TW201919571A - Composition for hair care - Google Patents
Composition for hair care Download PDFInfo
- Publication number
- TW201919571A TW201919571A TW107133071A TW107133071A TW201919571A TW 201919571 A TW201919571 A TW 201919571A TW 107133071 A TW107133071 A TW 107133071A TW 107133071 A TW107133071 A TW 107133071A TW 201919571 A TW201919571 A TW 201919571A
- Authority
- TW
- Taiwan
- Prior art keywords
- hair
- hair care
- surfactant
- care composition
- weight
- Prior art date
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- 210000004209 hair Anatomy 0.000 title claims abstract description 254
- 239000000203 mixture Substances 0.000 title claims abstract description 106
- 239000004094 surface-active agent Substances 0.000 claims abstract description 100
- 150000001413 amino acids Chemical class 0.000 claims abstract description 52
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 26
- 230000003752 improving hair Effects 0.000 claims abstract description 12
- -1 isostearyl glucoside Chemical class 0.000 claims description 28
- 229920006317 cationic polymer Polymers 0.000 claims description 9
- 230000002708 enhancing effect Effects 0.000 claims description 8
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 claims description 7
- 229930182478 glucoside Natural products 0.000 claims description 7
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 6
- 239000006210 lotion Substances 0.000 claims description 6
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 claims description 5
- 210000004761 scalp Anatomy 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000007921 spray Substances 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 3
- 229940073499 decyl glucoside Drugs 0.000 claims description 3
- 210000002966 serum Anatomy 0.000 claims description 3
- ORUDEUCNYHCHPB-OUUBHVDSSA-N (2r,3s,4s,5r,6r)-2-(hydroxymethyl)-6-tetradecoxyoxane-3,4,5-triol Chemical compound CCCCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O ORUDEUCNYHCHPB-OUUBHVDSSA-N 0.000 claims description 2
- 241000195940 Bryophyta Species 0.000 claims description 2
- JDRSMPFHFNXQRB-CMTNHCDUSA-N Decyl beta-D-threo-hexopyranoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)C(O)[C@H](O)C1O JDRSMPFHFNXQRB-CMTNHCDUSA-N 0.000 claims description 2
- WYUFTYLVLQZQNH-JAJWTYFOSA-N Ethyl beta-D-glucopyranoside Chemical compound CCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O WYUFTYLVLQZQNH-JAJWTYFOSA-N 0.000 claims description 2
- MLSJBGYKDYSOAE-DCWMUDTNSA-N L-Ascorbic acid-2-glucoside Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O[C@@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)=C1O MLSJBGYKDYSOAE-DCWMUDTNSA-N 0.000 claims description 2
- 229940067599 ascorbyl glucoside Drugs 0.000 claims description 2
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 claims description 2
- 229940080421 coco glucoside Drugs 0.000 claims description 2
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 claims description 2
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 claims description 2
- PYIDGJJWBIBVIA-UYTYNIKBSA-N lauryl glucoside Chemical compound CCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O PYIDGJJWBIBVIA-UYTYNIKBSA-N 0.000 claims description 2
- 229940048848 lauryl glucoside Drugs 0.000 claims description 2
- 235000011929 mousse Nutrition 0.000 claims description 2
- 235000016709 nutrition Nutrition 0.000 claims description 2
- 230000035764 nutrition Effects 0.000 claims description 2
- HEGSGKPQLMEBJL-RKQHYHRCSA-N octyl beta-D-glucopyranoside Chemical compound CCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O HEGSGKPQLMEBJL-RKQHYHRCSA-N 0.000 claims description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 230000008439 repair process Effects 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 229940024606 amino acid Drugs 0.000 claims 4
- 235000013923 monosodium glutamate Nutrition 0.000 claims 3
- 229940073490 sodium glutamate Drugs 0.000 claims 3
- JDRSMPFHFNXQRB-IWQYDBTJSA-N (3r,4s,5s,6r)-2-decoxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical group CCCCCCCCCCOC1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O JDRSMPFHFNXQRB-IWQYDBTJSA-N 0.000 claims 1
- NUSWKYLXVJRIQH-UHFFFAOYSA-N CNC.C(CCCCCCCCCCCCCCC(C)C)NCCC Chemical compound CNC.C(CCCCCCCCCCCCCCC(C)C)NCCC NUSWKYLXVJRIQH-UHFFFAOYSA-N 0.000 claims 1
- GRMLJBNJSBWLJC-UHFFFAOYSA-N CNC.C(CCCCCCCCCCCCCCCCC)N Chemical compound CNC.C(CCCCCCCCCCCCCCCCC)N GRMLJBNJSBWLJC-UHFFFAOYSA-N 0.000 claims 1
- 235000009917 Crataegus X brevipes Nutrition 0.000 claims 1
- 235000013204 Crataegus X haemacarpa Nutrition 0.000 claims 1
- 235000009685 Crataegus X maligna Nutrition 0.000 claims 1
- 235000009444 Crataegus X rubrocarnea Nutrition 0.000 claims 1
- 235000009486 Crataegus bullatus Nutrition 0.000 claims 1
- 235000017181 Crataegus chrysocarpa Nutrition 0.000 claims 1
- 235000009682 Crataegus limnophila Nutrition 0.000 claims 1
- 235000004423 Crataegus monogyna Nutrition 0.000 claims 1
- 240000000171 Crataegus monogyna Species 0.000 claims 1
- 235000002313 Crataegus paludosa Nutrition 0.000 claims 1
- 235000009840 Crataegus x incaedua Nutrition 0.000 claims 1
- ORAWFNKFUWGRJG-UHFFFAOYSA-N Docosanamide Chemical compound CCCCCCCCCCCCCCCCCCCCCC(N)=O ORAWFNKFUWGRJG-UHFFFAOYSA-N 0.000 claims 1
- BAVYZALUXZFZLV-UHFFFAOYSA-O Methylammonium ion Chemical compound [NH3+]C BAVYZALUXZFZLV-UHFFFAOYSA-O 0.000 claims 1
- VPPFGLQCFAENFZ-UHFFFAOYSA-N N-methyl-N-propylnonadecan-1-amine Chemical compound C(CCCCCCCCCCCCCCCCC)CN(C)CCC VPPFGLQCFAENFZ-UHFFFAOYSA-N 0.000 claims 1
- IIYMKVXMORHJHN-UHFFFAOYSA-N N-methyl-N-propylundecan-1-amine Chemical compound CCCCCCCCCCCN(C)CCC IIYMKVXMORHJHN-UHFFFAOYSA-N 0.000 claims 1
- SCRFBJSJENHELS-KOPOVESLSA-L N[C@@H](CCC(=O)[O-])C(=O)OCCCCCCCC.[Na+].[Na+].C(CCCCCCC)OC([C@@H](N)CCC(=O)[O-])=O Chemical compound N[C@@H](CCC(=O)[O-])C(=O)OCCCCCCCC.[Na+].[Na+].C(CCCCCCC)OC([C@@H](N)CCC(=O)[O-])=O SCRFBJSJENHELS-KOPOVESLSA-L 0.000 claims 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- YGEVMZLRIOFHSG-UHFFFAOYSA-L disodium dodecanoate Chemical compound [Na+].[Na+].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O YGEVMZLRIOFHSG-UHFFFAOYSA-L 0.000 claims 1
- MJEMIOXXNCZZFK-UHFFFAOYSA-N ethylone Chemical compound CCNC(C)C(=O)C1=CC=C2OCOC2=C1 MJEMIOXXNCZZFK-UHFFFAOYSA-N 0.000 claims 1
- URXQDXAVUYKSCK-UHFFFAOYSA-N hexadecyl(dimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[NH+](C)C URXQDXAVUYKSCK-UHFFFAOYSA-N 0.000 claims 1
- YBEFXFBAXWUBNQ-UHFFFAOYSA-N n-methylmethanamine;propan-1-amine Chemical compound CNC.CCCN YBEFXFBAXWUBNQ-UHFFFAOYSA-N 0.000 claims 1
- XHFGWHUWQXTGAT-UHFFFAOYSA-N n-methylpropan-2-amine Chemical compound CNC(C)C XHFGWHUWQXTGAT-UHFFFAOYSA-N 0.000 claims 1
- 239000002674 ointment Substances 0.000 claims 1
- 229940045845 sodium myristate Drugs 0.000 claims 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 claims 1
- JUQGWKYSEXPRGL-UHFFFAOYSA-M sodium;tetradecanoate Chemical compound [Na+].CCCCCCCCCCCCCC([O-])=O JUQGWKYSEXPRGL-UHFFFAOYSA-M 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 36
- 238000009472 formulation Methods 0.000 abstract description 3
- 235000001014 amino acid Nutrition 0.000 description 47
- 230000000052 comparative effect Effects 0.000 description 33
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 12
- 239000002552 dosage form Substances 0.000 description 11
- 230000001965 increasing effect Effects 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 230000003750 conditioning effect Effects 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 150000004665 fatty acids Chemical class 0.000 description 5
- 230000006870 function Effects 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- 125000005907 alkyl ester group Chemical group 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 230000003699 hair surface Effects 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 150000005215 alkyl ethers Chemical class 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000006071 cream Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 3
