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TW202006153A - Austenite alloy steel including manganese, aluminum, carbon, molybdenum, and iron - Google Patents

Austenite alloy steel including manganese, aluminum, carbon, molybdenum, and iron Download PDF

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TW202006153A
TW202006153A TW107123925A TW107123925A TW202006153A TW 202006153 A TW202006153 A TW 202006153A TW 107123925 A TW107123925 A TW 107123925A TW 107123925 A TW107123925 A TW 107123925A TW 202006153 A TW202006153 A TW 202006153A
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alloy steel
vostian
steel according
aluminum
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TWI715852B (en
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江明煌
黃丁一
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永鼎應用金屬股份有限公司
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Priority to CA3014436A priority patent/CA3014436C/en
Priority to CN201810932982.6A priority patent/CN110714167A/en
Priority to US16/107,810 priority patent/US20200017929A1/en
Priority to AU2018220088A priority patent/AU2018220088B1/en
Priority to EP18190883.1A priority patent/EP3594376B1/en
Priority to JP2018183072A priority patent/JP6735798B2/en
Priority to KR1020180146921A priority patent/KR102211466B1/en
Priority to MX2018016180A priority patent/MX2018016180A/en
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Abstract

The present invention provides an Austenite alloy steel, which includes 25 wt% to 31 wt% of manganese, 7 wt% to 10 wt% of aluminum, 1.2 wt% to 1.6 wt% of carbon, less than 6 wt% of molybdenum, and a balanced amount of iron. The Austenite alloy steel of the present invention has high strength, high ductility and high temperature strength, and has a density of 6.8 g/cm 3, which is 14% lighter than traditional steel for molds. The Austenite alloy steel further includes less than 6 wt% chromium, and less than 5 wt% cobalt, the elongation rate is 20% to 40% and the ultimate tensile strength is higher than 1250 MPa at 25 DEG C, and the ultimate tensile strength is higher than 1000 MPa at 300 DEG C.

Description

沃斯田體合金鋼Vostian alloy steel

本發明是有關於一種沃斯田體合金鋼,特別是指一種適用於製作熱加工工具的沃斯田體合金鋼。The invention relates to a Vostian alloy steel, in particular to a Vostian alloy steel suitable for making hot working tools.

麻田散體鋼材具有優異的硬度及韌性等機械性質,因此常被用於製作熱加工工具的材料,然而,麻田散體鋼材的延展性不佳,而可能造成製成的熱加工工具開裂的情況產生。Ma Tian loose steel has excellent mechanical properties such as hardness and toughness, so it is often used as a material for hot working tools. However, the ductility of Ma Tian loose steel is not good, which may cause the hot tool to crack.

AISI H13鋼材為其中一種用於製作熱加工工具的麻田散體鋼材,包含0.32wt%至0.45wt%的碳、0.8wt%至1.2wt%的矽、0.20wt%至0.50wt%的錳、4.75wt%至5.5wt%的鉻、1.10wt%至1.75wt%的鉬、0.8wt%至1.2wt%的釩、不大於0.03wt%的磷、不大於0.03wt%的硫,以及平衡量的鐵。該AISI H13鋼材的室溫硬度最高介於55至58、伸長率介於3%至5%,因伸長率較低在使用上易脆裂,故一般使用時會將該鋼材的硬度降低至42至50,使伸長率提高至介於5%至8%、衝擊韌性介於5焦耳至10焦耳,及高溫硬度(Rockwell C hardness,HRc)介於33至41。AISI H13 steel is one of the Ma Tian loose steel used for making hot working tools, including 0.32wt% to 0.45wt% carbon, 0.8wt% to 1.2wt% silicon, 0.20wt% to 0.50wt% manganese, 4.75wt % To 5.5wt% chromium, 1.10wt% to 1.75wt% molybdenum, 0.8wt% to 1.2wt% vanadium, no more than 0.03wt% phosphorus, no more than 0.03wt% sulfur, and a balanced amount of iron. The room temperature hardness of the AISI H13 steel is up to 55 to 58, and the elongation is between 3% and 5%. Because of the low elongation, it is easy to crack when used, so the hardness of the steel will be reduced to 42 during general use. To 50, the elongation is increased to 5% to 8%, the impact toughness is between 5 Joules to 10 Joules, and the high temperature hardness (Rockwell C hardness, HRc) is 33 to 41.

QRO 90鋼材為另一種用於製作熱加工工具的麻田散體鋼材,包含0.38wt%的碳、0.30wt%的矽、0.75wt%的錳、2.60wt%的鉻、2.25wt%的鉬、0.9wt%的釩,以及平衡量的鐵。該QRO 90鋼材的室溫硬度為45、伸長率為11%、衝擊韌性為10焦耳,以及高溫硬度(Rockwell C hardness,HRc)介於26至41。QRO 90 steel is another Ma Tian bulk steel used for making hot working tools, including 0.38wt% carbon, 0.30wt% silicon, 0.75wt% manganese, 2.60wt% chromium, 2.25wt% molybdenum, 0.9wt % Vanadium, and a balanced amount of iron. The QRO 90 steel has a room temperature hardness of 45, an elongation of 11%, an impact toughness of 10 joules, and a high temperature hardness (Rockwell C hardness, HRc) of 26 to 41.

另一方面,鐵錳鋁碳沃斯田體(Austenite)鋼材因其高機械強度及高延展性的特性而具有應用潛力,因此在過去數十年間受到廣泛的研究。On the other hand, iron-manganese-aluminum-carbon Austenite steels have application potential because of their high mechanical strength and high ductility, and therefore have been extensively studied in the past few decades.

習知鋼鐵合金中的碳含量超過約1.2wt.%時,合金的延展性將嚴重劣化或謂脆化。因此研究沃斯田體合金系統的先前技藝中,合金中的碳量均會控制在0.54-1.3wt.%之間。而於此碳含量的鐵錳鋁碳鋼則是藉由添加鉬、鈮,及/或鎢以增加機械強度,然而,添加上述元素雖可增加習知鐵錳鋁碳沃斯田體鋼材的機械強度,但也因為此類合金在時效處理過程容易在沃斯田體晶界上沉澱粗大碳化物,因而造成延展性(即伸長率)下降的問題,使得利用此類鋼料製成的熱加工工具於使用過程容易有開裂的情況產生。It is known that when the carbon content in a steel alloy exceeds about 1.2 wt.%, the ductility of the alloy will be seriously deteriorated or embrittled. Therefore, in the prior art of studying the Vostian body alloy system, the amount of carbon in the alloy will be controlled between 0.54-1.3wt.%. The iron-manganese-aluminum-carbon steel with this carbon content is to increase the mechanical strength by adding molybdenum, niobium, and/or tungsten. However, the addition of the above elements can increase the machinery of the conventional iron-manganese-aluminum-carbon Voss steel Strength, but also because such alloys tend to precipitate coarse carbides on the grain boundary of the Wust body during the aging process, resulting in the problem of reduced ductility (ie, elongation), making hot working tools made of such steel materials It is easy to crack during use.

