TW201406554A - Forming method of eco-friendly film and substrate - Google Patents
Forming method of eco-friendly film and substrate Download PDFInfo
- Publication number
- TW201406554A TW201406554A TW101128614A TW101128614A TW201406554A TW 201406554 A TW201406554 A TW 201406554A TW 101128614 A TW101128614 A TW 101128614A TW 101128614 A TW101128614 A TW 101128614A TW 201406554 A TW201406554 A TW 201406554A
- Authority
- TW
- Taiwan
- Prior art keywords
- substrate
- film
- release paper
- friendly
- molding
- Prior art date
Links
Landscapes
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
Description
本發明係關於一種膜材與基材之成型方法。 The present invention relates to a method of forming a film and a substrate.
按,習用的膜材與基材之製造方法,必須分為兩個廠房來分別製造一基材以及一面膜,其通常係將一基布導引使其經過一浸漬槽內,並經由該浸漬槽內物料的含浸,再將該基布引入一水槽內使其表面膠化凝固,再使用電熱烘乾設備予以乾燥處理以形成基材,另須製造該面膜,接著利用一接著劑使該基材與該面膜相互貼合,即完成合成皮之成品。 According to the conventional method for manufacturing a film and a substrate, it is necessary to divide into two factories to separately manufacture a substrate and a film, which usually guides a substrate through a dipping tank and through the dipping. Impregnation of the material in the tank, the substrate is introduced into a water tank to gelatinize and solidify the surface thereof, and then dried by an electric heating drying device to form a substrate, and the mask is further manufactured, and then the base is made by an adhesive. The material and the mask are adhered to each other, that is, the finished product of the synthetic skin is completed.
惟,習用的合成皮的製造過程中無論基材或面膜的製造均使用了大量的溶劑,其會對環境造成嚴重的環境污染,或經由人體吸收而導致中毒,另外,於貼合步驟時使用之接著劑亦為溶劑,同樣會有前述之環境汙染等現象,且基材與面膜須分為兩個廠房來分別製造,再利用接著劑使基材與面膜相互貼合,而無論是基材或面膜均分多次流程製造,其廠房的使用空閒大,且習用基材或面膜的製造均使用了電熱烘乾設備,耗費相當多的電力、人力等生產成本,另,該基布之邊料因為面積小,對於加工及製作過程並無再利用性,多將其廢棄,以廢料處理,而該廢料之處理方式係掩埋在一垃圾掩埋場或在一焚化爐設備中焚毀,除了造成環境污染外,亦會使地區生物產生健康問題,因此,如何研發出一種不使用烘箱、溶劑,且具有節能減碳、環保效益之環保型膜材與基材之成型方法,確實有其必要。 However, in the manufacturing process of the conventional synthetic skin, a large amount of solvent is used in the manufacture of the substrate or the mask, which causes serious environmental pollution to the environment, or poisoning through absorption by the human body, and is used in the laminating step. The adhesive is also a solvent, and the above-mentioned environmental pollution is also caused, and the substrate and the mask must be divided into two factories to be separately manufactured, and then the adhesive is used to bond the substrate and the mask to each other, regardless of the substrate. Or the mask is manufactured in multiple processes, the use of the factory is idle, and the manufacture of the substrate or the mask uses electrothermal drying equipment, which consumes a considerable amount of electricity, labor and other production costs, and the edge of the base fabric Because of the small area, it is not reusable for the processing and production process. It is discarded and disposed of as waste. The waste is disposed of in a landfill or burned in an incinerator facility, except for the environment. In addition to pollution, it will also cause health problems in local organisms. Therefore, how to develop an environmentally friendly membrane that does not use ovens, solvents, and has energy-saving, carbon-reducing and environmental benefits. A method of forming a substrate and, indeed its necessity.
本發明之主要目的,係在於提供一種環保型膜材與基材之成型方法,特別是一種不使用烘箱、溶劑,且具有節能減碳及環保效益。 The main object of the present invention is to provide a method for forming an environment-friendly film and a substrate, in particular, an oven and a solvent are not used, and the utility model has the advantages of energy saving, carbon reduction and environmental protection.