- 239000002453 shampoo Substances 0.000 description 3
- 210000000434 stratum corneum Anatomy 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 2
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- JSGVZVOGOQILFM-UHFFFAOYSA-N 3-methoxy-1-butanol Chemical compound COC(C)CCO JSGVZVOGOQILFM-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 2
- 229940063953 ammonium lauryl sulfate Drugs 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 229940075506 behentrimonium chloride Drugs 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- WQMJXFAFCDSZKC-UHFFFAOYSA-M bis(2-hexadecanoyloxyethyl)-(2-hydroxyethyl)-methylazanium;methyl sulfate Chemical compound COS([O-])(=O)=O.CCCCCCCCCCCCCCCC(=O)OCC[N+](C)(CCO)CCOC(=O)CCCCCCCCCCCCCCC WQMJXFAFCDSZKC-UHFFFAOYSA-M 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- JDRSMPFHFNXQRB-IBEHDNSVSA-N decyl glucoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O JDRSMPFHFNXQRB-IBEHDNSVSA-N 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 229940090933 dipalmitoylethyl hydroxyethylmonium methosulfate Drugs 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 150000008131 glucosides Chemical class 0.000 description 2
- 229930182470 glycoside Natural products 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 2
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 125000002801 octanoyl group Chemical group C(CCCCCCC)(=O)* 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000003002 pH adjusting agent Substances 0.000 description 2
- 229960005323 phenoxyethanol Drugs 0.000 description 2
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 2
- 229920001184 polypeptide Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 102000004196 processed proteins & peptides Human genes 0.000 description 2
- 108090000765 processed proteins & peptides Proteins 0.000 description 2
- 235000018102 proteins Nutrition 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229940079781 sodium cocoyl glutamate Drugs 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- 229940045898 sodium stearoyl glutamate Drugs 0.000 description 2
- KDHFCTLPQJQDQI-BDQAORGHSA-M sodium;(4s)-4-amino-5-octadecanoyloxy-5-oxopentanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC(=O)OC(=O)[C@@H](N)CCC([O-])=O KDHFCTLPQJQDQI-BDQAORGHSA-M 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004034 viscosity adjusting agent Substances 0.000 description 2
- 239000002888 zwitterionic surfactant Substances 0.000 description 2
- QEYATHUQKXAPIM-NRFANRHFSA-N (4s)-4-amino-5-octadecoxy-5-oxopentanoic acid Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)[C@@H](N)CCC(O)=O QEYATHUQKXAPIM-NRFANRHFSA-N 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- UCWYGNTYSWIDSW-QXMHVHEDSA-N (z)-n-[3-(dimethylamino)propyl]octadec-9-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)NCCCN(C)C UCWYGNTYSWIDSW-QXMHVHEDSA-N 0.000 description 1
- DWIUBTKCNCCGOO-QOYCNBSOSA-N (z,12r)-n-[3-(dimethylamino)propyl]-12-hydroxyoctadec-9-enamide Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(=O)NCCCN(C)C DWIUBTKCNCCGOO-QOYCNBSOSA-N 0.000 description 1
- ZWVMLYRJXORSEP-UHFFFAOYSA-N 1,2,6-Hexanetriol Chemical compound OCCCCC(O)CO ZWVMLYRJXORSEP-UHFFFAOYSA-N 0.000 description 1
- 229940015975 1,2-hexanediol Drugs 0.000 description 1
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- VNOUGORWQZQSHE-UHFFFAOYSA-N 1-(2-aminoimidazol-1-yl)-3-methoxypropan-2-ol Chemical compound COCC(O)CN1C=CN=C1N VNOUGORWQZQSHE-UHFFFAOYSA-N 0.000 description 1
- NCXUNZWLEYGQAH-UHFFFAOYSA-N 1-(dimethylamino)propan-2-ol Chemical compound CC(O)CN(C)C NCXUNZWLEYGQAH-UHFFFAOYSA-N 0.000 description 1
- BSLCSFCXSUCFQN-UHFFFAOYSA-N 1-aminobutane-2,3-diol Chemical compound CC(O)C(O)CN BSLCSFCXSUCFQN-UHFFFAOYSA-N 0.000 description 1
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- UZUMQQZPGOFJBQ-UHFFFAOYSA-N 1-aminopropane-1,2-diol Chemical compound CC(O)C(N)O UZUMQQZPGOFJBQ-UHFFFAOYSA-N 0.000 description 1
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 1
- IBLKWZIFZMJLFL-UHFFFAOYSA-N 1-phenoxypropan-2-ol Chemical compound CC(O)COC1=CC=CC=C1 IBLKWZIFZMJLFL-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- LJDSTRZHPWMDPG-UHFFFAOYSA-N 2-(butylamino)ethanol Chemical compound CCCCNCCO LJDSTRZHPWMDPG-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/602—Glycosides, e.g. rutin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
Description
本申請案主張基於2017年9月22日申請的韓國專利申請案第10-2017-0122260號及2018年9月6日申請的韓國專利申請案第10-2018-0106345號的優先權的利益，本說明書將上述韓國專利申請案的文獻中所揭示的所有內容包括作一部分。The present application claims the benefit of priority based on the Korean Patent Application No. 10-2017-0122260, filed on Sep. 22, 2017, and the Korean Patent Application No. 10-2018-0106345, filed on Sep. 6, s. The present specification includes all of the contents disclosed in the above-mentioned Korean Patent Application.
本發明是有關於一種改善毛髮糾結，表現出提高彈力及蓬鬆感的效果的毛髮護理用組成物，更具體而言，有關於一種包括陽離子界面活性劑、糖界面活性劑及胺基酸界面活性劑的毛髮護理用組成物。The present invention relates to a hair care composition for improving hair entanglement and exhibiting an effect of improving elasticity and fluffiness, and more particularly to a surfactant comprising a cationic surfactant, a sugar surfactant and an amino acid. A hair care composition for the agent.
通常，人的毛髮包括角質層（cuticle layer）、皮質層（cortex）及髓質層（medulla）3個層。角質層作為存在於最外面的層，包圍皮質層而發揮保護上述皮質層的作用，未受損的健康毛髮的角質層表面光滑，發揮使光折射且減少毛髮之間的摩擦力的作用。Generally, human hair includes three layers of a cuticle layer, a cortex, and a medulla. The stratum corneum acts as the outermost layer and surrounds the cortex layer to protect the cortex layer. The surface of the stratum corneum of the undamaged healthy hair is smooth, and functions to refract light and reduce the friction between the hairs.
毛髮容易受到外部環境的影響，具體而言，會因寒冷且乾燥的風、室內供暖設備、過度的梳理、壓力、營養不良及睡眠不足等原因而受到損傷。另外，最近現代人將毛髮視為一種時尚而頻繁地進行染髮、燙髮、脫色等毛髮處理、過度地使用毛髮美容製品、或長時間使用吹風機的情形增加，因此毛髮頻繁受損。The hair is easily affected by the external environment, and specifically, it is damaged by cold and dry wind, indoor heating equipment, excessive combing, stress, malnutrition, and lack of sleep. In addition, recently, modern people have regarded hair as a fashion and frequent hair treatment such as hair dyeing, perming, discoloration, excessive use of hair cosmetic products, or long-term use of a hair dryer, and thus hair is frequently damaged.
於毛髮因各種物理、化學或環境因素而受損的情形時，毛髮表面的角質層受損，因此毛髮內部的水分、蛋白質及脂質溶出而毛髮變粗糙，失去光澤且摩擦力增加，從而產生容易糾結、折斷或髮梢分叉的現象。另外，由於失去彈力，亦產生毛髮軟榻、蓬鬆感消失且毛髮變細的問題，於嚴重時，毛髮產生斷裂及牽引性脫髮現象。When the hair is damaged by various physical, chemical or environmental factors, the stratum corneum of the hair surface is damaged, so the moisture, protein and lipid inside the hair are dissolved and the hair is roughened, the gloss is lost and the friction is increased, which makes it easy to produce Tangle, break, or split ends. In addition, due to the loss of the elastic force, the hair soft sleeper, the fluffy sensation disappears, and the hair becomes thinner. In severe cases, the hair is broken and pulled off.
因此，隨著消費者對可保持毛髮的健康狀態的調整（Conditioning）製品的需求及喜愛日益增加，持續對此種製品進行研究。Therefore, as the consumer's demand for and enjoyment of Conditioning products that can maintain the health of the hair is increasing, research on such products continues.
現有的調整製品包括陽離子界面活性劑及矽酮，藉此改善毛髮狀態。然而，存在如下問題：即便護理毛髮表面來提高毛髮狀態，因集中至表面的劑型特徵而毛髮的吸收及塗抹感亦較差，從而無法實現適當的護理，於對毛髮賦予彈力及蓬鬆感的方面有限而毛髮軟塌。Existing conditioning articles include cationic surfactants and anthrone, thereby improving hair condition. However, there is a problem in that even if the hair surface is treated to improve the hair state, the absorption and application feeling of the hair is poor due to the dosage form characteristics concentrated on the surface, so that proper care cannot be achieved, and the elastic and fluffy feeling is imparted to the hair. The hair is soft and collapsed.