申請人的美國專利第9,528,177揭示了一種具有特定含量的鐵、錳、鋁,及碳的鐵錳鋁碳四元合金,該鐵錳鋁碳四元合金利用將碳含量控制在介於1.4wt.%至2.2wt.% 而可令該鐵錳鋁碳四元合金在固溶化處理(SHT)後的淬火期間,藉由旋節分解(spinodal decomposition)相變態機制於沃斯田體基相中形成高密度且細緻的κ’-碳化物,使該鐵錳鋁碳四元合金具有優異的延展性以及高機械強度。然而,於該鐵錳鋁碳四元合金中添加強碳化物形成元素,例如鉻、鈦,及鉬等元素,並無法對沃斯田體基相中高密度且細緻的κ’-碳化物的形成有明顯的效果,因此並不建議於該鐵錳鋁碳四元合金中添加該等強碳化物形成元素。Applicant's US Patent No. 9,528,177 discloses an iron, manganese, aluminum, and carbon quaternary alloy with a specific content of iron, manganese, aluminum, and carbon. The iron, manganese, aluminum, and carbon quaternary alloy utilizes the carbon content to be controlled between 1.4wt. % To 2.2wt.% and the iron-manganese-aluminum-carbon quaternary alloy can form a high density in the base phase of the Vostian body through the spinodal decomposition phase transformation mechanism during the quenching after solid solution treatment (SHT) And the delicate κ'-carbide makes the iron-manganese-aluminum-carbon quaternary alloy have excellent ductility and high mechanical strength. However, the addition of strong carbide-forming elements, such as chromium, titanium, and molybdenum, to this iron-manganese-aluminum-carbon quaternary alloy does not significantly affect the formation of high-density and fine κ'-carbides in the base phase of the Vostian body It is therefore not recommended to add the strong carbide forming elements to the iron-manganese-aluminum-carbon quaternary alloy.

因此,本發明之目的,即在提供一種在室溫具有優異機械性質且不影響延展性、在高溫下也具有優異強度的沃斯田體(Austenite)合金鋼。Therefore, the object of the present invention is to provide an Austenite alloy steel which has excellent mechanical properties at room temperature without affecting ductility and excellent strength at high temperatures.

於是,本發明沃斯田體合金鋼包含25wt%至31wt%的錳、7wt%至10wt%的鋁、1.2wt%至1.6wt%的碳、大於0wt%且小於6wt%的鉬,以及平衡量的鐵。Therefore, the Vostian alloy steel of the present invention contains 25 wt% to 31 wt% manganese, 7 wt% to 10 wt% aluminum, 1.2 wt% to 1.6 wt% carbon, more than 0 wt% and less than 6 wt% molybdenum, and the balance amount Iron.

本發明之功效在於:藉由在特定成分的鐵鋁錳碳沃斯田體合金鋼中添加小於6wt%的鉬,使該沃斯田體合金鋼於室溫下具有優異的機械性質,以及極限拉伸強度,且於高溫(~500℃)時也可具有良好的強度表現。The effect of the present invention is: by adding less than 6wt% of molybdenum to a specific composition of iron, aluminum, manganese, carbon, and field alloy steel, the field alloy steel has excellent mechanical properties at room temperature, and the limit Tensile strength, and can have good strength performance at high temperature (~500℃).

本發明揭示一種具有高強度及高延性的沃斯田體(Austenite)合金鋼,該沃斯田體合金鋼可應用於一般鋼板(如汽車鋼板)、零件(如齒輪)或熱模具鋼。The invention discloses an Austenite alloy steel with high strength and high ductility. The Austenite alloy steel can be applied to general steel plates (such as automobile steel plates), parts (such as gears) or hot die steels.

該沃斯田體合金鋼的合金組成包含25wt%至31wt%的錳、7wt%至10wt%的鋁、1.2wt%至1.6wt%的碳、大於0wt%且小於6wt%的鉬,以及平衡量的鐵。The alloy composition of the Vostian body alloy steel includes 25wt% to 31wt% manganese, 7wt% to 10wt% aluminum, 1.2wt% to 1.6wt% carbon, more than 0wt% and less than 6wt% molybdenum, and the balance amount Iron.

錳為沃斯田體強化元素,由於沃斯田體相為面心立方(face-center-cubic,FCC)結構,有較多的滑移系統,因此相較於體心立方(body-center-cubic,BCC)結構或六方最密堆積(hexagonal close packed,HCP)結構具有較佳的延展性。為了於室溫時能得到完全的沃斯田體結構,因此本發明沃斯田體合金鋼中的錳含量為25wt%至31wt%。於一些實施例中,該沃斯田體合金鋼的錳含量介於26wt%至30wt%。於一些實施例中,該沃斯田體合金鋼的錳含量介於27wt%至29wt%。Manganese is a Vostian body strengthening element. Since the Vostian body phase is face-center-cubic (FCC) structure and has more slip systems, it is compared to body-center cubic (body-center-cubic). cubic (BCC) structure or hexagonal close packed (HCP) structure has better ductility. In order to obtain a complete Voss field structure at room temperature, the manganese content in the Voss field alloy steel of the present invention is 25 wt% to 31 wt%. In some embodiments, the manganese content of the Vostian alloy steel is between 26 wt% and 30 wt%. In some embodiments, the manganese content of the Vostian alloy steel is between 27 wt% and 29 wt%.

鋁不僅是沃斯田體強化元素,也是形成(Fe,Mn)3 AlCx 碳化物(即κ’-碳化物)的主要元素,於本發明沃斯田體合金鋼中的鋁含量為7wt%至10wt%。於一些實施例中,該沃斯田體合金鋼的鋁含量介於8wt%至10wt%。於一些實施例中,該沃斯田體合金鋼的鋁含量介於8wt%至9wt%。Aluminum is not only the strengthening element of the Vostian body, but also the main element forming (Fe, Mn) 3 AlC x carbide (ie κ'-carbide). The aluminum content in the Vostian body alloy steel of the present invention is 7 wt% Up to 10wt%. In some embodiments, the aluminum content of the Vostian alloy steel is between 8 wt% and 10 wt%. In some embodiments, the aluminum content of the Vostian alloy steel is between 8 wt% and 9 wt%.

本發明沃斯田體合金鋼中的碳含量為1.2wt%至1.6wt%,高於習知含有鉬、鈮,及/或鎢的鐵錳鋁碳沃斯田體鋼材的碳含量(即最高為1.0wt%)。於一些實施例中,該沃斯田體合金鋼的碳含量為1.3wt%至1.6wt%。The carbon content of the Vostian body alloy steel of the present invention is 1.2 wt% to 1.6 wt%, which is higher than that of the conventional ferromanganese aluminum carbon Vostian body steels containing molybdenum, niobium, and/or tungsten (i.e. the highest 1.0wt%). In some embodiments, the carbon content of the Vostian alloy steel is 1.3 wt% to 1.6 wt%.