本發明之環保型膜材與基材之成型方法,包含有下列步驟:將一第一離型紙往預定方向輸送,再取一第一灌注設備置於該第一離型紙上方,將聚胺基甲酸酯(PU)灌注於該第一離型紙表面以成型一透明之膜材,再取一第二灌注設備置於該離型紙上方,將發泡之聚胺基甲酸酯(PU)灌注於該膜材表面以成型一基材,其中,該基材係利用該第二灌注設備以機械發泡之方式而產生發泡之聚胺基甲酸酯(PU),再將一基布貼合於該基材之頂面,最後利用一捲收裝置將成品於適當位置加以捲收,而獲得環保型膜材與基材之成品。 The method for molding an environment-friendly membrane and a substrate of the present invention comprises the steps of: conveying a first release paper in a predetermined direction, and then taking a first filling device placed above the first release paper to form a polyamine group; A formate (PU) is poured on the surface of the first release paper to form a transparent film, and a second infusion device is placed on the release paper to infuse the foamed polyurethane (PU). Forming a substrate on the surface of the film, wherein the substrate uses the second infusion device to mechanically foam to produce a foamed polyurethane (PU), and then attach a base cloth In combination with the top surface of the substrate, the finished product is finally taken up in a proper position by a retracting device to obtain an environmentally friendly film and a finished product of the substrate.
藉此,可縮短製程、節省廠房設備及人力物力的浪費,以及降低生產成本之效用,且不使用發泡劑或接著劑等化學溶劑,具有節能減碳及環保效益。 Thereby, the process can be shortened, the waste of plant equipment and manpower and material resources can be reduced, and the utility of the production cost can be reduced, and the chemical solvent such as a foaming agent or an adhesive agent can be used without energy saving, carbon reduction and environmental protection benefits.
敬請配合參閱第一圖所示,本發明合環保型膜材與基材之成型方法係包括有下列步驟:將一第一離型紙10往預定方向輸送,其中,該第一離型紙10係具有預定紋路。 Please refer to the first figure, the method for molding the environmentally friendly film and substrate of the present invention includes the following steps: conveying a first release paper 10 in a predetermined direction, wherein the first release paper 10 is Has a predetermined texture.
取一第一灌注設備20置於該第一離型紙10上方,將聚胺基甲酸酯(PU)灌注於該第一離型紙10表面以成型一透明之膜材11,其中,該第一灌注設備20係包含一混合槽21,其槽內設有一螺桿22,並於 該混合槽21的底部設有一灌注口23,藉此,將一含有NCO之異氰酸鹽聚合物24與一含有OH之羥化合物入料25至該混合槽內混合後,混合成一液態之聚氨基甲酸酯(PU),並灌注於該第一離型紙10表面以成型該膜材11,而該第一離型紙10係在逐漸反應的狀態下再往前輸送。 A first filling device 20 is placed above the first release paper 10, and a polyurethane is poured onto the surface of the first release paper 10 to form a transparent film 11, wherein the first The filling device 20 comprises a mixing tank 21, a screw 22 is arranged in the groove, and The bottom of the mixing tank 21 is provided with a filling port 23, whereby an NCO-containing isocyanate polymer 24 is mixed with an OH-containing hydroxy compound feed 25 into the mixing tank, and then mixed into a liquid mixture. A urethane (PU) is poured on the surface of the first release paper 10 to form the film 11, and the first release paper 10 is conveyed further in a gradual reaction state.
於該膜材11頂面貼合一第二離型紙30,該第二離型紙30係在該膜材11逐漸反應的狀態下即利用一滾輪31加以貼合,並於該膜材11行進一段距離後,即利用另一滾輪32加以剝離,使該膜材11表面被稍微整平而更加均勻。 A second release paper 30 is attached to the top surface of the film 11, and the second release paper 30 is adhered by a roller 31 in a state in which the film 11 is gradually reacted, and travels on the film 11 After the distance, the other roller 32 is used for peeling off, so that the surface of the film 11 is slightly flattened and more uniform.