於韓國註冊專利第10-1351473號中，為了全面提高使用時的按摩感、沖洗時的觸感、濕潤狀態下的柔順感、乾燥狀態下的柔順感，開發新穎的銨鹽化合物而與陽離子界面活性劑一併添加。然而，其效果未達到預期，且完全未對提高毛髮的彈力及蓬鬆感的效果進行記載。In order to comprehensively improve the massage feeling during use, the touch feeling during washing, the softness in a wet state, and the softness in a dry state, a novel ammonium salt compound and a cation interface have been developed. The active agents are added together. However, the effect was not as expected, and the effect of improving the elasticity and bulkiness of the hair was not described at all.
[先前技術文獻] [專利文獻] 韓國註冊專利第10-1351473號[Previous Technical Literature] [Patent Literature] Korean Registered Patent No. 10-1351473
[發明欲解決的課題][Question to be solved by the invention]
因此，本發明者等人為了解決上述問題而多角度地進行研究，結果確認到如下情形：於在毛髮護理用組成物中包括陽離子界面活性劑、糖界面活性劑及胺基酸界面活性劑的情形時，改善毛髮的糾結，從而不僅毛髮調整效果優異，而且提高彈力及蓬鬆感的效果優異。Therefore, the present inventors have conducted research from various angles in order to solve the above problems, and as a result, it has been confirmed that a cationic surfactant, a sugar surfactant, and an amino acid surfactant are included in the hair care composition. In the case of the hair, the hair is entangled, so that the hair conditioning effect is excellent, and the effect of improving the elasticity and the bulkiness is excellent.
因此，本發明的目的在於提供一種具有提高毛髮的狀態、彈力及蓬鬆感的效果的毛髮護理用組成物。Accordingly, an object of the present invention is to provide a hair care composition having an effect of improving the state of hair, elasticity, and bulkiness.
[解決課題的手段][Means for solving the problem]
為了達成上述目的，本發明提供一種毛髮護理用組成物，其包括陽離子界面活性劑、糖界面活性劑及胺基酸界面活性劑。In order to achieve the above object, the present invention provides a hair care composition comprising a cationic surfactant, a sugar surfactant, and an amino acid surfactant.
[發明效果][Effect of the invention]
本發明的毛髮護理用組成物提供如下效果：改善毛髮的糾結，提高毛髮的狀態且提高毛髮的彈力及蓬鬆感。The hair care composition of the present invention provides an effect of improving the entanglement of the hair, improving the state of the hair, and improving the elasticity and bulkiness of the hair.
以下，更詳細地對本發明進行說明。Hereinafter, the present invention will be described in more detail.
本發明是有關於一種毛髮護理用組成物，其包括陽離子界面活性劑、糖界面活性劑及胺基酸界面活性劑。The present invention is directed to a hair care composition comprising a cationic surfactant, a sugar surfactant, and an amino acid surfactant.
與通常主要使用陰離子界面活性劑的毛髮清潔劑不同，毛髮護理用組成物使用陽離子界面活性劑。與正常的毛髮不同，受損的毛髮因毛髮表面的脂肪酸（fatty acid）損耗而表現出陰離子性，因此使用上述陽離子界面活性劑來與毛髮內部形成離子鍵而填充毛髮的受損部位，藉此可護理受損的毛髮。Unlike hair cleansers, which typically use anionic surfactants, the hair care compositions use cationic surfactants. Unlike normal hair, damaged hair exhibits anionic properties due to the loss of fatty acid on the surface of the hair. Therefore, the above-mentioned cationic surfactant is used to form an ionic bond with the inside of the hair to fill the damaged portion of the hair. It can care for damaged hair.
然而，若僅使用陽離子界面活性劑，則存在如下問題：雖具有毛髮調整效果，但無法表現出提高毛髮的彈力及蓬鬆感的效果。However, when only a cationic surfactant is used, there is a problem in that although it has a hair conditioning effect, it does not exhibit an effect of improving the elasticity and bulkiness of the hair.
因此，本發明提供一種毛髮護理用組成物，其不僅具有毛髮調整效果，而且可表現出提高彈力及蓬鬆感的效果。Accordingly, the present invention provides a hair care composition which not only has a hair conditioning effect but also exhibits an effect of improving elasticity and bulkiness.
具體而言，本發明的毛髮護理用組成物包括陽離子界面活性劑、糖界面活性劑及胺基酸界面活性劑。Specifically, the hair care composition of the present invention comprises a cationic surfactant, a sugar surfactant, and an amino acid surfactant.
上述陽離子界面活性劑發揮如下作用：與表現出陰離子的受損毛髮形成離子鍵而填充毛髮的受損部位，藉此護理受損的毛髮。The above cationic surfactant functions to fill the damaged portion of the hair by forming an ionic bond with the damaged hair exhibiting an anion, thereby caring for the damaged hair.
上述陽離子界面活性劑為三級銨或四級銨，具體而言，可包括選自由硬脂醯胺丙基二甲基胺（stearamidopropyl dimethylamine）、山崳基三甲基氯化銨（behentrimonium chloride）、山崳基三甲基硫酸甲酯銨（behentrimonium methosulfate）、山崳基三甲基氯化銨（behenyltrimethylammonium chloride）、鯨蠟基三甲基氯化銨（cetyltrimethylammonium chloride）、硬脂基三甲基氯化銨（stearyltrimethylammonium chloride）、二硬脂基二甲基氯化銨（distearyl dimethylammonium chloride）、二鯨蠟基二甲基氯化銨（dicetyldimethylammonium chloride）、椰油醯胺丙基二甲胺（cocamidopropyldimethylamine）、硬脂醯胺丙基二甲胺（stearamidopropyldimethylamine）、山崳醯胺丙基二甲基胺（behenylamidopropyldimethylamine）、油醯胺丙基二甲胺（oleamidopropyl dimethylamine）、異硬脂醯胺丙基二甲胺（isostearamidopropyl dimethylamine）、棕櫚醯胺丙基三甲基氯化銨（palmitamidopropyltrimonium chloride）、蓖麻醇酸醯胺丙基二甲基胺（ricinoleamidopropyl dimethylamine）及二棕櫚醯基乙基羥乙基甲基硫酸甲酯銨（dipalmitoylethyl hydroxyethylmonium methosulfate）所組成的族群中的一種以上，較佳為可包括選自由硬脂醯胺丙基二甲基胺（stearamidopropyl dimethylamine）、山崳基三甲基氯化銨（behentrimonium chloride）、山崳基三甲基硫酸甲酯銨（behentrimonium methosulfate）及二棕櫚醯基乙基羥乙基甲基硫酸甲酯銨（dipalmitoylethyl hydroxyethylmonium methosulfate）所組成的族群中的一種以上。The above cationic surfactant is a tertiary ammonium or a quaternary ammonium, and specifically, may be selected from the group consisting of stearramidopropyl dimethylamine and behentrimonium chloride. , behentrimonium methosulfate, behenyltrimethylammonium chloride, cetyltrimethylammonium chloride, stearyl trimethyl Stearyltrimethylammonium chloride, distearyl dimethylammonium chloride, diceteldimethylammonium chloride, cocamidopropyldimethylamine ), stearramidopropyldimethylamine, behenylamidopropyldimethylamine, oleamidopropyl dimethylamine, isostearyl propylamine Misoamine (isostearamidopropyl dimethylamine), palmitosylpropyltrimethyl chloride One of a group consisting of ammonium (palmitamidopropyltrimonium chloride), ricinoleamidopropyl dimethylamine, and dipalmitoylethyl hydroxyethylmonium methosulfate The above may preferably include a selected from the group consisting of stearramidopropyl dimethylamine, behentrimonium chloride, and behenyltrimonium trimethylammonium sulfate (behentrimonium). One or more of the group consisting of methosulfate) and dipalmitoylethyl hydroxyethylmonium methosulfate.
另外，相對於毛髮護理用組成物的總重量，包括1重量%至10重量%、較佳為1重量%至5重量%的上述陽離子界面活性劑。Further, the above cationic surfactant is included in an amount of from 1% by weight to 10% by weight, preferably from 1% by weight to 5% by weight based on the total mass of the hair care composition.
若如上所述般包括1重量%至10重量%的上述陽離子界面活性劑，則可提高毛髮調整效果，特別是，可改善毛髮的糾結，均勻地護理毛髮表面而減少毛髮表面的摩擦力，從而提高毛髮的柔順感。If 1% by weight to 10% by weight of the above cationic surfactant is included as described above, the hair conditioning effect can be improved, in particular, the entanglement of the hair can be improved, the hair surface can be uniformly treated to reduce the frictional force of the hair surface, thereby Improves the suppleness of the hair.
於本發明中，“調整效果”是指修復受損的毛髮或防止健康的毛髮受損，具體而言，其是指對毛髮賦予柔順感、水潤感、光滑感等而保持健康的毛髮狀態。In the present invention, "adjusting effect" means repairing damaged hair or preventing damage to healthy hair, and specifically, it means imparting a feeling of suppleness, moisturization, smoothness, etc. to the hair while maintaining a healthy hair state. .
上述糖界面活性劑發揮如下作用：以糖塗覆毛髮表面而提高毛髮的彈力及蓬鬆感，改善毛髮的糾結而提高柔順感。The above-mentioned sugar surfactant acts to coat the surface of the hair with sugar to improve the elasticity and bulkiness of the hair, improve the entanglement of the hair, and improve the suppleness.