鉬為一種強碳化物形成元素,於本發明沃斯田體合金鋼中,鉬的含量為大於0wt%且小於6wt%。於一些實施例中,該沃斯田體合金鋼的鉬含量介於2wt%至6wt%。Molybdenum is a strong carbide-forming element. In the Wustfield alloy steel of the present invention, the content of molybdenum is greater than 0 wt% and less than 6 wt%. In some embodiments, the molybdenum content of the Vostian alloy steel is between 2 wt% and 6 wt%.

於一些實施例中,該沃斯田體合金鋼還包含同樣為強碳化物形成元素的鉻元素,且鉻元素的含量小於6wt%。In some embodiments, the Vostian alloy steel also contains chromium, which is also a strong carbide forming element, and the content of chromium is less than 6 wt%.

於一些實施例中,該沃斯田體合金鋼還包含同樣為強碳化物形成元素的鈷元素,且鈷元素的含量小於5wt%。In some embodiments, the Vostian alloy steel also contains cobalt element, which is also a strong carbide forming element, and the content of the cobalt element is less than 5 wt%.

要說明的是,該沃斯田體合金鋼中的低熔點元素(例如錳、鋁)的含量會因熔煉過程中揮發而造成製成的該沃斯田體合金鋼中部分元素的實際含量與熔煉時的添加量不同,然而,兩者間的差異並不大,且在可容許誤差範圍而不影響最終製成的該沃斯田體合金的性質。It should be noted that the content of low melting point elements (such as manganese and aluminum) in the Vostian body alloy steel will be caused by volatilization during the smelting process. The amount of addition during smelting is different, however, the difference between the two is not large, and it is within the allowable error range without affecting the properties of the finally produced Vostian body alloy.

配合參閱圖1,該沃斯田體合金鋼的製作方法包含步驟91至步驟95。Referring to FIG. 1, the manufacturing method of the Vostian alloy steel includes steps 91 to 95.

該步驟91為將前述該沃斯田體合金鋼的合金組成,於大氣下在高週波熔煉爐熔煉成鑄件。The step 91 is to smelt the aforementioned alloy composition of the Vostian body alloy steel into a casting in a high frequency melting furnace under the atmosphere.

之後進行步驟92,於1100℃至950℃對該鑄件進行熱作處理(例如:熱軋、熱鍛造等)至預定的形狀而成為一熱作件。Then, step 92 is performed, and the casting is hot-worked (for example: hot rolling, hot forging, etc.) at 1100°C to 950°C to a predetermined shape to become a hot work.

接著進行步驟93,將該熱作件進行第一次水淬並冷卻至室溫。Next, step 93 is performed, and the hot work is water quenched for the first time and cooled to room temperature.

接著進行步驟94。該步驟94為將第一次水淬處理後的該熱作件於480℃至600℃進行時效(Aging)處理。Then proceed to step 94. The step 94 is to perform aging treatment on the hot work piece after the first water quenching treatment at 480°C to 600°C.

詳細地說,該時效處理的溫度介於480℃至500℃時,該時效處理的時間(Aging time)為5至12小時;該時效處理的溫度大於500℃時,該時效處理的時間則為1至4小時。In detail, when the temperature of the aging treatment is between 480°C and 500°C, the aging time is 5 to 12 hours; when the temperature of the aging treatment is greater than 500°C, the aging time is 1 to 4 hours.

最後,進行步驟95,將經過時效處理後該熱作件進行第二次水淬並冷卻至室溫,即完成該沃斯田體合金鋼的製作。Finally, step 95 is performed, and the hot work piece after aging treatment is subjected to second water quenching and cooled to room temperature, that is, the production of the Vostian body alloy steel is completed.

本發明沃斯田體合金鋼的製作流程與習知碳含量較低且含有強碳化物形成元素的鐵錳鋁碳合金鋼不同,習知低碳含量且含有強碳化物形成元素的鐵錳鋁碳合金鋼於熱加工後,需進行固溶化熱處理,將於晶界上析出的粗大碳化物重新溶解於基地相中,以提升該鐵錳鋁碳合金鋼的延展性,而本發明該沃斯田體合金鋼組成,雖具有較高含量的碳,及強碳化物形成元素,然而,本發明利用熱作處理(熱軋或熱鍛造)溫度的控制(1100℃至950℃),因此可避免該鐵錳鋁碳合金組成於熱作處理過程在晶界上析出粗大的碳化物,故於熱作處理後不需進行習知的固溶化熱處理步驟,即可令製得的該沃斯田體合金鋼同時具有強度及延展性。The manufacturing process of the Vostian body alloy steel of the present invention is different from the conventional iron-manganese-aluminum-carbon alloy steel with low carbon content and containing strong carbide-forming elements, and the conventional iron-manganese-aluminum steel with low carbon content and containing strong carbide-forming elements is known. After hot working, the carbon alloy steel needs to be subjected to solution heat treatment, and the coarse carbides precipitated on the grain boundary will be re-dissolved in the base phase to improve the ductility of the iron manganese aluminum carbon alloy steel. The field alloy steel composition, although it has a relatively high content of carbon and strong carbide forming elements, however, the present invention utilizes the temperature control (1100°C to 950°C) of the hot working process (hot rolling or hot forging), so it can be avoided The iron-manganese-aluminum-carbon alloy is composed of precipitated coarse carbides on the grain boundaries during the hot working process. Therefore, after the hot working process, the conventional solid solution heat treatment step is not required to make the Vostian body obtained Alloy steel has both strength and ductility.

此外,要說明的是,前述該步驟95也可視製程而不需進行,即也可以選擇讓該熱作件於時效處理後自然冷卻至室溫,而不需進行第二次水淬。再者,本發明利用熱作處理溫度的控制,已可有效避免粗大碳化物析出而影響合金鋼的延性,因此,可不用進行習知的熱固溶步驟,而可有效減少整體製程時間。然而,於熱作處理及第一次水淬後也可以選擇再進行熱固溶步驟,此製程也不影響本案合金鋼的整體特性。In addition, it should be noted that the aforementioned step 95 can also be performed without a process, that is, the hot work piece can also be selected to be naturally cooled to room temperature after aging treatment without performing a second water quenching. In addition, the present invention uses heat as the control of the treatment temperature, which can effectively prevent the precipitation of coarse carbides and affect the ductility of the alloy steel. Therefore, it is possible to effectively reduce the overall process time without performing the conventional heat solution step. However, after the hot working treatment and the first water quenching, you can also choose to carry out the hot solution step. This process does not affect the overall characteristics of the alloy steel in this case.