取一第二灌注設備40置於該第一離型紙10上方,將發泡之聚胺基甲酸酯(PU)灌注於該膜材11表面以成型一發泡之基材12,其中,該第二灌注設備40之結構係與該第一灌注設備20相同,藉此,將一含有NCO之異氰酸鹽聚合物41、一含有OH之羥化合物42、一空氣(Air)43、一氮氣(N2)44及一射料(Color)45分別入料至該混合槽內混合後,利用該第二灌注設備40以機械發泡之方式而產生發泡之聚胺基甲酸酯(PU),並射出灌注於該膜材11表面以成型該基材12,而該第一離型紙10係在逐漸反應的狀態下再往前輸送。 A second infusion device 40 is placed on the first release paper 10, and a foamed polyurethane (PU) is poured on the surface of the film 11 to form a foamed substrate 12, wherein The structure of the second filling device 40 is the same as that of the first filling device 20, whereby an isocyanate polymer 41 containing NCO, a hydroxy compound 42 containing OH, an air (43), and a nitrogen gas are used. After (N 2 ) 44 and a color 45 are respectively fed into the mixing tank and mixed, the second perfusion apparatus 40 is used to mechanically foam to produce a foamed polyurethane (PU). And injecting the surface of the film 11 to form the substrate 12, and the first release paper 10 is transported forward in a state of gradual reaction.
於該基材12頂面貼合一第三離型紙50,該第三離型紙50係在該基材12逐漸反應的狀態下即利用一滾輪51加以貼合,並於該基材12行進一段距離後,即利用另一滾輪52加以剝離,使該基材12表面被稍微整平而更加均勻。 A third release paper 50 is attached to the top surface of the substrate 12, and the third release paper 50 is attached to the substrate 12 by a roller 51 in a state in which the substrate 12 is gradually reacted. After the distance, the other roller 52 is used for peeling off, so that the surface of the substrate 12 is slightly flattened and more uniform.
再將一基布13貼合於該基材12之頂面,其中,該基布13係可由 不織布、超細纖維或其類似物所構成。 A base fabric 13 is attached to the top surface of the substrate 12, wherein the base fabric 13 can be Nonwoven fabric, microfiber or the like.
最後,利用一捲收裝置60將成品於適當位置加以捲收,獲得環保型膜材與基材之成品,而可完成本發明之製程。 Finally, the finished product is wound up at a suitable position by a retracting device 60 to obtain a finished product of the environment-friendly film and the substrate, and the process of the present invention can be completed.
為供進一步瞭解本發明構造特徵、運用技術手段及所預期達成之功效,茲將本發明使用方式加以敘述,相信當可由此而對本發明有更深入且具體之瞭解,如下所述: 本發明係利用該第一灌注設備20,先於該第一離型紙10表面成型該膜材11,並於該膜材11在半反應而未完全硬化的狀態下,再利用該第二灌注設備40,將發泡之聚胺基甲酸酯(PU)灌注於該膜材11表面以成型該基材12,使該膜材11與該基材12相互接著,再於該基材12在半反應而未完全硬化的狀態下,貼合該基布13,使其相互接著,以完成環保型膜材與基材之成品,免除習用各別製造、製程複雜、儲存及堆積物料空間大,故本發明具有縮短製程、節省廠房設備及人力物力的浪費,以及降低生產成本之效用。 For a further understanding of the structural features of the present invention, the application of the technical means, and the intended effect, the manner of use of the present invention will be described. It is believed that the present invention may be more deeply and specifically understood as follows: The present invention utilizes the first infusion device 20 to form the film 11 prior to the surface of the first release paper 10, and reuse the second infusion device in a state in which the film 11 is not fully cured in a semi-reactive manner. 40, a foamed polyurethane (PU) is poured on the surface of the film 11 to form the substrate 12, the film 11 and the substrate 12 are mutually adhered, and then the substrate 12 is half In the state in which the reaction is not completely cured, the base fabric 13 is bonded to each other to complete the environmentally-friendly film and the finished product of the substrate, thereby eliminating the need for separate manufacturing, complicated process, large storage and accumulation material space, The invention has the effects of shortening the process, saving waste of plant equipment and manpower and material resources, and reducing production cost.
該膜材11、該基材12兩者均具有聚胺基甲酸酯(PU)的成份,故可完全相容外,又因其係在該膜材11未完全熟成、硬化的狀態下予以灌注、成型該基材12,更使該膜材11、該基材12相互接著,且於該基材12在半反應而未完全熟成、硬化的狀態下貼合該基布13,故可利用該基材12未完全熟成、硬化之黏性,而穩固的貼合該基布13。 The film 11 and the substrate 12 both have a polyurethane (PU) component, so that they are completely compatible, and because the film 11 is not fully matured and hardened. The base material 12 is poured and molded, and the film material 11 and the base material 12 are mutually adhered to each other, and the base material 13 is bonded to the base material 13 in a state in which the base material 12 is half-reacted and not fully cooked and hardened. The substrate 12 is not fully cooked, hardened and adhered to the base fabric 13 in a stable manner.