上述糖界面活性劑可包括選自由辛基/癸基葡萄糖苷（caprylyl/Capryl glucoside）、月桂基葡萄糖苷（lauryl glucoside）、異硬脂基葡萄糖苷（isostearyl glucoside）、乙基葡萄糖苷（ethyl glucoside）、椰油基葡萄糖苷（coco-glucoside）、辛基葡萄糖苷（caprylyl glucoside）、肉豆蔻基葡萄糖苷（myristyl glucoside）、抗壞血酸葡萄糖苷（ascorbyl glucoside）、鯨蠟硬脂基葡萄糖苷（cetearyl glucoside）、癸基葡萄糖苷（decyl glucoside）及甘油基葡萄糖苷（glyceryl glucoside）所組成的族群中的一種以上，較佳為可包括選自由辛基/癸基葡萄糖苷（caprylyl/Capryl glucoside）及鯨蠟硬脂基葡萄糖苷（cetearyl glucoside）所組成的族群中的一種以上。The above sugar surfactant may include one selected from the group consisting of caprylyl/capryl glucoside, lauryl glucoside, isostearyl glucoside, and ethyl glucoside. ), coco-glucoside, caprylyl glucoside, myristyl glucoside, ascorbyl glucoside, cetearyl glucoside And one or more of the group consisting of decyl glucoside and glyceryl glucoside, preferably including a group selected from the group consisting of caprylyl/capryl glucoside and whale One or more of the groups consisting of cetearyl glucoside.
另外，相對於毛髮護理用組成物的總重量，包括0.5重量%至5重量%、較佳為0.5重量%至3重量%的上述糖界面活性劑。Further, the above-mentioned sugar surfactant is included in an amount of 0.5% by weight to 5% by weight, preferably 0.5% by weight to 3% by weight based on the total mass of the hair care composition.
若如上所述般包括0.5重量%至5重量%的上述糖界面活性劑，則毛髮表面由糖塗覆而可獲得提高毛髮的彈力及蓬鬆感且改善糾結而使毛髮柔順的效果。然而，若糖界面活性劑超過5重量%，則毛髮表面由糖過度塗覆而產生毛髮僵硬的現象，從而無法獲得改善毛髮的彈力、蓬鬆感及糾結的效果。If 0.5% by weight to 5% by weight of the above-mentioned sugar surfactant is included as described above, the surface of the hair is coated with sugar to obtain an effect of improving the elasticity and bulkiness of the hair and improving the entanglement to make the hair smooth. However, if the sugar surfactant exceeds 5% by weight, the surface of the hair is excessively coated with sugar to cause hair stiffness, and the effect of improving the elasticity, fluffiness and entanglement of the hair cannot be obtained.
上述胺基酸界面活性劑作為陰離子界面活性劑，發揮如下作用：與上述陽離子界面活性劑形成陽離子/陰離子複合結構而使毛髮表面變柔順，改善髮絲間的糾結而提高毛髮的蓬鬆感。The above-mentioned amino acid-based surfactant acts as an anionic surfactant to form a cationic/anionic composite structure with the above-mentioned cationic surfactant to make the surface of the hair soft, improve the entanglement between the hairs, and improve the bulkiness of the hair.
上述胺基酸界面活性劑可包括選自由硬脂醯麩胺酸鈉（sodium stearoyl glutamate）、椰油醯麩胺酸鈉（sodium cocoyl glutamate）、月桂醯麩胺酸鈉（sodium lauroyl glutamate）、肉豆蔻醯麩胺酸鈉（sodium myristoyl glutamate）、椰油醯麩胺酸二鈉（disodium cocoyl glutamate）、月桂醯麩胺酸二鈉（disodium lauroyl glutamate）、硬脂醯麩胺酸二鈉（disodium stearoyl glutamate）及辛醯麩胺酸二鈉（disodium capryloyl glutamate）所組成的族群中的一種以上，較佳為可包括選自由硬脂醯麩胺酸鈉（sodium stearoyl glutamate）及椰油醯麩胺酸鈉（sodium cocoyl glutamate）所組成的族群中的一種以上。The above amino acid surfactant may include a salt selected from the group consisting of sodium stearoyl glutamate, sodium cocoyl glutamate, sodium lauroyl glutamate, meat. Sodium myristoyl glutamate, disodium cocoyl glutamate, disodium lauroyl glutamate, disodium stearoyl More than one of the group consisting of glutamate) and disodium capryloyl glutamate, preferably may be selected from the group consisting of sodium stearoyl glutamate and coco glutamic acid. More than one of the groups consisting of sodium cocoyl glutamate.
另外，相對於毛髮護理用組成物的總重量，包括0.1重量%至1重量%、較佳為0.1重量%至0.5重量%的上述胺基酸界面活性劑。Further, the above amino acid surfactant is included in an amount of 0.1% by weight to 1% by weight, preferably 0.1% by weight to 0.5% by weight based on the total mass of the hair care composition.
若如上所述般包括0.1重量%至1重量%的上述胺基酸界面活性劑，則可獲得改善毛髮的糾結而提高柔順感及蓬鬆感的效果。另外，若胺基酸界面活性劑超過1重量%，則劑型穩定性的危險度增加，因此欠佳。If 0.1% by weight to 1% by weight of the above-mentioned amino acid surfactant is included as described above, an effect of improving the entanglement of the hair and improving the feeling of softness and bulkiness can be obtained. Further, if the amino acid surfactant exceeds 1% by weight, the risk of stability of the dosage form increases, which is not preferable.
於本發明中，相對於毛髮護理用組成物的總重量，可包括1重量%至10重量%的陽離子界面活性劑、0.5重量%至5重量%的糖界面活性劑、及0.1重量%至1重量%的胺基酸界面活性劑，較佳為可包括1重量%至5重量%的陽離子界面活性劑、0.5重量%至3重量%的糖界面活性劑、及0.1重量%至0.5重量%的胺基酸界面活性劑。In the present invention, 1% by weight to 10% by weight of the cationic surfactant, 0.5% by weight to 5% by weight of the sugar surfactant, and 0.1% by weight to 1 may be included with respect to the total weight of the hair care composition. The wt% amino acid surfactant preferably comprises from 1% to 5% by weight of a cationic surfactant, from 0.5% to 3% by weight of a sugar surfactant, and from 0.1% to 0.5% by weight. Amino acid surfactant.
然而，於脫離上述範圍的情形時，毛髮護理用組成物的劑型穩定性不良而亦會難以劑型化。However, when it is out of the above range, the formulation of the hair care composition is poor in stability and it is difficult to form a formulation.
於本發明中，較佳為以10:1至1:1的重量比混合上述糖界面活性劑與胺基酸界面活性劑，更佳為以5:1至2:1重量比混合。In the present invention, it is preferred to mix the above sugar surfactant and the amino acid surfactant in a weight ratio of 10:1 to 1:1, more preferably in a weight ratio of 5:1 to 2:1.
若以10:1至1:1的重量比混合上述糖界面活性劑與胺基酸界面活性劑，則整個毛髮的毛髮護理用組成物吸收力及塗抹力增強，從而可改善毛髮糾結而提高毛髮的柔順感、彈力及蓬鬆感，於以5:1至2:1進行混合的情形時，可將上述效果極大化。If the above-mentioned sugar surfactant and amino acid surfactant are mixed in a weight ratio of 10:1 to 1:1, the hair care composition of the entire hair is enhanced in absorbency and application power, thereby improving hair tangling and improving hair. The suppleness, elasticity and fluffiness can be maximized when mixing from 5:1 to 2:1.
另外，本發明的毛髮護理用組成物可更包括陽離子聚合物。藉由包括上述陽離子聚合物，可獲得持續調整毛髮的效果，可進一步增大提高蓬鬆感的效果。Further, the hair care composition of the present invention may further comprise a cationic polymer. By including the above cationic polymer, the effect of continuously adjusting the hair can be obtained, and the effect of improving the feeling of bulk can be further increased.
上述陽離子聚合物可包括選自由聚四級銨-10（polyquaternium-10）、聚四級銨-11（polyquaternium-11）、聚四級銨-37（polyquaternium-37）、聚四級銨-51（polyquaternium-51）及聚四級銨-55（polyquaternium-55）所組成的族群的一種以上，較佳為可包括聚四級銨-55（polyquaternium-55）。上述聚四級銨-55（polyquaternium-55）具有疏水性鏈的長度較長的結構，因此可支持毛髮表面且堅固地包覆毛髮，故而最佳。The above cationic polymer may include a compound selected from the group consisting of polyquaternium-10, polyquaternium-11, polyquaternium-37, and polyquaternium-51. More than one group consisting of polyquaternium-51 and polyquaternium-55 may preferably include polyquaternium-55. The above polyquaternium-55 (polyquaternium-55) has a structure having a long length of a hydrophobic chain, and thus is excellent in supporting the surface of the hair and firmly covering the hair.
相對於毛髮護理用組成物的總重量，包括0.01重量%至5重量%、較佳為0.05重量%至1重量%的上述陽離子聚合物。The above cationic polymer is included in an amount of from 0.01% by weight to 5% by weight, preferably from 0.05% by weight to 1% by weight, based on the total weight of the hair care composition.
若如上所述般包括0.01重量%至5重量%的上述陽離子聚合物，則可獲得持續調整毛髮的效果及提高蓬鬆感的效果，因此較佳。If 0.01% by weight to 5% by weight of the above cationic polymer is included as described above, an effect of continuously adjusting the hair and an effect of improving the bulkiness can be obtained, which is preferable.