特別的是,利用本發明沃斯田鐵合金組成搭配本案的製作方法所製得的沃斯田體合金鋼為完全沃斯田體相,其室溫(25℃)降伏強度(YS)介於1200MPa至1400MPa、洛氏硬度(Rockwell C hardness,HRc)介於45至55、極限拉伸強度介於1200MPa至1500MPa,及伸長率(El)介於20%至40%,且同時可在高溫(<700℃)時具有良好的降伏強度(YS)及極限拉伸強度(UTS)。因此,本案的沃斯田體合金鋼除了可作為一般鋼板(如汽車鋼板)、零件(如齒輪)之外,更適用於熱作模具鋼。In particular, the Vostian body alloy steel prepared by using the Vostian iron alloy composition of the present invention and the manufacturing method of this case is a complete Vostian body phase, and its room temperature (25°C) yield strength (YS) is between 1200 MPa To 1400MPa, Rockwell C hardness (HRc) between 45 and 55, ultimate tensile strength between 1200MPa and 1500MPa, and elongation (El) between 20% and 40%, and at the same time can be at high temperature (< 700℃) has good yield strength (YS) and ultimate tensile strength (UTS). Therefore, in addition to being used as general steel plates (such as automobile steel plates) and parts (such as gears), the Vostian body alloy steel in this case is more suitable for hot work die steel.

此外,要說明的是,一般鐵鋁錳碳合金的密度約介於6.6~6.8g/cm3 ,相較於一般模具用鋼(密度約7.8~7.9g/cm3 )輕了14%。因此,本發明沃斯田體合金鋼除了具有高強度、高延性外還可具有輕量的優點。In addition, it should be noted that the density of the general iron-aluminum-manganese-carbon alloy is about 6.6~6.8g/cm 3 , which is 14% lighter than that of the general mold steel (density about 7.8~7.9g/cm 3 ). Therefore, in addition to high strength and high ductility, the Vostian body alloy steel of the present invention can also have the advantages of light weight.

習知高碳含量(1.4wt.%至2.2wt.%)的鐵鋁錳碳合金雖然經由製程控制(熱處理/固溶化/淬水)可得到顯微結構為完全沃斯田體相,且在沃斯田體相基地內有十分緻密細微的奈米尺寸的(Fe,Mn)3 AlCx 碳化物(κ′-碳化物),並可避免在晶界上析出粗大的碳化物,因此,該鐵鋁錳碳合金於室溫時可具有基本良好的機械性質及伸長率。然而,本發明發現,當進一步於特定比例的鐵錳鋁碳合金組成中添加含量介於2~6wt%的碳化物強化元素(鉬、鉻、鈷),並配合熱處理溫度的控制時,可有效避免在晶界上產生習知會大幅降低材料延展性的粗大碳化物沉澱的缺點,因此,除了可保有所製得的該鐵鋁錳碳合金鋼於室溫的延性之外,還可同時進一步提升該製鐵鋁錳碳合金鋼的室溫及高溫強度,此外,因為本案的該鐵鋁錳碳合金鋼不需固溶處理步驟,因此,還可有效減少整體製程時間。It is known that iron, aluminum, manganese and carbon alloys with high carbon content (1.4wt.% to 2.2wt.%) can be obtained through the process control (heat treatment/solid solution/quenching water) to obtain a microstructure of complete Vostian body phase, and in There are very dense and fine nano-sized (Fe, Mn) 3 AlC x carbides (κ′-carbide) in the Vostian body phase base, and the precipitation of coarse carbides on the grain boundaries can be avoided. Therefore, the The iron-aluminum-manganese-carbon alloy can have basically good mechanical properties and elongation at room temperature. However, the present invention found that it can be effective when further adding carbide strengthening elements (molybdenum, chromium, cobalt) with a content of 2-6 wt% to the composition of the iron-manganese-aluminum-carbon alloy in a specific ratio, together with the control of heat treatment temperature It avoids the disadvantages of coarse carbide precipitation that will reduce the ductility of the material on the grain boundary. Therefore, in addition to the ductility of the iron-aluminum-manganese-carbon alloy steel produced at room temperature, it can be further improved at the same time. The room temperature and high temperature strength of the iron-aluminum-manganese-carbon alloy steel made in this case, in addition, because the iron-aluminum-manganese-carbon alloy steel in this case does not require a solution treatment step, it can also effectively reduce the overall process time.

茲利用下述具體例1~11及比較例1~3的合金組成製成測試試片後進行相關物性測試,以更具體說明本發明該沃斯田體合金鋼的特性。The physical properties of the test specimens are made using the alloy compositions of the following specific examples 1 to 11 and comparative examples 1 to 3, and then tested to more specifically describe the characteristics of the Vostian body alloy steel of the present invention.

要注意的是,下述具體例是為了說明示範本發明該沃斯田體合金鋼,當不能以此限定本發明實施之範圍。It should be noted that the following specific examples are intended to illustrate the Vostian body alloy steel that exemplifies the present invention, but it cannot be used to limit the scope of the present invention.

具體例1Specific example 1

1.將含有30wt%的錳、8.5wt%的鋁、1.45wt%的碳、6%的鉬,以及平衡量的鐵的合金成分於大氣下以高週波熔煉爐熔製成厚度為2公分的鑄件。1. An alloy composition containing 30wt% manganese, 8.5wt% aluminum, 1.45wt% carbon, 6% molybdenum, and a balanced amount of iron is melted in the atmosphere in a high-frequency melting furnace to a thickness of 2cm casting.

2.將該鑄件於1100℃的爐中加熱20分鐘,接著於1100℃至950℃進行熱軋至厚度至少小於該鑄件厚度的25%,以得測試試片。2. The casting is heated in a furnace at 1100°C for 20 minutes, and then hot rolled at 1100°C to 950°C to a thickness of at least less than 25% of the thickness of the casting to obtain a test piece.

3.將測試試片進行第一次水淬至室溫,之後研磨去除氧化層,接著於500℃下進行時效處理(Aging),最後再將測試試片進行第二次水淬至室溫後待用。3. Perform the first water quenching of the test piece to room temperature, then grind to remove the oxide layer, then perform aging treatment at 500°C (Aging), and finally perform the second water quenching of the test piece to room temperature stand-by.

具體例2至11Specific examples 2 to 11

該具體例2至11的測試試片製作方式與該具體例1的測試試片相同,不同之處在於合金中各元素的含量。The test specimens of the specific examples 2 to 11 are made in the same way as the test specimen of the specific example 1, except for the content of each element in the alloy.

比較例1~3Comparative examples 1~3

該比較例1~3的測試試片製作方式與該具體例1相同,不同之處在於合金中各元素的含量。The test specimens of the comparative examples 1 to 3 are made in the same way as the specific example 1, except for the content of each element in the alloy.

茲將該等具體例及比較例的合金組成元素含量整理如表1所示。The content of alloy constituent elements of these specific examples and comparative examples is summarized in Table 1.

表1

Figure 107123925-A0304-0001
Table 1
Figure 107123925-A0304-0001

接著將前述該等具體例及比較例製得的測試試片進行降伏強度(YS)、極限拉伸強度(UTS)、伸長率(El),及硬度(HRc)測試。Next, the test specimens prepared by the foregoing specific examples and comparative examples are tested for yield strength (YS), ultimate tensile strength (UTS), elongation (El), and hardness (HRc).

該等測試試片的降伏強度、極限拉伸強度、伸長率,及硬度是利用下述的測試方式於室溫下量測,量測結果如表2所示。The yield strength, ultimate tensile strength, elongation, and hardness of the test specimens were measured at room temperature using the following test methods. The measurement results are shown in Table 2.