本發明係採機械發泡之方式產生發泡之聚胺基甲酸酯,因此,本發明於該膜材11上灌注、成型該基材12之步驟,僅會使該膜材11、該基材12相容、相接著,其製程穩定。 In the present invention, the foamed polyurethane is produced by mechanical foaming. Therefore, the step of injecting and molding the substrate 12 on the film 11 of the present invention only causes the film 11 and the substrate. The material 12 is compatible and, in turn, the process is stable.
本發明並不使用發泡劑或接著劑等化學溶劑,故本發明沒有因溶劑所易於產生火災的問題,且不會對空氣、水均會造成污染,而可符合環保之要求。 The present invention does not use a chemical solvent such as a foaming agent or an adhesive. Therefore, the present invention does not have a problem of causing a fire due to a solvent, and does not cause pollution to air or water, and can meet environmental protection requirements.
本發明之該基布13更可選自布料、皮料或其類似物之其中一種之邊料或廢材經回收再製之底材所構成,該基布13於貼合於該基材12頂面時,該基材12仍在半反應而未完全硬化的狀態下,此時該基材12將滲入該基布13間之間隙,過程中,該基材12將逐步反應、熟成與硬化,更加強該基材12與該基布13之間的連接,其中,該基布13係選自布料、皮料或其類似物之其中一種之邊料或廢材經回收再製之底材所構成,故符合再生利用之環保效益,亦可藉此廢物利用之作法降低生產成本、增加產業競爭力。 The base fabric 13 of the present invention may be further selected from the side material or the waste material of the fabric, the leather material or the like, which is formed by recycling the reconstituted substrate, and the base fabric 13 is attached to the top of the substrate 12 In the case of the surface, the substrate 12 is still in a semi-reactive state and is not completely cured. At this time, the substrate 12 will penetrate into the gap between the base fabrics 13, and the substrate 12 will gradually react, mature and harden during the process. The connection between the substrate 12 and the base fabric 13 is further enhanced, wherein the base fabric 13 is selected from the group consisting of a fabric, a leather material or the like, or a waste material which is recovered and reconstituted. Therefore, it is in line with the environmental benefits of recycling, and it can also be used to reduce production costs and increase industrial competitiveness.
本發明之該基布13更可選自不織布、彈性布、PE膜、PET膜及橡膠膜之其中一種經回收再製之底材所構成,另一實施例中該基布13係為PET膜經回收、抽絲再製之底材所構成,故符合再生利用之環保效益,亦可藉此廢物利用之作法降低生產成本、增加產業競爭力。 The base fabric 13 of the present invention may be further selected from the group consisting of a non-woven fabric, an elastic fabric, a PE film, a PET film and a rubber film, and the recycled fabric substrate. In another embodiment, the base fabric 13 is a PET film. Recycling, spinning and reconstituting the substrate, it is in line with the environmental benefits of recycling, and can also use this waste to reduce production costs and increase industrial competitiveness.
本發明之該基布13更可選自編織纖維布、針織纖維布或其類似物之其中一種所構成,且該基布13更利用熱昇華、熱轉印或UV印刷之其中一種方式將圖案成型於該基布13,而使該基布13上具有圖案。 The base fabric 13 of the present invention may be further selected from one of woven fabric, knitted fabric or the like, and the base fabric 13 further adopts one of thermal sublimation, thermal transfer or UV printing to pattern. The base fabric 13 is molded to have a pattern on the base fabric 13.
茲,再將本發明之特徵及其可達成之預期功效陳述如下: Hereafter, the features of the present invention and its achievable efficacy are stated as follows:
1、本發明係利用二灌注設備成型環保型模材與基材,具有縮短製程、節省廠房設備及人力物力的浪費,以及降低生產成本之效用。 1. The invention utilizes a two-infusion device to form an environmentally-friendly molding material and a substrate, which has the effects of shortening the process, saving waste of plant equipment and manpower and material resources, and reducing production cost.
2、環保型膜材與基材係利用其未完全熟成、硬化來相互接著,不 使用化學溶劑,符合環保之要求。 2, environmentally friendly membranes and substrates are not fully matured and hardened to follow each other, not Use chemical solvents to meet environmental requirements.
3、本發明之基布係可選用回收再製之底材所構成,更符合再生利用之環保效益。 3. The base fabric of the present invention can be composed of recycled and reconstituted substrates, and is more in line with the environmental benefits of recycling.