除上述成分以外，本發明的毛髮護理用組成物可更包括毛髮強化成分。上述毛髮強化成分作為作用於毛髮的外部而可增大毛髮的粗度或填充受損部位的物質，例如可為選自由來自動物、植物及礦物等天然物的提取物、胺基酸、多肽、蛋白質、聚合物化合物、矽化合物、脂肪醇、脂肪酸、蠟及酯類化合物所組成的族群中的一種以上。In addition to the above ingredients, the hair care composition of the present invention may further comprise a hair strengthening component. The hair-enhancing component may be a substance which acts on the outside of the hair to increase the thickness of the hair or fill the damaged part, and may be, for example, an extract selected from natural products such as animals, plants, and minerals, amino acids, polypeptides, and the like. One or more of a group consisting of a protein, a polymer compound, a hydrazine compound, a fatty alcohol, a fatty acid, a wax, and an ester compound.
另外，除上述成分以外，本發明的毛髮護理用組成物可包括本技術領域內的專家所熟知的用以保持基本物性及品質的通常的任意成分，例如，可更含有起泡劑、清潔劑、珠光劑、防腐劑、增黏劑、黏度調節劑、pH值調節劑、螯合劑、油、香料等，作為溶劑，可含有去離子水、有機溶劑等。Further, in addition to the above components, the hair care composition of the present invention may include a usual optional component known in the art to maintain basic physical properties and quality, for example, may further contain a foaming agent and a detergent. A pearlizing agent, a preservative, a tackifier, a viscosity modifier, a pH adjuster, a chelating agent, an oil, a perfume, etc., as a solvent, may contain deionized water, an organic solvent, or the like.
作為上述起泡劑及清潔劑，可包括陰離子界面活性劑、兩性（zwitter）離子界面活性劑或兩性界面活性劑、非離子界面活性劑或其組合物。As the above-mentioned foaming agent and detergent, an anionic surfactant, a zwitter ionic surfactant or an amphoteric surfactant, a nonionic surfactant or a combination thereof may be included.
作為上述陰離子界面活性劑，可自由烷基硫酸鹽類、烷基磺酸鹽類、烷基羧酸鹽類、烷基醚硫酸鹽類、烷基羥乙基磺酸鹽類、烷基牛磺酸鹽類、烷基磺基琥珀酸鹽類、烷基磺基乙酸鹽類、烷基磷酸鹽類、陰離子胺基酸衍生物、陰離子多肽衍生物、烷基聚葡萄糖苷的陰離子衍生物、脂肪酸皂及其混合物所組成的族群中選擇使用，其中，作為烷基硫酸鹽類，可使用月桂基硫酸銨（Ammonium Lauryl Sulfate，ALS）、月桂基乙基硫酸銨（Ammonium Laurylethyl sulfate，ALES）、月桂基硫酸鈉（Sodium Lauryl Sulfate，SLS）及月桂基乙基硫酸鈉（Sodium Laurylethyl Sulfate，SLES）等。As the above anionic surfactant, free alkyl sulfates, alkyl sulfonates, alkyl carboxylates, alkyl ether sulfates, alkyl isethionates, alkyl sulphonates Acid salts, alkyl sulfosuccinates, alkyl sulfoacetates, alkyl phosphates, anionic amino acid derivatives, anionic polypeptide derivatives, anionic derivatives of alkyl polyglucosides, fatty acids A mixture of soaps and mixtures thereof is used, and as the alkyl sulfates, Ammonium Lauryl Sulfate (ALS), Ammonium Laurylethyl sulfate (ALES), and Laurel may be used. Sodium Lauryl Sulfate (SLS) and sodium laurylethyl sulfate (SLES).
上述兩性離子界面活性劑或兩性界面活性劑並無限制，可使用(C8-C20)烷基甜菜鹼、N-(C8-C20)烷基醯胺甜菜鹼及其衍生物、甘胺酸衍生物、磺基甜菜鹼及其衍生物、(C8-C20)烷基聚胺基羧酸鹽、(C8-C20)烷基兩性基乙酸鹽、月桂醯基乙酸鈉及其混合物，較佳為可選自氧化胺、椰油基兩性基羧基甘胺酸鹽、椰油醯胺基丙基甜菜鹼及其混合物所組成的族群。The above zwitterionic surfactant or amphoteric surfactant is not limited, and (C8-C20) alkyl betaines, N-(C8-C20) alkylguanamine betaines and derivatives thereof, glycine derivatives can be used. , sulfobetaine and its derivatives, (C8-C20) alkyl polyamino carboxylate, (C8-C20) alkyl amphoacetate, sodium lauryl acetate and mixtures thereof, preferably optional A group consisting of an amine oxide, a cocoyl amphotery carboxyglycinate, cocoamidopropyl betaine, and mixtures thereof.
上述非離子界面活性劑可選自聚(環氧乙烷)與聚(環氧丙烷)的嵌段共聚物、聚(環氧乙烷)的烷基酯及聚烷基酯、氧伸烷基二醇、聚(環氧乙烷)的烷基醚及聚烷基醚、山梨醇酐經聚氧乙烯化而成的烷基酯及聚烷基酯、山梨醇酐經聚氧乙烯化而成的烷基醚及聚烷基醚、烷基糖苷及聚烷基糖苷或多糖苷、蔗糖的烷基酯及聚烷基酯、甘油經聚氧乙烯化而成的烷基酯及聚烷基酯、甘油經聚氧乙烯化而成的烷基醚及聚烷基醚、雙子界面活性劑、烷基醇類及其混合物。The above nonionic surfactant may be selected from the group consisting of block copolymers of poly(ethylene oxide) and poly(propylene oxide), alkyl esters of poly(ethylene oxide), polyalkyl esters, and oxygen alkyl groups. a diol, a poly(ethylene oxide) alkyl ether and a polyalkyl ether, a polyoxyethylated alkyl ester of sorbitan, a polyalkyl ester, and a sorbitan by polyoxyethylene Alkyl ethers and polyalkyl ethers, alkyl glycosides and polyalkyl glycosides or polyglycosides, alkyl esters and polyalkyl esters of sucrose, polyoxyethylated alkyl esters and polyalkyl esters of glycerol And alkyl ethers and polyalkyl ethers obtained by polyoxyethylation of glycerin, gemini surfactants, alkyl alcohols and mixtures thereof.
作為上述珠光劑，可使用二硬脂酸乙二醇酯、單硬脂酸乙二醇酯、脂肪酸等。As the pearlescent agent, ethylene glycol distearate, ethylene glycol monostearate, a fatty acid or the like can be used.
上述防腐劑包括對位甲基苯（methyl p-hydroxybenzoate）、對羥基苯甲酸甲酯（methylparaben）、對羥基苯甲酸丁酯、對羥基苯甲酸乙酯、對羥基苯甲酸丙酯、苄醇、苯氧基乙醇、苯氧基異丙醇、苯基丙醇、甲基氯異噻唑啉酮及甲基異噻唑啉酮的混合物。The above preservatives include methyl p-hydroxybenzoate, methylparaben, butyl p-hydroxybenzoate, ethyl p-hydroxybenzoate, propyl p-hydroxybenzoate, benzyl alcohol, Mixture of phenoxyethanol, phenoxyisopropanol, phenylpropanol, methylchloroisothiazolone and methylisothiazolinone.
上述增黏劑或黏度調節劑包括脂肪酸醇、脂肪酸、羥丙基甲基纖維素、羥甲基纖維素、氯化鈉、氯化銨、丙二醇及己二醇。The above tackifiers or viscosity modifiers include fatty acid alcohols, fatty acids, hydroxypropyl methylcellulose, hydroxymethylcellulose, sodium chloride, ammonium chloride, propylene glycol, and hexanediol.
上述pH值調節劑包括乙酸、乳酸、己二酸、胺基乙基丙二醇、胺基甲基丙二醇、胺基甲基丙醇、胺基丙二醇、抗壞血酸、壬二酸（Azelaic acid）、苯甲酸、丁基二乙醇胺、丁基乙醇胺、檸檬酸、二丁基乙醇胺、二乙醇胺、二異丙胺、二異丙醇胺、二甲基異丙醇胺、半乳糖醛酸（Galacturonic acid）、乙醇酸（Glycolic acid）、異丙醇胺、異丙胺、蘋果酸、丙二酸（Malonic acid）及甲基乙醇胺（Methylethanolamine）。The above pH adjusting agent includes acetic acid, lactic acid, adipic acid, aminoethyl propylene glycol, aminomethyl propylene glycol, aminomethyl propanol, amino propylene glycol, ascorbic acid, azelaic acid, benzoic acid, Butyl diethanolamine, butylethanolamine, citric acid, dibutylethanolamine, diethanolamine, diisopropylamine, diisopropanolamine, dimethylisopropanolamine, galacturonic acid, glycolic acid Glycolic acid), isopropanolamine, isopropylamine, malic acid, malonic acid, and methylethanolamine.