此外,該具體例4、7及9,以及比較例1~3的測試試片於300℃、500℃,及700℃下進行降伏強度及極限拉伸強度的測試,結果如表3所示。In addition, the test specimens of the specific examples 4, 7 and 9 and comparative examples 1 to 3 were tested at 300°C, 500°C and 700°C for yield strength and ultimate tensile strength. The results are shown in Table 3.

各特性的測試方式:Test method of each feature:

1.拉伸測試1. Tensile test

降伏強度(Yield Strength,YS):拉伸曲線圖以與彈性線平行0.2%應變量時的應力。Yield Strength (YS): The stress when the tensile curve is parallel to the elastic line by 0.2% strain.

極限拉伸強度(Ultimate Tensile Strength,UTS):拉伸曲線圖中最大應力。Ultimate Tensile Strength (UTS): The maximum stress in the tensile curve.

伸長率(Elongation,El):拉伸曲線圖以斷裂點畫與彈性線平行的應變量。Elongation (Elongation, El): The tensile curve plots the amount of strain parallel to the elastic line at the break point.

前述降伏強度、極限拉伸強度,及伸長率是利用Instron拉伸試驗機,於室溫(25℃)以拉伸速率10-3 /秒進行測試而得拉伸曲線圖。其中,測試試片的規格參照ASTM E8/E8M規範,於高溫測試時是將高溫爐加裝於拉伸試驗機,加熱至預定溫度後再進行拉伸測試。The aforementioned yield strength, ultimate tensile strength, and elongation are measured using an Instron tensile testing machine at room temperature (25°C) at a tensile rate of 10-3 /sec to obtain a tensile curve. Among them, the specifications of the test specimens refer to ASTM E8/E8M specifications. During high temperature testing, a high temperature furnace is installed in a tensile testing machine, and the tensile test is performed after heating to a predetermined temperature.

2.硬度測試(HRc)2. Hardness test (HRc)

使用洛式硬度機(Rockwell Hardness machine),以荷重150kgf進行測試,測試時使用壓痕器為金剛石圓錐。Rockwell Hardness machine (Rockwell Hardness machine), with a load of 150kgf for testing, the test using the indenter is a diamond cone.

表2

Figure 107123925-A0304-0002
Table 2
Figure 107123925-A0304-0002

表3

Figure 107123925-A0304-0003
table 3
Figure 107123925-A0304-0003

如表2所示,該具體例1至11製備的測試試片的室溫降伏強度介於1230MPa至1350MPa、室溫極限拉伸強度介於1280MPa至1386MPa、室溫伸長率介於20%至37%,以及硬度(HRc)介於45.0至47.7,相較於比較例1及比較例2的各特性數據,顯示,本發明該沃斯田體合金鋼確實具備高強度,且亦具有良好的延展性。要特別說明的是,藉由控制該沃斯田體合金鋼中的鉬含量於2wt%至6wt%,相較於比較例1~3,及AISI H13與QRO 90兩種習知熱作合金,本發明沃斯田體合金鋼不僅保有極佳的室溫強度及室溫伸長率,且於高溫時也可具有一定的強度,顯示本發明該沃斯田體合金鋼良好的延展性亦可作為新型的熱作合金鋼使用,而可避免製成的熱作工具於使用時開裂的情況。As shown in Table 2, the test specimens prepared in the specific examples 1 to 11 have a room temperature yield strength between 1230 MPa and 1350 MPa, a room temperature ultimate tensile strength between 1280 MPa and 1386 MPa, and a room temperature elongation between 20% and 37 %, and the hardness (HRc) is between 45.0 and 47.7. Compared with the characteristic data of Comparative Example 1 and Comparative Example 2, it is shown that the Vostian alloy steel of the present invention does have high strength and also has good extension. Sex. In particular, by controlling the molybdenum content in the Vostian alloy steel to 2wt% to 6wt%, compared to Comparative Examples 1 to 3, and two conventional hot working alloys of AISI H13 and QRO 90, The Voss body alloy steel of the present invention not only maintains excellent room temperature strength and room temperature elongation, but also has a certain strength at high temperatures, showing that the Voss body alloy steel of the present invention has good ductility and can also be used as The new type of hot work alloy steel is used, and it can avoid the cracking of the manufactured hot work tool during use.

較佳地,該沃斯田體合金鋼的碳含量介於1.42wt%至1.5wt%,鉬含量介於3.5wt%至5wt%,該沃斯田體合金鋼的極限拉伸強度可達1353MPa至1386MPa,降伏強度可達1310MPa至1340MPa,硬度可達47至47.7。Preferably, the carbon content of the Vostian body alloy steel is between 1.42wt% and 1.5wt%, the molybdenum content is between 3.5wt% and 5wt%, and the ultimate tensile strength of the Vostian body alloy steel is up to 1353MPa To 1386MPa, the yield strength can reach 1310MPa to 1340MPa, and the hardness can reach 47 to 47.7.

更佳地,該沃斯田體合金鋼的碳含量介於1.42wt%至1.45wt%,鉬含量介於3.5wt%至4wt%,該沃斯田體合金鋼的伸長率可達25%。More preferably, the carbon content of the Vostian alloy steel is between 1.42wt% and 1.45wt%, the molybdenum content is between 3.5wt% and 4wt%, and the elongation of the Vostian alloy steel can reach 25%.

較佳地,該沃斯田體合金鋼的錳含量介於27.7wt%至30wt%,鋁含量介於8.2wt%至8.5wt%,該沃斯田體合金鋼的極限拉伸強度可達1280MPa至1386MPa,降伏強度可達1250MPa至1350MPa,硬度可達46.7至47.7,伸長率可達20%至32%。Preferably, the manganese content of the Vostian body alloy steel is between 27.7wt% and 30wt%, the aluminum content is between 8.2wt% and 8.5wt%, and the ultimate tensile strength of the Vostian body alloy steel can reach 1280MPa To 1386MPa, yield strength can reach 1250MPa to 1350MPa, hardness can reach 46.7 to 47.7, elongation can reach 20% to 32%.

較佳地,沃斯田體合金鋼的錳含量介於27wt%至29wt%,鋁含量介於8.0wt%至8.5wt%,且鉬含量介於3.0wt%至6wt%,該沃斯田體合金鋼的伸長率可大於20%、室溫極限拉伸強度可大於1280MPa,降伏強度可大於1230MPa,且於300℃的極限拉伸強度及降伏強度均可大於1000MPa。Preferably, the manganese content of the Vostian body alloy steel is between 27wt% and 29wt%, the aluminum content is between 8.0wt% and 8.5% by weight, and the molybdenum content is between 3.0wt% and 6wt%. The elongation of alloy steel can be greater than 20%, the ultimate tensile strength at room temperature can be greater than 1280MPa, the yield strength can be greater than 1230MPa, and the ultimate tensile strength and yield strength at 300℃ can be greater than 1000MPa.