綜上所述,本發明在同類產品中實有其極佳之進步實用性,同時遍查國內外關於此類結構之技術資料,文獻中亦未發現有相同的構造存在在先,是以,本發明實已具備發明專利要件,爰依法提出申請。 In summary, the present invention has excellent advancement and practicability in similar products, and at the same time, the technical materials of such structures are frequently investigated at home and abroad, and the same structure is not found in the literature. The invention already has the invention patent requirements, and the application is filed according to law.
惟,以上所述者,僅係本發明之一較佳可行實施例而已,故舉凡應用本發明說明書及申請專利範圍所為之等效結構變化,理應包含在本發明之專利範圍內。 However, the above-mentioned ones are merely preferred embodiments of the present invention, and the equivalent structural changes of the present invention and the scope of the claims are intended to be included in the scope of the present invention.
10‧‧‧第一離型紙 10‧‧‧First release paper
11‧‧‧膜材 11‧‧‧membrane
12‧‧‧基材 12‧‧‧Substrate
13‧‧‧基布 13‧‧‧Kib
20‧‧‧第一灌注設備 20‧‧‧First filling equipment
21‧‧‧混合槽 21‧‧‧ mixing tank
22‧‧‧螺桿 22‧‧‧ screw
23‧‧‧灌注口 23‧‧‧Infusion port
24‧‧‧異氰酸鹽聚合物 24‧‧‧Isocyanate polymer
25‧‧‧羥化合物 25‧‧‧Hydroxy compounds
30‧‧‧第二離型紙 30‧‧‧Second release paper
31‧‧‧滾輪 31‧‧‧Roller
32‧‧‧滾輪 32‧‧‧Roller
40‧‧‧第二灌注設備 40‧‧‧Second filling equipment
41‧‧‧異氰酸鹽聚合物 41‧‧‧Isocyanate polymer
42‧‧‧羥化合物 42‧‧‧Hydroxy compounds
43‧‧‧空氣 43‧‧‧ Air
44‧‧‧氮氣 44‧‧‧Nitrogen
45‧‧‧射料 45‧‧‧ Shots
50‧‧‧第三離型紙 50‧‧‧ Third release paper
51‧‧‧滾輪 51‧‧‧Roller
52‧‧‧滾輪 52‧‧‧Roller
第一圖係本發明之製造流程圖。 The first figure is a manufacturing flow chart of the present invention.
第二圖係本發明之流程示意圖。 The second drawing is a schematic flow chart of the present invention.
第三圖係本發明沿著第二圖3-3方向之剖視圖。 The third drawing is a cross-sectional view of the present invention along the direction of the second Figure 3-3.
10‧‧‧第一離型紙 10‧‧‧First release paper
11‧‧‧膜材 11‧‧‧membrane
12‧‧‧基材 12‧‧‧Substrate
13‧‧‧基布 13‧‧‧Kib
20‧‧‧第一灌注設備 20‧‧‧First filling equipment
21‧‧‧混合槽 21‧‧‧ mixing tank
22‧‧‧螺桿 22‧‧‧ screw
23‧‧‧灌注口 23‧‧‧Infusion port
24‧‧‧異氰酸鹽聚合物 24‧‧‧Isocyanate polymer
25‧‧‧羥化合物 25‧‧‧Hydroxy compounds
30‧‧‧第二離型紙 30‧‧‧Second release paper
31‧‧‧滾輪 31‧‧‧Roller
32‧‧‧滾輪 32‧‧‧Roller
40‧‧‧第二灌注設備 40‧‧‧Second filling equipment
41‧‧‧異氰酸鹽聚合物 41‧‧‧Isocyanate polymer
42‧‧‧羥化合物 42‧‧‧Hydroxy compounds
43‧‧‧空氣 43‧‧‧ Air
44‧‧‧氮氣 44‧‧‧Nitrogen
45‧‧‧射料 45‧‧‧ Shots
50‧‧‧第三離型紙 50‧‧‧ Third release paper
51‧‧‧滾輪 51‧‧‧Roller
52‧‧‧滾輪 52‧‧‧Roller
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
TW101128614A TW201406554A (en) | 2012-08-08 | 2012-08-08 | Forming method of eco-friendly film and substrate |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
TW101128614A TW201406554A (en) | 2012-08-08 | 2012-08-08 | Forming method of eco-friendly film and substrate |
Publications (2)
Publication Number | Publication Date |
---|---|
TW201406554A true TW201406554A (en) | 2014-02-16 |
TWI508864B TWI508864B (en) | 2015-11-21 |
Family
ID=50550300
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW101128614A TW201406554A (en) | 2012-08-08 | 2012-08-08 | Forming method of eco-friendly film and substrate |
Country Status (1)
Country | Link |
---|---|
TW (1) | TW201406554A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI614140B (en) * | 2016-01-15 | 2018-02-11 | Perfection Mighty Industrial Co Ltd | Method for forming one-dimensional three-dimensional pavement skin and substrate |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI647356B (en) * | 2017-04-24 | 2019-01-11 | 凱力實業股份有限公司 | Environmentally friendly dough and substrate manufacturing method |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5364678A (en) * | 1989-10-17 | 1994-11-15 | Malden Mills Industries, Inc. | Windproof and water resistant composite fabric with barrier layer |