上述有機溶劑包括正丁醇、第三丁醇、苄醇、苯乙醇、己醇、異丙醇、甲醇、油醇、丙醇、環己烷二甲醇、苯氧基乙醇、丁氧基乙醇、乙氧基乙醇、甲氧基乙醇、甲氧基二甘醇、丁二醇、丙二醇（propylene glycol）、戊二醇、己二醇、苄基二醇（benzyl glycol）、二甘醇、二丙二醇、1,2-丁二醇、1,4-丁二醇、2,3-丁二醇、丙二醇（Propanediol）、1,5-戊二醇、異戊二醇、乙基己二醇、1,2-己二醇、1,2,6-己三醇、1,10-癸二醇、3-甲氧基丁醇、甲氧基異丙醇、甲氧基丁醇、碳酸乙二酯、碳酸丙二酯及其混合物。The above organic solvent includes n-butanol, tert-butanol, benzyl alcohol, phenylethyl alcohol, hexanol, isopropanol, methanol, oleyl alcohol, propanol, cyclohexanedimethanol, phenoxyethanol, butoxyethanol, Ethoxyethanol, methoxyethanol, methoxydiglycol, butanediol, propylene glycol, pentanediol, hexanediol, benzyl glycol, diethylene glycol, dipropylene glycol 1,2-butanediol, 1,4-butanediol, 2,3-butanediol, propylene glycol (Propanediol), 1,5-pentanediol, isoprene glycol, ethyl hexanediol, 1 , 2-hexanediol, 1,2,6-hexanetriol, 1,10-nonanediol, 3-methoxybutanol, methoxyisopropanol, methoxybutanol, ethylene carbonate , propylene carbonate and mixtures thereof.
另外，可更含有的成分中的保濕劑並無限制，可使用甘油、多元醇、丙二醇、1,3-丁二醇、二丙二醇，山梨醇酐等，色素可使用常用於頭皮及毛髮用製劑的成分，並無特別限制。Further, the humectant in the component which can be further contained is not limited, and glycerin, polyhydric alcohol, propylene glycol, 1,3-butylene glycol, dipropylene glycol, sorbitol anhydride or the like can be used, and the pigment can be used in preparations for scalp and hair. The composition is not particularly limited.
包括上述組成的本發明的毛髮護理用組成物使用陽離子界面活性劑、糖界面活性劑及胺基酸界面活性劑，因此可改善毛髮的糾結而提高毛髮的柔順感，可提高毛髮的彈力及蓬鬆感，較佳為可提高毛髮的彈力及蓬鬆感。The hair care composition of the present invention comprising the above composition uses a cationic surfactant, a sugar surfactant, and an amino acid surfactant, thereby improving hair entanglement and improving hair suppleness, and improving hair elasticity and fluffiness. The feeling is preferably to improve the elasticity and fluffiness of the hair.
因此，本發明的毛髮護理用組成物可用於改善毛髮的糾結，增進彈力或增進蓬鬆感，更佳為可用於增進毛髮的彈力或增進蓬鬆感。Therefore, the hair care composition of the present invention can be used for improving the entanglement of the hair, enhancing the elasticity or enhancing the feeling of bulkiness, and more preferably for enhancing the elasticity of the hair or enhancing the feeling of bulkiness.
本發明的毛髮護理用組成物可應用於護髮素、潤髮素、髮乳、髮露、頭皮修護膜、養髮露、髮妝水噴霧、毛髮營養化妝水、焗油膏、濃縮精華素、護髮精華液、慕絲、髮蠟、造型噴霧、造型凝膠或頭皮修護素等可使用於毛髮的所有劑型。此時，劑型化的方法並無特別限定，可無限制地使用本技術領域內公知的通常的方法。The hair care composition of the present invention can be applied to hair conditioner, conditioner, hair cream, hair lotion, scalp repair film, hair care lotion, hair makeup spray, hair nutrition lotion, oyster cream, concentrated essence , hair care essence, mousse, hair wax, styling spray, styling gel or scalp conditioner can be used in all dosage forms of hair. In this case, the method of dosage form is not particularly limited, and a usual method known in the art can be used without limitation.
以下，為了具體地說明本發明，列舉實施例而詳細地進行說明。然而，本發明的實施例可變更成其他多種形態，不應解釋為本發明的範圍限定於下文中詳述的實施例。本發明的實施例是為了向於業界具有常識者更完整地說明本發明而提供。Hereinafter, the present invention will be specifically described by way of examples in order to specifically describe the present invention. However, the embodiments of the present invention can be modified into other various forms, and the scope of the present invention should not be construed as being limited to the embodiments detailed below. The embodiments of the present invention are provided to more fully illustrate the present invention to those skilled in the art.
實施例Example 11 至實施例To the embodiment 1111 及比較例And comparative examples 11 至比較例To comparative example 6.6. 毛髮護理用組成物的製備Preparation of hair care compositions
按照下述表1及表2的組成及含量製備乳膏劑型的沖洗型毛髮護理用組成物。A rinse-type hair care composition of a cream type was prepared in accordance with the compositions and contents of Tables 1 and 2 below.
[表1] （單位：重量%）
[表2] （單位：重量%）
實驗例Experimental example 1.1. 毛髮彈力的測定Determination of hair elasticity
為了評估於上述實施例1至實施例9及比較例1至比較例6中製備的毛髮護理用組成物的彈力效果，於以所製備的上述組成物處理毛髮後測定毛髮的彈性力。In order to evaluate the elastic effect of the hair care composition prepared in the above Examples 1 to 9 and Comparative Examples 1 to 6, the elastic force of the hair was measured after the hair was treated with the prepared composition.
此時使用的毛髮是利用不具有調整功能的基礎洗髮精清洗髮束（tress）（phenix korea公司製造），漂洗1分鐘，吹乾2分鐘，之後塗抹0.3 g的上述實施例1至實施例9及比較例1至比較例6的毛髮護理用組成物。The hair used at this time was washed with a basic shampoo having no adjustment function (tress (manufactured by phenix korea), rinsed for 1 minute, dried for 2 minutes, and then applied with 0.3 g of the above Examples 1 to Examples. 9 and the hair care compositions of Comparative Examples 1 to 6.
利用多功能毛髮測定機MTT175（DiaStron公司製造）設備對塗抹有上述實施例1至實施例9及比較例1至比較例6的毛髮護理用組成物的毛髮測定毛髮的彈性力。The elastic force of the hair was measured on the hairs to which the hair care compositions of the above-described Examples 1 to 9 and Comparative Examples 1 to 6 were applied by a multi-functional hair measuring machine MTT175 (manufactured by DiaStron Co., Ltd.).
具體而言，將塗抹有上述實施例1至實施例9及比較例1至比較例6的毛髮護理用組成物的髮束固定成高1.5 cm的拱形形態。接著，將初始力設為0.001 N而利用推拉活塞以每秒增加0.001 N的力加壓。此時，自拱形形態的頂點沿垂直方向施加上述力，於加壓的同時，在安裝有上述推拉活塞的測定構件測定壓力。於測定到毛髮的拱形形態崩塌處的力後，反覆執行30次上述操作。此時，毛髮的彈力是指於將毛髮彎曲成拱形形態後，在按壓中心點時毛髮所支撐的力，支撐的力越大，則意味著毛髮的彈力越大。將此時獲得的結果示於圖1。Specifically, the hair bundles to which the hair care compositions of the above-described Examples 1 to 9 and Comparative Examples 1 to 6 were applied were fixed to an arch shape of 1.5 cm in height. Next, the initial force was set to 0.001 N and pressurized with a force of 0.001 N per second by a push-pull piston. At this time, the force is applied in the vertical direction from the vertex of the arch shape, and the pressure is measured, and the pressure is measured by the measuring member to which the push-pull piston is attached. After the force at which the arched shape of the hair was collapsed was measured, the above operation was repeated 30 times. At this time, the elasticity of the hair refers to the force supported by the hair when the hair is bent into an arch shape, and the greater the supporting force, the greater the elasticity of the hair. The results obtained at this time are shown in Fig. 1.
根據圖1的結果，可確認到如下情形：相較於未經處理的毛髮及利用比較例1至比較例6的毛髮護理用組成物進行處理的毛髮，利用以本發明的較佳的含量範圍包括陽離子界面活性劑、糖界面活性劑及胺基酸界面活性劑，並且亦以較佳的重量比範圍包括糖界面活性劑及胺基酸界面活性劑的實施例1至實施例5的毛髮護理用組成物進行處理的毛髮的彈力增加。According to the results of Fig. 1, it was confirmed that the hair treated with the hair care compositions of Comparative Examples 1 to 6 was used in comparison with the untreated hair and the hair having the hair care composition of Comparative Examples 1 to 6 to utilize the preferred content range of the present invention. Hair care of Examples 1 to 5 including a cationic surfactant, a sugar surfactant, and an amino acid surfactant, and also including a sugar surfactant and an amino acid surfactant in a preferred weight ratio range The elasticity of the hair treated with the composition is increased.
另外，利用以10:1的重量比包括糖界面活性劑及胺基酸界面活性劑的實施例6的毛髮護理用組成物進行處理的毛髮表現出彈力亦優異的結果，利用以超過10:1的重量比包括糖界面活性劑及胺基酸界面活性劑的實施例8的毛髮護理用組成物進行處理的毛髮因糖界面活性劑增加而表現出優異的彈力。In addition, the hair treated with the hair care composition of Example 6 including a sugar surfactant and an amino acid surfactant in a weight ratio of 10:1 exhibited excellent elasticity, and was utilized at more than 10:1. The hair treated with the hair care composition of Example 8 including the sugar surfactant and the amino acid surfactant showed an excellent elastic force due to an increase in the sugar surfactant.