較佳地,該沃斯田體合金鋼的鉬含量為3.0wt%,並含有3wt%的鉻或2wt%的鈷,該沃斯田體合金鋼於室溫的極限拉伸強度可達1280MPa至1344MPa,降伏強度可達1230MPa至1300MPa,硬度可達45至46.8,伸長率可達24%至37%。Preferably, the molybdenum content of the Vostian body alloy steel is 3.0 wt% and contains 3 wt% chromium or 2 wt% cobalt. The ultimate tensile strength of the Vostian body alloy steel at room temperature can reach 1280 MPa to 1344MPa, yield strength can reach 1230MPa to 1300MPa, hardness can reach 45 to 46.8, elongation can reach 24% to 37%.

此外,要說明的是,由表2的機械強度數據可知該具體例1至11的時效時間介於5至12小時對最終的機械強度並無顯著影響,顯示本發明藉由熱作處理溫度的控制,可有效避免粗大碳化物析出,因此,對時效處理的時間可具有較大的彈性,而並不會像習知鐵錳鋁碳鋼材時效時間越長,粗大碳化物析出現象越顯著而造成延展性下降的問題。In addition, it should be noted that the mechanical strength data in Table 2 shows that the aging time of the specific examples 1 to 11 between 5 and 12 hours has no significant effect on the final mechanical strength, showing that the present invention uses heat treatment temperature Control can effectively prevent the precipitation of coarse carbides. Therefore, the time for the aging treatment can be more flexible, and it will not cause the longer the aging time of the conventional iron-manganese-aluminum-carbon steel, the more obvious the appearance of coarse carbides. The problem of reduced ductility.

參閱圖2~圖4,圖2~圖4是該具體例1、3及8經過熱作處理後的光學顯微鏡照片,圖5~7則是該具體例1、3及8經過熱作處理及時效處理後的光學顯微鏡照片。由圖2~圖4可知,當利用將熱作溫度控制在1100℃~950℃時,經過熱作處理後也不易有粗大碳化物於晶界析出。因此,當進一步經過不同時效時間處理後,配合參閱圖5~7,亦不易產生粗大碳化物。然而,參閱圖8、9,圖8、9是該比較例1、2經過熱作處理後的光學顯微鏡照片,由圖8、9可知當強碳化物形成元素添加過量時,縱算控制熱作處理溫度,仍會析出大量的粗大碳化物,而不利於鐵錳鋁碳合金的延展性。Referring to FIGS. 2 to 4, FIGS. 2 to 4 are optical microscope photographs of the specific examples 1, 3, and 8 after hot working, and FIGS. 5 to 7 are the specific examples 1, 3, and 8 after hot working and Photograph of optical microscope after aging treatment. It can be seen from Figures 2 to 4 that when the hot working temperature is controlled at 1100°C to 950°C, coarse carbides are not likely to precipitate at the grain boundaries after the hot working treatment. Therefore, after further processing with different aging times, and referring to Figures 5-7, it is not easy to produce coarse carbides. However, referring to Figs. 8 and 9, which are optical micrographs of Comparative Examples 1 and 2 after hot working, it can be seen from Figs. 8 and 9 that when the excessive addition of strong carbide-forming elements, the hot working is controlled longitudinally The treatment temperature will still precipitate a large amount of coarse carbides, which is not conducive to the ductility of the iron-manganese-aluminum-carbon alloy.

此外,由前述表3的高溫拉伸強度結果可知,本發明製得的該鐵鋁錳碳沃斯田體合金鋼於300℃的降伏強度介於970MPa至1030MPa,極限拉伸強度達1022MPa至1070MPa,於500℃的降伏強度介於650MPa至700MPa,極限拉伸強度達719MPa至786MPa,於700℃的降伏強度介於410MPa至420MPa,極限拉伸強度達440MPa至449MPa。而比較例3雖於室溫時具有良好的延展性,然而於室溫及高溫(300℃、500℃)下的降伏強度及極限拉伸強度仍不及本發明,相較下,本發明該沃斯田體合金鋼不僅於室溫有良好的強度表現,於300℃及500℃時亦具有良好的機械強度,因此可作為新型的中低溫熱作合金鋼使用。In addition, from the high-temperature tensile strength results in Table 3 above, it can be seen that the yield strength of the iron-aluminum-manganese-carbon Vostian alloy steel produced by the present invention at 300°C is between 970 MPa and 1030 MPa, and the ultimate tensile strength is 1022 MPa to 1070 MPa The yield strength at 500°C is between 650MPa and 700MPa, the ultimate tensile strength is between 719MPa and 786MPa, the yield strength at 700°C is between 410MPa and 420MPa, and the ultimate tensile strength is between 440MPa and 449MPa. Although Comparative Example 3 has good ductility at room temperature, the yield strength and ultimate tensile strength at room temperature and high temperature (300°C, 500°C) are still inferior to the present invention. Starfield alloy steel not only has good strength performance at room temperature, but also has good mechanical strength at 300 ℃ and 500 ℃, so it can be used as a new medium and low temperature hot working alloy steel.

綜上所述,由先前技術的揭示,於習知碳含量低於1wt%的鐵錳鋁碳合金中添加含量較低的鉬、鎢等強碳化物形成元素(例如:Fe-29Mn-9Al-0.9C-0.6Mo、Fe-29Mn-9Al-0.9C-0.4Mo-0.6W等鐵錳鋁碳合金)可改善合金的延展性,然而並無法顯著提升合金強度,而於該低碳含量的鐵錳鋁碳合金中添加含量較多該等強碳化物形成元素(例如:Fe-27.9Mn-8.6Al-1.0C-0.51Mo-0.73W-0.55Nb鐵錳鋁碳合金),雖可增加合金的強度但卻無法維持良好的延展性。前述美國專利第9,528,177號亦揭示於高碳含量的鐵錳鋁碳合金中添加該等強碳化物形成元素並無法有效改善合金的延展性,因此並不建議於高碳含量的鐵錳鋁碳合金中添加該等強碳化物形成元素。然而,本發明沃斯田體合金鋼藉由控制高碳含量的鐵錳鋁碳合金組成中各元素的含量於特定範圍並配合特定的熱作處理溫度,使最終製得的該沃斯田體合金鋼於室溫時能同時具備優異的機械強度以及延展性,而於高溫時仍能維持適當的強度,且質輕而性能佳,可作為機械部件及熱作處理工具使用的鋼材,使本發明沃斯田體合金鋼除可作為一般鋼材使用外亦可作為熱作合金鋼使用,故確實可達成本發明之目的。In summary, according to the disclosure of the prior art, strong carbide-forming elements such as molybdenum and tungsten (eg Fe-29Mn-9Al- 0.9C-0.6Mo, Fe-29Mn-9Al-0.9C-0.4Mo-0.6W and other iron-manganese-aluminum-carbon alloys) can improve the ductility of the alloy, but it can not significantly improve the strength of the alloy, and the low-carbon iron The manganese aluminum carbon alloy contains more of these strong carbide forming elements (for example: Fe-27.9Mn-8.6Al-1.0C-0.51Mo-0.73W-0.55Nb iron manganese aluminum carbon alloy), although it can increase the alloy Strength but unable to maintain good ductility. The aforementioned US Patent No. 9,528,177 also discloses that adding these strong carbide forming elements to a high carbon content iron-manganese aluminum carbon alloy cannot effectively improve the ductility of the alloy, so it is not recommended for high carbon content iron-manganese aluminum carbon alloys Add these strong carbide forming elements. However, by controlling the content of each element in the composition of the high-carbon iron-manganese-aluminum-carbon alloy in a specific range and matching a specific heat treatment temperature, the Voss field alloy steel of the present invention makes the Voss body body finally obtained Alloy steel can have excellent mechanical strength and ductility at room temperature, while still maintaining proper strength at high temperature, and is lightweight and has good performance. It can be used as mechanical parts and steel for heat treatment tools. The invention of Vostian body alloy steel can be used not only as general steel but also as hot working alloy steel, so it can indeed achieve the purpose of cost invention.

