A與圖6B所示,製造方法的流程係接著執行步驟S2:利用原子層沉積技術(Atomic layer deposition,ALD)形成一緩衝層12於該二維材料層11之上。更詳細地說明,執行步驟S2時,係先對覆有該二維材料層11的該基板10做基本的表面清潔,接著使用ALD方法在石墨烯(二維材料層11)表面鍍上一未摻雜的氮化鎵(undoped GaN)薄膜。
Continue to refer to Figures 4A and 4B, and please refer to Figures 6A to 6 at the same time
6J, which shows a schematic manufacturing flow chart of the full-color LED display panel of the present invention. As shown in FIG. 6A, after step S1 is completed, a
繼續地,如圖4A與圖6C所示,製造方法的流程係接著執行步驟S3:利用濺鍍技術(Sputtering)形成一第一半導體材料層L1於該緩衝層12之上。更詳細地說明,執行步驟S3時,係先將一氮化鎵靶材結合至一濺鍍槍,在通入製程氣體之後,及利用濺鍍方法在所述未摻雜的氮化鎵(u-GaN)薄膜(即,緩衝層12)之上成長nGaN薄膜以作為所述第一半導體材料層L1。接著,如圖4A與圖6D所示,製造方法的流程係接著執行步驟S4:利用原子層沉積技術(ALD)形成一主動層L2於該第一半導體材料層L1之上。執行步驟S4時,係先對所述未摻雜的氮化鎵(u-GaN)薄膜作基本的表面處理,接著使用ALD方法於u-GaN膜之上製作出多重量子井結構以作為所述主動層L2。其中,該多重量子井結構為一未摻雜的氮化鎵(undoped GaN)層與一氮化銦鎵
(InxGa1-xN)層的多重交互堆疊結構,且該u-GaN層與該InxGa1-xN層的交互堆疊之層數介於8層至14層之間。
Continuing, as shown in FIG. 4A and FIG. 6C, the flow of the manufacturing method is followed by step S3: forming a first semiconductor material layer L1 on the
接著,如圖4A與圖6E所示,製造方法的流程係接著執行步驟S5:利用原子層沉積技術(ALD)形成一第二半導體材料層L3於該主動層L2之上。執行步驟S5時,係先對所述多重量子井結構作基本的表面處理,接著使用ALD方法於主動層L2之上製作一pGaN薄膜以作為所述第二半導體材料層L3。繼續地,如圖4B與圖6F所示,製造方法的流程係接著執行步驟S6:利用濺鍍技術(Sputtering)形成一表面電流擴散層13於該第二半導體材料層L3之上。更詳細地說明,執行步驟S6時,係使用濺鍍方法在所述pGaN薄膜的表面鍍上一層ITO透明導電膜以作為所述表面電流擴散層13。
Next, as shown in FIGS. 4A and 6E, the manufacturing method is followed by step S5: A second semiconductor material layer L3 is formed on the active layer L2 using atomic layer deposition (ALD). When step S5 is performed, a basic surface treatment is performed on the multiple quantum well structure first, and then a pGaN film is fabricated on the active layer L2 using the ALD method to serve as the second semiconductor material layer L3. Continuing, as shown in FIGS. 4B and 6F, the flow of the manufacturing method is followed by step S6: forming a surface
繼續地,如圖4B與圖6G所示,製造方法的流程係接著執行步驟S7:執行至少一蝕刻處理,以於該緩衝層12之上定義出複數個發光結構(Lr,Lg,Lb)。特別說明的是,此處所稱蝕刻處理為LED元件的平台蝕刻(Mesa etching)處理。並且,該複數個發光結構包括複數個第一發光結構Lr、複數個第二發光結構Lg、以及複數個第三發光結構Lb,其中,各所述發光結構(Lr,Lg,Lb)皆包括一部份所述第一半導體材料層L1、一部份所述主動層L2、一部份所述第二半導體材料層L3、以及一部份所述表面電流擴散層13,且各
所述發光結構(Lr,Lg,Lb)的該第一半導體材料層L1具有一露出的電極設置台面,同時各所述發光結構(Lr,Lg,Lb)的該表面電流擴散層13具有一露出窗131。
Continuing, as shown in FIGS. 4B and 6G, the flow of the manufacturing method is followed by step S7: at least one etching process is performed to define a plurality of light-emitting structures (Lr, Lg, Lb) on the