利用以1:1的重量比包括糖界面活性劑及胺基酸界面活性劑的實施例7的毛髮護理用組成物進行處理的毛髮及利用以未滿1:1的重量比包括糖界面活性劑及胺基酸界面活性劑的實施例9的毛髮護理用組成物進行處理的毛髮因糖界面活性劑的含量減少而增加毛髮彈力的效果甚微。Hair treated with the hair care composition of Example 7 comprising a sugar surfactant and an amino acid surfactant in a weight ratio of 1:1 and using a sugar surfactant at a weight ratio of less than 1:1 The hair treated with the hair care composition of Example 9 of the amino acid surfactant was less effective in reducing hair elasticity due to a decrease in the content of the sugar surfactant.
與此相反，利用不包括糖界面活性劑及胺基酸界面活性劑的比較例1及比較例4的毛髮護理用組成物進行處理的毛髮與僅包括胺基酸界面活性劑而不包括糖界面活性劑的比較例2及比較例5的毛髮護理用組成物進行處理的毛髮的彈力與未經處理的毛髮相似，利用雖包括糖界面活性劑但不包括胺基酸界面活性劑的比較例3及比較例6的毛髮護理用組成物進行處理的毛髮的彈力較未經處理的毛髮增加，但彈力增加小於實施例1至實施例6及實施例8。In contrast, the hair treated with the hair care compositions of Comparative Example 1 and Comparative Example 4 which did not include the sugar surfactant and the amino acid surfactant did not include the amino acid surfactant and did not include the sugar interface. The elasticity of the hair treated with the hair care composition of Comparative Example 2 and Comparative Example 5 of the active agent was similar to that of the untreated hair, and Comparative Example 3 including a sugar surfactant but not including an amino acid surfactant was used. The elasticity of the hair treated with the hair care composition of Comparative Example 6 was increased as compared with the untreated hair, but the elastic force was increased less than those of Examples 1 to 6 and Example 8.
根據上述內容可知，本發明的毛髮護理用組成物具有提高毛髮彈力的效果。From the above, it is understood that the hair care composition of the present invention has an effect of improving hair elasticity.
實驗例Experimental example 2.2. 毛髮蓬鬆感的測定Determination of hair fluffiness
為了評估於上述實施例1至實施例9及比較例1至比較例6中製備的毛髮護理用組成物的彈力效果，於以所製備的上述組成物對毛髮進行處理後，測定毛髮的蓬鬆感。In order to evaluate the elastic effect of the hair care composition prepared in the above Examples 1 to 9 and Comparative Examples 1 to 6, the hair was measured after the hair was treated with the prepared composition. .
此時使用的毛髮是利用不具有調整功能的基礎洗髮精清洗髮束（phenix korea公司製造），漂洗1分鐘，吹乾2分鐘，之後塗抹0.3 g的實施例1至實施例9及比較例1至比較例6的毛髮護理用組成物。The hair used at this time was washed with a basic shampoo having no adjustment function (manufactured by phenix korea), rinsed for 1 minute, dried for 2 minutes, and then applied with 0.3 g of Example 1 to Example 9 and a comparative example. 1 to a hair care composition of Comparative Example 6.
利用多功能毛髮測定機MTT175（DiaStron公司製造）設備測定髮束通過固定直徑時的阻力來測定蓬鬆感，將結果示於圖2。The bulkiness was measured by measuring the resistance of the hair bundle through a fixed diameter using a multi-functional hair measuring machine MTT175 (manufactured by DiaStron Co., Ltd.), and the results are shown in Fig. 2 .
根據圖2的結果，可確認到如下情形：相較於未經處理的毛髮及利用比較例1至比較例6的毛髮護理用組成物進行處理的毛髮，利用以本發明的較佳的含量範圍包括陽離子界面活性劑、糖界面活性劑及胺基酸界面活性劑，並且亦以較佳的重量比範圍包括糖界面活性劑及胺基酸界面活性劑的實施例1至實施例5的毛髮護理用組成物進行處理的毛髮的蓬鬆感增加。According to the results of Fig. 2, it was confirmed that the hair treated with the hair care compositions of Comparative Examples 1 to 6 was used as compared with the untreated hair and the preferred content range of the present invention. Hair care of Examples 1 to 5 including a cationic surfactant, a sugar surfactant, and an amino acid surfactant, and also including a sugar surfactant and an amino acid surfactant in a preferred weight ratio range The fluffiness of the hair treated with the composition is increased.
另外，利用以10:1的重量比包括糖界面活性劑及胺基酸界面活性劑的實施例6的毛髮護理用組成物進行處理的毛髮表現出蓬鬆感亦優異的結果，利用以超過10:1的重量比包括糖界面活性劑及胺基酸界面活性劑的實施例8的毛髮護理用組成物進行處理的毛髮因胺基酸界面活性劑減少而未能表現出充分提高蓬鬆感的效果，但效果優於比較例1至比較例6。In addition, the hair treated with the hair care composition of Example 6 including a sugar surfactant and an amino acid surfactant in a weight ratio of 10:1 showed excellent results of bulkiness and was utilized at more than 10: The hair treated with the hair care composition of Example 8 including the sugar surfactant and the amino acid surfactant at a weight ratio of 1 failed to exhibit an effect of sufficiently improving the bulkiness due to a decrease in the amino acid surfactant. However, the effect was superior to Comparative Example 1 to Comparative Example 6.
利用以1:1的重量比包括糖界面活性劑及胺基酸界面活性劑的實施例7的毛髮護理用組成物進行處理的毛髮及利用以未滿1:1的重量比包括糖界面活性劑及胺基酸界面活性劑的實施例9的毛髮護理用組成物進行處理的毛髮因胺基酸界面活性劑的含量增加而表現出增加毛髮的蓬鬆感的效果。Hair treated with the hair care composition of Example 7 comprising a sugar surfactant and an amino acid surfactant in a weight ratio of 1:1 and using a sugar surfactant at a weight ratio of less than 1:1 The hair treated with the hair care composition of Example 9 and the amino acid surfactant showed an effect of increasing the bulkiness of the hair due to an increase in the content of the amino acid surfactant.
與此相反，利用不包括糖界面活性劑及胺基酸界面活性劑的比較例1及比較例4的毛髮護理用組成物進行處理的毛髮的蓬鬆感較未經處理的毛髮減少。另外，利用僅包括胺基酸界面活性劑而不包括糖界面活性劑的比較例2及比較例5的毛髮護理用組成物進行處理的毛髮的蓬鬆感較未經處理的毛髮略微增加，但未能表現出實施例1至實施例9的程度的效果。利用僅包括糖界面活性劑而不包括胺基酸界面活性劑的比較例3的毛髮護理用組成物進行處理的毛髮表現出蓬鬆感與未經處理的毛髮相似的結果。利用組成與比較例3相同但糖界面活性劑含量高於比較例3的比較例6的毛髮護理用組成物進行處理的毛髮的蓬鬆感較未經處理的毛髮減少。On the contrary, the hair treated with the hair care composition of Comparative Example 1 and Comparative Example 4 which did not include the sugar surfactant and the amino acid surfactant was less bulky than the untreated hair. In addition, the hairiness of the hair treated with the hair care composition of Comparative Example 2 and Comparative Example 5 including only the amino acid surfactant and not including the sugar surfactant was slightly increased compared with the untreated hair, but not The effect of the degree of Example 1 to Example 9 can be exhibited. The hair treated with the hair care composition of Comparative Example 3 including only the sugar surfactant and not including the amino acid surfactant exhibited a result similar to the untreated hair. The hair having the same composition as that of Comparative Example 3 but having a higher sugar surfactant content than the hair care composition of Comparative Example 3 of Comparative Example 3 was less bulky than untreated hair.
根據上述內容可知，本發明的毛髮護理用組成物具有提高毛髮的蓬鬆感的效果。According to the above, the hair care composition of the present invention has an effect of improving the bulkiness of the hair.
實驗例Experimental example 3.3. 毛髮糾結的測定Hair entanglement
為了評估於上述實施例1至實施例9及比較例1至比較例6中製備的毛髮護理用組成物的糾結改善效果，於以所製備的上述組成物對毛髮進行處理後，測定毛髮的梳理阻力。In order to evaluate the tangled improvement effect of the hair care composition prepared in the above Examples 1 to 9 and Comparative Examples 1 to 6, the hair combing was measured after the hair was treated with the prepared composition described above. resistance.
毛髮的梳理阻力越高，則意味著毛髮的糾結程度越高。The higher the combing resistance of the hair, the higher the degree of entanglement of the hair.
此時使用的毛髮是利用不具有調整功能的基礎洗髮精清洗髮束（phenix korea公司製造），漂洗1分鐘，吹乾2分鐘，之後塗抹0.3 g的上述實施例1至實施例9及比較例1至比較例6的毛髮護理用組成物。The hair used at this time was washed with a basic shampoo having no adjustment function (manufactured by phenix korea), rinsed for 1 minute, dried for 2 minutes, and then applied with 0.3 g of the above-mentioned Examples 1 to 9 and compared. The hair care compositions of Examples 1 to 6.