惟以上所述者,僅為本發明之實施例而已,當不能以此限定本發明實施之範圍,凡是依本發明申請專利範圍及專利說明書內容所作之簡單的等效變化與修飾,皆仍屬本發明專利涵蓋之範圍內。However, the above are only examples of the present invention, and should not be used to limit the scope of the present invention. Any simple equivalent changes and modifications made according to the scope of the patent application of the present invention and the content of the patent specification are still classified as This invention covers the patent.

91~95‧‧‧步驟91~95‧‧‧Step

本發明之其他的特徵及功效,將於參照圖式的實施方式中清楚地呈現,其中: 圖1是本發明沃斯田體合金鋼的製作流程方塊圖; 圖2是本發明沃斯田體合金鋼的具體例1於熱作處理後的光學顯微鏡照片; 圖3是本發明沃斯田體合金鋼的具體例3於熱作處理後的光學顯微鏡照片; 圖4是本發明沃斯田體合金鋼的具體例8於熱作處理後的光學顯微鏡照片; 圖5是本發明沃斯田體合金鋼的具體例1於時效處理後的光學顯微鏡照片; 圖6是本發明沃斯田體合金鋼的具體例3於時效處理後的光學顯微鏡照片; 圖7是本發明沃斯田體合金鋼的具體例8於時效處理後的光學顯微鏡照片; 圖8是本發明沃斯田體合金鋼的比較例1於熱作處理後的光學顯微鏡照片;及 圖9是本發明沃斯田體合金鋼的比較例2於熱作處理後的光學顯微鏡照片。Other features and effects of the present invention will be clearly presented in the embodiment with reference to the drawings, in which: FIG. 1 is a block diagram of the manufacturing process of the Vossian alloy steel of the present invention; FIG. 2 is the Vossian body of the present invention Specific example 1 of alloy steel after hot working treatment; optical micrograph; Figure 3 is the photomicrograph of specific example 3 of Vostian body alloy steel of the present invention after hot working; Figure 4 is the photomicrograph of Vostian body of the present invention. Specific example 8 of alloy steel after hot work optical micrograph; FIG. 5 is specific example 1 of Vostian body alloy steel of the present invention after aging treatment; FIG. 6 is Vostian body alloy of the present invention Specific example 3 of steel after aging treatment optical micrograph; FIG. 7 is an optical microscope photo of specific example 8 of Vostian body alloy steel of the present invention after aging treatment; FIG. 8 is photograph of Vostian body alloy steel of the present invention Comparative Example 1 is an optical microscope photograph after hot working treatment; and FIG. 9 is an optical microscope photograph after comparatively hot working treatment of Comparative Example 2 of the present invention.

Claims (19)