US5680653A (en) * | 1994-12-02 | 1997-10-28 | Kimberly-Clark Worldwide, Inc. | Surgical gown cuff and method for making the same |
US20030060110A1 (en) * | 1999-12-24 | 2003-03-27 | Desai Dilipkumar R. | Expanded extruded polymeric textile |
JP4024019B2 (en) * | 2001-07-23 | 2007-12-19 | 高圧クロス株式会社 | Sheet structure and manufacturing method thereof |
JP4184178B2 (en) * | 2002-07-09 | 2008-11-19 | 株式会社クラレ | Thermoplastic polymer composition |
TWI247674B (en) * | 2004-10-27 | 2006-01-21 | Perfection Mighty Ind Co Ltd | Method for making foaming substrate |
JPWO2010024249A1 (en) * | 2008-08-28 | 2012-01-26 | 株式会社クラレ | Leather-like sheet and manufacturing method thereof |
TW201041726A (en) * | 2009-05-20 | 2010-12-01 | Perfection Mighty Ind Co Ltd | Pattern formation method for breathable synthetic leather |
-
2012
- 2012-08-08 TW TW101128614A patent/TW201406554A/en unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI614140B (en) * | 2016-01-15 | 2018-02-11 | Perfection Mighty Industrial Co Ltd | Method for forming one-dimensional three-dimensional pavement skin and substrate |
Also Published As
Publication number | Publication date |
---|---|
TWI508864B (en) | 2015-11-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102642421A (en) | Preparation method and transfer printing method of film capable of being printed in transfer mode | |
CN102877626B (en) | Rubber floor tile with elastic fitting effect and method for manufacturing rubber floor tile | |
CN102390193B (en) | Film transfer printing method | |
TW201406554A (en) | Forming method of eco-friendly film and substrate | |
CN104095504A (en) | Method for manufacturing rubber floor mat | |
TW393398B (en) | Process for producing polyurethane synthetic leather | |
TWI548481B (en) | Polishing pad and method for making the same | |
CN103660495A (en) | Forming method of environment-friendly film material and base material | |
CN201703047U (en) | Transfer film structure | |
CN1260427C (en) | Synthetic leather manufacturing method in which base material and skin are molded at one time | |
TW201344006A (en) | Double sided polyurethane artificial leather and integrated molding manufacture method thereof | |
CN110920286A (en) | Green double-sided printing method | |
CN202969125U (en) | Environmental-friendly waterborne polyurethane leather for sporting gloves | |
CN109652994A (en) | Two-sided no folding line no-solvent polyurethane luggage synthetic leather of one kind and preparation method thereof | |
CN103525325A (en) | Process flow for manufacturing movable traceless glue | |
CN104309268A (en) | Method for printing pattern on acrylic plate | |
CN202742760U (en) | Adhesive-less composite material | |
CN203129536U (en) | Rubber floor tile with elastic fitting effect | |
CN102416750B (en) | Spraying type water injection device and water injection type double mirror jointing method | |
CN102444055B (en) | Decorative wallpaper material for environmentally-friendly wall and preparation method thereof | |
CN101543813B (en) | Method for manufacturing composite coating material | |
TWI614140B (en) | Method for forming one-dimensional three-dimensional pavement skin and substrate | |
TWI857633B (en) | Continuous Stamping Surface Treatment of Vegetable Leather | |
CN203126099U (en) | Waterborne wet-process bass production line | |
CN202543698U (en) | Novel synthetic leather production line |