利用多功能毛髮測定機MTT175（DiaStron公司製造）設備對塗抹有上述實施例1至實施例9及比較例1至比較例6的毛髮護理用組成物的毛髮測定梳理時的髮束阻力來測定毛髮的糾結，將結果示於圖3。The hair of the hair care composition to which the above-mentioned Examples 1 to 9 and Comparative Examples 1 to 6 were applied was measured by the multi-functional hair measuring machine MTT175 (manufactured by DiaStron Co., Ltd.) to measure the hair strand resistance at the time of carding. The entanglement is shown in Figure 3.
根據圖3的結果，可知如下情形：利用以本發明的較佳的含量範圍包括陽離子界面活性劑、糖界面活性劑及胺基酸界面活性劑，並且亦以較佳的重量比範圍包括糖界面活性劑及胺基酸界面活性劑的實施例1至實施例5的毛髮護理用組成物進行處理的毛髮的梳理阻力小於未經處理的毛髮（104.75 gmf）及利用比較例1至比較例6的毛髮護理用組成物進行處理的毛髮，因此糾結程度更低。According to the results of Fig. 3, it is known that the preferred content range of the present invention includes a cationic surfactant, a sugar surfactant, and an amino acid surfactant, and also includes a sugar interface in a preferred weight ratio range. The combing resistance of the hair treated with the hair care composition of Examples 1 to 5 of the active agent and the amino acid surfactant was smaller than that of the untreated hair (104.75 gmf) and the comparative examples 1 to 6. The hair care composition is treated with hair, so the degree of entanglement is lower.
另外，利用以10:1的重量比包括糖界面活性劑及胺基酸界面活性劑的實施例6的毛髮護理用組成物進行處理的毛髮及利用以超過10:1的重量比包括糖界面活性劑及胺基酸界面活性劑的實施例8的毛髮護理用組成物進行處理的毛髮因糖界面活性劑增加而測定到的毛髮糾結程度略高，但表現出低於比較例1至比較例6的結果。Further, the hair treated with the hair care composition of Example 6 comprising a sugar surfactant and an amino acid surfactant in a weight ratio of 10:1 and the use includes a sugar interface activity in a weight ratio exceeding 10:1. The hair treated with the hair care composition of Example 8 of the agent and the amino acid surfactant was slightly higher in hair entanglement measured by the increase in the sugar surfactant, but showed lower than Comparative Example 1 to Comparative Example 6 the result of.
利用以1:1的重量比包括糖界面活性劑及胺基酸界面活性劑的實施例7的毛髮護理用組成物進行處理的毛髮及利用以未滿1:1的重量比包括糖界面活性劑及胺基酸界面活性劑的毛髮護理用組成物進行處理的毛髮因胺基酸界面活性劑的含量增加而表現出優異的毛髮糾結改善效果。Hair treated with the hair care composition of Example 7 comprising a sugar surfactant and an amino acid surfactant in a weight ratio of 1:1 and using a sugar surfactant at a weight ratio of less than 1:1 The hair treated with the hair care composition of the amino acid surfactant exhibits an excellent hair tangling improving effect due to an increase in the content of the amino acid surfactant.
根據上述內容可知，本發明的毛髮護理用組成物具有改善毛髮的糾結而提高毛髮的柔順感的效果。According to the above, the hair care composition of the present invention has an effect of improving the entanglement of the hair and improving the suppleness of the hair.
根據上述實驗例1至實驗例3的結果，可確認到包括糖界面活性劑及胺基酸界面活性劑的本發明的毛髮護理用組成物表現出提高彈力、提高蓬鬆感及改善毛髮糾結的效果。According to the results of the above Experimental Example 1 to Experimental Example 3, it was confirmed that the hair care composition of the present invention comprising a sugar surfactant and an amino acid surfactant exhibits an effect of improving elasticity, improving bulkiness, and improving hair entanglement. .
特別是，以本發明的較佳的含量範圍包括陽離子界面活性劑、糖界面活性劑及胺基酸界面活性劑，並且亦以較佳的重量比範圍包括糖界面活性劑及胺基酸界面活性劑的毛髮護理用組成物的提高彈力、提高蓬鬆感及改善毛髮糾結等三種效果均表現出優異的效果。In particular, preferred levels of the present invention include cationic surfactants, sugar surfactants, and amino acid surfactants, and also include sugar surfactants and amino acid interfacial activity in a preferred weight ratio range. The hair care composition of the agent exhibits excellent effects in three effects of improving elasticity, improving bulkiness, and improving hair entanglement.
另外，實施例3的毛髮護理用組成物的提高彈力、提高蓬鬆感及改善毛髮糾結的效果最優異，藉此可知於使用山崳基三甲基氯化銨作為陽離子界面活性劑、使用辛基/癸基葡萄糖苷作為糖界面活性劑、使用硬脂醯麩胺酸鈉作為胺基酸界面活性劑、使用聚四級銨-55作為陽離子聚合物時，上述效果最優異。Further, the hair care composition of Example 3 is most excellent in the effect of improving the elasticity, improving the bulkiness, and improving the hair entanglement, whereby it is known that the use of behenyltrimethylammonium chloride as a cationic surfactant and the use of an octyl group When the thiol glucoside is used as a sugar surfactant, stearyl glutamate is used as an amino acid surfactant, and poly quaternary ammonium-55 is used as a cationic polymer, the above effects are most excellent.
因此，本發明可克服因彈力及蓬鬆感不優異而毛髮軟塌的先前問題，可將本發明的毛髮護理用組成物廣泛地應用於各種劑型的製品。Therefore, the present invention can overcome the previous problem that the hair is softly collapsed due to the lack of elasticity and bulkiness, and the hair care composition of the present invention can be widely applied to products of various dosage forms.
劑型例Dosage form 1.1. 潤髮素Hair conditioner
按照下述表3的組成及含量，藉由通常的方法製備潤髮素。The conditioner was prepared by a usual method according to the composition and content of Table 3 below.
[表3]
劑型例Dosage form 2.2. 髮露Reveal
按照下述表4的組成及含量，藉由通常的方法製備髮露。The hair repellency was prepared by a usual method according to the composition and content of the following Table 4.
[表4]
劑型例Dosage form 3.3. 護髮精華液Hair care essence
按照下述表5的組成及含量，藉由通常的方法製備護髮精華液。The hair care essence was prepared by a usual method according to the composition and content of Table 5 below.
[表5]
劑型例Dosage form 4.4. 護髮精華素Hair care serum
按照下述表6的組成及含量，藉由通常的方法製備護髮精華素。The hair care essence was prepared by a usual method according to the composition and content of the following Table 6.
[表6]
劑型例Dosage form 5.5. 髮乳Hair milk
按照下述表7的組成及含量，藉由通常的方法製備髮乳。The milk was prepared by a usual method according to the composition and content of the following Table 7.
[表7]
劑型例Dosage form 6.6. 造型劑Styling agent
按照下述表8的組成及含量，藉由通常的方法製備造型劑。The styling agent was prepared by a usual method in accordance with the composition and content of the following Table 8.
[表8]
無no
圖1是表示本發明的實驗例1的測定毛髮的彈性力的結果的圖表。 圖2是表示本發明的實驗例2的測定毛髮的蓬鬆感的結果的圖表。 圖3是表示本發明的實驗例3的測定毛髮的糾結程度的結果的圖表。Fig. 1 is a graph showing the results of measuring the elastic force of hair in Experimental Example 1 of the present invention. Fig. 2 is a graph showing the results of measuring the feeling of bulkiness of hair in Experimental Example 2 of the present invention. Fig. 3 is a graph showing the results of measuring the degree of entanglement of hair in Experimental Example 3 of the present invention.
Claims (12)
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| KR1020180106345A KR20190034084A (en) | 2017-09-22 | 2018-09-06 | Composition For Hair Care |
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| CN111957228B (en) * | 2020-08-11 | 2021-05-07 | 广州碧涛化妆品有限公司 | Emulsifying device and preparation method of pomade |
| KR20220039389A (en) * | 2020-09-22 | 2022-03-29 | (주)아모레퍼시픽 | Composition for Hair Conditioning |
| KR102301510B1 (en) * | 2021-04-29 | 2021-09-13 | 주식회사 리치바이오 | hair treatment composition |
| CN115887315A (en) * | 2022-10-10 | 2023-04-04 | 青岛中科蓝智生物科技发展有限公司 | Application of glycerol glucoside in pet hair conditioning |
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| ATE306889T1 (en) * | 2003-08-08 | 2005-11-15 | Kpss Kao Gmbh | COSMETIC HAIR COMPOSITION CONTAINING CETYL PEG/PPG-10/1 DIMETHICON AND A CERAMIDE |
| KR101351473B1 (en) | 2007-05-17 | 2014-01-14 | 주식회사 엘지생활건강 | Hair conditioner composition having improved sm00thness and slippery feel on dry hair |
| KR20140019427A (en) * | 2011-04-01 | 2014-02-14 | 코그니스 아이피 매니지먼트 게엠베하 | Hair care agent |
| EP2833861B1 (en) * | 2012-04-03 | 2018-06-27 | Basf Se | Hair cosmetic composition which comprises a plant lecithin |
| CN102895151B (en) * | 2012-10-22 | 2014-04-16 | 广州立白企业集团有限公司 | Sulfate-free hair cleanser and preparation method thereof |
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