一種沃斯田體合金鋼,包含25wt%至31wt%的錳、7wt%至10wt%的鋁、1.2wt%至1.6wt%的碳、大於0wt%且小於6wt%的鉬,以及平衡量的鐵。A Vostian body alloy steel, containing 25wt% to 31wt% manganese, 7wt% to 10wt% aluminum, 1.2wt% to 1.6wt% carbon, more than 0wt% and less than 6wt% molybdenum, and a balanced amount of iron . 如請求項1所述的沃斯田體合金鋼,其中,該錳的比例介於26wt%至30wt%,該鋁的比例介於8wt%至10wt%。The Vostian body alloy steel according to claim 1, wherein the proportion of the manganese is between 26wt% and 30wt%, and the proportion of the aluminum is between 8wt% and 10wt%. 如請求項2所述的沃斯田體合金鋼,其中,該錳的比例介於27wt%至29wt%,該鉬的比例介於2wt%至6wt%。The Vostian body alloy steel according to claim 2, wherein the proportion of manganese is between 27wt% and 29wt%, and the proportion of molybdenum is between 2wt% and 6wt%. 如請求項3所述的沃斯田體合金鋼,其中,該鋁的比例介於8wt%至9wt%。The Vostian body alloy steel according to claim 3, wherein the proportion of the aluminum is between 8 wt% and 9 wt%. 如請求項1所述的沃斯田體合金鋼,其中,該碳的比例為1.4wt%至1.6wt%。The Vostian alloy steel according to claim 1, wherein the ratio of the carbon is 1.4 wt% to 1.6 wt%. 如請求項1所述的沃斯田體合金鋼,其中,該鉬的比例介於2wt%至6wt%。The Vostian body alloy steel according to claim 1, wherein the proportion of the molybdenum is between 2wt% and 6wt%. 如請求項1所述的沃斯田體合金鋼,還包含比例小於6wt%的鉻。The field alloy steel according to claim 1 further contains chromium in a proportion of less than 6wt%. 如請求項1所述的沃斯田體合金鋼,還包含比例小於5wt%的鈷。The field alloy steel according to claim 1, further comprising cobalt in a proportion of less than 5 wt%. 如請求項1所述的沃斯田體合金鋼,其中,該沃斯田體合金鋼為完全沃斯田體相,且於25℃的伸長率介於20至40%、極限拉伸強度大於1250MPa,且於300℃的極限拉伸強度大於1000MPa。The Vostian body alloy steel according to claim 1, wherein the Vostian body alloy steel is a full Vostian body phase, and the elongation at 25°C is between 20 and 40%, and the ultimate tensile strength is greater than 1250MPa, and the ultimate tensile strength at 300℃ is greater than 1000MPa. 一種沃斯田體合金鋼的製作方法,包含: 步驟(a):將如請求項1所述的合金組成熔煉成鑄件; 步驟(b):於1100℃至950℃對該鑄件進行熱作處理而成為一熱作件; 步驟(c):將熱作處理後的該熱作件進行第一次水淬;及 步驟(d):將第一次水淬後的該熱作件於480℃至600℃進行時效處理。A method for manufacturing Vostian body alloy steel, comprising: Step (a): melting the alloy composition as described in claim 1 into a casting; Step (b): performing heat treatment on the casting at 1100°C to 950°C It becomes a hot work piece; Step (c): The first hot work piece after the hot work treatment is water quenched; and Step (d): The hot work piece after the first water quench is at 480 ℃ Aging treatment to 600℃. 如請求項10所述的沃斯田體合金鋼的製作方法,其中,該時效處理的溫度為時間為480℃至500℃時,該時效處理的時間為5至12小時,該時效處理的溫度大於500℃至600℃時,該時效處理的時間為1至4小時。The method of manufacturing a Vostian body alloy steel according to claim 10, wherein the temperature of the aging treatment is from 480°C to 500°C, the time of the aging treatment is from 5 to 12 hours, and the temperature of the aging treatment When it is greater than 500°C to 600°C, the aging treatment time is 1 to 4 hours. 如請求項10所述的沃斯田體合金鋼的製作方法,還包含一步驟(e),將經過時效處理的該鑄件進行第二次水淬。The manufacturing method of the Vostian body alloy steel according to claim 10, further comprising a step (e), the second water quenching of the aging-treated casting. 如請求項10所述的沃斯田體合金鋼的製作方法,其中,該步驟(b)是將該鑄件進行熱作處理至厚度至少小於該鑄件厚度的25%。The method for manufacturing a Vostian body alloy steel according to claim 10, wherein in step (b), the casting is hot-worked to a thickness of at least 25% of the thickness of the casting. 一種如請求項10所述的製作方法製得的沃斯田體合金鋼,該沃斯田體合金鋼於室溫的伸長率介於20至40%,且於300℃極限拉伸強度大於1000MPa。A Vostian body alloy steel produced by the manufacturing method as described in claim 10, which has an elongation at room temperature of 20 to 40% and an ultimate tensile strength greater than 1000 MPa at 300°C . 如請求項14所述的沃斯田體合金鋼,其中,該沃斯田體合金鋼於室溫的降伏強度介於1230至1350MPa,極限拉伸強度介於1280至1386MPa。The Vossian alloy steel according to claim 14, wherein the Vossian alloy steel has a yield strength at room temperature of 1230 to 1350 MPa and an ultimate tensile strength of 1280 to 1386 MPa. 如請求項14所述的沃斯田體合金鋼,其中,該沃斯田體合金鋼於室溫的洛氏硬度介於45至48。The Vossian alloy steel according to claim 14, wherein the Vossian alloy steel has a Rockwell hardness of 45 to 48 at room temperature. 如請求項14所述的沃斯田體合金鋼,其中,該沃斯田體合金鋼於300℃的降伏強度大於970MPa。The bulk alloy steel according to claim 14, wherein the bulk strength of the bulk alloy steel at 300°C is greater than 970 MPa. 如請求項14所述的沃斯田體合金鋼,其中,該沃斯田體合金鋼於500℃的降伏強度大於650MPa,極限拉伸強度大於700MPa。The Vossian alloy steel according to claim 14, wherein the Vossian alloy steel has a yield strength at 500° C. greater than 650 MPa and an ultimate tensile strength greater than 700 MPa. 如請求項14所述的沃斯田體合金鋼,其中,該沃斯田體合金鋼於700℃的降伏強度介於410至420MPa,極限拉伸強度介於440至449MPa。The Vossian alloy steel according to claim 14, wherein the Vossian alloy steel has a yield strength at 700°C of 410 to 420 MPa and an ultimate tensile strength of 440 to 449 MPa.
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Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB841366A (en) * 1957-07-02 1960-07-13 Langley Alloys Ltd Improvements in iron aluminium alloys
US4865662A (en) * 1987-04-02 1989-09-12 Ipsco Inc. Aluminum-manganese-iron stainless steel alloy
GB2220674A (en) * 1988-06-29 1990-01-17 Nat Science Council Alloys useful at elevated temperatures
US4975335A (en) * 1988-07-08 1990-12-04 Fancy Steel Corporation Fe-Mn-Al-C based alloy articles and parts and their treatments
US4875933A (en) * 1988-07-08 1989-10-24 Famcy Steel Corporation Melting method for producing low chromium corrosion resistant and high damping capacity Fe-Mn-Al-C based alloys
FR2634221A1 (en) * 1988-07-13 1990-01-19 Nat Science Council Cast articles made of alloys based on Fe-Mn-Al-Cr-Si-C
JPH02228450A (en) * 1989-03-02 1990-09-11 Tokushu Denkyoku Kk Casting alloy
US4944814A (en) * 1989-03-02 1990-07-31 Ipsco Enterprises, Inc. Aluminum-manganese-iron steel alloy
KR920702870A (en) * 1989-08-31 1992-10-28 죤 콤리 Aluminum-manganese-iron steel alloy
JPH0699775B2 (en) * 1991-12-27 1994-12-07 東大精密鋳造股▲フン▼有限公司 Precision casting method for iron-manganese-aluminum alloy
US5167733A (en) * 1992-02-06 1992-12-01 Eastern Precision Casting Co., Ltd. Method for manufacturing iron-manganese-aluminum alloy castings
JP4235077B2 (en) * 2003-06-05 2009-03-04 新日本製鐵株式会社 High strength low specific gravity steel plate for automobile and its manufacturing method
JP4179112B2 (en) * 2003-09-08 2008-11-12 ダイキン工業株式会社 Equipment management device, equipment management system, and equipment management method
JP5317048B2 (en) * 2008-06-10 2013-10-16 株式会社Neomaxマテリアル Resistance alloy manufacturing method
US7931758B2 (en) * 2008-07-28 2011-04-26 Ati Properties, Inc. Thermal mechanical treatment of ferrous alloys, and related alloys and articles
DE102011117135A1 (en) * 2010-11-26 2012-05-31 Salzgitter Flachstahl Gmbh Energy-saving container made of lightweight steel
DE102011000089A1 (en) * 2011-01-11 2012-07-12 Thyssenkrupp Steel Europe Ag Method for producing a hot rolled flat steel product
JP5177310B2 (en) * 2011-02-15 2013-04-03 Jfeスチール株式会社 High tensile strength steel sheet with excellent low temperature toughness of weld heat affected zone and method for producing the same
TWI445832B (en) * 2011-09-29 2014-07-21 The composition design and processing methods of high strength, high ductility, and high corrosion resistance alloys
WO2015099221A1 (en) * 2013-12-26 2015-07-02 주식회사 포스코 Steel sheet having high strength and low density and method of manufacturing same
US20170088910A1 (en) * 2015-09-29 2017-03-30 Exxonmobil Research And Engineering Company Corrosion and cracking resistant high manganese austenitic steels containing passivating elements
US20180274055A1 (en) * 2015-10-06 2018-09-27 Nippon Steel & Sumitomo Metal Corporation Austenitic stainless steel sheet
US10227681B2 (en) * 2015-10-21 2019-03-12 Caterpillar Inc. High manganese steel with enhanced wear and impact characteristics
WO2017203312A1 (en) * 2016-05-24 2017-11-30 Arcelormittal Cold rolled and annealed steel sheet, method of production thereof and use of such steel to produce vehicle parts
CN106244927B (en) * 2016-09-30 2018-04-03 北京理工大学 A kind of low-density unimach and preparation method thereof
KR101836714B1 (en) * 2016-10-12 2018-03-09 현대자동차주식회사 High manganese steel

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