接著,如圖4B、圖6H與圖6I所示,製造方法的流程係接著執行步驟S8:形成一第一電極層E1於各所述發光結構(Lr,Lg,Lb)的該第一半導體材料層L1的該電極設置台面之上,且透過所述露出窗131形成一第一電極層E1於各所述發光結構的該第二半導體材料層L3之上。最終,如圖4B、圖6J、圖3A、以及圖3B所示,製造方法的流程係接著執行步驟S9:於各所述第二半導體材料層L3之上形成一有機容置件14,且令該複數個有機容置件14之一第一部分容置複數個紅光轉換材料RM,令該複數個有機容置件14之一第二部分容置複數個綠光轉換材料GM,且該複數個有機容置件14之剩餘部分未容置所述紅光轉換材料RM或所述綠光轉換材料GM。
Next, as shown in FIG. 4B, FIG. 6H and FIG. 6I, the flow of the manufacturing method is followed by step S8: forming a first electrode layer E1 on the first semiconductor material of each of the light-emitting structures (Lr, Lg, Lb) The electrode of the layer L1 is disposed on the mesa, and a first electrode layer E1 is formed through the
完成步驟S9之後,如圖2所示,容置有所述紅光轉換材料RM的一個所述有機容置件14、一個所述表面電流擴散層13、一個所述發光結構、一個所述第一電極E1、與一個所述第二電極E2係組成一個紅色子畫素(Sub pixel)。並且,容置有所述綠光轉換材料GM的一個所述有機容置件14、一個所述表面電流擴散層13、一個所述發光結構、一個所述第一電極E1、與一個所述第二電極E2係組成一個綠
色子畫素(Sub pixel)。同時,未容置有所述紅光轉換材料RM或所述綠光轉換材料GM的一個所述有機容置件14、一個所述表面電流擴散層13、與個所述發光結構、一個所述第一電極E1、與一個所述第二電極E2係組成一個藍色子畫素(Sub pixel)。依據本發明之設計,該紅光轉換材料包括複數個紅光量子點,且該綠光轉換材料包括複數個綠光量子點。簡單地說,本發明特別設計令一個所述紅色子畫素、一個所述綠色子畫素與一個所述藍色子畫素係共同組成一個畫素(Pixel),且整個全彩LED顯示面板1則包括M×N個畫素。
After step S9 is completed, as shown in FIG. 2, one of the organic
如此,上述係已完整且清楚地說明本發明之全彩LED顯示面板及其製造方法。必須加以強調的是,上述之詳細說明係針對本發明可行實施例之具體說明,惟該實施例並非用以限制本發明之專利範圍,凡未脫離本發明技藝精神所為之等效實施或變更,均應包含於本案之專利範圍中。 Thus, the above system has completely and clearly explained the full-color LED display panel and the manufacturing method thereof of the present invention. It must be emphasized that the above detailed description is a specific description of possible embodiments of the present invention, but this embodiment is not intended to limit the patent scope of the present invention. Any equivalent implementation or modification that does not deviate from the technical spirit of the present invention, All should be included in the patent scope of this case.
1‧‧‧全彩LED顯示面板 1‧‧‧Full-color LED display panel
10‧‧‧基板 10‧‧‧Substrate
11‧‧‧二維材料層 11‧‧‧Two-dimensional material layer
12‧‧‧緩衝層 12‧‧‧Buffer layer
13‧‧‧表面電流擴散層 13‧‧‧Surface current spreading layer
14‧‧‧有機容置件 14‧‧‧Organic container
Lr‧‧‧第一發光結構 Lr‧‧‧First light-emitting structure
Lg‧‧‧第二發光結構 Lg‧‧‧Second light-emitting structure
Lb‧‧‧第三發光結構 Lb‧‧‧Third light-emitting structure
RM‧‧‧紅光轉換材料 RM‧‧‧Red light conversion material
GM‧‧‧綠光轉換材料 GM‧‧‧Green light conversion material
Claims (20)
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